JEE

Arjuna JEE Fastrack (2024)

Chemistry
DPP: 6
Hydrocarbans

Q1 Heating a mixture of sodium benzoate and Q6 Presence of a nitro group in a benzene ring
soda lime gives (A) Activates the ring towards electrophilic
(A) Methane substitution
(B) Phenol (B) Renders basic character to the ring
(C) Calcium benzoate (C) Deactivates the ring towards nucleophilic
(D) Benzene substitution
(D) Deactivates the ring towards electrophilic
Q2 Benzene is obtained when phenol is distilled
substitution
with
(A) Copper turnings Q7 The increasing order of nitration of the following
(B) Aluminium dust compounds is
(C) Zinc dust
(D) Pumice stone

Q3 Benzene reacts with n-propyl chloride in the

presence of anhydrous AlCl 3 to give
predominantly (a)
(A) Isopropyl benzene
(B) n-propyl benzene
(C) Propiophenone
(D) 1-chloro-3-propyl benzene
(b)
Q4 In Friedel-Craft's synthesis of toluene, the
reactants in addition to anhydrous AlCl3 are
(A) C6 H5 Cl + CH4
(B) C6 H5 Cl + CH3 Cl
(C) C6 H6 + CH4

(D) C6 H6 + CH3 Cl (c)

Q5 Nitration of benzene is
(A) Nucleophilic substitution
(B) Electrophilic substitution
(C) Electrophilic addition
(D) Nucleophilic addition (d)

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(A) (b) < (a) < (c) < (d) Q10 Nitrobenzene can be prepared from benzene
(B) (a) < (b) < (c) < (d) by using a mixture of conc. H2 SO 4 and conc.
(C) (b) < (a) < (d) < (c) HNO3 in the nitrating mixture, HNO3 acts as a
(D) (a) < (b) < (d) < (c) (A) Base (B) Acid
(C) Reducing (D) Catalyst
Q8 Arrange the following compounds in the order
of decreasing reactivity towards electrophilic
substitution reaction
(I)

(II)

(III)

(IV)

(A) IV > I > II > III

(B) I > II > IV > III
(C) I > II > III > IV
(D) I > III > IV > II

Q9 Benzene reacts with acetyl chloride in presence

of anhydrous aluminium chloride to form
(A) Acetophenone (B) Phenyl acetate
(C) Chlorobenzene (D) Benzoic acid

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Answer Key
Q1 (D) Q6 (D)

Q2 (C) Q7 (D)

Q3 (A) Q8 (A)

Q4 (D) Q9 (A)

Q5 (B) Q10 (A)

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