Blockbuster Problems Chemistry Qns

Contents
1. Some Basic Concepts of Chemistry
2. Atomic Structure 9-16
3. Periodic Properties and Chemical Bonding 17-22
4. Gaseous State 23-32
5. Chemical Energetics 33-40
6. Equilibrium 41-48
7. The Solid State 49-56
8. Liquid Solution 57-64
9. Electrochemistry & Redox Titration 65-72
10. Chemical Kinetics 73-82
11. Surface Chemistry 83-90
12. General Organic Chemistry 91-102
13. Isomerism 103-114
14. Hydrocarbons and Halogen Containing Compounds 115-126
15. Alcohol, Phenols, Ether, Aldehyde & Ketones 127-140
16. Carboxylic Acids & its Derivatives and Nitrogen

Containing Compounds 141-156
17. Biomolecules and Polymers 157-166
18. Hydrogen ands-Block 167-176
19. p-Block Elements 177-186
20. d & f-Block and Metallurgy 187-194
21. Co-ordination Compounds and Qualitative Analysis 195-204

Some Basic
Concepts of
Chemistry
~ MCQs with One or More than One Option Correct
1. 100 ml solution ofFeC2 O 4 and FeSO4 is completely oxidised by 60 ml of 0.02 M KMnO 4 in acidic
medium. The resulting solution is then reduced by Zn and dil. HCI. The reduced solution is again
oxidised completely by 40 ml of 0.02 M KMnO4 . What is molarity ofFeC2 O 4 in solution.
•
(a) 10-2 M (b) 10-3 M (c) 10---4 M (d) 2 x 10-2 M
EB
H PO undergo dissociation as H 3 PO4 ~ 3H + PO4- . If
3 n t·
ca ion
+ namon
·
= -8 then
2.
3 4 nH P (undissociated) 3 '
3 03
percentage dissociation of H 3PO4 w ill be
(a) 40% (b) 20% (c) 80% (d) 60%
3. When 'x' g carbon is burnt with 'y' g of oxygen in a closed box and no residue is left, which of the
following statement is correct regarding the relative amounts of oxygen and carbon?
(a) 2'.. must be less than 1.33 (b) 2'.. must be greater than 1. 33
X X
(c) 2'.. must be greater than 2.67 (d) 2'.. must lie between 1. 33 and 2 .67
X X
4. What is the% of free SO 3 in a sample of oleum labelled as 104.5%?

(a) 20% (b) 40% (c) 60% (d) 80%
5. Some amount of commercial AgNO 3 of 50% purity is dissolved in 50 ml of water. It is treated with
50 ml of KI solution. The silver iodide thus precipitated is filtered off. Excess of KI in the filterate is
. M . . . . . .
treated with 50 ml of ~ KI03 solution m presence of cone. HCl when all the 10dme 1s converted mto
10
ICI. 25 ml of the same stock solution of KI requires 30 ml of M KI03 under similar conditions. What
is the amount of AgNO 3 initially taken? 1O
(a) 0.68 g (b) 0.54 g (c) 0.45 g (d) 2 g

6. One mol of mixture of N 2 , NO 2 and N 2 O4 hasa meanmolarmass of 55 .4 g. On heating to a temperature,
at which all the N 2 O4 is dissociated into NO2 , the mean molar mass tends to a lower value of 39 .6 g.
What is the mol ratio of N 2 : NO 2 and N 2 O4 in the original mixture?
(a) 5 : 1 : 4 (b) 1:1 : 1 (c) 1:4 :5 (d) 1 : 5: 4
2 CHEMISTRY
7. 40gH2
40gmolecule 0 2
44.8 lit N 2 at STP
What amount of He should be introduced in this container so that resulting mixture should have
4.2154 x 1025 gaseous particles.
(a) 32 g (b) 36 g (c) 8 g atom (d) 9 g atom
8. A chloride mixture is prepared by grinding together pure BaC12 .2H2 O, KCl and NaCl. What is the
smallest and largest volume of 0.15 M AgNO3 solution that may be used for complete precipitation of
chloride ion from 0.3g sample of the mixture which may conatin any one or all of the constituents
(a) Smallest volume is 16.38 ml (b) Largest volume is 34.18 ml
(c) Largest volume is 16.38 ml (d) Smallest volume is 8.18 ml
9. A quantity of 0.22 g of a gas occupies a volume of 112 ml at pressure ofl atm and temperature of 273
K. The gas may be
(a) Nitrogen dioxide (b) Nitrous oxide (c) Carbon dioxide (d) Propane
10. Red ink is composed of eosin (molar mass 692). If 'YOGESH PATHAK' is written by red ink, it
weighs 1.73 x 10-10 g and 'VAIBHAV TRIVEDI' is written by graphite pencil, it weighs 3 x 10-12 g.
Select correct statements.
(a) Graphite particles are more than eosin particles.
(b) Eosin particles are greater than graphite particles.
(c) Both graphite and eosin have same number of particles.
(d) Mol percentage of 'Br ' in eosin is 10.8.
Br Br
Eosin
~ Numeric Value Answer

11. Consider the following reactions :
XeF2 + F2 ~ XeF6
•
XeF6 + -fCH 2 - CH 2 t n ~ -fCF2 - CF2 t n + 4nHF + 4nXeF4
What mass of F 2 (in kg) is required for preparation of 1 kg of fluorinated polymer?
12. 0.2828 g of iron wire was dissolved in excess dilute H 2 SO4 and the solution was made upto 100 ml.
20 ml of this solution required 30 ml ofN/30 K 2 Cr2 O 7 solution for exact oxidation. Calculate% purity
of Fe in wire?
13. Calculate the amount of calcium oxide required when it reacts with 568 g of P4 0 10?
Some Basic Concepts of Chemistry 3
14. Reaction Yield of reaction

(i) 2A + B ~ 3C + D 20%
(ii) 2C+E~4F 40%
(iii) H+3F~8G 50%
where B , E and H given in excess. Starting with 10 moles of A. Moles of G formed are?
15. Find the mass of Cu(NO 3)2.3H 2O produced by dissolving 10 g of copper in nitric acid and then
evaporating the solution?
16. Calculate molality of 1 litre solution of 93% H 2SO4 (WN). The density of solution is 1.84 g mL-l _
( I ) Integer Answer
17.
18.
105 mol of pure water is saturated w ith NH3 gas producing a solution of density 0.9 g/ml. If the
solution contains 30% ofNH 3 by weight and final volume of solution is

500
X
•
ml, then what is 'x'?
A 1.0 gram sample of pure organic compound containing chlorine is fused with Na2O 2 to convert
chlorine into NaCl. The sample is then dissolved in water and chloride ion is precipitated by adding
AgNO3 in the solution. If 1.96 g ofAgCl is obtained and mo lar m ass of organic compound is 147, how
many Cl atoms does each molecule contain?
19. Based on the following information, determine value of x
(CH3)x AlCly ~xCH + yCl- +AI+3
4 AgN03 AgCl(s)
0.643g 0.222g 0.996g
20. 3
A quantity of 1 gram dry green algae absorbs 5.0 x 10- moles of CO2 per hour by photosynthesis. If
the carbon atoms were all stored after photosynthesis as starch (C6H 10O 5)n, then how long (in hours)
would it take for algae to increase its own weight by 8 1% , assuming that photosynthesis taking place
at a constant rate?
g---..: Match the Following

2 1.
(A) N2
Match the Column-I with Column-II :
Column-I
(p) 40% carbon by mass
Column-II
•
(B) co (q) Empirical formula CH 2O
(C) C6H1 2O6 (r) Vapour density = 14
(D) CH 3COOH (s) 14NA (NA = 6.023 x 1023) electrons in a mole
22. Match the Column-I with Column-IL

Column-I Column-II
(A) N 3-(l mol) (p) 10 mol electrons
(B) 0 2- 0 mol) (q) 8 mol protons
(C) CH4 (1 mol) (r) 6.023 x l022 electrons
(D) H 2O (1 mol) (s) 10 mol protons
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4 CHEMISTRY
f Passage Based Questions

Passage-I
Estimation of N in a compound is made by Kjeldahl's method. A sample containing 0.4775 g of
•
(NH4 hC2 0 4 and inert materials was dissolved in water and made strongly alkaline with KOH, which
converted NH! to NH 3 . The liberated ammonia was distilled into exactly 50.0 mL of 0.05035 M
H 2 S04 . The excess H 2 S04 was back titrated with 11.3 mL of0.1214 M NaOH.
[Mo!. wt. of(NH,i)2 C2 0 4 = 124.10 and at. wt. ofN = 14.00]
23. Percent of(NH,i)2 C2 0 4 :
(a) 10.74 (b) 47.8 (c) 12.74 (d) 42.8
24. Percent of N in sample.
(a) 17.40 (b) 7.04 (c) 47.10 (d) 10.74
Passage-II
H 20 2 is used to produce 0 2 which can be used for the oxidation of other substances. The strength of
H 2 0 2 is expressed in several ways like M, N, % (WN) and volume strength. If a bottle of H 2 0 2 is
labelled as "20 volume", it means that 1 litre ofH2 0 2 sample will release 20 litre of 0 2 at S.T.P.
1
H 2 0 2 (aq) ➔ H 2 0(l)+-0 2 (g)
2
25. What is the strength of 20 volume H 2 0 2 ?
(a) 60. 71 g/lit (b) 30.5 g/lit (c) 3.05 g/lit (d) 6.071 g/lit
26. What is the % strength (WN) of 11.2 volume H 2 0 2 ?
(a) 1.7 (b) 34 (c) 3.4 (d) 17
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10. ~®@@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 IAI 22. 18 1 lcl 1° 1

23. ~®@@ 24. ~®@@ 25. ~@@@
26. ~®@@
Atomic Structure

1.
(a) increases by 2r1
(b) increases by (2n - 1)r1, where n is lower orbit number
•
As the orbit number increases, the distance between two consecutive orbits (r 1 = radius of first orbit)
(c) increases by (2n - l )r1, where n is higher orbit number

(d) rem ains constant
2. The time period of revolution in the third orbit ofLi+2 ion is " x" second. The time period of revolution
in the second orbit of He+ ion should be
2x 8x
(a) x second (b) l. 5x second (c) - second (d) - second
3 27
3. The following electronic transition occur when Lithium atoms are sprayed into hot flame
2s ~ 2p ~ 3d ~ 3p ~ 4s ____:!___,, 3p
(a) I, II & IV (b) III & V (c) III, IV & V (d) All of these steps
4. Which of the following nuclides is u sed medicinally to treat hyperthyroidism?
(a) Uranium-238 (b) Americium-241 (c) Carbon-14 (d) Cobalt-60
5. Suppose the electron is in a l s orbital of a hydrogen atom. What is the probability of finding the
electron in a small region at a distance a 0 from the nucleus relative to the probability of finding it in
the same small region located right at the nucleus?
(a) 0.14 (b) 0.1 8 (c) 0.26 (d) 0.5
6. Find the circumference of 5 th Bohr orbit of an electron whose de-Broglie wavelength coresponds to
translational kinetic energy of ' H ' atom at 27°C
(a) 31.16 nm (b) 32.0 nm (c) 38.56 nm (d) 40 nm
7. Let An be the area enclosed by nth orbit in H-atom. The graph log(~:) vs. log n
(a) will pass through origin
(b) will be straight line with slope 4
(c) will be m onotonically increasing non-linear curve
( d) will be rectangular hyperbola
8. Which of the following can be concluded correctly from the solution of Schrodinger equation
(a) For all orbitals, the radial wave function (\I') approaches infinity
(b) The radial probability density (\11 2) for ls orbital is maximum at nucleus
(c) The radial distribution function (4nr2\1'2) for l s orbital is minimum at the nucleus
(d) In plot ofradial wave function (\I'), \I' changes its sign at nodes
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10 ===================== CHEMISTRY
9. If the Aufbau principle is not followed in filling up electrons in the subshells, the block (s, p, d or f)
of which element will change in the periodic table?
(a) K (19) (b) Sc (21) (c) V (23) (d) Sr (38)
10. Which of the following is/are true for the given nuclear reaction?
90 Th22s -----4 g3Bi212
(a) A total of 4 a and 1 ~ particles are emitted per nucleus of Th
(b) 90Th228 is above the band of stability
(c) A total of 5 a and 3 ~ particles are emitted per nucleus of Th
(d) 90Th228 is decaying to 83 Bi212 because later is the most stable isotope
11.
Numeric Value Answer
For single electron system: 'I'

3P
= -4-( -Z
81✓6 90
)¾ (6cr - cr 2
)e- ~3
•
. . .
If a 0 IS Bohr radius, CJ = -
~
and r is radial node distance. The value r in
A up to one decimal place
ao
for He+ is
12. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a 0 is Bohr radius]
2
2h- - then x = ?
Given as - -
2 2 '
(x)1t ma0
13. Photochemical dissociation of Cl2 result in the production of two chlorine atoms one in ground state
and other in excited state [Cl*].
hv *
Cl 2 ~ C l + Cl
The maximum wavelength (1c) needed for this 160 nm. If the excitation energy Cl ➔ ci* 4 x 10-201.
How much energy in eV is needed for dissociation of one chlorine molecule into normal atoms in
ground state (he = 12400 eVA)
14. If sum of maximum electrons present in Fe and Cr atoms having ( n + e) ~ 4 and m = - l is equal to x.
And the difference between nth and (n + l)th Bohr radius ofH-atom is equal to its (n - lYh Bohr radius.
Thenx + n =?
15. If electron makes transition from 7 th excited state to 2 nd state in H-atom. Then maximum number of
spectral line observed?
16. A hydrogen like atom (z) is in higher excited state of quantum number 'n'. This excited atom can
make a transition to the first excited state by successive emitting two photons of energy 10.2 eV and
17.00 eV respectively. Alternatively, the atom from the same excited state can make transition to the
second excited state by successively emitting two photons of energy 4.25 eV and 5.95 eV respectively.
Determine value of n*z = ?
17. An electron in a hydrogen like species is in the excited state (n2). The wavelength corresponding to a
■
transition to second orbit is 48.24 nm. From the same orbit, wavelength corresponding to a transition
to third orbit is 142.6 nm. The value of n2 will be
18. Total number of subshells which can haven + l = 5 are
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Atomic Structure 11
19. The five valence electrons of 15P are labelled as
G 3s
lclnl EI
The spin quantum numbers of electron B and E are + ~. For how many pairs of electrons, three of
2
quantum numbers are identical?
20. The value of de-Broglie wavelength of the gas at- 73 °C is 'M ' times that of the de-Broglie wavelength
ofNe at 727 °C. The value ofM is

2 1. Match the Column-I with Column-II :
Column-I
(A) Orbital with equal number of radial and angular nodes (p) 3dx2-v2
Column-II
•
(B) Orbital with number of radial nodes less than that of angular nodes (q) 2pz
(C) Orbitals with zero radial nodes but two angular nodes (r) 3px
(D) Orbital with no node (s) 5dxy
(t) ls
22. Match the Column-I with Column-IL
Column-I (Orbital) Column-II (R vs. r plot)

(A) 3s (p)
\ I'-
\J
~
(B) 4s (q)
(C) 2p (r)
(\
v-
(D) 3p (s)
\(\
V V
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12 CHEMISTRY

Passage-I
A gas of identical H-like atom has some atoms in the lowest energy level A and some atoms in a
particular excited state B and there are no atoms in any other energy level. The atoms of the gas make
transition to higher level by absorbing photon having energy 2.7 eV Subsequently, the atoms emits
•
radiation of only six different photons energies. Some of the emitted photons have energy 2 .7 eV
Some have more and some have less than 2.7 eV
23. The principal quantum number of initially excited level B is
(a) 2 (b) 3 ( c) 4 ( d) 5
24. The ionisation energy for the gas atoms
(a) 14 eV (b) 14.4 eV (c) 13.6 eV (d) 20.2 eV
Passage-II
Suppose a particle has four quantum numbers such that the permitted values are n = l , 2, 3 ..... .
l = (n - 1), (n - 3), (n - 5) .. .. but no negative values
j = (z +½) or (1 - ½} the later is not negative

m = - j to + j (only integer values)
25. The other permitted values for n = 2
3 3
(a) l = l j =- m = - -
, 2' 2
1 3
(c) l = l j = - m =- - ( d) All of these
, 2' 2
26. For n = 3, the possible sets of (n, l, j, m) is
(a) 10 (b) 8 (c) 12 (d) 6
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10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
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Periodic Properties
and Chemical
Bonding

1. Which of the following molecules have a dative n:-bond?
I. P40 10 II. (SiH3) 3N III. P 4 0 6 IV. NO
•
(a) I & II (b) I, II & IV (c) I & III (d) I, II & III
2. Which of the following is the correct order of angle between two fluorine atoms linked to central atom
in the given molecules?
I. F 2C = 0 II. N = SF3 III. I02F2
e IV. F 5I = 0
(a) I > II > III > IV (b) I > III > II > IV (c) II > III > I > IV (d) III > II > I > IV
3. Choose incorrect statement.
(a) The electron affinity of 'N ' is zero while that of phosphorus is 3 kJ/mol.
(b) Vander-waal's radius of iodine is more than its covalent radius.
(c) First I.E. of nitrogen is higher than oxygen while second I.E. of oxygen is higher than that of
nitrogen.
( d) All isoelectronic ions belong to same period of periodic table.
4. The HOMO in nitric oxide molecule is
* *
(a) 1tzPx = 1tzpy (b) 1tzPx = 1tzPy (c) CTzPx
5. The species in which central atom is not sp 3 hybridised is/are :

(a) Na2S04 (b) K 2 Cr0 4
(c) Ni(C0)4 (d) all have sp3 hybridised central atom
6. Banana bond is present :
(b) Solid BeH 2 (d) All of these
7. Which of the following statement is incorrect?
(a) In 0 2F 2 the O - 0 bond is shorter than 0 - 0 bond in H20 2.
(b) In 0 2F 2 the O - 0 bond is larger than 0 - 0 bond in H20 2.
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18 ===================== CHEMISTRY
(c) H 20 2 and 0 2F2 have similar structures, hence, the O - 0 bond of the two molecules is identical.
(d) Rotation about O - 0 bond in H20 2 and 0 2F2 is a free rotation.
8. Ionisation energy of an element is :
(a) Equal in magnitude but opposite in sign to the electron gain enthalpy of the cation of the element.
(b) Same as electron affinity of the element.
(c) Energy required to remove one valence electron from an isolated gaseous atom in its groumd
state.
(d) Equal in magnitude but opposite in sign to the electron gain enthalpy of the anion of the element.
9. Which of the following increases the basic character of elements?
(a) Increasing metallic character of element (b) Increasing electronegativity of metal
( c) Decreasing ionisation potential of metal (d) Decreasing effective nuclear charge
10. Species where 0-bond is absent is/are
11. Total number of mixed an hydrides among :
0 0 0 0
•
N204, N203, Cl207, Cl206, )lo~ , Jo\
Cl Cl
12. Maximum number of atoms present in one plane in PFi{CH 3)3.

