Iitjee Advanced 2013 Question Paper 1 With Solutions

CODE : O
IIT - JEE 2013 (Advanced)

(2) Vidyalankar : IIT JEE 2013 − Advanced : Question Paper & Solution
2
IIT JEE 2013 Advanced : Question Paper & Solution (Paper – I) (3)
PART I : PHYSICS
SECTION I : (Only One option correct Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
⎡ x î + y ˆj⎤
1. The work done on a particle of mass m by a force, K ⎢ ⎥
⎢⎣ ( x + y ) (x + y )
2 2 3/2 2 2 3/2
⎥⎦
(K being a constant of appropriate dimension), when the particle is taken from the point
(a, 0) to the point (0, a) along a circular path of radius a about the origin in the x-y plane is
2Kπ Kπ Kπ
(A) (B) (C) (D) 0
a a 2a
1. (D)
G k G G
F = 3 r ⇒ F is conservative
r
⎡⎛ ∂ 1 ⎞ ⎤
G
⎢ ⎜ ⎟ î + ∂ 1 î ⎥ G
F = −K ∂x 1 = −∇U
⎢⎜ (x 2 + y 2 ) 2 ⎟ ∂y 2 1
⎥
⎢⎣ ⎝ ⎠ (x + y )
2 2
⎥⎦
K
U= 1
[potential energy]
(x 2 + y 2 ) 2
U(0, a) = U(a, 0) ⇒W=0
2. Two rectangular block, having identical dimensions, can be arranged either in
configuration I or in configuration II as shown in the figure. One of the block has thermal
conductivity k and the other 2k. The temperature difference between the ends along the x-
axis is the same in both the configurations. It takes 9 s to transport a certain amount of
heat from the hot end to the cold end in the configuration I. The time to transport the same
amount of heat in the configuration II is
(A) 2.0 s (B) 3.0 s (C) 4.5 s (D) 6.0 s

2. (A)
Thermal resistance of individual block are
2R and R.
2
For config 1; R1 = 3R ; For config 2; R 2 = R
3
Q1 1 2 2
Ratio of heat currents = ⋅ R=
Q 2 3R 3 9
Q 2
Q1 t1 = Q2 t2 ⇒ t 2 = 1 ⋅ t1 = × 9s = 2sec
Q2 9
3
3. two non-reactive monoatomic ideal gases have their atomic masses in the ratio 2 : 3. The
ratio of their partial pressures, when enclosed in a vessel kept at a constant temperature, is
4 : 3. The ratio of their densities is
(A) 1 : 4 (B) 1 : 2 (C) 6 : 9 (D) 8 : 9
3. (D)
P1V1 = P2 V2
P1 M 2ρ1
=
P2 M1ρ2
ρ1 4 2
= × =8/9
ρ2 3 3
4. A particle of mass m is projected from the ground with an initial speed u0 at an angle α
with the horizontal. At the highest point of its trajectory, it makes a completely inelastic
collision with another identical particle, which was thrown vertically upward from the
ground with the same initial speed u0. The angle that the composite system makes with the
horizontal immediately after the collision is
π π π π
(A) (B) + α (C) − α (D)
4 4 2 2
4. (A)
u2
H= sin 2 α
2g mu0 cos α
Speed the particle that was thrown vertically at the
highest point be “v”.
u 2 sin 2 α
v 2 − u 02 = −2g × 0 ⇒ v = u0 cos α
2g θ
py mu0 cos α
∴ tan θ = =1
px
5. A pulse of light of duration 100 ns is absorbed completely by a small object initially at

rest. Power of the pulse is 30 mW and the speed of light is 3 × 108 ms−1. The final
momentum of the object is
(A) 0.3 × 10−17 kg ms−1 (B) 1.0 × 10−17 kg ms−1
−17 −1
(C) 3.0 × 10 kg ms (D) 9.0 × 10−17 kg ms−1
5. (B)
P = h / d or E = PC
3 × 10−2 ×10−7
P= = 1× 10−17
3 ×10 8
6. In the Young’s double slit experiment using a monochromatic light of wavelength λ, the
path difference (in terms of an integer n) corresponding to any point having half the peak
intensity is
λ λ λ λ
(A) ( 2n + 1) (B) (2n + 1) (C) (2n + 1) (D) (2n + 1)
2 4 8 16
6. (B)
δ
I = 4I0 cos 2 ⎛⎜ ⎞⎟
⎝2⎠
If I = 2I0
4
δ δ δ π
∴ cos 2 ⎜⎛ ⎟⎞ = ⇒ cos ⎜⎛ ⎟⎞ = ±
1 1
⇒ = nπ ±
⎝2⎠ 2 ⎝2⎠ 2 2 4
2π Δx π
⇒ Δx = ⎜⎛ 2n ± ⎟⎞ λ
1
⋅ = 2nπ ±
λ 2 4 ⎝ 4⎠
7. The image of an object, formed by a plano-convex lens at a distance of 8 m behind the
lens, is real and is one-third the size of the object. The wavelength of light inside the lens
2
is times the wavelength in free space. The radius of the curved surface of the lens is
3
(A) 1 m (B) 2 m (C) 3 m (D) 6 m
7. (C)
3
v = 8 m, μ =
2
1
m = −
3
1 1 1 v v
− = ⇒ 1− = = m
v u f f u
f −v 1
⇒ =m=−
f 3
f −8 1
⇒ =− ⇒ f=6
f 3
R
f = ⇒ 2R = 6 ⇒ R=3
( μ − 1)
8. One end of a horizontal thick copper wire of length 2L and radius 2R is welded to an end
of another horizontal thin copper wire of length L and radius R. When the arrangement is
stretched by applying forces at two ends, the ratio of the elongation in the thin wire to that
in the thick wire is
(A) 0.25 (B) 0.50 (C) 2.00 (D) 4.00
8. (C)
2R R
F F
2L
L
F F
4A = A 2 1
⇒ =
Δ 2 Δ 1 4Δ 2 Δ 1
2L L
Δ 1 Δ
⇒ 2
= ⇒ 1
=2
Δ 1 2 Δ 2
9. A ray of light travelling in the direction

1 ˆ
2
( )
i + 3jˆ is incident on a plane mirror. After
reflection, it travels along the direction

