Professional Documents
Culture Documents
Introduction
Acid Additives
Carbonate Acidizing
Sandstone Acidizing
Laboratory Testing
Reference
Introduction
To remove damage, fluids are injected into the natural porosity of the
reservoir at '' matrix''/subfracturing/ rates and pressures. This relatively
low rates and pressures are necessary to remove the damage located
just around the well bore. The flow rate is also limited to prevent
fracturing of the formation, which would result in uncontrollable
.stimulation of only part of the reservoir
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Need for acidizing
3
Acidizing Method
Acid Washing
This operation is designed to remove the acid soluble scales present in the well
bore or to open perforations. In this method, small quantity of acid is spotted at
position in the bore, allowed it to react and circulated back to surface. Pumping
is stopped to allow acid to soak the perf.’s under hydrostatic pressure.Then the
.well is immediately produced
Matrix Acidizing
In this method, the acid is injected into the formation at a pressure (lower than
the fracture pressure) of the formation. The goal is to achieve radial acid
penetration into the formation. It often increases production without increasing
.the GOR or water cut
Acid- fracturing
In this method, the acid is injected into the formation at a pressure high enough
(above the fracture pressure) to fracture the formation or open existing fracture.
Stimulation is achieved when a highly conductive flow channel remains open
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after the treatment. This channel is formed by acid reaction on the acid-soluble
.wall of the fracture
Organic acids
Other acids used alone or in conjunction with HCL are acetic acid and formic
acid. These are organic acids and are considered to be much weaker acids than
.hydrochloric acid
They may be used alone as retarded acids. Acetic acid is slower to react than
.formic acid. They are also used where low corrosivity is important
5
Specialty Acids
Some special acids such as sulfamic, citric, lactic and others are used on
.occasions for particular applications
Acid Additives
Surfactants
Surfactants are chemicals composed on an oil
soluble group /lipophilic group /and a water
soluble group /hydrophilic group. These chemicals
lower the surface tension of a liquid by adsorbing
at the interface between the liquid and gas.
Surfactants are also capable of lowering the
interfacial tension by adsorbing at interfaces between two immiscible liquids
and of changing contact angles by adsorbing at interfaces between a liquid and
.solids
Classes of Surfactants
Surfactants can be classified into four major groups, depending upon the
:nature of the water soluble group. These divisions of surfactants are
Anionic
Cationic
Nonionic
Amphoteric
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modified to prevent corrosion of pipe, formation of emulsions, plugging of
.formation with insoluble fines, and precipitation of sludge
Suspending Agents
As hydrochloric acid reacts on limestone or dolomite formation, the
carbonates are dissolved by the acid. However, because most formations are
.not 100% carbonate, many acid insoluble fines may be released
When the spent acid is removed from the formation upon completion of a job,
these insoluble fines may be left in the formation and can reduce the formation
permeability. It is, therefore, desirable to remove these fines with the spent
.acid
Anti-sluding Agents
When acid is pumped into a well and contacts
crude oil, sludge may be formed at the acid-oil
interface, usually those containing a high
.percentage of asphaltenes
Once it forms it cannot be easily redissolved
into oil again. Hence, this material can
accumulate in the formation and result in a
.decrease in permeability
Penetrating Agents
These surfactants are most commonly used in acidizing tight gas well
formations and in scale removal treatment. Their main function is to lower the
.surface tension of the acid
Corrosion inhibitors
When inhibited acid is pumped into a well, the acid
will react with the tubing and cause severe corrosion
.and possibly complete disintegration of the tubing
To prevent this, corrosion inhibitors have been
developed that will effectively retard the rate of the
rate of reaction of acid on steel. Some factors that
:influence the rate of reaction of acid on steel are
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1. Temperature
2. Time of contact
3. Type of acid
4. Pressure
5. Type of steel
6. Concentration of acid
7. Ratio of volume of acid to exposed steel surface
Corrosion inhibitors do not stop corrosion, but they will decrease the rate
.of the reaction of acid of steel
Non-Emulsifiers
Because crude oils contain natural surfactants, one of the major problems
encountered in acid treatment is emulsions of crude oil and acid or
.emulsions of crude oil and spent acid
By adding specific surfactant to the acid before pumping, emulsion can be
.prevented from forming during acid treatment
Non-Emulsifier
Because crude oils contain natural surfactants, one of the major problems
encountered in acid treatment is emulsions of crude oil and acid or emulsions of
.crude oil and spent acid
Emulsion can be classified into groups depending on nature of the external
:phase
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Iron retention acid may contain an iron sequestering additive and PH control
agent that together help prevent the precipitation of iron and other metallic
.salts or bases as the hydrochloric acid spend
Alcohol
They have been used to aid in cleaning up water
blocked gas wells. Straight alcohol has been found to
provide quick return of permeability to the undamaged
.state
Mutual Solvent
Scale Inhibitors
The acid containing the inhibitor will deposit some of the inhibitor and feed the
.rest
Clay Stabilizers
This process depends on the deposition of a hydroxy
aluminum film over the clay minerals to minimize their
swelling and / or stabilize them so that they can not
.move
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Aromatic Solvent
The aromatic solvent-surfactant dispersions can be
utilized in acid to remove paraffin and asphaltenes at
the same time the acidizing treatment is being
.conducted
Foaming Agents
Foaming agents, liquid or solid, are used to remove water and oil from
.producing gas wells
Wettability Agents
Certain surfactants are used to alter the wetting properties of a producing
.formation
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Carbonate Acidizing
Carbonate rocks, by definition, contain more than 50% carbonate minerals.