13. Total number of species among the following which favours oxidation :
Mn(CO)s, 0 ~, N 2, Nd+2, 0~, F~, Ce+4.

14. Total number of planar species among:
CH2 = CH - cHf, XeF4, [NiFCl(CN)2] 2- , N203, O·

15. Total nmnber of amphoteric metals among :
Sn, Cr, Sb, As, Al, Pb, Zn, Ni.
16. Total number of elements having sizes smaller than Zn :
Sc, Ti, V, Cr, Fe, Cs, F, I, Cu.
17. Total number of p7t - d7t bonds in Xe02F 2 .
18. Total number of species having bond order greater than that of co EB .
CO, N 2, N 2e , C2e , C032- , F2EB , S 8 , C 30 2, Ci(CN)2 .
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Periodic Properties & Chemical Bonding 19

19. Match the columns :
Column-I Column-II
•
(A) Bond order ofNO 38 (p) 2
(B) Bond order of SO2 (q) Equal to the B.O. of benzene
(C) Bond order of 0 3 (r) 1.33

(D) Bond order of CO2 (s) 1.5

Column-I Column-II
(A) XeO 3, XeF2 , ClF3, PC13 (p) All are sp3d except one
(B) CH , XeO , ClO e , POC1 (q) All are sp3 except one
4 3 4 3
(C) BFf, so/- , co/- , POCl3 (r) All are sp3
(D) SO 2 , SnC12 , SO 3, SO2 Cl2 (s) All are sp2 except one

Passage-I
Lewis concept of covalency of an element involved octet rule. Later on it was found that many
•
elements in their compounds, e.g., BeF2 , BF3 etc. have incomplete octet whereas PC15 , SF6 etc. have
expanded octet.
This classical concept also failed in predicting the geometry of molecules. Modern concept of
covalence was proposed in terms of V.B.T. Hybridisation concept along with V.B.T. successfully
explained the geometry of various molecules.
2 1. Which are true statements among the following ?
I. Ie
3
has bent structure
II. pn - dn bonds are present in SO 2
III. XeFf has pentagonal planar shape but PC15 is triangular planar
IV MgSO 3.3H 2 O and MgCO 3.3H2 O are isomorphs
(a) II, III (b) II, III, IV (c) I, II, III (d) I, II, III, IV
22. The bond angles in Nor , NO2 and NOf are respectively :
(a) 180°, 134°, 115° (b) 11 5°, 134°, 180° (c) 134°, 180°, 115° (d) 115°, 180°, 130°.
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20 CHEMISTRY
Passage-II
The platinum-chlorine distance has been found to be 2.32 A in several crystalline compounds. This
value applies to both of the compounds shown :
N H3 NH3
I I
Cl - Pt - Cl Cl - Pt - N H3
I I
NH3 Cl
(A) (B)
23. Cl - Cl distance in structure (A) is :

(a) 2.32 A (b) 4.64 A (c) 1.16 A (d) 9.28 A
24. Cl - Cl distance in structure (B) is :
(a) 2.32 A (b) 1.52A (c) 2. 15 A (d) 3.28 A
25. Which statement is/are correct about A and B?
(a) Both have COS (Centre of symmetry) (b) Both have POS (Plane of symmetry)
( c) Both are rotamers of each other (d) Both are different configuration
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10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
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Gaseous State

1. A mixture of 0.5 mo! of CO and 0.5 mo! of CO2 is taken in a vessel and allowed to effuse out through •
a pin hole into another vessel which has vacuum. If a total of' A' mo! has effused out in time 't' shows
that M 1A + M 2 (1 -A) where M 1 and M 2 are the mean molar masses of the mixture that has effused
out and the mixture still remaining in the vessel, respectively.
(a) 40 (b) 55 (c) 30 (d) 36
2. Cl2 O7 gas decomposes as: Cl2 Oig) ➔ Clig) + Oig)
A partially decomposed gaseous mixture is allowed to effuse through a pin-hole and the gas coming
out initially was analysed. The mo! fraction of the 0 2 was found to be 0.6, determine the degree of
dissociation.
(a) 40% (b) 30% (c) 20% (d) 10%
3. The valve ofa commercial cylinder ofN2 gas was left slightly open so that small amount of gas leaked
into laboratory. The leak rate was proportional to the pressure difference (internal pressure one atm).
If the initial leak rate was found to be 1 gram per second and initial pressure inside the 7 .28 m 3 tank
was 17180 KPa, what would be the pressure inside the tank after 10 days assuming temperature of lab
to be 27 °C
(a) 94.33 atm (b) 91.22 atm (c) 90.33 atm (d) 98.23 atm
4. Clig) and F 2 (g) are mixed in molar of 1 : 3 in a flask and sealed where they combine partially to
produce some ClFig). The rate of equilibrium mixture was found to be 1.3 times slower than the rate
of effusion of pure 0 2 gas. What would be the mo! fraction of Cl2 in the mixture at equilibrium?
(a) 0.207 (b) 0.623 (c) 0.170 (d) 0.173
5. A rubber balloon weighing 10 gram is 40 cm in diameter when inflated with He(g) at 760 torr and 27 °C.
How much weight will the balloon lift in addition to its own weight? ( density of air = 1.2 g/lit)
(a) 29 g (b) 31.74 g (c) 19.73 g (d) 28.84g
6. A liquid of mass 0.0184 g is introduced into a syringe like the one shown below, by injection through
the rubber tip. The syringe is then transferred to a temperature bath heated to 45 °C and the liquid
vaporises. If the pressure inside the syringe is 1.0 atm and empirical formula of compound is CH2 ,
determine molecular formula of compound.
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24 CHEMISTRY
n-1...P~·. .~. . . . . .?_

.. 4 2 o
U ~' ~ u b b c c tip
Radius of syringe = 0.56 cm
7. A 2 metre long tube closed at one end is lowered vertically into water until the closed end is flushed
w ith the water surface (see figure). Calculate the water level height (i.e. h). If vapour pressure of water
is negligible and 1 atm = 10 m of hydrostatic water head.
:::::::::::1...:.:.:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
::::::::::: h ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
...............................................................................................
........... . .................................................................................
::j:::::: !1!!111!!1 :::::::::j::::::::::::::::::::::::j:::::j::::::::::::::::j:::::j::
....................................................................................................
....................................................................................................
....................................................................................................
(a) 1.01 m (b) 0.29 m (c) 1.71 m (d) 0.92 m
8. n moles of He gas is placed in a vessel of volume V litre at T K. If V1 is free volume of He, then the
diameter of He atom is
I I I I
(a) ( 3Vj
2rcNA n
)3 (b) [3(V - Vj)]3
2rcNA n
(c) [6(V - Vj)]3
rcNAn
(d) ( re: ny
9. Which sequence(s) of ease of liquifaction of gases is/are correct?
(b) CH4 > CO2 > H 2 0
(c) H 2 0 > CO 2 > CH 4 (d) \ / >/ \ / > H 20

10. Which are correct for an ideal gas?
(a) (::t-(:;L-(:;t =0
(c) (:;t-(:~L-(:;t = -l (d)

Thermal expansion of coefficient of gas = !._
-I-so-th_e_rm-al_c_o_m_p_re-s-si-bi-li_ty_c_o_n_st_an_t_ T
(ill
11.
The value of b for NH 3 and CS2 are given as 0.03713 and 0.07262 respectively (L/mol). Calculate the
ratio of molecular radii of the gases (Give answer till two decimal place).
•
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Gaseous State 25
12. In the following arrangment, find the pressure of the confined gas (in cm of Hg).
p = 13.6 gm/cc
13. Air is trapped in a horizontal glass tube by 40 cm Hg column as show n below.
(..__~
~ i_r_ _.___H_
g ____.__~O
I
1 atm
~ 40cm ➔
If the tube is held vertical keeping the open end up, length of air column shrink to 19 cm. Length in
cm by which the Hg column shift down is
14. A mole of CC14 vapours at 77 °C occupies a volume of 16 L. Tf vander-Waal 's constant are a = 20.19
L2 atrn mol-2 and b = 0.1383 L mo1- 1 . What will be compressibility factor at low pressure region?
15. The density of vapour of a substance (X) at 1 atm pressure and 500 K is 0.8 Kg/m 3 . The vapour effuses
through a small hole at a rate of 4/5 times slower than oxygen under the same condition. What is the
compressibility factor (z) of the vapour?
16. What would be the value ofvan-der-waal constant 'a' w hen b = 0? Here Pis in atm and Vis in
litre/mol.
•
30
i~~···-········~·
~ 15 11
2 3 4 5 6
l/V ~
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26 ===================== CHEMISTRY
17. Which of the following velocity distributions belongs to the gas with highest molecular m ass if all the
m easurements were done at same temperature.
i 0.8
.c
:; 0.6
.g
.£J 0.4
2
0....
0.2
Velocity ~
18. In the following figure, when the two stopcorks are opened, the total pressure inside the flask will be
. be the value of x.
-10 what will
X
Stopcork- 1 Stopcork-2
2.0 atrn 4.0 atm 1 atm

1.5 litre 1.5 litre 1 litre
19. How many of the following statements are true
(a) limit{PV) = C at con stant T (b) . . (PV)

hm1t - =l
P➔ O P ➔O RT
(c) limit(PV) = Cat constant T (d) . . (PV)

hrmt - =R
V ➔O V➔ O RT
( e) Critical temperature of a gas is lesser than that of Boyle 's temperature.
20 . .
The equation o f state fior a certam
. gas 1s
. p =---
RT -a , w h ere ' a ' an d ' b' are constants
V,llb vm
distinct from zero. As certain w hether the gas has a critical point or not. A nswer as
(1) if the gas has critical point and as (2), ifno critical point.
W WW.JEEBOOKS.INI
Gaseous State 27

2 1.
Column-I Column-II
•
Match the parameters in left column with the parameters in the right column on which they depend :
(A) Kinetic Energy (p) Mol fraction

(B) Partial pressure (q) Density
(C) Rate of effusion (r) Molar mass
(D) Vapour pressure (s) Absolute temperature
22. Match the Column-I with Column-II.

C olumn-I Column-II
(A) H2 gas at 300 K (p) Maximum translational kinetic energy per mol
(B) CH 4 gas at 400K (q) Maximum translational kinetic energy per gram
(C) 0 2 gas at 1000K (r) Minimum translational kinetic energy per mol
(D) He gas at 600K (s) Minimum translational kinetic energy per gram

Passage-I •
Ideal gas equation PV = RT is not followed by real gases. Real gases follow van-der-waal equations in
. . . an 2 . .
which pressure is substituted as P +- - and volume term is substituted by (V - nb).
2
V
i.e. ( p + ; : ) (V - nb) = nRT whoce 'a' and 'b' am called van-de,-waal cons tant. By the help of 'a'
and 'b' we can study critical phenomenon of gases.
23. The ratio of coefficient of thermal expansion a =( dV) IV and the isothermal compressibility
K = -(dV) IV for an ideal gas is dT P
dP T
p p T T
(a) (b) (c) (d)
T T p p
24. ForBF/g)van-der-Waal equation canbewritten as (r+ : 2

)(V-0.l)=2RT
Critical volume ofBF3 gas will be :
(a) 0.15 litre (b) 0.3 litre (c) 24litre (d) 0.4litre
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28 CHEMISTRY
Passage-II
Gases show ideal gas behaviour in Boy le temperature range. Assume for the air this temperature range
between 300 K to 900 K.
An op en vessel at 27 °C is heated untill 315 th of the air in it has b een expelled. Assuming that volume
of vessel remains constant.
25. The temperature a t which vessel was h eated
(a) 750 K (b) 400 K (c) 350 K (d) 620 K
26. The escap e out if vessel is heated at 900 K
(b) !!__
2n (d) n
(a) n (c)
3 3 2
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
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Chemical
Energetics

1. Only gaseous product remain after 15.0 g of carbon is treated with 25 litre of air at 27 °C and 5.5 atm
pressure. Assume that the air contains 19% 0 2 , 80% N 2 and 1% CO2 by volume. Determine the total
•
heat evolved under constant pressure.
~ H =- 94 KCal
1
C(s) + - O2 (g) ➔ CO(g); ~H = - 28 KCal
2
(a) - 83.23 KCal (b) - 92.42 KCal (c) - 84.24 KCal (d) - 90 KCal
2. A Carnot engine works between 120 °C and 30 °C. If the power produced by the engine is 400 watt.
What is the amount of heat absorbed from the source?
(a) 1625 watt (b) 1840 watt (c) 17 11 watt (d) 1747 watt
3. If the pressure and density of CO 2 gas in adiab atic process changes from (P 1, d) to (P 1, d 1) where
P = 32P 1 then dld 1 is equal to
I I I
(a) 1 )1.3
( -32
3
(b) ( 312 y-~ii (c) (32)1.33 (d) (32)!.4
4. One mole of a gas at 100 K is compressed isothermally from 20 dm3 to 5 dm3 . What will be the work
done on the system if the equation of state is ( p + ; ) V = RT where a = 0. 384 m 6 Pa/mol

2
(a) 1095 J (b) 8046 J (c) 5723 J (d) 985 J

5. Consider the following hypothetical reaction :
~N\
N N
3Ni(g) ➔ I II (g)
N N
~ NI
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34 CHEMISTRY
Given, B.E. of N 2, N - N and N = N are 942 KJ/mol, 170 KJ/mol and 420 KJ/mol.
If resonance energy of the product molecule of the given reaction is - 140 KJ/mol. What would be
MI
1 of the reaction?
(a) 812 KJ/mol (b) 715 KJ/mol
(c) 614 KJ/mol (d) 916 KJ/mol
/p'. /p'. /p'.
6. P+P--+ - P
'. p / '.p/
?
p - ·-p
'.p/
P- I I 11H = - 104 KJ/mol of P4
White (g) Red (g)
Solid white phosphorous undergoes polymerisation to give red phosphorous. What would be the bond
enthalpy of P - P bond in red phosphorous joining the two units of white phosphorous? Given that
enthalpy of sublimation of white phosphorous is 59 KJ/mol and enthalpy of atomisation is 316.25 KJ/mol
of P(g)
(a) 41 6 KJ/mol (b) 298 KJ/mol
(c) 305 KJ/mol (d) 513 KJ/mol
7. Calculate the work done when a system raises a column of water of radius 5.0 mm through 10 cm
(a) - 5.37 X 10-3 ] (b) 2.87 X 10- 3 ]
(c) -4 X 10-3 ] (d) - 3.85 X 10-3 ]
8. For a process !1T = 0, the process may be

(a) Isothermal (b) Cyclic
(c) Adiabatic free expansion (d) Isochoric
9. For adiabatic irreversible expansion, which statement(s) is/are correct?
(a) i1S8 ys= + ve (b) i1SSU11"= 0
(c) i1Ssys= 0 (d) 11Ssys= - ve
!ill
10.
Assume that human body is a heat engine. For a food intake equivalent to 1.0 x 107 Joule per day, a
human can work for 6.2 hour per day at a rate equivalent to 0.0374 HP (1 HP= 746 W). W hat is the
•
efficiency (in percentage) of human body?
11. One mo! of an ideal gas CP = 4R at 300 K is expanded reversibly adiabatically to n times the original
volume. What is the value of n if temperature falls to 75 K?
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Chemical Energetics 35
12. One m ole of an ideal monoatomic gas is caused to go through the cycle shown in figure. Then, the
change in internal energy in expanding the gas from a to c along path abc is xRT0 . Calculate x?
C
2PO ----------------------------------
l~
:::l
"'
£ po --------~-j i, b
I
V0 4V0
Volume ~
13. For the reaction :

cis-2-butene ~ trans-2-butene and cis-2-butene ~ I-butene ; AfI = - 950 cal/mol
and 11H = 1800 cal/mo! respectively. The heat of combustion of I-butene is - 650 Kcal/mo!. Determine
the heat of combustion of trans-2-butene. Data B.E . of C = 0 = 196, 0 - H = 110, 0 = 0 = 118, C - C
= 80 and C - H = 98 Kcal/mo!; Aflv (H2 O) = 11 Kcal/ mol.
14. If a gas expands adiabatically at constant pressure such that T oc
a : 2. The value of a is
•
v- 112 . The value of Cp: Cvfor it is
15. The heat evolved on combustion of 1 gram of starch, (C6H 10O 5)x into CO 2 (g) and H 2O(l) is 4.6 KCal.
Heat of formation of CO2 (g) and H 2 O(l) are - 94 .2 and - 68 .4 KCal/mol respectively. The magnitude
of standard enthalpy of formation of 1 g of starch (in KCal) is
16. An isobaric process, the ratio of heat supplied to the system and work done by the system for a
diatomic gas is a : 2. What is the value of a?
17. A solution of 6.3 g of haemoglobin (Molar mass 64000 in 25 ml of solution shows a temperature rise
of 0.03°C for complete oxygenation. Each mol of haemoglobin binds four moles of oxygen. If the heat
capacity of the solution is 4.2 J/K. ml, then the amount of heat released per m ol of oxygen bound (in KJ) is
18. A solution of 500 ml of 2M KOH is added to 500 ml of 2M HCI and the mixture is well shaken. The
rise in temperature T 1 is noted. The experiment is again performed for 250 ml KOH and 500 ml HCI
and rise is temperature T2 is reported. If 7i is ~ , then x will be

T2 2
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36 CHEMISTRY

19. Match the column-I with column-II :
Column-I (Gas) Column-II (Thermodynamic property)
•
(A) 02 (p) y =l.4
(B) Nz (q) 7
C = ~R
p 2
(C) CO2 , CH4 (r) Cp = 23 R

6
(D) 1 mol 0 2 + 2 mol 0 3 (s) y= 1.33
20. Match the Column-I with Column-II :

Column-I Column-II
(A) N 2 (g) + 0 2 (g) ➔ 2NO(g) (p) ~S = O
(B) 2KI(aq) + Hglz(aq) ➔ K 2 Hgl4 (aq) (q) ~S < O
(C) PClig) + Cl2 (g) ➔ PC1 5(g) (r) ~ > O
(D) NHlg) + HCl(g) ➔ NH4 Cl(s) (s) ~ < O
The third law of thermodynamics states as follows :

Passage-I •
"The entropy of a system approaches a constant value as its temperature approaches absolute zero".
The constant value can not depend on any other parameters characterising the closed system, such as
pressure or applied magnetic field. At zero kelvin, the system must be in a state with minimum possible
energy. Entropy is related to the number of accessible microstates and there is typically one unique state
(ground state) with minimum energy. In such a case, the entropy at O K will be exactly zero.
lim S➔ 0 (Nemst theorem)
T ➔ OK
21. Which of the following is incorrect for the charge shown below ?
aA+bB
c,.,s; cC+dD
(298K) (298K)
~rs; j, i ~rs;
aA+bB
c,.,s; cC+dD
(OK) (OK)
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Chemical Energetics 37
(a) llrs; = cs;+ ds; - (as: + bs; ) (b) llrs;=- [as:+bs; ]

(c) !lrs; = 0 (d) llrs; = -(cS~ +ds;)
22. Which sequence of llS is correct?
(a) ~ < 0 < /\/v

(g) (g) (g)
(b) He < SOz < SO3 < C 6H 6 (at 25°C)
(c) Fz < Clz < Brz < Iz (at 25°C)
(at 25°C)
Passage-II
2Hz(g) + Oz(g) ➔ 2HzO(g); llH = - 483.636 K J/mol
3Hz(g) + Oig) ➔ 3HzO(g); llH = - 868.2 KJ/m ol
Hz(g) + HzOz(g) ➔ 2H zO(g); llH = - 347.33 KJ/mol

23. W hich oxidising agent will generate the greatest amount of energy?
(a) Oz (g)
24. Which oxidising agent will generate the greatest amount of energy for 1 gram of oxidising agent?
(a) Oz (g) (d) All are same
RESPONSE SHEET
1. ~®@@ 2. ~®@@ 3. ~®@@
4. ~®@@ 5. ~®@@ 6. ~®@@
7. ~®@@ 8. ~®@@ 9. ~@Cs)@
10. 11. 12.
13. 14. 15.
16. 17. 18.
19. IAI 1
8 1 lcl lnl 20. IAI 1
8 1 lcl lnl
21. ~®@@ 22. ~®@@ 23. ~@Cs)@
24. ~®@@
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Equilibrium