1 ˆ
2
( )
i − 3jˆ . The angle of incidence is
(A) 30° (B) 45° (C) 60° (D) 75°
5
9. (A)
Angle between I and R is
( )( ) I R
I.R i + 3 ˆj i − 3 ˆj 1 − 3 1
cos δ = = = =− δ
| I || R | ( 2) ( 2) 4 2
δ = 120°
180 − 2 i = 120°
2i = 60°
i = 30°
10. The diameter of a cylinder is measured using a Vernier caliper with no zero error. It is
found that the zero of the Vernier scale lies between 5.10 cm and 5.15 cm of the main
scale. The Vernier scale has 50 divisions equivalent to 2.45 cm. The 24th division of the
Vernier scale exactly coincides with one of the main scale divisions. The diameter of the
cylinder is
(A) 5.112 cm (B) 5.124 cm (C) 5.136 cm (D) 5.148 cm
10. (B)
M.S.R. = 5.1 cm
2.45
1 V. C. = = 0.049 cm
50
L.C. = 0.050 − 0.049
= 0.001 cm
V.S.R. = 24
⇒ d = (5.1) cm + 24 × 0.001 = 5.124 cm
SECTION II : (One or more options correct Type)
(C) and (D) out of which ONE or MORE are correct.
11. In the circuit shown in the figure, there are two parallel plate capacitors each of
capacitance C. The switch S1 is pressed first to fully charge the capacitor C1 and then
released. The switch S2 is then pressed to charge the capacitor C2. After some time, S2 is
released and then S3 is pressed. After some time,
(A) the charge on the upper plate of C1 is 2CV0.
(B) the charge on the upper plate of C1 is CV0.
(C) the charge on the upper plate of C2 is 0.
(D) the charge on the upper plate of C2 is −CV0.
11. (B), (D)

After S1 is released :
+2CV0
−2CV0
C1 C2
6
After S2 is released
+CV0 +CV0
−CV0 −CV0
C1 C2
After S3 is released
+CV0 −CV0
−CV0 +CV0
C1 C2
12. A particle of mass M and positive charge Q, moving with a constant velocity
u1 = 4iˆ ms −1 , enters a region of uniform static magnetic field normal to the x-y plane.
The region of the magnetic field extends from x = 0 to x = L for all values of y. After
passing through this region, the particle emerges on the other side after 10 milliseconds
( )
with a velocity u 2 = 2 3iˆ + ˆj ms−1. The correct statement(s) is (are)
(A) The direction of the magnetic field is −z direction.
(B) The direction of the magnetic field is +z direction.
50πM
(C) The magnitude of the magnetic field units.
3Q
100πM
(D) The magnitude of the magnetic field is units.
3Q
12. (A), (C)
Magnetic field is clearly in −z axis.
vy 1 π
tan θ = = ⇒ θ=
vx 3 6
mv
r=
qB
r sin θ = L
mv mv
⇒ sin θ = L ⇒ B = sin θ
qB qL
rθ vt
Time of travel = = t ⇒ r =
v θ
vt
∴ sin θ = L
θ
mv m π 50πm
∴ B= .θ = −3
=
qvt q ×10×10 6 3q
7
13. A horizontal stretched string, fixed at two ends, is vibrating in its fifth harmonic according
to the equation, y(x, t) = (0.01 m) sin [(62.8 m−1)x]. cos[(628 s−1)t]. Assuming π = 3.14,
the correct statement(s) is (are)
(A) The number of nodes is 5.
(B) The length of the string is 0.25 m.
(C) The maximum displacement of the midpoint of the string, from its equilibrium
position is 0.01 m.
(D) The fundamental frequency is 100 Hz.
13. (B), (C)
y = 0.01 sin [(62.8 m−1) x] cos [(628 s−1) t]
= 0.01 sin (20π x) cos (200 πt)
2π 1
k = 20 π ⇒ λ = = m = 10 cm
K 10
ω
ω = 200 π ⇒ ν = = 100s −1
2π
ω
v = = 10 m/s
k
in 5th harmonic.
5v 5
ν = ⇒ = λ = 25cm … (B)
2 2
⇒ 6 nodes ⇒ A is wrong.
Mid-point is antinode.
⇒ sin (20 πx) = 1
⇒ y = 0.01 cos (200 π t)
⇒ ymax = 0.01 m … (C)
v 10
ν0 = = = 20 hz. … (D) is wrong.
2 ⎛1⎞
2⎜ ⎟
⎝4⎠
14. A solid sphere of radius R and density ρ is attached to one end of a mass-less spring of
force constant k. The other end of the spring is connected to another solid sphere of radius
R and density 3ρ. The complete arrangement is placed in a liquid of density 2ρ and is
allowed to reach equilibrium. The correct statement(s) is (are)
4πR 3ρg
(A) the net elongation of the spring is
3k
8πR 3ρg
(B) the net elongation of the spring is .
3k
(C) the light sphere is partially submerged.
(D) the light sphere is completely submerged.
14. (A), (D)
B = 2ρ vg
Kx B
3 mg = 3ρ vg
⇒ Kx + B = 3 mg 3m
⇒ Kx = ρ vg1
3 mg
8
4
ρ πR 3g
ρvg 4πR 3ρg B′
⇒ x = = 3 =
K K 3K
B′ = mg + Kx= ρ vg + ρ vg
B′ = 2ρ vg Kx
mg
2ρ Δvg = 2ρ vg
⇒ v = Δv
⇒ Sphere is completely submerged
15. Two non-conducting solid spheres of radii R and 2R, having uniform volume charge
densities ρ1 and ρ2 respectively, touch each other. The net electric field at a distance 2R
from the centre of the smaller sphere, along the line joining the centres of the spheres, is
ρ
zero. The ratio 1 can be
ρ2
32 32
(A) −4 (B) − (C) (D) 4
25 25
15. (B), (D)
A 2R P R B
ρ1V 8 ρ2V
|Q1 | = ρ1 V
|Q2 | = 8ρ2 V
ρ1
Case I : If P is between A and B then + Ve
ρ2
ρ1
Case II : If P is left of A then − ve
ρ2
Case II Case I
+ve −ve
P
R 2R
2R
Q1 Q2 Q1 Q 2 (R)
⇒ = ⇒ =
4πε0 (2R) 4πε0 (5R)
2 2
4πε0 (2R) 2
4πε 0 (2R)3
Q 4 Q Q
⇒ 1 = ⇒ 1= 2
Q 2 25 4 8
ρ1 V 4 Q1 1
⇒ = ⇒ =
8 ρ2 V 25 Q2 2
ρ1
32 ρ1V 1
⇒ = ⇒ =
ρ2 25 8ρ2 V 2
ρ −32 ρ
⇒ 1 = ⇒ 1 =4
ρ2 25 ρ2
9
SECTION III : (Integer value correct Type)

