Sheet1

LAB DATA
Acetone Vol (ml) Benzene Vol (ml) XA XB
0.9 0.1 0.909406533644592 0.0905934663554083
0.8 0.2 0.816899353520903 0.183100646479097
0.7 0.3 0.722417173837194 0.277582826162806
0.6 0.4 0.625896063700447 0.374103936299553
0.5 0.5 0.527269302856229 0.472730697143771
0.4 0.6 0.426467227883144 0.573532772116857
0.3 0.7 0.323417068096781 0.676582931903219
0.2 0.8 0.218042770350862 0.781957229649138
0.1 0.9 0.110264811849166 0.889735188150834

Standard Data of Mixture Components

Density (Kg/m3) Molecular Weight (gm/mol)

Acetone 729 58.08
Benzene 879 78.11

Linear Interpolation (Regression)

RI = m*XA + C Y-Intercept 1.47683318677653

Slope -0.107732912268715

LIQUID

Temp (°C ) RIAVG XA XB

57.9 1.4078 0.640780847029744 0.359219152970257
64.2 1.4379 0.361386190688119 0.638613809311882

Relative
Volatility (α) 2.41454945501069

Henry’s Constant Calculation

LIQUID

Temp (°C ) RIAVG XA XB

57.9 1.4078 0.640780847029744 0.359219152970257
64.2 1.4379 0.361386190688119 0.638613809311882

Psat Calculation using Antoine Equation

Psat-Acetone
Temp (°C ) A B C
57.9 7.1327 1219.97 230.653
64.2 7.1327 1219.97 230.653

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Activity Coefficient Calculation using Modified Rault’s Law

Temp (°C ) Psat-A (bar) Psat-B (bar) Ptotal (bar)

57.9 1.07081 0.484497 0.86019514076455
64.2 1.31841 0.604403 0.862435269854652

Van Laar Constant Calculation

log(γA) log(γB) ln(γA/γB) a

0.007502952337 0.0419941407328 -0.0794188962394547 0.00750560310317421
-0.065941072589 0.0679599355337 -0.308318465239426 -0.064900820260566

Final Data
Temp (°C ) XA YA γA
57.9
64.2

Gibs Duhem Equation Area Calculation using Trapezoid Method of Numerical Inte

Slope 0.819269674
Y-Intercept -0.604391212 Is Area Less than Acceptable Limit (|A| < 0.2)
Approx Area -0.194756375 TRUE

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Refractive Index (RI) Calibration Curve : RI v/s Acetone

1.3793
f(x) = − 0.107732912268715 x + 1.47683318677653
1.3883 1.48
1.3963
1.46
1.411
1.4237 1.44 Acetone Vol (ml)

Refractive Index
1.4274 1.42 Linear (Acetone V
1.4433 (ml))
1.4
1.4547
1.4633 1.38
1.36
1.34
Boiling Point (°C) 1.32
56.2 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
81.1 Xa

VAPOUR

RIAVG YA YB
1.3894 0.81157359376 0.188426406
1.4257 0.47462920754 0.525370792

VAPOUR KH Values

RIAVG YA YB KA KB
1.3894 0.81157359376 0.188426406 1.26653847 0.524544431
1.4257 0.47462920754 0.525370792 1.313357344 0.822673711

Psat-Benzene
Psat-A A B C Psat-B
1.07081 6.87987 1196.76 219.161 0.484497
1.31841 6.87987 1196.76 219.161 0.604403

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Modified Rault’s Law

γA γB
1.01742628262874 1.10152444827
0.85913008498835 1.16939150752

b
0.04204135917439 // Values Calculated assuming log = log10
0.06761568538139

γB ln(γA/γB) KA KB

n using Trapezoid Method of Numerical Integration

an Acceptable Limit (|A| < 0.2) Is Thermodynamically consistent A more Volatile than B
FALSE TRUE

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v/s Acetone Calibration Curve : RI v/s Acetone

268715 x + 1.47683318677653 f(x) = − 0.1076 x + 1.47461111111111
1.48
1.46
Acetone Vol (ml) 1.44
Linear (Acetone Vol Acetone Vol (ml)
Refractive Index

1.42
(ml)) Linear (Acetone Vol
1.4 (ml))
1.38
1.36
1.34
1.32
0.8 0.9 1 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
Acetone Vol (in ml)

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Regression
Regression MoLinear

LINEST raw output

0.819269674 -0.60439121
0 0
1 0
#N/A 0
0.026197506 0

Regression Statistics
R^2 1
Standard Error 0
Count of X var 1
Observations 2
Adjusted R^2 #DIV/0!

Analysis of Variance (ANOVA)

df SS
Regression 1 0.026197506
Residual 0 0
Total 1 0.026197506

Confidence lev 0.95

Coefficients Standard Error

Intercept -0.60439121 0
X1 0.819269674 0

X1 Predicted Y Y
0.640780847 -0.0794189 -0.0794189
0.361386191 -0.30831847 -0.30831847

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Regression
Regression MoLinear

LINEST raw output

-0.10773291 1.476833187
0.003176685 0.001843866
0.993950572 0.002457532
1150.134113 7
0.006946193 4.22762E-05

Regression Statistics
R^2 0.993950572
Standard Error 0.002457532
Count of X var 1
Observations 9
Adjusted R^2 0.993086368

Analysis of Variance (ANOVA)

df SS MS F Significance F
Regression 1 0.006946193 0.006946193 1150.134113 5.02292E-09
Residual 7 4.22762E-05 6.03946E-06
Total 8 0.006988469

Confidence lev 0.95

Coefficients Standard Errort-Statistic P-value Lower 95%

Intercept 0.001843866 800.9440757 1.24895E-18 1.472473138
X1 0.003176685 -33.9136272 5.02292E-09 -0.11524458

X1 Predicted Y Y Residual
0.909406534 1.378860172 1.3793 0.000439828
0.816899354 1.38882624 1.3883 -0.00052624
0.722417174 1.399005081 1.3963 -0.00270508
0.625896064 1.409403581 1.411 0.001596419
0.527269303 1.420028929 1.4237 0.003671071
0.426467228 1.43088863 1.4274 -0.00348863
0.323417068 1.441990524 1.4433 0.001309476
0.21804277 1.453342804 1.4547 0.001357196
0.110264812 1.464954037 1.4633 -0.00165404

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MS F Significance F
0.026197506 #N/A #N/A
#DIV/0!

t-Statistic P-value Lower 95% Upper 95%

#DIV/0! #DIV/0! Err:502 Err:502
#DIV/0! #DIV/0! Err:502 Err:502

Residual
0
0

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Significance F

Upper 95%
1.481193236
-0.10022125

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