You are on page 1of 15

See discussions, stats, and author profiles for this publication at: https://www.researchgate.

net/publication/272429071

Injection rates and cost estimates for CO2 storage in the west Mediterranean
region

Article in Environmental Earth Sciences · March 2015


DOI: 10.1007/s12665-015-4029-z

CITATIONS READS

24 1,858

5 authors, including:

R. Martínez Yassine Zarhloule


Instituto Geológico y Minero de España Université Mohammed Premier
31 PUBLICATIONS 232 CITATIONS 59 PUBLICATIONS 723 CITATIONS

SEE PROFILE SEE PROFILE

A. Rimi
Mohammed V University of Rabat
46 PUBLICATIONS 1,105 CITATIONS

SEE PROFILE

All content following this page was uploaded by A. Rimi on 04 February 2016.

The user has requested enhancement of the downloaded file.


Injection rates and cost estimates for CO2
storage in the west Mediterranean region

Júlio Carneiro, Roberto Martinez, Isabel


Suaréz, Yassine Zarhloule & Abdelkrim
Rimi

Environmental Earth Sciences

ISSN 1866-6280

Environ Earth Sci


DOI 10.1007/s12665-015-4029-z

1 23
Your article is protected by copyright and
all rights are held exclusively by Springer-
Verlag Berlin Heidelberg. This e-offprint is
for personal use only and shall not be self-
archived in electronic repositories. If you wish
to self-archive your article, please use the
accepted manuscript version for posting on
your own website. You may further deposit
the accepted manuscript version in any
repository, provided it is only made publicly
available 12 months after official publication
or later and provided acknowledgement is
given to the original source of publication
and a link is inserted to the published article
on Springer's website. The link must be
accompanied by the following text: "The final
publication is available at link.springer.com”.

1 23
Author's personal copy
Environ Earth Sci
DOI 10.1007/s12665-015-4029-z

THEMATIC ISSUE

Injection rates and cost estimates for CO2 storage in the west
Mediterranean region
Júlio Carneiro • Roberto Martinez •
Isabel Suaréz • Yassine Zarhloule • Abdelkrim Rimi

Received: 24 February 2014 / Accepted: 5 January 2015


Ó Springer-Verlag Berlin Heidelberg 2015

Abstract The COMET project aimed at studying the on the emission mitigation scenario, and should be the
development of an integrated CO2 transport and storage focus of future research.
infrastructure for Morocco, Portugal and Spain, and
included the assessment of existing storage opportunities Keywords CCS infrastructure  CO2 storage  Injection
and capacities. Those countries have, jointly, enough rate  Storage costs  Pressure build-up  Morocco 
capacity to store almost 200 years of their current CO2 Portugal  Spain
emissions, but defining a cost-effective infrastructure
implies establishing the storage costs at each potential site.
This article describes the methodology pursued and the Introduction
results of that cost assessment, including the estimates
made for the annual injection rate and number of admis- CO2 capture and storage (CCS) is a greenhouse gas
sible wells at each site. Several analytical solutions abatement technology that can contribute up to 14 % to the
describing the pressure build-up with CO2 injection were CO2 emission reduction required in 2050 to ensure that the
applied and a total injection rate of 558 MtCO2/a was global temperature rise stays below 2 °C (IEA 2012).
found for the study area, although many potential sites are While CO2 capture technology can be developed at an
uneconomical due to presenting a very low injection rate. international level, the development of a CO2 transport and
The storage costs spread over a very broad spectrum of storage infrastructure requires insights into specific regio-
values, but around 50 % of the injection sites show storage nal and local circumstances. In the EU co-funded COMET
costs below 10 €/tCO2. Of the 43 storage clusters defined in project (Boavida et al. 2011, 2013a), these insights were
the study area, about 11–15 are cost-effective, depending generated for the region encompassing Morocco, Portugal,
and Spain, here designated as the west Mediterranean
region. These countries were responsible for emissions
from stationary sources of 170 Mt CO2-equivalent in 2009,
J. Carneiro (&) and due to its peripheral location, this region will have
Departamento de Geociências, Escola de Ciências e Tecnologia,
difficulties in connecting to other CCS infrastructures in
Instituto de Investigação e Formação avançada, Centro de
Geofı́sica de Évora, Universidade de Évora, Évora, Portugal Europe or Africa. The motivations for considering an
e-mail: jcarneiro@uevora.pt integrated infrastructure for this region are related not only
to the geographical proximity but also to the increasing
R. Martinez  I. Suaréz
connections between the energy and industrial sectors in
Instituto Geológico y Minero de España-IGME, Madrid, Spain
the region, to the continuity of sedimentary basins and to
Y. Zarhloule the existing experience in managing a large-scale gas
University Mohamed I, Oujda, Morocco transport infrastructure.
The overall strategy of COMET considered three stages:
A. Rimi
University Mohamed V Agdal-Institut Scientifique, (1) harmonized inventory and mapping of CO2 sources and
Rabat, Morocco storage capacities in the region; (2) modelling of national

