JEE

Arjuna JEE 3.0 (2024)

Chemistry
DPP: 2
Hydrocarbon

Q1 Which one is not prepared by Wurtz reaction? (A) Ethane (B) Ethyl alcohol
(A) C4H10 (C) Methyl alcohol (D) Methane
(B)
Q7 Wurtz reaction is used to prepare
(C) CH4 (A) Methane only
(D) (B) Symmetrical alkanes
(C) Unsymmetrical alkanes
(D) All of these

Q2 To prepare a pure sample of n -hexane using Q8 Which of the following will form cyclohexane on
sodium metal as one reactant, the other will be reaction with two moles of Na in ether?
(A) Ethyl chloride and n-butyl chloride (A) CH3CH2 − Br
(B) Methyl chloride and n-pentyl bromide (B)
(C) Ethyl bromide and n-butyl bromide
(D) n-propyl bromide

Q3 Which alkane could not be prepared by (C) Br − CH2 − CH2 − CH2 − CH2 − CH2
kolbes electrolytic method? − CH2 − Cl
(A) 2c alkane (D)

(B) 4c alkane
(C) 3c alkane
(D) 6c alkane Q9 Clemmensen reduction of a ketone is carried
out in the presence of which of the following?
Q4 Sodalime decarboxylation of sodium
propionate produces (A) H2 and Pt as catalyst
(B) Glycol with KOH
(A) Propane (B) Ethane
(C) Methane (D) Butane (C) Zn − Hg with HCl
(D) LiAlH4
Q5 Electrolytic decarboxylation of sodium
Q10 The wol -Kishner reduction reduces ketones to
propionate produces
.............
(A) Propane (B) Ethane
(A) Alcohol (B) Hydrocarbons
(C) Methane (D) Butane
(C) Ketones (D) Acids
Q6 When Grignard reagent (CH3MgBr) is treated
Q11
with water, we get

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(D)

The above conversion can be achieved by

(A) Clemmensen reduction
(B) Wol -kishner reduction Q16
(C) Red P +HI
(D) All of the above Here (A) is :
(A)
Q12 The reagent used in wol -kishner reduction is:
(A) NH2 − NH2 (B)
(B) Zn − Hg, HCl
(C) NaOH (C)
(D) NaOH + CaO

Q13 Isopropyl bromide on wurtz reaction gives (D)

(A) Hexane
(B) Propane
(C) 2,3-dimethylbutane
(D) Neohexane

Q14

(P) cannot be
(A) Zn − Hg, conc. HCl
(B) NH2 − NH2, NaOH, Δ
(C) NaOH + CaO, Δ
(D) Red P, HI

Q15 1-Bromo-3-chloro cyclobutane on reaction

with 2-equivalent of sodium in ether gives
(A)

(B)

(C)

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Answer Key
Q1 (C) Q9 (C)

Q2 (D) Q10 (B)

Q3 (C) Q11 (D)

Q4 (B) Q12 (A)

Q5 (D) Q13 (C)

Q6 (D) Q14 (C)

Q7 (B) Q15 (C)

Q8 (C) Q16 (C)

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