FR2 Samples Left to Run for the GPC

Approximate
MAB0905 Volume Left
Station
1-000 1.8 **
1-200 2.3
1-integrated 4 **
2-000
2-1000
3-000 2.3
3-200 2.3
4-000 4
4-065
5-000
5-043-pre
6-000-pre 0.5
7-000-pre
8-000-pre 1.1
9-000-pre 3.2
10-000-pre 2
10-026-pre 1
11-000-pre 0.2
11-026-pre 0.4
12-000-pre 2.5
12-019-pre 3
7p-000-pre
blk 3
MAB0406
1-000 3.75
1-200 3.8
4-000-pre 3.75
4-065-pre 3.75
5-000-pre 4.2
5-043-pre 4
10-000-pre 4
10-026-pre 3.5
11-000-pre 3.4
11-020-pre 2.6
12-000-pre 4.1
12-018-pre 3.6
b1-28-000-pre 4.5
b1-14-000-pre 4.5
b2-2-000-1 4.5
b2-2-000-2 4.5
b3-0-000-1 4.5
b3-0-000-2 4.8

MAB0806
1-000-pre
1-017-pre
2-000-pre
2-026-pre
4-000-pre
4-075-pre
7-000-1-pre
7-000-2-pre
7-1000-1-pre
7-1000-2-pre
8-000-pre
8-200-pre
10-000-pre
10-035-pre
11-000-pre
11-025-pre
12-000-pre
14-000-pre
16-000-1-pre
16-000-2-pre
19-000-1-pre
19-000-2-pre
20-000-pre
21-000-pre

MAB1006
101406mb-B - surf 8.2
101406-ub-A - surf 9
101206B - B28 - surf 4.6
1-1000 3
2-000 3
2-deep 4.3
3-000 5.8
3-030 4
4-000 5.8
4-025 6
5-000 6
5-111 4
6-000 6
6-021 4
7-000 6.2
7-020 4.2 2?

MAB1206
2-0
2-50
3-30 (R1)
3-30 (R2)
4-20 (R1)
4-20 (R2)
6-0
6-15
7-0 (R1)
7-0 (R2)
8-0 (R1)
8-0 (R2)
9-0
9-20
11-0 (R1)
11-0 (R2)
13-0
14-0 (R1)
14-0 (R2)
 9169764.xls

11/23/2207
Lignin-derived phenols MARS/ GC analysis
MAB Cruise Sept. 2005
C18 SPE extractions FR2
all stations recalculated by rdv using peak area from GC files and '200/300*5ml/20L'
new data in peak area units (ng/uL)
FR2
microw
GC (Digestion) ave vol total
water FR2 (ul) total lignin lignin C/V [Ad/Al]v [Ad/Al]s
Station comments vol (L) vol (ml) N used (Λ) (ug/L) S/V C/V [Ad/Al]v [Ad/Al]s (Λ) stdev S/V stdev stdev stdev stdev
1-000-pre 20 5.6 9/6/2007 2 600 0.74 2.3 1.01 0.81 5.27 0.03 0.17 0.03 0.18 0.94
1-200-pre 15 5.6 9/6/2007 2 800 0.71 3.66 1.15 1.21 0.7 0.06 0.08 0.1 0.19 0.03
1-40m integrated? 20 8.7 9/6/2007 2 600 1.68 2.08 0.84 2.05 7.24 0.79 0.13 0.35 1.9 6.72
2-000-pre 20 3 9/6/2007 2 800 0.36 1.61 1.63 0.6 4.41 0.04 0.89 0.42 0.4 1.13
2-1000-pre 20 3 8/29/2007 2 600 0.79 1.8 1.27 0.62 19.28 0.05 0.36 0.16 0.16 1.51
3-000-pre 20 5.2 8/22/2007 2 600 0.84 1.13 1.23 0.48 3.65 0.14 0.12 0.1 0.3 0.31
3-200-pre 20 8.3 8/22/2007 2 600 0.91 1.31 1.62 1.02 3.16 0.08 0.12 0.01 0.05 0.47
4-000-pre 20 8.4 10/9/2007 2 600 1.27 2.13 1.11 1.43 8.06 0.06 0.3 0.04 0.96 0.96
4-065-pre 20 5 8/17/2007 2 600 1.29 2.62 1.97 0.75 4.05 0.27 0.28 0.74 0.12 0.69
5-000-pre 20 3 10/3/2007 2 500 0.7 2.1 1.16 1.56 3.8 0.16 0.09 0.26 0.62 0.3
5-043-pre 20 5 10/3/2007 2 500 0.82 1.37 1.25 1.23 4.07 0.03 0.16 0.09 0.21 0.22
6-000-pre 20 3.5 1/19/07 (1/17) 3 200 3.29 1.07 0.28 0.83 1.4 0.05 0.04 0.01 0.01 0.07
7-000-pre (not fractionated) 20 8.3 1/19/07 (1/18) 3 200 10.24 1.1 0.28 0.89 1.2 0.86 0.03 0.02 0.04 0.08
8-000-pre 20 4 1/10/07 (1/8-10) 3 200 5.31 1.12 0.31 1.03 1.2 0.21 0.02 0 0.14 0.1
9-000-pre 20 6 12/14/06 (12/13) 2 196 5.55 0.98 0.29 1.06 1.16 0.17 0.02 0.01 0.05 0.01
10-000-pre 20 5.4 8/14/2007 2 600 1.16 2.02 1.03 0.83 2.28 0.07 0.09 0.27 0.01 0.08
10-026-pre 20 4.9 8/14/2007 2 600 1.62 2.15 0.83 1.86 5.36 0.65 0.03 0.27 1.51 4.67
11-000-pre 20 5.5 1/25/07 (1/22) 3 400 1.8 0.93 0.22 0.95 1.37 0.16 0.04 0.01 0.01 0.12
11-026-pre 20 5.5 2/8/07 (2/5) 2 600 1.78 0.78 0.22 1.01 1.74 0.38 0.01 0 0.1 0.1
12-000-pre 20 5 1/25/07 (1/23) 3 400 2.38 1.01 0.33 0.95 1.46 0.04 0.02 0.07 0 0.02
12-019-pre 20 5.5 2/8/07 (2/7) 2 600 2.24 0.99 0.3 0.97 1.71 0.08 0.04 0.01 0.11 0.22
7p-000-pre 20 8 12/14/06 (12/11-12)2 200 9.9 1.17 0.32 1.06 1.35 1.89 0 0.02 0.08 0.24

