11th Standard - Chemistry - Govt Public Exam Original Question Papers - 6 Sets - EM

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11TH
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CHEMISTRY
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et t
alv n kalv n kalv nk alv nk alv nk alv nk alv nkalv
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lvi.
net c) SOlv2i.net lvi.
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alv n k a k a k a k a k a k a k a
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12.which
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t et net net t net net net
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alv a)
n k a lbenzene
n k a n k a b)
n k a lvethane
.tn k a n k a n k a
w.t w.t w.t w.t ww w.t w.t
ww ww ww ww ww ww ww
c) propene d) ethynew
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unit
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heat
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t
i.ne
t
i.ne
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w.t JK mol ww.t
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c)wwKJ w.t d).t cm
w w.t
ww w ww ww ww ww ww
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t et t t t t t t
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alv kal n k alv b) 50% nkalv c) 20% n k alv n k alv d) n
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15.osmotic pressure ( π) of a solution is given by the relation :
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t t t t net net net net
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six of the n e
lvi following kquestions.
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Question lvi. no.24 islvi. compulsory. lvi. 6 X 2 = 12 lvi.
alv n k a n k a a k a k a k a k a
w.t w.t .tn w.t
n
w.t
n
w.t
n
w.t
n
ww
16.State
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ww ww ww ww ww
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n
w.t
n
w.t
n
w.t
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w.t
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ww w ww ww ww ww ww ww
19.State the third law of thermodynamics ?
alv
alv
i.ne
i.ne
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t
20.What
ww
w. t n k
wwcan be determined
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ww
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a lvi.
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k
k
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a lvi.
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the length
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ww
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by et
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n
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k alv
i.ne
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n
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ww
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t net net net net net net net
alv
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n .tn n n n n n
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ww is thewsuitable methodww for detection ww of nitrogenww present in food
ww and fertilizers? ww ww
t et et et
PART-IIIet t t t
i.ne vi.n vi.n vi.n i.n i.ne i.ne i.ne
alv Answer n k a l
any six of nthe
k a l
following n k al
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n k alv no.33 n k alv compulsory
is n k alv 6 X 3 = 18 n k alv
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alv
i.ne
t 26.Explain alv
i.ne diagonal relationship
t
alv
i.ne
t . alvi.net alv
i.ne
t
alv
i.ne
t
alv
i.ne
t
alv
i.ne
t
t n k t n k t n k t n k t n k t n k t n k
w.
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ww ww prepared ?ww ww ww ww ww ww
t
28.Define –Le-Chatelier t
principle.
t
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the term “isotonic
k a lv
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n n n n n n n
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i.ne
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lvi.
net
lvi.
net
lvi.
net
lvi.
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w.t .tn w.t
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w.t
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w.t
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ww whywCa(OH)
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CHEMISTRY
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w
ww ww
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ii) Write the de-broglie equation.
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t
i.ne
t net net ne t
alv al al alv alv lvi. lvi. lvi.
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t et 0 net net net -1 net net et
i.ne vi.n
lwater at 0 c. enthalpy
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i.ne i.n i. n i.n n i.ne net net
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37. a) i) Write the IUPAC names for the following compounds.
t t t t t t t t
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alv alv alv alv alv alv alv alv
w .tnk w.t
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w. tn k
w.t
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w.t
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w.t
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w.t
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11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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w
ww
47. Find its molecular formula.
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k a hydrocarbon
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n k a
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t
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t
i.ne
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alv alv alv alv alv alv alv lvi.
n k n k n k n k n k n k nka
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t t t t net net t net
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t t t t t t t t
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11TH
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11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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n extinguisher w.t
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w.t
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k a lvi.
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ww Tollen‟s reagent ww ww ww d) Baeyer‟s ww reagent ww ww ww
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n k a l
w.t
n k a l
w.t
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11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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11.Assertion : Helium has the highest value of ionisation energy among all the
i.ne
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lvi.
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lvi.
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lvi.
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lvi.
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lvi.
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i.ne
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t
i.ne
t
i.ne
t
i.ne
t
i.ne
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i.ne
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alv nk alv n k alv and reason nk alis nk alv n k alv n k alv nka
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w . t . tn
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i.ne
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i.ne net n et et
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is www.tn k .tnk nka nka .tnk
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lv
nka
lv
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alv
alv
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i.ne
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t
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PART-II
vi.n
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a lvi.
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a lvi.
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a lvi.
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a lvi.
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16.Define basicity.Find the basicity of tortho-phosphoric Acid.
i.ne i . n et i . n et i . n e i .n et i.ne
t
i.ne
t
i.ne
t
alv 17.Writen k alv the exchange n k alv reactions of n k
v
alDeuterium. n k alv n k alv n k alv n k alv
18.state zeroth Law of Thermodynamics.
i.ne
t 19.Explain i.ne homogeneous
t
i.ne and heterogeneous
t
i.ne
t equilibria. i.ne
t
i.ne
t
i.ne
t
i.ne
t
alv n kalv n k alv n k alv n k alv n k alv n k alv n k alv
w. t w. t t
w. geomentry w. t w. t w. t w. t
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ww and molecular ww ww for BF 3 ww ww ww ww
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t net et net net net net net
i.ne lvi.the no bond vi.n lvi. lvi. propene ?kalvi. lvi. lvi.
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n k a shown n k a by n n k a n k a
23.Give the structure and uses of DDT .
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alv a lvi. a lvi. a lvi. a lvi. a l . a lvi. l
w w.t
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w w w w w w w ww

alv lvi. lvi. al vi.n lvi. alvi.n lvi. lvi.
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t ASST IN CHEMISTRY
i.ne
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i.ne
t 7708543401
i.ne
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alv nka
lv
nka
lv
nka
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t t
11TH
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CHEMISTRY
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PUBLIC
et
QUESTIONS
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Part-III
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w
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ww
w.t
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ww
w.t
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ww
w.t
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ww
26.Derive ionic radius using pauling‟s method .
t t net net t net net net
i.ne i.ne lvi. para hydrogen lvi. into ortho i.ne lvi. lvi. lvi.
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n k a n k a n k a lvhydrogen.
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i.ne
t 29.Calculate i.ne
t the mole fraction
i.ne
t of methanol i.ne
t and water i.ne
t when
i.ne
t
i.ne
t
i.ne
t
w.t mole of methanol
0.5 w.t w.t with 1.5 moles
is mixed w.t of water. w.t w.t w.t
30.What is hybridisation ? mention the type of hybridization found in CH4
t t t t net t t t
i.ne 31.Explain i.ne the different i.ne i.ne lvi. ethyne. i.ne i.ne i.ne
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nk alv nk ain n k alv n k alv n k alv
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32.What is green house effectww? Name the gases ww
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i.ne
t
i.ne
t
i.ne
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lv a lv alv nka
lv a lv
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PART-IV
t t t t t t t t
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alv
.
lvi.
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w.t
n
w.t
n
w.t
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w.t
n
w.t
n
w.t
n
w.t
n
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alv
alv
i.ne
i.ne
t
t
w
w.
w
t
w
n k
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i.ne
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t
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ww
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ww
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ww
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t n
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i.ne
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ww
ww
w.
w.t
t n
nka
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lv
alv
i.ne
i.ne
t
ww
w.t
nka
l vi.n
e t
ww
ww
ii) Name the different methods of liquefaction of gases.
t net net net net net et et
alv
i.ne
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n
al vi.n
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ww prepared ?www ww ww
w
ww
w
ww
t
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the uses ofemagnesium.
t t t t
i.ne vi.n i.n i.ne i.ne i.ne net net
lvi. lvi.
alv iii)Write
w.t
n k a l
the mathematical
w.t
n k alv formula
w.t
n k alv for compressibility
w.t
n k alv factor
w.t
n k alv „Z‟
w.tnk
a
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alv
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alv
i.ne
t the relation alv
i.ne between lenthalpy
t
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i.ne
t ΔH aand lvi.
net internal energy
alv
i.ne
t ΔU for anne
alv
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t
a
t
t n k t n k tn k t n k t n k t n k t n k
w. . w. w. w. w. w.
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ww ww ww ww ww ww
t t t t
(OR) t t
i.ne i.ne i.ne i.ne ne i.ne net 0lvi.ne
t
alv b) i)k a lv
Calculate the k a lv
entropy change k a l v
during the k a lvi.
melting of one k a lvmole of ice k lvi. water at 0
into
a k a C
n n n n n n n
ww ww ww ww ww -1 ww ww ww
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et orbital
lvi.
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net
lvi.
net
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nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
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t
i.ne
t PG
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i.ne
t
i.ne
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i.ne
t Page 14
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
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Tnkalvi.Net
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
i.ne
t 37.a) i)What lvi.
net is van‟t hoff
lvi.
net factor „i‟ ?
lvi.
net vi.n
et
vi.n
et i. net vi.n
et
alv k a k a k a al al alv al
w.t
n
w.t
n
w.t
n .tnk .tnk .tnk .tnk
ww ii) complete
w w w w
t t t et et t et t
i.ne A) i.ne i.ne vi.n vi.n lvi.
ne vi.n i.ne
alv alv H2C=CH2nk+
alvH-Br al al nka al alv
w. tnk t w. w .tnk w .tnk w . t w .tnk w .tnk
t
B) CH
et
3CHO
i.ne n net n et net net net ne t
alv lvi. alv
i. lvi. lvi. lvi. lvi. lvi.
nka .tnk .tnk
a
.tnk
a nka .tnk
a nka
w.t w w w w.t w w.t
t C) .net net t t net net net

i.ne i lvi. i.ne i.ne i. lvi. lvi.
alv nk alv nka nk alv nk alv nk alv nka nka
alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
ww ww ww ww w w ww ww ww
t t et et et net et et
i.ne vi .ne vi.n lvi.
n vi.n lvi. lvi.
n vi.n
alv nD)
kal al nka al a nka al
w.t w .tnk w .t w .tnk w.t
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w .t w .tnk
ww ww (OR) ww ww ww ww ww ww
t b) Explain
t the purification
t of a solidt organic compound
t by crystallization
t method
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i.ne .ne vi .ne .ne lvi .ne .ne lvi .ne lvi lvi lvi lvi.
ww ww ww ww ww w ww ww ww
38.a) i) write Brich reduction .
alv
alv
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i.ne
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t
ww
ww
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alv Write any nthree
ww
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w w
k a
w
lvi.
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i.ne strategies to
net
ww
w. t n
involved
w w .tn
k
k a
i.ne
lvi.
w
t
alv control environment
net
ww
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t n k alv
in the elimination
w w .tn k a
i.ne
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w. t n k alv
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t
ww
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ww .tn k a lvi.
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w w .tnk
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alv
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t
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ww ww ww ww ww

w .t n
w .tnk w .t n k
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w .tnk w .tnk
t t t t t t t t
w .tnk w.t
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w. tn k
w.t
nk
w.t
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w.t
nk
w.t
nk

l
w .tnk w .tnk w .tnk w .tnk w .tnk w .tnk w.t

nka .tnk
a
a
w.t w w w.t w w.t w
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t PG
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i.ne
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i.ne
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alv nka
lv
nka
lv
nka
lv
nka
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Tnkalvi.Net
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
i.ne
t
vi.n
et i. net
lvi.
net Sep-2021 lvi.
net vi.n
et i. net vi.n
et
w .tnk w .tnk w.t
n k
PART-I
w.t
n k
w .tnk w .tnk w .tnk
alv
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a lvi.
choose
n et the amost
lvi.
net appropriate
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net answer from
a lvi.
net the given
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nk .tn k nk n k .tn k n k .tnk
w.t writewthe
ww option code w.t w.t w.t
ww ww and the corresponding
ww wanswer
ww . ww 15 X 1 w=ww15 ww
t et t t net net net t

alv
i.ne 1. Which
alv
i.none of the following
alv
i.ne of presents
alv
i.ne 180g of
alv
i.water ? lvi. lvi. lvi.
ne
nk nk .tnk .tnk nka .tnk
a nka
w.t 6.022 w.t 24 ww w w.t ww w.t
ww ww X 10 w ww ww ww ww
a) moles of water b) 5 moles of wwater
180
t et 24 et
i.ne c) vi.n 6.022 X 10 vi.n moles of awater net i.ne
t
d) 90almoles vi.n
et of water i.ne
t
i.ne
t
alv k a l k a l k lvi. k alv k k alv k alv
t n t n t n t n t n t n t n
w. ww
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2.Which
ww of the wfollowing compound(s)
ww has/have
ww percentage ww of carbon w same as that inwww ww
t
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i.ne i.ne net net net net net net
alv l v lvi. lvi. lvi. lvi. lvi. lvi.
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k a k a b) propene n k a n k a c) ethanew.tn k a d) nethyne
k a n k a
w.t w w.t w.t w.t w.t
3.Assertion ; permanent hardness of water is removed by treatment with washing soda
alv
i.ne
t Reasonsalvi.:netWashing asoda lvi.
net reacts with
a lvi.
nsoluble
et calciuma lvi.
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alvi.
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neand
t sulphate a lvi.
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n k n k n k n k n k n k n k
w.t in hardw.t w.t insoluble carbonates. w.t w.t w.t w.t
ww ww water to from ww ww ww ww ww ww
t
a) Assertion is true but reason is falset
i.ne net n et i.ne et net i.ne
t
i.ne
t
alv
i.
alvassertion and
i .
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b) Both
.t n k
w.t
n k .t k
w.t
n k alis the correct
w.t
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alv
alv
i.ne
i.ne
t
t d)Both lassertion
ww
w.
4.Flame t
5. Formula
ww
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w
n k
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i.ne
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colour wof
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t
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ww
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t
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ww
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alv
i.ne
lvi.
net
ww
t
w
ww
ww
a) 3CaSO4.H2O b) CaSO4.2H2O c) 2CaSO4.2H2O d) CaSO4. H2O
2
t t net t net t t t
i.ne 6. Rate ne
of diffusion of a gas is : nka
lvi. lvi. lvi.
ne
lvi. lvi.
ne
lvi.
ne
lvi.
ne
alv nka n k a nka nka nka nka
w . t w . t w . t w . t w . t w . t w . t
ww ww
a) directly ww
proportional to the square ww root of its wwmolecular weight ww ww ww
t b)et directly proportional et to its et density t t t t

alv k al k al k al k alv k alv k alv k alv
ww
w.t
n c) inversely
ww
w.t
n proportional
ww
w.t
n to the square
ww
w.t
n root of its
ww
wmolecular
.t n weight
ww
w.t
n
ww
w.t
n
ww
d) directly proportional to its molecular weight
t net t t t t t t
i.ne 7. Heatkaof lvi. combustion i.ne i.ne i.ne i.ne i.ne i.ne
alv n n k alv is always :nkalv n k alv n k alv n k alv n k alv
ww a) zero ww ww ww ww
b) positive ww ww ww
t c)et either positive or negativeet d)etnegative

i.ne n net n n net net net
alv k a lvi. k a lvi. k a lvi. k a lvi. k alvi. k a lvi. ka lvi.
8. For
ww
.tn the following
ww
.tn reversible rections
ww
.tn at equilibrium
ww
.tn A +wB
w.t
n C.
ww
If.tnthe concentration
ww
.tn of
w w w w w w w ww
the reactants A and B are doubled, then the equilibrium constant will :
i.ne
t a)et be halvedlvi.net
i.n lvi.
net
lvi.
net b) be doubled lvi.
net
lvi.
net
lvi.
net
alv alv a a a a a a
.tnk n k
w.t the same ww.t
n k
w.t
n k
w.t
n k
w.t
n k
w.t
n k
ww
w c) remain
ww w ww d) become
ww one fourth
ww ww ww
9.The molality of a solution containing 1.8g of glucose dissolved in 250g of water is
i.n et et i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
alv a) vi.n
al0.02M alv b) 0.2M alv c) alv 0.04M alv d) 0.01M alv alv
.tn k .t n k .t nk .tn k .t nk .t n k .t n k
w w w w w w w
i.ne
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t
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t PG
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t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
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w ww w ww ww ww ww
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ww www ww
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
10.Match the following
i.ne
t 1)
lvi.
net N2 molecule
lvi.
net
lvi.
net i) chemical
lvi.
net bond lvi.net lvi.
net
lvi.
net
alv n k a nk a n k a n k a n k a k a k a
ww
w.t 2) w.t
BF3wwmolecule ww
w.t w.t
ww ii) Trible covalent ww
w.t bond www.tn ww
w.t
n
ww
3) HF molecule iii) Electron deficient molecule
t t t t t net net net
i.ne lvi. n e
lvi . n e
lvi . ne i.ne lvi.bond lvi. lvi.
alv nk a4) NaCl .tn k a nk a iv)
.tn k a lvpolar covalent
.tn k a
.tn k a
.tn k a
w.t ww w.t ww ww ww ww
ww ww ww
a) 1)- iii)w, 2)- i) , 3)-iv) , 4)- ii)w b) 1)-ii) , w2)- iv) , 3)-i)w , 4)- iii) w
i.ne
t c) v1)- i.ne
t i) , 2)- iv)net , 3)- ii) , 4)-
i. i.ne
t iii) d)vi.1)- net ii) , 2)-iii) i.ne
t , 3)- iv) , ne4)-
i.
t i) i.ne
t
alv n k al n k alv n k alv n k al n k alv n k alv n k alv
w.t structure wof
11.The w.t isobutyl group w.t in organic .t
wcompound w.t w.t w.t
t t net t t net net net