1. A weak monobasic acid is titrated against a strong monoacidic base. On addition of 20 mL of base, the
pH of the solution was 4.0 while upon addition of30 mL ofbase,pH of the solution was 5.0. What is
the value of Ka of weak acid?
•
(a) 1.8 x 10-5 (b) 1.7 x 10-4 (c) 1.87 X 10-S (d) 1.63 x 10-4
2. PC15(g) is taken in a flask at 1.0 atm, sealed and allowed to attain the following equilibrium :
PC15 ~ PCl3 + Cl2
The equilibrium mixture was then allowed to pass through a pin hole and the gases coming out of pin
hole initially, was collected, analysed and mol fraction ofC12 was found to be 0.53. What is the value
of KP for the dissociation of PC15(g)?
(a) 2.577 bar (b) 4.238 bar (c) 2.378 bar (d) 5.744 bar
3. Following three equilibria are maintained in the same container:
A(g) ~ B(g) + C(g)
E(g) ~ X(g) + C(g)
X(g) ~ F(g) + G(g)
Select the correct option if at the stage of equilibrium we add few moles of C.
(a) [E] increases (b) [G] decreases (c) [A] increases (d) [B] decreases
K1
4. For a reversible reaction A:;::::===B, the initial molar concentration of A and B are a and b mol per
K2
litre respectively. If 'x' mol per litre of' A' is reacted till the achievement of equilibrium, then x is
K 1a K 2b K 1a-K2b K 1a-K2b K 1a+K2b
(a) ~ -- (b) ~ -- (c) ~ -- (d)
Ki Kz Ki -Kz K1K2 Ki +K2
5. The rate for the A2 + C ➔ product for which mechanism is given below is 5.0 mol/litre-second. When
the concentrating of reactant A 2 and C are 10 mol/litre and 4 mol/litre respectively.
Step-I:
Step- II: A+C~AC

The rate constant for the change A + C ~ AC is
(a) 1.25 x 10-1 (b) 1.25 x 10-3 (c) 1.25 x 10-2 (d) 1.25
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42 ===================== CHEMISTRY
6. The resulting mixtures which act as buffer are:

(a) 10 ml 0.1 M HCl + 20 ml 0.1 M NaCN
(b) lOml0.l MNaOH+20ml0.l M NH4 CN
(c) 10 ml 0.1 MNH4 OH + 20 ml 0.1 M CH 3 COONH4
(d) 10 ml 0.1 M CH 3 COOH + 20 ml 0.1 M CH 3 COONH 4
7. H 3BO3 + Glycerine ~ H 3BO3 -glycerine; Kc= 0.9. How many moles of glycerine should be
added per litre of 0.1 M H 3BO3 so that 80% of the H 3BO 3 is converted to the boric acid glycerine
complex?
(a) 4.44 (b) 4.52 (c) 3.6 (d) 0.08
8. A solution contains 0.1 M of Mg+2 and 0.1 M of Sr+2 _The concentration of ~CO3 is adjusted to 0.05 M.
Determine the pH range which would permit the precipitation of SrCO 3 without any precipitation of
MgCO 3 . The H© ion concentration is controlled by external factors. Given that Ksp of SrCO3 and
MgCO 3 9 x 10-lOand 4 x 10-8 respectively. K 0 (overall) ofH2 CO3 = 5 x 10- 17
(a) 4.78 to 5.6 (b) 4.6 to 5.78 (c) 5.78 to 6.4 (d) 5.22 to 5.4
9. What minimum volume of a buffer solution, which is 0.1 M in both lactic acid and sodium lactate
must be diluted to exactly 100 mL so that the resulting buffer solution will change its pH by not more
than 0.5 pH unit upon addition of 10 mL of 0.01 M HCl?
(a) 5.2 mL (b) 4.93 mL (c) 6.92 mL (d) 1.92 mL
10. Which of the following relation(s) is/are true for alkaline solution?
Kw
(a) (b) pH > pOH (c) pOH < E__ (<l) pH < pOH
2
(fil Numeric Value Answer ■

11. Calculate the p H of0.15 M aqueous solution of AlC13 . Given: log 2 = 0.3, log 3 = 0.48.
[Al(H2 O)6 ] 3+ + H 2 O (/) ~ [Al(H 2 O) 5 OH] 2+ (aq) + H 3 O+ (aq)
K0 = 1.5 X 10-5
12. The solubility product of Ca(OH)2 at 25 °C is 4.42 x 10-5 . A 500 ml of saturated solution ofCa(OH)2 is
mixed with equal volume of0.4 M NaOH solution. How much Ca(OH)2 in milligrams is precipitated.
13. l L solution contains 0.1 mol Ag+ and 0.1 mol c 1-1 (Ksp of AgCl = 10-10). Calculate minimum moles
ofNH3 added to stop precipitation of AgCl? K [ Ag(NH3 ) 2 = l 06 .
1
t
14. Calculate the p H of 0.1 M Na2 HPO4 solution?
G 1.ven th at .. K =10- 2 K = 10- 7 and K = 10- 12,.
a1 ' a2 a3
1or H PO . 3 4
. . . . . .
15. If a 1s degree of dissociation of monobas1c acid, then a = (1 ) . What is the value of x?
l+x pKa - pH
16. A volume of30 mL of0.06 M solution of the protonated form ofan amino acid, methionine (H 2A+)
in titrated against 20 mL of 0.09 M NaOH . pH of resulting solution if pK01 = 2.28 pK02 = 9.72
•
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Equilibrium 43
17. Total number of aqueous salt solutions whose pH are independent of their concentrations are :
CH 3 COONa, KCl, CuCN , CH 3 COONH 4 , NH4 Cl, Sodium lactate, FeC13 , Cu SO4
18. An acid base indicator has K Hin value of 1.2 x 1o-3 . The acid form of this indicator is red and the basic
form is blue. The change in [H+] required to change the indicator from 60% red to 60% blue is 1o-x
mol/litre. What is the value of x?
19. 0.1 mol of H 2 and 0.2 m ol of CO2 are introduced in a closed vessel at 723 K and 50.67 KPa
H 2 (g) + CO 2 (g) ~ H 2 O(g) + CO(g) ... (1)
Analysis of the mixture shows that it contains 10 mol % ofH 2O(g). A mixture of CoO(s) and Co(s) is
then introduced such that the additional equilibria are established
CoO(s)+ H 2 (g)~Co(s) + H 2 O(g) ... (2)
CoO(s) + CO(g) ~ Co(s) + CO2 (g) ... (3)
Analysis ofnew equilibrium mixture shows that 30% (mol) ofH 2O(g) are present. What would be the
Kc for equation (2)?
20. Total number of solutions which will have p H greater than that of 0.1 M CH 3 COOH (Ka = 10- 5)
(i) 0. 1 M HCl
(ii) 0.1 M CH 3 COOH + 0. 1 M CH 3 COONa
(iii) 0. 1 M NH 4 OH (Kb = 10-5)
(iv) 0. 1 M CH 3 COONa
(v) 10-8 MHCl
(vi) 0.1 M CH 3COONH 4 (Ka = 10-5 & Kb = 10-5)
(vii) 0.1 M NaHA (K1 = 10-5 K2 = 10-7)

2 1. Match the column-I with column-II :
Column-I (Titration)
(A) Strong acid versus strong base (p)
Column-II (Indicator used)
M ethyl orange (3 - 4.4)
•
(B) Weak acid versus strong base (q) Methyl red (4.3 - 6.3)
(C) Strong acid versus weak base (r) Phenolphthalein (8 - 10)
(D) Weak acid versus weak base (s) No suitable indicator

Column-I Column-II
(A) Degree of ionization of weak electrolytes increases (p) Common ion effect
(B) p H of water decreases on (q) p H=4
(C) The solution has hydronium ion concentration of 0.0001 moUlitre (r) Heating
(D) The addition of NaOH to Ca(OH)2 solution precipitates Ca(OH)2 (s) On dilution
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44 CHEMISTRY

Passage-I
10 mole of NH 3 is heated at 15 atm from 27 °C to 347 °C assuming volume constant. The pressure at
equilibrium is found to be 50 atm. The equilibrium constant for dissociation ofNH 3 :
•
PN 2 X(P8 2 )3
2NH3 ~ N 2 +3H2 ; Aff = 91.94 kJ can be written as K = (atm)2
p 2
(PNH3)
23. The degree of dissociation ofNH3 is :
(a) 61.3% (b) 20% (c) 48% (d) N one of these
24. The equilibrium constant KP for the reaction is :
(a) 7.08 x l 02 (b) 3.06 x l02 (c) 7.6 x l02 (d) 1.53 x l03
Passage-II
A 10-2 M solution of P4 O2 (NO 3) 2 was found to have pH of 3.8. Answer the following questions if
Antilog (- 3.8) = 1.6 x 10-4
25. What is hydrolysis constant for P4 o z2+?
(a) 2.56 x 10-6 (b) 3.7 x 10-6 (c) 4.9 x 10-6 (d) 3.7 x 10-8
26. What is the value of Kb for P4 O 2 .0 H© ?
(a) 10-6 (b) 3.9 x 10-8 (c) 4 X 10-? (d) 3.9 x 10- 9
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
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The Solid State

1.
number of atoms of B in unit cell is
(a) X: y (b) y: X (c) x 2 :y (d) y2: X
•
If the ratio of coordination numbers of A to that of B is x : y, then ratio of number of atoms of A to that
2. What fraction of the Ca atoms lies on the surface ofa cubic crystal that is 1.0 cm in length, if the radius
of Ca atoms is 96 pm and it crystallizes in bee arrangement
(a) 1.11 x 10-8 (b) 2.3 x 10-5 (c) 2.3 x 10-8 (d) 1.11 x 10-8
3. What will be the void space in closest packing of 'n ' spheres of radius 'l' unit, 'n' spheres of radius
0.414 units and 2n spheres of radius 0.225 units
(a) 15% (b) 18% (c) 19% (d) 32%
4. FeO is doped with 0.2 moles of Al2 0 3 number of cation vacancies will be :
(a) 0.1 NA (b) 0.2 NA (c) 0.3 NA (d) 0.4 NA
5. The sublimation temperature of a substance is - 83°C. It exists as cubic close packed structure with
unit cell edge length of 5.0 A and density 8/3 g/cm3 at - 100 °C. What would be the density of
substance at 0 °C and 1 atm assuming NA = 6 x 1023
(a) 50 g/cm3 (b) 2.23 g/cm3 (c) 2.23 g/litre (d) 1.86 g/litre
6. In a hypothetical solid, 'C' atoms from ccp lattice. 'A ' atoms occupy all tetrahedral voids and 'B'
atoms occupy all octahedral voids. The plane shown in the figure will looks like
(a) (b) (d)
7. There are three cubic unit cells A, B and C. Crystal A is fee and all of its tetrahedral voids are occupied.
'B' is also/cc and all of its octahedral voids are also occupied. 'C' is simple cubic and all of its cubic
voids are also occupied. If voids in all unit cells are occupied by the spheres exactly at their limiting
radius, then the order of packing efficiency would be
(a) A < B < C (b) C < A < B (c) C < B < A (d) A < C < B
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50 ===================== CHEMISTRY
8. In anfcc unit cell, atoms are numbered as shown below. The atoms touching each other are :
4
1 3 •
.··•·························
....····
...
2
(Atom numbered 3 is face centre of front face)
(a) 3 and 4 (b) 1 and 2 (c) 1 and 3 (d) 2 and 4
9. Following three planes (P1, P 2 , P 3) in anfcc unit cell are shown. Consider the following statements
and choose the correct statement.
........................
//
(a) P 1 contains no three dimensional voids

(b) I'2 contains only octahedral voids
( c) P 3 contains both octahedral and tetrahedral voids
( d) Ratio of number of atoms present in P 2 and P 3 planes is 5 : 6
10. Diamond crystallizes in/cc unit cell and alternate tetrahedral voids are also occupied by carbon atoms.
Silicon crystallizes in a structure similar to diamond. If the density of unit cells of diamond and silicon
are 3.5 and 2.23 g/c.c., then select correct statement regarding C - C and Si - Si bonds
(a) C - C bond is longer than Si - Si bond
(b) C - C bond is weaker than Si - Si bond
(c) C - C bond is stronger than Si - Si bond
(d) Ratio of bond lengths of C - C and Si - Si is 1.54 : 1.88
~
11.
12.
The number of square faces in a truncated octahedron is
cell in diamond is 'y', then value of (x + y) = ?
.
KF has NaCl type structure. If radius of K+ and F- are
186
r;:; and
214
•
'x' and the number of carbon atoms per unit
r;:; pm respectively and distance

between two nearest K+ in pm is ? '\/ 2 '\/ 2
13. A mineral has ccp structure formed by 0 2- ion where one fourth of the octahedral voids are occupied
by x2 + ion and one fourth of the tetrahedral voids are occupied by y +3 ions. The simplest chemical
formula of the mineral is XaYbOc. Calculate a 2 + b2 + c 2 = ?
14. What is the number of thirst nearest neighbours in/cc unit cell?
15. Number of tetrahedral voids in HCP= x and number of octahedral voids in HCP= y . Then x + y = ?
WWW.JEEBOOKS.INI
The Solid State 51
16.
17.
and NaCl are
Consider the following cases
(a) Ge is doped with As (b) As is doped with Ge
•
Total number of antiferromagnetic substances am ong MnO, CrO 2 , Fe, NiC12 , MgFe2 O 4 , Fe 3 O 4 , C 6H 6
(c) Si is doped with Ge (d) Ge is doped with Si

(e) As is doped with Si
Total number of cases which will report p -type semiconduction.
18. Number of regular trigonal faces in a truncated tetrahedron is.
19. Ice crystallizes in a hexagonal lattice. At low temperatures at which the structure was determined, the
lattice constants were a= 4.53A and b = 7 .41A. How m any H 2O molecules are contained in an unit
cell? Given that density of ice = 0.92 g/c.c.
20. The total number of ions per unit cell in sphalerite (zinc blend) structure if there is a schottky defect
of one anion per unit cell, are?
g-..:
2 1.
Match the Following
Match the column-I with column-II :
(A) Molecular solid

Column-I
(p) Low m elting
Column-II
•
(B) Ionic solid (q) High m elting
(C) Metallic solid (r) Brittle
(D) Cavalent network solid (s) Malleable hard
(t) Electrically conducting

Column-I Column-II
(A) At least two interfacial angle be 90° (p) Unit cell of m onoclinic sulphur
(B) At least two crystallographic axis length be same (q) Unit cell of diamond
(C) None fo the axial lengths to be sam e (r) Orthorhombic crystal
(D) None of the interfacial angles to be same (s) Tetragonal crystal
(t) Triclinic crystal
!WWW.JEEBooKS.INI
52 CHEMISTRY

Passage-I •
Copper crystallizes in/cc lattice. Impurity atoms having radius 0.3 times the radius of Cu atoms are
inserted in this lattice. If radius of Cu atom is 1.3 A, then answer the following questions.
23. Calculate packing fraction after the insertion of impurity atoms
(a) 0.65 (b) 0.84 (c) 0.74 (d) 0.68
24. Minimum distance between Cu atom and an impurity atom is
(a) 2.758 A (b) 2 .328 A (c) 1.293 A (d) 1.688 A
Passage-II
The unit cell length of NaCl is observed to be 0.5627 nm by X-ray studies. The measured density of
NaCl is 2.1 64 g/c.c.
25. Which defect is/are not possible in this crystal?
(a) Schottky (b) Frenkel
( c) Anion vacancy (d) Extra cation occupy interestitial void
26. Calculate percentage of missing Na+ and c 1-
(a) 1.322% (b) 2.333% (c) 5.325% (d) 2.973%
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
Liquid Solution

1. An unknown compound is immiscible with water. It is steam distilled at 98 °C and P
P~
20
= 707 Torr
the unknown?
•
= 737 Torr,
at 98 °C. This distillate was 75% by weight water. What is the molecular weight of
(a) 140 g (b) 141.4 g (c) 145g (d) 149 g

2. 10 gram of a weak monocarboxylic acid in 100 gram of benzene freezes at 3.35 °C. Assume that
acid undergoes complete association in benzene. Find the [H+] in the solution if 10 gram of acid in
100 gram of water freezes at- 1.75 °C. Given that K ofwater and benzene are 1.86 and 5.12 Kim.
1
Freezing point of benzene is 5.51 °C.
(a) 0.1008M (b) 0.237M (c) 0.138M (d) 0.246M
3. 'x' gram ofa non-electrolyte compound (molar mass - 200) are dissolved in l lilre of NaCl of0.05 M
concentration. The osmotic pressure of this mixture at 27 °C is found to be 4.92 atm. What will be the
value of 'x'?
(a) 40 g (b) 30 g (c) 20 g (d) 50 g
4. Correct order of osmotic pressure is/are :
(a) 0.1 M Glucose > 0.01 M NaCl > 10-3 M MgCl2
(b) 0.1 M Glucose > 0.1 M NaCl > 0.1 M MgCl2
(c) 0.1 M Glucose > 0.1 M NaCl (a= 0.5) > 0.1 M MgCl2
(d) 0.1 M Glucose > 0.01 M NaCl (a= 0.5) > 0.1 M MgCl2
5. IfN2 is bubbled through water at 293 K, how many milli moles ofN2 gas would dissolve in 1 litre of
water? Given that partial pressure ofN2 is 0.987 bar, KH for N 2 is 76.48 x 103 bar.
(a) 0.178 (b) 0.817 (c) 0.781 (d) 0.718
6. Vapour pressure of water at 80 °C is 355 torr. A 100 ml piston fitted cylinder (as shown below) contain
water vapour in equilibrium with 0 2 gas at 80 °C and 1.0 atm.
100 ml 50 ml
Compression
80°C 80°C
Volume of equilibrium mixture was reduced to 50 ml. Assuming that no condensation occurs and
temperature remains same, what will be the final partial pressure of 0 2 gas
(a) 810 torr (b) 360 torr (c) 760 torr (d) 715 torr
7. 1
Resistance of MgCl2 at 27 °C is 100 0. Cell constant is 0.01 cm- . If molar conductance of this
WWW.JEEBOOKS.INI
58 CHEMISTRY
solution is 10 n- 1 cm2 mo1-1 then osmotic pressure of this solution after the addition of 0.6 gram of
urea in 1 litre ofMgC12 solution will be
(a) 1.24 atm (b) 0.4926 atm (c) 0.3624 atm (d) 0.9852 atm
8. Which among the following solution will have more boiling point than 0.1 M CH3COOH
(a) 0.1 M CF3 COOH (b) 0.1 M CC13COOH
OH
0 2N ~ N 02
(d) 0.1 Mof ~
9. Consider the following two diagrams : N02
Solvent o
Solvent •
(I)
Suppose that the solute molecules on the surface of solution occupy 10% of the surface area. The
correct statement is (are)
(a) If the water in the left vessel (I) was transferred to a container with 10% less surface area, the
vapour pressure would be lowered to same value as the vapour pressure in vessel (II).
(b) Mol fraction of solute in (II) is 0.33
( c) Boiling point of solution (II) is 114.44°C
( d) If the cross-sectional area of surface of solution in container (II) is increased by 10%, the number
of molecules in the vapour phase will increase by 10%
10. Consider 0.1 m aqueous solution of two solutes X and Y. The solute X behaves as a univalent
electrolyte, while Y dimerises in solution. Which of the following statement(s) is/are correct regarding
these solutions?
(a) The boiling point of the solution of X will be higher than that of Y
(b) The osmotic pressure of the solution of X will be higher than that of Y
( c) The freezing point of the solution of X will be higher than that of Y
(d) The relative lowering of vapour pressure of both the solution will be the same
~
11.
12.
•
0.02 M KI and 0.01 M AgNO 3 aqueous solutions are mixed in 2 : 3 volume ratio. What will be the value
of depression in freezing point. (dsolution = 1 g/ml)
1 mol. of A and 1 mol of B are mixed to form ideal solution. (VP. of pure A = 20 torr, VP. of pure
B = 80 torr)
Calculate the total pressure when last drop of liquid is remaining?
13. Calculate molal depression constant K for water? Latent heat of fusion= 80 cal/gm, F.P. of water= 0°C.
1
WWW.JEEBOOKS.INI
Liquid Solution 59
14. Air is saturated with water vapour having 1230 torr pressure if volume is doubled. Calculate new
pressure in container at equilibrium. (VP. H 2O = 30 torr)
15. A solute 'S ' undergoes a reversible trimerization when dissolved in a certain solvent. The boiling point
elevation of its 0 .1 molal solution was found to be identical to the boiling point elevation in case of a
0.08 molal solution of a solute which neither undergoes association nor dissociation . To what percent
had the solute 'S' undergone trimerization?
16. Safrole is contained in oil of sassafras and was once used to flavour root beer. A 2.4 mg sample of
safrole was dissolved in 100.0 mg of diphenyl ether. The solution had a freezing point of 25.64 °C.
The freezing point of pure diphenyl ether is 26.84 °C and the freezing point depression constant K ,
1
•
is 8.00 °C/m. The molar mass of safrole is
17. Total number of mixtures which are the examples of positive deviation
C 6 H 6 +C 6 H 5 CH 3 , CH3 Cl +H2 O, 0 +CH3 COCH3 , DMSO+C 6 H 6 , DMF+CH 3Br,
CH 3 Cl + CH3 Br, C 2 H 5 OH + H 2 O, CH 3 COCH3 + H 2 O.
18. Total nmnber of mixtures which are showing negative deviations :