This section contains 5 questions. The answer to each question is a single digit integer,
ranging from 0 to 9 (both inclusive).
16. A bob of mass m, suspended by a string of length l1, is given a minimum velocity required
to complete a full circle in the vertical plane. At the highest point, it collides elastically
with another bob of mass m suspended by a string of length l2, which is initially at rest.
Both the strings are mass-less and inextensible. If the second bob, after collision acquires
1
the minimum speed required to complete a full circle in the vertical plane, the ratio is
2
16. [5]
m gA 1 = m 5gA 2 A2
5g 2
A 1 = 5A 2
m
A1
=5
A2 A1
A1
17. A particle of mass 0.2 kg is moving in one dimension under a force that delivers a
constant power 0.5 W to the particle. If the initial speed (in ms−1) of the particle is zero,
the speed (in ms−1) after 5 s is
17. [5]
d ⎛1 2⎞
P = ⎜ mv ⎟
dt ⎝ 2 ⎠
d 2 2P
ν =
dt m
ν t
dν 2P P
2ν
dt
=
m
; ∫ ν dv =
m ∫0
dt
0
ν2 P
= t
2 m
2P 2 × 0.5
ν2 = t = × 5 = 25
m 0.2
ν = 5 m/s ν = 5
18. The work functions of Silver and Sodium are 4.6 and 2.3 eV, respectively. The ratio of the
slope of the stopping potential versus frequency plot for Silver to that of Sodium is
18. [1]
h φ
Vs = ν −
e e
h
Slope = for both silver and Na
e
∴ Ratio of slope = 1
10
19. A freshly prepared sample of a radioisotope of half-life 1386 s has activity 103
disintegrations per second. Given that n 2 = 0.693, the fraction of the initial number of
nuclei (expressed in nearest integer percentage) that will decay in the first 80 s after
preparation of the sample is
19. [4]
N = N 0e −λt
N
= e −λt
N0
N
∴ 1− = 1 − e −λt
N0
⎛ −ΔN ⎞
⎜
⎝ N0 ⎠
(
⎟ = 1− e
−λt
)
λ t << 1 ⇒ 1 − e −λt ≈ λt
⎛ −ΔN ⎞ n2 ⎛ 0.693 ⎞
⎜ ⎟ = λt = t =⎜ ⎟ 80 = 0.04
⎝ N0 ⎠ t1/ 2 ⎝ 1386 ⎠
−ΔN
⇒ × 100 = 4 ⇒ |ΔN| % = 4 %
N0
20. A uniform circular disc of mass 50 kg and radius 0.4 m is rotating with an angular
velocity of 10 rad s−1 about its own axis, which is vertical. Two uniform circular rings,
each of mass 6.25 kg and radius 0.2 m, are gently placed symmetrically on the disc in
such a manner that they are touching each other along the axis of the disc and are
horizontal. Assume that the friction is large enough such that the rings are at rest relative
to the disc and the system rotates about the original axis . The new angular velocity
(in rad s−1) of the system is
20. [8]
R = 0.4
M = 50 km
R
ω = 10
mR = 6.25 kg
r = 0.2
1
2
mR 2ω =
⎡
( 1
) 2⎤
⎢ 2 2m R R + 2 mR ⎥ ω′
⎣
2
⎦
1 ⎛ 1 ⎞
× 50 × 0.16 × 10 = ⎜ 4 × 6.25 × 0.04 + 2 × 50 × 0.16 ⎟ ω′
2 ⎝ ⎠
25 × 0.16 × 10 = ( 25 × 0.04 + 25 × 0.16 ) ω′
4 × 10 = 5 ω′
ω′ = 8
11
PART II : CHEMISTRY
21. Consider the following complex ions, P, Q and R.

P = [FeF6]−3, Q = [V(H2O)6]2+ and R = [Fe(H2O)6]2+
The correct order of the complex ions, according to their spin−only magnetic moment
values (in B.M.) is
(A) R < Q < P (B) Q < R < P (C) R < P < Q (D) Q < P < R
21. (B)
P = [ Fe F6 ]
3−
i.e. Fe +3 = [ Ar ] 3d 5
Magnetic moment = n ( n + 2) B M
= 35 B M
+2
Q = ⎡⎣ V ( H 2O )6 ⎤⎦ V +2 = [ Ar ] 3d3
Magnetic moment = 15 B M
+2
R = Fe ( H 2 O )6 i.e. Fe +2 = [ Ar ] 3d 6
Magnetic moment = 4 ( 4 + 2)
= 24 B M
P>R>Q
22. The arrangement of X− ions around A+ ion in
solid AX is given in the figure (not drawn to
scale). If the radius of X− is 250 pm, the radius
of A+ is
(A) 104 pm (B) 125 pm
(C) 183 pm (D) 57 pm
22. (A)
rA+ rA+
= 0.414 = −
rx− rx
rA+ = 0.414 × 250 pm = 104 pm
23. Sulfide ores are common for the metals

(A) Ag, Cu and Pb (B) Ag, Cu and Sn (C) Ag, Mg and Pb (D) Al, Cu and Pb
23. (A)
Factual
24. The standard enthalpies of formation of CO2(g), H2O ( ) and glucose (s) at 25 °C are
−400 kJ/mol, −300 kJ/mol and −1300 kJ/mol, respectively. The standard enthalpy of
combustion per gram of glucose at 25 °C is
(A) + 2900 kJ (B) − 2900 kJ (C) − 16.11 kJ (D) + 16.11 kJ
24. (C)
C6 H12O6 + O 2 ⎯⎯ → 6CO 2 + 6H 2O
CO 2 ⎯⎯
→ − 400 kJ/ mol
12
H2O = −300 kJ / mol