123
Author's personal copy
Environ Earth Sci

and regional energy systems; (3) definition and assessment Spain was conducted at a local scale, focusing in the areas
of least cost transport networks in the study area. and reservoirs previously identified in the EU GeoCapac-
Stages 2 and 3 involved the use of an energy system ity, and aiming to define the most suitable structures and
model (TIMES-COMET) to estimate the volume of CO2 traps (Martinez et al. 2013).
likely to be captured at source clusters from 2020 to 2050 The effective storage capacity in the three countries
(Kanudia et al. 2013). The geographic definition of the amounts to nearly 30 GtCO2, with Spain holding around 22
transport and storage infrastructure depends on identifying GtCO2, while estimates for Portugal indicate 7.5 GtCO2
the storage clusters able to accommodate that amount of and onshore storage in Morocco amounts only to 0.4
CO2 at the lowest transport and storage cost. Transport GtCO2 (Boavida et al. 2013b). Structures with a capacity
costs are addressed by a linear cost model implemented in a lower than 3 Mt were discarded and the Morocco offshore
GIS tool, detailed in van den Broek et al. (2013). The storage capacity was not assessed. The storage capacity is
storage costs are strongly dependent on site-specific factors distributed through several sedimentary basins, with more
and some of these factors, such as the injection rate and than 95 % being located in deep saline aquifers in onshore
number of injection wells, are difficult to define in the settings (Fig. 1a). As expected, given the size of the sedi-
initial stages of planning. These factors are critical for safe mentary basins and the results of the regional-scale
storage, because assuming high injection rates to minimize assessment conducted in EU GeoCapacity Project, the
costs can result in excessive pressure build-ups, increasing number of potential structures identified in Spain is large,
the risk of fracturing the reservoir or containment totalling 118. A much lower number of potential injection
formations. sites were identified for the other countries, 36 sites in
This article presents the methodology and results of Portugal and only 9 sites in Morocco (Fig. 1b). In total, the
storage cost estimation, which implied quantifying the effective storage capacity assessed in the 163 potential sites
injection rate and number of injection wells. Ultimately the is enough to store almost 200 years of the current CO2
objective was to maximize the total injection rate without emissions from stationary sources in the three countries.
inducing pressure increases that could jeopardise the
The 163 potential injection sites were combined in 43
integrity of the storage complex. The components of the
storage clusters, identified in Fig. 1a by the designation S#,
storage costs and a brief overview of the existing analytical
according to three criteria:
solutions for computing the injection rate are first intro-
1. Continuity of geological basin/structure—if contigu-
duced. The methodology, relying on the use of some of
ous storage sites are part of the same sedimentary basin
those analytical solutions and on assumptions related to the
they may be considered in the same cluster;
admissible pressure build-up and well interference, is then
2. Distance between centres of sites—several clusters
described. Finally, the results for the study region are
may still result in the same basin if the centroids of the
presented and their influences on the overall design of the
polygons defining the sites (regarded as the potential
storage infrastructure in the target countries are discussed.
injection well location) are very distant from each
other. No constant distance was imposed and instead a
decision was made on a case-by-case analysis;
Background
3. Onshore/offshore setting—clusters cannot include sites
on different onshore/offshore settings, even if there is
Storage capacity in the study region
geological continuity between them due to the very
different costs expected for onshore and offshore
The identification and assessment of cost-effective CO2
storage.
storage opportunities were required in COMET to delineate
a suitable CO2 transport and storage infrastructure for its
specific study region. Storage cost components
Spain had already conducted a regional storage capacity
assessment within the scope of the EU GeoCapacity Pro- CO2 storage costs depend strongly on the type of reservoir
ject (Vangkilde-Pedersen et al. 2009a, b), but previous (saline aquifers, hydrocarbon fields, etc.), setting (onshore,
work regarding CO2 geological storage in Portugal (Car- offshore), surface area that needs to be characterized and
neiro et al. 2011; Machado et al. 2007) and Morocco monitored during operation, or the previous existence of
(Carneiro et al. 2008) had been done only at very pre- wells and/or facilities. As any economic analysis of an
liminary stages. In the COMET project deep saline aquifers industrial operation, storage cost estimation includes
in Portugal and deep saline aquifers and depleted oil and investments needed, capital costs and operational costs,
gas fields in Morocco have been identified and their storage including monitoring and verification. In COMET the
capacity assessed at the regional scale. The approach in development costs (previous exploration and

123
Author's personal copy
Environ Earth Sci

(a) (b)
Number of sites

36

Morocco
118 Portugal

Spain

Storage capacity (Mt CO2)


417

7469

21776

Fig. 1 Location of potential storage areas (a) and their estimated capacities in the west Mediterranean region (b)

implementation of facilities) were considered an invest- preparation of the drilling site and costs for environmental
ment dependent on the volume of the potential storage impact assessment study. It also includes monitoring invest-
complex and its injection rate. ment costs before the injection phase. In general, it is expected
The investment costs for each site were estimated that for depleted gas and oil fields geological and geophysical
according to van den Broek et al. (2010): data are available (in €).
I ¼ W ðCd H þ Cw Þ þ Csf þ Csd ð1Þ Although not specifically included in Eq. (1), the vol-
ume of CO2 per unit time that can be injected at each site
where I = investment costs (€); W = number of wells per without affecting safety conditions, i.e., the injection rate,
site. The number of wells depends on the storage potential and is an essential component of the storage costs since it
the injection rate per well for the site; Cd = drilling costs (€ constrains the number of injection wells that can be con-
per metre, Cd = 0 if old wells can be re-used); H = drilling sidered in each structure.
depth, being the depth of the reservoir starting at the bottom of
the sea (for offshore sites) or the ground surface (for onshore Overview of injection rate calculation methods
sites) plus the thickness of the reservoir (in metre); Cw = fixed
costs per well (in €). In case of re-use of existing wells, these The importance of the injection rate to the viability of CO2
are the costs for the workovers of those wells (i.e. to make the storage was stressed by Ehlig-Economides and Econo-
well suitable for CO2 storage); Csf = investment costs for the mides (2010), in which the authors advocate that low
surface facilities on the injection site and investments for compressibility of fluids and rocks does not allow for large-
monitoring (e.g. purchase and emplacement of permanent scale storage of CO2. A reply by Cavanagh et al. (2010)
monitoring equipment) (in €); Csd = investment costs for the stresses the importance of clearly distinguishing between
site development costs, e.g. site investigation costs, costs for closed and open reservoirs and that evidence from the