blank QH20 4.7

5-000-pre 20 3 10/11/2007 1 300

6-000-pre 20 3.5 8/14/2007 2 200 2.42 2.03 1 0.69 1.53 0.12 0.14 0.03 0.14 0.75
7-000-pre 20 8.3 connected 2 200 9.31 1.07 0.26 0.86 1.07 0.18 0.1 0.02 0.04 0
7-000-pre 20 8.3 10/8/2007 2 400 3.73 0.89 0.55 0.6 0.73 0.85 0.04 0.07 0.02 0.06
8-000-pre 20 4 1/10/07 (1/9) 2 200 5.04 1.13 0.29 1.14 1.44 0.34 0.05 0.01 0.35 0.28
8-000-pre 20 4 10/9/2007 2 300 2.4 1.27 0.49 0.83 1.23 0.27 0.05 0.01 0.08 0.16
7p-000-pre 20 8 10/8/2007 2 400 3.23 1.16 0.66 0.32 0.77 0.11 0.15 0.09 0.42 0.01

Lignin-derived phenols MARS/ GC analysis

MAB Cruise Sept. 2005
C18 SPE extractions FR2
values recalculated by rdv using ng/uL provided by lynne and 200/300*5ml/20L
new data in ug/L units (ng/uL)
FR2
microw
GC (Digestion) ave vol total
water FR2 (ul) total lignin lignin C/V [Ad/Al]v [Ad/Al]s
Station comments vol (L) vol (ml) N used (Λ) (ug/L) S/V C/V [Ad/Al]v [Ad/Al]s (Λ) stdev S/V stdev stdev stdev stdev
1-000-pre 20 5.6 9/6/2007 2 600 0.69 0.16 0.1 0.06 0.02 0.01 0.03 0 0 0.01
1-40m 20 8.7 9/6/2007 2 600 1.83 0.35 0.18 0.11 0.03 0.82 0.16 0.03 0.01 0.04
1-200-pre 15 5.6 9/6/2007 2 800 0.85 0.2 0.12 0.1 0.02 0 0.02 0.01 0.02 0.01
2-000-pre 20 3 9/6/2007 2 800 0.34 0.08 0.05 0.04 0.01 0 0.01 0 0.01 0.01
2-1000-pre 20 3 8/29/2007 2 600 0.66 0.09 0.06 0.03 0.88 0.04 0.02 0.01 0.01 0.17
3-000-pre 20 5.2 8/22/2007 2 600 1.22 0.19 0.09 0.05 0.04 0.39 0.02 0 0 0.01
3-200-pre 20 8.3 8/22/2007 2 600 0.95 0.31 0.19 0.13 0.11 0.06 0.02 0.01 0.02 0
4-000-pre 20 8.4 10/9/2007 2 600 1.12 0.27 0.28 0 0.24 0.08 0.04 0.01 0 0.34
4-065-pre 20 5 8/17/2007 2 600 0.74 0.08 0.16 0.05 0.18 0.22 0 0.1 0.02 0.12
5-000-pre 20 3 10/3/2007 2 500 0.59 0.07 0.06 0.04 0.07 0.13 0.01 0.01 0.01 0
5-043-pre 20 5 10/3/2007 2 500 1.43 0.13 0.08 0.07 0.17 0.11 0.02 0 0.01 0.01
6-000-pre 20 3.5 1/19/07 (1/17) 3 200 4.12 0.19 0.04 0.14 0.23 0.01 0.01 0 0 0.01
7-000-pre (not fractionated) 20 8.3 1/19/07 (1/18) 3 200 11.62 0.46 0.1 0.38 0.47 0.29 0.01 0.01 0.02 0.03
8-000-pre 20 4 1/10/07 (1/8-10) 3 200 6.57 0.21 0.05 0.18 0.25 0.03 0 0 0.03 0.02
9-000-pre 20 6 12/14/06 (12/13) 2 196 7 0.26 0.05 0.28 0.35 0.11 0.01 0 0.02 0
10-000-pre 20 5.4 8/14/2007 2 600 1.03 0.2 0.1 0.05 0.03 0.02 0 0 0 0
10-026-pre 20 4.9 8/14/2007 2 600 1 0.1 0.06 0.05 0.2 0.22 0.05 0.01 0 0.06
11-000-pre 20 5.5 1/25/07 (1/22) 3 400 2.05 0.12 0.01 0.11 0.21 0.06 0.01 0 0 0.02
11-026-pre 20 5.5 2/8/07 (2/5) 2 600 1.78 0.07 0.01 0.08 0.17 0.14 0 0 0.01 0.01
12-000-pre 20 5 1/25/07 (1/23) 3 400 3.02 0.12 0.03 0.1 0.2 0.17 0 0.01 0 0
12-019-pre 20 5.5 2/8/07 (2/7) 2 600 2.51 0.09 0.02 0.08 0.16 0.04 0 0 0.01 0.02
7p-000-pre 20 8 12/14/06 (12/11-12)2 200 11.81 0.42 0.08 0.37 0.53 1.44 0 0 0.03 0.11

