CHEMISTRY

26. Which represents an alkane

(a) 𝐶5 𝐻8 (b) 𝐶8 𝐻6 (c) 𝐶9 𝐻10 (d) 𝐶7 𝐻16
27. The decreasing order of boiling points is
(a) n-Pentane > iso-Pentane > neo-Pentane
(b) iso-Pentane > n-Pentane > neo-Pentane
(c) neo-Pentane > iso-Pentane > n-Pentane
(d) n-Pentane > neo-Pentane > iso-Pentane
28. To prepare a pure sample of n-hexane using sodium metal as one reactant,
the other reactant will be
(a) n-propyl bromide
(b) Ethyl bromide and n-butyl bromide
(c) Ethyl chloride and n-butyl chloride
(d) Methyl bromide and n -pentyl chloride
29. Sodium acetate can be converted to ethane by
(a) Heating with 𝐿𝑖𝐴𝑙𝐻4 (b) Electrolysing its aqueous solution
(c) Heating with soda lime (d) Heating with calcium acetate
30. In the reaction 𝐶𝐻3 − 𝐵𝑟 + 2𝑁𝑎 + 𝐵𝑟 − 𝐶𝐻3 →, the product called
(a) Wurtz reaction (b) Aldol condensation
(c) Perkin’s reaction (d) Levit reaction
31. Iodoethane reacts with sodium in the presence of dry ether. The product is
(a) Pentane (b) Propane (c) Butene (d) Butane
32. Which of the following is oxidised by 𝐾𝑀𝑛𝑂4
(a) Methane (b) Pentane (c) Isobutane (d) Neopentane
33. When ethylene bromide is treated with 𝑍𝑛, we get
(a) Alkane (b) Alkene (c) Alkyne (d) All
34. Ethene when treated with 𝐵𝑟2 in the presence of 𝐶𝐶𝑙4 which compound is formed
(a) 1, 2-dibromoethane (b) 1-bromo-2-chloroethane
(c) Both (a) and (b) (d) 1, 1, 1-tribromoethane
35. Alkenes usually show which type of reaction
(a) Addition (b) Substitution (c) Elimination (d) Superposition
36. The propene reacts with HBr to form
(a) Ethane (b) Hexane (c) 1-bromo-propane (d) 2-bromo propane
37. Ethylene may be obtained by dehydration of which of the following with
concentrated 𝐻2 𝑆𝑂4 at 160 − 170𝑜 𝐶
(a) 𝐶2 𝐻5 𝑂𝐻 (b) 𝐶𝐻3 𝑂𝐻 (c) 𝐶𝐻3 𝐶𝐻2 𝐶𝐻2 𝑂𝐻 (d) (𝐶𝐻3 )2 𝐶𝐻𝐶𝐻2 𝑂𝐻
38. The disappearance of the characteristic purple colour of 𝐾𝑀𝑛𝑂4 in its reaction with
an alkene is the test for unsaturation. It is known as
(a) Markownikoff's test (b) Baeyer's test
(c) Wurtz's test (d) Grignard test
39. A gas formed by the action of alcoholic KOH on ethyl iodide, decolourises
alkaline𝐾𝑀𝑛𝑂4 . The gas is
(a) 𝐶2 𝐻6 (b) 𝐶𝐻4 (c) 𝐶2 𝐻2 (d) 𝐶2 𝐻4
anhydrous
40. 𝐶6 𝐻6 + 𝐶𝐻3 𝐶𝑙 → 𝐶6 𝐻5 𝐶𝐻3 + 𝐻𝐶𝑙 is an example of
𝐴𝑙𝐶𝑙3
(a) Friedel-Craft's reaction (b) Kolbe's synthesis
(c) Wurtz reaction (d) Grignard reaction
41. On heating a mixture of sodium benzoate and sodalime, the following is obtained
(a) Toluene (b) Phenol (c) Benzene (d) Benzoic acid
42. Benzene on treatment with a mixture of conc. 𝐻𝑁𝑂3 and conc. 𝐻2 𝑆𝑂4 at 100𝑜 𝐶 gives
(a) Nitrobenzene (b) m-dinitrobenzene
(c) p-dinitrobenzene (d) o-dinitrobenzene
43. Aromatisation of n-heptane by passing over (𝐴𝑙2 𝑂3 + 𝐶𝑟2 𝑂3 ) catalyst at 773 K gives
(a) Benzene (b) Toluene (c) Mixture of both (d) Heptylene
44. Which among the following is anti-aromatic ?

(a) (b) (c) (d)

45. Which of the following molecules have all C–C bonds are of equal length?
–

(a) (b) (c) (d) All of these

46. Total resonance structure of phenol ________.

47. Number hybrid orbital in ethane ________.
48. Number pure orbital in benzene _______.
49. Double bond equivalence of benzene ______.
50. Sum of 𝜋 and 𝜎 bond in 1,3 butadiene ______.