123
Author's personal copy
Environ Earth Sci

existing large-scale storage sites (e.g. Sleipner, In Salah, uniform and independent of permeability. Mathias et al.
Weyburn, etc.) demonstrates that high injection rates can (2009a) consider slight fluid and formation compressibility
be obtained, although the issue of pressure build-up should and do not require an arbitrary radius of influence, but it still
be considered carefully. Numerical analysis for determin- assumes an abrupt interface and constant fluid viscosity.
ing the storage capacity of the Utsira Formation (Bergmo Vilarrasa et al. (2010a) suggest calculating the radius of
et al. 2011; Lindeberg et al. 2009), a large size aquifer with influence using Cooper and Jacobs (1946) solution and
excellent permeability, indicates that pressure build-up propose a method to account for CO2 compressibility effects
control requires a large number of injection and production and viscosity variations and apply it to the analytical solu-
wells. This issue is particularly relevant for onshore stor- tions of Dentz and Tartakovsky (2009). Recently Azizi et al.
age, where production wells may be less acceptable due to (2013) provided a set of type curves, based on numerous
the difficulties for discarding the high salinity water in an numerical simulations, to estimate the injection rate of wells
environmentally sound and cost-effective manner. based on the permeability, surface area, depth and thickness
For closed aquifers, the pressure build-up will be of the reservoir.
accommodated mostly by the rock and fluid (brine and A detailed analysis of the differences and merits of each
CO2), which have low compressibility. For that reason, of these solutions is beyond the scope of this article and the
analytical solutions for estimating the CO2 storage capacity reader is referred to the original papers.
in closed systems usually assume very low storage effi-
ciencies, mostly ranging from 1 to 4 % of the available
pore space (Bradshaw et al. 2007; CO2CRC 2008; Good- Methodology
man et al. 2011; Vangkilde-Pedersen et al. 2009a). How-
ever, at the regional scale pressure gradients and flow of For each potential CO2 injection site, investment costs were
water across the cap-rock cannot be ignored (Cavanagh estimated according to Eq. 1. Costs were differentiated for
et al. 2010; Zhou et al. 2008). For open aquifers, even storing CO2 in onshore fields or offshore fields, and for oil
though the brine can migrate outside of the target structure, and gas fields or aquifers. Given that in the study area depths
effectively increasing the pore space available for the to seabed can reach hundreds to thousands of metres at rel-
injected CO2, pressure build-up is still a constraining fac- atively short distances from the coast, screening was, in
tor, since it remains necessary to ensure that the pressure at general, restricted to the shallow continental shelf (water
the injection well will stay below the cap-rock capillary column\200 m), except in the Alboran sea and the offshore
entry pressure and the values likely to induce fracture of south from Portugal, where sites with water column up to
the reservoir and cap-rock. 600 m were screened. The cost components distinguish
The pressure build-up is dependent on many reservoir- between storage with water column lower than 60 m, from
specific parameters, including permeability, porosity, for- 60 to 100 m and above 100 m.
mation thickness, areal extent, pressure, temperature, rock In some circumstances, for large injection sites, many
and fluid compressibility, and brine salinity. At the site injection wells may be admissible and multiple surface
characterization stage, complex numerical models that facilities will be required. In this study, it was assumed that
require a great deal of input data are implemented to cope a surface facility should be considered for each 10 vertical
with the non-linearity between pressure and injection rate, injection wells. The operating, maintenance, and monitor-
the two-phase behaviour and relative permeability effects. ing (OMM) costs were always based on a fixed percentage
At the early stages of site selection, simpler analytical and (5 %) of the investment costs for development of the
semi-analytical solutions are more amenable to be used for storage site from scratch.
describing pressure build-up and estimate the injection rate, Table 1 lists the value assigned to each CO2 storage cost
and have been presented by several authors (e.g. Dentz and component in Eq. 1, with the exception of the number of
Tartakovsky 2009; Mathias et al. 2009a, b; Mathias and wells, which depends on the injection rate per well and the
Roberts 2013; Nordbotten et al. 2005; Saripalli and McGrail annual injection rate for each site. A spreadsheet tool was
2002; Vilarrasa et al. 2010a, b). Inevitably, all these solutions implemented to calculate the injection rate and number of
consider simplifying assumptions, for instance both Saripalli wells for each site resorting to some of the analytical
and McGrail (2002) and Nordbotten et al. (2005) assume that solutions previously mentioned and taking into account
fluids and formation are incompressible and that pressure is parameters such as depth, permeability, radius of influence
averaged across the aquifer thickness, a common feature also of wells, interference between wells, pressure build-up,
to Dentz and Tartakovsky (2009) or Mathias et al. (2009a). rock and fluids compressibility and CO2 density under
Neglecting compressibility imposes the need to assume an storage conditions (Table 2).
arbitrary radius of influence. Zhou et al. (2008) do consider The analytical solutions implemented were those of
rock compressibility, but pressure build-up is spatially Dentz and Tartakovsky (2009), Mathias et al. (2009a),

123
Author's personal copy
Environ Earth Sci

Table 1 Storage cost components (all values in €2007)


Cost component Onshore aquifer Offshore aquifera Offshore aquifer Offshore aquifer
(WD \60 m) (60 m \ WD \ 100 m) (100 m \ WD \ 1,000 m)

Site development costs (Csd) 24,480 k€ 24,097 k€ 24,097 k€ 24,097 k€


Drilling costs per metre (Cd) 4 k€ 10 k€ 18 k€ 26 k€
Well fixed costs (Cw) –b 8,200 k€ 8,200 k€ 8,200 k€
Surface facilitiesc (Csf) 1,530 k€ 61,200 k€ 61,200 k€ 61,200 k€
Monitoring investments 1,530 k€ 1,530 k€ 1,530 k€ 1,530 k€
OMMd 5% 5% 5% 5%
a
WD—depth to seabed
b
For onshore wells, the fixed costs per well are included in the drilling costs (assumed reservoir depths of around 3,000 m)
c
One surface facility per each 10 injection wells
d
Operating, maintenance and monitoring (OMM) costs are given as a percentage of investment costs

Table 2 Parameters and Parameters Source of data and range of valuesa


sources of data used in the
analytical solutions Reservoir properties
Intrinsic permeability (k) COMET database (2.5–1,300 mD)
Porosity (/) COMET database (0.03–0.43)
Pore volume (Vt) COMET database
Reservoir thickness (H) COMET database (11–1,235 m)
Reservoir pressure (P0) COMET database (4.41–42 MPa)
Reservoir temperature (T0) COMET database (27–97 °C)
Reservoir area (A) COMET database (0.35–3,075 km2)
Rock compressibility (a) Yale et al. (1993) solution (2.83 9 10-10–2.06 9 10-9/Pa)
Brine properties
Brine salinity (XS) COMET database (10–269 g/l)
Brine compressibility (b) TOUGH2-ECO2N subroutines
Brine viscosity (lw)
Brine density (qw)
Specific storage (Ss) gqw ða þ /bÞ
CO2 properties
CO2 viscosity (lc) TOUGH2-ECO2N subroutines
CO2 density (qc)
Other parameters
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
Radius of influence (R0) 2:25tkqw g=Ss lw
Well radius (rw) 0.15 m
Time (t) 30 years
Limit to pressure increase (DP) 0.2P0
a
Where no range of values is Well efficiency 80 %
indicated, calculations are made Limit to interference between wells \0.25DP
internally in the spreadsheet