blank QH20 4.7

5-000-pre 20 3 10/11/2007 1 300 0.89 0.14 0.12 0.05 0.32 0.44 0.01 0.03 0.01 0.1
6-000-pre 20 3.5 8/14/2007 2 200 2.77 0.11 0.11 0.16 0.2 0.39 0 0.01 0 0.01
7-000-pre 20 8.3 connected 2 200 11.83 0.46 0.08 0.32 0.4 0.31 0.04 0.01 0.01 0
7-000-pre 20 8.3 10/8/2007 2 400 2.67 0.15 0.12 0.19 0.37 0.55 0 0.01 0 0.02
8-000-pre 20 4 1/10/07 (1/9) 2 200 6.27 0.21 0.04 0.21 0.29 0.29 0.01 0 0.07 0.06
8-000-pre 20 4 10/9/2007 2 300 1.47 0.22 0.1 0.02 0.41 0.28 0.01 0.02 0.01 0.04
7p-000-pre 20 8 10/8/2007 2 400 2.19 0.17 0.11 0.18 0.39 0.52 0 0 0.01 0.01

Prepared by rdv 10/17/2008 Page 4

 9169764.xls

Lignin-derived phenols MARS/ GC analysis

MAB Cruise Sept. 2005 Each run digested individually
C18 SPE extractions FR2 200/300*(5ml/20L)
new data together units (ng/uL)
FR2
microw
GC (Digestion) ave vol total total total
water FR2 (ul) lignin lignin lignin [Ad/Al]v [Ad/Al]s
Station comments vol (L) vol (ml) N used VAL VON VAD SAL SON SAD CAD FAD (Λ) S/V C/V [Ad/Al]v [Ad/Al]s (Λ) S/V C/V [Ad/Al]v [Ad/Al]s (Λ) stdev S/V stdev C/V stdev stdev stdev
1-000-pre 20 5.6 9/6/2007 2 600 1.05 0.43 0.66 2.34 0.67 0.22 1.14 1 0.7 0.14 0.09 0.06 0.01 0.69 0.16 0.1 0.06 0.02 0.01 0.03 0 0 0.01
20 5.6 600 0.86 0.39 0.57 2.21 0.66 0.69 1 0.9 0.68 0.18 0.1 0.06 0.03
1-40m 20 8.7 9/6/2007 2 600 1.09 0.42 0.81 2.86 0.86 0.05 1.28 1.24 1.25 0.24 0.16 0.11 0 1.83 0.35 0.18 0.11 0.03 0.82 0.16 0.03 0.01 0.04
20 8.7 600 1.18 0.87 0.94 5.72 1.75 2.09 2.38 1.67 2.41 0.46 0.2 0.12 0.05
1-200-pre 15 5.6 9/6/2007 2 800 0.71 0.55 0.85 3.04 0.87 0.29 1.48 1.3 0.85 0.18 0.12 0.11 0.01 0.85 0.2 0.12 0.1 0.02 0 0.02 0.01 0.02 0.01
15 5.6 800 0.77 0.51 0.74 2.87 0.86 0.89 1.3 1.17 0.85 0.21 0.11 0.09 0.03
2-000-pre 20 3 9/6/2007 2 800 0.71 0.55 0.85 3.04 0.87 0.29 1.48 1.3 0.34 0.07 0.05 0.04 0 0.34 0.08 0.05 0.04 0.01 0 0.01 0 0.01 0.01
20 3 800 0.77 0.51 0.74 2.87 0.86 0.89 1.3 1.17 0.34 0.09 0.05 0.04 0.01
2-1000-pre 20 3 8/29/2007 2 600 0.53 2.11 0.22 0.27 0.25 5.32 0.65 3.34 0.63 0.1 0.07 0.02 1 0.66 0.09 0.06 0.03 0.88 0.04 0.02 0.01 0.01 0.17
20 3 600 0.36 3.24 0.27 0.34 0.25 5.22 0.61 3.56 0.69 0.08 0.05 0.04 0.76
3-000-pre 20 5.2 8/22/2007 2 600 1 0.85 0.61 3.33 1.3 1.2 1.34 1.31 0.95 0.21 0.09 0.05 0.03 1.22 0.19 0.09 0.05 0.04 0.39 0.02 0 0 0.01
20 5.2 600 1.17 2.37 0.67 4.74 1.29 2.61 1.37 3.03 1.5 0.18 0.09 0.05 0.05
3-200-pre 20 8.3 8/22/2007 2 600 0.47 0.62 0.52 1.58 0.56 1.26 0.64 1.51 0.99 0.29 0.18 0.15 0.11 0.95 0.31 0.19 0.13 0.11 0.06 0.02 0.01 0.02 0
20 8.3 600 0.48 0.5 0.41 1.5 0.51 1.18 0.63 1.33 0.9 0.32 0.2 0.12 0.11