HNO 3 + H 2 O, CH 3 COCH 3 + H 2 O, H 2 SO4 + H 2 O, CHC13 + CHBr3 , CHC13 + CH 3 COCH 3 ,
C 6 H 6 + CH 3COCH 3
19. Vapour pressure of a volatile liquid 'A ' is 60 torr at 27 °C. Vapour pressure of another volatile liquid
'B ' is 42 torr at 27 °C. IIow many moles of ' B ' should be added to 4 moles of 'A ' in order to bring
down the vapour pressure of solution by 20% at 27 °C.
20. Total number of pairs where London forces are present as intermolecular attractive interaction
Cl
CHCJ, + cc1,, CHCJ, + co,, co,+ SF,, co,+ cc1,,

Cl
,© Cl
+ CCI,, r, + SF,,
g----: Match the Following

2 1. Match the column-I with column-II :
(A) n-hexane + n-heptane

Column-I
(p)
Column-II
Can be perfectly separated by distillation
•
(B) Aceton + CHC13 (q) Maximum boiling azeotrope
(C) Acetone + Aniline (r) Can not be perfectly separated by distillation
(D) C 2 H 5 OH + H 2 O (s) Minimum boiling azeotrope
22. Match the solution in Column-I with their osmotic properties in Column-II :
WWW.JEEBOOKS.INI
60 CHEMISTRY
Column-I Column-II
(A) S 1 : 0 .1 M glucose ; S2 : 0 .1 M urea (p) S 1 and S2 are isotonic
(B) S 1 : 0.1 MNaCl ; S2 : 0.1 MNa2 SO4 (q) S 1 hypertonic to S2
(C) S 1 : 0.1 MNaCl ; S2 : 0.1 M KCl (r) S 1 is hypotonic to S 2
(D) S 1 : 0.1 M CuSO4 ; S 2 : 0.1 M Sucrose

Passage-I •
Copper crystallizes infcc lattice. Impurity atoms having radius 0.3 times the radius of Cu atom s are inserted
in this lattice. If radius of Cu atom is 1.3 A, then answer the following questions.
23. Calculate packing fraction after the insertion of impurity atoms
(a) 0.65 (b) 0.84 (c) 0.74 (d) 0.68
24. Minimum distance between Cu atom and an impurity atom is
(a) 2.758 A (b) 2 .328 A (c) 1.293 A (d) 1.688 A
Passage-II
The unit cell length of NaCl is observed to be 0.5627 nm by X -ray studies. The measured density of NaCl is
2.164 g/c.c.
25. Which defect is/are not possible in this crystal?
(a) Schottky (b) Frenkel
(c) Anion vacancy (d) Extra cation occupy interestitial void
26. Calculate percentage of missing Na+ and c 1-
(a) 1.322% (b) 2.333% (c) 5.325% (d) 2.973%
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
Electrochemistry
& Redox Titration
1. In 100 ml M CH 3COOH, 50ml M NaOH is added and after this a platinometer is dipped in this
10 10
•
resulting solution and H 2 gas at ' l ' atm pressure is passed by the help of glass jacket. What will be the
electrode potential of the resulting solution at 25 °C assuming that Ka for CH3 COOH is 10-5 7
(a) + 0.2955 volt (b) - 0.2955 volt (c) - 0.3456 volt (d) + 0.3456 volt
2. Calculate the value of solubility product for solid Agl by using following data :
Ag+(aq) + e- ~ Ag(s) E 0 = 0. 800 volt
Agl(s) + e- ~ Ag(s) + 1-(aq) E 0 = - 0 164 volt
(a) 5 x 10-17 (b) 6 x 10-15 (c) 2 x 10-14 (d) 4 x 10- 12
3. A half cell reaction: Ag 2 S+ 2e- ~ 2Ag + s2 - is carried out in a half cell PtAg S I Ag,H 2 S(0.1M), at
2
(solid) (solid)
pH= 3. What will be the electrode potential of this electrode ifE0 Ag+/Ag = 0.8 volt, Ka for H 2S is
10-21 and Ksp of Ag2 S = 10-49
(a) -0.1735V (b) -0.19V (c) +0. 1735V (d) +0.19V
4. Reduction of NOf ions occur as
e (±)
NO3 + 4H +3e- ~NO+2H 2 O ; E 0 = 0.96 volt.
The electrons are provided by cathode till that the solution originally having 0.1 M NOf and 0.4
M H® shows that 80% of NOf ions are converted to NO showing l bar pressure. The reduction
potential of remaining solution
(a) 0.84 volt (b) 1.36 volt (c) 1.08 volt (d) 1.56 volt
5. For the cell: Ag(s) I AgBr(s) I KBr(aq) II Hg2Bris) I Hg
the variation of emf with temperature is shown by the graph given below:
0.071
i
E
0.069
0.067
0.065 ,....____,•_ _ _ _ _ __
293 K 303 K
T ~
What will be LiH of the reaction ?
(a) 9.882 kJ (b) 12.762 kJ (c) 6.782 kJ (d) 13 .884 kJ
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66 ===================== CHEMISTRY
6. What will be hydrolysis constant of anilinium hydrochloride Pt 1H2 (1 atm) I HEB (1 M) II PhNH3 Cl
(M/32) I H 2 (1 atm), Pt if cell potential of the cell is - 0.188 volt at 298 K
(a) 1.352 x 10-5 (b) 4.32 x 10-6 (c) 8.72 x 10-5 (d) 7.98 x 10-4
7. Impure Cu contains only Fe, Au and Ag as impurities . After passage of 140 ampere for 482.5 seconds
the mass of anode decreased by 22.260 gram and the cathode increased in mass by 22.011 gram.
Calculate the % of iron in impure copper.
(a) 2% (b) 0.85% (c) 5.5% (d) 98.88%
8. Consider the following reactions:
A+B ~ C+D Kc = K 1 and E 0 = a volt
2A + 2B ~ 2C + 2D 0
Kc = K 2 and E = b volt
then select correct option :
(a) a = b (c) a = 2b (d) b = a 2
9. The tarnishing of silver ornaments in atmosphere is due to
10. A lead storage battery is discharged which causes the H 2 SO4 electrolyte to charge from a concentration
of 40% by weight (d = 1.260 g/ml) to 28% by weight. The original volume of solution was 1 litre.
Select correct statement(s)
(a) Overall reaction will be Pb(s) + PbO2 (s) + 2H 2 SO 4 (aq) ~ 2PbSO 4 (aq) + 2H 2 O(£)
(b) A total 2.0 moles ofH 2 SO4 is reacted.
(c) The total charge released from anode of the cell is 1.93 x 105 coulomb.
(d) The mass of electrolyte solution has decreased.
rfil
11.
12.
If an aqueous NaCl solution is electrolysed using a current of 5 A for 200 minutes, volume of Cl2 (g)
in ml, produced under STP conditions is (F = 96500 C).
Gold is to be plated out on a square coaster of side-length of 5 cm by electrolysis of a solution
•
containing K[Au(CN)2 ]. If thickness of gold plating is x x 10-2 mm by passing 2 A for 1 hour. What
is the value of x?
13. How many Faradays of electricity is required for electrolysis of 144 gram of acidified water?
14. Ag I AgBr I Br- I II Cl- I AgCl I Ag ; K sp of AgBr = 10-13 ; K sp of AgCl = 10-IO
(s) (s) (0.1 M) 0.0IM (s) (s)
Calculate Ecell at 25°C?
15. A lead storage battery contains 2L H2 SO4 solution (1.2 g/ml density and 40% W/W). During
discharging, density of H 2 SO 4 reduces to 1.1 gm/ml and % W /W = 20%.
Calculate amount charge (in F) produced keeping volume constant.
16.
17.
Equivalent conductance of 0.2 M aqueous solution of a weak monobasic acid (HA) is 10 S cm 2 eq- 1
and that at infinite dilution is 200 S cm 2 eq-1 . Hence, pH of this solution is :
A 500 ml of aqueous NaCl solution is electrolysed for 1 minute using a current of 8 mA at 25 °C. What
•
is the pH of the final solution?
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Electrochemistry & Redox Titration 67
18. The charge required for discharging 115 gram ofNa from molten NaCl is .. .. Faradays.
19. Emf of a cell corresponding to the reaction.
Zn(s) + 2HEB(aq) ➔ z n+2(aq) (0.1 M) + Hi(g) (1.0 atm) is 0.3 175 volt at 25°C.
A lso, at 25°C, E 0 Zn+2/Zn = - 0.76 volt. The pH of solution in cathode chamber is.
20. A current of 0.01 A is passed through a solution of iridium bromide. The only reaction of the cathode is
the deposition of iridium metal. A fter 3.0 hrs, 0.072 g oflr is deposited. The oxidation state of iridium
ion (atomic weight= 192) is

2 1. •
An aqueous solution of 'X ' is added slowly to an aqueous solution of ' Y ' as shown in column-I. The
variation in conductivity of these reactions is given in column-II :
Column-I (X + Y) Column-II
(A) Me3N + CH 3COOH (p) Conductivity decreases then increases.
(B) KI (0.1 M) + AgNO3 (0.01 M) (q) Conductivity decreases and then does not charge much.
(C) CH 3COOH + KOH (r) Conductivity increases and then does not charge significantly.
(D) NaOH + HI (s) Initially conductivity remains same and then increases.
22. At 25 °C standard reduction potentials of various electrodes are given below:

Fe+3 + e- ➔ Fe+2 E 0 = 0.77 volt
Fe+2 + 2e ➔ Fe E 0 = - 0.44 volt
c u+2 + 2e- ➔ Cu E 0 = 0.34 volt
0 2 + 4HEB + 4 e- ➔ 2H 2O E 0 = 1.23 volt
0 2 + 2H 2O + 4e- ➔ 4OH- E 0 = + 0.4 volt
c r+3 + 3e- ➔ Cr E 0 = - 0.74 volt
Cr+2 + 2e- ➔ Cr E 0 = - 0.91 volt
Column-I Column-II
(A) E 0 (Fe+3, Fe) (p) - 0.70 volt
(B) E 0 (4H2O ➔ 4HEB + 4OH-) (q) - 0.40 volt
(C) E 0 (Cu+2 + Cu ➔ 2Cu) (r) - 0.04 volt
(D) E (Cr+3, Cr+2)
0
(s) - 0.83 volt
•6£? Passage Based Questions

•
Passage-I
A current of 15 ampere is used to plate N i from N iSO4 bath. Both H 2 and Ni are formed at cathode. The
current efficiency ofNi formation is 60% (at wt . of N i is 58.71).
•
23. The thickness of plating if the cathode consists of a sheet of 4 cm 2 which is coated on both sides,
density of N i is 8.9 g/ml
(a) 0.276 cm (b) 0.272 cm (c) 0.316 cm (d) 0. 138 cm
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68 CH EMISTRY
24. The volume ofO2 is formed per hour at S.T.P.
(a) 6.26 litre (b) 3.1 3 litre (c) 9.39 litre (d) 2.51 litre
Passage-II
Redox reactions play a pivotal role in chemistry and biology. The values of standard redox potential (E0 ) of
two half-cell reactions decide which way the reaction is exp ected to proceed. A simple example is a Daniel
cell in which zinc goes into solution and copper gets deposited. Given below are a set of half cell reactions
(acidic medium) along with their E 0 (V w ith respect to normal hydrogen electrode) values. Using this data
obtain the correct explanations to questions given.
12 + 2e- ➔ 21- E 0 = 0.54 volt
Cl2 + 2e- ➔ 2c1- E 0 = 1.36 volt
Mn+3 + e- ➔ Mn+2 E 0 = 1.50 volt
Fe+3 + e- ➔ Fe+2 E0 = 0.77 volt
Oz+ 4H© + 4e- ➔ 2H2 O E 0
= 1.23 volt
25. Select correct statement.
(a) Chloride ion is oxidised by 0 2 (b) Fe+2 is oxidised by iodine
( c) Iodide ion is oxidised by chlorine (d) Mn +2 is oxidised by chlorine
26. While Fe+3 is stable, Mn+3 is not stable in acidic medium because
(a) Oz oxidises Mn+2 to Mn+3 (b) 0 2 oxidises both Mn+2 and Fe+z
(c) Fe+3 oxidises H 2 O to 0 2 (d) Mn+3 oxidises H 2 O to 0 2
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
Chemical
Kinetics
1. A radioactive substance 'X' has half life of 2 hour. An injection contains 2 µg of 'X' is repeatedly
given to the patient for the treatment of cancer with the time interval of2 hour. How much amount of
•
'X' will be present in the body of patient just after 4th injection
(a) 8 µg (b) 3.125 µg (c) 3.75 µg (d) 6.5 µg
7
2. Cl2 0 7 (g)~Cl2 (g) +-02 (g) (first order)
2
When decomposition is carried out in a closed box, pressure measured after 15 minutes and after a
very long time were found to be 240 and 900 mm of Hg respectively. Calculate the pressure that would
be observed in the box after 140 min under identical codnitions of temperature
(a) 495.75 mm (b) 660 mm
(c) 450 mm (d) 461.5 mm
3. A reaction rate increases by a factor of 500 in the presence of catalyst at 37 °C. If the reaction is carried
out in presence of a catalyst at 127 °C by what factor, compared to original rate in absence of catalyst
at 27 °C, the rate will increase. In absence of catalyst activation energy is 106 kJ/mol.
(a) 8.33 x 105 (b) 2.04 x 105
(c) 5.05 X 106 (d) 3 x 106
4. Two radioactive nuclides A and B have halflives in the ratio 2 : 3 respectively. An experiment is made
with one mo! of each of them. Calculate the molar ratio of A and B after a time interval of three times
of half live of A
1 1
(a) (b)
2 4
1 2
(c) (d)
3 3
5. In order to determine the volume of blood in an animal, a 1.0 ml sample of solution of 103 dpm of
3
1H is injected into the animal blood stream. After sufficient time for circulatory equilibrium to be
established, 2 ml of blood is found to have activity to 10 dpm. The volume of blood in animal is :
(a) 20 ml (b) 150 ml
(c) 195 ml (d) 199 ml
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74 ===================== CHEMISTRY
6. Gaseous HI first adsorbed on the surface of gold and then undergoes decomposition into H 2 and 12 .
Which of the following graph correctly represents the reaction?
t----HI
p
t
p
t
p---HI
(a) Hz (b) (c) (d) t----Ii
HI HI
Time~ Time ~ Time~ Time~
7. Various intermediates are produced during A ➔ B transformation. t,Jf= 500 kJ

By the help of follow ing potential energy diagram predict, how many intem1ediates are involved in
this transformation.
Reaction coordinates ~
(a) 1 (b) 2
(c) 3 (d) 4
8. A reaction takes place in three steps; the rate constants are K 1, K 2 and K 3 . The overall rate constant
K = (Ki K 3 ) . If the energies of activation are 40, 30 and 20 kJ/mol, the overall E 0 will be if 'A' is
Kz
constant for all
(a) 40 kJ/mol (b) 30 kJ/mol
(c) 20 kJ/mol (d) 45 kJ/mol

I
9. The rate of change of concentration of ' B ' for the reaction A ➔ Bis given as + d(B) = K[A]3 . The
dt
half life period of the reaction will be
2 2 2 2
- -
3[Ao]3(23 -1) 3[Ao]3 (2 3 -1)
(a) 5 (b) 2
23 K 23K
2 2 2 2
3[Ao]3(2 3 -l) 2[Ao]3(2 3 - l)
(c) 5
(d) 2
23 K 3x23 K
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Chemical Kinetics 75
10. Select correct statement.

(a) Half life period of all reactions decreases with increase in temperature
(b) Half life period of first order reaction is always constant.
( c) Higher is the rate constant of a reaction, lesser will be its energy of activation
(d) Rate ofreaction whether exothermic or endothermic usually increases with temperature .
(ill
11.
12.
•
A given sample of milk turn sour at room temperature (27 °C) in 16 hours. In a refrigerator at 7 °C, milk
can be stored three times as long before its sours. How long (in min.) it takes for milk to sour at 57 °C?
A wooden lamp excavated recently was found to emit 5~ particles per minute per gram of carbon. The
minute per gram of carbon. The freshly cut wood is found to emit 14~ particles per minute per gram of
carbon. Calculate the age of wooden lamp. Half life period of 14C 6 is 5760 years.
13. A substance (Bicyclohexene) undergoes !81 order decomposition. The decomposition follows two
parallel path as
~ Cyclohexene
Bicyclohexene
~ Methyl cyclopentene
k 1 = 1.26 x 10-4 s - I , k2 = 3.8 x 10- 5 s. What is the percentage distribution of cyclohexene and methyl
cyclopentene?
14. For the reaction, A B C. Find the time at which concentration of B is

maximum?
15. A substance A undergoes a reaction such that its concentration at any time t (in seconds) can be
represented by the equation :
[A]4-_1_
1
- (t+ 1)
The rate of disappearance of 'A ' (in 10-6 M sec1) at the concentration [A]= 0.2 Mis?
16. Mechanism of OCI + 1
e K1
e e ow'
~
e e
OI + Cl is given below :
e
•
OCI + H 2O ~ HOCI + OH (fast)
K2
le+ HOCI~ HOI + Cle (slow)
K'
e __ ~ e
OH + HOI ~ H2O +OI (fast)
What is the order of reaction?
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76 ===================== CHEMISTRY
17. How many of the following graphs are correct?
t t 1 - - - - - - [0 order]
I.
[O order]
II.
t
X
[O order]
III.
dx
dt
a~ a~ (a-x) ~
t (1.5 o rder)
t
..j(a-x) ~ Noc)
IV -
3 V
(a-x) 2
/ ~
a = initial concentration of reactant ; t = time of the reaction progress

x = amount of reactant converted into product.
18. Consider the following first order decomposition process An ➔ nA
i
C:
0
-~
~
u
C:
8
Time ~
th
Here, t corresponds to the time at which (¼) of reactant is decomposed. The value of ' n ' is
19. The half of a gaseous compound (A(g) ➔ B (g)) initially at 2 atm is 200 seconds. If the initial pressure
is taken as 1 atm, the half life reduces to 100 seconds. The order of reaction is
20. If for a reaction A ➔ products, the concentration of A are Co, aCo, a 2Co, a 3Co ..... after time interval
of 0, t, 2t, 3t .... where 'a ' is a constant and O< a < l. The order ofreaction is
W WW.JEEBOOKS.INI

2 1. Match the columns :
(A) Rate of reaction

Column-I
(1) ~[A]
Column-II
d[A] (a)
Column-III
!'!.H = + ve or - ve
•
---=---
~t dt
(B) Rate constant of reaction (2) Vt = Vt (b) !'!.H = - ve
(C) V .Vo.T
-- (3) Vt "'F Vo (c) t➔O
1
- 273
(D) Vapour pressure (4) Increases (d) M➔ O
(E) V0 .t (5) Decreases (e) T➔ O