Glucose = −1300 kJ / mol
ΔH = ΔHP − ΔHR
= 6ΔH f (CO2 ) + 6H f (H 2O) − ΔH f ( C6H12Ο6 )
= (6 × −400) + 6(−300) − (−1300)
= −2400 − 1800 + 1300 = −2900 kJ / mol
−2900
ΔH = = −16.11 kJ / gm
180
25. Upon treatment with ammoniacal H2S, the metal ion that precipitates as a sulfide is
(A) Fe(III) (B) Al(III) (C) Mg(II) (D) Zn(II)
25. (D)
White ppt of zinc sulfide by adding ammoniacal H2S to Zn(II).
ZnS + 2HCl ⎯⎯ → ZnCl2 + H 2S
ZnCl2 + 2NaOH ⎯⎯
→ Zn(OH) 2 + 2NaCl
Zn(OH) 2 + 2NaOH ⎯⎯ → NaZnO 2 + 2H 2O
Na 2 ZnO 2 + H 2S ⎯⎯
→ ZnS + 2NaOH
white ppt.
26. Methylene blue, from its aqueous solution is adsorbed on activated charcoal at 25° C. for
this process, the correct statement is
(A) The adsorption requires activation at 25° C.
(B) The adsorption is accompanied by a decrease in enthalpy.
(C) The adsorption increases with increase of temperature.
(D) The adsorption is irreversible.
26. (B)
Factual
27. KI in acetone, undergoes SN2 reaction with each of P, Q, R and S. The rates of the
reaction vary as
(A) P > Q > R > S (B) S > P > R > Q (C) P > R > Q > S (D) R > P > S > Q
27. (B)
SN2 reactions are through back attack of attacking Nu− and not on the basis of stability of
carbocation.
28. In the reaction,

P + Q ⎯⎯ →R +S
the time taken for 75% reaction of P is twice the time taken
for 50% reaction of P. The concentration of Q varies with
reaction time as shown in the figure. The overall order of the
reaction is
(A) 2 (B) 3
(C) 0 (D) 1
13
28. (D)
For P, t75% = 2t50% Ist order wrt ‘P’
For Q, [Q] = [Q0] − kt. i.e. zero order.
i.e. overall order of a reaction = 1
29. Concentrated nitric acid, upon long standing, turns yellow − brown due to the formation of
(A) NO (B) NO2 (C) N2O (D) N2O4
29. (B)
Sunlight
4HNO3 ⎯⎯⎯⎯ → 4NO 2 + 2H 2O + O 2
30. The compound that does NOT liberate CO2, on treatment with aqueous sodium
bicarbonate solution, is
(A) Benzoic acid (B) Benzenesulphonic acid
(C) Salicylic acid (D) Carbolic acid (Phenol)
30. (D)
Compound with COOH gr or SO3H group can liberate CO2 with NaHCO3 solution.

31. The initial rate of hydrolysis of methyl acetate (1M) by a weak acid (HA, 1M) is 1/100th
of that of a strong acid (HX, 1M), at 25°C. the Ka of HA is
(A) 1 × 10−4 (B) 1 × 10−5 (C) 1 × 10−6 (D) 1 × 10−3
31. (A)
Ka = Cα2 = 1 × (0.01)2 = 1 × 10−4
32. The hyperconjugative stabilities of tert − butyl cation and 2 − butene, respectively, are due to
(A) σ → p (empty) and σ → π* electron delocalisations.
(B) σ → σ* and σ →π electron delocalisations.
(C) σ → p (filled) and σ → π electron delocalisations.
(D) p(filled) → σ* and σ → π* electron delocalisations.
32. (A)
H
+
CH 2 − C − CH3 σ − p(empty) delocalisation
CH3
CH3 − CH = CH2 (σ − π* electron) delocalization.
33. The pair(s) of coordination complexes / ions exhibiting the same kind of isomerism is (are)
(A) [Cr(NH3)5Cl]Cl2 and [Cr(NH3)4Cl2]Cl
(B) [Co(NH3)4Cl2]+ and [Pt(NH3)2(H2O)Cl]+
(C) [CoBr2Cl2]2− and [PtBr2Cl2]2−
(D) [Pt(NH3)3(NO3)]Cl and [Pt(NH3)3Cl]Br
33 . (B) , (D)
Factual.
14
34. Among P, Q, R and S, the aromatic compound(s) is /are
(A) P (B) Q (C) R (D) S

34. (A) , (B) , (C) , (D)
OH
⊕
⊕
N
H
(P) (Q) (R) (S)
All are Aromatic except (R)
35. Benzene and naphthalene from an ideal solution at room temperature. For this process, the
true statement(s) is(are)
(A) ΔG is positive (B) ΔSsystem is positive
(C) ΔSsurroundings = 0 (D) ΔH = 0
35. (B) , (C) , (D)
Conditions for Ideal Solution.

36. The atomic masses of He and Ne are 4 and 20 a.m.u, respectively. The value of the de
Broglie wavelength of He gas at −73°C is “M” times that of the de Broglie wavelength of
Ne at 727°C. M is
36. [5]
λ He M Ne .TNe 20 × 1000
= = =5
λ Ne M He .THe 4 × 200
37. EDTA4− is ethylenediaminetetraacetate ion. The total number of N − Co − O bond angles

in [Co(EDTA)]1− complex ion is
37. [8]
Total no. of N − Co − O bond angle in [Co (EDTA)]−1 = 8
15
38. The total number of carboxylic acid groups in the product P is
38. [2]
O O O
O O
C C HO C
.. H3O + O
.O. ⎯⎯⎯
Heat
→ ⎯⎯⎯
3 →
H 2O 2
C C HO C
O
O O O O
Total no. of carboxylic group = 2
39. A tetrapeptide has − COOH group on alanine. This produces glycine (Gly), valine (Val),
phenyl alanine (Phe) and alanine(Ala), on complete hydrolysis. For this tetrapeptide, the
number of possible sequences (primary structures) with −NH2 group attached to a chiral
center is
39. [4]
NH2
Glycine = CH2
COOH
NH2
Alanine = CH3 CH
COOH
NH2
Valine (CH3)2CH CH
COOH
NH2
phenyl alanine Ph CH2 CH
COOH
No. of possible sequences (primary structures) with −NH2 group attached to a chiral
center is 4
40. The total number of lone − pairs of electrons in melamine is
40. [6] ..
NH2
.. ..
N N Melamine
..
NH2
.NH
. 2 .N.
Lone Pairs → 6.
16
PART III : MATHEMATICS