4-000-pre 20 8.4 10/9/2007 2 600 0.94 0.73 0 0.47 1.47 1.63 1.06 2.13 1.18 0.3 0.27 0 0.48 1.12 0.27 0.28 0 0.24 0.08 0.04 0.01 0 0.34
20 8.4 600 0.93 0.65 0 0 1.26 1.52 1.08 2.13 1.06 0.25 0.28 0 0
4-065-pre 20 5 8/17/2007 2 600 1.34 1.57 0.63 0.59 1.11 1.88 1.15 2.53 0.9 0.08 0.09 0.04 0.27 0.74 0.08 0.16 0.05 0.18 0.22 0 0.1 0.02 0.12
20 5 600 0.55 0.46 0.47 0.47 0.45 0.58 0.82 3.2 0.58 0.08 0.23 0.07 0.1
5-000-pre 20 3 10/3/2007 2 500 1.3 1.04 1.07 1.47 1.31 1.76 1.9 1.6 0.69 0.08 0.06 0.05 0.07 0.59 0.07 0.06 0.04 0.07 0.13 0.01 0.01 0.01 0
20 3 500 1.17 0.79 0.77 1 0.95 1.23 1.24 1.18 0.5 0.07 0.05 0.04 0.07
20 3 10/11/2007 1 300 1.19 0.74 0.58 0.48 1.45 1.5 0.96 2 0.89 0.14 0.12 0.05 0.32 0.89 0.14 0.12 0.05 0.32 0.44 0.01 0.03 0.01 0.1
5-043-pre 20 5 10/3/2007 2 500 2.14 1.65 1.38 1.58 1.66 2.8 1.92 1.94 1.51 0.12 0.07 0.06 0.18 1.43 0.13 0.08 0.07 0.17 0.11 0.02 0 0.01 0.01
20 5 500 1.56 1.54 1.16 1.48 2.14 2.43 2.03 1.18 1.35 0.14 0.08 0.07 0.16
6-000-pre 20 3.5 1/19/07 (1/17) 3 200 3.99 3.14 3.16 3.52 2.69 4.95 1.1 1.02 4.13 0.19 0.04 0.14 0.25 4.12 0.19 0.04 0.14 0.23 0.01 0.01 0 0 0.01
20 3.5 200 4.02 3.28 3.12 3.52 2.67 4.59 1.13 1.15 4.11 0.18 0.04 0.14 0.23
20 3.5 200 3.99 3.19 3.08 3.75 2.63 4.52 1.17 1.17 4.11 0.19 0.04 0.14 0.21
20 3.5 8/14/2007 2 200 2.51 1.38 2.28 1.23 1.5 1.33 1.66 2.39 2.5 0.12 0.12 0.16 0.19 2.77 0.11 0.11 0.16 0.2 0.39 0 0.01 0 0.01
20 3.5 200 3.22 1.82 2.89 1.44 1.85 1.72 1.89 2.57 3.05 0.11 0.1 0.16 0.21
7-000-pre (not fractionated) 20 8.3 1/19/07 (1/18) 3 200 4.78 3.43 4.22 4.88 3.87 5.23 1.43 1.22 12.06 0.47 0.09 0.37 0.44 11.62 0.46 0.1 0.38 0.47 0.29 0.01 0.01 0.02 0.03
20 8.3 200 4.65 3.55 3.83 4.37 3.49 5.13 1.52 1.51 11.64 0.45 0.1 0.34 0.49
20 8.3 200 4.07 3.05 4.1 4.17 3.67 4.73 1.5 1.56 11.14 0.46 0.11 0.42 0.47
20 8.3 connected 2 200 4.91 3.76 3.95 4.85 3.45 4.74 1.29 1.03 11.61 0.43 0.08 0.33 0.41 11.83 0.46 0.08 0.32 0.4 0.31 0.04 0.01 0.01 0
20 8.3 200 4.99 3.41 3.76 5.42 3.71 5.27 1.33 1.15 12.05 0.49 0.08 0.31 0.4
20 8.3 10/8/2007 2 400 2.34 1.9 2.19 0.93 2.24 1.61 1.29 2.27 3.06 0.15 0.11 0.19 0.36 2.67 0.15 0.12 0.19 0.37 0.55 0 0.01 0 0.02
20 8.3 400 1.68 1.42 1.57 0.68 1.53 1.28 0.91 1.94 2.29 0.16 0.13 0.19 0.39
8-000-pre 20 4 1/10/07 (1/8-10) 3 200 5.14 3.82 5.27 5.02 3.95 5.57 1.64 1.5 6.38 0.2 0.04 0.2 0.22 6.57 0.21 0.05 0.18 0.25 0.03 0 0 0.03 0.02
20 4 200 5.38 4.18 4.53 4.9 3.81 6.1 1.74 1.44 6.42 0.21 0.05 0.17 0.25
20 4 200 5.62 4.44 4.79 4.89 4.21 6.84 1.98 1.85 6.92 0.21 0.05 0.17 0.28