Vi=Vo+-
273
22. Match the Column-I with Column-II.
Column-I Column-II
(A) " (p) t 00 = 2xt112
t
t 1/,
I
- Co ---+
(B) ~ (q)
t3 ! 4 = 2xt112
(C)
1112
I I/. - Co ---+
,
(r)
tI ~
'
i
-dc1
-
ct dt
I
I -
~ Time -+ ,
Time---+
(D) ' (s) t112 x c0 = constant
t
In c,
I -----
Time ---+
(t) Zero order
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78 CHEMISTRY
2-
Passage-I
e
S20 8 + 31 ~2S04 + 13
2- e
•
This reaction is of first order both with respect to persulphate and iodide ions. Taking the initial
concentrations as 'a' and 'b' respectively, and taking x as the concentration of triiodide ion at time 't',
a differential rate equation can be written.
Two suggested mechanisms for the reaction are :
I. (fast) ; (slow)
(fast)
3- k2 2- EB
II. (slow); S2 0 8I ~ 2S04 + I (fast)
k
(fast) ; 12 + l e ~ I3e (fast)
23. The general differential equation for the above reaction is
dx dx
(a) dt =k[a-x][b-3x] (k>O) (b) - =-k[a-x][b-3x] (k>O)
dt
dx dx
(c) - = k[a-x][b-x] (k > 0) (d) dt =-k[a-x][b-x] (k > O)
dt
(I)
dt 2 dt
The correct option is

(a) Only I (b) I and IV (c) II and IV (d) Only III
Passage-II
Two consecutive irreversible first order reaction can be represented by A ~ B ~ C

The rate equation for A is readily integrated to obtain
[A]t = [A]o .e-k1t and [B]t = k1 [A]o [e-k1t -e-kzt ]

kz -k1
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25. When k 1 = 1 s- 1 and k 2 = 500 s- 1; select appropriate graph .
c.i
C
(a) (b) 8
t (sec) t (sec)
c.i c.i
C
0 C
(c) u (d) 8
[A ],
t (sec) t (sec)
26. If k 1 and k2 both are almost same then which graph in the above question is most suitable?
(a) Graph 1 (b) Graph 2 (c) Graph 3 (d) Graph 4
RESPONSE SHEET
1. Ci)@@@ 2. Ci)@@@ 3. Ci)@@@
4. Ci)@@@ 5. Ci)@@@ 6. Ci)@@@
7. Ci)@@@ 8. Ci)@@@ 9. Ci)@@@
10. Ci)@@@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 1
8 1 lcl lnl
23. Ci)@@@ 24. Ci)@@@ 25. Ci)@@@
26. Ci)@@@
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Surface
Chemistry

1. •
A catalyst has total surface area of 103 cm2 and adsorption sites availabe on it are 6 x 10 15 sites/cm2 .
H 2 gas is adsorbed on this surface occupying only 5% of the available sites of total surface area. On
heating catalyst releases H2 back and whole of the H 2 adsorbed is measured to occupy 2.46 ml at 0.03
atm and 300 K. The number ofH2 molecules adsorbed on each site has equal to
(a) 6 (b) 2 (c) 3 (d) 4
2. A one litre vessel contained a gas at 27 °C. 6 gram of charcoal was introduced into it. The pressure
of the gas fell down from 700 mm Hg to 400 mm Hg. Calculate the volume of the gas (at N.T.P.)
adsorbed per gram of charcoal. Density of charcoal sample used was 1.5 g/c.c.
(a) 60.107 C.C. (b) 63.203 C.C. (c) 59.232 C.C. (d) 65.113 C.C.
3. In an adsorption experiment, a graph between " log (x/m) vs. log P " was found to be linear with slope
of 45°. The intercept on the y-axis was found to be 0.3010. What is the amount of the gas adsorbed per
gram of charcoal under a pressure of 0.5 atm.
(a) 1.0 (b) 2.0 (c) 3.0 (d) 4.0
4. One litre vessel having 20 gram charcoal (d = 2 g/c.c.) was filled with a gas at 300 K. The pressure of
the gas was 760 torr. Due to adsorption the pressure of gas falls to 608 torr. What is the number of gas
molecules adsorbed per gram of charcoal?
(a) 2.4 x 1021 (b) 2.4 x 1020 (c) 2_4 X 1022 (d) 2.4 x 1023
5. One gram of activates carbon has a surface area of 1000 m 2 . Considering complete coverage as well as
mono moleclular adsorption, how much NH 3 at S.T.P. would be adsorbed on the surface of 44/7 gram.
Carbon ifradius of a NH 3 molecules is 10-8 cm (NA= 6 x 1023 )
(a) 7.46litre (b) 0.25litre (c) 44.8litre (d) 25litre
6. A catalytic poison renders the catalyst ineffective beacause
(a) It is preferentially adsorbed on the catalyst.
(b) It adsorbs the molecules of the reactants.
(c) It always combines chemically with the catalyst.
( d) It combines with one of the reactant.
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84 ===================== CHEMISTRY
7. Select the correct statement.

(a) Lamp black in water is passed in colliodal state on addition of gum.
(b) White precipitate ofBaSO4 on washing continuosly with water gives BaSO4 sol.
(c) Electrodialysis is used to remove ionic impurities faster.
(d) Brownian movement occurs due to unbalanced collision among D.P. and D.M.
8. Select correct statement(s).
(a) Brownian movement was noticed in colliodal solution by Robert Brown.
(b) Enzyme catalyst are highly specific.
(c) Enzyme catalyst's promotors are called co-enzyme.
(d) 1 : 1 molar mixture of AgNO3 and KI will form +ve sol.
9. Which of the following will show Tyndall effect?
(a) Aqueous solution of sodium stearate above critical micelle concentration (CMC).
(b) Aqueous solution of sodium stearate below CMC.
( c) Aqueous solution of sodium stearate above kraft temperature.
( d) Aqueous solution of salt.
10. Which of the following is not lyophilic?
(a) Gelatin sol (b) Silver sol (c) Sulphur sol
~
11.
•
The mass of gas absorbed x per unit mass of adsorbate m was measured at various pressure p. A graph
between log(:) and logp gives a straight line with slope equal to 2 and the intercept equal 0.4771.
The value of ~ at a pressure of 4 atm is ?

m
12. The chemisorption of hydrogen on Mn is activated but only weakly. So careful measurements
have shown that it proceeds 20 times faster at 1000 K than at 600 K. If the activation energy for
chemisorption is x x 10 cal then what is 'x' if e3 = 20.
13. In a solution of 100 ml 0.5 M acetic acid, 1 g of active charcoal is added, which absorbs acetic acid.
It is found that concentration of ace tic acid becomes 0.49 M. If the surface area of charcoal is
3.01 x 102 m 2 . If the area occupied by single acetic acid molecule on the surface of charcoal is
x x l 0-20 m 2 . Calculate x ?
14. When 6 x 10-5 g of a protective colloid was added to 20 ml of a standard gold sol, the precipitation of
latter was prevented on addition of 2 ml of 10% NaCl solution. The gold number of protective colloid
IS
15. For the coagulation of 200 mL ofAs2 O3 , 10 mL of 1 M NaCl is rquired. What is the coagulating value
of NaCl?
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Surface Chemistry 85
16. Total number of statements which are correct regarding heterogeneous catalysis. •
(a) The surface of catalyst unlike the inner part of the bulk, has free valencies which provide the seat
for chemical forces of attractions.
(b) In last step of heterogeneous catalysis heating is must for desorption of product moelecules from
catalyst's surface.
(c) For hydrogenation reaction catalytic activity increases from group 5 to group 11 metal.
Catalyst
(d) In hydrogenation reaction maximum activity in shown by group 7-9 elements of periodic table.
(e) Porosity range of ZSM - 5 is 0.26 nn1 to 0.56 nm.
17. The gold number of gelatin is 0.01 . If the amount of gelatin to be added to 1000 ml of a colliodal
solution of gold to prevent its coagulation before adding 1 ml of 10% NaCl is 'x ' mg then 'x ' is
18. A ssuming haemoglobin as +ve sol, how many among the following can coagulate haemoglobin
Fe(OH)3 sol, Ca(OH) 2 , Al(OH)3 , Starch, Clay, As2 S3 sol, CdS sol, Basic dye.
19. 526.3 ml of 0 .5 m HCI is shaken with 0.5 g of activated charcoal and filtered. The concentration of
filterate is reduced to 0.4 m. Degree of adsorption (x/m) will be.
20. Among the following colloids the number of colloids having negatively charged colloidal particles is:
Soap solution of sodium stearate, solution ofAgCl obtained by mixing equimolar mixture of AgNO 3
and KCI, gold sol, Fe(OH)3 sol, Silicic acid sol, Basic dye, acidic dye, metal sulphide sol, PHBV in
acetone.
g-..:
2 1.
Match the Following
Match the columns :
Column I
(A) Placing silica gel in water vapour (p)
Column II
Enzymatic catalysis
•
(B) Placing anhydrous CaC12 in water vapours (q) Occlusion
(C) Placing finely divided nickel in closed vessel having H2 gas (r) Adsorption
(D) Conversion of proteins into amino acids (s) Absorption
(t) Negative adsorption

Column I (Colliodal sol) Column II (D.P.) Column III (D.M.)
(A) Colloid ion (p) Water (1) C2 H 5 OH
(B) Fog (q) Cellulose (2) 0 : 1
(C) Butter (r) Fat (3) Air
(D) Milk (4) H 2 O
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86 CHEMISTRY

Passage-I
Emulsions are the colliodal solutions in which both D.P. and D.M. are immiscible liquids. To stabilize
the emulsions some stabilising agents are added called emulsifier. Emulsions may be oil in water (o/w)
or water in oil (w/o) type.
•
23. Which of the following example is/are o/w type ?
(a) Ink (b) Detergent (c) Soap (d) Milk
24. A ddition oflyophilic solution to the emulsion forms
(a) A protective film around the dispersed phase.
(b) A protective film around the dispersion medium.
( c) An aerosol.
(d) True solution.
Passage-II
Specific surface area of a solid adsorbent is the surface area of the unit mass of the adsorbent. For any
adsorbent, the specific surface area may be increased by taking the adsorbent in powdered form or by
increasing the pores in the solid.
25. If the unit mass of a solid taken as a cube of volume 8 cm 3 is powdered into identical l 0 12 cubes, then
the specific surface of the solid.
(a) 1012 times (b) 104 times (c) 10-8 times (d) 103 times
26. A volume of 11 2 c.c. H 2 gas is adsorbed uniformly at the surface of 5 g ' Pd' at 273 °C and 2 atm. If
the effective surface area of each H 2 m olecule is 0.4 nm2 , then the sp ecific surface area of Pd is
(NA = 6 x 1021)
(a) 1.2 x 107 cm 2/g (b) 6.0 x 107 cm2/g (c) 2.4 x 106 cm 2/g (d) 6 x 105 cm 2/g
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
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General Organic
Chemistry

1. Which of the following are more acidic than given molecule?
I~ COOH
•
(a) HO ~ COOH (b) H3~ ~ COOH
(c) HOOC ~ COOH (d) NC ~ COOH
2. Which of the following is/are correct order for Ka?
c0
COOH COOH COOH COOH
(a) @JCH,>@ >® cH/

CH3
(b) ~ COOH >@-cooH>CH,-COOH >~ OH

S03H
COOH COOH COOH
(d)OH'@'OH >@ >@ OH
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92 ===================== CHEMISTRY
3. The correct order of resonance energy is/are
~) @ < 00 < ®s@{@l§)

(c) @-@ >00
(d)@X)§) >@X§X)
4. Which of the following statements is/are correct?
(a) HCOOH is stronger acid than Ph - COOH
(b) Oximes (R2 C = N - OH) are more acidic than hydroxyl oxime (NH2 - OH)
(c) R 3 Si - CH 2 - COOH is more acidic than R 3 C - CH 2 - COOH
0
(d) oA o > Ho t = !o > R - SO H > R - COOH

3
H0'>===-1..0H HO O (acidity order)
5. Correct stability order of carboanions

0 0
(a) ~ > ~ OMe > ~
e e e
~) o $:e>0
~
>
e
N02
0 ~:e>
e
(c) > HC=c: 8
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General Organic Chemistry 93
6. Which of the following represents correct order of basic character?
(b) Me3 N > Me2 NH (Gas phase)

NH2
HN
~
I
H
7. Which of the statements are incorrect?
(a) W and CH 2 ~ CH - 0 6 are ooplana,
(b) CH3 and CF3 are coplanar

e e
(c) CH3 < CH3 (stability)
14
w
8. Which of the following is/are correct?
(a) is anti arnmatie
~) ¢ a >
0
o
(order ofR.E.)
0
(c) Carbolic acid not react with NaHSO3 but react with Na
Ph
(d) Ph is a aromatic compound
9. Which of the followings is/are incorrect?
(a) [:::N - CH3 < C N - CH, ( frequency of invension)
~) l Q > (HOC)
(c) Ph - CH= CH - Ph is colourful but Ph - (CH= CH)4 - Ph is colourless.

(d) CH3CN is more acidic than HC = CH.
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94 ===================== CHEMISTRY
10. Which of the following can show resonance?

(a) CH 2 = C = CH2 (b) O=C=O
(;'yo
(d) ~
\
11. P = Number of anti-aromatic compound in given list.
CH 0
•
□ @0 0 60
f
Q = No. of resonating structure of SO 42- R= No. ofa-H i n u
T = No. of compound more acidic than ~ O H
OH
@,
Then (P + Q + R + S + T) - 15 is ?
12. How many compounds liberate hydrogen gas on reaction with Na metal?
OH
0 @0 0 0
( I) (2) (3) (4) (5)
HO~OH
COOH
(6)
CH3 - CH3
(7)
HO
o*o 0
(8)
OH
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H0)-1'0
HO~O ~ ~ /'0- ~ / ' - . . /NH'-../

(9) ( 10) (11) ( 12) (13) (14)
H
I ..
00
( 15) ( 16)
13. Number of ambidented nucleophiles are
CH3 -CH = 0, CN-, SCN-, Na El\ Cl-, OCN-, NCS-, N3, CH3COO-, C20~-, C202S~-,
(1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11)
08
14.
(12) ( 13)
Number of carbocation which will show rearrangement.

6 ( 14)
EB NH2
HO/'-../
R OH ,
✓1
15. How many of the following are more stable than Ph - CHf?
VIII IX
YL ,
EB O co3~
CD3
co
·3
o EB,
X Xl Xll
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96 ===================== CHEMISTRY
16. Number of species which will show amine inversion more comfortably than (ipr)3N:
I
H
17. The compounds which are more acidic than HC = CH.
H
,0 , CH 3 - CaCH,
8
18. Which of the following are better nucleophile than@-~ : in polar aprotic solven?
8
H,N -@--0°, r-, B,-, c1-,F-, @ - s 8 , @ - se , @:o 0
,
@-oH
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EE>
Column-I (Reagent)
(p) +I
Column-II (Product)
•
(A) - NH3
EE>
(B) - PEt
(q) -I
3
..
(C) - 9 C2Hs (r) +R
H (s) -R
(D)
~ Cl
(t) + H
(u) -H
Column-I Column-II
N (p) Carbene
(A)
0~ t:,.
.'
o-◊Ts
(q) N itrene
(B) t:,.
.'
t:,.
(C) CH2CO . (r) Free radical
0 t:,. (s) Carbocation

.'
(D)
~~
0 0
(i)
Passage-I
Aromatic compounds are those that meet the following criteria :
The structure must be cyclic, containing (4n + 2)n electrons
•
(ii) Each atom in the ring must have p-orbitals.
(iii) Unhybridised p-orbitals/lone pair/ vacant orbital must overlap.
(iv) Structure must be planar.
In anti-aromatic compound (4nn) electron are delocalization but delocalization of TT-electrons over the
ring increases the electronic energy.
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98 ===================== CHEMISTRY
21. Which of the following are aromatic?
(a) 0 (singlet carbene system) (b)
(c)
~
(d)~
22. Which are correct?
(a)
C = C (x) is more reactive towards methylene insertion because it do not involve in aromaticity.
¢
0
(b) is anti-arnmatic and quickly dimerises w ith benzyne.
(c) o(
D
D
and A are not same at very low temperature.
D D
~- & ~ :CD all a,:e arnmatic species.
Passage-II
OH OH OH OH
~OH ~ N02
( i) lSJ (ii) ~
~OH
(v) lSJ (vi)
@lN0 2
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(x) '$
OH OH OH OH
~ COOH O2N ~ N02 /2yN0 2
(vii) ~ (viii) ~ (ix) ~
NO2 NO2
23. Correct order of Ka value
(a) (i) > (ii) > (iii) > (xi) (b) (ii) > (iii) > (i) > (xi)
( C) (ii) > (xi) > (iii) > (i) (d) (ii) > (i) > (iii) > (xi)
OH
24. @ K,:,o, p
(Major)
~
OH
(b) ~
LS(OH
(c) (d)
LOH
lSJ
OH
RESPONSE SHEET
1. ~®@@ 2. ~®@@ 3. ~®@@
4. ~®@@ 5. ~®@@ 6. ~®@@
7. ~®@@ 8. ~®@@ 9. ~@Cs)@
10. ~®@@ 11. 12.
13. 14. 15.
16. 17. 18.
19. IAI 1
8 1 lcl lnl
21. ~®@@ 22. ~®@@ 23. ~@Cs)@
24. ~®@@
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Isomerism

1.
M(® 1
H Me •
N
H,,,A,,Me
Me H
(a) It contains POS (b) It contains COS

(c) It contains AAOS (d) It is optically active
2. Which of the following cannot be separated by fraction crystallization?
Me Me
H* OH H* OH
(b) H OH HO H
H OH H OH
Me Me
Me Me
H Cl Br H
(c) (d)
Br H CI H
= Me Me
3. Which of the following is/are correct?
(a) N-methylethanamine exist as non-isolable racemic mixture.
(b) N-methylethanamine react with excess at DCl and give configurational enantiomers.
(c) Two confo rmational isomers of butane have equal energy and they are chiral.
(d) Penta-2,3-diene exist in optically active isomeric form.
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104 ===================== CHEMISTRY
4. Identify resolvable compound?

