General Chemistry 1 Final Exam Spring, 2013 (1/2)

감독자인
계열/학부/학과: 학번: 고유번호: 성명:
수업요일 및 담당교수명: ( , )요일 ( )교수 자필서명:

H He <주의 사항>
Li Be B C N O F Ne 1. 답은 지정된 자리에 반드시 영문(English)으로 기입할 것.
Na Mg Al Si P S Cl Ar 2. 시험 시간은 60분임. 400점 만점 (full score = 400 pt).
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 3. 문제지는 1장(2면)임. 연습지 및 영한사전 사용 불가.
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 4. 6-11번은 풀이과정을 반드시 밝힐 것. (단위, 유효숫자에 유의)
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 5. 계산기 사용 무방하나 빌려 쓰지는 못함.
Fr Ra Ac

1. Write ‘T’ for true statement or ‘F’ for false statement in ( ). 3. Choose the correct answer and write it in ( ).
−
[10 pt each]
[7 pt for right answer, 3 pt for wrong, and 0 pt for no answer] ( B) Choose the case in which the order of acid strength is
( F) During a titration the point at which stoichiometrically incorrectly indicated.
equivalent amounts of acid and base have reacted is called the (A) H2SeO4 < H2SO4 (B) H2Se < H2S (C) H2SO4 > H2SO3
end point. (D) H2SeO4 > H2SeO3 (E) H2SO4 > HSO4-
( F) A solution whose molarity is very accurately known is called ( A) Which response lists the acid-base reactions that can be
a primary standard. explained only by the Lewis acid-base theory?
I. SnCl4(l) + 2Cl−(aq) →
SnCl62−(aq)
→
( F) Quartz is an example of a molecular crystal.
II. Al(OH)3(s) + 3HCl(aq) AlCl3(aq) + 3H2O(l)
( F) Diffusion only occurs with gases and liquids.
III. BCl3(g) + NH3(g) →Cl3B:NH3
( F) Dipole-dipole interactions have a relationship to distance that →
IV. CO2(g) + H2O(l) H2CO3(aq)
7
is equal to 1/d . V. NH3(g) + HBr(g) →
NH4Br(s)
( T) A liquid will rise in a capillary when the adhesive forces are (A) I, III, and IV (B) I, II, and V (C) II, IV, and V
stronger than the cohesive forces. (D) II, III, and IV (E) I, IV, and V
( F) Molecular geometry of hydrogen sulfide molecule is linear. ( A) If 200.0 mL of 2.00 M H3PO4 solution is added to 600.0
( T) The greater the bond order is, the shorter the bond length is. mL of 2.00 M NaOH solution, the resulting solution will be
( T) In a diatomic molecule, the character of antibonding orbital molar in Na3PO4.
is closer to the character of less electronegative element than that (A) 0.500 (B) 0.667 (C) 0.800 (D) 1.50 (E) 1.500
of more electronegative element. ( E) How many sigma (σ) bonds and how many pi (π) bonds
( T) All Arrhenius acids are also Lewis acids. does the acetylene molecule contain?
+
( F) Protons (H ions) in water can exist either as hydronium ions (A) 5 σ and 1 π (B) 2 σ and 3 π (C) 3 σ and 1 π
or as free protons. (D) 2 σ and π (E) 3 σ and 2 π

( T) HCl, HBr, and HI in water have the same acid strength. ( A) The conduction band of magnesium is thought to result from
the combination of molecular orbitals resulting from overlap of
2. The following is a molecular orbital energy level diagram for a
__________ atomic orbitals.
heterogeneous diatomic molecule, XY, in which both X and Y
(A) 3s and 3p (B) 3s and 3d (C) 3d and 4s
are from Period 2 and Y is slightly more electronegative.
(D) 3p and 3d (E) 3s and 4s
(1) What is the bond order of NO?
2.5 [10 pt] ( A) For which of the following would hydrogen bonding not be

(2) Is NO
− paramagnetic or an important factor in determining physical properties of liquids?
(A) HBr (B) H2O (C) HF (D) NH3 (E) H2O2
diamagentic? [10 pt]
( C) Which one of the statements below about the following
paramagnetic reaction is false? CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(g)
(3) In the following list of diatomic (A) Every methane molecule produces two water molecules.
molecules, find all the molecules (B) If 16.0 g of methane react with 32.0 g of oxygen, the
whose bond will become weaker maximum amount of CO2 produced will be 22.0 g.
when an electron is added into their (C) If 11.2 liters of methane react with an excess of oxygen, the
molecular orbital. Some molecules are volume of CO2 produced at STP is (44/16)(11.2) liters.
stable only in the vapor state at (D) If 16.0 g of methane react with 64.0 g of oxygen, the
elevated temperatures. [15 pt] combined masses of the products will be 80.0 g.
(E) If 22.4 liters of methane at STP react with 64.0 g of oxygen,
B2, C2, F2, NO, HF 22.4 L (STP) of CO2 can be produced.
F2, NO, HF ( E) What is the oxidation number of phosphorus in Ca (PO ) ?
3 4 2
(A) +6 (B) +7 (C) +3 (D) +4 (E) +5