20 4 1/10/07 (1/9) 2 200 4.66 4.07 5.9 4.17 3.77 6.84 1.71 1.24 6.47 0.2 0.04 0.25 0.33 6.27 0.21 0.04 0.21 0.29 0.29 0.01 0 0.07 0.06
20 4 200 5.32 3.69 4.24 4.7 3.79 5.76 1.52 1.26 6.06 0.22 0.04 0.16 0.25
20 4 10/9/2007 2 300 1.89 0.88 0.21 0.64 2.17 1.83 0.89 0.98 1.27 0.21 0.08 0.01 0.38 1.47 0.22 0.1 0.02 0.41 0.28 0.01 0.02 0.01 0.04
20 4 300 2.07 1.09 0.4 0.77 2.74 2.53 1.11 1.8 1.67 0.23 0.11 0.03 0.44
9-000-pre 20 6 12/14/06 (12/13) 2 196 4.12 3.29 3.94 3.41 2.32 3.93 1.35 0.75 7.07 0.26 0.06 0.29 0.35 7 0.26 0.05 0.28 0.35 0.11 0.01 0 0.02 0
20 6 196 4.18 3.19 3.71 3.61 1.88 4.2 1.13 0.71 6.92 0.27 0.05 0.27 0.36
10-000-pre 20 5.4 8/14/2007 2 600 1.53 0.26 0.82 3.32 1.23 1.15 0.89 2.08 1.02 0.2 0.1 0.05 0.03 1.03 0.2 0.1 0.05 0.03 0.02 0 0 0 0
vol was 500; changes to 600
20 5.4 600 1.65 0.28 0.83 3.42 1.33 1.22 0.88 2.06 1.05 0.19 0.1 0.05 0.03
10-026-pre 20 4.9 8/14/2007 2 600 1.86 1.3 1.04 0.68 1.44 1.35 0.78 1.95 0.85 0.07 0.05 0.05 0.16 1 0.1 0.06 0.05 0.2 0.22 0.05 0.01 0 0.06
20 4.9 600 1.03 2.43 0.58 1 3.03 2.98 1.44 1.66 1.16 0.14 0.06 0.05 0.24
11-000-pre 20 5.5 1/25/07 (1/22) 3 400 2.71 2.43 2.28 1.91 1.52 2.7 0.66 0 1.95 0.11 0.01 0.12 0.19 2.05 0.12 0.01 0.11 0.21 0.06 0.01 0 0 0.02
20 5.5 400 2.69 2.5 2.23 2.04 1.37 3.23 0.8 0 2.04 0.12 0.01 0.11 0.22
20 5.5 400 3.38 2.51 2.33 2.02 1.39 3.31 0.71 0 2.15 0.11 0.01 0.09 0.23
11-026-pre 20 5.5 2/8/07 (2/5) 2 600 3.54 3.72 3.51 2.26 1.54 4.34 1.22 0.41 1.88 0.07 0.01 0.09 0.18 1.78 0.07 0.01 0.08 0.17 0.14 0 0 0.01 0.01
20 5.5 600 3.46 3.43 2.94 2.07 1.34 3.79 0.87 0.46 1.68 0.07 0.01 0.08 0.17
12-000-pre 20 5 1/25/07 (1/23) 3 400 3.79 3.18 3.17 2.9 2.27 4.41 1.1 1.84 2.83 0.12 0.04 0.1 0.19 3.02 0.12 0.03 0.1 0.2 0.17 0 0.01 0 0
20 5 400 4.35 3.4 3.64 3.35 2.51 5.17 1.25 0.97 3.08 0.12 0.02 0.1 0.19
20 5 400 4.6 3.37 3.5 3.36 2.29 5.61 1.11 1.24 3.14 0.12 0.03 0.1 0.21
12-019-pre 20 5.5 2/8/07 (2/7) 2 600 4.33 4.17 4.13 3.07 2.89 5.98 1.25 1.89 2.54 0.09 0.02 0.09 0.18 2.51 0.09 0.02 0.08 0.16 0.04 0 0 0.01 0.02
20 5.5 600 4.7 3.69 3.81 3.58 2.83 5.74 1.17 1.57 2.48 0.09 0.02 0.07 0.15
7p-000-pre 20 8 12/14/06 (12/11-12)2 200 5.5 3.91 4.74 5.41 3.44 6.16 1.63 1.26 12.82 0.42 0.08 0.34 0.46 11.81 0.42 0.08 0.37 0.53 1.44 0 0 0.03 0.11
20 8 200 4.35 3.28 4.22 3.88 2.8 5.91 1.54 0.99 10.79 0.42 0.09 0.39 0.61
20 8 10/8/2007 2 400 1.54 0.81 1.43 0.58 1.44 1.16 0.73 1.43 1.82 0.17 0.11 0.19 0.4 2.19 0.17 0.11 0.18 0.39 0.52 0 0 0.01 0.01
20 8 400 2.26 1.21 1.89 0.79 2.16 1.51 1.01 1.98 2.56 0.17 0.11 0.17 0.38
blank QH20 4.7