i.ne i.ne lvi. i.ne i.ne i. lvi. lvi.
w.t a) w.t w.t w.t b) w.t w.t w.t
alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
t
c)t t t
d)
t
i.ne vi.n
e i.ne i.ne i.ne net net net
alv kal l v l v l v lvi. lvi. lvi.
12.Which
w.t
n of the following
w.t
n k a is optically
w.t
n k a active w?.tn k a
w.t
n k a
w.t
n k a
w.t
n k a
a) meso-tartaric acid b) 3-chloropentane
t c)i.net glucose alvi.net t t d) 2-chloropropane t t t
i.ne i.ne i.ne i.ne i.ne i.ne
alv n k alv n k n k alv n k alv n k alv n k alv n k alv
w.t w.t w.t t w.t w.t w.t
13.The
ww geometrical ww shape of carbocation
ww iswww. ww ww ww ww
Tnkalvi.Net
t
a) planar b) linear t c) pyramidal d) tetrahedral
i.ne i. net i. net i . ne i . net i . net i.ne
t
i.ne
t
alv 14.An n k al v
alkene is obtained
n k al v
by n k al
decarboxylation v
of n al v
sodium
k al
propionate.same
n k
v
alkene
n k alv can be n k alv
prepared by :
i.ne
t a)lvi.reduction
net oflv1-chloro
i.ne
t propane lvi.
net b) catalyticlvi.
net hydrogenation lvi.
net of propene lvi.
net
lvi.
net
w.t c) reduction w.t .tn .tn w.t
n
w.t
n
w.t
n
ww ww of bromo w methane
ww wd)
ww action of sodium ww metal on ww iodomethane ww ww
15.Of the following compounds , which has the highest boiling point?
t net net net net et net net
i.ne lvi.a) t-butyl chloride lvi. lvi. lvi. b) n-butyl vi.n
lchloride lvi. lvi.
alv n k a n k a n k a n k a n k a n k a n k a
c) n-propyl chloride d) Isobutyl chloride
i.ne
t
i.ne
t
i.ne
t
i.ne
t PART-II i.ne
t
i.ne
t
i.ne
t
i.ne
t
Answer
ww
w.t
n any sixwwfrom w.t
n the following
ww
w.t
n questions.Q.no.24
ww
w.t
n is wcompulsory.
ww
.t n
ww
w.t
n 6 X 2 =ww12 w.t
n
ww
16.What is the empirical formula of the following ?
t et et et et t t t
i.ne vi.n vi.n vi.n lvi.
n i.ne i.ne i.ne
alv a).tnFructose
kal (C6H kalO6)
.tn12
ii).tnCaffeine
kal ( C8.tH
nka10N4O2) nk alv nk alv nk alv
w w w w w.t w.t w.t
17.State Aufbau principle
t net net net net net et net
i.ne lvi. lvi. para hydrogen lvi. into ortho lvi. lvi. vi.n lvi.
alv 18.How nka do you convert
nka nka nka hydrogen ? nka al a
w.t w.t w.t w.t w.t w .tnk w .tn k
19.Give any two characteristics of gibbs free energy ?
t t t t t et net et
i.ne i.ne i.ne i.ne i.ne vi.n i. vi.n
alv 20.Define
w.t
nka
lv
Hess‟s wlaw
.tnk of constant
alv
w.t
nheat
kal
v
summation.
w.t
nka
lv
w .tnk
al
w.tnk
alv
w.t
nka
l
21.What is the relation between KP and KC ? Give one example for which KP is equal
t t et t net et net net
i.ne i.ne lvi.
n vi.n
e
lvi. vi.n lvi. lvi.
alv tow.K alv al al
tnkC.
a nka nka a
w .tnk w .tnk w.t w .tnk w.t w .tnk
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
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i.ne
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i.ne
t Page 17
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
22.What is molal depression constant ?
t t t t et et net et
i.ne 23.Write ne
lvi.short noteskaon
ne
lvi. Swarts reaction
lvi.
ne ? vi.n vi.n i. vi.n
alv nka nka al al alv al
w.t
n
w.t w.t w .tnk w .tnk w .tnk w .tnk
24.Complete the following :
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne
ww a) ww
CH3-CH=CH2 + H2 ww ww ww ww ww ww
i.ne
t b) CH neMgCl
lvi. 3
t + H2lO
vi.n
et
lvi.
n et
lvi.
net
lvi.
net
lvi.
net
lvi.
ne t
alv nka a a a nka a nka
w.t w .tnk w .tnk w .tnk w.t w .tnk w.t
ww ww ww Part-III ww ww ww ww ww
t Note : Answer et
any six questions.
et
Questionet
NO.33etis compulsory. t 6 Xet3 = 18
i.ne vi.n vi.n vi.n i.n i.ne n net
alv l l l al.v alv lvi. lvi.
25. Distinguish
w. t nk a between
w. tn k a oxidation
w. t nk and
a reduction
w. t nk
w.t n k
w.t
nka
w.t
nka
26.Define electronegativity. State the trends in the variation of electronegativity in
alv l
group and period
nka nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
27.What are homogeneous and heterogeneous equilibria? Give example
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
28.What
ww
are idealwwsolutions ? Give example ww
.tnk .tnk w .t .tnk w.t
n k
w .t w .tnk
w w ww w ww ww ww ww
29.Give the shapes of molecules predicted by VSEPR theory
i.ne vi.n lvi.
n
w .tnk
a) BeCl2 b) .tnk
w NH3 c)w H O
w.t 2 w .tnk w.t .tnk w.t
ww ww w ww ww www ww ww
Tnkalvi.Net
t
30.Give thet general formula
t
for the following
t
class of
t
organic compounds
t t t
i.ne i.ne lvi.
n e i.ne i.ne i.ne i.ne i.ne
alv nk alv nka nk alv nk alv nk alv nk alv nk alv
a) Alkanes
ww
w.t
ww
b) Alkenes
w.t
ww
w.t c) Alkynesww w.t
ww
w.t
ww
w.t
ww
w.t
ww
t
31.What is tresonance ?
i.ne i.ne et et et net i.ne
t e t
alv alv l vi.n al vi.n alv
i.n
alv
i. lv l vi.n
.tnk nka .tnk .tnk .tnk nka nka
32.Suggest
w w w a simple
ww
chemical test to distinguish
w.t
ww
w propane wand
ww propene ww
w
ww
w.t
ww
w.t
ww
3
t
33.Inside aetcertain automobile
et
engine e,t the volume of
et
air in a cylinder
et
is 0.375 dm
et
,
i.ne vi.n i. n vi.n vi.n vi.n n net
alv al alv al al al lvi. lvi.
.tnk .tnk .tnk .tnk .tnk t nka tnk
.3
a
ww
w when the pressure
ww
w is 1.05atm
ww
w . When the wgas
w
w is compressed
ww
w to a volume of 0.125 wdm
ww ww
w .
ww
t at the same
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w
ww
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Note : Answer all the questions . 5 X 5 = 25
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b) i) Define atomic radius.
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11TH
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CHEMISTRY
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PUBLIC
et
QUESTIONS
et t
35. a) Discuss the similarities between beryllium and aluminium
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t t t t t t et t
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t et net et et net net t
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n i. lvi.
n i.n lvi. lvi. lvi.
ne
alv nka .tnk
alv
.tnk
a (OR)
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nk
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t t t t t et et et
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l
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t t net net et net et et
i.ne lvi.
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ww ww ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
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i.ne
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et i. net
lvi.
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net vi.n
et i. net vi.n
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w w ww w w w
Note : i) Answer all the questions. 15 X 1 = 15
t t t t t t net net
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lvi. ne
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ww ww ww
w
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w
ww ww
a) C9H18 b) C8H14 c) C8H18 d) All of the above
ww ww ww
2.Equimolal aqueous solutions of NaCl andwwKCl are prepared . If the freezing ww ww ww ww
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i.ne
t point of i.ne
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0
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.tn0 C
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3
t b) –CH et 3 > -CH et 2CH3 > -CH(CH

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d) –CH(CH3)2 > -C(CH3)3 > -CH2CH3 > -CH3
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t net t net net net net net
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alv
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i.ne
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6.Thew. intensive property w. among w. w. w. w. w.
ww ww ww the quantities ww below is : ww ww ww ww
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t a) Enthalpy t tb) mass t c) et
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i.n ei.n e i.n 𝑣𝑜𝑙𝑢𝑚𝑒
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w.t w.t
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? w w.t
ww ww w.t
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t t net net net net net et
i.ne to i.ne same extent.
lvthe lvi. lvi. lvi. lvi. lvi. vi.n
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i.ne
t net
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d)
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w.can
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w.t
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alv nka
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
i.ne
t 8.Matchlvof i.ne following lvi.ne
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lvi.
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lvi.
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lvi.
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t t t net net net net net
i.ne . n e
lvi -CH -CH kalvi . n e
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n k a n k a n k a n k a n k a
4) –NH2 iv) Nitro
i.ne
t a) (1)- v(iii), i.ne
t (2)-(ii) , (3)-(iv),
i.ne
t (4)-(i) i.ne
t b) (1)- i.ne
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i.ne
t
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9.Spodumene is the mineral source for which of the following alkali metal ?
t net t t t t t t
i.ne a) .tLithium lvi. i.neb) Sodiumlvi.ne c) i.ne
Rubidium i.ne d) Potassium i.ne i.ne
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d) CaCl t
ne2 net
alv k a lv k alvi. k a lv k a lvi. k a lvi. k a lvi. k a lvi.
11.Tritiumn nucleus n n n n n n
w.t w.t contains : ww.t w.t w.t w.t w.t
a) 1p+2n b) 1p+on c) 1p+1n d) 2p+1n
t t t t t t net net
i.ne 12.Which ne
lvi. one of thekafollowing lvi.
ne
is ne
diamagnetic
lvi. ? lvi.
ne
lvi.
ne
lvi. lvi.
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2 2
t 13.Splitting et of spectrali.n lines

et in an electric et field is called et : t t t
i.ne vi.n vi.n vi.n i.ne i.ne i.ne
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k a l k a l k alv k alv k alv
a)
w.t Comptonweffect
n
w.t
n
w.t
n
w.t
n b) Zeeman w.t effect
n
w.t
n
w.t
n
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alv
alv
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i.ne
t
t
14.A bottle
ww
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wsimultaneously
w
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ww
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Tnkalvi.Net
e
n t
t
i.n of ammonia
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ww at both ends.
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ww
w
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ww
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ww
ww
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w
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ww
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ww
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w
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15.
i.ne
t a) optical
lvi.
net isomers vi.netb) resonating
lvi.
netstructures vi.nec)
t conformers
lvi.
net d) tautomers
lvi.
net
lvi.
net
alv a l a l a a a a a
w .tnk w .tnk w .tnk w.tnk w .tnk w.tnk w .tnk
Part-II
t et et t t t t t
i.ne vi.n i.n i.ne i.ne i.ne i.ne i.ne
alv Note.tn: answer any.tnsix
kal k questions.
alv
tn k Question No.24
alv
t n k alv is compulsory
t n k alv
t n k alv6 X 2 = 12 nkalv
t
w ww w. w. w. w. w.
16.Define Gramw equivalent mass
i.ne
t 17.Calculate net the maximum net number vof neelectrons
t that netcan be accommodated net inviL netshell net
alv k a lvi. k a lvi. k a l i. k a lvi. k a lvi. k a l . k a lvi.
n .tn types of covalent n n n n n
w.t
18.Mention the wthree
ww w.t w.t .
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19.What are the condition for the spontaneity of a process
i.ne 20.Explain lvi. sign convention lvi. of heat lvi. lvi. lvi. lvi. lvi.
alv n k a nk a k a k a k a k a k a
w.t w.t .tn w.t
n
w.t
n
w.t
n
w.t
n
ww ww ww ww equilibrium wwreaction for which ww ww ww
21.Give a balanced chemical wequation for the the
t [𝑁𝐻3 ]4 [𝑂2 ]5
et
equilibrium constant et t et t net net
alv
i.ne vi.n vi.n is given by viexpression
.ne Kc vi.n= v i.ne lvi. lvi.
kal
n kal kal
.tn kal .tn n kal6
[𝑁𝑂]4 [𝐻.2tn𝑂] nka .tnk
a
w.t w w w.t w w.t w
i.ne
i.ne
t
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t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 21
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
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Tnkalvi.Net
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
22.Define the term “isotonic” solution
i.ne
t 23.Howlvwill i.ne you convert
t
lvi.
net ethyl chloride
lvi.
net to ethane v?i.net vi.n
et i. net vi.n
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alv k a k a k a al al alv al
.tn .tn .tn .tnk .tnk .tnk .tnk
24.Complete
ww
w thewwfollowing reactions
w
ww
w
ww
w
ww
w
ww
w
ww
w
ww
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne
w .tnk w . t w .tnk w.tnk w . t w.tnk w .tnk

i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne
w.t w .tnk w .tnk PART-III
w .tnk w.t w .tnk w.t
Note : Answer any six questions. Question No.33 is compulsory 6X3=18
t t t t t t t t
i.ne 25.Calculate i.n e
the oxidation i.ne
number n e
lvi. underlined vi.n
e i.n e i.ne i.ne
alv nk alv n k alv nk aof n k alelements . n k alv n k alv n k alv
w. t w. t . t w. t w. t w. t w. t
i) CO2 ii) H2SO4 w
i.ne
t 26.Definei.neelectron t affinity net net net net net net
alv k a lv k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi.
n .tn of partial pressures. n n n n n
27.State
ww
w.t DaltonwLaw ww ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
28.Write the formula to calculate the molar mass of a solute from realative lowering of
i.ne vapour lvi. pressure kvalues. lvi. lvi. lvi. lvi. lvi. lvi.
alv n k a a k a k a k a k a k a
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32.what happens when ethylene is passed through cold dilute alkaline potassium
alv
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ww How many ww orbitals are wwpossible for n=4 ww ? ww ww ww ww
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n k a l
n k a l
(OR) n k a l
n k alv n k alv n k alv
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t 35.a) i)aWhat net are the areasons net for the t t t ? alvi.net t
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i.ne of Berylium i.ne i.ne
alv n k n k n k alv n k alv n k alv n k n k alv
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i.ne
t 7708543401
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t Page 22
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alv nka
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11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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37.a) How will you determine the ionic character in covalent bond using electronegativity
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lvi.
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lvi.
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lvi.
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lvi.
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lvi.
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alv n k a nk a n k a n k a n k a n k a n k a
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i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne

i.ne lvi.
n i. lvi.
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lvi. lvi. lvi. lvi.
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alv nka
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i.ne vi. vi. lvi. lvi. lvi. lvi. lvi.
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nka ? nka nka
w . t w . t w .t w . t w .t . t . t
w
ww
i) nitrobenzene ii) benzene sulphonic acid iii) BHC w
i.ne
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alv nka
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11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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net vi.n
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wPart-I
w w ww w w w
t net t net et net net net
i.ne lvi. choose the i.ne lvi. vi.n lvi. four alternatives lvi. lvi.
alv nk ii)
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alv a l al al nka
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1. Total number of electrons present in 1.7 g of ammonia is :
i.ne vi.n vi.n 6.022𝑋 10a22
lvi.
n vi.n
6.022𝑋al10 24
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2. The total number of orbitals associated with the principle quantum number n=3
alv nka
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a) 9 b) 8 c) 5ww d)w w
7 ww ww ww
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alv a lv a lvi. a lvi. a lvi. alvi. a lvi. a lvi.
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t t net t t t t t
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alv n k alv lvi.
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8.If X is the fraction of PCl5 dissociated at equilibrium in the reaction
t
alv
i.ne PClk5alvi.net k alv
t
i.ne PCl3 + Cl
k alv2
i.ne
t
k alv
i.ne
t
k alv
i.ne
t
k alv
i.ne
t
k alv
i.ne
t
n n n n n n n
w.t w.t w.t w.t ww
.t w.t w.t
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ww atarting with ww 0.5 mole of wwPCl5 , the total ww number ofwmoles of reactants
ww and products
ww at ww
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a)ww.tn0.5-X n b)
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w. t w. t w. t w. t w. t w. t
9.Which one of the following binary liquid mixtures exhibit positive deviation
alv
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t
fromalvRaoult‟s i.ne
t
lawal?vi.net a lvi.
net
a lvi.
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a lvi.
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n k .tn k .tn k n k n k n k n k
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lvi. lvi. lvi.
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w.t
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i.ne
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i.ne
t 7708543401
i.ne
t Page 24
i.ne
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alv nka
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t t
11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
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.tnk .tnk w.t
n k .tnk .tnk .tnk .tnk
11.The
ww
w IUPAC wname
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ww ww
w
ww
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ww
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i.ne vi.n lvi.
n vi.n vi.n lvi.
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ww
w
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w
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w Is ww
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ww
w
ww
w
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a) 2-ethylbut-2-enoic acid b) 3-ethylbut-3-enoic acid
t t t t net t t t
i.ne i.ne i.ne i.ne lvi. i.ne i.ne lvi.
ne
alv c) .tnk3-ethylbut-2-enoic
alv n k alv acid n k alv n k ad) 2-ethylbut-3-enoic
n k alv acidn k alv nka
w w.t w.t w .t w .t w .t w.t
12.Match the following
i.ne
t 1) -NH2 i.ne
t
i.ne
t i) Sulpho-
i.ne
t
i.ne
t
i.ne
t
i.ne
t net
t nk t n k t nk t n k t n k tn k nka
2)
w. -CN www. w. ii) Formyl w. - w. w. w.t
3) -SO3H iii) Amino -
t t t net net net net et
i.ne 4).tnkalv-CHOi. n e
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lvi.iv) Cyano -kalvi. lvi. lvi. vi.n
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w .tn w.t
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a) 1)- i) , 2)-wii) , 3)- iii), ww 4)- iv) ww
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a) -CH2CH3 b) -F c) -Cl d) -NO2
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(A) innkthe i.n e n e
: nkalvi.ne
alv nka
lvi.
nka
lvi. alv following nka
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lvi.
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lvi.
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alv
alv
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15. Assertion : Increasingt order of boiling points of halo alkanes are
i.ne . n et . n e . n et .n et i.ne
t
i.ne
t net
alv k alv
i
CH k lv
aCl
i
< CH Clk alv
i
< CHCl k
i
alv < CCl k alv k alv a lvi.
w.t
n
w.t
n 3 2
w.t
n 2 w.t
n 3 4
w.t
n
w.t
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w .tnk
Reason : The boiling points of halo alkanes increase with increase in the
i.ne
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n k a n k a n k a n k a n k a n k a
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t
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t 7708543401
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alv nka
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t t
11TH
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CHEMISTRY
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PUBLIC
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QUESTIONS
et t
i.ne
t
vi.n
et i. net
lvi.
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lvi.
net vi.n
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w
ww
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16.What is meant by limiting reagents ?
i.ne i.ne .ne
alv 17.Staten k a lvHeisenberg”s
n k a lviuncertainty
.tn k aprinciple
lvi.
n k a lvi.
n k a lvi.
n k a lvi.
n k a lvi.
w.t w.t ww w.t w.t w.t w.t
18.Give an example for ionicwhydride and covalent hydride.
i.ne
t 19.Whatviis .ne path function
t
i.ne
t? Give two examples
i.ne
t . vi.net i.ne
t
i.ne
t
i.ne
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w.t
20.Define reaction w.tquotient w.t w.t w.t w.t w.t
21.50g of tab water contains 20 mg of dissolved solids. What is the TDS val;ue in ppm?
t t t t t t t t
i.ne 22.How i.ne i.ne ethane by lvKolbe”s i.ne i.ne i.ne i.ne i.ne
alv nk alvwill you prepare n k alv nk a electrolytic
nk alv method n k alv ? n k alv n k alv
w. t . t . t w. t w.t w. t w. t
ww ww ww
23.Mention anywtwo methodswof preparationwwof haloalkanes ww
from alcohols. ww ww ww
i.ne
t 24.If an automobile net
engine net
burns petrol net
at a temperature net
of 1089i.nK et and if the isurrounding
net net
alv k a lvi. k a lvi. k a lvi. k a lvi. k a lv k a lv . k a lvi.
n
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is w294 K , calculate n its maximum n possible efficiency n . www.tn n
w.t w.t w.t w.t w.t
PART-III
t t t t net net t net
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i. n e
following n e
lvi any six questions
. lvi . n e
lvi. lvi. 6 lvXi.ne 3 = 18 lvi.
w.t .tn w.t
n
w.t
n
w.t
n
w.t
n
w.t
n
ww ww ww ww ww ww
25.calculate thewempirical formula of a compound containing 76.6% carbon, 6.38%, ww ww
t hydrogen et and rest of etoxygen. t t t t t

i.ne vi.n vi.n i.ne i.ne i.ne i.ne i.ne
alv k a l k a l k alv k alv k alv k alv k alv
26.compare
w.t
n the ionisation
w.t
n energyw.t of beryllium
n
w.t and boron ww.t
n n
w.t
n
w.t
n
27.Distinguish between diffusion and effusion.
alv
alv
i.ne
i.ne
t
t
28.At particular
ww
w.t
kal
Calculate
w.t
n k
n
H2S(g)
a
wwi) 2H2S(g)
vi.n
lvi.
et
Tnkalvi.Net
temperature
ww
net Kc for each
ww
w.t
n
w.t
k a
n kal
lvi.
vi.n
et
Kc = k4X
et the following
nof
2H2(g) w.t
n k
ww + S2(g)
a
w.t
ww 1
H2(g) +
lvi.
n
2
i.ne
S2(g)
net reactions.
ww
w.t
n
t -2
alv 10 for the
k a lvi.
ww
net
kal
w.t
n
i.ne
t
vreaction
kal
ww
ww
vi.n
w.t
w
et
n
.tnk
alv
i.
kal
net
vi.n
ww
ww
et
w.t
w.t
n
nka
lv
kal
vi.n
i.ne
t
et
ww
ww
w.t
w.t
n
nka
l vi.n
e t
ww
ww
3
t ii) 3H2.nSet(g) net
3H2(g) + t S2(g) et et et et
i.ne vi lvi.
ne
lvi.2 vi.n vi.n lvi.
n vi.n
alv al a a al al nka al
.tnk .t n k .tnk .tnk .tnk .t .tnk
29.What
ww
w are thewconditions
ww when
ww
w a solution tends
ww
w to behavelike
ww
w an ideal solution? ww
w
ww
w
ww
30.Describe fajan‟s Rule
t t net t t t t net
i.ne i.ne lvi. hyper conjugation i.ne i.ne i.ne i.ne lvi.
alv 31.Writen k alv short notes n k aon n k alv n k alv n k alv n k alv
.tnk
a
w.t w.t ww
.t w.t w.t w.t w
32.Explain Brich reduction w
i.ne
t 33.Give van i.ne
texample forneach
i. e
t of the vfollowing
i.ne
t typevi.nof et organic compounds i.ne
t
i.ne
t
i.ne
t
alv n k al n k alv n k al n k al n k alv n k alv nk alv
t t t t t t w.t
ww
i)
w. Non-benzonoid
ww
w. aromatic ww
compound
w .
ww
w.
ww
w.
ww
w.
ww ww
ii) Aromatic heterocyclic compound
i.ne iii) lvi.
carbocyclic lvi.
compound lvi. lvi. lvi. lvi. lvi.
alv k a k a k a k a k a k a ka
.tnw .tn w .tn w .tn w.tn .tn w w w .tn
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 26
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
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w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
i.ne
t
vi.n
et i. net
lvi.
net PART-IV
lvi.
net vi.n
et i. net vi.n
et
.tnk .tnk w.t
ANSWER
ww
w ALLwwTHE
w QUESTIONS
ww ww
w
ww
w 5 X 5 = 25 ww
w
ww
w
ww
34. a) i) Describe about magnetic quantum number ?
t t net net net net net net
i.ne .ne
lviGive lvi. lvi.
2+
lvi. and Cr
3+ lvi. lvi. lvi.
alv n ii)
k a the electronic
n k a configuration
n k a of Mn n k a n k a n k a n k a
(OR)
i.ne
t b) i) What i.ne
t are f-block i.ne
t elements ? net
i. i.ne
t
i.ne
t
i.ne
t
i.ne
t
w.tii) State theww .t
trends w.t
in thewwvariation w.t
of electronegativity w.tin group and t
w.periods w.t
ww w ww ww ww ww ww
35. a) Discuss the similarities between lithium and magnesium
t t t t t t t t
i.ne i.ne i.ne i.ne (OR) i.ne i.ne i.ne i.ne
alv nk alv n k alv nk alv nk alv n k alv n k alv n k alv
w. t w. t . t w. t w. t w. t w. t
b) i) Define entropy .Give wits unit.
i.ne
t ii) Listi.ne
t any three characteristics
i.ne
t
i.ne
oft gibbs freei.nenergy. et i.ne
t
i.ne
t
i.ne
t
alv a lv alv nka
lv a lv alv nka
lv a lv
w ww ww w
ww www w ww w ww w ww ww
36. a) Derive KC and KP for synthesis of ammonia
t net net net net net et et
i.ne lvi. lvi. lvi. (OR) lvi. lvi. lvi.
n vi.n
alv k a k a k a k a k a nka al
w.t
n
w.t
n
w.t
n .tn w.t
n .t .tnk
wwb) Discuss the ww formation of wwC moleculewusing ww ww ww
w
ww
w
ww
2 MO theory
i.ne vi.n lvi.
n
37. a) mention the shape of the following molecules based on VSPER theory
alv
alv
i.ne
i.ne
t
t
ww
w. t n k ali)
b) Describe
w w w.tnk
alv
et
vi.nBF3
et
Tnkalvi.Net
ii) BrF
ww
w. tn k alv 3
any two types