The most common carbonate minerals are calcite (calcium carbonate, CaCO3)
and dolomite.
Acid is used in carbonate formations to dissolve the matrix and bypass the
damage. For this reason, both damage and rock characteristics must be taken
into account when designing the treatment.
L
i
m
e
s
t
ne o
Dolomite
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Sandstone Acidizing
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Laboratory Testing
The amount of acid required to dissolve a given Amount of mineral is
determined by the stoichiometry of the chemical reaction, which describes the
:number of moles of each species involved in the reaction. For example
Mineral Acids
Organic Acids
HCH3CO2 + CaCO3 Ca (CH3CO2)2 + H2O + CO2 2
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Consideration of Reaction Rate
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Acid treatment Design
Design Problem
The following data was obtained from a naturally flowing oil well completed in
a homogeneous dolomite formation having a reservoir pressure above the
bubble point pressure and it is underlined by strong water drive aquifer. In order
to increase the productivity of the well, the completion engineer was asked to
-:Prepare an acid design program. Given the following data
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Separator temperature ( F ) 90
Wellhead temperature ( F ) 100
Acid specific gravity 1.08
Acid concentration 15%
Acid spending time (minutes) 60
Desired injection rate( ft3/ft.min ) 0.2
Xacid 0.082
Sor 25%
Specific gravity of dolomite 2.83
Given also the following laboratory acid performance data (15 %) HCl
injected:
16
Calculate:-
1. Construct the inflow performance curve and the tubing intake curve for
the well.
2. The maximum possible oil flow rate from the well and the
corresponding bottom hole flowing pressure and the required wellhead
pressure before acidizing
3. Construct the acid performance curve for field conditions
4. The maximum acid injection volume to produce the maximum
stimulation permeability.
5. The optimum oil flow rate and the corresponding bottom hole flowing
pressure and the wellhead pressure corresponding to the maximum
stimulation permeability.
6. The productivity ratio for the stimulated well at the maximum acid
injection volume.
7. The radius and the permeability of the stimulated zone after acidzing.
8. The weight of dolomite dissolved and the resulting porosity of the
stimulated zone.
9. The wellhead surface acid injection pressure.
Solution:
TPC calculation using vertical multiphase flow correlations and THP
calculation using horizontal multiphase flow correlations:
Qo assumed
THP (psi) Pwf (psi)
(bbl/D)
1000 170 960
2000 265 1140
3000 370 1480
4000 500 1870
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Qo (bbL/D) 2830
Pwf (psi) 1400
Pe (psi) 1820
2000
1800
1600
1400
1200
P
(p
si)
1000
800
600
400
200
0
0 2000 4000 6000 8000 10000
Qo (bbl/D)
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Ti Ts-Ti cum.(Ts-Ti) cum. wt
Qi (cc/min) Vs (cc) PVI ks/ke Wd (gm) Xmin
(min) (min) (min) PVI (gm)
0 0 0 0 0 0 0 1 15 0 0
0.15 7.6 51 9 9 0.95 0.95 1.2 14.877 0.123 0.008
0.16 8 51 9 18 1 1.95 1.4 14.769 0.231 0.015
0.16 8 51 9 27 1 2.95 1.6 14.661 0.339 0.023
0.16 8 51 9 36 1 3.95 1.8 14.553 0.447 0.030
0.15 7.68 51 9 45 0.96 4.91 2 14.445 0.555 0.037
0.16 8 51 9 54 1 5.91 2.2 14.337 0.663 0.044
0.16 8 51 9 63 1 6.91 2.4 14.229 0.771 0.051
0.16 8 51 9 72 1 7.91 2.3 14.121 0.879 0.059
0.16 7.92 51 9 81 0.99 8.9 1.8 14.013 0.987 0.066
0.15 7.84 51 9 90 0.98 9.88 1.4 13.905 1.095 0.073
Table 1:
0.080
0.070
0.060
0.050
Xmin
0.040
0.030 Xmin = 0.0008(Ts-Ti) + 0.001
0.020
0.010
0.000
0 20 40 60 80 100
.min )Ts-Ti(
Figure.1
The following equation is induced from the above curve which will be used
for calculation of percent mineral dissolved by acid in the reservoir as function
of rock exposure time.
