Example 3.

6 - Lona (2018) Chapter 3

Parameters
Ea 48500 J/mol
R 8.314 J/mol-K
k0 8.20E+07 min^-1
hHr -72800 J/mol
Cp 1750 J/kg-K
rho 880 kg/m3
T0 300 K
CA0 100 mol/m3
CB0 0 mol/m3
CC0 0 mol/m3
Euler method
h 1 min
t (min) CA (mol/m3) CB (mol/m3) CC (mol/m3) T (K) k (min^-1)
0 100 0 0 300 0.2943803
1 70.56197135 58.87605729 29.43802865 301.3916 0.3220338
2 47.83863481 104.3227304 52.16136519 302.4658 0.3449488
3 31.33675564 137.3264887 68.66324436 303.2459 0.3624948
4 19.97734608 160.0453078 80.02265392 303.7829 0.3750333
5 12.48517637 175.0296473 87.51482363 304.1371 0.3835144
6 7.696931667 184.6061367 92.30306833 304.3634 0.3890242
7 4.702638735 190.5947225 95.29736126 304.505 0.3925057
8 2.856826219 194.2863476 97.14317378 304.5922 0.3946657
9 1.729334878 196.5413302 98.27066512 304.6455 0.3959904
10 1.044534951 197.9109301 98.95546505 304.6779 0.3967968
11 0.630066786 198.7398664 99.36993321 304.6975 0.3972857
12 0.379750281 199.2404994 99.62024972 304.7093 0.3975812
13 0.228768724 199.5424626 99.77123128 304.7165 0.3977595
14 0.137773795 199.7244524 99.8622262 304.7208 0.397867
15 0.08295815 199.8340837 99.91704185 304.7234 0.3979318
16 0.049946467 199.9001071 99.95005353 304.7249 0.3979708
17 0.030069232 199.9398615 99.96993077 304.7259 0.3979943
18 0.01810185 199.9637963 99.98189815 304.7264 0.3980084
19 0.010897161 199.9782057 99.98910284 304.7268 0.3980169
20 0.006559907 199.9868802 99.99344009 304.727 0.3980221
21 0.003948919 199.9921022 99.99605108 304.7271 0.3980251
22 0.00237715 199.9952457 99.99762285 304.7272 0.398027
23 0.00143098 199.997138 99.99856902 304.7272 0.3980281
24 0.00086141 199.9982772 99.99913859 304.7272 0.3980288
25 0.000518544 199.9989629 99.99948146 304.7272 0.3980292
26 0.000312148 199.9993757 99.99968785 304.7273 0.3980294
27 0.000187904 199.9996242 99.9998121 304.7273 0.3980296
28 0.000113113 199.9997738 99.99988689 304.7273 0.3980297
29 6.809048E-05 199.9998638 99.99993191 304.7273 0.3980297
30 4.098844E-05 199.999918 99.99995901 304.7273 0.3980298
31 2.467382E-05 199.9999507 99.99997533 304.7273 0.3980298
32 1.485291E-05 199.9999703 99.99998515 304.7273 0.3980298
33 8.941007E-06 199.9999821 99.99999106 304.7273 0.3980298
34 5.38222E-06 199.9999892 99.99999462 304.7273 0.3980298
35 3.239936E-06 199.9999935 99.99999676 304.7273 0.3980298
36 1.950345E-06 199.9999961 99.99999805 304.7273 0.3980298
37 1.174049E-06 199.9999977 99.99999883 304.7273 0.3980298
38 7.067428E-07 199.9999986 99.99999929 304.7273 0.3980298
39 4.254381E-07 199.9999991 99.99999957 304.7273 0.3980298
40 2.56101E-07 199.9999995 99.99999974 304.7273 0.3980298
 Reactor temperature vs time
306
305
Reactor temperature (K)

304
303
302
301
300
299
298
297
0 5 10 15 20 25 30 35 40
Reaction time (min)
ture vs time
Concentration of A, B, C vs time
250

200
Concentration (mol/m3)

Concentration of A
150 Concentration of B
Concentration of C
100

25 30 35 40 45 50

time (min)
0
0 5 10 15 20 25 30 35 40 45
Reaction time (min)
40 45