Br
(a) (b) Trans-cyclocta-1-ene
(d) Twistane
5. Which of the following pairs can be resolved?
Q R2 OH
I
OH
I
(a)
N R, ~ rN _;R3 (b)
R~i~R HOOC( / i ~ H H( / J ~COOH
=
I
R2
3
0 Me Me
(c)
Me( /
.. e
C
1~C2H 5 H 5C? " Me
.. e
C
1~ (d)
4"-H
<r/H&
Q
6.
H H
The compounds which can show racemisation under mild basic condition is/are?
0
Me Me
0
(a)
0
ft~ 0
(b) (c)
~
,/✓
,,,
O
(d)
Me . Me Me Et
7. If x = Total number of chiral steremsomer of 1,2,3 ,4,5,6-hexachloro cyclohexane.
If y = Total number of a chiral stereoisomer of 1,2,3 ,4-tetra chloro cyclobutane.
(a) x + y = 6 (b) x + y = 8 (c) I x - y I = 2 (d) lx- y l=3
8. The conformer in which gauche form is m ore stable than anti
(a) F - CH 2 - CH 2 - F
~) F - CH 2 - CH 2 - CH3
$
(c) F - CH 2 - CH 2 - NH3
(d) HOOC - CH 2 - CH2 - COOH in NaHCO3 solution.
9. The compounds which are meso?
Cl
OH OH
J
u
C~ f>CI
(b) ~ (c) (d)

(a) ~
=
OH OH
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Isomerism 105
10. Which of the following system can show GI?
(a)
Me
H
>=c = C=
/Me
C',_
H
(b) 0
Br H00C Br
/0~0~
(c) (d) ~
H00C l N02
11.
12.
Total no. of cyclic structural isomer possible with formula C 6H 10 .
Find out number of compound those have ' R' configuration from following.
CH 21
I
HytyH
•
0HC j
~
- { H
CH20H 0 H~Br
H
Br
I
13. Total number of compound having POS are :
H_=f=CH
3 Br
Cl H
H Br
C
CH3
FAF
u
H H
(Uans-COT)
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106 CHEMISTRY
F
14. Total number of optically active isomers possible for this compound.
15. Number of stereoisomer for this compound.
COOR
CH = CH
I
CH
Br N02 II
C
Me-NH
. is( 1.
0
; - CH = CH
s~
"o
MH
I
16. Total number of stereocentre?
oa
Et
17. The compounds in which enol form is more stable than keto form.
0 0
0
(I)
6
(2)
6a(3) (4)
0
(5)
0
00
A A OEt
(6)
00
AA
(7)
0 0 0 0 0
~ ~
II
0 2N - CH2 - C - Me
Ph
0 (8) (9) (10) ( 11)
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Isomerism 107
0 0 0
Ph ~
~ 0
otf° HNC
(12) (13) (1 4 ) (15)

18. Total no. of chiral centre+ Total no. of stereoisomer possible for twistane?

19.
(A)
Match the Column-I with Column-II :
Column-I
(p) 2
Column-II
•
0
II
MeO -P
~
OMe
(B) NH2 (q) 4
~0
MeO-x~k _JV
OMe
(C) (r) 6
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108 ===================== CHEMISTRY
(D) OH (s) 8
c;6 0
Column-I Column-II C olumn-II
(A) (p) P OS (w) 2
0
(
(B) ( q) Optically active (x) 8
Cl
(C) (r) Show geom etrical isomerism (y) 6
11
~
(D) 0 (s) cos (z) Zero
00 0

Passage-I •
Optical activity is arises in compound due to absence of symmetry. So to check if compound is
optically active or optically inactive, one must check three type of symmetry.
( 1) POS (2) COS (3) AAOS (Alternative Axis of Symmetry)
If all are ab sent then compound is optically active otherwise inactive.
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Isomerism ========================= 109
H Cl
2 1.
Cl H
(a) It is optically inactive due to POS (b) It is optically inactive due to COS
(c) Itisoptically inactive due toAAOS (d) All (a), (b)and(c)
22 Which of the following compound are optically inactive?
0
//
(a)
Me
(c) oo (d)oo
Passage-II
Me
NH
Cyclohexane exist in many conformations at room temperature by flipping process with frequency of
10 8 per second. Considering this, answer the following questions.
23. Number of carbon in one plne in half chair form?
(a) 2 (b) 3 (c) 4 (d) 5
24. cis-1 ,4-ditertbutyl cyclohexane exist in which conformation?
(a) Chair (b) Boat (c) Twisted Boat (d) Half Chair
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Hydrocarbons and
Halogen Containing
Compounds

1. Which of the following are syn addition
(a) ~
BH3 / THF
(b) ~
BH3 / THF
•
NH2CI X2
Hg(OAc)i I H2O
(1 )9-BBN / O
J
(c) ~ (d) ~ )
NaBH4
2. In which of the following reaction rate of SN2 will be greater than>-- Br
(a) CH 3 -Br (b) ~ Br
(c) & sr
3. In which reaction C = C is more reactive than C = C ?
(a) Towards dil. H 2 SO4
(b) In ozonolysis
(c) In catalytic hydrogenation
HCI
(d) HC=C - CH =CH z --➔
4. Which of the following will undergo in Ring Expansion?
(a) l (b)
R OH
(c)
HOA NH2
(d)
o;
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116 CHEMISTRY
~
5. HCl / t:-.
I mol.
possible products
(a)
~Cl Cl
(b)
¢Cl
(c)
Qc1 (d)
6
X
2HX I .
6. CH 3 - C= CH CH3 - C - CH3 1s true for
I
X
(a) X = F (b) X = Cl (c) X = Br (d) X = I
7. In w hich of the follow ing the rate of SN 1 and SN2 follows the same order ?
(b) /'-... > /'-...

(a) ~ B r > C r ' B r MeO Cl Cl
0
(c) ~ CI > ~ Cl (d) ~ Cl > ~ Cl
8. Which will be anti elimination?
(a)
H
Cl-+-H
Me
----t--
Br
Me
Zn / dust
,t,;.
(b)
Hi=!
H
CH 3
I
Self
~
/";.
(d) All
Br
9. - c=c"""124- ~ ) (P)
( I eq.)
Correct statements about product?
Br Br
(a) Pis ~
Br
(b) Pis
Br
~
( c) Alkene w ill be cis (d) Alkene w ill be trans.
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Hydrocarbons & Halogen Containing Compounds 117
10. Which will give more than 3 products on chlorination?

(a) /'-.../ (b) ~
(c) □ (d)
11.
0 Cl2
hv
Total number of products on trichlorination?

•
Cl2
12.
hv
What will be the% of major product?

13. Total number of products :
Br2 : CH2
(a)
Y" hv > (P) (b) '=I .
Smglet
) (Q)
~
: CH2
~
: CH2
(c) (R) (d) (S)
Singlet Triplet
: CH2
~
(e) (T) (f) ~ B , Cone. NaOH (U)
Triplet 35°c
(P) + (Q) + (R) + (S) + (T) + (U) = ?

14. Which of the following can reduce non-terminal C = C?
H 2 / Ni H 2 / Pt - O 2 H2 /[(Ph3P))RhCl]
(1) (2) (3)
H 2 / Pd-BaSO4 Na / liq. NH 3
(4) (6)
Zn / HCl LAH SBH BH3 / THF with CH3 COOH

(7) (8) (9) (IO)
Br
15.
OC Cl
What will be the D.U. of P?
D.E.
Na
p
16. Which of the following reactions will produce racemic mixture?

Me Me Me H
(a) ~ HBr (b) ~ H2/ Ni
CH3 H
~ -,,~ BH3 / THF HBr
(c) ~
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118 CHEMISTRY
Me H
(e)
~ 0
CH3 OH 8
Traces
(f)
0 Br2 / CCl4
(g)
00 OH
Br2 / CCl4
(h)
co Br2
CC I )
4
(i)
Q
CH3
1/
H
li
!!,.
(j) @r'
0
Br 2
hv
)
(k)
0
)l__,,,
(m) Sucrose
KCN
H30EB
6
(1)
LAH
17. Total number of a -H present in the product?
((' EtO8 NaEB

EtOH, !!,.
(P) ;
OH H
!!,.
+
(Q)
No. of a-Hin (P) + No. of a -H in (Q) = ?

Cl
18. @2mol
+ Cl3C - CHO Cone. H 2SO4
!!,. (P)
Number ofD.U. in P will be?
o... ■ Match the Following

D ··•
Column-I Column-II
•
(A)
@-cH 2 - ?H - CH3
(p) Hoffmann elimination
F
OH 8
!!,.
~
(B) !!,. ., (q) Sytzeff elimination
0 - C - SMe
II
s
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(C) (r) Syn elimination
(5-+◊K+ /';. .
(D) Cl (s) Anti elimination
20.
tY ale. KOH.
Match the columns :

/';.
,
Column-I Column-II
(A) (p) Meso
6 HCI
~
M.
aJ0f
er
(B) (q) Racemic mixture
Cold KMnO 4 ;
(C) Et (r) Diastereomers
Cf,,,
u
HCI
~ Major
(D) (s) Carbocation Intermediate

Hg(OAc), i H,O , .
NaBH4 MaJor
(t) Optically inactive
rc:nr an BH, ,s
Passage-I
e(octrnpluhc spec;e, wh;cohOha
•
ve only 6e- and solvated by a solvent THF
H 3B
It is a syn addition reaction that takes place with alkene and alkyne. Answer the following questions.
2 1. During mechanism which of the intermediates is/are not obtained during this reaction?
>=
BH3 / THF
';n
H OH
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120 CHEMISTRY
0 - 0 - ----<
I
(b) _,,,,.B......_
;:0 - 0 0 - 0~
22. Which of the following can be used to convert this reactant into product?
0
? II
CH 3 - C =CH ~ CH 3 - CH 2 - CH
(a) BH3 / THF; H 2 O 2 / OH(-)
(b) Sia 2 BH / THF; H 2 O 2 / OH(-)
(c) 9 - BBN / THF; H 2 O 2 / 0H(-)

0
z+ $ II
(d) Hg (0 -C-CF3 )z / H 2 O;NaBH4
Passage-II
Conjugated diene (4nrre-) reacts with unsaturated (2rre-) in presence of heat to produce six membered
ring. It is called Diels-Alder (4 + 2) addition.
For this conjugated <lien should be in cisiod form:
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(a) (b)
CN
(d) None of these
24. Which of the following can show Diels Alder reaction?
(a) ~ (b) Q
I
(c) 0 (d) ~ ~
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13. 14. 15.
16. 17. 18.
19. IAI 1
8 1 lcl lnl
21. ~®@@ 22. ~®@@ 23. ~@Cs)@
24. ~®@@
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Alcohol, Phenols,
Ether, Aldehyde &
Ketones
1. W hich of the following can not show Aldol condensation (self)? •
6
CHO
0
(a) ~ (b) >- C HO (c) (d) @:(

CHO
2. Which of the following can show +ve iodoform test?
(a)
OH
'8'
~ OH
(b) 06
II
Ph-CH 2 -C-CH 3 (c)
0
3. Which of the following can show cannizaro reaction?
$
CHO
(a) (b) >- CHO (c) c1,c-CHO (d)

D/
0
II
C
"-n
/ N "-.
4. Which of the following reaction will produce Ph - CHO as a product?
(b) @J HCl+CO
(1) S02Cl2 (2 eq)

(d) Ph-CH 2 -OH Mno2
(2) H3dB
H
CHO
5.
6 ~ r,
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128 CHEMISTRY
OH
0
Which of the following options are correct?

0
(a) Migration of antigroup takes place so ring contraction takes place.
(b) The migration aptitude in pinnacol-pinnacolon rearrangement.
H > Ar > 3° > 2° > 1° > CH 3
(c) Ring expension is also known as 1, 2 bond shift.
(d) R.D.S. is shifting of carbocation.
6. Which of the following will produce phenol or substituted phenol?
(,)@ Fe2+
(b)@r) ~
Li
0
II
0 - C- R
(c)@ ~
HBr
Cone.
7. Which of the following compound will give aromatic compound as a product?

0 0
(a) ~ P2i 5 (b) ~ P2S5
Li
0 0 0 0
(c) ~ ~
3
(d) A Cone. H2S04
Li
0
8. Identify the reactions in which correct product is mentioned?
0 0 OH
(a) 0-~-~-0 _K_

O_
H /_Li.,.
~
'Z._
0
_)>--6I e +
COO K
(b) Go~CHO _alc_,.K_':,. CN➔ Go cH-c-0

OH
OH o I
0
11
(c)@ 0
=O==O= --
0
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Alcohol, Phenol, Ether, Aldehyde & Ketones 129
0 0
II
(d) Ph -CH= CH - C-CH =CH-Ph + CH 2 (COOEt)i
Phf)Ph
EtOOC COOEt
9. Identify the intermediate products during the entire course of following reactions.
OH
0 =Q 0
( I) CH3MgBr
(2) Hp
(3) OH
6
/ti
isl
(,) D
OH OH 0
0
0
(b) X
AAo (d) 6 0
A Br2
oT-f3 ) (P) + (Q)
I Br2
CH COOH) (R)
3
Correct options is/are?
0 0
(a) (P) = Ao0 (b) (Q) = CHBr3 (c) (R) =~ (d) None of these
Br
11. Number of moles ofCH4 obtained when 1 mol of the given compound reacts with excess ofCH 3MgBr.
SH OH
•
OH
CN OH
12. Which will give +ve Br2 I H 2 0 test? Calculate the number of compounds.
~ CH3 -CeCH O @ 6 D
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130 CHEMISTRY
0
0 0
13.
CH 3 - CHO HCHO
A Glucose
Degree ofunsaturation of the product + No. ofN atom in the product will be equal to?
Fructose
NH3+HCHO p
14. Number of six membered rings in the product?

0
0
Ph Ph
Glycerol
H
(±)
p
_x_CH_I)➔
15.
CX O:rsrO....,__Ph
0
The value of x = ?
0
/ Et
16. Number of compounds which can not show +ve Iodoform test?
HCHO, Me - CHO, Et - CHO, Et - OH, Cl3C - CHO, Me - COOH, Me - COCl, ipr-1, Et-I
OH O O O O O 0
~ , Ph -CH 2 -LCH,,)l,__)l___,AoA, Me-~-COOH,
OH
17. Number of compound which can give the Tollen's Test.
OH
Ph/ n
.,,l_ _,, , CH3
0
Glucose Fructose Ph- NH-OH HCOOH
0
18.
CH 3 - CHO HCHO
Number of compounds that can be oxidised by HIO4 .

~ QOCH 3
~
OH
OH
AA
OH OH
+uu 0
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Alcohol, Phenol, Ether, Aldehyde & Ketones 13 1
OH OH
~K KOH
OH OH HO OH HO ~H
~ NH 2
~ OH
U oH
g-----: Match the Following

OH
•
OH
Column-I (Reagent) Column-II (Product)
(A) Cu I 300°C (p) OH
(B) (q)
~0
OH
COOH
H$ / KMnO 4 / 25°C
(C)
A0
(r)
n CHO OH
~
(i-pro) 3Al /
0 CHO
(D) (s) OH
~
C,03 / @ / HCI
N
O OH
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132 ===================== CHEMISTRY

Column-I Column-II
(A) 0 (p) Formation of six m embered ring takes place.
(B)
60
HCN
traces of KOH
A
LAH
B
NaN02
HCI
C
Find product is ketone or a, ~ unsaturated ketone

(q)
(C)
6 NH20H
A ~B
HGl
(r) Final product w ill give +ve Tollen's Test.

0 0
II II OH-
CH3 -C-CH2 -CH2 -CH2-C-H /}.
A
(D ) (s) Final product w ill give +ve 2, 4 DNP Test.
~
HGl
CH3 ~ A
OH OH
(t) Ring expansion takes place.

Passage-I
A+B CHCl3 (D) [E] + [F]

•
I NaOH
i'FeCI3
[CJ
[A] ----+ + ve Victor Mayer Test (Red)
I J>
.___ _Li_ _ _
) W (maj or)
2 1. W is
(a) CH 3 - CHO (b) HC = CH (c)

CHO
I
CHO
(d) C)
22. [E] and [F] are
(a) Geom etrical Isomers (b) Optical Isomers
( c) Functional Isomers (d) Positional Isomers
Passage-II
Dehydration of alcohol using cone. H 2 S0 it...
m ay follow E I or E 2 mechanism depending on degree of
alcohol. Ethanol will form ethene on treatment of cone. H2 S04 using E 2 where HSo4- 1 act as a base.
Regarding the concept of dehydration answer the following questions.
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Alcohol, Phenol, Ether, Aldehyde & Ketones 133
23. Which do not represent correct product?
~ ~
OH
(a) ( O) (b) ( OH Conc. H3P04
C0
Cone. HiS04
HO O OH
OH OH
LoNoH
Ph Ph
N,NO, (dl T:o, ~

HCI ~ ~
24. The case where rate of dehydration of first is greater than second
0 0
V OH
g
~ OH
LI (b) A A
U oH Y
(a)
OH
OH
QA
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8 1 lcl lnl
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24. ~®@@
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Carboxylic Acids & its
Derivatives and Nitrogen
Containing Compounds

1. Which of the following will undergo in decarboxylation on heating. •
(a) (§1 N COOH
(b)
~
COOH
N0 2
(c) ~ COOH (d)

0 COOH
0
2. Consider the following reaction:
II. Benzonitrile (1) LAH B

(2) MeCI/NaOH ( )
III.
ex OH
OH
+ HI (excess) ~
(l)AgN02
<±>
(2) Fe / H
(C)
Out of A, B, C and D the product(s) which can show hoffmann mustard oil test is/are
(a) B and D (b) Only D
(c) A, B and D (d) Only C
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142 ===================== CHEMISTRY
3. Which of the following can lead to fomiation of carboxylic acid?

Cl
(a) /4c-t~
NH
(I ) NaOI-1
(2) I-ICI ) (b) 0 hot
(d) ~
4. Which of the following are correct?
(a) Rate of esterification for alcohol CH 3 - OH > 1° > 2° > 3°
(b) rate of esterification for carboxylic acid CH 3 - COOH > 1° > 2° > 3°
(d) R-COOH > R-COCI
0
11 1s
5. R- C-OH+ R '-OH cone. H2S04 >
6
Products obtained
0 0
II 11 18
(a) R -C- O - R' (b) R -C- O- R'
18 18
0 0
II 11 18
(c) R -C- O - R' (d) R -C- O- R'
0
II 18 H EB
6. Me 3 C-C- OH + Me - OH--➔
0 0
11 18 II
(a) Me 3 C-C- O - Me (b) Me 3C-C- O - Me
(d) Me C- O - Me
7. Which of the following ester can show Claisen condensation?
0 0
(a)
)-
II
C- OEt (b)
+ II
C- OEt (c)
~ OEt
II
0
(d) Me-COOEt
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Carboxylic Acids & its Derivatives & NCMP 143
8. Which of the following reactions are correct?
(a) n OAc
OAc
_ t,_
0
II 0
C-0-Me
~QPh
(b) lSJ
0
~II
~ C-Me
( !)Na .,,,,....__ .,,,,

(d) ~ ----~✓
(2) CS2
~
OH (3) Me-I
(4) t,
9. Consider the following reaction : A
The starting substance 'A' can be :

OH
(a)
$ (b) $NH2
NH2
OH
(c)
$CH 3
(d) $OH
0
II LAH
10. CH3 - C - NH2 (I mo!)
X
I LiAID4
) y
(a) X = CH3 - CH = NH (b) X=CH3 -CH=O
(c) Y = CH3 - CO 2 - NH2 (d) Y=CH3 -CH2 -N
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144 CHEMISTRY
11. Number of compound which on decarboxylation produces racemic mixture.
Me
•
HOOC - + - COOH
H -----t-- CH 3
Me
P OOH
COOH
Me
A
HOOC ~ COOH --
t:..--+
H Me Me
P OOH
COOH
A
a COOH
Me Me COOH
o:
0
COOH II
F3C - C - CH2 - COOH
(±)
COOH
I t:.. )
t:..
12. Identify number of reaction in which amine ( 1°) will be formed.