Nordbotten et al. (2005), Vilarrasa et al. (2010b). These solutions have been published since the completion of the
solutions were selected because, while being mathemati- COMET project (Azizi and Cinar 2013; Azizi et al. 2013;
cally robust, they can be easily implemented in spread- Mathias et al. 2011a, b, 2013; Mathias and Roberts 2013),
sheets, an important requirement when modelling 163 and although no systematic comparison was made for the
potential injection sites, and are compatible with the level 163 sites, tests were conducted using some of those new
of information gathered for the sites. Other analytical solutions and no major differences were found in the

123
Author's personal copy
Environ Earth Sci

results that could invalidate the conclusions of the COMET Economides (2010) translates into an average pressure
project. increase given by Vc =ðVt ct Þ where Vc is injected volume of
The constraint imposed to define the injection rate at CO2 over time, Vt is the pore volume and ct is the total
each storage site was a maximum pressure build-up of compressibility of the system (rock, water and CO2). To
20 % of the initial reservoir pressure. This is possibly much simulate the effect of pressure build-up on a closed struc-
below the reservoir and cap-rock fracture pressure, but was ture that average pressure increase was added to the pres-
deemed adequate in light of uncertainty on the existing sure build-up simulated by the aforementioned analytical
data. All CO2 and brine properties, such as density, vis- solutions.
cosity and compressibility, were computed taking into The radius of influence of each well was used to esti-
account the pressure and temperature dependence and mate the number of wells admissible in each structure,
resorting to the subroutines in TOUGH2 (Pruess et al. considering assumptions of pressure interference varying
1999) and ECO2N (Pruess 2005; Pruess and Spycher 2007) from 0 to 25 % of the injection well pressure, and the area
which were available to the spreadsheet via a Fortran DLL. of the structure. The radius of influence of each well was
All four selected analytical solutions were applied to the estimated using the Cooper and Jacobs (1946) solution for
163 injection sites, and the injection rate and well numbers evaluating transient groundwater pumping tests and well
adopted for each site were averaged over the results of the field history, except for Mathias et al. (2009a) which does
four solutions (which in fact retrieved very similar results, not require the calculation of a radius of influence. The
with the main deviations being found in the Nordbotten number of injection wells was calculated as the integer
et al. (2005) solution, usually resulting in higher injection ratio between the area of the reservoir and the radius of
rates, although normally less than 10 % above the average influence (or the radial distance corresponding to the
of the other solutions). admissible pressure interference).
A common assumption of the four solutions is that the The injection phase was set to 30 years and well effi-
reservoir is unbounded, i.e., it is infinite in length. How- ciency was set to a constant 80 %. Rock compressibility
ever, out of the 163 injection sites, 96 were considered as was found to be a key parameter for which no estimates
closed or semi-closed structures, due to the faulted nature existed for any of the potential storage sites and to be very
of the reservoirs and complex tectonic history of some of scarce in the literature for the depths required for CO2
the sedimentary basins occurring in the study region. storage. Rock compressibilities were computed following
Closed structures imply larger pressure build-ups and lower Yale et al. (1993) solution, taking into account the rock
injection rates. types and reservoir depth and pressure, and given by:
The level of detail and data gathered for the structures (
identified in Spain was sufficient to identify the structures Cf ¼ Aðr  BÞC þD
as open, semi-closed or closed. However, for Portugal and ð2Þ
r ¼ K1 rv  K2 pi þ K3 ðpi  pÞ
Morocco, there was considerable doubt about the hydraulic
behaviour of the sites due to the scarcity of hydraulic tests. where Cf is formation compressibility, pi is initial reservoir
Because all sites in Portugal were geometrically defined pressure, p is pressure (in psi) following production and rv
using as boundaries large faults that cross the reservoirs is overburden stress. Constants A, B, C and K1 to K3 are
(and thus some sites are contiguous), it was assumed that given in Table 3.
those sites would be modelled as closed structures. The Since most of the storage sites are onshore, brine pro-
same approach was applied for the structures in clusters duction wells were not considered an option to control
S08 (Essaouira basin) and S28 (Doukkala basin) in pressure build-up. A final assumption was made that no
Morocco. single well could have an injection rate above 1 MtCO2/a.
This approach of assuming closed-reservoirs when fully
delimited by faults is conservative (fully closed structures
will result in lower injection rates and higher storage costs) Results
since it is likely that pressure dissipation can occur along
some of the faults. This cautionary approach was consid- The total injection rate for the 163 potential storage sites
ered adequate due to the uncertainty associated to the data is estimated at 558 MtCO2/a, with an average injection
gathered for Portugal and Morocco. The approach is less rate of 3.4 MtCO2/a/site. However, 11 % of the sites
conservative for Spain, where confidence about the open/ cannot sustain injection rates above 0.1 MtCO2/a, and
closed hydraulic behaviour of the structures is higher. 33 % of sites do not allow injection rates above 0.5
The consequence of assuming the reservoir has a closed MtCO2/a (Fig. 2a).
volume is that the average reservoir pressure will increase The number of wells per storage site is on average of
over time, which according to Ehlig-Economides and four wells, with a distribution skewed to the lower number

123
Author's personal copy
Environ Earth Sci

Table 3 Constants for compressibility calculation (from Yale et al. 1993)


Rock type Constants for stress conditions Constants for compressibility calculation
K1 K2 A B C D

