Chapter-2 : Chemistry 1st Paper
Knoledge Based Question
1. What is isotope?
2. What is isobar?
3. What is Isotone?
4. What is isoelectronic?
5. What is α-particle?
6. What is light?
7. What is wavelength?
8. What is frequency?
9. What is wave number
10. What is stationary orbit?
11. What are atomic models?
12. What is nucleus?
13. What is quantum number?
14. What is principal quantum number?
15. What is magnetic quantum number?
16. What is spin quantum number?
17. What is orbit?
18. What is orbital?
19. What is node/nodal point/nucleus of
an orbital?
Comprehensive Based question
1. Most of the space inside an atom is
vacant?
2. Why ZnS layer is used in Rutherford
experiment?
3. Why gold foil is used in Rutherford
experiment?
4. Bohr atomic model is applicable for
Li2+/He+-explain.
5. What are Zeemen and sterk effect?
6. What are the significances of
quantum number?
20. What is nodal plane?
21. State Aufbau principle.
22. State Hund’s Law.
23. State Pauli Exclusion Principle.
24. What is H-spectrum?
25. What is atomic spectrum?
26. What is emission spectrum?
27. What is sterk effect?
28. What is Zeemen effect?
29. What is Rydberg constant?
30. What is Balmer series?
31. What is Lymen series?
32. What is flame test?
33. What is MRI?
34. What is angular momentum?
35. What is energy shell?
7. What are the differences between
orbit and orbital?
8. 2p is possible but 2d not-why?
9. 3p is possible but 3f not-why?
10. p-orbital contains maximum six
electrons-why?
11. d-orbital contains maximum ten
electrons-why?
12. f-orbital contains maximum fourteen
electrons-why?
13. Which has higher energy between 4s
and 3d orbital?
14. Which has higher energy between 5s
and 4d orbital?
15. Why does 19th electron of K(19) enter
into 4s instead of 3d?
16. Why does 37th electron of Rb(37)
enter into 5s instead of 4d?
17. Electronic configuration of Cr(24) is
exceptional-why?
18. Electronic configuration of Cu(29) is
exceptional-why?
19. How is H-spectrum obtained?
Explain.
20. Why conc. HCl is used in flame test?
21. How can you detect fake currency by
using UV-light?
22. Why does Mg and Be don’t take
participation in flame test?
23. Explain Pauli Exclusion Principle
considering the example of two
electrons of He atom.
24. Explain Pauli Exclusion Principle
considering the example of last two
electrons of Mg atom.
25. Explain Pauli Exclusion Principle
considering the example of two
electrons of Ca atom.
26. Draw the shape of p-orbital.
27. Na is paramagnetic but Mg is
diamagnetic-why?
28. Fe is paramagnetic but Zn is
diamagnetic-why?
29. N is more paramagnetic than oxygen
-why?
30. What do you mean by dual nature of
electron?

Large Question

1. What are the limitations of Rutherford atomic model?

2. What are the postulates of Neils Bohr atomic model?
3. What are the differences between Rutherford and Bohr models?
4. Which one is more reliable between Rutherford and Bohr atomic models? Analyze
with your logic.
5. Explain the all series of H-spectrum.
6. Calculate the wavelength of a photon when electron jumps from 5th energy level to 2nd
energy level. (Ans: 434nm)
7. What will be wavelength, wavenumber and colour of the radiation originated due to
transition of electron from 4th shell to 2nd shell in H-atom? (Ans: Wavelength =
486.085nm, wave number = 0.00205725 × 109 m-1, colour = Blue)
8. What is the wave length of 3rd line of Bracket series of H-spectrum? (Ans: 2165.439
nm)
9. What is the wavelength and colour of third line of Balmer series of H-spectrum?
(Ans: Wavelength = 434nm, , colour = Indigo)
10. Calculate the wavelength of a radiation if an electron of H-atom comes back to 2nd
energy shell from infinite orbit. (Ans: 364nm)
11. Calculate the frequency of α-line and δ- line spectra of Balmer series.
(Ans: Frequency α=4.5699 × 1014 s-1 and δ = 7.557 × 1014 s-1)
12.
n=5
n=4
n=3
n=2=
X Y Z

