PINNAACLE CLASSES

46. Which of the following represents thecorrect order

of the acidity in the givencompounds
(a)

(b) (c)

(c)

(d)
(d)
(2005) (2007)

47. A carbonyl compound reacts with hydrogen 50. In a set of the given reactions, acetic acid yielded a
cyanide to form cyanohydrin which on hydrolysis product
forms a racemic mixture of ‐hydroxy acid. The
carbonyl compound is
(a) formaldehyde Product would be
(b) acetaldehyde (a)
(c) acetone
(d) diethyl ketone. (2006) (b)

(c)
48. In a set of reactions propionic acid yielded a
compound D

. The (d) (2003)

structure of would be
(a)

(b)

(c)
51. In the above reaction
(d) (2006) product P is

49. When ‐chlorobenzaldehyde is treated with 50%

KOH solution, the product(s) obtained is (are)

(a) (b)

(a)

(b) (c) (d) (2002)

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52. Which one of the following compounds will react 58. is a lighter phenol and is an aromatic
with solution to give sodium salt and carboxylic acid. Separation of a mixture of and
carbon dioxide?. can be carried out easily by using a solution of
(a) Acetic acid (a) sodium hydroxide
(b) ‐Hexanol (b) sodium sulphate
(c) Phenol (c) calcium chloride
(d) Both(b) and (c) (1999) (d) sodium bicarbonate. (1992)

53. Which of the following compounds gives benzoic 59. The compound formed when malonic acid is
acid on hydrolysis?. heated with urea is
(a) Chlorobenzene (a) cinnamic acid
(b) Benzoyl chloride (b) butyric acid
(c) Chlorophenol (c) barbituric acid
(d) Chlorotoluene (1996) (d) crotonic acid. (1989)

60. Among the following the strongest acid is

54. An acyl halide is formed when reacts with an
(a) amide (a)
(b) ester
(b)
(c) acid
(d) alcohol. (1994) (c)

(d) . (1988)
55. can be oxidised to
61. Which of the following is the correct decreasing
CHCOOH by order of acidic strength of(i) methanoic acid (ii)
(a) chromic acid ethanoic acid (iii) propanoic acid (iv) butanoic acid
(b) (a)
(c) at
(b)
(d) (1993)
(c)
56. In which of the following, the number of carbon
(d) (1988)
atoms does not remain same when carboxylic acid
is obtained by oxidation?.
62. For the reaction given below :
(a)

(b)

(c)

(d) (1992)

The compound which is formed as a product in

57. Benzoic acid gives benzene on being heated with
the reaction is a :
and phenol gives benzene on being heated
with . Therefore, and are respectively (a) compound with both alcohol and acid
functional groups
(a) soda‐lime and copper
(b) monocarboxylic acid
(b) Zn dust and NaOH (c) dicarboxylic acid
(c) Zn dust and soda‐lime (d) diol
(d) soda‐lime and zinc dust. (1992)

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63. The structures of A and B formed in the following

reaction are :
[Ph=-C6H5] (a)

(b)

(a) (c)

(d)

66. Isobutyraldehyde on reaction with formaldehyde

and K2CO3 gives compound ‘A’ Compound 'A'
(b) reacts with KCN and yields compound 'B' which on
hydrolysis gives a stable compound 'C'. The
compound 'C' is
(c)

(a) (b)

(d)

64. The structure of the starting compound P used in (c) (d)

the reaction given below is :

(a) (b)

67. p-cresol reacts with chloroform in alkaline

(c) (d) medium to give the compound A which adds
hydrogen cyanide to form the compound B. The
latter on acidic hydrolysis gives chiral carboxylic
acid. The structure of carboxylic acid is

65. The final product 'A' in the following reaction

sequence

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 PINNAACLE CLASSES

(b) Both A and R are correct but R is not correct

explanation of A.
(c) A is correct but R is incorrect.
(d) Both A and R are false.

(a) (b) 72. Assertion: Hydrogen bonding in carboxylic acid

is stronger than alcohols.
Reason: Highly branched carboxylic acids are
more acidic than unbranched acids.
(a) Both A and R are correct and R is the correct
explanation of A.
(b) Both A and R are correct but R is not correct
(c) (d) explanation of A.
(c) A is correct but R is incorrect.
68. Following reaction is used to prepare alkane from (d) Both A and R are false.
sodium salt of carboxylic acid. The name of
reaction is 73. Consider the following reaction

(a) Decarboxylation
(b) Kolbe electrolysis
(c) HVZ reaction
Here, ‘X’ and ‘Y’ respectively are:
(d) None of these

69. In which of the following solvent, carboxylic acid

is/are soluble?
(a) benzene
(b) ether
(a)
(c) chloroform
(d) All of these

70. Assertion: Carboxylic acids are reduced to

alkanes on reaction with HI in presence of red
phosphorus. (b)
Reason: Melting point of carboxylic acid shows
a regular pattern.
(a) Both A and R are correct and R is the correct
explanation of A.
(b) Both A and R are correct but R is not correct (c)
explanation of A.
(c) A is correct but R is incorrect.
(d) Both A and R are false.