Consolidated sandstones 0.85 0.8 -2.40E-05 300 0.0623 4.31E-05


Low-porosity consolidated sandstones 0.85 0.6 -2.40E-05 300 0.0623 4.31E-05
Friable sandstones 0.9 0.9 1.05E-04 500 -0.225 -1.10E-05
Unconsolidated sands 0.95 0.95 -2.81E-05 300 0.1395 1.18E-04
Carbonates 0.85 0.85 -2.40E-05 300 0.0623 4.31E-05

(a) 30 (a) 20%


Offshore (46 sites)
25
Onshore (117 sites)
15%
20
Frequency

Frequency
15
10%
10

5 5%

0
0.1 0.4 0.7 1 4 7 10 13 16 19 22 25 28
0%
Total injecon rate per site (MtCO2/a)

420
20

60

100

140

180

220

260

300

340

380

460

500
(b) 100 Investment costs (€/tCO2/a)

80 (b) 30%

60 25%
Frequency

Offshore (46 sites)


20%
Frequency

40 Onshore (117 sites)


15%
20
10%
0
1 3 6 10 14 18 22 26 30 34 38 42 46
5%
Number of wells per site
0%
Fig. 2 Injection rate (a) and number of wells per potential injection
site (b)
Total storage costs (€/(tCO2)

of wells (Fig. 2b). In about half of the injection sites, a Fig. 3 a Investments costs per annual injection rate; b total storage
single well is admissible, reflecting the large radius of costs per ton of CO2, including investment and OMM costs, for a
30-year injection scenario at the maximum admissible injection rate
influence for each well for the 30-year injection period. and assuming a 7 % discount rate. All costs in € 2007
Most of the selected sites are relatively small in area (the
mean radius of an equivalent circle is approximately
4 km), particularly in the case of Spain, where site selec- pressure build-up, which resulted in an increased number
tion was made at the structure scale (e.g. anticlines, fault of wells in those sites. However, the increase in total
traps, etc.), and pressure build-up affects the entire injection rate is less significant due to the reduction in the
structure. injection rate in each well to account for pressure
The low number of injection wells for most storage sites interference.
also reflects the option to maximize the injection rate in Investment costs per annual injection rate vary as
each well. It is possible to obtain higher total injection rates shown in Fig. 3a for each site and aggregated in Table 4
by allowing for pressure interference between wells, each for each cluster. The minimum onshore investment cost
with lower injection rates. This was studied for the storage is 9.3 €/tCO2/a, with 46 % of sites costing less than 60
sites with an area larger than 100 km2, allowing for pres- €/tCO2/a, but exceeding 500 €/tCO2/a in 10 % of the
sure interferences up to 25 % of the maximum induced potential sites, which are economically unfeasible. These

123
Author's personal copy
Environ Earth Sci

Table 4 Total injection rate and investment costs (in €2007) per storage cluster
Cluster Cluster name Country Storage Injection rate Investment Total storage costsb
capacity MtCO2 MtCO2/a costs €/tCO2/a (investment and
OMM) €/tCO2

S01 Porto Basin 1 Portugal 1,205 17.1 100.4 13.1


S02 Porto Basin 2 Portugal 800 3.8 180.4 23.6
S03 North Lusitanian 1 Portugal 2,211 11.8 92.4 12.1
S04 North Lusitanian 2 Portugal 1,591 11.4 173.0 22.6
S05 Lusitanian Onshore Portugal 330 10.7 36.2 4.7
S06 South Lusitanian Portugal 85 1.7 349.0 45.6
S07 Algarve 2 Spain/Portugal 557 36.7 242.1 31.6
S08 Essaouira Morocco 266 7.2 73.3 9.6
S09 Almazán Spain 127 11.8 112.4 14.7
S10 San Vicente de la B. Spain 47 1.0 254.2 33.2
S11 Graus Spain 41 22.0 115.2 15.0
S12 Jaca Spain 359 1.3 235.7 30.8
S13 Alcañiz Spain 2,040 75.8 49.1 6.4
S14 Zaragoza Spain 156 2.3 92.1 12.0
S15 Logroño Spain 4,161 35.7 22.7 3.0
S16 Reinosa Spain 54 1.7 47.6 6.2
S17 Burgos Spain 1,298 9.6 70.5 9.2
S18 León Spain 471 2.8 46.1 6.0
S19 Aranda de Duero Spain 568 24.9 47.0 6.1
S20 Madrid Spain 2,215 2.9 54.2 7.1
S21 Tarancón Spain 1,210 11.2 58.5 7.6
S22 Cuenca Spain 1,035 65.9 27.4 3.6
S23 Almansa Spain 959 23.7 18.3 2.4
S24 Albacete Spain 134 0.6 318.1 41.5
S25 Úbeda Spain 1,082 41.0 11.0 1.4
S26 Baena Spain 38 3.9 86.5 11.3
S27 Valladolid Spain 4,312 4.4 70.3 9.2
S28 Safi Morocco 147 0.4 416.8 54.4
S29 Huelva Spain 217 0.1 275.9 36.0
S30 Estepona Spain 12 0.6 77.8 10.2
S31 Moratalla Spain 413 24.3 10.4 1.4
S32 Bermeo Spain 30 0.5a 252.7 33.0
S33 Gijón Spain 64 0.5a 301.8 39.4
S34 Ribadeo Spain 23 0.5a 230.5 30.1
S35 Vigo Spain 131 0.5a 240.9 31.5
S36 Alborán Morocco 218 2.0 263.1 34.4
S37 San Pedro del Pinatar Spain 63 0.5a 228.2 29.8
S38 Calpe Spain 5 0.5a 890.9 116.3
S39 Valencia Spain 6 0.5a 548.7 71.7
S40 Castellón de la Plana Spain 36 0.5a 246.6 32.2
S41 Barcelona Spain 93 0.5a 237.0 31.0
S42 Algarve 1 Portugal 845 13.0 98.6 12.9
S43 Gharb Morocco 4 0.4 243.6 31.8
a
Assumed, since there was not enough information to estimate the injection rate
b
For a 30-year injection period and considering annual OMM costs equal to 5 % of investment costs and a 7 % discount rate

123
Author's personal copy
Environ Earth Sci

Fig. 4 CO2 storage over time in the study area until 2050 for the conservative CCS ccenario (40 % emissions reduction target until 2050,
optimistic economic growth and no cross-frontier transport allowed)