41. For a > b > c > 0, the distance between (1, 1) and the point of intersection of the lines
ax + by + c = 0 and bx + ay + c = 0 is less than 2 2. Then
(A) a + b − c > 0 (B) a − b + c < 0 (C) a − b + c > 0 (D) a + b − c < 0
41. (A)
Given equations are
ax + by + c = 0
bx + ay + c = 0
Now,
x y 1
= = 2
bc − ac bc − ac a − b2
∴ x = 2
( b − a ) c = −c
a − b2 a+b
(b − a)c −c
y = 2 =
a −b 2
a+b
Now
2 2
⎛ c ⎞ ⎛ c ⎞
⎜1 + ⎟ + ⎜1 + ⎟ <2 2
⎝ a+b⎠ ⎝ a+b⎠
2(a + b + c) 2
<2 2
(a + b) 2
2(a + b + c)
< 2 2
a+b
(a + b + c) < 2a + 2b
a+b−c >0
42. The area enclosed by the curves y = sin x + cos x and y = | cos x − sin x | over the interval
⎡ π⎤
⎢⎣ 0, 2 ⎥⎦ is
(A) 4 ( 2 − 1) (B) 2 2 ( 2 − 1) (C) 2( 2 + 1) (D) 2 2 ( 2 + 1)
42. (B)
⎛ π⎞
∵ y = 2 sin ⎜ x + ⎟
⎝ 4⎠
⎛ π⎞
y = 2 sin ⎜ x − ⎟
⎝ 4⎠ π
π/4
⎡ 4
⎛ π⎞ ⎛ π⎞⎤
Area of shaded part = ∫ ⎢ 2 sin ⎜ x + ⎟ − 2 sin ⎜ x − ⎟ ⎥ dx
⎣ ⎝ 4⎠ ⎝ 4⎠⎦
0
π /2
⎡ ⎛ π⎞ ⎛ π⎞⎤
+ ∫ ⎢ 2 sin ⎜ x + ⎟ − 2 sin ⎜ x − ⎟ ⎥ dx
⎝ 4⎠ ⎝ 4⎠⎦
π /4 ⎣
17
⎡ π/4 ⎛ ⎛ π⎞ ⎛ π ⎞⎞
π /2
⎛ π⎞ ⎛ π ⎞⎤
= 2 ⎢ ∫ ⎜ sin ⎜ x + ⎟ + sin ⎜ x − ⎟ ⎟ dx + 2 ∫ sin ⎜ x + ⎟ − sin ⎜ x − ⎟ ⎥
⎣⎢ 0 ⎝ ⎝ 4⎠ ⎝ 4 ⎠⎠ π /4 ⎝ 4⎠ ⎝ 4 ⎠ ⎦⎥
=2− 2 +2− 2
=4− 2 2
43. The number of points in (−∞, ∞), for which x2 − x sin x − cos x = 0, is
(A) 6 (B) 4 (C) 2 (D) 0
43. (C)
f(x) = x2 − x sin x − cos x
f′(x) = 2x − sin x − x cos x + sin x
= x (2 − cos x)
⎧> 0 ∀x>0
⎪
So, f′(x) = ⎨0 x=0
⎪< 0 ∀x<0
⎩
(0, −1)
For x = 0, f(x) = −1
Hence two solutions
⎛ 23 ⎛ n ⎞⎞
44. The value of cot ⎜ ∑ cot −1 ⎜1 + ∑ 2k ⎟ ⎟ is
⎜ ⎟
⎝ n =1 ⎝ k =1 ⎠ ⎠
23 25 23 24
(A) (B) (C) (D)
25 23 24 23
44. (B)
⎛ 23 ⎛ n ⎞⎞
cot ⎜⎜ ∑ cot −1 ⎜1 + ∑ 2k ⎟ ⎟⎟
⎝ n =1 ⎝ k =1 ⎠ ⎠
⎛ ⎛ ( n + 1) ⎞ ⎞ = cot ⎛ 23 cot −1 n 2 + n + 1 ⎞
( )
23
= cot ⎜⎜ ∑ cot −1 ⎜1 + 2n ⎟⎟ ⎜∑ ⎟
⎝ n =1 ⎝ 2 ⎠ ⎟⎠ ⎝ n =1 ⎠
⎛ 23 1 ⎞ ⎛ 23 −1 (n + 1) − n ⎞
= cot ⎜ ∑ tan −1 ⎟ = cot ⎜ ∑ tan ⎟
⎝ n =1 1 + n(n + 1) ⎠ ⎝ n =1 1 + (n + 1).n ⎠
⎡ 23 ⎤
= ( )
cot ⎢ ∑ tan −1 (n + 1) − tan −1 n ⎥ = cot ⎡⎣ tan −1 24 − tan −1 1⎤⎦
⎣ n =1 ⎦
⎡ ⎛ 24 − 1 ⎞ ⎤ ⎡ −1 25 ⎤ 25
= cot ⎢ tan −1 ⎜ ⎟ ⎥ = cot ⎢ cot ⎥ = 23
⎣ ⎝ 1 + 24.1 ⎠⎦ ⎣ 23 ⎦
⎛ π⎞
45. A curve passes through the point ⎜1, ⎟ . Let the slope of the curve at each point (x, y)
⎝ 6⎠
y ⎛y⎞
be + sec ⎜ ⎟ , x > 0. Then the equation of the curve is
x ⎝x⎠
⎛y⎞ 1 ⎛y⎞
(A) sin ⎜ ⎟ = log x + (B) cosec ⎜ ⎟ = log x + 2
⎝x⎠ 2 ⎝x⎠
⎛ 2y ⎞ ⎛ 2y ⎞ 1
(C) sec ⎜ ⎟ = log x + 2 (D) cos ⎜ ⎟ = log x +
⎝ x ⎠ ⎝ x ⎠ 2
18
45. (A)
dy y ⎛y⎞
= + sec ⎜ ⎟
dx x ⎝x⎠
y
let =v
x
y = vx
dy dv
=v+x
dx dx
dv
v+x = v + sec v
dx
dx
∫ cos v dv = ∫ x
sin v = lnx + lnC
π
Given it passes (1, )
6
π
⇒ Sin = ln1 + lnC
6
1
⇒ lnC =
2
1
So, curve is sin v = lnx+
2
⎛y⎞ 1
sin ⎜ ⎟ = lnx +
⎝x⎠ 2
⎡1 ⎤
46. Let f : ⎢ ,1⎥ → (the set of all real numbers) be a positive, non-constant and
⎣2 ⎦
⎛1⎞
differentiable function such that f ′(x) < 2f (x) and f ⎜ ⎟ = 1. Then the value of
⎝2⎠
1
∫ f (x) dx lies in the interval

