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Arjuna JEE Fastrack (2024)

Chemistry
DPP: 2
Hydrocarbons

Q1 2-methyl butane on reacting with bromine in (B) But-2-ene

the presence of sunlight gives maximum (C) Ethene & Ethane
content of (D) All
(A) 1-bromo-3-methyl butane
Q7 In the complete combustion of Cn H2n+2 , the
(B) 2-bromo-3-methylbutane
number of oxygen moles required is
(C) 2-bromo-2-methyl butane
(A)
n

(D) 1-bromo-2-methyl butane 2O2

(B) ( n+1 ) O2
2
Q2 The order of reactivity of halogens in
(C) ( 3n+1 ) O2
aliphatic substitution reaction is: 2

(A) Br2 > Cl 2 > F2 (D) ( n+2

) O2
2

(B) Cl2 > Br2 > F2

(C) F2 > Cl 2 > Br2 Q8

AlC l3 ⋅H C l
(D) F2 > Br2 > Cl 2
−−−−−−→ A, A is:
Heat

Q3 Photochemical chlorination of alkane is initiated (A)

by a process of
(A) Pyrolysis (B) Substitution (B)
(C) Heterolysis (D) Homolysis

Q4 Rate determining step in chlorination of CH4 is (C)

(A) Cl2
∗
→ 2Cl

(B) CH4
∗ ∗
+ Cl → CH3 + HCl
(D)
(C) ∗ ∗
CH3 + Cl 2 → CH3 Cl + Cl

(D) Cl
∗ ∗
+ Cl → Cl 2

Q9 On mixing a certain alkane with chlorine and

Q5 Ethane can be prepared by irradiating it with ultraviolet light, it forms only
(A) Heating sodalime with sodium acetate one monochloroalkane. This alkane could be
(B) Electrolysis of sodium succinate (A) Isopentane (B) Neopentane
(C) Electrolysis of sodium acetate (C) Propane (D) Pentane
(D) All of these

Q6 On pyrolysis n-butane gives Q10 An alkane containing atleast _________ carbon

(A) But-1-ene atoms is converted into an aromatic

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hydrocarbon, when heated in the presence of

Cr 2 O3 on Al2 O3 .
(A) 6 (B) 4
(C) 3 (D) 5

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Answer Key
Q1 (C) Q6 (D)

Q2 (C) Q7 (C)

Q3 (D) Q8 (C)

Q4 (B) Q9 (B)

Q5 (C) Q10 (A)

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