123
Author's personal copy
Environ Earth Sci

Table 5 Storage clusters and mass of CO2 stored in the COMET Conservative CCS scenario (after Boavida et al. 2013b)
Cluster Country Injection limits Simulated injection Percentage share
cumulative/total
Annual Cumulative Max. annual Cumulative
(MtCO2/a) (MtCO2) (MtCO2/a) (MtCO2)

S13 Spain 75.8 2,040 46.1 930 27.6


S25 Spain 25.5 1,082 25.5a 780 50.7
S19 Spain 10.3 568 10.3a 339 60.7
S15 Spain 35.7 4,161 13.4 284 69.1
S31 Spain 7.3 413 7.3a 274 77.2
a
S05 Portugal 10.7 330 10.7 247 84.6
S22 Spain 16.5 1,035 13.7 224 91.2
S08 Morocco 2.9 266 2.9a 94 94.0
S23 Spain 15.5 959 4.7 90 96.7
S03 Portugal 11.8 2,211 4.6 59 98.5
S16 Spain 1.7 54 1.7a 31 99.4
S42 Portugal 13.0 845 0.73 9.5 99.7
S36 Spain 0.5 218 0.50a 6.5 99.9
S43 Morocco 0.4 3.8 0.30 3.8b 99.98
S01 Portugal 17.1 1,205 0.05 0.7 100.0
Total cumulative stored = 3,375 MtCO2 in 40 years
a
The maximum annual injection rate is hit
b
The cumulative capacity has been reached

high costs reflect the considerable depth of some of sites, methodology for defining the transport and storage infra-
and are also a function of the conservative values structure can be found elsewhere (Kanudia et al. 2013; van
adopted for the hydraulic and petrophysic parameters of den Broek et al. 2013; Boavida et al. 2013b), but Fig. 4 and
some sites. Table 5 illustrate the storage locations and amount to be
Offshore investment costs show a minimum of 61.1 €/ stored at each cluster for the COMET central scenario,
tCO2/a, not surprisingly much higher than the onshore which considers a 40 % reduction of CO2 emissions in
costs, and with 50 % of the offshore sites costing up to 240 2050 with respect to 2005, an optimistic economic growth
€/tCO2/a. Again, more than 10 % of the offshore sites have and impose that transport routes should follow existing
investment costs above 500 €/tCO2/a. Given the existing natural gas pipeline connections and that no cross-bound-
onshore storage capacity, it is likely that offshore storage ary transport is possible.
will be only marginally required. In this scenario only 14 clusters out of the total 43
Taking into account all investment costs and OMM clusters are selected for storage, with the injection rate and
components, assuming a 30-year continuous injection costs being the dominant factors on the selection of those
period at the maximum rate per well and applying a 7 % clusters, together with the constraints imposed to transport
discount rate, the onshore storage costs would range from routes. The cumulative amount stored in 40 years is 14 %
1.2 €/tCO2 for the most favourable onshore clusters to of the permanent storage capacity in the study area and the
values above 100 €/tCO2 for 3 % of the onshore sites, but maximum annual flow rate would not exceed 50 % of the
with more than 50 % costing less than 10 €/tCO2 (Fig. 3a annual injection capacity. Seven sink clusters use the
for each storage site and aggregated per cluster in Table 4). maximum sustainable injection rate (Table 5).
Offshore storage costs are much higher, with a minimum of The most relevant clusters are located in Spain, namely
8 €/tCO2 and only 7 % of the sites costing less than 10 €/ the clusters of Logroño (S15), Úbeda (S25), Alcañiz (S13),
tCO2. 40 % of the storage sites cost up to 30 €/tCO2. Cuenca (S22), Almansa (S23), Moratalla (S31), and
The optimization conducted to minimize transport and Aranda de Duero (S19), in decreasing order of importance
storage costs, using the TIMES-COMET model, and the (Fig. 4). The sink cluster in Úbeda (S25) is very compet-
resulting CO2 transport network were highly influenced by itive, but is limited by both annual and cumulative
these injection rates and storage costs, since the source– capacity.
sink match focused not only on the available storage In Portugal the Lusitanian Onshore cluster (S05) is the
capacity, but also on the injection rates. Details about the most relevant site, with the costs being considerably lower

123
Author's personal copy
Environ Earth Sci

than the alternative offshore clusters. Storage at S05 is Uncertainty in the parameters characterizing the reser-
limited by the annual capacity, and for large cumulative voirs is high, and in some cases hydraulic and petrophys-
volumes Portugal could store CO2 in Spain (if cross- ical parameters were inferred from shallow depth
boundary transport is possible) or in the offshore cluster information. The analysis conducted indicates the rele-
S03. vance of those parameters for planning a CCS infrastruc-
In Morocco, the main storage site is the cluster centred ture in the study area. Future research in Portugal, Morocco
in the Essaouira Basin (S08), which has vast capacity, and Spain should focus on decreasing uncertainty about
while the Gharb basin cluster (S43) is limited by the very permeability of the reservoirs, compressibility of rocks of
small capacity, and ultimately CO2 captured at facilities in the storage complexes and on criteria for establishing the
the north of Morocco can be stored cost-effectively in the injection rate per well and the sustainable injection
south of Spain. However, the result for Morocco could be pressure.
considerable different once offshore storage capacity is Research and exploration efforts should be primarily
assessed. directed to those clusters indicated by the COMET sce-
These results are regarded as conservative (and integrate narios as most cost-effective and listed in Table 5, and to
the CONSERVATIVE CCS scenario, one of the six sce- those sites with very high storage capacity but for which
narios modelled in COMET) partly because of the cautious low injection rates were estimated. Increasing the reli-
approach to the injection capacity. The injection rates and ability of the geological data would result in less uncer-
number of wells estimated for the storage clusters in Por- tainty in the estimated injection rate and number of wells,
tugal and clusters S08 and S28 in Morocco are regarded as and in more reliable storage cost estimates.
very conservative due to the assumption that they behave
as closed-structures. For instance, simulating the potential Acknowledgments This research has been carried out in the context
of the EU funded COMET project, contract no. 241400. We are
storage sites in Portugal as open-structures would result in grateful to all project partners that have supported the work for
an increase in total injection rate from 106 MtCO2/a to 177 identification of storage sites. Authors would like to thank all the
MtCO2/a. This would translate in lower storage costs and, institutions that have supplied data for the consecution of these and
possibly, selection of different or additional storage clus- future results. Special acknowledgments go to all contributors to the
work done in COMET WP3: Yves-Michel LeNindre, Ruxandra Nita,
ters in the COMET energy system modelling. Other sce- Alexander Brugeron, Mohammed Dakki, Abdallah Ait Salem,
narios considered in COMET included an OPTIMISTIC António Correia, Fátima Cardoso, Carlos Ribeiro, Augusto Costa,
scenario with higher injection rates, and its results are Carlos Rosa, Diogo Rosa, Elsa Ramalho, Helena Amaral, João
published in the project final report (Boavida et al. 2013b). Carvalho, José Sampaio, Pedro Terrinha, Susana Machado, Tiago
Cunha, Maria Olho Azul and Pablo Gentil. DPEP (the Portuguese
Division for Oil Exploration and Production) is gratefully acknowl-
edged for providing access to technical reports and databases.
Conclusion