0 0
II LAH II ./ LAH
(a) ............... NH2 -- (b) ............... NH,,,
0
II ./ LAH LAH )
(c) ............... N ,, (d) @ - N02
" N02
(e) 0- N02 LAH (f) @ H/ Pt

)
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(g)
i NO
0
2
(h)
H '-..
CH /
3
0
NaBH3CN
C = NH - - - -
II II ( l ) PCI5
(i) R -C-NH2 (j) R- C - NH - OH - - - +
(2) 01.f / ~
(3) H$
0
CH3CI II ( I) NH3
(k) NH3 excess (1) R- C- CI
(2) LAH
~ HO© 3
(m ) ~ (N-R- -
0
13. Total number of compound more basic than aniline.
cS- ( I)
c$)_
(2)
$$ (3)
OCH3
(4)
-.........✓
N
~
(5)
CH,
@ (6)
e s r - CONH 2
(7)
$ C- H
II cS-NH 2
cS-O
H
0
(8) (9) ( 10)
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146 CHEMISTRY
l ~
Ph - - Ph
r&C
N
( 11 )
Cl
(12)
@( 13)
NH
NH2/
II
C
( 15)
'-... NH2
c5 (16)
~ NH2
(17) ( 18) ( 19) (20)
14. Number of carboxylic acid that are more acidic than Ph-COOH.
COOH
COOH COOH
@rN0 2
®-NO, $
( I) (2)
COOH
COOH
@rCH, @rNH COOH
$ CH3
(6)
2
(4) (5)
COOH COOH COOH
®-NH, ®-OH ®-OH

(6) (7) (8)
3
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COOH COOH
$ $
COOH
(9)
S03H
( 10)
COOH
I
COOH
( 11 )
HCOOH
( 12)
( COOH COOH
Me -COOH
COOH HOOC f
( 13) ( 14) ( 15)
15. r\.._L
~0-S
-
II
Me
0
II
-<>-
! O-S-0----r-U
II Me -
0
II ___f__r\
0 H20/Warrn 0
(P)
Total number of product obtained in above reaction.
16. How many of the following amines will undergo diazotisation.
tert - butylamine, Ethanamine, Aniline, N - methylaniline,

(I) (II) (ID) (IV)
p - toluidine, m- chloroaniline,
(V) (VI)
2 - phenylethanamine, 0 - Anisidene, 2, 4, 6 - tribromoaniline

(VII) (YID) (IX)
17. What is the number of isomer with pyridine nucleus possible for compound having M.F. = C 7 H9 N?
0
1. Br2 (1 mol)/CCl4 1. CHr I (excess)
18. A----- B
2. (CH3)iNH 2. AgOH / I'!. (major)
(excess)
Number of delocalised electrons in B will be?
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148 CHEMISTRY

19. Match the columns:
Column-I (Reaction) Column-II (Product)
•
6P (p) Product contains ketonic group
{A) 0
dil. H,S0 4 _
/',.
-
(B) 0 (q) Product contains CONH2 group
(C)
6 (!) KCN / H2 S0 4
(2) H20 2 I OI-1
0
6
(r) Product contains COOH group

H 30 +
NC+=(CN CN
/',.
(D) NH2 0H (s) Product contains OH group
II
HONO.
/',.
20. Maleh lhe columns :

Column-I Column-II
(A) (B - (p) Sodium fusion extract of compound gives prussian
NH2 - NH3 Cl blue colour with FeSO4
(B) (B (q) Sodium fusion extract of compound gives blood

3 red colour FeS04
~ NH
8
s03
(C) (B e (r) White ppt. with AgN03

~ NH,cJ
OH
(D)
¢7~~2 (B )3 (s) In basic medium reaction with aldehyde followed

by acidification gives corresponding hydrazone.
N02
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0 -~-~-H
0 0
Passage-I
(1) 0: P,
LiAIH4
•
0 (2) H
I- - - - ~ ) P3
RedP + HI
2 1. P 1 is
(a)
0~
~
OH 0
(b) O - t H- ~- H
0
OH
(c) O - bH -COOH
0
0
(d) O - ~- COOH
0
22.
(a) reduce tollen's reagent

(b) show cannizaro reaction
(c) can release CO 2 with NaHC0 3
(d) can react with NaHS0 3
Passage-II
0
0 0
+ B, 2 + KOH ~ P, + P2
(1) H Ell AIC13

Pz --~---➔ P3
(2) NaOH I Cao It:,. HCI
If P 1 contains ' Br ' then.
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150 CHEMISTRY
+ COOH
Sequence of reagent required for this transformation is

6
(a) PC15 , KCN, H 2 0
(b) H 6 / d , HBr, KCN, H 30 +
(c) SOC12 , Mg / ether, CO 2 , H 3 0 +

( d) PCC, KMnO 4
(1) H IB
24 P.2
· (2) CaO / Li
r----f'o
(b) L_j
(d) L
RESPONSE SHEET
1. Ci)@@@ 2. Ci)@@@ 3. Ci)@@@
4. Ci)@@@ 5. Ci)@@@ 6. Ci)@@@
7. Ci)@@@ 8. Ci)@@@ 9. Ci)@@@
10. Ci)@@@ 11. 12.
13. 14. 15.
16. 17. 18.
19. IAI 1
8 1 lcl lnl
21. Ci)@@@ 22. Ci)@@@ 23. Ci)@@@
24. Ci)@@@
rwww.JEEBOOKS.1Nl
Bio111olecules and
Poly111ers

1. Which of the following structure is methyl a -D-galactopyranoside?
CHO
•
H
HO
HO
H
OH
(a) OMe (b)

HO OMe
HOH
OH
(c) H (d) HO
HO OMe
2. Which of the following are reducing sugars?
(a) Fructose (b) Sucrose
(c) Maltose (d) Lactose
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158 ===================== CHEMISTRY
3. Which of the following carbohydrate are D-isomers
OH OMe
(a) H
O OH
H~+~H
COOH CHpMe
(d) M e O ~ Q OH
(c)
MeO~
COOH OMe
4. Salicin (structure given below) is a glucoside, found in the base of willow tree, used in relieving pain.
Observe the following reaction of Salicin :
dil. HC I
P+ Q
..__.,
Products
(P) is carbohydrate. The correct statcmcnt/s is (arc)
(a) Pis D-Glucose
(b) Q is 2-hydroxybenzylalcohol
( c) Q can be converted to a modem analgesic
(d) The above reaction occurs through carbocation intermediate
5. The phenomena ofmutarotation are shown by
(a) Glucose (b) Fructose (c) Lactose (d) Starch
6. Select the correct statement
(a) Although fructose is a ketone but it gives +ve Tollen's test
(b) Invert sugar is leavo rotatory
(c) ~-D-(+) Glucopyranose is more stable than a-D-(+) glucopyranose
(d) Starch contains a-link and cellulose contains ~-link.
7. Which of the following tests are shown by Glucose
(a) 2, 4-DNP (b) Schiff Test (c) NaHS0 3 (d) Tollen's
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Biomolecules & Polymers 159
8. The gycosidic linkage involved in linking glucose units in amylopectin part of starch is
9. Identify the primary as well as optically active amino acid
(a) Glycine (b) Serine (c) Argenine (d) Proline
10. Which of the following is/are correct for this sugar?
OH OH
(a) It is pentose (b) It is pentulose (c) It is a a-anomer (d) It is a pyranose
11. (a) Number of stereocentre in linear glucose = x
(b) Number of stereocentre in cyclic glucose = y

•
(c) DNA and RNA differ in pentose sugar structure at carbon= z.
x+y + z= ?
12. In a mixture of equilibrium of a, ~ and open chain. %a = 36%, %~ = 63.98% and % of open chain
= 0.02%. If 20% ~ form is taken then after some time what is the% of a form?
OH
13. Glucose
@@
-----+P
10%
D.U. ofP?
14. N inhydrin reagent react with a -amino acids to give purple colour. In the reaction of Ninhydrin with
phenyl alanine, number of C present in the product?
15. Amongst the following the total number of biodegradable polymer are :
Nylon 6, 6 PHBV Cellulose Glyptal
Dextron Nylon-2-Nylon-6 Nylon 6 PAN

Bakelite Melam ac Polystyrene PVC
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160 ===================== CHEMISTRY
16. In Lobry-Debruenvan ekenstein rearrangement, the number of compound in equilibrium are?
17. How many of the following vitamins are water soluble?
(i) Vitamin A (ii) Vitamin B
(iii) Vitamin C (iv) Vitamin D
(v) Vitamin B 6 (vi) Vitamin E
(vii) Vitamin B 12 (viii) Vitamin K
(ix) Vitamin B 2
18. Number of compound which can form silver mirror on reaction with Ag+, NH 3 ?
CH OH
HO~oyNH-0-Me HO
(;J >--Z ~ (ii) HO 0~
HO
OH OH OH
OH OH
(iv) H O K
OH
OH
OH
CH 20 H
CH20H
0 I\
(v) o'V::>fHzOH (vi) 0 0
OH
pOH
'-.../
CHz- o
(vii) ~-o_J (viii) Maltose

HO~OH
OH
(ix) Galactose (x) Fructofuranose
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Biomolecules & Polymers 16 1
19. A tetrapeptide has - COOH group on alanine. This produces glycine (Gly), Valine (Val), Phenyl
alanine (Phe) and alanine (Ala), on complete hydrolysis. For this tetrapeptide, the number of possible
sequence (primary) structure are?
20. Number of chiral centre present in nucleoside of DNA?
g-.. .:
2 1.
Match the Following
Match the columns :

•
Column-I (Component of mix) Column-II (Reagent)
(A) Crystalline Na2 CO 3 + Sodium citrate + CuSO4 (aq. sol.) (p) Fehling Solution
(B) CuSO4+ Rochelle Salt + NaOH (q) Nesseler's reagent
(C) 10% a -naphthol in alcohol (r) Bennedict's solution
(D) HgI 2 + KI + KOH (s) Molisch's reagent
Column-I (Functional Group) Column-II (Test used or complex formed during

confirmatory test)
(A) R- CHO (p) Neutral FeC13
(B) Phenolic (q) Cu 2+ + Sodium potassium tartrate
(C) Alcohol
R--CH(OH}---OSONH--®'
(r)
R-CH(OH)- OSONH--(Q)/
C
0 -
NH
(Violet Red)
(D) a -D-Glucopyranose (s) (ROH) 2 Ce(NO3) 4 {Red}
(t) Molisch's Test
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162 CHEMISTRY
Passage-I
•
(I) NH20H
P2
(2) HEB / t:,.
+
(2) H /t:,.
(3) Rh/t:,.
(4) H 2SO/ t:,. Polymerisation
P3_ _ _ ___.
(S)NaOH
(6) NaOH (fuse)
+
(7) H
23. Select correct statement(s)
H+
(a) P4 + HCHO--->Novalac
H+
(b) P4 +HCHO--->Bakelite
(c) P4 + HOoc - - @ - cooH ~ Terylene
H2NY NY NH2
(d) P4 + ~ N --+ Melami ne polymer
NH2
24. Select correct statement(s) about P5 .
(1) Zn / t:,.
P4 - - - - - - - P s
(2) 03 / H20 / Zn / t:,.
(3) NaBH4 / THF
(a) It can produce terylene with terephthalic acid
(b) It can produce acetaldehyde on heating with H 2 S0 4 .
OH
I
(c) P5 +CH3 - CH-CH2 -CHOH Polymerisation PHBV
(d) None of these
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Biomolecules & Polymers 163
Passage-II
An a -amino acid 'A' has molecular formula C 3H 7N0 3 . ' A' on treatment with methanol in presence
ofHCl yields 'B ' [C 4 H 10N03 Cl]. 'B ' on further treatment with PC15 yield 'C' [C4 H 9N02 Cl]. Which
on acidic hydrolysis yields ' D ' [C3 H 6N02 Cl]. ' D ' on reduction with Na(Hg) in dilute acidic medium
yields alanine.
25. Compound 'A ' has how many functional group?
(a) 1 (b) 2 (c) 3 (d) 4
26. Compound ' D ' is
NH2 0 0
I II II
(a) H- C- C- CI (b) CH - CH -NH- C - CI
I 2 2
I
CH 0H OH
2
NH2
(c) H-
I COOH
C- (d) (a) and (b) both are possible.
I
CH CI2
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
Hydrogen and
s-Block

1. Which of the order are correct?
(a) Li2 C0 3 > Na2 C03 > K 2 C0 3 > .... (Solubility)
•
(b) LiCl > NaCl > KCl > RbCl > CsCl (Solubility)
(c) BeF2 < MgF2 < CaF2 < SrF2 < BaF2 (Solubility)
(d) BeC2 0 4 > MgC2 0 4 > CaC2 0 4 > BaC2 0 4 > SrC 20 4 (Solubility)
2. Which of the statements are correct?
(a) L H - 0 - 0 - His greater in gas phase than solid phase.
(b) H 2 0 2 is more acidic than H 2 0.
(c) H 2 0 2 forms more H.B. than H 2 0 but all hydrogen bonds are weaker as compared to H 2 0.
OH 0
0 2 (air)
(d)
H2
OH
3. Which of the following statements are correct?
(a) Li < K < Na < Rb < Cs (Density)
(b) LiOH < NaOH < KOH < RbOH < CsOH (Basic strength)
(c) LiCl < NaCl < KCl < RbCl < CsCl (Melting point)
(d) K0 2 is used in purification of air
4. Which of the order are correct?
(a) Cs < Rb < K < Na < Li (Reactivity with hydrogen)
(b) LiCl < LiBr < Lil (Covalent nature)
( c) BeC12 > MgC12 > CaC12 > SrC12 > BaC12 (Ionic character)
(d) Cal2 < CaBr2 < CaC12 < CaF2 (Melting point)
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168 CHEMISTRY
5. Both Na and Li are placed in air (dry), we can get
(a) Na2 O (b) Li3 N
(d) NaOH
6. In Castner-Kellner cell, which of the following statements are true?
(a) At cathode Na combines with Hg even H 2 O has more tendency.
(b) The formation of Na-Hg amalgam provided stability and also over voltage for H 2 is high with Hg
cathode are main reason.
(c) Na-Hg+H2 O~NaOH+ Hg +H2 i
(recycled)
(d) Brine solution is taken; mercury as anode and carbon as cathode.

7. Select the correct statement.
(a) In NaHCO3 , HCO3- l forms chain like
0
II o+ o+_... oe........_c_......o........_H
e _.. . . c . . . . _ _......H-.... e _......H···
.. o o ··o.. . . ._ _......o 11
✓ C O
II
0
(b) InKHCO 3 , HCO 3- 1 forms dimer
8
o
O=C /
0 •·•••· H -
' C=O
"-o-H······O/
e
(c) Solvay process can not be employed for the preparation of KHCO 3 because it is difficult to
separate due to more solubility.
(d) LiHCO3 exist in solid state.
8. Which of the following reaction give 0 2 as product?
(a) Na 2 O 2 + H 2 O ~ (b) Na 2 0 2 +H2 0 ~

Cold Wann
9. The statement regarding Solvay process are correct.

(a) Raw materials : CaCO 3 + NH3 + NaOH
(b) By products: CaO + NH 4 Cl
(c) Na2 CO3 ·lOH 2 O is formed.
350K
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Hydrogen & s-Block Elements 169
10. Statement which are incorrect regarding Be?

(a) Be has low tendency to form complex.
(b) BeC12 is covalent.
(c) Be2 C+H 2 0~Be(OH)z +CH 4
(d) Be(OH)2 is soluble due to high hydration energy ofBe2 +.
11.
12.
The total number of neutrons present in D 2 0 17
molecule (hypothetical) are?
•
The hydrogen when combined with Halogen form Hydrogen halides. IfpKa of HF, HCl, HBr and HI
arex 1,x2 ,x3 ,x4 then x 12 -x2 +x3 -x4 =?
13. As like alkane, Si also form compounds with hydrogen.
SiCl 4 +NaH~SiH4 +NaCl
l Polymerise
Si XHy
If x is the maximum value, then x + y = ?

pyrolysis
14. NCNC(NH 2 )z P . Number of lone pairs present in compound P.
15. In [Bei0H)8]2-, the number of OH molecules acting as bridge.
16. LiCl+H 2 0~LiCl-xH 2 0; What is the maximum value ofx?
17. The number of moieties available for H-bonding in one molecule ofR-S0 3H.
18. Number of boiling point order which are represented correctly
(i) H 2 0 > H 2Te > H 2 Se > H 2 S
(ii) HF > HI > HBr > HCl

(iii) SnH4 > GeH4 > SiH4 > CH4
(iv) NH 3 > SbH3 > AsH3 > PH3

19. Tritium undergoes in ~-emission decay.
3T f3-emission X
I
What is the atomic no. + Mass no. of X = ?
20. What is the maximum C.N. ofBe+2?
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17 0 CHEMIST RY

2 1. Match the order of compound with property.
Column-I Column-II
•
(A) Li > Na > K > Rb > Cs (p) Melting point
(B) H2 < D2 < T2 (q) Boiling point
(C) H2O > H 2Te > H 2Se (r) Latent heat of vaporisation
(D) o-H2 > p -H 2 (s) Spin isomer
22.
Column-I Column-II
(A) /',. (p) One of the product has sp2 hybridisation central
Na2 SO4 +C+CaCO3 ~
atom
(B) /',. (q) One of the product is neutral oxide

NaCl + NH4HCO3 ~
(C) KOH+NO (r) One of the product has sp3 hybridisation of central
2 4 atom
(D) Na 2 CO3 +Ca(OH)i (s) One of the product is insoluble as precipitate.

Passage-I •
Boiling point (°C), melting point (°C) and enthalpies of vaporization ofhydrides depends on m olecular
weight as well as hydrogen bonding.
23. Select the correct graph?
(a) (b)
B.Pt.
B.Pt.
Period
Period
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Hydrogen & s-Block Elements 171
vm
(c) (d)
B.Pt. B .Pt.
Br
HCI
Period Period
24. The correct indicated orders are
(a) M.Pt.
H2Te
ttiS
Period
(b) ~H,,.p,
H 2Te
ttiS
Period
(c) ~Hvap.
Period
(d) M.Pt.
Period
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172 CHEMISTRY
Passage-II
Hydrogen peroxide is an important chemical used in pollution control treatment of domestic and
industrial effluents.
25. Which of the following incorrect regarding H 2 0 2 ?
(a) It is pale blue or almost colourless.
(b) H 20 2 is insoluble in H 20 .
(c) It can be prepared by acidifying barium peroxide and removing excess water.
(d) 2HSO-4 l (1) electrolysis H O
(2)Hydrolysis 2 2
26. Calculate the strength of 20 volume solution of H 2 0 2 .

(a) 1.5% (b) 3%
(c) 6% (d) 20%
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
p-Block
Elements

•
then the correct statement about above equations :
(a) The geometry ofB- and o- are same.
(b) The geometry of A+ and c+ are same.
( c) The geometry of A+ and o- are same.
( d) The geometry of c + and B- are same.
2. Which of the following oxidising agent can oxide P-- to F2 ?
(a) KMnO4 (b) MnO2
(c) K2 Cr 2 O 7 (d) H 4 XeO6
3. Which of the following compound give H 2 S on reaction with cone. H 2 SO4 ?
(a) Zn and Hg (b) Mg and Zn
(d) Ag and C
4. Which of the following are correct regarding B2 H 6?
(a) 11 < 12 (b) 01 > 02
(c) 11 > 12 (d) 01 < 02
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178 CHEMISTRY
5. Which of the following statements are incorrect?
(a) In 0 2F 2 , the O - 0 bond is shorter than O - 0 bond in H 20 2
(b) H 20 2 and 0 2F 2 have similar structures, hence the 0- 0 bond of the two molecules are identical
(c) In 0 2F 2, the O - 0 bond is longer than O - 0 bond in H 20 2
( d) 0 2F 2 does not contains the peroxide bond (- 0 - 0 -)
6. The hybridization of central atom nitrogen in azide ion is same as that of
(a) N 20
(c) C 6H 6
(a) When BF3 is treated with excess ofNaF in acidic aqueous solution gives NaBF4
(b) When BC13 is treated with excess of NaCl in acidic aqueous solution gives H 3B03
(c) When BBr3 is treated with NH(CH3)i in a hydro-carbon solvent gives B[N(CH3)ih
(d) When B 2H 6 is treated with BeH2 the product formed is Be(BH4) 2
8. Which one of the following arrangements does not give the correct picture of the trends indicated
against it?
(a) F 2 > Cl2 > Br2 > 12 Bond dissociation energy
(b) F 2 > Cl2 > Br2 > 12 Electronegativity
(c) F 2 > Cl2 > Br2 > 12 Oxidising power
( d) F > Cl > Br > I Electron gain enthalpy
9. Hybridisation ofBerylium hydride can be
(a) sp (b) sp2
(c) sp3 (d) sp3d
10. Which of the following are not oxides?
(a) K 20
(c) OF2
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p-Block Elements 179
11.
12.
The numbers of P - 0 present in (HPO3h. •
3.55 g of a bleaching powder when treated with acetic acid and excess of KL Liberated iodine required
30 ml of 0.5 N sodium thiosulphate solution. The percentage of available chlorine in the sample is?
13. Number of Dichloroderivatives of benzene are x and for inorganic benzene are y then x + y = ?
14. Number of oxygen acids formed on hydrolysis of P 4 0 10?
15. Number of oxygen atom shared with other unit in cyclic silicate having general formula (SiO 3- 2 )n.
16. Number of S - 0 - S bonds in H 2 S2 O4 ?
17. Which of the following reactions will give NH 3 on heating?
Li Li
(i) NH 4 NO3 ~ (ii) N H 4 NO 2 ~
Li Li
(iii) NH 4 IO 3 ~ (iv) N H 4 ClO4 ~
Li Li
(v) (NH4 )zCr2 O 7 ~ (vi) (NH4 )3PO4 ~
(vii) NH 4 Cl ~ (viii) NH 4 B r ~
Li
(ix) (NH 4 )z CO3 ~ (x) (NH 4 )zSO4 ~
18. Which of the following compound will undergo dimerisation?
19. How many of the following can undergo disproportionation?
Zn Pb
s
ZnO XeF 6
BeO BN AlN
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180 ===================== CHEMIST RY
20. Which of the following indicated order are incorrect?
(i) HF > HCl > HBr > HI (Thermodynamic stability)
(ii) HF > HI > HBr > HCl (B.P.)
(iii) HF > HCI > HBr > HI (Volatility)
(iv) HF > HCl > HBr > HI (Bond dissociation energy)
(v) HCl > HF > HBr > HI (Dipole moment)
(vi) HI > HBr > HCl > HF (Acidity)
(vii) HI > HBr > HCl > HF (Reducing power)
g-..:
2 1.
Match the Following
Match the following.
Column-I Column-II
•
(A) H S 0 H 20 (p) dibasic
2 2 8
(B) HO (q) can act as flexi-dentate ligand

SF
(C) H 20 (r) can act as both oxidising and reducing agent

NCl3
(D) H 20 (s) can act as m ono-dentate ligand

NO2
(t) non-redox hydrolysis
22. Match the following.
Column-I Column-II
(A) P + NaOH ➔ PH +H O+ ...... (p) Phosphinic acid

4 3 2
(B) 520K 870K (q) Phosphoric acid

H 3PO4 H4PzO7 ......
(C) PCl3 +HzO ➔ HCI+ ...... (r) Metaphosphoric acid
(D) P4O10 + 2H2O2 + 2H 2O ➔ ..... . (s) Per-mono oxo phosphoric acid
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p- Block Elements 181
Passage-I
Following flow sheet is used to prepare pure Silicon. Answer the questions based on it.
•
co
__
C._l'i_> [ } [ ] t
1Cl2
A
Pure SiCl4
Impurities
Ultr~f ure E C [}0--B_ __.