i.n
ww
t
et
w.t
ww
nka
w. t n k a
net SF
i.ne iii) PCl5 lvi.iv)
of constitutional
l vi.n
et
6
ww
w.
(OR)
ww
w
v)kaIF
t n
net
lvi. 7
isomers.
.tnk
al
et
ww
vi.n
w. t n k alv
ww
i.ne
et
w
t
ww
w.
.tnk
t
alv
n k
i.n
alv
i.ne
et
t
ww
w .tnk
alv
i. n
ww
w.t
nka
lv i.n
ww
ww
w.t
w.t
nk
nka
l
alv
vi.n
i.ne
e
t
t
ww
ww
38. a) An organic compound (A) C2H4 decolourises bromine water. (A) on reaction with
t net net t et (C) . identify net (A), (B) and net (C) explain net
alv
i.ne chloride
k a lvi. giveska(B) lvi. . (A) reacts k a lviwith
.ne HBr tokalgive vi.n
k a lvi. k a lvi. k a lvi.
n n n n n n n
ww the reactions.ww ww ww ww ww ww ww
t et et et
(OR) et t t t
alv b) n k a l
Starting from nCH
k al
MgI , how n k al
will you prepare
n k alv the following n k alv ? n k alv n k alv
w.t w.t 3 w.t w.t w.t w.t w.t
i) Acetaldehyde ii) Acetone iii) Methane
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk
ww ww ww ****************
ww ww ww ww ww

l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 27
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t

w .tnk w .tnk w.t
n k
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne

i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne

alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
n k
w .t w .tnk
alv
i.ne
t
al vi.n
et UNITWISE PUBLIC QUESTIONS
a lvi.
n et
lvi.
net
lvi.
net
lvi.
net
lvi.
net
lvi.
net
.tnk .tnk nka .tnk
a nka .tnk
a nka
w w w.t w w.t ww w.t
alv
alv
i.ne
i.ne
t
t
ww
w w
w.t
w
nk
.tnk
alv
alv
Tnkalvi.Net
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nka
nka
l
lvi.
vi.n
n et
et
ww
ww
w.t
w
nk
.tnk
al
alv
i.ne
vi.n
t
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.ne
i.n
t
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.
i.ne
net
t
ww
ww
w.t
w.t
nk
nka
alv
lv
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
n vi.n

w .t n
w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
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i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
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Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
alv
i.ne
t
1.Basic Concepts Of Chemistry And Chemical Calculations
al vi.n
et
alv
i. net
a lvi.
net
al vi.n
et
al vi.n
et
alv
i. net
al vi.n
et
w .tnk w .tnk w.t

n k
t net
alv
i.ne ONE MARKS k a lvi. ;- kalvi.net k a lvi.
net
k a lvi.
net
k a lvi.
net
k a lvi.
net
k a lvi.
net
n n n n n .tn n
w.t
1.which w.t
of the following w.t
compound has same w.t w.t w.t
ww ww ww ww percentage wwof carbon aswthat ww of ethylene ww ww
t
(C2H4) ?t (mar 19) t t t t t t
i.ne vi.n
e i.ne i.ne i.ne i.ne i.ne i.ne
alv a)
n k albenzene n k alv n k alv n k alv b) ethane n k alv n k alv n k alv
c) propene d) ethyne
i.ne
t 2.The oxidation i.ne
t number i.neof carbon in
t
i.neCH2F2 is ______
t
i.ne
t (jun19)lvi.net i.ne
t
i.ne
t
alv n k alv n k alv nk alv nk alv n k a n k alv n k alv
t
w. a) +4 w. t w. t w. t w. t w. t w. t
ww ww ww ww b) -4ww ww ww ww
c) 0 d)+2
t t t t t net net net
i.ne vi. ne ne
lvi. mass of ethanol lvi.
n e
lvi.
n e
lvi. lvi. lvi.
alv 3.The.tnrelative
kal molecular
.tn k a
.tn k a is ___.tn k (sep20)
a
.tn k a
.tn k a
.tn k a
w w w w w w w
a) 0.46g b) 4.6 g
t t t t t net et et
i.ne c) . n e
lvi 460g lvi . n e
lvi . n e . n e
lvi d) 46g lvi. lvi.
n vi.n
alv k a k a k a k a k a nka al
.tn w.t
n
w.t
n
w.t
n
w.t
n .t .tnk
ww w w
4.wWhich one ofwwthe followingwwof presents 180g ww of water ?ww(sep21) ww ww ww
t t 6.022 X 10 24 t
i.ne a) i.ne i.ne moles of awaternet net b) 5 moles t
i.ne of water lvi.ne
t net
alv alv 180.tnkalv lvi. a lvi. alv a lvi.
.tnk nk .tnk nk .tnk nka
ww c) 6.022 wwX 1024 moles ww of water ww w
wd) 90 moles of w water ww ww
Tnkalvi.Net
t 5.Which of et the following et compound(s) et has/have percentage et of carbon et same as.nthat et in t
i.ne vi.n vi.n vi.n vi.n vi.n vi i.ne
alv k a l k a l k a l k a l k a l k a l k alv
ethylene
ww
w. t n (C2Hw4w)w?. (sep21) www.
tn t n
ww
w. t n
ww
w. t n
ww
w. t n
ww
w. t n
ww
a) benzene b) propene c) ethane d) ethyne
t t t t t t net net
i.ne 6. Total lvnumber
i. n e
of electrons
lvi.
n e
present n e
lvi.in 1.7 g of kammonia lvi.
n e
is : (jul22)
lvi.
n e
lvi. lvi.
alv n k a n k a n k a n a n k a n k a n k a
w.t w.t ww
.t w.t ww24
.t w.t w.t
ww ww23 w6.022𝑋 10 22 ww 6.022𝑋w10 ww6.022𝑋 10 23 ww ww
a) 6.022 X 10 b) c) d)
1.7 1.7 1.7
t t net t net t et et
i.ne lvi.
ne
lvi. lvi.
ne
lvi. lvi.
ne
lvi.
n vi.n
alv a a a a a nka al
w .tnk w.t
n k
w .tnk w .tnk w .tnk w .t w .tnk
ww
2&3&5 MARKS ww :- ww ww ww ww ww ww
t 1.Calculate
net
the equivalent
net
mass of H2nSO
et 4
(mar 19).(ipn
net
: 9) t net net
i.ne i. i. i. lvi. i.ne lvi. lvi.
alv alv alv alv a alv a a
.tnk .tnk .tnk .tnk .t n k .tnk .tnk
2.wcalculate
ww oxidation
ww
w numberwwofw oxygen in wH
ww2O2 (mar 19).
ww (ipn : 21)
w
ww
w
ww
w
ww
t 3.A compoundt having the t empirical formula

t C6H6O thas the vapour t density 47.neFind
t its t
i.ne .ne .ne
i .ne .ne i .ne .
lvi i i i i.ne
alv alv alv nka alv alv alv alv
w .tnk w.t
nk
w.t w.t
nk
w.t
nk
w.t
nk
w.t
nk
molecular formula.
ww ww (mar 19).(b/b-42)
ww (ipn
ww: 247) ww ww ww ww
i.ne
t 4.What do
i.ne
you
t understand
i.ne
t by the term
i.ne
tmole ? (jun19)(b/b-27)
i.ne
t (ipn
i.ne
t : 6) et net
alv alv alv al v al v alv al vi.n a lvi.
w .tnk .tnk .tnk .tnk .tnk .tnk .tn k
5.What
ww ww
are autowredox rections w w
ww? give an example
ww .(jun19)
w (ipn : 23) w w
ww
w
ww
w
ww
i.ne
t 6.Definevibasicity.Find
.ne
t the
vi.n
et basicity ofi.northo-phosphoric
et
vi.n
et Acid.(sep20)
vi.n
et i. net vi.n
et
alv al v al al al al alv nka
l
w .tnk w .tnk + w .tnk w.tnk w .tnk w .tnk w.t
ww ww no. of moles
Basicity is ww of ionisable
ww H ions present
ww ww
in 1 mole of the acid w w ww
et t t t t net
-1 t net
i.ne
ortho-phosphoric i.ne Acid H PO i.ne H3PO i.ne i.ne
a4lv basicity = a3
lvi.eq mol
i.n lvi.
alv k alv k alv 3
k alv 4 k k k alv a
w. tn t n
w. t n
w. tn
w. t n t
w.
n
w. w .tnk
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
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t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
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ww ww
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Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
7.Calculate the empirical formula and molecular of a compound containing 76.6%
t t t t t t t t
i.ne carbon,6.38%ne vi.n
of nhydrogene
andnkresti.ne i.ne ne ne ne
alv nka
lvi. kal alv oxygen. Its
nka
lvvapour density
nka
lvi. is 47. (sep20)
nka
lvi. (b/b-42) kalvi.
n
(ipn : 247)
t et et et et et et t
i.ne 8.What vi.nthe empirical i.n n
lvi. following vi.n i.n vi.n i.ne
alv alis alv formula of athe al? (sep21)(b/b-38)
alv al alv
.tnkw .tnk .tnk
w .tnk w.tnk w w w .tnk w .tnk
a) Fructose (C6H12O6) ii) Caffeine ( C8H10N4O2)
t et et et et et net t
i.ne i.n i.n i.n vi.n i.n lvi. lvi.
ne
alv 9. Distinguish
.tnk
alv between
.tnk
alv oxidation nand
.t k
alv reductionnk.al(sep21)
.t
(b/b-30)
.tnk
alv
.tnk
a nka
w w w w w w w.t
10..Define Gram equivalent mass (May22) (b/b-28) (ipn :8)
t t t t t t net net
i.ne lvi .ne lvi lvi .ne
lvi lvi .ne .ne .ne lvi. lvi.
alv 11.Calculate
nka the oxidation
nka number nkaof underlined nka elements . .(May22)
nka nka nka
w.t w.t w.t w.t wt w.t w.t
i) CO2 ii) H2SO4
alv l al al al l
i)wCO w.t
nka2
w.t
nka
w .tnk w.t
n k a
w.tnk w .tnk w.t
nka
t t
x+2(o) =et 0 et et
i.ne vi.n
e
vi.n n vi.n net n et
vi.n
et
alv kal al lvi. al lvi. lvi. al
n .tnk nka .tnk n k a nka .tnk
w.t .t w.t .t
ww x +ww2(-2)
w
=0 ww
w
ww
w
ww ww
w
ww
w
ww
alv
i.ne
t
al vi.n
et x-4
alv
i.n=
et 0
lvi.
net
lvi.
net
lvi.
net
lvi.
net
lvi.
net
.tnk .tnk nka .tnk
a nka .tnk
a nka
x = +4
alv
alv
i.ne
i.ne
t
t
ww
w.t
ii) H2SO4t
w w w
nka
.tnk
lvi.
oxidation
alv
n
Tnkalvi.Net
et
number
w.t
i.ne
nka
n
lvi. of carbon
ww
ww
w.t
nka
lvi.
l
n
nka is +4
vi.n
2(H)+x +4(o) = 0
w.t
et
et
ww
ww
w .tnk
al vi.n
et
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.ne
i.n
t
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.
i.ne
net
t
ww
ww
w.t
w.t
nk
nka
alv
lv
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
i.ne
t
vi.n
et 2(+1)+x
lvi.
net +4(-2) = v0
l i.
net vi.n
et
vi.n
et
lvi.
n et
vi.n
et
alv al a a al al nka al
ww ww
2+xww-8 = 0 ww ww ww ww ww

i.ne i.ne x-6 = i.ne i.ne
alv 0
i. lvi. lvi. lvi.
alv k alv alv a alv a a
w .t n
w .tnk .tw
n k
w .tnk w .t n k
w .tnk w .tnk
x =+6
et i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
alvi.n alv alv alv alv alv alv alv
oxidation number
ww
w .tnk
ww
of sulfur
ww
is +6 w.t
nk
w. tn k
ww
w.t
nk
ww
w.t
nk
ww
w.t
nk
ww
w.t
nk
ww
t
12.What isetmeant by limiting
et
reagentset? (jul22) (ipnet: 17)
i.ne i.n i.n vi.n vi.n i. net vi.n
et net
alv alv alv al al alv al a lvi.
.tnk .tnk .tnk .tnk .tnk .tnk .tn k
13.calculate
ww
w thewempirical
ww formula
ww
w of a compound
ww
w containing
w 76.6% carbon,
ww
w 6.38%, www w w
ww
et
hydrogen
net
and rest ofnetoxygen. (jul22)
net
(b/b-42) (ipn
net
: 247) et net et
i.n i. vi. i. vi. vi.n i. vi.n
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 30
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
2.Quantum Mechanical Model Of Atom
w .tnk w .tnk w.t
n k
ONE MARKS ;-
alv
i.ne
t 1.Splittinga lvi.
neoft spectralalvlinesi.ne
t in an electric
a lvi.
net field is called
a lvi.
net _____ (mar a lvi.
net 19)
a lvi.
net
a lvi.
net
nk n k nk .tn k n k n k n k
ww a) Compton wweffect ww wb)
ww stark effect ww ww ww ww
t
c) Zeeman effect t d) shielding effect
i.ne . n et . n e . n et . n et i.ne
t
i.ne
t
i.ne
t
alvis –E . Thenenergy
i i i i
alv 2.The n k alv
energy of an n k alv
electron in the n k alv
third orbit of n alv
hydrogen
k atom n k k alv of an n k alv
electron in the first orbit will be _____ (jun19)
t 𝐸 𝐸
i.ne net
a)kalvi.-3E i.ne
t
b) - i.ne
t
c) vi-.n
et i. net d) -9E vi.n
et net
alv lv alv kal alv kal lvi.
n nka 3 .tnk n 9 nk n nka
w w.t w w.t ww w w.t w.t w.t w.t
w ww w ww ww
3.The maximumw number of electrons
w w
that can w
be accommodated in L orbit is _____(sep20)
t t t t t t t t
i.ne a) lv8 i.ne lvi.
ne b) 2
lvi.
ne c)lvi4.ne lvi.
ne d) 6nkalvi.ne lvi.
ne
alv nka nka nka nka nka nka
w . t w . t . t . t . t . t . t
ww ww ww w
ww is called : (May22) ww
w
ww
w
ww
w
ww
4.Splitting of spectral lines inwan electric field
t a) Compton net
effect net net
b)neZeeman
t effect net net net
w.c) Stark effect n d) Shielding
tn w.t effect
n n n n n
w.t w.t w.t w.t w.t
5. The total number of orbitals associated with the principle quantum number n=3 (jul22)
t
alv
i.ne a)kalv9i.net k alv
t
i.ne b) 8
k alv
i.ne
t
k ac)
net
lvi. 5 k alv
i.ne
t
d) 7kalvi.net k alv
i.ne
t
n n n n n n n
ww
2&3&5 MARKS ww :- ww ww ww ww ww ww
Tnkalvi.Net
t 1.state andetexplaine pauli‟s et
exclusion eprinciple. t (maret 19).(b/b-31)et(ipn :52 ) et t
i.ne vi.n vi.n vi.n i.n i.n i.n i.ne
alv a l a l a l alv alv alv alv
2. Write
w. t n k the de-broglie
w. t n k equation. w. t (mar
n k 19). (ipn
w. t n :
k 40 ) w. t n k
w. t n k
w. t n k
ww ww ww ww ww 2 2 ww ww ww
3. Define orbital.What are the n and l values for 3px and 4dx -y electron ? (jun19)
t net net
alv
i.ne (b/b-32) k a lvi. (ipnkal:vi.44,257 ) kalvi.net k a lvi.
net
k a lvi.
net
k a lvi.
net
k a lvi.
net
.tn .tn .tn w.t
n .tn w.t
n
w.t
n
ww
4.wcalculate ww
the wuncertainty ww position of
inwthe ww an electron,wif wwthe uncertainty ww in its velocity
ww is ww
5 -1
t
5.7 x 10et ms (jun19)et (ipn : 43,252et)EY :2
i.ne n n n net net net net
5.Calculate
w.t
n k a the orbital
w.t
n k a angular momentum
w.t
n k a for
w.t
dn kand
a f orbital.
w.t
n k(a jun19) (compulsory
w.t
n k a 2 mark)
w.t
n k a
ℎ
Angular momentum = 𝑙(𝑙 + 1)
t t t 2𝜋 t
i.ne i.ne i.ne ne net i.ne
t net net
alv orbital alv lv lvi. lvi. alv lvi. lvi.
nk angular momentum forw.dt nka nka .tnk
a n k .tnk
a
.tnk
a
w.t w.t w w .t w w
l=2
t t t t ℎ et t t t
alv
i.ne
alv
i.ne lv i.ne = 2(2 + 1)
alv
i.ne vi.n alv
i.ne
alv
i.ne
alv
i.ne
.tnk nka n k 2𝜋.tnkal nk nk nk
w w.t w. t w w.t w.t w.t
ww ww ww ℎ ww ww ww ww ww
= 6
2𝜋
t et et et et net et net
i.ne orbital angular momentum
vi.n for fnkal=3 vi.n vi.n vi.n i. vi.n lvi.
alv kal l kal al alv al a
n
w.t
n
w.t w.t .tnk .tnk .tnk .tn k
ww ww ww w wwℎ ww w
ww
w
ww
w
ww
= 3(3 + 1)
2𝜋
i.ne
t e t net ne t ℎ et et net et
alv vi.n lvi. = 12 lvi. vi.n vi.n alv
i. vi.n
n kal .tnk
a nka .tnk
al
.tnk
al
.tnk nka
l
w.t w w .t 2𝜋 ww w w w.t
ww ww ww ww ww w ww
ℎ w w
=2 3
t t t t 2𝜋 net et net net
i.ne i.ne i.ne i.ne ℎ lvi. vi.n lvi. lvi.
alv nka
lv
nka
lv alv nka al nka a
w.t w.t w = 3
.t nk
w.t w .tnk w.t w .tnk
ww ww ww 2𝜋 ww ww ww ww ww
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 31
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
6.In degenerate orbitals, why do the completely filled and half filled configurations are more
i.ne
t stablelvthan
i.ne
t the partially
lvi.
net filled configurations
lvi.
net ? l(sep20)
vi.n
et (compulsory
lvi.
net 2 mark)
lvi.
net
lvi.
net
The stability of exactly half-filled orbitals in degenerate orbitals is stronger than that of other
t t net et net net t net
i.ne i.ne lvi. vi.n be explained lvi. using symmetry lvi. i.ne lvi.
alv partiallyn k a lvfilled configurations.
n k a This n k a lcan
n k a n k a and then k a lvconcept of n k a
exchange energy . half and completely-filled subshells become more stable because of the
i.ne
t symmetrical i.ne
t distriburion
i.ne
tof electron. net
i. i.ne
t
i.ne
t
i.ne
t
i.ne
t
w.t
Reason :- w.t w.t w.t w.t w.t w.t
i) Symmetrical distribution of electron in orbital
t t t t t t t t
i.ne i.ne i.ne energy i.ne i.ne i.ne i.ne i.ne
alv nk alvii) Exchangen k alv nk alv nk alv n k alv n k alv n k alv
. t
w . t w . t w . t w.t . t
w . t w w
i.ne
t 7.State Heisenber‟s net
Uncertainty
net
Principle net
. (sep20)i.n(ipn et : 42 ) i.net net net
alv k a lvi. k a lvi. k a lvi. k a lv k a lv k a lvi. k a lvi.
n
8.Calculate .tn
the wtotal .tn tn n present in 3d n and 4f orbitals. n
ww
w.t ww number of ww
wangular nodes
ww
w.and radial nodes
ww
w.t
ww
w.t
ww
w.t
ww
(sep20) (b/b-28) (ipn : 257 )
t et net net net net net net
i.ne 9.What vi.nexchange energy
lis lvi. ? (sep21) lvi. (ipn :56 ) kalvi. lvi. lvi. lvi.
alv n k a n k a n k a n n k a n k a n k a
ww
10.State Aufbauwwprinciple (sep21) ww (ipn : 52ww) ww ww ww ww
t 11.Write .anenote t on principal et quantum.nenumber t (sep21) et (ipn : 44 )i.net t t