Identification of nearly 30 GtCO2 storage capacity in References


Morocco, Portugal and Spain demonstrates that, together,
Azizi E, Cinar Y (2013) A new mathematical model for predicting
these countries have enough capacity to store almost CO2 injectivity. Energy Procedia 37:3250–3258. doi:10.1016/j.
200 years of their present CO2 emissions. Thus, the main egypro.2013.06.212
constraints for definition of the CCS infrastructure are the Azizi E, Cinar Y, Allinson G, Michael K (2013) A new tool to predict
annual injection rate and the storage costs. Resorting to injection well number for a total injection rate and given
formation properties. Energy Procedia 37:3259–3266. doi:10.
several analytical solutions, the total injection capacity in 1016/j.egypro.2013.06.213
the 163 potential injection sites was estimated at about 558 Bergmo PES, Grimstad A-A, Lindeberg E (2011) Simultaneous CO2
MtCO2/a, which is far above the annual injection rate injection and water production to optimise aquifer storage
needs. However, about 11 % of the injection sites do not capacity. Int J Greenh Gas Con 5:555–564. doi:10.1016/j.ijggc.
2010.09.002
allow for injection rates above 0.1 Mt/a, requiring a large Boavida D, Carneiro JF, Ramı́rez A, Martinez R, Czernichowski-
number of wells, and being uneconomic. Nevertheless, Lauriol I, Tosato G, Rimi A, Zarhloule Y, Simões S, Cabal H
around 50 % of the injection sites show storage costs below (2011) Integrated infrastructure for CO2 transport and storage in
10 €/tCO2 and are likely to be the primary targets for CO2 the west Mediterranean. GHGT-11, Amsterdam, pp 2440–2447
Boavida D, Carneiro J, Martinez R, van den Broek M, Ramirez A,
storage. In fact, the simulations indicated that from the 43 Rimi A, Tosato G, Gastine M (2013a) Planning CCS develop-
storage clusters defined in the study region, only the most ment in the west Mediterranean. Energy Procedia 37:3212–3220.
cost-effective 11–15 clusters, depending on the scenario, doi:10.1016/j.egypro.2013.06.208
are likely to be required for CO2 storage and should be the Boavida D, Carneiro J, Tosato G, Martinez G, Van den Broek M,
Gastine M (2013b) Final report-COMET. Integrated
focus of future research.