1 2 3 4 5 6 7 8 9 10 11 Total
84 35 80 15 60 15 15 17 15 32 32 400
 General Chemistry 1 Final Exam Spring, 2013 (2/2)
4. Arrange the following in order of increasing melting points and 9. Using the Clausius-Clapeyron equation determine the vapor
note the intermolecular forces involved or structure responsible pressure of water at 50.0 °C. The molar heat of vaporization of
for the melting point. KCl, He, C (diamond), H2O, HF. [15 pt] water is 40.7 kJ/mol, the gas constant is 8.314 J/K·mol. [15 pt]
( ) < ( ) < ( ) < ( ) < ( ) æ ö
ln ç P 2 ÷ =
DH vap æ1
ç –
1 ö÷
reason: è P1 ø R è T1 T2 ø
He (dispersive or London) < HF (weak H-bonding) < H2O (strong P1 = 1.00 atm or 760. torr, T1 = 373 K,
H-bonding) < KCl (Ion-Ion) < C (covalent solid)
and T2 = 323 K

5. Complete the following table. [15 pt each]

∴ P2 = 0.131 atm or 99.7 torr
Type L for linear; B for bent (or angular); 10. Molybdenum(III) oxide will be oxidized to potassium
TP for trigonal planar; SP for square planar; molybdate, K2MoO4, by reaction with KMnO4 in acidic solution.
Td for tetrahedral; Oh for octahedral;
SS for seesaw; T for T-shaped; (1) Balance the related net ionic equation. What is the sum of the
TBP for trigonal bipyramidal; SPy for square pyramidal; coefficients? [17 pt]
TPy for trigonal pyramidal (or pyramidal). −
MnO4 + Mo + H2O
3+ 2+
Mn + MoO4 + H→2− +

Molecule Electronic Molecular Hybridization (e.g., sp) (unbalanced)

or Ion
Cl2O
Geometry
( Td )
Geometry
( B )
of the Central Atom
( sp
3
) 2-
-
3 MnO4 + 5 Mo
+
3+
+ 8 H2O 3 Mn
2+
+ 5 →
IF4
− ( Oh ) ( SP ) ( sp d
3 2
)
MoO 4 + 16 H

AsH3 ( Td ) ( TPy ) ( sp3 ) 40

3
ClF3 ( TBP ) ( T ) ( sp d )
6. How much heat would be required to convert 234 g of solid (2) What mass of molybdenum(III) oxide will be completely
benzene, C6H6(s), at 5.5°C into benzene vapor, C6H6(g), at 100.0 oxidized to potassium molybdate, K2MoO4, by 35.0 mL of 0.200
°C? [Atomic mass (g/mol): H = 1.01, C = 12.0] [15 pt] M KMnO4? [Molar atomic mass (g/mol) of Mo = 95.9, K =
mp of C6H6(s) = 5.5°C, ΔHfusion at 5.5°C = 9.92 kJ/mol 39.1, Mn = 54.9, O = 16.0] [15 pt]
bp of C6H6(l) = 80.1°C, ΔHvaporization at 80.1°C = 30.8 kJ/mol
molMo2O3 = (0.200×0.0350)×(5/3)×(1/2) = 0.00583 mol
molar heat capacity of C6H6(l) = 136 J/mol·°C
molar heat capacity of C6H6(g) = 81.6 J/mol·°C gMo2O3 = 0.00583×239.8 = 1.40 g
molC6H6 = 234. / (6×12.0 + 6×1.01) = 3.00 mol
Heat = 3.00 × (9.92 + 0.136×74.6 + 30.8 + 0.0816×19.9)
= 29.8 + 30.4 + 92.4 + 4.87 = 157.47 = 157.5 kJ
11. Magnesium carbonate, MgCO3, decomposes according to:
(or = 3.00 × 52.5 = 157.5 = 158 kJ) MgCO3(s) MgO(s) + CO2(g). →
A 17.00 g sample of impure magnesium carbonate is completely
decomposed at 1000 °C in a previously empty 1.00 L vessel.
7. Hydrogen was collected over water at 19 ºC and 757 torr. After the reaction was complete, the solid residue (consisting
The volume of this gas sample was 35.3 mL. What volume only of MgO and the original impurities) had a mass of 14.35
would the dry hydrogen occupy at STP? Vapor pressure of g. Assume that no other constituent of the sample produced a
water: VP(19 ºC) = 16 torr. [15 pt] gas and that the volume of any solid was negligible compared to
– –
P(H2) = Ptotal P(H2O) = 757 16 = 741 torr the gas volume. [R = 8.314 J/K·mol = 0.0821 L·atm/K·mol;
Molar masses (g/mol): C = 12.01; O = 16.00; Mg = 24.31]
(1) What was the pressure of the CO2 produced? [17 pt]
Weight CO2 = (17.00 – 14.35) g = 2.65 g
M(CO ) = 44.01 g/mol ∴ 2.65 g CO = 0.06021 molCO
2 2 2

P = nRT / V
8. Metallic calcium crystallized in a face-centered cubic lattice, = 0.06021 mol × 0.0821 Latm/Kmol × (1000+273) K / 1 L
and the atomic radius of calcium is 1.97 Å. Calculate the
= 6.29 atm
density of calcium. [Molar atomic mass (g/mol) of Ca = 40.1 ,
23
NA = 6.02 × 10 ] [17 pt] (2) What percent of the original sample was magnesium
carbonate? [15 pt]

Unit cell volume = {(4 × 1.97×10

-8
cm)/ √2} 3
=1.73×10
-22 3
cm
n(CO2) : n(MgCO3) = 1:1 ∴ n(MgCO ) = 0.06021 mol
3

with M(MgCO3) = 84.32 g/mol

Unit cell mass = 4 × 40.1 / (6.02×1023) = 2.66×10-22 g
∴ density = 2.66×10 -22
/ 1.73×10
-22
= 1.54 g/cm
3 m(MgCO3) = 0.06021 × 84.32 = 5.077 g
% purity = 5.077g / 17.00 g (total) × 100% = 29.86 %

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