i.ne vi vi.n vi vi.n i.ne i.ne
12.Calculate
w.t
n the wmaximum
w.t
n number
w.t
n of electrons w.t that can be
n
waccommodated
.t n
w.t in L
n
w.t
n
shell(May22)
alv
alv
i.ne
i.ne
t
t
ww
Thekalvmaximum
w.
w.t
t n
L shell
n ka lvi.
i.ne
wwshell is 2n . ww
Tnkalvi.Net
net
t
2 w.
number
tn
is n = 2 et
ww
w.=
k alv
a lvi.
tn 2 (2)
k
i.ne
n
t
2
of electrons
ww
ww
w.
w.t
t n
n
k
k
alv
a lvi.
net
t
i.ne that can be
ww
ww
w.
w.t
t
n
n
k
k
a lvi.
i.ne
net
t
alv accommodated
ww
ww
w.
w.t
t
n
n
k
k
a
alv
lvi.
net
t
i.ne in a givenlvi.ne
ww
ww
w.
w.t
t
n
n
k
k
a
a
lvi.
net
t
ww
ww
w.
w.t
t
n
n
k
k
a
alv
i.ne
lvi.
net
t
ww
ww
=8
t t t net can be accommodated net net net net
alv
i.ne maximum k a lvi.
ne number k alviof.ne electrons that
k a lvi. k a lvi. k a
in
lvi. L shell = 8kalvi. k a lvi.
n n n .tn n n n
13.How
ww many orbitals
ww are possible
ww for n=4 w?ww(May22) (b/b-27)(ipn ww : 256
ww ) ww ww
t
14. Write the et
electronic configuration
et
and orbital diagram
et et
for nitrogen et
? (May22) et
(ipn :54 ) et
i.ne vi.n vi.n vi.n vi.n vi.n vi.n i.n
.tnk Heisenberg”s .tnk uncertainty .tnkprinciple (jul22)
alv 15.State l l l l
(ipn : 42 l l alv
.tn)k
a a a a a a
w w w w .tnk w w .tnk w .tnk
16. Describe about magnetic quantum number ? (jul22) (ipn : 45 )
2+ 3+
alv
i.ne
t 17.Givealvthe i.ne electroniclviconfiguration
t
a
.ne
t
alv
i.of
net Mn and Cr
alv
i.ne
t (jul22) (b/b
alv
i.ne : 39 )
t
alv
i.ne
t
alv
i.ne
t
nk nk nk nk nk nk nk
2+ 2 2 6 2 6 0 5
t
Mn 1st 2s 2p 3s 3p 4s 3d
i.ne et 3+ alvi.ne 2 6 alvi.2ne
t
3lvi.ne
t net et net
alv vi.n 2 6 0 alv
i. vi.n lvi.
nkal Crw.tnk 1s 2s 2p n k 3s 3p 4s 3d nk a
.tnk .tnk
al
.tn ka
w.t w.t w.t w w w
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 32
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
3.Periodic Classification Of Elements
w .tnk w .tnk w.t
n k
ONE MARKS ;-
alv
i.ne
t 1.The elementa lvi.
net with positive
a lvi.
net electron a lvi.
ngain
et enthalpy a lvi.
nis
et _____ (mar
a lvi.
ne19)
t
a lvi.
net
a lvi.
net
ww a) Argon ww ww wwb) Fluorine ww ww ww ww
t
c) Hydrogen d) sodium
i.ne i . n et i . n et i . n et i.ne1
t
i.ne
t
i.ne
t
i.ne
t
alv 2.The n k alv
effective nuclearn k alv charge experienced n k alv by the
n k alv d electronnkin alv the given electronic
n k alv n k alv
ww ww 2 8w
w 8 w1w 2 ww ww ww ww
configuration, (1s) (2s,2p) (3s,3p) (3d) (4s) is : (jun19)
i.ne
t a) lv4i.net i.nb) et 3 i.ne
t c) 2.1lvi.net i.ne
t d)lvi.6.9net i.ne
t
alv nk a n k alv nk alv nk a n k alv n k a n k alv
w. t w. t w. t . t w.t . t w. t
3.Assertion
ww : Helium
ww has the highest ww value wofwwionisation energy
ww among wall ww the elements ww ww
known.
t t net et net net net net
i.ne n e
lvi. : Helium has lvi. the highest vi.n lvi. affinity among lvi. lvi. lvi.
alv Reason n k a n k a n k a lvalue of electron
n k a n k a all the nelements
k a known. n k a
(sep20)
i.ne
t a) Both net assertionvi.and net reason are nefalse
t net net net net
alv k a lvi. k a l k a lvi. k a lvi. k alvi. k a lvi. k a lvi.
tn
w.b) w.t
n n
w.t are true and
n
w.tthe reason is .tn w.t
n
w.t
n
ww
Both assertion ww
and reason ww ww ww
wcorrect explanation
ww
for the
ww ww
assertion
t t t net t t t t
i.ne c) i.ne i.ne lvi. true but the i.ne i.ne i.ne i.ne
alv n k alvBoth assertion n k alv and reason n k aare n k alv reason is not n k alv the correctnkexplanation
alv for
n k alv
w.t ww
.t w.t w.t w.t w.t w.t
the wassertion
Tnkalvi.Net
i.ne
t d) Assertion et is true et and reason etis false . i.ne
t
i.ne
t
i.ne
t
i.ne
t
alv a l vi.n a l vi.n a l vi.n alv alv alv alv
2&3&5
ww
w. t MARKS ww
w:-
. t
ww
w. t
ww
w. t
ww
w. t
ww
w. t
ww
w. t
ww
t
1.Explain diagonal
et
relationship
et
(mar 19)
et
(b/b-41) (ipn
et
: 90)
i.ne i.n vi.n vi.n i.n i. net i.ne
t
vi.n
e t
alv alv nka
l al alv alv nka
lv
nka
l
2.State w.tnk
and explain Dobereiner”s “triad” (mar
w.t w 19) (ipn :69w) w .tnk .tnk .tnk w.t w.t
w w ww ww ww ww ww ww ww
t 3.Ionisation
et
potential of enitrogen
t is greater
et
than thatetof oxygen . explain
et
by giving
et et
i.ne vi.n i. n vi.n vi.n vi.n lvi.
n vi.n
.tnk .tnk .tnk .tnk .tnk .t .tnk
ww
w appropriate wreason.
ww ( jun19)(b/b-44i)
ww
w (ipn
ww : 85 )
w
ww
w
ww
w
ww
w
ww
t 4.Give thenegeneral
t electronic
net
configuration
net
of lanthanides
net
and actinides.
net
( jun19)
net
(b/b-36) net
i.ne i. i. i. lvi. i. lvi. lvi.
.tnk .tnk .tnk .tnk .tnk .tnk .tnk
ww (ipn
w :78 ) ww
w
ww
w
ww
w
ww
w
ww
w
ww
w
ww
i.ne
t 5.Derive iionic
.ne
t radius using
i.ne
t pauling‟si.nmethod
et . (sep20)
i.ne
t (b/b-39) i(ipn
.ne
t : 83)
i.ne
t
i.ne
t
alv alv alv nka
lv alv alv alv alv
w .tnk w.t
nk
w.t w.t
nk
w.t
nk
w.t
nk
w.t
nk
6. Explain why wthe
ww w electron affinity
ww of Be and
ww N is almost
ww zero(sep20)ww
(ipn : 86) ww ww
i.ne
t 7.Define ielectronegativity.
.ne
t
i.ne
t State the trends
i.ne
t in the variation
i.ne
t of electronegativity
i.ne
t int
i.ne net
alv alv alv al v al v alv al v a lvi.
w .tnk w .tnk .tnk .tnk .tnk .tnk .tn k
ww group and period
ww (sep21)www(b/b-47) (ipn w
ww:87,88 ) ww w
ww
w
ww
w
ww
i.ne
t 8.Definelviatomic
.ne
t radius.
lvi.
n(sep21)
et (ipnlvi.:ne79
t ) vi.n
et
vi.n
et i. net vi.n
et
alv a a a al al alv nka
l
ww
9.Explain ww relationship
diagonal ww (sep21) (ipn
ww : 90 ) ww ww w w ww
i.n et 10.Define
lvi.
neelectron
t affinity
lvi.
net (May22)vi(ipn
l .
net : 86 )
lvi.
net vi.n
et
lvi.
net
lvi.
net
alv nka a a nka al nka a
w.t w .tnk w .tnk w.t w .tnk w.t w .tnk
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 33
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
.t .t w.t w.t w.t.tnk .t
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
11.Describe the pauling method for determination of ionic radius . (May22) (ipn : 83 )
t t t t t et net et
i.ne 12.What .ne f-block elements
lviare lvi.
ne
? (jul22)
lvi.
ne
(ipn : 78nka)lvi.ne vi.n i. vi.n
alv nka nka nka al alv al
w.t w.t w.t w.t w .tnk w .tnk w .tnk
13. State the trends in the variation of electronegativity in group and periods (jul22)
i.ne (b/b-47) i.n (ipn :87,88lvi.n) vi.n vi.n lvi.
ne vi.n i.ne
alv alv a al al nka al alv
.tnk
w .tnk w w .tnk w .tnk w . t w .tnk w .tnk
14. define valency (mar 19) (ipn :88 )
i.ne i.n i.n i.n i.n i.n i.n i.n
alv 15.How
.tnk
alvwill you determine
.tnk
alv the ionic
.tnk
alv character nin
.t k
alvcovalent bond
.tnk
alv using electronegativity
.tnk
alv
.tnk
alv
w w w w w w w
values ? (May22)
t t t t t t t t
i.ne .ne
lvi estimatedkathe
lvi percentage lvi .ne lvi .ne
lvi A δ- – Bδ+ polar
lvi lvi.ne .ne .ne .ne
alv Pauling
nka n nka of ionic character
nka in various
nka nka covalentnka
bonds from known (XA–XB) values and has derived the following
alv conclusions :
nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
δ- δ+
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t t t t t net et et
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alv
alv
i.ne
i.ne
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t
ww
w w w
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t A
.tnk
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ww
Tnkalvi.Net
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ww
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i.ne
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i.ne
t ASST IN CHEMISTRY
i.ne
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i.ne
t 7708543401
i.ne
t Page 34
i.ne
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alv nka
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
alv n kalv n kalv nk alv nkalv nk alv nkalv nk alv
w
4.Hydrogen
ONE .tnk
w MARKS ;- w .tnk w.t
n k
1.What percentage of solution of H2O2 is called as “100-volume‟ H2O2 ? (mar 19)
i.ne
t a)vi.ne15% t net net neb)t 50% net net net
alv k a l k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi.
w.t c) 20% ww.t d) 30%
n n n n n n n
w.t w.t w.t w.t w.t
2.The type of H-bonding present in orthonitro phenol and p-nitro phenol are ______
i.ne
t Respectively. i.ne
t (jun19) i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
w.t a) Inter molecular w.t H-bonding
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ww ww ww ww molecular H-bonding ww ww ww ww
3.Intra molecular hydrogen bonding is present in________ (sep20)
t net Ortho-nitro net phenol net net b) Ice net net net
alv
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a)
lvi. k alvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi.
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d) Hydrogen w.t
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4.Assertion ; permanent hardness of water is removed by treatment with washing soda
i.ne Reasons lvi.: Washingkasoda lvi. reacts with lvi. soluble calcium lvi. and magnesium lvi. chloride lvi. and sulphate lvi.
alv n k a n n k a k a k a k a k a
w.t w.t w.t .tn w.t
n
w.t
n
w.t
n
ww ww water to form ww ww ww ww ww ww
in hard insoluble wcarbonates. (sep21)
i.ne
t a) Assertion i.ne
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i.ne
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5.Tritium
ww
6.Tritium
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n
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Tnkalvi.Net
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alv assertion and
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t
lvi. 1p+1n
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w.
w.t
t n
n
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lvi.
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ww
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i.ne i.n i.ne i.ne i.n i.n n net
alv a l v a l v a l v a l v a l v a lvi. a lvi.
2&3&5w.t
n MARKS :-
k
w.t
n k
w.t
n k
w.t
n k
w.t
n k
w.t
n k
w.t
n k
1.How is Tritium prepared ? (mar 19)(ipn : 104 )
i.ne
t 2. complete i.ne
t the following
i.ne
t equation (ipn
i.ne
t : 111 )
i.ne
t
i.ne
t
i.ne
t
i.ne
t
w.t
n k
Na2Ow2w.+ t ?
n k
 Naw2SO n k
w.t 4+ H2O2 (mar w.t 19)
n k
w.t
n k
w.t
n k
w.t
n k
ww w w ww ww ww ww ww
3.What is syn gas ? How it is prepared ? ( jun19) (ipn :103 )
i.ne
t 4.Why hydrogen i.ne
t peroxide i.ne
t is stored inneplastic
i.
t bottle i.ne
containers
t not i.ne
tin glass container
i.ne
t ? i.ne
t
(jun
ww
w. 19) (ipn : w112
t n
w
w. t n ) ww
w. t n
ww
w. t n
ww
w. t n
ww
w. t n
ww
w. t n
ww
5.Write the exchange reactions of Deuterium. (sep20) (ipn : 105 )
i.ne
t 6.How do lvi.
neyou
t convertlvipara .ne
t hydrogen lvi.
into
ne t ortho hydrogen.
lvi.
net (sep20) lvi.
net (ipn : 102v)i.net
lvi.
net
alv n k a n k a n k a k a k a k a l k a
7.Write
w.t the laboratory w.t methodwwof w.t preparation .tn hydrogen .w(sep20)
wof .tn (ipn tn
:w.103 ) w.t
n
8.How do you convert para hydrogen into ortho hydrogen ? (sep21) (ipn : 102 )
t 9.Mention t
nethe three types net of covalent et
nhydrides . a(May22) net (ipn a:lv113 i.ne )
t net net
i.ne lvi. lvi. lvi. lvi. lvi. lvi.
alv n k a n k a n k a n k n k n k a n k a
w.t
10.Give an example w.t for ionic hydride w.t w.t
and covalent hydride. w.t w.t w.t
ww ww ww ww ww (jul22) (ipn ww: 113 ) ww ww

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
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t
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t 7708543401
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t Page 35
i.ne
t
alv nka
lv
nka
lv
nka
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
5.Alkali And Alkaline Earth Metals
ONE .tnk
MARKS ;-ww .tnk w.t
www w ww ww
w
ww
w
ww
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1.Find A in the following reaction CaO + 3C A + CO (mar 19)
t t t t t t t net
i.ne a) . n
lvi CaC2
e
lvi . n e
b) CO lvi . n e
c) lvi Ca
. n e
lvi . n e
d) Ca i.ne
l2vO lvi.
alv k a k a k2a k a k a k a k a
.tn w.t
n .tn w.t
n
w.t
n
w.t
n
w.t
n
2.wwhich
ww compound ww is namedwas ww “blue john” wwamong the following ww compounds
ww ? (mar
ww19) ww
t
a) Ca 3(PO4)2 b) CaO t c) CaH 2 d) CaF2 t
i.ne i . n et i . n et i . n e i . n et i. n et i.ne i.ne
t
alv 3.When.t n k alvCaC2 is heated n k alv in atmospheric n k alv nitrogen n k ain
lv an electrickafurnace,
n
lv the compound
n k alv formedn k alv
ww w.t w.t w.t w.t w.t w.t
wis __________ ww (jun19) ww ww ww ww ww ww
t
a) Ca(CN) 2 b) CaNCNet c) CaC 2N2 d) CaNC2 et
i.ne i . net i . net i . n i . net i . net i.n i.ne
t
alv 4.Formula
. t nk al v of Gypsum. tn k al is ________
v
. t nk al(sep20)
v
. t nk al v
.t n k al v
. tn k alv
. tn k alv
w w w w w w w
1
a) CaSO4 b) CaSO4.2H2O c) CaSO4. H20 d) CaSO4. H20
t t t t t 2 t net et
i.ne i. ne
lvi.
n e n e
lvi.bunsens burner
n e
lvi. (sep21) kalvi.
n e
lvi. vi.n
alv 5.Flame n k a lvcolour of potassium
n k a salts n kin
a n k a n n k a nka
l
a) Lilac (violet ) b) crimson red c) Apple green d) yellow
i.ne
t 6. Formula lvi.
netof plaster of
lvi.
neparis
t (sep21) lvi.
net
lvi.
net
lvi.
net
lvi.
net vi.n
et
alv a a nka a nka nka al
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a)w 3CaSO4.Hw2O
ww ww b) CaSO4.2H2O
ww ww
w
c) 2CaSOw4.2H
w
2O d) CaSO
ww 4 . H2 O w
ww ww
𝟐
i.ne
t 7.Spodumene i.ne
t is the mineral i.ne
t source for i.ne
t which of the
i.ne
following
t alkali
i.ne
t metal ? (May22) i.ne
t
i.ne
t
w.ta) Lithium b) Sodium w.t c) Rubidium d)wwPotassium
n n n n n n n
w.t w.t w.t .t w.t
8.Which of the following has highest hydration energy ? (May22)
alv
alv
i.ne
i.ne
t
t
9._________
ww
w. t
10. Among
ww
w.t
n
n
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a lvi.
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Tnkalvi.Net
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ww
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w.t
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ww
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w.t
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2
ww
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t 2&3&5 MARKS t :- net net net net net net

i.ne i.ne lvi. lvi. lvi. lvi. lvi. lvi.
alv 1.Explain n k a l v
why Ca(OH) n k a is used in n k white
a washing n k a . (mar 19) (ipn
k a : 145 ) k a k a
w.t w.t 2 w.t w.t .tn w.t
n
w.t
n
2.Among the alkaline earth metals BeO is insoluble in w
t water t but other oxides t are soluble t .why ? (mar t 19) (ipn : 142 t ) t t
3.Write
w.t
n k any two wsimilarities
w.t
n k between
w.t
n k beryllium w.t and aluminium
n k
w.t
n k ( jun19).ww(ipn .t n k : 140 ) ww.t n k
ww w ww ww ww w w ww
4.Among the alkali metal halides, which is covalent ? explain with reason. ( jun19)(ipn:130)
i.ne
t 5.why blue i.ne
t colour appears
i.ne
t during thendissolution
i. e
t ofi.ne
alkali
t metalsi.nin et liquid ammonia i.ne
t
i.ne
t
(jun19)
w. t n (ipn : 130 w. )
t n
w. t n
w. t n
w. t n
w. t n
w. t n
6.How is bleaching powder prepared ? (sep20) (ipn :145 )
i.ne
t 7.Write the net uses of magnesium. net (sep20) net (ipn : 141) net net net net
alv k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi.
8.wDiscuss
ww
.tn the similarities
ww
w.t
n between
ww
w.t beryllium
n
ww
wand
.tn aluminium ww
w.t (sep21) (ipn
n
ww
w.t: 140 )
n
ww
w.t
n
ww
9. What are the reasons for the anomalous properties of Berylium ? (May22) (ipn : 139)
i.ne
t 10. Givelviany .ne
t three properties
lvi.
net of beryllium lvi.
net that arelvi.different
net from lvi.
ne other
t elements lvi.
net of the
lvi.
net
w.tgroup (May22) w.t (ipn : 139 w.)t w.t w.t w.t w.t
11. Discuss the similarities between lithium and magnesium (jul22) (ipn :129 )
nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
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t
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t 7708543401
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t Page 36
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
6.Gaseous State
ONE .tnk
n k
1.use of hot air ballone in meteorological observatory is an (mar 19)
alv
i.ne
t applicationa lvi.
net of________
a lvi.
net
a lvi.
net
a lvi.
net
a lvi.
net
a lvi.
net
a lvi.
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k k k k k k k
ww a) Kelvin‟s ww Law b)
w.t Brown‟s Law
n n n n n n n
ww ww ww ww ww ww
c) Boyle’s Law d) Newton‟s Law
t t t t t t t
alv
i.ne 2.Whenalvan i.n ideal gas undergoes
e
alv
i.n e unrestrained
alv
i.n e expansion,alv
i.ne no cooling alv
i.ne occurs because
alv
i.ne the alvi.net
.t n k n k n k n k n k n k nk
wmolecules
ww ________
ww (jun19) ww ww ww ww ww ww
a) are above the inversion temperature b) exert no attraction force on each other
t t t t net collide without t net t
i.ne c) do e e e i.ne i.ne
alv work equal ato
lvi. the loss inkkinetic energykalvi.d) loss ofkaenergy
i.n n i.n lvi.
alv nk n k n alv n n k alv n n k alv
3.Gases
ww tent to behaveww ideallywwonly at _____ww(sep20) ww ww ww ww
a) Low temperature and low pressure b) High temperature and High pressure
t t t t t net net pressure vi.net
i.ne c)nkHigh i. n e
temperature lvi.
n e
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lvpressure i.ne Low temperature
lvd) lvi. and High
lvi.
alv alv k a k a k a k a k a al
w .t w .tn w .tn w .tn w.tn w .tn w .tnk
4.wRate
w of diffusion ww of a gas isww: (sep21) ww ww ww ww ww
a) directly proportional to the square root of its molecular weight