Which of the above spectrum line has comparatively larger wavelength among all the
X, Y and Z spectrum lines? (Ans: Z- spectrum line)
13. What will be the energy of photon of the radiated energy originated due to transition
of electron from 5th to 2nd energy shell? (Ans: 4.588 × 10-19 J )
14. The wavelength of third line of Balmer series is 434 nm. From which shell the
electron comes back? ( Ans: 5)
15. Will the radiant energy be visible, if the electron of H-atom falls back from 5th to 2nd
energy shell? ( Ans: Yes, wavelength = 434 nm in visible range, Indigo colour)
16. How many line spectra will be produced of the H-atom comes back to 2nd shell 6th
shell?
(Ans: 10)
17. Explain all the quantum numbers with significance.
18. Draw and explain the shape of d-orbitals.
19. Calculate the number of electron in N-shell (n=4) with the help of four quantum
numbers.
20. Calculate the number of electron in M-shell (n=3) with the help of four quantum
numbers.
21. Calculate the number of orbitals in N-shell (n=4) with the help of n, l and m.
22. Calculate the number of orbitals in M-shell (n=3) with the help of n, l and m.
23. Calculate the number of electron in N-shell (n=4) with the help of n and l.
24. Calculate the number of electron in M-shell (n=3) with the help of n and l.
25. Explain the exceptional electronic configuration of Cr(24), Cu(29), Mo(42), Ag(47),
La (57) and Au(79).
26. Explain Pauli Exclusion Principle considering the last two electrons of Ca.
27. Explain Pauli Exclusion Principle considering the last two electrons of Mg.
28. Explain Pauli Exclusion Principle considering the last two electrons of Be.
29. Explain Pauli Exclusion Principle considering the 5th and & 7th electrons of oxygen.
30. Explain Pauli Exclusion Principle considering the 17th and 23rd electrons of oxygen.
Creative question

1. Stem : …………(n-1)d5ns1 Where , n = 1 [D. B-22]

(c) The electronic configuration of the element ‘A ‘of the stem is exceptional-Explain.
(d) Though the other quantum numbers are same but magnetic quantum numbers are
different for the electrons existing d-shell of the stem.-Analyze the statement.
2. [D. B-22]

Fig: Excited state of H-atom

(c) Calculate highest electron containing capacity of the outermost shell of stem by
determining value of l and m.
(d) Whether the spectrum created by the transition of electron of the stem will be visible or
not? Analyze mathematically. (Ans : Not visible, λ=97.25nm)
3.
[M. B-22]

(a) What is an orbital?

(b) Why does 2d orbital not exist?
(c) Determine the wavelength of radiation generated due to transition of electron of the stem.
(Ans: λ= 656.5nm)
(d) Determine the total electron number in the last shell of the atom using the value of l and m.
4. [R. B-22]

Here, the energy of photon of emitted ray for the stepped

sown electron from N-shell is 1.45 x 10-21KJ.
(c) Determine the total number of electrons can exist in
the last shell by determining the number of orbitals in the
stem with the help of quantum numbers.
(d) Show the differences of the wavelength of reflected ray
for the stepped down electron in the stem. (Ans : Diff. in
wavelength= 137nm)
5. [C. B-21]

(c) Calculate the wavelength of the radiated ray of the

stem. (Ans: λ= 102.57nm)
(d) ‘N-shell of the stem does not contain more than 32
electrons’-Explain with quantum numbers.

6. [R. B, C.B, Ctg. B, B.B -18]

(c) Calculate the total electron in Z shell from the value of

I and m.
(d) Due to the change of step of the electron mentioned in
the stem, in which region of the electromagnetic
spectrum the emitted ray will exist? Explain
mathematically.(Ans: visible, λ=656.4nm)

7. [B. B-19]

(c) Pauli's exclusion principle is applicable or

not for e1 and e2-Explain it.
(d) The radiation shown in part-2 is used in
either medical or testing fake notes-Analyze
it. (Ans: λ= 102.57nm)
(e)

8. [Ctg. B-21]

(c) Show the application of Pauli's exclusion principle

for outer-most electrons mentioned in the stem
(ii).
(d) Evaluate mathematically, which one of the series
shows visible spectrum between two series of the
stem (i)? (Ans: Series-2)
(ii) Mg(12) 1s22s22p63s2
9.

(c) Which model is supported by the figure of the

stem? Explain the limitations of this model.
(d) If an electron comes back to 2nd shell last shell of
the figure, then what will be the value of
wavelength, frequency and wavenumber and
colour of the spectrum line?
He+
(Ans: Wavelength = 486.27 nm, frequency
=6.16×1014 Hz, wavenumber = 2.16×10-3 nm-1.)