2020 년 기말고사 (6 월 16 일 화)

1. A liquefied mixture gas contains 0.07% H2S and 99.93% CO2. Calculate the concentration (ppm) of H2S in
CO2 when the gas is vaporized. (M.W.(H2S) = 34) (10 points)

2. Silicon rods used in the manufacture of chips can be prepared by the Czochralski process in which a cylinder
of rotating silicon is slowly drawn from a heated bath (see the image below). 30 kg of silicon in the initial
bath is completely consumed for 2 hrs when cylindrical ingot is to be removed slowly from the melt at the
rate of 3 mm/min. Calculate the diameter of silicon ingot in cm. Assume that the silicon ingot has a specific
gravity of 2.33. (10 points)

3. Assume that methanol and twice the stoichiometric amount of air needed for complete oxidation of the
CH3OH are fed to the reactor, that 90% conversion of the methanol results, and that a 75% yield of
formaldehyde occurs (based on the theoretical production of CH 2O by reaction 1). Determine composition of
the product gas leaving the reactor. (10 points)

4. Determine the ratio of the recycle stream to the fresh feed stream if the overall conversion of benzene is 95%
and the single-pass conversion through the reactor is 20%. Assume that 20% excess hydrogen is used in the
fresh feed and that the composition of the recycle stream is 22.74 mol% benzene and 78.26% hydrogen. (10
points)
 5. Toluene reacts with H2 to form benzene (B), but a side reaction occurs in which a by-product, diphenyl (D),
is formed:

C7H8 + H2 → C6H6 + CH4 (a)

(toluene) (hydrogen) (benzene) (methane)

2 C7H8 + H2 → C12H10 + 2CH4 (b)

(diphenyl)

The process is shown in figure below. Hydrogen is added to the gas recycle stream to make the ratio of H 2
to CH4 1 to 1 before the gas enters the mixer. The ratio of H2 to toluene entering the reactor at G is 4 H2 to 1
toluene. The conversion of toluene to benzene on one pass through the reactor is 80% and the conversion of
toluene to the by-product diphenyl is 8% on the same pass. Calculate the mole fraction of R G (10 points)

H2 CH4 C2H6 C7H8 C12H10

MW 2 16 78 92 154

<주의 사항>

1. 답안지는 깨끗하게 정리하여 쓸 것. (답 밑에 밑줄을 긋고 반드시 답이라고 표시할 것)

2. 학번, 이름 반드시 확인하고 답안지에 쓸 것. (답안지는 2 장까지 사용 가능)
3. 빨간색 펜은 절대 사용하지 말 것
4. 시험성적 및 학점은 반드시 찾아와서 물어볼 것 (e-mail 또는 전화로 물어 보지 말 것.)
5. 공시된 학점은 이의신청 검토 이후 점수가 다시 반영되므로 최종학점과 다를수 있음.
(본 과목은 김영란법에 따라 학점에 대한 어떠한 편의도 제공되지 않으며 오직 학칙에 따라 모든 학생에게 동일한
판단 기준으로 성적이 부여됩니다. 따라서 학점 조정을 위한 어떠한 시도도 거부합니다.) .
6. 코로나로 인하여 이번 학기만 한시적으로 절대평가로 학점 부여 (A+, A0, B+, B0, F )
- 모든 문제는 부분점수 없음 (풀이과정과 답이 맞아야 점수로 인정함)