1/2
⎛ e −1 ⎞ ⎛ e −1 ⎞
(A) (2 e − 1, 2 e) (B) (e − 1, 2e − 1) (C) ⎜ , e − 1⎟ (D) ⎜ 0, ⎟
⎝ 2 ⎠ ⎝ 2 ⎠
46. (D)
f′(x) < 2f(x)
f ′(x)
<2
f (x)
f ′(x)
∫ f (x) dx < ∫ 2dx
n {f (x)} < 2x + c
f(x) < e2x + c
f(1/2) < e1 + c
1 < e1 + c ….(f(1/2)) = 1)
e0 < e 1 + c
0<1+c
c > −1 ….(i)
19
1 1
∫ ∫e
2x + c
f (x)dx < dx
1/2 1/2
1
1 2x + c 1
∫ f (x)dx < ⎡e
2⎣
⎤
⎦1/2
1/2
1
1
∫ f (x)dx < 2 ⎡⎣e − e1 + c ⎤⎦
2+c
1/2
1
1 1+ c
∫ f (x)dx < 2 e [e − 1]
1/2
1
1
Maximum value of ∫ f (x)dx is
2
[e − 1]
1/2
1
And minimum value of ∫ f (x) dx is greater than zero because it is positive, non-
1/2
constant function.
47. Let PR = 3iˆ + ˆj − 2kˆ and SQ = î − 3jˆ − 4kˆ determine diagonals of a parallelogram PQRS
and PT = î + 2ˆj + 3kˆ be another vector. Then the volume of the parallelepiped determined
by the vectors PT, PQ and PS is
(A) 5 (B) 20 (C) 10 (D) 30
47. (C)
PR = 3iˆ + ˆj − 2kˆ and SQ = î − 3ˆj − 4kˆ are diagonals of a parallelogram.
PT = î + 2ˆj + 3kˆ is another vector.
Volume of the parallelepiped by the vector PT, PQ & PS
a + b = 3iˆ + ˆj − 2kˆ S a
R
a − b = î − 3ˆj − 4kˆ
b
a = 2iˆ − ˆj − 3kˆ b
b = î + 2ˆj + kˆ P Q
a
Volume of parallelepiped formed by PT, PQ & RS is given by scalar triple product of
î + 2ˆj + 3kˆ , 2iˆ − ˆj − 3kˆ & î + 2ˆj + kˆ
1 2 3
Volume = 2 −1 −3 = 1(5) + 2(−5) + 3(5) = 5 − 10 + 15 = 10
1 2 1
x + 2 y +1 z
48. Perpendiculars are drawn from points on the line = = to the plane
2 −1 3
x + y + z = 3. The feet of perpendiculars lie on the line
x y −1 z − 2 x y −1 z−2
(A) = = (B) = =
5 8 −13 2 3 −5
x y −1 z − 2 x y −1 z−2
(C) = = (D) = =
4 3 −7 2 −7 5
20
48. (D)
x+2 y +1 z
Any point on = = is (2r − 2, −r−1, 3r).
2 −1 3
Let P(x, y) be feet of perpendicular then,
x − x1 y − y1 z − z1 ⎛ ax + by + cz + d ⎞
= = = − ⎜ 1 2 1 2 12 ⎟
a b c ⎝ a +b +c ⎠
x − (2r − 2) y − ( −r − 1) ) z − 3r 4r − 6
= = =−
1 1 1 3
4r − 6 2r 3 − 7r 5r + 6
So, x = 2r − 2 − = ; y= ; z=
3 3 3 3
⎛ 2r 3 − 7r 5r + 6 ⎞ x y −1 z − 2
Obviously ⎜ , , ⎟ satisfy = =
⎝ 3 3 3 ⎠ 2 −7 5
49. Four persons independently solve a certain problem correctly with probabilities
1 3 1 1
, , , . Then the probability that the problem is solved correctly by at least one of
2 4 4 8
them is
235 21 3 253
(A) (B) (C) (D)
256 256 256 256
49. (A)
Required Probability = 1 − P(No one solves the problem correctly)

1 1 3 7 235
=1− × × × =
2 4 4 8 256
1
50. Let complex numbers α and lie on circles (x − x0)2 + (y − y0)2 = r2 and (x − x0)2 +
α
(y − y0) = 4r , respectively. If z0 = x0 + iy0 satisfies the equation 2 |z0|2 = r2 + 2, then |α| =
2 2
1 1 1 1
(A) (B) (C) (D)
2 2 7 3
50. (C)
| α − Z0| = r (1)
1
and − Z0 = 2r (2)
α
(1) ⇒ (α− Z0) ( α − Z0 ) = r2
r2 r2
⇒ |α|2 − α Z0 − Z0 α + + 1 = r2 (∵, |Z0|2 = +1)
2 2
r2
⇒ α Z0 + Z0 α = | α |2+ 1 − (3)
2
(2) ⇒ 1 − αZ0 = 2r α
⇒ (1 − αZ0 ) .(1 − α Z0 ) = 4r2 α α
⎛ r2 ⎞
⇒ 1 − α Z0 − α Z0 + |α|2 ⎜⎜ + 1⎟⎟ = 4 r |α|
2 2
⎝ 2 ⎠
7r 2 2
⇒ α Z0 + α Z0 = 1 + |α|2 − |α| (4)
2
r2 7 1
(3) = (4) ⇒ |α|2 + 1 − = |α|2+ 1 − r2|α|2 ⇒ |α| =
2 2 7
21

51. A line passing through the origin is perpendicular to the lines
: (3 + t)iˆ + (−1 + 2t)ˆj + (4 + 2t)k,
1
ˆ −∞ < t < ∞
2 : (3 + 2s)iˆ + (3 + 2s)ˆj + (2 + s)k,