i.ne b) lvi.
directly proportional lvi. to its lvi.
density lvi. lvi. lvi. lvi.
ww c) inversely ww proportional ww to the square ww root of itsww molecular ww
weight ww ww
t
d) directly proportional to its molecular weight t
i.ne . n et . n et . n et 0 i.ne net net i.ne
t
alv 5.7.5.tngkaof i
lv a gas occupies k alv
i
a volume k aof
i
lv 5.6 L at 0 k alvC and 1 atm k lvi.
apressure .The k lvi. is (May22)
agas k alv
n n n n n n
w w.t w.t w.t w.t w.t w.t
ww a) CO ww b) NO ww ww c) CO2ww ww d) N2O ww ww
Tnkalvi.Net
t
6.A bottle eao ammonia and a bottle of eHCl connected through a long tube are opened
i.ne i . n t i. net i . n t i . net i . net i.ne
t
i.ne
t
alv simultaneously
t n k al v at
t n k aboth
l v ends. The
t n k al white ammonium
v
t n k al v chloridet n k al ring will be
v
t n kfirst
alv formed t :
n k alv
w. w. w. w. w. w. w.
(May22) ww
t a) nearethe ammonia ebottle b) at the centre of the tube et

i.ne n t n t net net net n net
c)w.tnthroughout wthe
k a
.tn length of the
k a
w.t
n tube
k a
w.t
n k a d) nearw.thetn k a hydrogen w.t
nchloride bottle
k a
w.t
n k a
7.If temperature and volume of an ideal gas is increased to twice its values, the initial
t pressure net
P becomes :.n(jul22) et net net net net net
i.ne lvi. lvi lvi. lvi. lvi. lvi. lvi.
alv na) 4P
k a n k a b) w2P k a n c)
k a P w.tn k a d) w.tn 3P k a k a
w.t w.t .tn w.t w.t
n
2&3&5 MARKS :-
i.ne
t 1.what are i.ne
ideal
t gas ? (mar i.ne
t 19) (ipn : n169
i. e
t ) i.ne
t
i.ne
t
i.ne
t
i.ne
t
2. State
w.t
n k Diffusionwwlaw. .t n k (mar 19) w.(ipn
t n k : 168 ) ww.t n k
w.t
n k
w.t
n k
w.t
n k
ww w ww w ww ww ww ww
3.What is inversion temperature ? ( jun19) (ipn : 175)
i.ne
t 4.Derive iideal .ne
t gas equation. i.ne
t ( jun19)i.n(ipn et : 165 ) i.net i.ne
t
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n
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3
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t t t t t et net
i.ne i.ne i.ne i.ne lvi.
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ww ww ww ww ww : 168 ) ww ww ww
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i.ne
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t ASST IN CHEMISTRY
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alv nka
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11TH
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QUESTIONS
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7.Thermodynamics
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k a lvi. k a lvi.
n n n n n .tn n
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t
alv
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t
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i.ne i. net i. net i . n t i . net i . n t i . net i.n
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: (jul22) al v al v al v al v al v alv
w .tnk w .tnk w .tnk w .tnk w .tnk w .tnk w.tnk
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i.ne i.ne vi.n vi.n i.n i. i.ne vi.n
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alv
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a
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lvi. lvi.
n
al vi.n
ww ww ww ww ww ww
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2.calculate w
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w
t et et et -1 t t net net
i.ne enthalpy
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vJi.nmol . (maralv19) lvi. lvi.
alv kal k kal k ka a a
.tn .tn .tn .tn .tn .tnk .tnk
(s) + O2(g)  CO2(g) Calculate the standard entropy change for the above reaction, given
w w w w w w w
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t t t t -1 t t t t
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thenkstandard entropies
lvi.
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lC
ne O
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lvi. and ne ne
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lvi. i.ne
alv alv nka
2(g),
nka n nka nka nk alv
(mar19) (ipn : 212 )
t t t t t t et net
i.ne 4.Define i.ne i.ne e
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e
vi.n lvi.
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alv Give alits alv a ) al a
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w. tnk w. tnk w. w. w .tnk w .tn k
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t et et et et et net et
i.ne i.n n i.n n
alv 6.state
.tnk
zeroth
alv Law .tof lvi.
nka Thermodynamics.
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alv (sep20)
.tnk
lvi.
a(ipn :195 ).tnkalvi.n .tnk
alv
i.
nka
l vi.n
w w w w w w w.t
7.Distinguish between extensive and intensive property. (sep20) (ipn : 189 )
t et et t net et net net
i.ne lvi.
n
lvi.
n vi.n
e
lvi. vi.n lvi. lvi.
alv nka a al nka al nka a
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
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t
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t 7708543401
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t Page 38
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
t t t t t t net et
alv
i.ne 8.Derive
nka
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lvithe
nka
lvi.
ne
enthalpy
nka
lvi.
ne
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alv
i.ne energy
nka
lvΔU
i.ne for an
alv
i.
al vi.n
w.t w.t w.t w.t w.t w .tnk w .tnk
ideal gas. (sep20) (ipn : 197 )
i.ne 9. Calculate i.n the entropy i.n i.n the melting i.n i.n i.n at 0 0c andlvi.n
alv alv alv change during
alv alv of one mole alvof ice into nwater
alv a
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i.ne ne
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alv summation.
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alv (sep21) (ipn
.tnk
alv: 207 )
.tnk
a nka
w w w w w w w.t
11.Give any two characteristics of gibbs free energy ? (sep21) (b/b-52)
t t t t t t net net
i.ne lvi .ne lvi lvi .ne lvi lvi .ne .ne .ne lvi. lvi.
alv 12. State
nka the first lawnka of thermodynamics
nka (sep21)nka (ipn : 195.tn)ka nka nka
w.t w.t w.t w.t w w.t w.t
13. What are the conditions for the spontaneity of a process? (sep21) (ipn : 215 )
alv l
14.What are the condition for the
nka spontaneity of a process (May22) (ipn w: 215 )
nka al a al al nka
l
w.t w w.t .tnk w.t
n k
w.tnk .tnk w.t
15.Explain sign convention of heat (May22) (ipn : 192 )
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
16.wExplain
w
the characteristics
.tnk
ww
of internal energy
.tnk
ww
. (May22) (ipn : 191 )w
w .t .tnk w.t
n k
w .t w .tnk
w w w ww w w w ww ww
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i.ne vi.n lvi.
n
18.If
ww
an automobile
.tnk
ww
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w
petrol at a wtemperature
.tnk w ofw 1089 K and if the surrounding
w.t w
.tnk w.t ww
.tnk w.t
w w w w w w w ww
Tnkalvi.Net
temperature is 294 K , calculate its maximum possible efficiency . (jul22)
t t et t t t t t
i.ne i.ne lvi.
n i.ne i.ne i.ne i.ne i.ne
(ipn : 211 ) (compulsory
ww
w.t
ww
2 mark) w.t
ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
t
19.Define entropy
t
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t
unit. (jul22)t (ipn : 210,211
t
)
i.ne i.ne vi.n
e
vi.n
e i.n e i. net i.ne
t
vi.n
e t
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l al alv alv nka
lv
nka
l
20. w.tnk
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n vi.n

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w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

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nka .tnk
a
a
w.t w w w.t w w.t w
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i.ne
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i.ne
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alv nka
lv
nka
lv
nka
lv
nka
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11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
ww
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8.Physical And Chemical Equilibrium
ww ww ww ww ww ww

ONE .tnk
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-ve
alv
i.ne
t a) aK l vi.p n<K
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ww kb and kf for wwa reversible reaction ww are 0.8 ww x 10 and 1.6x ww 10 respectively ww ,the value
ww of ww
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t -1et
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t
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ww
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ww ww ww w ww ww ww
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t t t t t t t t
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alv n alv n k alv equilibrium nk alv ,Q is always nk alv less than the n k alv equilibrium n k alvconstant nkalv
w. t w. t w. t . t .t . t w. t
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d) Presence of catalyst affects both the forward reaction and reverse reaction to the same
i.ne extent.
lvi. lvi. lvi. lvi. lvi. lvi. lvi.
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n
w.t
n
w.t
n
w.t
n .tn w.t
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ww the following
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ww A+ wwB ww If the
wC. ww ww
t
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i.ne . n e . n e . n e . n e .n e . n e net
alv (sep21) k a lvi k a lvi k a lvi k a lvi k alvi k a lvi k a lvi.
n .tn n n n n n
ww a) be whalved ww ww b)wwbe doubled ww ww ww
t
c)t remain the tsame t t
d) becomet one fourth t t
alv 5. Which n k a l v one of the n k following
a lv is nincorrect
k a l v statement
n k a l v ?(may22) n k alv n k alv n k alv
w.t w.t w.t w.t w.t ww
.t w.t
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alv
alv
i.ne
i.ne
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t
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Tnkalvi.Net
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w.t
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n
k
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alv
a
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lvi.
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t
ww
t
w.t
n
n
k
k
alv
a
i.ne
lvi.
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t
ww
ww
t net
PCl5 net net
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k a n 0.5 mole of
k a nPCl5 , the total
k a n number of.tmoles
k a n k a of reactants
n k a and productsn k a
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i.ne
t a) 0.5-X i.ne
t b)
i.ne
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t d) X+1
i.ne
t
i.ne
t
2&3&5 MARKS :-
t t t t t t t t
alv –Le-Chatelier
i.ne 1.Define i.ne i.ne i.ne 19) b/b-32(ipn i.ne : 16 ) i.ne i.ne i.ne
alv alv principle.nk(mar
alv alv alv alv alv
tnk
w. tnk t w. tnk w. tnk w. w. w.t
nk
w.t
nk
[𝐶𝑎𝑂 (𝑆) ][𝐶𝑂2(𝑔) ]
2.Write the balanced chemical equation for the Kc= (mar 19) (ipn : 8 )
t et et et et [𝐶𝑎𝐶𝑂et3(𝑔) ] et
i.ne vi.n vi.n vi.n vi.n vi.n vi.n net
alv kal kal al al al al a lvi.
w.t
n
w.t
n .tnk .tnk .tnk .tnk .tn k
ww ww CaCO3www ww
w
CaO
ww w
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w
ww
w
ww
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vi.n
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t inert gas
vi.n
eon
t the rection
vi.n
et at equilibrium
vi.n
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vi.n
et :19vi.n)et
alv al nka
l al al nka
l al nka
l
w .tnk w.t w .tnk w .tnk w.t w .tnk w.t
ww ww ww
4.Derive the relation between kp and kc for a general homogeneous gaseous reaction. ww ww ww ww ww
i.n et
lvi.
n et
lvi.
n et
vi.n
e t
lvi.
net vi.n
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lvi.
net (ipn :6 )vi.net
alv nka a al nka al a l a
w.t w .tnk w .tnk w.t w .tnk w .tnk w .tnk
i.ne
i.ne
t
i.ne
t PG
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i.ne
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alv nka
lv
nka
lv
nka
lv
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
5.Explain homogeneous and heterogeneous equilibria. (sep20) (ipn : 5 )
t t t t t et net et
i.ne 6. Define ne
lvi. reaction quotient.
lvi.
ne
(sep20) i.ne : 11 )
lv(ipn lvi.
ne vi.n i. vi.n
alv nka nka nka nka al alv al
w.t w.t w.t w.t w .tnk w .tnk w .tnk
7.What is the relation between KP and KC ? Give one example for which KP is equal
i.ne to .K i.n lvi.
n
28(ipn.tn:ka7lvi).n vi.n lvi.
ne vi.n i.ne
alv al.v (sep21) ab/b- al nka al alv
tnkC
w .tnk
w w w .tnk w . t w .tnk w .tnk
8.What are homogeneous and heterogeneous equilibria? Give example (sep21) (ipn :5 )
i.ne i.n i.n i.n i.n i.n n
lvi. equilibrium i.n
alv 9.Give
.tnk
aalv balanced chemical
.tnk
alv equation
.tnk
alv for the equilibrium
.tnk
alv reaction
.tnk
alv for which
.tnk
athe
.tnk
alv
w w w w w w w
[𝑁𝐻3 ]4 [𝑂2 ]5
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i.n et i.ne
t
i.ne i.n e [𝑁𝑂]4 [𝐻2 𝑂]i.6net t
i. ne ne net
alv alv alv alv alv alv lvi. lvi.
nk nk nk .tnk nk nka nka
w.t w.t w.t w w.t w.t w.t
i.ne
t
vi.n
et 4NO
lvi.
ne+t 6H2O vi.n
et
lvi.
net 4NH3 + 5O 2net
lvi. vi.n
et
vi.n
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alv nka
l
nka al a a al nka
l
w.t w.t w .tnk w.t
n k .tnk .tnk w.t
ww ww ww ww w ww ww
w
ww ww
t -2 -2
net
10.The aequilibnrium t
concentrations of t
i.ne NH3 and N et
i.nand H2 area1.8 net t
M andalvi.net
alv
i.ne lvi. alv
i.ne
alv alv2 lvi. x10 M , 1.2x10
alv
i.ne
ww -2 ww ww ww ww ww ww ww
3x 10 M respectively. Calculate the equilibrium constant for the formation of NH3 from
t t et t et net net net
i.ne N2 kand i.neH2 (May22) i.ne
vi.n (ipn :15 a)lv(compulsory 3vi.nmark) lvi. lvi. lvi.
alv alv kal k kal nka a nka
.tn .tn w.t
n .tn w.t .tnk w.t
w ww w w ww w w ww ww www ww ww
11.Define reaction quotient (jul22) (ipn : 11)
alv
alv
i.ne
i.ne
t
t
ww
w
kal
w
w.t
w
vi.n
.tnk
e
12.Atnparticular
alv
i.
nka
Tnkalvi.Net
temperature
lvi.
t
ne Kc =nk4X
H2S(g)
net
Calculate Kwcwfor
ww
.tn each of the

www
i.ne
w.t
-2
alv 10 for the
nka
kal
i.ne
lvreaction
vi.net
.tnfollowing reactions.
ww
t
(jul22)
nka
ww
w
w.t
ne
lvi. (b/b-44 )k(ipn
H2(g) +
n a
kal
vi.
ne
lvi. : 295)
net
1
2
t
ww
S2(g)
w
w.t
.tnk
alv
i.n et
t
ww
ww
w.t
w .tnk
alv
i. net
t
ww
ww
w.t
w.t
nka
lv i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e
t
t
ww
ww
t
i) 2H2St (g) 2H2(g) + S2(g)
i.ne vi. ne net t
vi.n
e
vi.n
et
vi.n
et n et
vi.n
et
alv kal lvi. al al al lvi. al
n nka .tnk 3 .tnk .tnk nka .tnk
w.t ii) 3H2S(g) w.t 3H .t
ww2(g) + S2(g)
w w w w w
2
i.ne
t 13. Derive
lvi.
net KC and KP
lvi.
nefor
t synthesis
lvi.
nof
et ammonia i(jul22)
lv .
net (ipn :lvi14
.ne )
t
lvi.
net
lvi.
net
alv a a a a a a a
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l
w .tnk w .tnk w .tnk w .tnk w .tnk w.tnk w.t

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 41
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
9.Solutions
ONE .tnk
n k
w .tnkw .tnk w w .tnk .tnk
1.osmotic pressure ( π) of a solution is given by the relation __ (mar 19)
i.ne
t a)net π rt=n vi.net net net b) V= πvnRT net net net
alv a lvi. a l a lvi. a lvi. a l i. a lvi. a lvi.
n c) π= n RT.tn
k k n k n k
d)wwπw.V=nRT
tn k n k n k
w.t w w.t w.t w.t w.t
2.Assertion : Mixture of carbon tetrachloride and chloroform show positive deviation from
t t raoult‟s law t t t t t t
Reason
ww
w.t : In thewwmixture
w.t the inter
ww
w.t molecularwforce
w
w.t of attraction
ww
w.t betweenwwchloroform
w.t and
ww
w.t
ww
carbon tetrachloride is weaker than those between molecules of carbon
i.n tetrachloride i.neand chloroform i.ne molecules. i.ne(jun19)
t t t t t t t t
i.ne e i.ne i.ne i.ne
alv nk alv n k alv nk alv nk alv n k alv n k alv n k alv
w. t t
w. and reason w. t w. t .t w. t . t
a)
ww Both assertion ww ww are correct ww and reasonwis wwthe correct wwexplanationwof ww ww
assertion
t net net net net is not the vcorrect net net
alv
i.ne b) Both k a lvi. assertion and k alvi. reason arekcorrect a lvi. and reasonk a lvi. k a l i. explaination
k a lvi. for kalvi.net
n n n n n n n
ww assertion ww ww ww ww ww ww ww
c) Both assertion and reason are false
t net t et net net net net
i.ne d) Assertion lvi. is trueka,lvbut i.ne reason is lfalse vi.n lvi. lvi. lvi. lvi.
alv n k a n n k a n k a n k a n k a n k a
w.t
3.osmotic pressure w.t w.t w.t the relation w.t w.t w.t
ww ww (π) of a solution ww is givenwwby ww (sep20) ww ww ww
i.ne
t a) πi.netRT=n i.ne
t
i.ne
t
i.ne
tb) π= n RT net
i. i.ne
t
i.ne
t
wc) π V=nRT d) None w.t of these
.t n k n k n k n k n k n k n k
w.t w.t w.t w.t w.t
4.The molality of a solution containing 1.8g of glucose dissolved in 250g of water is (sep21)
alv
alv
i.ne
i.ne
t
t
ww
w.
a) al0.02M
w.t
t n
5.Equimolal
ww
n
k
k
0
vi.n
Tnkalvi.Net
et
ww
w.
aqueous tn k alv
i.ne b) 0.2M lvi.ne
t
solutions w. t n k a
ww of NaCl andww
t
is -2 c , the freezing point of KCl solution is expected to be (May22)