Table 2:
The reservoir pore volume per foot invaded by acid is calculated form the
following equation:
The total volume of required acid to dissolve certain amount of rock in the
reservoir is calculated from the following equation:
PVI = Vs
Vp
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Ti (min) 5 10 20 30
X' 4.50% 4.10% 3.30% 2.50%
Assumed Vs Vs Qi Vs Qi Vs Qi
Vp (ft³/ft) PVI Qi (ft³/ft.min) PVI PVI PVI
rs (ft³/ft) (ft³/ft) (ft³/ft.min) (ft³/ft) (ft³/ft.min) (ft³/ft) (ft³/ft.min)
1 0.17 1.67 10.10 0.33 1.54 9.30 0.15 1.27 7.68 0.06 1.00 6.06 0.03
1.5 0.40 4.05 10.10 0.81 3.73 9.30 0.37 3.08 7.68 0.15 2.43 6.06 0.08
2 0.73 7.39 10.10 1.48 6.79 9.30 0.68 5.61 7.68 0.28 4.43 6.06 0.15
2.5 1.16 11.67 10.10 2.33 10.74 9.30 1.07 8.87 7.68 0.44 7.00 6.06 0.23
3 1.67 16.91 10.10 3.38 15.55 9.30 1.56 12.85 7.68 0.64 10.14 6.06 0.34
3.5 2.29 23.10 10.10 4.62 21.25 9.30 2.12 17.55 7.68 0.88 13.85 6.06 0.46
4 2.99 30.24 10.10 6.05 27.82 9.30 2.78 22.98 7.68 1.15 18.13 6.06 0.60
Table 3:
Ti (min) 40 50 60
X' 1.70% 0.90% 0.10%
Assume Qi Vs Qi Qi
Vp (ft³/ft) Vs (ft³/ft) PVI PVI Vs (ft³/ft) PVI
d rs (ft³/ft.min) (ft³/ft) (ft³/ft.min) (ft³/ft.min)
1 0.17 0.73 4.44 0.02 0.47 2.82 0.01 0.20 1.20 0.00
1.5 0.40 1.78 4.44 0.04 1.13 2.82 0.02 0.48 1.20 0.01
2 0.73 3.24 4.44 0.08 2.06 2.82 0.04 0.88 1.20 0.01
2.5 1.16 5.13 4.44 0.13 3.26 2.82 0.07 1.39 1.20 0.02
3 1.67 7.43 4.44 0.19 4.72 2.82 0.09 2.01 1.20 0.03
3.5 2.29 10.15 4.44 0.25 6.45 2.82 0.13 2.75 1.20 0.05
4 2.99 13.29 4.44 0.33 8.44 2.82 0.17 3.60 1.20 0.06
The following table presents the related results of the table no. 3
Table 4:
Assumed rs 1 1.5 2 2.5
Ti Qi
Qi Vs Qi Vs Qi
(min PVI Vs (ft³/ft) Vs (ft³/ft) (ft³/ft.min)
(ft³/ft.min) (ft³/ft) (ft³/ft.min) (ft³/ft) (ft³/ft.min)
)
5 10.10 1.67 0.33 4.05 0.81 7.39 1.48 11.67 2.33
10 9.30 1.54 0.15 3.73 0.37 6.79 0.68 10.74 1.07
20 7.68 1.27 0.06 3.08 0.15 5.61 0.28 8.87 0.44
30 6.06 1.00 0.03 2.43 0.08 4.43 0.15 7.00 0.23
40 4.44 0.73 0.02 1.78 0.04 3.24 0.08 5.13 0.13
50 2.82 0.47 0.01 1.13 0.02 2.06 0.04 3.26 0.07
60 1.20 0.20 0.00 0.48 0.01 0.88 0.01 1.39 0.02
Assumed rs 3 3.5 4
Ti Qi Vs Qi Vs Qi
PVI Vs (ft³/ft)
(min) (ft³/ft.min) (ft³/ft) (ft³/ft.min) (ft³/ft) (ft³/ft.min)
5 10.10 16.91 3.38 23.10 4.62 30.24 6.05
10 9.30 15.55 1.56 21.25 2.12 27.82 2.78
20 7.68 12.85 0.64 17.55 0.88 22.98 1.15
30 6.06 10.14 0.34 13.85 0.46 18.13 0.60
40 4.44 7.43 0.19 10.15 0.25 13.29 0.33
50 2.82 4.72 0.09 6.45 0.13 8.44 0.17
60 1.20 2.01 0.03 2.75 0.05 3.60 0.06
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The stimulation ratios for different acid penetration radius are presented in
table no. 5.