ˆ −∞ < s < ∞
Then, the coordinate (s) of the point (s) on 2 at a distance of 17 from the point of
intersection of and 1 is (are)
⎛7 7 5⎞ ⎛7 7 8⎞
(A) ⎜ , , ⎟ (B) (−1, −1, 0) (C) (1,1,1) (D) ⎜ , , ⎟
⎝ 3 3 3⎠ ⎝9 9 9⎠
51. (B), (D)
1 : r = (3i − j + 4k) + t(i + 2 j + 2k)
ˆ ˆ ˆ ˆ ˆ ˆ
2: r = (3iˆ + 3jˆ + 2k)

ˆ + s(2iˆ + 2ˆj + k)
ˆ
Vector perpendicular to î + 2ˆj + 2kˆ and 2iˆ + 2ˆj + kˆ is
î ˆj kˆ
1 2 2 = − 2iˆ + 3jˆ − 2kˆ
2 2 1
So, line is r = k (−2iˆ + 3jˆ − 2k) ˆ
For point of intersection of and 1
k (−2iˆ + 3jˆ − 2k)
ˆ = 3iˆ − ˆj + 4kˆ + t (iˆ + 2ˆj + 2k)
ˆ
(−2k − 3)iˆ + (3k + 1)ˆj + (−2k − 4)kˆ = t (iˆ + 2ˆj + 2k)
ˆ
−2k − 3 = t … (i)
and 3k + 1 = 2t … (ii)
−2k − 4 = 2t … (iii)
3k + 1
(ii) ÷ (iii) =1
−2k − 4
⇒ 3k + 1 = −2k − 4 ⇒ k = −1
From (i), −2 (−1) − 3 = t
⇒ t = −1. So, : r = 2iˆ − 3jˆ + 2kˆ
So, point of intersection of and 1 is A ≡ (2, −3, 2).
x −3 y −3 z −2
The line 2 can be written as = = =s
2 2 1
Any point on 2 (2s + 3, 2s + 3, s + 2) = B
Given, AB = 17
⇒ (2s + 1)2 + (2s + 6)2 + s2 = 17
⇒ 9s2 + 28s + 20 = 0
⇒ (s + 2) (9s + 10) = 0
10
s = −2 or s = −
9
⎛7 7 8⎞
So, point B ≡ (−1, − 1, 0) and ⎜ , , ⎟
⎝9 9 9⎠
22
52. Let f(x) = x sin πx, x > 0. Then for all natural numbers n, f ' ( x ) vanishes at
⎛ 1⎞
(A) a unique point in the interval ⎜ n, n + ⎟
⎝ 2⎠
⎛ 1 ⎞
(B) a unique point in the interval ⎜ n + , n + 1⎟
⎝ 2 ⎠
(C) a unique point in the interval (n, n + 1)
(D) two points in the interval (n, n + 1)
52. (B), (C)
f(x) = x sinπx
f′(x) = sinπx + (x) π(cosπx)
sinπx + xπ cosπx = 0
sinπx = −πx cos πx
tanπx = −πx
y
x
3 −1 1 1 1 3
− − 0
2 2 2 2
4n k(k +1)
53. Let Sn = ∑ (−1) 2 k2. Then Sn can take value(S)
k =1
(A) 1056 (B) 1088 (C) 1120 (D) 1332
53. (A), (D)
k(k +1)
4n
∑ (−1)
2
Sn = .k 2
k =1
= (−1)1.12 + (−1)3.22 + (−1)6.32+ (−1)10.42 + ….. upto 4n terms
= − 12 − 22 + 32 + 42 − 52 − 62 + …. + (4n)2
= − 1 + 5 − 9 + 13 − 17 + ….. + 16n2 (2n − 1 + 2 terms)
= 4 + 4 + 4 + 16n 2
n times
2
= 16n + 4n
54. For 3 × 3 matrices M and N, which of the following statement(s) is (are) NOT correct?
(A) NT M N is symmetric or skew symmetric, according as M is symmetric or skew
symmetric
(B) M N − N M is skew symmetric for all symmetric matrices M and N
(C) M N is symmetric for all symmetric matrices M and N
(D) (adj M) (adj N) = adj (M N) for all invertible matrices M and N
23
54. (C), (D)

(C) is wrong as (MN)T = NT MT = NM ≠ MN
(D) is wrong as adj (MN) = adj (N) adj (M) for all invertible M and N.
55. A rectangular sheet of fixed perimeter with sides having their lengths in the ratio 8 : 15 is
converted into an open rectangular box by folding after removing squares of equal area
from all four corners. If the total area of removed squares is 100, the resulting box has
maximum volume. Then the lengths of the sides of the rectangular sheet are
(A) 24 (B) 32 (C) 45 (D) 60
55. (A), (C)
Let the sides be 8C and 15C where C is a parameter given 2 (8C + 15 C) = K (constant)
K
⇒ C =
46
Now,
15C − 2x
∴ Volume is given by
xx xx
V = (8C − 2x) (15C − 2x) x
or V = 4x3 − 46x2C + 120C2x
dv 8C − 2x
⇒ = 12x2 − 92 xC + 120 C2 … (1)
dx
area of all squares = 4x2 = 100
⇒ x=5
dv
∴ = 0 for maximum volume at x = 5
dx
∴ using x = 5 in (1) we get
120 C2 − 460 C + 300 = 0
⇒ 6C2 − 23C + 15 = 0
⇒ C = 3 or 5/6
but C = 5/6 and x = 5 makes sides negative. Thus C = 3 is the only value of the
parameter.
Hence sides are 24, 45.