71. Assertion: Strong oxidising agents oxidise (d)

toluene and its derivatives to benzoic acid.
Reason: Chromyl chloride and chromic oxide
74. The carboxylic carbon is less electrophilic than
stop the oxidation of toluene at aldehyde stage. [Page:
carbonyl carbon because of
362]
(a) bond polarity
(a) Both A and R are correct and R is the correct
explanation of A. (b) resonance
(c) carbocation formation

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 PINNAACLE CLASSES

(d) carbanion formation 82. Which compound can exist in a dipolar (zwitter ion)
state
75. The product formed by the reaction of an (a) C 6 H 5 CH 2 CH( N =CH 2 )COOH
aldehyde with a primary amine is
(a) Ketone (b) (CH 3 )2 CH . CH ( NH 2 )COOH
C 6 H 5 CONHCH 2 COOH
(b) Carboxylic acid (c)
(c) Aromatic acid HOOC .CH 2 CH 2 COCOOH
(d)
(d) Schiff base
83. Albumin proteins are most abundant in
76. Which of the following does not act as mild
oxidising agent? (a) Meat (b) Milk
(a) Tollen’s reagent (c) Egg (d) Soyabean
(b) Fehling’s reagent
(c) Benedict’s reagent 84. The most important energy carrier in all the living
cells is
(d) Alk. KMnO4
(a)AMP (b) ATP
77. A compound A has molecular formula C2Cl3OH. It (c) ADP (d) UDP
reduces Fehling’s solution and on oxidation gives
a monocarboxylic acid B. A can be obtained by 85. The correct statement in respect of protein
the action of chlorine on ethyl alcohol. A is haemoglobin is that it
(a) chloroform (a) Acts as an oxygen carrier in the blood
(b) monochloroacetic acid (b) Forms antibodies and offers resistance to
(c) chloral diseases
(d) methyl chloride (c) Functions as a catalyst for biological reactions
(d) Maintains blood sugar level
78. List-I List-II
Reaction Reagents
86. The bond that determines the secondary structure
(A) Hoffmann Degradation (I) Conc.KOH,
(B) Clemenson reduction (II) CHC13, of proteins is or secondary structure of protein is
NaOH/H3O+ due to
(C) Cannizaro reaction (III) Br2, NaOH (a) Coordinate bond
(D) Reimer-Tiemann reaction (IV) Zn-Hg/HCl (b) Covalent bond
(a)(A)-III, (B)-IV,(C)-II,(D)-I (c) Hydrogen bond
(b) (A) - II, (B) - IV, (C) -I, (D) - III (d) Peptide bond
(c)(A)-III, (B)-IV,(C)-I,(D)-II
(d) (A) - II, (B) -I, (C) - III, (D) - IV
87. The ‘iodine value’ of an oil indicates
79. The prosthetic group of haemoglobin is (a) Its boiling point
(a) Porphin (b) Haem (b) Inflammability
(c) Globin (d) Globulin (c) Unsaturation present in acid contents
(d) Solubility of salt in oils
80. pH in stomach is approximately
(a) 7 (b) 2.0 88. The waxes are long chain compounds of fatty
(c) 6.5 (d) 10 acids, which belong to the class of
(a) Esters (b) Ethers
81. Which of the following contains the highest (c) Alcohols (d) Acetic acid
percentage of protein

CHOR`}cSub{size8\ln` `}cSup{size8\ln` `}cSub{italCHr sze8{2}italOC {R}sup'cS{size8talCHrSub{size82}talOCi{R}sup'`{widevcsz8{Enyme}cSub{size8Hydrols}{itaCHO}cSub{size8\ln` }cSup{size8\ln` } cSub{italCHr sze8{2}italOHcSup{italCHrbsze8{2}italOH+{ R}sup'italCOH`}cSub{size8+}cSup{size8+} cSub{R}sp'italCOH}cSup{size8R}up{'italCOH}{¿
(a) Groundnut (b) Cow's milk
(c) Egg (d) Wheat

89.
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 PINNAACLE CLASSES

The enzyme used in the above reaction is

(a) Amylase (b) Lactase
(c) Lipase (d) Invertase

90. Oleic, stearic and palmitic acids are

(a) Fatty acid (b) Amino acid
(c) Nucleic acid (d) Essential acid

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