Cinetica Quimica: Parametros Cineticos por el metodo integral

The liquid-phase irreversible reaction:

Was carried out in a batch reactor at 25 °C in a solution or benzene and pyridine in an excess of methanol (CB0
precipitates as pyridine hydro-chloride thereby making the reaction irreversible. The reaction is first order in m
chloride (A) was measured as a function of time and is shown below:

Time (min) Concentration of A

(mol/dm3)
0 0.05
50 0.038
100 0.0306
150 0.0256
200 0.0222
250 0.0195
300 0.0174
CB = 0.5

METODO INTEGRAL
ORDEN CERO PRIMER ORDEN
Time(min) CA Time(min) In(CA0/CA)
0 0.05 0 0
50 0.038 50 0.27443685
100 0.0306 100 0.49102300
150 0.0256 150 0.66943065
200 0.0222 200 0.81193072
250 0.0195 250 0.94160854
300 0.0174 300 1.05555280

K´= 0.1248 a 25°C

K= 0.2496 a 25°C
l metodo integral

n an excess of methanol (CB0 =0.5 mol/dm3). Pyridine reacts with HCI, which then
The reaction is first order in methanol. The concentration of triphenyl methyl

70

60
f(x) = 0.124794016573669 x + 20.1175244754766
50

40

30

20

10

0
0 50 100 150 200 250 300 350

SEGUNDO ORDEN
Time(min) 1/CA
0 20
50 26.3157895
100 32.6797386
150 39.0625
200 45.045045
250 51.2820513
300 57.4712644
Cinética Química Parámetros cinéticos por regresión no lineal 
The liquid phase reaction:

Was carried out in a batch reactor at 25 °C in a solution of benzene and pyridine in an excess of methanol (CB0
which then precipitates as pyridine hydro-chloride thereby making the reaction irreversible. The reaction is firs
triphenyl methyl chloride (A) was measured as a function of time and is shown below:

Time (min) Concentration of A Concentration of A Time (min) [Calculate]

(mol/dm3) (mol/dm3)
[Experimental] [Calculated]
0 0.05 0.05 0
50 0.038 0.038070555328726 50.3891042768907
100 0.0306 0.030737039166755 101.162439196416
150 0.0256 0.025772493783491 152.08586421072
200 0.0222 0.022188655232886 199.816252845748
250 0.0195 0.019479850975436 249.576802807335
300 0.0174 0.017360473965215 298.956045872664

α= 2
K´= 0.125340379915837

K= 0.250680759831674 a 25 °C

CB = 0.5
no lineal 

n excess of methanol (CB0=0.5 mol/dm3). Pyridine reacts with HCI,

ersible. The reaction is first order in methanol. The concentration of

s2

0
0.1514021383
1.3512648854
4.3508295056
0.0337630167
0.1790958639
1.08984022
7.15619563