a
t
i.ne -1 C
lva)
c) 00Cwww
0
.tn k a lvi.
net
ww
w.t
n k a lvi.
net
ww
w.
KCl
w.t
t
n
c)alvi0.04M
n
k
k
a lvi.
.ne
net
t
are prepared ww
b) -2
t
w.t0
d)ww-4
n
0
n
C
k
C
k
alv
a
i.ne
lvi.
t
net
d) 0.01M
w. . If the freezing
ww
ww
w.
w.t
t
n
n
k
k
a
alv
i.ne
lvi.
net
t
point of
ww
w.
w.t
t
ww NaCl
n
n
k
k
a
alv
i.ne
lvi.
net
t
ww
ww
6.Which one of the following binary liquid mixtures exhibit positive deviation from Raoult‟s
t t net net net net net net
i.ne i.ne lvi. lvi. lvi. lvi. lvi. lvi.
alv law n ?
k a lv(jul22)
.tn k a
.tn k a n k a n k a n k a n k a
w.t ww ww w.t w.t w.t w.t
ww ww ww ww ww ww
a) Acetone w+ Chloroformw b) Water + Nitric acid
i.ne
t c) HCl vi.n
et + Water i.net
vi.n
et d)et Ethanolvi.ne+Water
vi.n
t
vi.n
et
vi.n
et
alv al v al al al al al al
2&3&5 MARKS :-
et .ne
t
.ne
t
.ne
t
.ne
t
.ne
t
i.ne
t
i.ne
t
vi.n lvi lvi lvi lvi i
al 1.State nkathe term “isotonic
nka solution”nka (mar 19)(b/b-37)
nka (ipn : w56)
.tnk
alv nk alv nk alv
2. NH3 and HCl do not obey Hentry‟s law. Why ? (mar 19) (ipn : 40)
alv 3.What is vapour wpressure of a liquid
k a alv al
? what wis relative lowering of vapour al alv al a
w .tn w .tnk .tnkw .tnk w.tnk .tnk w .tn k
pressure ?(jun19) (b/b-32 )
i.ne i.n vi.n lvi. vi.n vi.n i. vi.n
alv alv al a al al alv nka
l
4.What
ww
is the mass
.tnk
ww
of glucose w(C
w H O ) in it
.tnk
ww
one litre solution
ww
which iswisotonic
k
.t6n 12 6
w with 6gl- .tnk .tnk .tnk
ww.t
w w w w w w w ww
1 of urea (NH2CONH2) ? ( jun19) (ipn : 57,299)ey-13
i.ne lvi.
n
lvi.
n vi.n
e
lvi. vi.n lvi. lvi.
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 42
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
t t t t t t t t
i.ne 5. Draw i.ne explain the
lvand
ne
lvi. graph obtained
lvi.
ne
by plotting ne
lvi. solubility kversus
lvi.
ne
temperature
lvi.
ne
for calciumlvi.
ne
alv nka nka nka nka n a nka nka
chloride . ( jun19) (ipn : 37)
i.ne 6.Calculate i.n the mole fraction
i.n of .methanoli.n n
lvi. when 0.5
and .twater vi.n i.n is mixed lvi.n
alv alv alv alv nka almole of methanol
alv a
.tnk
w .tnk w tnk w .tnk .tnk w .tnk w w w
with 1.5 moles of water. (ipn : 33) (SEP20)
t et et et et net net t
i.ne ne
alis
vi.nvan‟t hoff factor „i‟ ? (sep20)
i.n i.n i.n lvi. lvi. lvi.
alv 7.What
.tnk .tnk
alv
.tnk
alv (ipn : 58)
.tnk
alv nka .tnk
a nka
w w w w w.t w w.t
8.What is molal depression constant ? (sep21) (ipn : 54)
t t t t t t net net
i.ne lvi .ne lvi i .ne lvi lvi .ne .ne .ne lvi. lvi.
alv 9.What nka are ideal solutions
nka ? Give alv
nkexample (sep21)
nka (ipn :46 ).tnka nka nka
10.How will you determine the molar mass of a solute from osmotic pressure ?
alv l
(sep21)(ipn:56 )
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
11.Define the term “isotonic” solution . (May22) b/b-37(ipn :56 )
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
12.Write
ww
the formula
.tnk
ww
to calculate the molar mass
.tnk
ww
of a solute from realative
w .t lowering of
ww
.tnk w.t
n k
w .t .tnk
w w w ww w w w w w ww
vapour pressure values. (May22) (ipn : 50 )
i.ne vi.n lvi.
n
13.wHow
w will youwwdetermine the
.tnk
w
molar mass wof
w solute from
.tnk
w
elevation of boiling point ?w
w.t .tnk w.t ww
.tnk w.t
w w w w w w w ww
Tnkalvi.Net
(May22) (ipn :53 )
t et et et et et t t
i.ne i.n vi.n i.n i.n i.n i.ne i.ne
alv nk alv kal nk alv nk alv nk alv nk alv nk alv
14.50g
ww
of tab water
w.t
ww
contains 20 mg of dissolved
w.t
n
ww
solids. What is the TDS
ww
w.t
ww
val;ue in ppm?
ww
w.t
ww
w.t w.t w.t
ww
t
(jul22) (ipn :34 )
i.ne i. net vi. net vi. net vi.n
et net t
i.ne vi.n
e t
alv alv kal kal kal lvi. lv l
.tnk .tn n n nka nka nka
15.What
w w are thewconditions
w ww when
ww
w.t a solution tends
ww
w.t to be have
ww
w.t like an ideal
ww
solution? w.t
ww
w.t
ww
t
(jul22) (ipn : 46 )et
i.ne vi. net net net net et
vi.n n vi.n
et
alv kal lvi. alv
i.
kal
vi. al lvi. al
n nka .tnk n .tnk nka .tnk
w.t w.t w w.t w w .t w

w .t n
w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 43
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
10.Chemical Bonding
ONE .tnk
n k
w .tnk
w .tnk w w .tnk .tnk
1.which of the following molecule does not contain π bond ? (mar 19)
i.ne
t a)neCO t 2 net net b)viH ne2t O net net net
alv k a lvi. k a lvi. k a lvi. k a l . k a lvi. k a lvi. k a lvi.
n c) SO2
w.t d) NO2
n n n n n n
2.Shape and hybridation of IF5 are : (jun19)
i.ne
t a)
vi.n
etTrigonal bipyramidal
vi.n
et spl3vdi.n2et b) eTrigonal
vi.n
t bipyramidal
vi.n
et sp3lvdi.net i.ne
t
alv n k a l
n k a l
n k3a 2 n k a l
n k a l 3 2 n k a n k alv
ww
w.t c) Square ww
w.t pyramidal
ww
wsp
.t d
ww
w.t d) Octahedral,
ww
w.t sp d www.t ww
w.t
ww
3.Match the following (sep21)
t net N t t t
alv
i.ne
k a1)
lvi. 2 moleculek alv
i.ne
k alv
i.ne i) kchemical
alv
i.ne bondkalvi.net k alv
i.ne
t
k alv
i.ne
t
t n tn t n t n t n tn tn
w. w. w. w. w. . w.
ww 2) BF3wwmolecule ww ww ii) Trible covalent ww bond www ww ww
t 3) et HF molecule t t iii) Electron t deficient t molecule net

i.ne i.n i.ne i.ne i.ne i.ne net
alv a l v al v a l v a l v a l v a lvi. a lvi.
w.t 4) NaCl wiv)
.tn polar covalent bond ww.tn
n k n k n k k n k k n k
w.t w.t w.t w.t
a) 1)- iii) , 2)- i) , 3)-iv) , 4)- ii) b) 1)-ii) , 2)- iv) , 3)-i) , 4)- iii)
t t t t net ii) , 2)-iii) t t t
alv
i.ne c) alv1)- i.ne i) , 2)- iv)
alv
i.ne , 3)- ii) , lvi4)-
a
.ne iii) d)
alv
i.1)-
alv
i.ne , 3)- iv) l,vi.ne4)- i)
a alv
i.ne
4.Which one of the following is diamagnetic ? (May22)
t t 2- t t t + t t net
i.ne i.ne i.ne i.ne i.ne i.ne i.ne
alv nk alva) O2 n k alv n k alv n k alvb) O2 n k alv n k alv nka
lvi.
w.t .t w.t w.t w.t w.t w.t
ww c) Ow2 ww ww ww d) None ww of these ww ww ww
5.The ratio tof number of tsigma ( ) and pi ( π) bonds
Tnkalvi.Net
t t t
in 2-butynalt is : (jul22) t t
i.ne i.ne lvi.
n e i.ne 8 lvi.n
e i.ne i.ne i.ne
alv alv𝟖 nka
5 alv alv 9 alv alv
w.t
nk
a) w.t b) w.t
nk c) ww.tnka w.t
nk d) w.t
nk
w.t
nk
ww 𝟑 ww 3 ww w 2 ww 2 ww ww ww
e
alv alv nka
l al alv alv nka
lv
nka
l
2&3&5
w MARKS
w ww :- ww ww ww ww ww ww
i.ne
t 1.what is
vi.n
called
et bond vlength
i.ne
t ? namevi.the
net techniques
vi.n
ethrough
t which
vi.n
et the length iof
v .n
et a bond can i.net
alv nka
l al al v al al nka
l al
w.t w .tnk w .tnk w .tnk w .tnk w.t w .tnk
ww ww
be determined . (mar 19) ( ipn ; 76) ww ww ww ww ww ww
i.ne
t 2. Writelvthe
i.ne structure lof
t
vi.n
ethe
t following
lvi.
necompounds.
t
lvi.
n(mar
et 19) ( ipn
lvi.
ne;t 82,83 )
lvi.
net
lvi.
net
alv a a a a a a a
w .tnk w .tnk w .tnk w.tnk w .tnk w.tnk w .tnk
ww ww A) NH3 ww B) BFw3w ww ww ww ww
alv
i.ne
t 3.Both aClvi2.nHet2 and CO2alvhave
i.ne
t the same
alv
i.structure.
net Explain
alv
i.ne
t why. (MAR19)
alv
i.ne
t
alv
i.ne
t
alv
i.ne
t
ww
 C2H2 andwCO
w ww ww
2 has sp hybridisation linear structure
ww ww ww ww
alv
i.ne
t
 kThe
alv
t
i.nelinear structure
kal
vi.n
et of ethyne iand
kal
v .n
et that of carbon
kal
vi.n
et dioxide
kal
vis
t
i.neexplained on
kal
et
vi.nthe basis of
kal
vi.n
et
n n n n n n n
hybridisation.
alv
i.ne
t
 kEthyne
alv
i.ne
t
molecule
kal
et
vi.nis formed when
kal
et
vi.n both the acarbon
k l
vi.n
et net
atomskaundergo
lvi.
et
sp hybrisation
kal
vi.n andkalvi.net
n n n n n n n
have two unhybridised orbitals (2py and 2px)
nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 44
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
4.Linear form carbon dioxide molecules has two polar bonds .yet the molecule has zero
t t t t t et net et
i.ne dipole ne
lvi. moment. Why
ne ne
lvi. ? ( jun19)kab/b-40
lvi. ( ipnnk;a80 ne
lvi. ) vi.n i. vi.n
alv nka nka al alv al
w.t w.t
n
w.t w.t w .tnk w .tnk w .tnk
5.Draw the M.O diagram for oxygen molecule . calculate its bond order and magnetic
i.ne vi.n
character. vi.n
(.tnjun19) ( ipn .;tn100 vi.n ) vi.n lvi.
ne vi.n i.ne
alv al kal kal al nka al alv
w .tnk w w w .tnk w . t w .tnk w .tnk
6.Calculate the formal charge on carbon and oxygen for the following structure
i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne
ww ww ( jun19)
ww ( ipn : 72)ww ww ww ww ww
i.ne
t 7.Write lthe
vi.n
et shape and molecular
lvi.
net geomentry
lvi.
net for BF
lvi.
3et (sep20) ( ipn
n
lvi.
net: 91 )
lvi.
net
lvi.
net
alv nk a nka nk a nk a nk a nka nka
ww
8.What ww
is hybridisation ww
? mention the type wofw hybridization found in CH
ww (sep20) ( ipn : 92 ) ww ww ww
4
i.ne
t 9.Write lany
vi.n
et four postulates
lvi.
net of molecular
lvi.
net orbital theory.
lvi.
net (sep20)lvi(.neipn
t : 97) vi.n
et
vi.n
et
alv nka nka a nka a al nka
l
w.t w.t w .tnk w.t .tnk .tnk w.t
ww ww of molecules
ww predicted by
ww VSEPR theory w ww w
10.Give the shapes w (sep21) (wipn :82,83,83ww) ww
t t t t et net et et
i.ne vi .ne vi .ne i .ne vi.n lvi. lvi.
n vi.n
alv kal
a)w.tnBeCl b) kal 3
nNH alv
c) wH.tn2kO al a nka al
2 w.t w .tnk w.t
n k
w .t w .tnk
t 11.DefineneBond
t Order. ne(sep21)
t ( ipn n:et76 ) net net net net
i.ne vi. lvi. lvi. lvi. lvi. lvi. lvi.
.tnk .tnk w.t .tnk w.t .tnk w.t
12.What
ww
w are thewsalient
ww features
ww of VB theory
ww ? (sep21) (wipn
w w : 86 ) www ww ww
Tnkalvi.Net
i.ne
t 13.Explain
i.ne
tthe formation
i.ne
t of H2 molecule
i.ne
t using MO-theory
i.ne
t (sep21)
i.ne
t ( ipn : 99 ) net
i. i.ne
t
alv nk alv nka
lv
nk alv nk alv nk alv nk alv nk alv
14.What
ww is resonance
ww ? (sep21) ( ipn :78 ) ww ww ww ww ww ww
i.ne
t 15.Describe
i.ne
t the formation
i.ne
t of HF molecule
i.ne
t by orbital
i.ne
t overlap. (May22)
i.ne
t ( ipn :88
i.ne
t ) e t
alv alv l v al v alv alv lv l vi.n
w w.t w w w w.t w.t
16.Define
w w i) Bond
ww length ii)Bond angle iii)Bond
ww enthalpy
ww. (May22) ( wipn
ww w : 76,77) ww ww
i.ne
t 17.Describe net fajan‟s Rule net (jul22) ( ipn net: 81 ) vi.n
et
vi.n
et n et
vi.n
et
alv lvi. a lvi. lvi.
a a al al lvi. al
w w w w w w w
wwDiscuss the wformation
18. w ww molecule using
of C ww ww (jul22) ( ipn : 100 )
MO theory ww ww ww
2
i.ne
t 19.mention
lvi.
net the shape of
lvi.
nethe
t following
lvi.
nemolecules
t based
lvi.
net on VSPER
lvi.
net theory (jul22)
lvi.
net
lvi.
net
alv a a a a a a a
ww i) BF3 ww ii) BrF3 iii)wwPCl5 iv) SF6ww v) IF7 ( ipnww: 82,83,83,84,84
ww ) ww ww
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 45
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
11.Fundamentals Of Organic Chemistry
ONE .tnk
w
n k
w .tnk w .tnk w .tnk .tnk
1.many of the organic compounds are inflammable because of Its_______ (mar 19)
i.ne
t a) vander net waal‟svforce net net b) co-ordinate
net nature net net net
alv k a lvi. k a l i. k a lvi. k a lvi. k a lvi. k a lvi. ka lvi.
w.c)
tn covalent wnature
.tn w.td) ionic nature
n n n n n
w.t w.t w.t w.t
2.Which of the following is optically active ? (jun19)
i.ne
t a) lvi.3-chlolro
net pentane i.ne
t
i.ne
t b) 2-chloro
i.ne
t propane i.ne
t
i.ne
t
i.ne
t
alv n k a n k alv n k alv n k alv n k alv n k alv n k alv
w.c)
t meso-tartaric
w.t acid www.t w.d)
t glucose w.t w.t w.t
t et et t t net net net

i.ne vi.n vi.n i.ne i.ne i. lvi. lvi.
alv al kal alv alv alv nka nka
3.Write
ww
.tnk the IUPAC
ww
.tnname of w.t
nk
w.t
nk
w.t
nk (sep20) w.t w.t
w w ww ww ww ww ww ww
a) 1-formyl propanol b) 1-hydroxy butanal
t t t t net et net et
i.ne c) lvi.
ne
2-hydroxy ne
lvi. butanal kalvi.
n e
d) lvi.3- hydroxyl vi.n
lbutanal lvi. vi.n
alv n k a k a k a k a k a nka
l
w.t .tn w.t
n
w.t
n
w.t
n
w.t
n
w.t
4.The
ww structure wof wwisobutyl group ww in organicwwcompound (sep21)
ww ww ww ww
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
n k
w .t w .tnk
ww a) ww ww ww b) ww ww ww ww

i.ne vi.n lvi.
n
alv
alv
i.ne
i.ne
t
t
5.Which
ww
ww
w.t
6.Which
w.t
n k
nk
a
alv
vi.
lc)
c)
n e
Tnkalvi.Net
i.ne
t
ww
glucose
ww
. t
of the wfollowing
a) meso-tartaric acid
t
.tn
of the wfollowing
n k
k
alv
a
i.ne
lvi.
n e
t
t
ww
ww
w.
w.t
t
is optically
is aliphatic
n
n
k
k
alv
a
i.ne
lvi.
n e
t
ww
saturated
.
w.t
t
n
n
activeww?w(sep21)
k
k
a
alv
lvi.
i.ne
hydrocarbon
n e
td)
t
ww
d)
ww
w.
w.t
t n
n
k
k
alv
b) 3-chloropentane
lvi.
? (May22)ww
i.ne
net
2-chloropropane
a
t
ww
w.
w.t
t n
n
k
k
alv
a
i.ne
lvi.
net
t
ww
ww
w.
w.t
t n
n
k
k
alv
a
i.ne
lvi.
t
net
ww
ww
t a) net C9H18 tb) C8H14 t c) Cn8eH t 18 t d) All of the above

t net
i.ne i. i.ne i.ne i. i.ne i.ne lvi.
alv 7.match n k a l v
of following k a l v
(May22) k a l v
k a l v
k a l v
k a lv
k a
w.t .tn w.t
n
w.t
n
w.t
n
w.t
n
w.t
n
1) –NO2 w i) propyl
t 2)-OCH et 3 et ii) Amino t t t t t
i.ne vi.n vi.n i.ne i.ne i.ne i.ne i.ne
alv a l al alv alv alv alv alv
3)-CH
w.t
n k
2 -CH -CH
2 w.t 3n k iii)Methoxy
w.t
n k
ww
.t n k
w.t
n k
w.t
n k
w.t
n k
ww w ww ww ww ww ww
4) –NH2 w iv) Nitro w
i.ne
t a) (1)-i.n(iii), et (2)-(ii) ,i.n(3)-(iv),et (4)-(i) i.ne
t b) (1)-i.ne(iii), t (2)-(iv)i.n, e(3)-(i),t (4)-(ii) i.ne
t
i.ne
t
c)
ww
. (1)- (iv), (2)-(iii)
t n k
ww
. t n k , (3)-(i),
ww
. (4)-(ii)
t n k
ww
d). (1)- (ii), (2)-(i)
t n k
ww
. t n k , (3)-(iv),ww(4)-(iii)
. t n k
ww
. t n k
w w w w w w w ww

i.ne lvi. i.n vi.n vi.n i. i.n lvi.
alv 8. .tn k a
.tnk
alv
.tnk
al
.tnk
al
.tnk
alv (May22)
.tnk
alv
.tn ka
w w w w w w w
et
a) optical t
isomers et b) resonating structures et
i.n i.ne i.n net i.ne
t
i.n net vi.n
et
alv c) v
conformers
a l alv lvi. v
d)tautomers
l alv alv
i. l
.tnk .tnk nka .tnk
a
.tnk .tnk nka
w w w.t w w w w.t

alv lvi. lvi. al vi.n lvi. alvi.n lvi. lvi.
nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 46
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
9.The IUPAC name of the compound (jul22)
w .tnk w .tnk w.t
n k
w .tnk .tnk .tnk .tnk
ww ww ww ww w ww ww
w
ww
w
ww
Is
t a) 2-ethylbut-2-enoic t t acid net
b) 3-ethylbut-3-enoic
t acid
t net net
i.ne i.ne i.ne lvi. i.ne i.ne lvi. lvi.
alv l v
c)w.tnk3-ethylbut-2-enoic
a n k a l v
acid nk a ka l v
d) w.tn2-ethylbut-3-enoicn ka l v
acid n k a n k a
w.t w.t w.t w.t w.t
10.Match the following (jul22)
i.ne
t 1) -NH2 i.ne
t
i.ne
t i) Sulpho-
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
w.t
2) -CN www.t w.t ii) Formyl w.t - w.t w.t w.t
3) -SO3H iii) Amino -
t t t t t t t t
i.ne 4).tnkalv-CHO i.ne i.n e i.ne i.ne i.ne i.ne i.ne
alv n k alv n k alviv) Cyano n - k alv n k alv n k alv n k alv
w . t w. t . t w. t . t w. t
a) 1)- i) , 2)-wii), 3)- iii , 4)- iv) b)w 1)- iv , 2)- iii) , 3)- ii) , 4)-w i)
i.ne
t c) 1)- iii), net
2)- iv), 3)-i.neti) , 4)- ii) i.net d) 1)- iii), net
2)- i) , 3)- iv) net
, 4)- ii) i.net net
alv k a lvi. k a lv k a lv k a lvi. k a lvi. k a lv k a lvi.
n .tn n n n n n
2&3&5
ww
w.t MARKS ww
w:-
ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
w.t
ww
1.Describe the reaction involved in the detection of nitrogen in an organic compound by
t net method. (mar net 19) (ipn :vi.138) net net net net net
alv
i.ne lassaigne
k a lvi. k a lvi. k a l k a lvi. k a lvi. k a lvi. k a lvi.
n n n n n n n
2.which
ww is the suitable
ww methodwwfor detectionwwof nitrogen present ww in foodwwand fertilizers? ww ww
t et et
(compulsory et
2 mark) et
(mar e19) t
(ipn :147 e)t t
i.ne vi.n vi.n vi.n vi.n vi.n i.n i.ne
alv a l a l a l a l a l alv alv
This w.t
method
n k is carried
w.t
n k much more
w.t
n k easily than the
w.t
n k Dumas method.
w.t
n k It is used
w.t
n k largely in the
w.t
n k
analysis of foods and fertilizers. Kjeldahls method is based on the fact that when an organic
alv
alv
i.ne
i.ne
t
t
compound
ww
w.
w .
t
t
n k
quantitatively
ww
nka
alv
3.Give the structural