123
Author's personal copy
Environ Earth Sci

infrastructure for CO2 transport and storage in the west pressure buildup. Int J Greenh Gas Con 3:577–585. doi:10.1016/
Mediterranean. Lisbon, p 58 j.ijggc.2009.05.002
Bradshaw J, Bachu S, Bonijoly D, Burruss R, Holloway S, Mathias SA, Gluyas JG, Miguel de Martı́nez González GJ, Hosseini
Christensen NP, Mathiassen OM (2007) CO2 storage capacity SA (2011a) Role of partial miscibility on pressure buildup due to
estimation: issues and development of standards. Int J Greenh constant rate injection of CO2 into closed and open brine
Gas Con 1:62–68 aquifers. Water Resour Res 47:W12525. doi:10.1029/
Carneiro J, Zarhloule Y, Boughriba MAC, Rimi A (2008) Carbon 2011WR011051
storage in fissured rock aquifers: potential sites in northern Mathias SA, Miguel de Martı́nez González GJ, Thatcher KE,
Morocco. In: CO2NET 2008 seminar, Warsaw Zimmerman RW (2011b) Pressure buildup during CO2 injection
Carneiro JF, Boavida D, Silva R (2011) First assessment of sources into a closed brine aquifer. Transport Porous Media 89:383–397.
and sinks for carbon capture and geological storage in Portugal. doi:10.1007/s11242-011-9776-z
Int J Greenh Gas Con 5:538–548. doi:10.1016/j.ijggc.2010.08. Mathias SA, Gluyas JG, Miguel de Martı́nez González GJ, Bryant SL,
002 Wilson D (2013) On relative permeability data uncertainty and
Cavanagh AJ, Haszeldine RS, Blunt MJ (2010) Open or closed? A CO2 injectivity estimation for brine aquifers. Int J Greenh Gas
discussion of the mistaken assumptions in the economides Con 12:200–212. doi:10.1016/j.ijggc.2012.09.017
pressure analysis of carbon sequestration. J Petrol Sci Eng Nordbotten JM, Celia MA, Bachu S (2005) Injection and storage of
74:107–110. doi:10.1016/j.petrol.2010.08.017 CO2 in deep saline aquifers: analytical solution for CO2 plume
CO2CRC (2008) Storage capacity estimation, site selection and evolution during injection. Transp Porous Media 58:339–360
characterisation for CO2 storage projects. Cooperative Research Pruess K (2005) ECO2N: a TOUGH2 fluid property module for
Centre for Greenhouse Gas Technologies, Canberra, p 52 mixtures of water, NaCl, and CO2. Lawrence Berkeley National
Cooper HH, Jacobs CE (1946) A generalized graphical method of Laboratory, Berkeley, p 76
evaluating formation constants and summarizing well-field Pruess K, Spycher N (2007) ECO2N—a fluid property module for the
history. US Department of the Interior, Geological Survey, TOUGH2 code for studies of CO2 storage in saline aquifers.
Water Resources Division, Ground Water Branch Energy Convers Manag 48:1761–1767
Dentz M, Tartakovsky DM (2009) Abrupt-interface solution for Pruess K, Oldenburg C, Moridis G (1999) TOUGH2 user’s guide,
carbon dioxide injection into porous media. Transp Porous version 2.0. Lawrence Berkeley National Laboratory, Berkeley,
Media 79:15–27. doi:10.1007/s11242-008-9268-y p 210
Ehlig-Economides C, Economides MJ (2010) Sequestering carbon Saripalli P, McGrail P (2002) Semi-analytical approaches to modeling
dioxide in a closed underground volume. J Petrol Sci Eng deep well injection of CO2 for geological sequestration. Energy
70:123–130. doi:10.1016/j.petrol.2009.11.002 Convers Manag 43:185–198
Goodman A, Hakala A, Bromhal G, Deel D, Rodosta T, Frailey S, van den Broek M, Ramirez A, Groenenberg H, Neele F, Viebahn P,
Small M, Allen D, Romanov V, Fazio J, Huerta N, McIntyre D, Turkenburg W, Faaij A (2010) Feasibility of storing CO2 in the
Kutchko B, Guthrie G (2011) US DOE methodology for the Utsira formation as part of a long term Dutch CCS strategy an
development of geologic storage potential for carbon dioxide at evaluation based on a GIS/MARKAL toolbox. Int J Greenh Gas
the national and regional scale. Int J Greenh Gas Con 5:952–965. Con 4:351–366. doi:10.1016/j.ijggc.2009.09.002
doi:10.1016/j.ijggc.2011.03.010 van den Broek M, Mesquita P, Carneiro J, Silva JR, Berghout N,
IEA (2012) Energy technology perspectives 2012: pathways to a Ramı́rez A, Gouveia JP, Seixas J, Cabal H, Martinez R, Rimi A,
clean energy system, International Energy Agency, Paris Zarhloule Y, Sardinha M, Boavida D, Tosato G (2013) Region
Kanudia A, Berghout N, Boavida D, van den Broek M, Cabal H, specific challenges of a CO2 pipeline infrastructure in the west
Carneiro J, Fortes P, Gargiulo M, Gouveia JP, Labriet M, Mediterranean area model results versus stakeholder views.
Lechón Y, Martinez R, Mesquita P, Rimi A, Seixas J, Tosato Energy Procedia 37:3137–3146. doi:10.1016/j.egypro.2013.06.
G (2013) CCS infrastructure development scenarios for the 200
integrated Iberian Peninsula and Morocco energy system. Vangkilde-Pedersen T, Anthonsen KL, Smith N, Kirk K, Neele F, van
Energy Procedia 37:2645–2656. doi:10.1016/j.egypro.2013.06. der Meer B, Le Gallo Y, Bossie-Codreanu D, Wojcicki A, Le
149 Nindre YM, Hendriks C, Dalhoff F, Christensen NP (2009a)
Lindeberg E, Vuillaume J-F, Ghaderi A (2009) Determination of the Assessing European capacity for geological storage of carbon
CO2 storage capacity of the Utsira formation. Energy Procedia dioxide—the EU GeoCapacity project. Energy Procedia
1:2777–2784 1(1):2663–2670
Machado S, Sampaio J, Carvalho J, Dias RP, Costa A, Oliveira JT Vangkilde-Pedersen T, Hladik V, Anthonsen KL (2009b) EU
(2007) Armazenamento de CO2 em aquı́feros salinos.-Hipóteses GeoCapacity—assessing European capacity for geological stor-
para Portugal. Ciclo de conferências Energia e Sociedade- age of carbon dioxide. In: CO2NET seminar 2009, Trondheim
Carvão: um combustı́vel fóssil na via da sustentabilidade? Vilarrasa V, Bolster D, Dentz M, Olivella S, Carrera J (2010a) Effects of
ISCTE, Lisbon, Novembro 2007 CO2 compressibility on CO2 storage in deep saline aquifers. Transp
Martinez R, Suárez I, Carneiro J, Zarhloule Y, Nindre YML, Boavida Porous Media 85:619–639. doi:10.1007/s11242-010-9582-z
D (2013) Storage capacity evaluation for development of CO2 Vilarrasa V, Bolster D, Olivella S, Carrera J (2010b) Coupled
infrastructure in the west Mediterranean. Energy Procedia hydromechanical modeling of CO2 sequestration in deep saline
37:5209–5219. doi:10.1016/j.egypro.2013.06.437 aquifers. Int J Greenh Gas Con 4:910–919. doi:10.1016/j.ijggc.
Mathias SA, Roberts AW (2013) A Lambert W function solution for 2010.06.006
estimating sustainable injection rates for storage of CO2 in brine Yale DP, Nabor GW, Russell JA, Pham HD, Yousef M (1993)
aquifers. Int J Greenh Gas Con 17:546–548. doi:10.1016/j.ijggc. Application of variable formation compressibility for improved
2013.04.007 reservoir analysis. In: 68th Annual technical conference and
Mathias S, Hardisty P, Trudell M, Zimmerman R (2009a) Approx- exhibition of the society of petroleum engineers. Society of
imate solutions for pressure buildup during CO2 injection in Petroleum Engineers, Houston. pp 435–450
brine aquifers. Transp Porous Media 79:265–284 Zhou QL, Birkholzer JT, Tsang CF, Rutqvist J (2008) A method for
Mathias SA, Hardisty PE, Trudell MR, Zimmerman RW (2009b) quick assessment of CO2 storage capacity in closed and semi-
Screening and selection of sites for CO2 sequestration based on closed saline formations. Int J Greenh Gas Con 2:626–639

123

View publication stats

You might also like