Lignin-derived phenols MARS/ GC analysis Analysis year 2006&2007

MAB Cruise Sept. 2005 Each run digested individually
C18 SPE extractions FR2
old data GC (Digestion) units (µg/L) VAD/VAL SAD/SAL
seawater FR2 total lignin
Station vol (L) vol (ml) N VAL VON VAD V SAL SON SAD S CAD FAD C (Λ) S/V C/V [Ad/Al]v [Ad/Al]s
1-000-pre 20 5.6
1-200-pre 15 5.6

Prepared by rdv 10/17/2008 Page 5

 9169764.xls

1-integrated 20? 8.7

2-000-pre ? ?
2-1000-pre ? 3
3-000-pre 20 5.2
3-200-pre 20 8.3*
4-000-pre 20 8.4 2/2/07(2/1)
4-065-pre 20 5
5-000-pre 20 ?
5-043-pre 20 5
6-000-pre 20 3.5* 1/19/07 (1/17) 3 0.700± 0.003 .56± .01 .547± .0071.81± .01 .63± .02 .47± .01 .82± .04 1.92± .04 .199± .006 .20± .02 .93± .02 4.12± .01 1.06± .03 .22± .01 .78± .01 1.3± .1
7-000-pre 20 8.3 1/19/07 (1/18) 3 1.87± .16 1.39± .11 1.68± .08 4.94± .26 1.86± .15 1.53± .08 2.09± .11 5.47± .3 .62± .02 .59± .08 1.21±.0911.6± .5 1.11± .02 .25± .03 .90± .09 1.13± .05
8-000-pre 20 4* 1/10/07 (1/8-10) 3 1.08±.05 .83±.06 .97±.08 2.88±.08 .99±.01 .80±.04 1.23±.13 3.02±.15 .36±.03 .32±.04 .68±.08 6.6±.3 1.05±.03 .23±.02 .91±.10 1.25±.14
1/10/07 (1/9) 2 0.10± .1 .78± .05 1.01± .23 2.79± .19 .89± .07 .757± .003 1.26± .15 2.90± .07 0.32± .03 .251± .003 .57± .02 6.27±.29 1.04± .05 .206± .006 1.0± .3 1.4± .3
9-000-pre 20 <6 12/14/06 (12/13) 2 1.27± 0.01 .99±.02 1.16±.05 3.43±.06 1.07±0.04 .6±.1 1.24±.06 2.96±.01 .38±.05 .22±.01 .60±.06 7.0±.1 .86±.02 .17±.01 .92±.05 1.16±.01
10-000-pre 20 5.4
10-026-pre 20 4.9
11-000-pre 20 5.5 1/25/07 (1/22) 3 0.40± .05 .341± .006.314± .0071.06± .06 .27± .01 .20± .01 .42± .05 .89± .04 .10± .01 ND .10 ± .012.05 ± .10 .85 ± .04 .09 ± .01 .79 ± .09 1.55 ± .12
11-026-pre 20 5.5 2/8/07 (2/5) 2 0.321 ± .005 0.33 ± .020.30 ± .04.94 ± .06 .20 ± .01 .13 ± .01 .37 ± .04 .70 ± .06 .10 ±.02 .040 ±.004 .14 ±.02 1.78 ± .14 .74 ± .02 .14 ± .01 .92 ± .10 1.88 ± .07
12-000-pre 20 5* 1/25/07 (1/23) 3 .53± .05 .41± .02 .43± .03 1.38± .09 .40± .03 .29±.02 .63± .08 1.33± .11 .14± .01 .16± .06 .31± .05 3.02± .16 .96± .02 .23± .05 .81± .04 1.58± .08
12-019-pre 20 5.5 2/8/07 (2/7) 2 .41 ± .02 .36 ± .03 .36 ± .02 1.14 ± .03.30 ± .03 .262 ± .004.54 ± .02 1.10 ± .01.111 ± .005.16 ± .02 .27 ± .032.51 ±.04 0.97 ± .04 .24 ± .02 .88 ± .10 1.78 ± .25
7p-000-pre 20 <8 12/14/06 (12/11-12)3 1.93±.24 1.42±.13 1.85±.14 5.21±.46 1.76±.35 1.22±.13 2.44±.06 5.43±.51 .65±.04 .42±.08 1.07±.0711.7±1.0 1.04±.04 0.20±.0.01 .96±.09 1.41±.24
blank QH20 4.7

needed to redo to adjust the final volume of py in GC vial!!

st8 2 vessels connected to each other for digestion & used 300watts for the microwave