l v
Tnkalvi.Net
i.ne
a)m-dinitrobenzene
t
i.necontaininglvnitrogen
t
w.
w
ww
.
t
converted
ww
t
n k
nka
a
l v
i.ne
formula
i.ne
t
t
is heated
w.
to ammonium
ww
w .
t
ww
t
n k
nka
alv
for the following

l v
b)p-dichlorobenzene
i.ne
t
i.ne with Conc.
w
w.
sulphate
ww
.
t
t
n k
.
nka
ww
alv
compounds.
l v i.ne
t
i.neH2SO4, thelvnitrogen
t
ww
w.
w
t n k
(mar 19)
. t nka
a
ww
l
c)1,3,5,Tri-methyl v
i.ne
i.ne
t
t
ww
in italvis
w. t n
(compulsory
Benzene
w .t nka
k
l
ww
v
i.ne
i.ne
t
t
ww
w. t
3 mark) t
w .t
n
nka
k alv
i.ne
lvi.
ne
t
ww
ww
ww
n vi.n
t 4.Identify.nthe et cis and trans et isomers for etthe following et compounds e(mar
t 19) .net net
i.ne vi vi.n vi.n vi.n vi.n i lvi.
alv al al al a l al alv a
w .tnk a) w .tnk w .tnk w .tnk b) w .tnk w .tnk w .tnk
w
w w w w w w w
w w w w ww ww
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk
t TRANS
et net net net net
CIS et net
i.ne lvi. lvi. i.n lvi. lvi. vi.n lvi.
alv a a alv a a al a
5.Write
ww
the IUPAC
.tn k
ww
names for wthe
w.t following wcompounds.
n k .tnk w.t
nk (mar
ww
.tn 19)
k
w .tnk w .tn k
w w w w w ww ww ww
l
(A) (B)
t t et t t et et net
i.ne vi.n
e
vi.n i.ne i.ne vi.n i.n lvi.
alv n kal 2-methyl
.tn
butane.tnk
kal alv nk alv
.tnk
al2,2-dimethyl propane
.tnk
alv
.tnk
a
w.t w w w.t w w w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 47
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
6. Write any two different components you get during fractional distillation of coal tar at any
i.ne
t two ldifferent
vi.n
et temperatures.
lvi.
net (marlvi.19) net
lvi.
net
lvi.
net
lvi.
net
lvi.
net
w.t
S.NO Namewwof w.t the fraction w.t Temperature w.t range www.t Name ofwwthe w.t components w.t
ww ww ww ww ww
t
1 t
Crude tightt oil t
350-443k t Benzene, t
toluene,xylene
i.ne . n e . n e . ne . n e . n e net net
alv lvi lvi lvi lvi lvi lvi. lvi.
2
w.t
n k a Middle
w.t
n k a oil w.t
nk a 443-503k
w.t
n k a
w.t
n k a Phenol,naphthalene
w.t
n k a
w.t
n ka
3 Heavy oil 503-543k Napththalene,cresol
alv
i.ne
t 4 alvi.net Green alv
i.oil
net
alv
i.ne
t 543-633k net
alv
i.
alv
i.ne
t Antharacenealv
i.ne
t
alv
i.ne
t
ww 5 ww Pitch ww Alone
ww 633k ww residue
ww ww ww
t t t t t t t t
7.Howw .tnk do you detect w .tnk the presence w .tnkof nitrogenw.and tnk sulphur together
w .tnk in an organic
w.tnk w .tnk
compounds ? ( jun19) (ipn : 139)
t naetsuitable method net net net net net net
alv
i.ne 8.explain a lvi. alvi.
for purifying
a lvi.
and separating
a lvi.
liquids a
present
lvi.
in a amixture
lvi.
having a lvi.
n k n k .tn k n k n k tn k n k
w.t w.t w.t w.t w.t
wwvery close boiling ww ww
point. ( wjun19) (ipn : 150)
ww (fractional ww distillationww )w. ww ww
t
9. Write thet IUPAC names t
for the following t
compounds t
: ( jun19)t t t
alv nk alv nk alv nk alv nk alv nk alv nk alv nk alv
t
(x) t t
(Y) t t t
(Y) t t
i.ne i.ne i.ne i.ne i.ne lvi.
ne i.ne i.ne
alv k alv
5-oxohexanoic acid k alv k alv
4-chloro alv
pent-2-yne
k a 2-ethoxyalv propane alv
w.t
n
w.t
n
w.t
n
w.t
n
w .tnk w.t
n k
w.t
n k
alv
alv
i.ne
i.ne
t
t 10.Explain
11. w.
12.Give
ww
t
.tnw
n k alv
wwExplain the w
t
Tnkalvi.Net
i.ne geometrical
. tn
method (sep20) (ipn : 149 )

k a
i.ne
lvthe
t
general.tn
ww
k
k
alv
purification
ww
w
i.nisomerism
lvi.
formula
a
et
net
for
t
the
.tn
n k
k
ini.n2-butene.
alv
ofwwaw.solid organic
a
ww
w
et
i.ne
t
lvfollowing
w. t n
(sep20)
class
.tn k
k
a
alv
ww compound wby
i.ne
net
t (ipn :135
. t n k alv
lvi. of organickacompounds
ww
.tn
w
i.n)
lvi.
et (compulsory
ww crystallization
net
ww
w. t
.tn
ww
w
n
k
k
a
alv
i.ne 3 mark)
lvi.
(sep21)
t
net
ww
w. t
.tn
n
k
k
a
alv
i.ne
lvi.
ww
w
net
t
ww
w
ww
ww
a) Alkanes b) Alkenes c) Alkynes
t t t net et et et et
i.ne vi .ne vi .ne lvi. vi.n vi.n lvi.
n vi.n
alv kalnH2n+2
nC kalnH2n
nC k a CH al al nka al
w.t w.t w.t
n n 2n-2 w .tnk w .tnk w .t w .tnk
13.What is meant by homologous series ? (sep21) (ipn : 112)
t t t t t t net net
i.ne i.ne i.ne i.ne i.ne i.ne lvi. lvi.
alv 14.Give lv
nka the structure
lv
nkafor the following
nka
lv
compounds
nka
lv
. (sep21) nka
lv a a
w.t w.t w.t w.t w.t w .tnk w .tnk
1) 3-methylpentane
et i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
alvi.n
kalv 2) 2-methylpropan-2-ol
k alv k alv k alv alv alv alv
t n t n tn t n nk nk nk
w. w. w. w. w.t w.t w.t
ww 3) Propanone
3-methylpentane 2-methylpropan-2-ol Propanone
i.ne vi.n vi.n vi.n vi.n vi.n vi.n lvi.
alv kal kal al al al al a
w.t
n
w.t
n
w .tnk w .tnk w.tnk w .tnk w .tn k
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
t 7708543401
i.ne
t Page 48
i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
15.What is meant by optical isomerism ? (May22) (ipn : 137 )
i.ne
t 16.Givelvthe
i.ne IUPAC names
t
lvi.
net of the following
lvi.
net compounds
lvi.
net . (May22)
lvi.
net i. net vi.n
et
alv a a nka a a alv al
w .tnk w .tnk w.t w .tnk w.tnk w .tnk w .tnk
t et et et et net net t
i.ne vi.n lvi.
n vi.n vi.n2-bromo-3-methylbutane
lvi. lvi. i.ne
alv al nka al al a a alv
w .tnk w . t w .tnk w .tnk w.t
n k
w.t
n k
w .tnk
methoxymethane
t t t t net net net t
i.ne i.ne i.ne i.ne lvi. lvi. lvi. lvi.
ne
alv nka
lv alv a lv a nka a nka
2-hydroxybutanal
i.ne
t
vi.n
et net vi.n
et net4-chloropent-2-yne net vi.n
et
vi.n
et
alv l lvi. al lvi. lvi. al l
nka nka .tnk n k a n k a
.tnk nka
w.t w.t w w.t w.t w w.t
t v) CHn2et= CH – CH n=et CH2 et net

1,3-butadiene
net et et
i.ne vi. vi. vi.n vi. lvi. lvi.
n vi.n
alv kal kal kal kal nka nka al
.tn .tn .t n .tn .t .t .tnk
w ww w ww w ww
w ww ww w w
ww
w
ww
17.Which element exhibits maximum catenation and whyw ? w
(ipn : 110)
t 18.Give an etexample for each
et of the following et type .nof et organic compounds et (jul22) t net
i.ne vi.n vi.n vi.n vi vi.n i.ne lvi.
alv k a l k a l k al k a l k a l k alv nka
(compulsory
ww
w.t
n 3 wmark)
ww
.t n
ww
w.t
n
ww
w.t
n
ww
w.t
n
ww
w.t
n
ww
w.t
ww
i) Non-benzonoid aromatic compound
alv
alv
i.ne
i.ne
t
t
ww
w w
w.t
w
nk
.tnk
alv
alv
i.
Tnkalvi.Net
i.ne
net
t
ii) Aromatic
w.t
ww
w.t
nka
kal
lvi.
vi.
n heterocyclic compound
ww
n
w
et
net
ww
azulene
ww
w.t
w
nk
.tnk
al
alv
i.ne
vi.n
et
t
ww
ww
w.t
nk
.tnk
alv
alv
i.n
i.ne
et
t
ww
ww
w.t
w
nk
.tnk
alv
alv
i.
i.ne
net
t
ww
ww
w.t
w.t
nk
nka
alv
lv
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
n vi.n

w .t n
w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
iii) carbocyclic compound
t et t t t t t t
i.ne vi.n i.ne i.ne i.ne i.ne i.ne i.ne
alv n kal nk alv n k alv nk alv nk alv nk alv nk alv
w.t w.t w. t w.t w.t w.t w.t

alv
.tn k a cyclopropane
.tnk
alv
.tnk
al
.tnk
al
.tnk
alv
.tnk
al
.tn ka
w w w w w w w
et
19. Describe
et
any two types
et
of constitutional
et
isomers.
et
(jul22) (ipnet: 132)
i.n i.n vi.n i. n vi.n vi.n i. net vi.n
et
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
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i.ne
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i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
12.Basic Concepts Of Organic Reactions
w .tnk w .tnk w.t
n k
ONE MARKS ;-
i.ne 1.Which i.n i.n species does i.n not exert alvresonance
i.n i.n vi.n i.ne
alv alv of the following
alv alv a effect
alv ? (mar.tn19)
kal alv
.tnkw .tnk .tnk
w .tnk w.tnk w w w w .tnk
a) C6H5NH2 b) C6H5NH3+ c) C6H5OH d) C6H5Cl
i.ne i.n i.n vi.n i.n i.n lvi. lvi.
ne
alv 2.Which
.tnk
alv of the following
.tnk
alv species.tnis
kal not electrophile
.tnk
alv in naturenk?alv(jun19)
.t .tnk
a nka
w w w w w w w.t
+ + +
a) Cl b) BH3 c) H3O d) NO2
t et et t et t net net
i.ne vi.n vi.n i.ne vi.n i.ne lvi. lvi.
alv 3.Whichnka of the following
l
nka
l is electron lv
nka deficient .?nk(sep20)
al nk alv nka nka
w.t w.t w.t wt w.t w.t w.t
a) NH3 b) PH3 c) (CH3)2 d) BH3
alv l
4.The geometrical shape of carbocation
nka
l
is (sep21)
nka al kal al al nka
l
w.t w w.tw.t
n .tnk w.tnk w .tnk w.t
a) planar b) linear c) pyramidal d) tetrahedral
t t t t t net et et
i.ne lvi.
ne
lvi.
ne vi.n
e
lvi.
ne
lvi. lvi.
n vi.n
5.The
ww
correct relative
.tnk
ww
order of w+I
w.t
neffect of alkyl groups is : .(May22)
.tnk
ww ww
t .tnk n k
w .t w .tnk
w w w w w ww ww ww
a) -C(CH3)3>-CH(CH3)2>-CH2CH3>-CH3 b) –CH3>-CH2CH3>-CH(CH3)2>-C(CH3)3
i.ne vi.n lvi.
n
lvi. lvi. i.ne lvi. i.ne
alv al alv alv
w c) .tnk -CH2CH >-CH3>-C(CH 3w.tn
ka
) >-CH(CH ) nka
w.t3 3 3.tn2
ww
ka d) –CH(CH ) >-C(CH ) >-CH2CH >-CH
n k
w.t 3 2 3 .t3n
ww
ka
3 w.tn k
3
ww www w w w w w ww ww
Tnkalvi.Net
6.-I effect is not shown by (jul22)
t t et t t t t t
i.ne i.ne lvi.
n i.ne i.ne i.ne i.ne i.ne
ww
a) -CH2CH
w.t 3 w.t
ww
b) -F
ww
w.t
ww
w.t c) -Cl ww
w.t
ww
d) -NO2
w.t
ww
w.t
ww
t
2&3&5 MARKS
t
:-
i.ne i.ne et et et net i.ne
t e t
alv alv l vi.n al vi.n alv
i.n
alv
i. lv l vi.n
1.w Explain withwexample
w w w the positive mesometric
w.t
ww
w effect. w(mar
ww 19) ( ipnw:w 169 )
ww
w w.t
ww
w.t
ww
t
2. What areet nucleophileset and electrophiles
et
? give one
et
example each
et
(mar 19) (etipn : 164 ) et
n vi.n
t 3. t (mar 19) ( ipn : 174 )

i.ne ne net ne t
i.ne
t net et n net
alv lvi. lvi. lvi. lv lvi. lvi. lvi.
nka nka nka nka nka .tnk
a
.tnk
a
w.t w.t w.t w.t w.t w w
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk
Amide carboxylic acid
t et et et et net et net
i.ne vi.n vi.n vi.n vi.n i. vi.n lvi.
alv kal kal al al alv al a
4.The
ww
.tnbond lengthw.between
w
tn allwthe
w
four carbon
ww
atoms is same in 1,3-butadiene.
ww
Explain
.tnk
ww
.tnk
w w.tnk .tnk .tn k
w w w w w w w ww
(compulsory 3 mark) ( jun19) ( ipn : 168 )
t t net t t et net et
i.ne vi.n
e
lvi. lvi.
ne
lvi.
ne vi.n i. vi.n
alv kal a nka a al alv nka
l
1,3-butadiene
ww
.tn iswaw conjugated wmolecule
w.t withwwfour overlapping
.tnk
ww
p-orbital won
w adjacent .tnk .tnk .tnk
ww.t
w w w w w w w ww
atoms,and a electrons are delocalised over four atoms. This shortens the bond length of
i.ne lvi.
n
lvi.
n vi.n
e
lvi. vi.n lvi. lvi.
central c bond thus,
w.t w the bond length
w between .tnk
all the four-c-w atoms are same .tnk
in 1,3-butadiene
w w.t .tnk w.t .tnk
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
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i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww w ww ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
5. explain about inductive effect . ( jun19) ( ipn : 166 )
t t t t t t t et
i.ne 6.Write e ne
vi.n no bond resonance
lthe structure ne
shownnkby i.ne ne ne vi.n
alv nka nka
lvi.
nka
lvi. alv propene (sep20)
nka
lvi. ( ipn : 170
nka
lvi. ) al
w.t w.t w.t w.t w.t w.t w .tnk
7.Give any three differences between nucleophiles and electrophiles. (May22) ( ipn : 164 )
i.ne 8. complete i.n ( ipn i.n i.n vi.n lvi.
ne vi.n i.ne
alv alv a:lv173,173,173,173
alv ) al nka al alv
.tnk
w .tnk
w .tnk w w .tnk w . t w .tnk w .tnk

i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne
w.t w .tnk
A) w .tnk w .tnk
(sep20) w.t w .tnk w.t

B) H2C=CH2 + H-Br
alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
ww ww ww
C) CH3CHO ww w w ww ww ww
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
n k
w .t w .tnk

i.ne vi.n lvi.
n
alv
alv
i.ne
i.ne
t
t
ww
w w
w.t
w
nk
.tnk
alv
alv
Tnkalvi.Net
i.ne
i.ne
t
t
ww
ww
w.t
w.t
D) lvi.net
nka
9.Write short notes on hyper conjugation (jul22) ( ipn : 170 )
nka
l vi.n
et
ww
ww
w.t
w
nk
.tnk
al
alv
i.ne
vi.n
t
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.ne
i.n
t
et
ww
ww
w.t
w
nk
.tnk
alv
alv
i.
i.ne
net
t
ww
ww
w.t
w.t
nk
nka
alv
lv
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
n vi.n

w .t n
w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
i.ne
t
i.ne
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i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
w
13.Hydrocrbons
i.ne
t ONE MARKS
lvi.
net ;- i. net
lvi.
net vi.n
et
vi.n
et i. net vi.n
et
alv a alv a al al alv al
w .tnk w .tnk w.t
n k
ww
1.______group isw ortho para directing
w ww ww
and deactivating ww
group (jun19) ww ww ww
alv
i.ne
t
al vi.n
et a) amino
alv
i.ne
t
al vi.n
et
al vi.n
et b) amethyl
lvi.
net
al vi.n
et
alv
i.ne
t
w .tnk w.t
nk
w .tnk w .tnk w.t
nk
w .tnk w .tnk
ww w ww ww ww
c) whalogen d) aldehydeww ww ww
t net alkaline vKMnO t t et net net t

alv
i.ne 2.Cold adilute
lvi. al
i.ne 4 is known
alv
i.ne as ______
alv
i.n(sep20) lvi. lvi. lvi.
ne
nk .tnk .tnk .tnk nka .tnk
a nka
w.t w w w w.t w w.t
a) Schiff”s reagent b) Fenton”s reagent
t et et t et t t net
i.ne vi.n vi.n i.ne vi.n i.ne i.ne lvi.
alv
w.t
nk al c) Tollen‟s
w .tnk
al reagent nkalv
ww
.t w.t
nk al
w
d)
.tnk Baeyer’s reagent
alv
w.tnk
alv
w.t
nka
ww ww w ww w w w w ww ww
3.n-propyl bromide on rection with alcoholic KOH gives (sep20)
alv nka
l
nka al a al al nka
l
w.t w.t .tnk w.t
n k .tnk .tnk w.t
ww a) Butyl alcoholwww
ww ww w w w
b) Propene
ww
w
ww ww
i.ne
t
vi.n
etc) Butenevi.net n et
vi.n
et d) vPropyl
i.ne
t alcoholvi.net vi.n
et
alv al al lvi. al l l al
.tnk .tnk t nka .tnk nka nka .tnk
w w . w.t w.t
4.An
ww alkene is obtained
ww by decarboxylationwwofw sodium propionate.same
ww ww
ww
w
alkene can bewww ww
i.ne
t prepared
lvi.
net by : (sep21)
lvi.
net
lvi.
net
lvi.
net
lvi.
net
lvi.
net
lvi.
net
alv a a nka a nka a nka
ww ww of 1-chloro
wwpropane ww ww ww ww ww
a) reduction b) catalytic hydrogenationwof propene
alv
alv
i.ne
i.ne
t
t
w w
w.t
w
nk
.tnk
alv
net
Tnkalvi.Net
c)alvi.reduction
5.wwIdentify the compound
ww
i.ne
ofalvbromo
i.ne
t methane
w.t
(A) in the following
t
ww
w.t
alv
nk
nka
i.ne
l
t
ww reaction : (jul22)
vi.n
et
ww
ww
w.t
w
nk
.tnk
al vi.n
et
d) action
ww
alv
w.t
w
i.ne of sodium
nk
.tnk
t
alv
i.n
alv
i.metal
et
net
ww
ww
w
on iodomethane
w.t
nkalv
i.ne
.tnk
alv
t
i. net
ww
ww
w.t
w.t
nk
nka
lv i.ne
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
n vi.n

w .t n
w .tnk w .t n k
w .tnk w .t n k
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk
2&3&5 MARKS :-
alv 1.How will you get
k a the following products with alv
the given reactants ? (mar 19) al al alv al a
w .tn w w w .tnk w .tnk .tnk w.tnk .tnk w .tn k
A)Acetylene  Benzene (ipn :204 )
alv alv l alv al al alv l
w .tnk B)Phenol .tnka Benzene (ipn : 210 ) .tnk .tnk .tnk .tnk w.t
nka
ww w ww ww w ww
w
ww
w
ww
w
w w ww
C)Benzene Tolune (ipn : 210 )
i.ne lvi.
n
lvi.
n vi.n
e
lvi. vi.n lvi. lvi.
i.ne
i.ne
t
i.ne
t PG
i.ne
t ASST IN CHEMISTRY
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alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
2.The simple aromatic hydrocarbon compound (A) reacts with bromine to give (B).
t t t t t t t t
i.ne compound
lvi.
ne
(A) reacts ne
lvi. with Raney
ne
lvi. Ni and gives
ne
lvi.(C). Identify i.ne , (B) andlv(C).(MAR19)
lv(A) i.ne lvi.
ne
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne

i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne

alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
w .tnk .tnk .t .tnk w.t
n k .t .tnk
ww www ww
w ww
w ww ww w
ww
w
ww
S.NO COMPOUNDS FORMULA NAME
t et et net et net et net
i.ne vi.n lvi.
n
lvi. i.n lvi. i.n lvi.
alv
.tnk
al 1 .tnk
a A nka C6.H
tnk6
alv nka Benzene
.tnk
alv nka
w w w.t w w.t w w.t
Tnkalvi.Net
2 B C6H5-Br bromobenzene
t et et et et et t t
i.ne i.n vi.n i.n i.n i.n i.ne i.ne
alv nk alv n kal nk alv nk alv nk alv nk alv nk alv
w.t 3 w.t C w.t w.t
C H12 w.t w.t
cyclohexane w.t
ww ww ww ww6 ww ww ww ww
e
alv alv nka
l al alv alv nka
lv
nka
l
w
3.What
w happenswwwhen acetylene undergoeswozonolysis
w ww
? (wwjun19) (ipn :w203
w
) ww ww
t et t t t t t et
alv
i.ne 4.Whatalis
vi.npolymerisation
alv
i.ne ? explain lthe
av
i.ne two types lof
av
i.nepolymerisation
alv
i.ne rection of
alv
iacetylene
.ne . al vi.n
w .tnk w .tnk w .tnk w .tnk w .tnk w.t
nk .tnk
( jun19) (ipn w: 204 )
t t t et et et et et
alv
i.ne 5. What
kal
vdo
i.ne you mean lvby
ka
i.ne conformation
kal
vi.n ? Explainalabout
k
vi.n staggered
kal
vi.n conformation
kal
vi.n in ethane a.lvi.n
k
n n n n n n n
( jun19) (ipn : 187 )
t et et et et t net net
i.ne 6. An organic
vi.n compoundvi.n (A) of molecular
vi.n formula i.ne
vi.n C2H6O, onalvheating withkaconc.H
lvi. 2SO4 kalvi.
alv kal n kal kal n kal k n n n n n
gives compound (B) . (B) on treating with cold dilute alkaline KMnO4 gives compound
t t t t t t et net
i.ne . Identify ne
lvi. (A), (B) kand
ne
lvi. (C) and explain
lvi.
ne ne
the reactions.(JUN19)
lvi. lvi.
ne vi.n lvi.
alv nka n a nka nka nka al a
w.t w.t w.t w.t w.t w .tnk w .tn k
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
i.ne
t
i.ne
t PG
i.ne
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i.ne
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alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww www ww ww ww
w
ww www ww
n k .tnk .tnk
ww
w
ww
w
ww
w
ww
w
ww ww
w
Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t

w .tnk w .tnk w.t
n k
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne vi.n i.ne

i.ne lvi.
n i. lvi.
n
lvi. lvi. lvi. lvi.
ne
w.t .tnk .tnk .tnk w.t .tnk w.t
ww S.NO COMPOUNDS
ww
w
ww
w FORMULA
ww
w
ww NAME
ww
w
ww ww
alv
i.ne
t
alv
1i.net Anet
lvi. alv
i.ne
t C2H5OH
alv
i.ne
t
alv
i. net Ethanol
alv
i.ne
t
lvi.
net
nk nka nk nk nk nk nka
2 B CH2 = CH2 Ethene
alv nka
l
3 nka C al HO-CH -CH -OH a al Ethane-1,2-diol al nka
l
w.t w.t w .tnk 2w.tn k
2 w.tnk .tnk w.t
ww ww ww ww w w ww
w ww ww
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
.tnk .tnk .t .tnk w.t
n k .t .tnk
7.Explain
ww
w the different
ww
w types of polymerisation
ww
w in ethyne. w
w (sep20) (ipn w
ww
w : w204 ) w
ww
w
ww
t 8. write Brich
net
reductionne.t (sep20) (ipnne:t 215 ) net net net net
i.ne vi. lvi. lvi. lvi. lvi. lvi. lvi.
.tnk .tnk w.t .tnk w.t .tnk w.t
9.Complete
ww
w the wfollowing
ww : (sep21)
ww (compulsory
ww
w 2 mark)ww www ww ww
alv
alv
i.ne
i.ne
t
t
w w w.tnk
al
a).tnkCH
ww
alv
3-CH=CH
i.
ww
b) CH3MgCl + H2O
Tnkalvi.Net
vi.n
et
al
.tnk2 + H2
net
w
ww
w.t
nkal
vi.
vi.n
et
net
ww
ww
w.t
w.t
n
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vi.
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CH
w
w
w
Propane et
ww
w
kal
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v
w
2
alv
-CH
CH4 + Mg(OH)Cl
i.ne
3
w
i.n
w
t
.tnk
alv
w
ww
.tnk
alv
i.
i.ne
net
t
ww
ww
w.t
w.t
nk
nka
alv
lv
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nk
nka
l
alv
i.ne
vi.n
e t
t
ww
ww
n vi.n
w .tnk w .tnk w .tnk methane
ww
.tnk w .tnk w .t w .tnk
ww ww ww w ww ww ww ww
i.ne
t 10.Suggest
vi.n
eta simple chemical
vi.n
et test tovi.distinguish
net propane
vi.n
et and propene
vi.n
et (sep21)vi.(b/b-39
net ) net
alv al al al al al al a lvi.
11.How does Huckel rule help to decide the aromatic character of a compound?
t t t t t t et t
i.ne i.ne i.ne i.ne i.ne i.ne i.n i.ne
alv
.tnk
alv nk alv n k alv nk alv nk alv (sep21)(ipn
.tnk
alv: 205 ) nk alv
w w.t w. t w.t w.t w w.t
12.Write the rection for conversion of acetylene to benzene. (sep21) (ipn : 210 )
t net net net net net et net
i.ne lvi. lvi. lvi. lvi. lvi. vi.n lvi.
alv 13.How nka will you convert
nka ethyl chloride
nka to ethane nka ? (May22).tnka al a
w.t w.t w.t w.t w w .tnk w .tn k
Zn/HCl [H]
l
w
CH3-CH2-Cl
.tnk
ww
.tnk w .tnk w.tnk CH3-CH + HCl 3 .tnk
ww w .tnk w.t
ww w ww ww w ww w w ww
ethyl chloride ethane
t t et t t et net net
i.ne vi.n
e
vi.n i.ne i.ne vi.n lvi. lvi.
alv kal kal alv alv al nka a
w.t
n
w .tn w .tnk w.t
nk
w .tnk w.t w .tnk
i.ne
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t
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t PG
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t ASST IN CHEMISTRY
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t
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i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
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lv
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
14.what happens when ethylene is passed through cold dilute alkaline potassium
i.ne permanganate
lvi.
ne
? i. ne
(May22) (ipn ne
lv:i. 198 ) vi.n vi.n i. vi.n
alv nka alv nka al al alv al
w.t w .tnk w.t w .tnk w .tnk w .tnk w .tnk
15. How will you prepare the following compounds from benzene ? (May22)
t et et et et t et et
i.ne vi.n lvi.
n vi.n vi.n lvi.
ne i.n
(ipn : 211,212,215 ) .tnkalvi.n
alv al nka al al nka alv
w .tnk w . t w .tnk w .tnk w . t .tnk
w w
i)nitrobenzene ii)benzene sulphuric acid iii)BHC
i.ne ne
alvwill you prepare ethane .tby
nka Kolbe”s electrolytic method alv ? (jul22) (ipn
i.n i.n lvi.
n i.n i.n i.n lvi.
alv 16.How
.tnk .tnk
alv
.tnk
alv
.tnk .tnk
alv :201 ) nka
w w w w w w w.t
17.Explain Brich reduction (jul22) (ipn : 215 )
t t t t t t t t
i.ne lvi .ne lvi lvi .ne lvi .ne
lvi (A) on reaction
lvi .ne .ne .ne .ne
alv 18. An
w.t
nkaorganic compound
w.t
nka (A) C2H4
w.t
nka decolourises
w.t
nka bromine water.
w.t
nka
w.t
nka withw.tnkalvi
chloride gives (B) . (A) reacts with HBr to give (C) . identify (A), (B) and (C) explain
alv l
the reactions. (jul22)
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
n k
w .t w .tnk

i.ne vi.n lvi.
n
alv
alv
i.ne
i.ne
t
t
ww
w w
w.t
w
nk
.tnk
alv
alv
S.NO
Tnkalvi.Net
i.ne
i.ne
t
t
ww
ww
w.t
w.t
nka
COMPOUNDS
nka
l
lvi.
vi.n
n et
et
ww
ww
w.t
w
nk
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al
alv
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vi.n
t
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ww
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FORMULA
w.t
nk
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alv
i.ne
i.n
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ww
ww
w.t
w
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alv
alv
i.
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NAME
w.t
w.t
nk
nka
alv
lv
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i.ne
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w.t
w.t
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alv
i.ne
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t
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t et
alv
i.ne
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vi.n alv Anet
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CH2 = CH vi.n
kal 2
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al vi.n
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vi.n
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al vi.n
et
w .tnk w .tnk w .tnk w.t

n
w .tnk w.t
n
w .tnk
2 B Cl-CH2-CH2-Cl 1,2-dichloroethane
t t t t net t net net
i.ne i.ne i.ne i.ne lvi. i.ne lvi. lvi.
w .tnk 3 w .tnk C w .tnk CHw3w-CH
w 2-Br.tnk w .t n k
bromoethane
w .tnk w .tnk
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk

l

nka .tnk
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t PG
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t ASST IN CHEMISTRY
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t
alv nka
lv
nka
lv
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Tnkalvi.Net
ww
w
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
ww
w ww
14.Haloalkanes And Haloarenes
ww ww ww ww ww ww
t t t t t t t t
i.ne ONEtnMARKS vi.n
e
;- tnkalvi.ne lvi.
ne
lvi.
ne
lvi.
ne
lvi.
ne
lvi.
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alv kal nka nka nka nka nka
w . w . w . t w . t w . t w . t w . t
1.match
ww the following ww (mar 19) ww ww ww ww ww ww
t
Compound t t
uses
i.ne i.ne i.ne net net net net net
1)Chloro
w.t
n k a picrinw.tn k a i) detection
w.t
nk a of primary w.t
n amine
k a
w.t
n k a
w.t
n k a
w.t
n k a
2)Methyl isocyanide ii) DDT
t 3)Chlolro t benzene net iii) paint remover t t t t t
i.ne i.ne i. i.ne i.ne i.ne i.ne i.ne
ww4)Meythylene ww chlorine iv) wwsoil sterilizerww ww ww ww ww
t
a) (1)- (iv), (2)-(iii) , (3)-(ii), (4)-(i) t b) (1)- (iii), (2)-(iv) , (3)-(ii), (4)-(i) t
i.ne i . net i . net i . ne i . net i . net i.ne i.ne
t
alv c) w.tn(1)- v
kal (i), (2)-(ii) n k
v
a,l (3)-(iv), (4)-(iii) n k al v
d) (1)-
n k
v
al (iv), (2)-(i) n k
v
a,l (3)-(ii), (4)-(iii) n k alv n k alv
w. t w. t w. t w. t w. t w. t
2.The raw material for rasching process is _______ (jun19)
i.ne
t a) chloro lvi.
net benzene vi.net b) phenol lvi.
net c) lbenzene vi.n
et
lvi.
net d) anisole lvi.
net
lvi.
net
alv k a k al k a k a k a k a k a
.tn w.t
n
w.t
n
w.t
n
w.t
n
w.t
n
w.t
n
3.wmatch
ww the following ww (sep20) ww ww ww ww ww ww
1)Iodoform i) Fire extinguisher

i.ne i . n
lv2)Carbon
e
lvi . n e
alv n k a tetrachloride
n k a n k aii)Insecticide n k a n k a n k a n k a
3)CFC iii) Antiseptic
i.ne
t 4)DDT
i.ne
t
i.ne
t iv)Refrigerants
i.ne
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
a) w.t w.t , (3)-(iv), w w.t .t w.t .t w.t
ww (1)- (iii), (2)-(i) ww w (4)-(ii) wb)
ww (1)- (ii), (2)-(iv) ww , (3)-(i),w(4)-(iii)
ww ww ww
c) (1)- (iii), (2)-(ii) , (3)-(iv), (4)-(i) d) (1)- (i), (2)-(ii) , (3)-(iii), (4)-(iv)
alv
alv
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i.ne
t
t
4.Of .the
ww
w t
5.Assertion
ww
w.t
nka
n ka lvi.
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i.n
lvfollowing
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ww
w. t
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: Inwmonohaloarenes,
ww
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ww
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net
(sep21)
ww
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a
i.ne
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ww
ww
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w.t
t n
n
k
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alv
a
i.ne
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t
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ww
ww
Reason : Halogen atom is a ring deactivator (May22)
t net t net net net net net
i.ne a)lvi. Assertion i.netrue but reson
lvis lvi. is false kalvi. lvi. lvi. lvi.
alv n k a k a k a k a k a k a
w.t .tn .tn w.t
n
w.t
n
w.t
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ww ww ww
b) Both wassertion and wreason are truewwand reason iswwthe correct explation ww ww
of assertion ww
t c).neBoth t assertion et and reason i.are et false t t t t

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ww
w.t
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ww
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n
ww
w.t
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ww
w.t
n
ww
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t t t t t t t t
i.ne 6. Assertion e
: Increasing i.ne order of boiling i.ne points kof i.ne i.ne i.ne i.ne
alv halo alkanes alvare
i.n
alv n k alv n k alv n k alv n n k n k alv n k alv
ww wwCH3Cl < CH ww 2Cl2 < CHCl ww 3 < CCl ww 4 ww ww ww
t Reason net
: The boiling net
points of halo net
alkanes increase net
with increase net
in the number net
of net
alv a a a a a a a
w.t
n k halogen
w.t
n k atoms (jul22) w.t
n k
w.t
n k
w.t
n k
w.t
n k
w.t
n k
a) Assertion is true but reason is false
t t net net and reason net net explanation net net
i.ne b) both lvassertion
i.ne and lvi.reason arekatrue lvi. lvi. is the correct lvi. lvi. of assertion lvi.
alv n k a n k a n n k a n k a n k a n k a
c)wwBoth Assertion ww and reason ww are false ww ww ww ww ww
et
d) both assertion et
and reason et
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reason is not et
the correctetexplanation of et
assertion et
i.n lvi.
n
lvi.
n vi.n lvi.
n vi.n lvi.
n
lvi.
n
alv a nka nka
l a nka
l
nka nka
.tnk w.t .t .tnk .t .t .t
w ww ww w ww w ww w ww w ww w ww ww
i.ne
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t
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t PG
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alv nka
lv
nka
lv
nka
lv
nka
lv alv nka
lv
nka
lv
w ww w ww ww ww ww
w
ww w ww ww
n k .tnk .tnk
ww
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ww
w
ww
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Tnkalvi.Net
ww
w
ww
t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t
2&3&5 MARKS :-
i.ne
t 1.how is ialkane net
prepared net
from Grignard net
reagent ? i(mar net
19)(ipn :i.n241 et ) net net
alv lv . lvi. lvi. lv . lv lvi. lvi.
n note on Williamson‟s synthesis. (mar w19)
k a k a k a k a k a k a k a
2.Write
w.t w.t
n
w.t
n .tn (ipn : 234 w.t )
n
w.t
n
w.t
n
3. Among the following compounds ,o-dichloro benzene and p-dichloro benzene , which has
i.ne
t higher nemelting
t point ne?
t explain with net reason . ( jun19) net (b/b-41(ii) net net net
alv k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. k a lvi. ka lvi.
4.Give
ww
w.t the structure
n
ww
w.t and uses of
n
ww
wDDT
.tn . (sep20)
ww
w.t (ipn : 250 ww
n
w
).tn ww
w.t
n
ww
w.t
n
ww
5.explain the mechanism involved in the elimination reaction of tertiary butyl chloride with
i.ne
t alcoholic i.ne KOH. (sep20)
t
i.ne
t (ipn : 237 i.ne)
t
i.ne
t
i.ne
t
i.ne
t
i.ne
t
.t w.t w.t HBr to form w.t .t w.t w.t
6.wSimplest
ww alkene
ww (A) rects with ww ww compoundw(B). ww Compound ww (B) reacts ww ww
with ammonia to from compound (C) of molecular formula C2H7N. Compound
t t et et et et et et
i.ne (C) i.ne
vundergoes carbylamines
vi.n test. vi.nIdentify (A), vi.n(B) and (C). vi.n (sep21) (lesson vi.n 13& 14) vi.n
alv kaln kal n kal n kal kal n kal n kal n n
alv nka
l
nka al a al al nka
l
w.t w.t w .tnk w.t
n k
w.tnk w .tnk w.t
B
t t t t t net et et
i.ne lvi.
ne
lvi.
ne vi.n
e
lvi.
ne
lvi. lvi.
n vi.n
w .tnk w .tnk w.t
n
w .tnk w.t
n k
w .t w .tnk

i.ne vi.n lvi.
n
Tnkalvi.Net
i.ne
t S.NO
i.ne
t COMPOUNDS
i.ne
t
i.ne
t FORMULA
i.ne
t
i.ne
t NAMEi.net i.ne
t
alv nka
lv
nka
lv
nka
lv
nka
lv
nka
lv
nk alv nk alv
ww 1 ww A ww CHww2 = CH2 ww ww
Ethene ww ww
t et et et et net et t
i.ne 2i.n vi.n
B vi.n CH3-CH vi.n i. i.n vi.n
e
alv alv nka
l al a2l-Br alv Bromoethane
alv nka
l
w.tnk w.t w .tnk .tnkw w .tnk .tnk
w w.t
3 C CH3-CH2-NH2 Ethylamine
t t net t net t et et
i.ne lvi.
ne
lvi. lvi.
ne
lvi. lvi.
ne
lvi.
n vi.n
alv a a a a a nka al
w .tnk w.t
n k
w .tnk w .tnk w .tnk w .t w .tnk
7.Write short notes on Swarts reaction ? (sep21) (ipn : 231 )
i.ne
t 8.Complete
lvi.
net the following
lvi.
net reactions v.i.(May22)
net (ipn
lvi.
n:et243,244 ) v(compulsory
l i.
net 2lvi.nmark)
et
lvi.
net
alv a l a a a a a a
t t t t t t t t
w .tnk w.t
nk
w. tn k
w.t
nk
w.t
nk
w.t
nk
w.t
nk
ww
9.Simlest alkeneww(A) reacts with ww HCl to form ww compoundsw(B) w
.compounds ww (B) reactswwithw ww
t
ammoniat to form compound t
(C) of moleculart
formula t
C2H7N compounds t
(C)t undergoes t
alv carbylamines
.tnk
a lv test.
.tnk
Identify
a lv (A),(B)
.tnk
a and (C). (May22)
l v
.tnk
a l v
.tnk
al v
.tnk
alv
.tnk
alv
w w w w w w w
l

nka .tnk
a
a
w.t w w w.t w w.t w
i.ne
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t
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t PG
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alv nka
lv
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lv
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Tnkalvi.Net
ww
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t t
11TH
t
CHEMISTRY
et
PUBLIC
et
QUESTIONS
et t

w .tnk w .tnk w.t
n k
t
S.NO
et
COMPOUNDS
et t
FORMULAet NAME
i.ne i.n vi.n i.ne vi. n net vi.n
et i.ne
t
alv alv kal alv kal lvi. al alv
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w w.t w . t
ww 1 ww A ww CHww2 w= CH2 ww
w
ww
w
Ethene ww
w
ww
t et
alv
i.ne lvi.2n
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i. lvi.
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lvi.
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kal
vi.n
et
lvi.
ne t
nka .tnk .tnk
a
.tn nka .tn nka
w.t w w w w.t w w.t
3 C CH3-CH2-NH2 Ethan amine
10. A simple aromatic hydrocarbon (A) reacts with chlorine to give compound (B) .
i.ne compound lvi. (B) reacts lvi.with ammonia lvi. to give compound lvi. (C) whichlvi. undergoes lvi. carbylamines lvi.
.tn w.t
n
w.t
n
w.t
n
w.t
n .tn w.t
n
ww
wreaction. ww
Identify (A), (B) and ww (C) and explain ww ww
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i.ne vi.n vi.n lvi.
n vi.n lvi. lvi.
n vi.n
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i.ne vi.n lvi.
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i.ne
i.ne
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t
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t et t net t t t net

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11TH CHEMISTRY PUBLIC QUESTIONS

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