23. Step A is
(a) Fractional distillation (b) Zone refining
(c) Ultra filteration (d) None of these
24. Step B involves
(a) Thermal decomposition (b) Reduction with H 2
(c) Reduction with Na or Mg (d) Hydrolysis
Passage-II
expose 100°c 220°c

CuSO4 -5H2O A B C
to air
D + E d
(black)
1 T > 800°C
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182 ===================== CHEMISTRY
25. Compound Bis blue in colour. What is compound B?
(a) CuSO4 · 3H 2 O (b) CuSO 4 ·H 2 O
(c) CuSO4 (d) CuO
26. The black coloured compound D and gas E are respectively?
(a) Cu 2 O + SO2 (b) CuO + SO2
(c) CuO + SO 3 (d) Cu 2 O + SO3
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
d&f-Block and
Metallurgy

1. Acidified KMnO4 solution can be decolourised by
(a) white vitriol (b) blue vitriol

•
(c) green vitriol (d) all of these
2. Correct order of melting point in transition element is
(a) W > Mo > Cr (b) Cr > Fe > Mn
(c) Cu > Au > Ag (d) V > Cr > Ti
3. What will be the correct representation of quantum numbers for the last electron entered into Ce?
n l m s n l m s
(a) 4 3 -3 - 1/2 (b) 4 3 0 - 1/2
(c) 4 2 -3 + 1/2 (d) 4 3 +2 -1/2
4. Select the correct statement :
(a) Sm2 +, Eu2 + and Yb2 + are good oxidizing agent.
(b) Zr and Hf show similar properties.
(c) La(OH) 3 is the strongest base than other lanthanum hydroxide.
(d) Magnetic susceptibility values of actinides are greater than lanthanides.
5. The transition metals which do not form amalgams?
(a) Zn (b) Fe
(c) Pt (d) Cd
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188 ===================== CHEMISTRY
6. Metals which can be extracted by smelting process are:
(a) Pb (b) Fe
(c) Zn (d) Al
7. Zn and Ag can be separated from each other by
(a) distillation
(b) heating with cone. NaOH
(c) treating with dil. HNO3
(d) treating with cone. H2 SO4
8. Which of the following statements is/are correct about the making of blue prints?
(a) Ferric oxalate or citrate is reduced to ferrous salt on being exposed to light.
(b) Ferrous salt give blue colour with K 3 [Fe(CN)6 ].
(c) Ferric salt give blue colour with KiFe(CN)6 ].
(d) White lines are obtained in place of the ink drawing on a deep blue background.
9. Which of the following reaction takes place in the reduction zone of blast furnace?
(a) CO 2 +C~2CO
(b) Fe2 O 3 + CO~Fe3 O4 +CO 2
(c) Fe3O 4 +CO~FeO+CO 2
(d) FeO+CO~Fe+CO2
10. Which of the following are correct statements?
(a) Van arkal method is used for Zr, Ti.
(b) Zone refining can be done for Si, B, Ga, In, Ge.
( c) CaO + SiO2 ~ CaSiO3 , in this reaction SiO2 is slag.
( d) In refining of Zn, C is much better reducing agent than CO.
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d & f- Block and Metallurgy 189
11. What is the atomic number of circled element?

•
M.P.
Z Atomic no. (3d)
12. If x 1, x 2 and x 3 are the oxidation state of Fe in haematite, magnetite and Iron pyrites than
13. How many of the following oxides of transition metal are basic in nature?
14. How many of the following oxides are mixed oxides?
15. Number of ore in which Cu is present.
Bauxite Copper glance Cryolite

Casseterite Copper pyrite Chile saltpeter
Colemanite Atacamite
Galena Malachite
Cinnabar Azurite
16. Total number of alloys which contains Al as metal?
Magnelium N ickeloy Solder

Duralumin Dutch metal y-Alloy
Alnico Brass German silver
Bronze
17. Among the following elements, number of elements for which zone refining can be used is
Zr, Ga, Ti, Ge, B, Si
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190 ===================== CHEMISTRY
18. What is oxidation state Cu in copper pyrites?
19. How many Cl atoms are available in cam allite?
20. Number of oxide ores are :
Cuprite, Galena, Cassiterite, Magnetite, Bauxite, Cam allite, Calamin e, Bronze.
g---: Match the Following

2 1. Match the following.
Column-I Column-II
•
(A) Metal extraction from galena (p) Leaching with complexing agent or alkali
(B) Metal extraction from silver (q) Electrolytic reduction/refining
(C) Metal extraction from haematite (r) Carbon reduction process
(D) Metal extraction from bauxite (s) Self reduction process
22. Match the following.
Column-I (Ions) Column-II (Colour)
(A) Sc3+ (p) Green
(B) Ti4+ (q) Red
(C) y3+ (r) Purple
(D) Cr3+ (s) Colourless
(E) Mn3+ (t) Blue
(F) Fe 3+ (u) Yellow
(G) Ti3+ (v) Violet
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d & f- Block and Metallurgy 19 1
(H) Fe2 + (w) Pink
(I) Co2 + (x) White
(J) Ni2 +
(K) Cu 2 +
(L) c u+
(M) Zn2+
Passage-I
•
In the froth flotation process, finely divided ore, water, pine oil and sodium ethyl xanthate are taken
together and air is blown from the bottom at the container. Froth are formed, these froth are collected
into beaker and sep arated.
23. Which of the collector can be used in Froth Flotation method?
(a) Sodium lauryl sulphate (C 12H 25 - 0 - SO3 Na+)
(b) Trimethylcetyl ammonium bromide (C 6H 13N+Me3)Br
(c) Dicresyl dithiophosphate
(d) Mercaptobenzthiazole
24. Which of the statements are correct regarding froth flotation method?
(a) NaCN act as depressant for ZnS.
(b) NaCN act as depressant for PbS.
(c) Surface tension plays major role in formation of bubble.
( d) Reagent such as aniline or cresol are used to stabilize the froth.
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192 CHEMISTRY
Passage-II
IfKOH
B
Mn02 KOH
A I Cold water
little alkali
Green
Solution
On
evaporation
is used
IfNaOH
C
Pyrolusite Green melt is used
25. Compound A is
(b) M noJ- (d) MnOJ-
26. Compound (B) and (C) are?
(d) KMnO 4 & NaMnO4
RESPONSE SHEET
1. (i)@(s)@ 2. (i)@(s)@ 3. (i)@(s)@
4. (i)@(s)@ 5. (i)@(s)@ 6. (i)@(s)@
7. (i)@(s)@ 8. (i)@(s)@ 9. (i)@(s)@
10. (i)@(s)@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

23. (i)@(s)@ 24. (i)@(s)@ 25. (i)@(s)@
26. (i)@(s)@
rwww.JEEBOOKS.1Nl
Co-ordination
Compounds and
Qualitative Analysis

1. Which of the following are correct statements?
(a) NH 2 - NH2 is a bidented chelating ligand.
•
(b) In DMG- 1 both oxygen atom act as donor atom.
(c) Chelation effect is maximum for five and six members rings.
(d) The oxidation state of Fe in [Fe(H 2 0)5 (NO)]S0 4 is + 1.
2. Which of the following statement are correct?
(a) [Ni(CN)5 ] 3- is found to be diamagnetic with 2 types of Ni - C bond length, out of which four
bond lengths are equal.
(b) Ncs- 1 is a WFL.
(c) [Pt(bn)2 ] 2+ have total 7 stereoisomers.
(d) [Mni(C0) 10] contains Obridging CO molecules .
(a) The hybridisation of [Fe(C0 ) 5] is dsp 3 and it is trigonal bipyramidal.
(b) All complex of Pd2+ and Pt2 + under C.N. = 4 are square planer.
(c) EDTA3-is hexadentate ligand.
(d) In Zeise's salt C = C bond length is nearly 1.37 A.
(a) In [CoICl(OX) 2]+ geometrical isomer exists, while optical isomerism does not exist.
(b) There are 3 geometrical isomer and 15 stereoisomer possible for [Pt(N0 2 )(NH3)(NH 2 0 H)(Py) t
and [PtFC1Br(N0 2)(Me- NH2)(Pji )] respectively.
(c) (glycinato) Zinc (II) is optically active.
(d) [Ni(CN)4 ] 4- is square planer complex.
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196 ===================== CHEMISTRY
5. In w hich o f the following inclu ding metal atleast 5 a tom s are in a line?
(a) [Ag(NH3)2t (b) [ A g(NC)2r
( c) [ Ag(SCN)2r (d) [Pt(CN) 4]2-

6. Black sulphides are formed by
(a) Cu 2+ (b) Sb 3+ (c) Pb2+ (d) Bi3+
7. Whic h of the sta temetns are true?
,i
(b) NH4NO3 ~NO2 + NH3
(c) NO2 + starch iodide pap er ➔ Blue colour
(slowly)
(d) Bc 1, 1-1 and No2- 1 interfere the brown ring test for N o 3- 1 .
8. W hic h of the following ions can be separated by using NH4C l and NH4OH ?
(a) Fe2+ a nd Cr 3+ (b) Cr3+ an d Mg2+
( c) Cr 3+ and Co2+ (d) Al3+ and Ba2+

9. W hic h of the following iodide are insoluble?
(a) Agl
10. Whic h of the following sche mes are correct?
dilHCl Zn 2+ Br2 HN03
(a) ZnS MnO 2 .J,, HMnO4
or or Hz0 Black Pb0z (purple)
MnS Mn2+
Na0H
(b) Cr 3+ Na0H
Cr(OH)3
excess
[Cr(OH) 4 r 1 Hz0z
OH
cr02-
4
AgN03
Ag 2CrO4
green (Brick red)
(c) Co(N03)z
Al2O3 l -2drop Al2O3.CoO
(Pink mass)
Bi+3 H2S
(d) Bi 2S3 .J,, (Black) .
11. Total number of compound wh ose hybridisation is d 2 sp3 :
[Cr(H 2O) 6] 3+, [Cr(CN ) 6] 3- , [Cr(H 2O) 6]2+, [Mn(Br) 4]2-, [Mn (NH 3) 6]2+, [Fe(NH 3) 6] 2+,
•
[Co(H 2O)6]3+, [Co(C2O4h] 3- , [IrC16] 3- , [NiF612- , [AuC14r 1
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Coordination Compounds & Qualitative Analysis 197
12. The compounds in which E.A.N. (Effective atomic number) is not 36 :
0 0
[Fe(1t -C5H 5 h] , [1t(cr - C 5 H 5 h (1t-C5H 5 h] , [Fei(CO)9 ], [Coi(CO) 8 ], [Mn(CO)6 ], [Mn(CO)5 ],
[Ni(en)2 Cl2 ] 0 , [Fe(C2 O4 ) 3 ] 3- , [Pb(EDTA)]2-, [Zn(gly)i]o
14. Consider the following complex compounds :
If x 1 + x 2 + x 3 are possible co-ordination isomer of given complex compound respectively then value
ofx/+x/ + x/ = ??
15. Na S + ~ H, ), f<Cl, Blue colom compound

2
N H2
The D.U. of blue compound?
16. Total number of stereoisomer possible for [M(AB )a2 bc] type complex?
17. Identity black colour ppt amongst the following :
18. Consider the following reaction:
Na3 PO4 + (NH 4) 2 MoO4 + HNO 3 (dil) ➔ ' P'

"Canary yellow ppt."
Total number of O atoms in P.
19. A small amount of mixture is treated with dil. H 2 SO4 solution, how many of the following anions can
give positive test?
20. How many of the following compound evolve NH 3 on heating.

NH 4 Cl, NH 4NO 3 , (NH 4 ) 2 CO3 , (NH 4) 2 SO4 , NH4 HCO3 , NH4NO 2 , (NH 4 ) 2 Cr 2O 7 , Mg(NH 4)PO4 .
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198 CHEMISTRY

21. Match each set or hybrid orbitals from column-I to column-II.
Column-I Column-II
•
(A) dsp2 (p) [NiF6]2-
(B) sp3 (q) [NiCliPPh3) 2]
(C) sp3d2 (r) [Mn(NH3) 6]2+
(D) d2sp3 (s) [Ni(CO)4 ]
(E) dsp3 (t) [Ni(CN)4 ] 2-
(u) [Fe(CO)5]
(v) [Fe(EDTA)r
22. Which of the anions in the column-I shows one or more observation from the column-II
Column-I (Ions) Column-II (Colour)
(A) s2- (p) White ppt. with AgNO3
(B) No 2- (q) Decolourises KMnO/ H+
(C) so32- (r) Pungent smell gas with Al+ NaOH
(D) CH3Coo- (s) Brown fumes with hot cone. H 2SO4

Passage-I
A bluish green coloured compound ' A' on heating gives two product ' B ' and 'C'. A metal 'D ' is
•
deposited on passing H 2 through heated ' B ' . The compound 'A' and 'B ' are insoluble in water. ' B ' is
black in colour, dissolves in HCl on treatment with K 4 [Fe(CN)6], it gives a chocolate gas and turns
lime water milky.
23. Compound 'A' is
(a) CuSO4 (b) CuCO 3 (c) FeSO4 (d) CrC13
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Coordination Compounds & Qualitative Analysis 199
24. Compound ' B ' and 'C' are respectively

(a) CuS, SO2 (b) CuO, CO2 (c) FeO, H 2 S
Passage-II
If ligand also contains chiral centre then number of stereo-isomer increases and is calculated as like
we calculate in organic chemistry.
25. [Pt(bn)2 ] 2+ posseses
(a) 5 Geometrical isomers (b) 4 Geometrical isomers
(c) 6 Total isomers (d) 7 Total isomers
26. [Pb(H 2 N-CH-C008 h ]o posseses

I
CH3
(a) 5 Geometrical isomers (b) 4 Geometrical isomers

( c) 6 Total isomers (d) 7 Total isomers
RESPONSE SHEET
1. Ci)@@@ 2. Ci)@@@ 3. Ci)@@@
4. Ci)@@@ 5. Ci)@@@ 6. Ci)@@@
7. Ci)@@@ 8. Ci)@@@ 9. Ci)@@@
10. Ci)@@@ 11. 12.
13. 14. 15.
16. 17. 18.
19. 20.
21. IAI 1
8 1 lcl lnl
23. Ci)@@@ 24. Ci)@@@ 25. Ci)@@@
26. Ci)@@@
rwww.JEEBOOKS.1Nl

Blockbuster Problems Chemistry Qns

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Blockbuster Problems Chemistry Qns

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Contents

1. Some Basic Concepts of Chemistry

2. Atomic Structure 9-16

3. Periodic Properties and Chemical Bonding 17-22

4. Gaseous State 23-32

5. Chemical Energetics 33-40

7. The Solid State 49-56

8. Liquid Solution 57-64

9. Electrochemistry & Redox Titration 65-72

10. Chemical Kinetics 73-82

11. Surface Chemistry 83-90

12. General Organic Chemistry 91-102

13. Isomerism 103-114

14. Hydrocarbons and Halogen Containing Compounds 115-126

15. Alcohol, Phenols, Ether, Aldehyde & Ketones 127-140

16. Carboxylic Acids & its Derivatives and Nitrogen

17. Biomolecules and Polymers 157-166

18. Hydrogen ands-Block 167-176

19. p-Block Elements 177-186

20. d & f-Block and Metallurgy 187-194

21. Co-ordination Compounds and Qualitative Analysis 195-204

4. What is the% of free SO 3 in a sample of oleum labelled as 104.5%?

(a) 0.68 g (b) 0.54 g (c) 0.45 g (d) 2 g

~ Numeric Value Answer

14. Reaction Yield of reaction

solution contains 30% ofNH 3 by weight and final volume of solution is

g---..: Match the Following

22. Match the Column-I with Column-IL

f Passage Based Questions

13. 14. 15.

16. 17. 18.

21. IAI 18 1 lcl 1° 1 IAI 22. 18 1 lcl 1° 1

~ MCQs with One or More than One Option Correct

(c) increases by (2n - l )r1, where n is higher orbit number

For single electron system: 'I'

19. The five valence electrons of 15P are labelled as

g---..: Match the Following

22. Match the Column-I with Column-IL

Column-I (Orbital) Column-II (R vs. r plot)

f Passage Based Questions

j = (z +½) or (1 - ½} the later is not negative

13. 14. 15.

16. 17. 18.

21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

~ MCQs with One or More than One Option Correct

5. The species in which central atom is not sp 3 hybridised is/are :

12. Maximum number of atoms present in one plane in PFi{CH 3)3.

Mn(CO)s, 0 ~, N 2, Nd+2, 0~, F~, Ce+4.

CH2 = CH - cHf, XeF4, [NiFCl(CN)2] 2- , N203, O·

CO, N 2, N 2e , C2e , C032- , F2EB , S 8 , C 30 2, Ci(CN)2 .

g---..: Match the Following

(C) Bond order of 0 3 (r) 1.33

20. Match the columns :

f Passage Based Questions

23. Cl - Cl distance in structure (A) is :

13. 14. 15.

16. 17. 18.

21. IAI 18 1 lcl 1° 1 22. IAI 18 1 lcl 1° 1

~ MCQs with One or More than One Option Correct

n-1...P~·. .~. . . . . .?_

Radius of syringe = 0.56 cm

(c) H 2 0 > CO 2 > CH 4 (d) \ / >/ \ / > H 20

(c) (:;t-(:~L-(:;t = -l (d)

13. Air is trapped in a horizontal glass tube by 40 cm Hg column as show n below.