by Lynne
seawate microw
r FR2 ave V
Station vol (L) vol (ml) date of anaysis N (ul) VAL VON VAD SAL SON SAD CAD FAD
1-000-pre 20 5.6 9/6/2007 600 1.05 0.43 0.66 2.34 0.67 0.22 1.14 1
600 0.86 0.39 0.57 2.21 0.66 0.69 1 0.9
1-40m 20? 8.7 9/6/2007 600 1.09 0.42 0.81 2.86 0.86 0.05 1.28 1.24
600 1.18 0.87 0.94 5.72 1.75 2.09 2.38 1.67
1-200-pre 15 5.6 9/6/2007 800 0.71 0.55 0.85 3.04 0.87 0.29 1.48 1.3
800 0.77 0.51 0.74 2.87 0.86 0.89 1.3 1.17
2-000-pre ? 3 8/29/2007 500 0.53 0.18 0.29 0.41 0.46 1.1 0.73 1.69
500 0.76 0.2 0.36 0.34 0.18 2.39 0.63 1.55
2-1000-pre ? 3 8/29/2007 600 0.53 2.11 0.22 0.27 0.25 5.32 0.65 3.34
600 0.36 3.24 0.27 0.34 0.25 5.22 0.61 3.56
3-000-pre 20 5.2 8/22/2007 600 1 0.85 0.61 3.33 1.3 1.2 1.34 1.31
600 1.17 2.37 0.67 4.74 1.29 2.61 1.37 3.03
3-200-pre 20 8.3* 8/22/2007 600 0.47 0.62 0.52 1.58 0.56 1.26 0.64 1.51
600 0.48 0.5 0.41 1.5 0.51 1.18 0.63 1.33
4-000-pre 20 8.4 10/9/2007 600 0.94 0.73 0 0.47 1.47 1.63 1.06 2.13
600 0.93 0.65 0 0 1.26 1.52 1.08 2.13
4-065-pre 20 5 8/17/2007 600 1.34 1.57 0.63 0.59 1.11 1.88 1.15 2.53
600 0.55 0.46 0.47 0.47 0.45 0.58 0.82 3.2
5-000-pre 20 3 10/3/2007 500 1.3 1.04 1.07 1.47 1.31 1.76 1.9 1.6
500 1.17 0.79 0.77 1 0.95 1.23 1.24 1.18
20 3 10/11/2007 300 1.19 0.74 0.58 0.48 1.45 1.5 0.96 2
5-043-pre 20 5 10/3/2007 500 2.14 1.65 1.38 1.58 1.66 2.8 1.92 1.94
500 1.56 1.54 1.16 1.48 2.14 2.43 2.03 1.18
6-000-pre 20 3.5* 8/14/2007 200 2.51 1.38 2.28 1.23 1.5 1.33 1.66 2.39
200 3.22 1.82 2.89 1.44 1.85 1.72 1.89 2.57
7-000-pre 20 8.3 10/8/2007 400 2.34 1.9 2.19 0.93 2.24 1.61 1.29 2.27
400 1.68 1.42 1.57 0.68 1.53 1.28 0.91 1.94
8-000-pre 20 4* 10/9/2007 300 1.89 0.88 0.21 0.64 2.17 1.83 0.89 0.98
300 2.07 1.09 0.4 0.77 2.74 2.53 1.11 1.8
9-000-pre 20 <6 12/14/06 (12/13)
10-000-pre 20 5.4 8/14/2007 600 1.53 0.26 0.82 3.32 1.23 1.15 0.89 2.08
500 1.65 0.28 0.83 3.42 1.33 1.22 0.88 2.06
10-026-pre 20 4.9 8/14/2007 600 1.86 1.3 1.04 0.68 1.44 1.35 0.78 1.95
600 1.03 2.43 0.58 1 3.03 2.98 1.44 1.66
11-000-pre 20 5.5 8/7/2007 200
200
11-026-pre 20 5.5 8/7/2007 200
200
12-000-pre 20 5*
12-019-pre 20 5.5
7p-000-pre 20 <8 10/8/2007 400 1.54 0.81 1.43 0.58 1.44 1.16 0.73 1.43
400 2.26 1.21 1.89 0.79 2.16 1.51 1.01 1.98

by tammi

Lignin-derived phenols MARS/ GC analysis

MAB Cruise Sept. 2005 Each run digested individually
C18 SPE extractions FR2
units (ng/uL) VAD/VAL SAD/SAL
GC (Digestion) FR2
seawater FR2 vol (ml) total lignin
Station vol (L) vol (ml) N used VAL VON VAD V SAL SON SAD S CAD FAD C (Λ) S/V C/V [Ad/Al]v [Ad/Al]s
1-000-pre 20 5.6
1-200-pre 15 5.6
1-integrated 20? 8.7

Prepared by rdv 10/17/2008 Page 6

 9169764.xls

2-000-pre ? ?
2-1000-pre ? 3
3-000-pre 20 5.2
3-200-pre 20 8.3*
4-000-pre 20 8.4 2/2/07(2/1)
4-065-pre 20 5
5-000-pre 20 ?
5-043-pre 20 5
6-000-pre 20 3.5* 1/19/07 (1/17) 3 200 3.99 3.14 3.16 3.52 2.69 4.95 1.1 1.02
200 4.02 3.28 3.12 3.52 2.67 4.59 1.13 1.15
200 3.99 3.19 3.08 3.75 2.63 4.52 1.17 1.17
7-000-pre 20 8.3 1/19/07 (1/18) 3 200 4.78 3.43 4.22 4.88 3.87 5.23 1.43 1.22
200 4.65 3.55 3.83 4.37 3.49 5.13 1.52 1.51
200 4.07 3.05 4.1 4.17 3.67 4.73 1.5 1.56
connected 200 4.91 3.76 3.95 4.85 3.45 4.74 1.29 1.03
200 4.99 3.41 3.76 5.42 3.71 5.27 1.33 1.15
8-000-pre 20 4* 1/10/07 (1/8-10) 3 200 5.14 3.82 5.27 5.02 3.95 5.57 1.64 1.5
200 5.38 4.18 4.53 4.9 3.81 6.1 1.74 1.44
200 5.62 4.44 4.79 4.89 4.21 6.84 1.98 1.85
1/10/07 (1/9) 2 200 4.66 4.07 5.9 4.17 3.77 6.84 1.71 1.24
200 5.32 3.69 4.24 4.7 3.79 5.76 1.52 1.26
9-000-pre 20 <6 12/14/06 (12/13) 2 196 4.12 3.29 3.94 3.41 2.32 3.93 1.35 0.75
196 4.18 3.19 3.71 3.61 1.88 4.2 1.13 0.71
10-000-pre 20 5.4
10-026-pre 20 4.9
11-000-pre 20 5.5 1/25/07 (1/22) 3 400 2.71 2.43 2.28 1.91 1.52 2.7 0.66 0
400 2.69 2.5 2.23 2.04 1.37 3.23 0.8 0
400 3.38 2.51 2.33 2.02 1.39 3.31 0.71 0
11-026-pre 20 5.5 2/8/07 (2/5) 2 600 3.54 3.72 3.51 2.26 1.54 4.34 1.22 0.41
600 3.46 3.43 2.94 2.07 1.34 3.79 0.87 0.46
12-000-pre 20 5* 1/25/07 (1/23) 3 400 3.79 3.18 3.17 2.9 2.27 4.41 1.1 1.84
400 4.35 3.4 3.64 3.35 2.51 5.17 1.25 0.97
400 4.6 3.37 3.5 3.36 2.29 5.61 1.11 1.24
12-019-pre 20 5.5 2/8/07 (2/7) 2 600 4.33 4.17 4.13 3.07 2.89 5.98 1.25 1.89
600 4.7 3.69 3.81 3.58 2.83 5.74 1.17 1.57
7p-000-pre 20 <8 12/14/06 (12/11-12)3 200 5.5 3.91 4.74 5.41 3.44 6.16 1.63 1.26
200 4.35 3.28 4.22 3.88 2.8 5.91 1.54 0.99
blank QH20 4.7