Table 5:
Assumed
1 1.5 2 2.5 3 3.5 4
rs
Assumed
ks'
ks/ke
1 150 150 150 150 150 150 150
1.4 156.21 158.75 160.60 162.07 163.29 164.33 165.25
1.8 159.89 164.07 167.17 169.66 171.74 173.55 175.14
2.1 161.80 166.87 170.66 173.72 176.31 178.55 180.55
2.5 163.67 169.64 174.15 177.81 180.92 183.64 186.06
2.9 165.05 171.71 176.76 180.90 184.42 187.51 190.26
3 165.34 172.14 177.32 181.55 185.16 188.33 191.16
11 11.00 1.50
10 10.00 rs=1.5ft
Cum. Pore Volume Injected
9 9.00
PV
8 8.00 I .v
s. T
i in 1.00
7 7.00
qi (ft³/ft.min)
f ie
ld
6 6.00
PVI
rs=1ft
5 5.00
4 4.00
0.50
3 3.00
2 2.00
1 1.00
0 0.00 0.00
3.5 3 2.5 2 1.5 1 0.5 0 0 10 20 30 40 50 60
Stimulation Ratio (ks/ke) Ti (min)
rs=1.5ft 5.00
160
rs=2ft
10.00
165 rs=2.5ft
rs=1ft
Acid volume (ft³/ft)
15.00
170
rs=3ft
Ks' (md)
20.00
rs=1.5ft 175
rs=2ft rs=3.5ft 25.00
180
rs=2.5ft
rs=4ft 30.00
rs=3ft 185
35.00
rs=3.5ft
190
rs=4ft
40.00
195
Figure. 2
Vs Qi
rs (ft) Ks/Ke k's Ti (min)
(gal/ft) (gal/ft.min)
73.3089 2.5 2.17 174.5 1.4961 31.9
Construct IPR curve after acidizing , THP ,and TPC then find (P'wf ,Qs).
Qs = Ks . (Pe - P'wf)
Qe Ke (Pe – Pwf)
Assumed Qs
Pwf'(psi) (bbl/D)
1000 11989.8
1200 9065.4
1500 4678.9
1800 292.4
1820 0.0
2000
1800
1600
1400
1200
1000
800
600
400
200
0
0 2000 4000 6000 8000 10000 12000 14000
Figure.3
From figure 3 we find that:
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Qs (bbl/D) P'wf (psi)
3300 1600
PR= 2.23
The concentration of dissolved rock in the acid solution is calculated from
the following equation:
Xacid
ΔØ = 2.16 %
Øs = 10.16 %
Design parameters:
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Optimum volume of acid (gal/ft) 73.31
Optimum injection time (min.) 31.90
Desired injection rate (gal/ft.min) 1.50
Radial distance of acid penetration inside the formation (ft) 2.50
Stimulation ratio after acidizing 2.17
Maximum average reservoir permeability after acidizing (md) 174.53
Oil flow rate after acidizing (bbl/D) 3300
Bottom hole flowing pressure after acidizing (psi) 1600
Productivity ratio after acidizing 2.23
The concentration of dissolved rock in the acid solution (lbs/gal) 13.10
Increase in porosity after acidizing 2.2%
Porosity after acidizing 10.2%
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Corrosion
Iron precipitation
Fluid incompatibilities
Fines mobilization
28
Reference
1. Petroleum Engineering .Hand book
2. Halliburton Presentation
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