{ }
56. Consider the set of eight vectors V = ai + b j + ck : a, b, c∈{−1,1} . Three non−coplanar
vectors can be chosen from V in 2p ways. Then p is,
56. [5]
Total number of vectors are,
î + ˆj + kˆ î + ˆj − kˆ
− î + ˆj + kˆ − î + ˆj − kˆ
î − ˆj + kˆ î − ˆj − kˆ
− î − ˆj + kˆ − î − ˆj − kˆ
Total no. of ways choosing non−coplanar vectors
( ) ( ) ( )
= 4 C2 × 2 C1 + 4 C1 × 3C 2 + 2 4 C3 = 12 + 12 + 8 = 32
P
2 = 32
P=5
24
57. Of the three independent events E1, E2 and E3, the probability that only E1 occurs is α,
only E2 occurs is β and only E3 occurs is γ. Let the probability p that none of events E1, E2
or E3 occurs satisfy the equations (α − 2β) p = αβ and (β − 3γ) p = 2βγ. All the given
probabilities are assumed to lie in the interval (0, 1).
Pr obability of occurrence of E1
Then =
Pr obability of occurrence of E3
57. [6]
P (E1) = x
P (E2) = y
P (E3) = z
Then x (1 − y) (1 − z) = α
y (1 − z) (1 − x) = β
z (1 − x) (1 − y) = γ
(1 − x) (1 − y) (1 − z) = P
Now,
(α − 2β) P = αβ
⇒ [x (1 − y) (1 − z) − 2y (1 − z) (1 − x)] (1 − x) (1 − y) (1 − z)
= xy (1 − y) (1 − z)2 (1 − x)
⇒ x (1 − y) − 2y (1 − x) = xy
⇒ x − xy − 2y + 2xy = xy
⇒ x = 2y
x
⇒ = 2(1)
y
Also,
[y (1 − z) (1 − x) − 3z (1 − x) (1 −y)] (1 − x) (1 − y) (1 − z) = 2yz (1 − z) (1 − y) (1 − x)2
⇒ y (1 − z) − 3z (1 − y) = 2yz
y
⇒ y − 3z = 0 ⇒ =3
z
x
∴ =6
z
58. The coefficients of three consecutive terms of (1 + x)n + 5 are in the ratio 5 : 10 : 14.
Then n =
58. [6]
Let the coefficients of three consecutive terms be n +5 Cr , n +5 Cr +1 and n +5 C r + 2
n +5 n +5 n +5
Given Cr : Cr +1 : C r + 2 : : 5 : 10 : 14
Solving n +5 Cr : n +5 Cr +1 : : 5 : 10
We get 3r = n + 3 …(1)
likewise solving
n +5
C r +1 10
n +5
= we get
Cr + 2 14
12r = 5n + 6 …(2)
solving (1) & (2) we get n = 6.
59. A pack contains n cards numbered from 1 to n. Two consecutive numbered cards are
removed from the pack and the sum of the numbers on the remaining cards is 1224. If the
smaller of the numbers on the removed cards is k, then k − 20 =
25
59. [5]
n(n + 1)
The sum of first n cards is, S = .
2
if two consecutive cards numbered k and k + 1 are removed then
n(n + 1)
s′ = − (k + k + 1) = 1224 (given)
2
⇒ n(n + 1) = 2450 + 4k, which is satisfied for n = 50
and k = 25 in the given limits
∴ k = 25 and k − 20 = 5.
x 2 y2
60. A vertical line passing through the point (h, 0) intersects the ellipse + = 1 at the
4 3
points P and Q. Let the tangents to the ellipse at P and Q meet at the point R.
max
Δ ( h ) and , Δ 2 =
min
If Δ(h) = area of the triangle PQR, Δ1 = Δ ( h ) then
1/ 2 ≤ h ≤ 1 1/ 2 ≤ h ≤ 1
8
Δ1 − 8Δ 2 =
5
60. [9]
Let, line x = h
h 2 y2 ⎛ 3 ⎞
For P and Q points + =1 P ⎜ h, 4 − h2 ⎟
4 3 ⎝ 2 ⎠
⎛ h2 ⎞
⇒ y 2 = 3 ⎜⎜1 − ⎟⎟ (h, 0) R
⎝ 4 ⎠
3 ⎛ ⎞
y 2 = (4 − h 2 ) Q ⎜ h, −
3
4 − h 2 ⎟⎟
4 ⎜ 2
⎝ ⎠
3
y=± 4 − h2
2
3
y⋅ 4 − h2
xh 2 ⎛4 ⎞
Tangent at P, + =1. So, R ⎜ , 0⎟
4 3 ⎝h ⎠
⎛4 ⎞ 4 − h2 3 (4 − h 2 )3/2
ΔPQR =
1
2
⋅ ( 3 4 − h2 ) ⋅⎜ − h⎟ =
⎝h ⎠ 2
3
⋅ 4 − h2 ⋅
h
=
2
⋅
h
4 − h2
Δ′ = −6 3 ⋅ <0∀h ⇒ Δ is decreasing
h2
3/2
⎛ 1⎞
⎜ 4− ⎟ 3/2
⎛ 1⎞ 3 ⎝ 4⎠ ⎛ 15 ⎞
So, Δ1 = max Δ (h) ⎜ at h = ⎟ = ⋅ = 3 ⋅⎜ ⎟
≤
≤
1
h 1 ⎝ 2⎠ 2 1 ⎝4⎠
2
2
3 3/2
Δ2 = min Δ(h) (at h = 1) = ⋅3
2
8 ⎡ 1 ⎛ 15 ⎞
3/2
3 3/2 ⎤ ⎡5×9 9 ⎤
So, Δ1 − 8Δ 2 = 8⎢ ⋅ 3 ⋅⎜ ⎟ − 3 ⎥ = 8⎢ − ⎥ =9
5 ⎣⎢ 5 ⎝ 4⎠ 2 ⎦⎥ ⎣ 8 2⎦
26

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IIT - JEE 2013 (Advanced)

(A) 2.0 s (B) 3.0 s (C) 4.5 s (D) 6.0 s

5. A pulse of light of duration 100 ns is absorbed completely by a small object initially at

9. A ray of light travelling in the direction

reflection, it travels along the direction

11. (B), (D)

SECTION III : (Integer value correct Type)

21. Consider the following complex ions, P, Q and R.

23. Sulfide ores are common for the metals

H2O = −300 kJ / mol

28. In the reaction,

SECTION II : (One or more options correct Type)

34. Among P, Q, R and S, the aromatic compound(s) is /are

(A) P (B) Q (C) R (D) S

All are Aromatic except (R)

SECTION III : (Integer value correct Type)

37. EDTA4− is ethylenediaminetetraacetate ion. The total number of N − Co − O bond angles

38. The total number of carboxylic acid groups in the product P is

PART III : MATHEMATICS

∫ f (x) dx lies in the interval

Required Probability = 1 − P(No one solves the problem correctly)

SECTION II : (One or more options correct Type)

2 : (3 + 2s)iˆ + (3 + 2s)ˆj + (2 + s)k,

2: r = (3iˆ + 3jˆ + 2k)

54. (C), (D)

SECTION III : (Integer value correct Type)

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