needed to redo to adjust the final volume of py in GC vial!!

st8 2 vessels connected to each other for digestion & used 300watts for the microwave

Prepared by rdv 10/17/2008 Page 7

Lignin-derived phenols MARS/ GC analysis
MAB Cruise Apr. 2006
C18 SPE extractions FR2
units (µg/L)
GC
seawater FR2 Analysis
Station vol (L) vol (ml) Date N VAL VON VAD V
1-000-pre 20 4.89
1-200-pre 20 4.78
4-000-pre 20 5.34
4-065-pre 20 4.97
5-000-pre 20 4.9
5-043-pre 20 5
10-000-pre 20 4.94
10-026-pre 20 4.95
11-000-pre 20 4.99
11-020-pre 20 4.99
12-000-pre 20 4.92
12-018-pre 20 4.99
b1-28-000-pre 20 4.91
b1-14-000-pre 20 4.95
b2-2-000-1 20 5*
b2-2-000-2 20 5.07
b3-0-000-1 20 5.07
b3-0-000-2 20 4.96

needed to redo to adjust the final volume!!

 total lignin
SAL SON SAD S CAD FAD C (Λ) S/V C/V
VAD/VAL SAD/SAL

[Ad/Al]v [Ad/Al]s
Lignin-derived phenols MARS/ GC analysis
MAB Cruise Apr. 2006
C18 SPE extractions FR2
units (µg/L)
GC
seawater FR2 Analysis
Station vol (L) vol (ml) Date N VAL VON VAD V
1-000-pre 20 4.398
1-017-pre 20 4.218
2-000-pre 20 4.199
2-026-pre 20 4.199
4-000-pre 20 4.348
4-075-pre 20 4.298
7-000-1-pre 20 2.215
7-000-2-pre 20 4.298
7-1000-1-pre 20 4.247
7-1000-2-pre 20 4.137
8-000-pre 20 4.226
8-200-pre 20 4.108
10-000-pre 20 4.327
10-035-pre 20 4.284
11-000-pre 20 4.218
11-025-pre 20 4.199
12-000-pre 20 5.399
14-000-pre 20 6.643
16-000-1-pre 20 4.624
16-000-2-pre 20 5.610
19-000-1-pre 20 5.395
19-000-2-pre 20 5.447
20-000-pre 20 7.925
21-000-pre 20 4.994
seater vol check!!
 total lignin
SAL SON SAD S CAD FAD C (Λ) S/V C/V
VAD/VAL SAD/SAL

[Ad/Al]v [Ad/Al]s
Station FR2 volume
101206-B28 5.1
101206-B28B 5.5
101306B26 9.2
101306B26A 9.54
101406MB-A 9.1
101406MB-B 9.25
101406UB-A 10.29
101406UB-B 9.54
101506-B0A 20.84
101506-B0B 10.98
1-1000 3.2
2-000 4.2
2-200 5.1
3-000 6.2
3-030 4.24
4-000 6.26
4-025 6.2
5-000 2.3
5-111 4.2
6-000 6.39
6-021 4.2
7-000 6.4
7-020 4.34
MAB1206

Station # Depth Fr2 Added

2 0 400
2 50 400
3 30 (R1) 500
3 30 (R2) 500
4 20 (R1) 500
4 20 (R2) 500
6 0 500
6 15 500
7 0 (R1) 300
7 0 (R2) 300
8 0 (R1) 300
8 0 (R2) 300
9 0 500
9 20 500
11 0 (R1) 400
11 0 (R2) 400
13 0 300
14 0 (R1) 400
14 0 (R2) 400
MAB Cruise Date Station # Depth FR2 Added
MAB0806 19 0 200
MAB0806 8 0 400
MAB0806 11 surface 300
MAB0806 11 deep 300
MAB0905 11 surface 300
MAB0905 11 deep 300
MAB0905 6 0 100
MAB0905 7 original 100
MAB0905 8 0 50
MAB0905 9 0 100