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QUALITY :

See end of document.

TS :
Approved datasheet for soft rubber lining : KERABUTYL BS - 6mm.
KERABUTYL BBS was not submitted for review to JESA.
07.10.2022 LT/BB/ HT/SS/YB/
HSE: MM/MA KE
Inadequate risk assessment :
1. The risk assessment is global and not evaluating the hazards associated with the work method
statement (ex: using physical risk as a designation of the risk and “use safe working method as and
action ” also provide the required PPE )
2. The risk and action must be specific as the activities is specific and also actions required
Lack of emergency response plan related to the activity

DAP units 107 D, 107 E & 107F

DOCUMENT HISTORY & REVISION

10

19/09/2022 Modified revision - JESA Comments Y.MOHAMMADI I.JAOUAD 1

22/06/2022 First edition Y.MOHAMMADI I.JAOUAD 0

Description - Revision Subject Prepared by Checked by Approved by Rev

DOCUMENT DESCRIPTION & REFERENCES

CLIENT NAME: OCP

PROJECT LOCATION : JORF LASFAR MAROC

PROJECT DESCRIPTION : DAP 107DEF

JE PROJECT NUMBER Q3510

PURCHASE ORDER REFERENCE : 4500001316/1317

REQUISITION REFERENCE :

OTHER REFERENCE (tag, unit) :

DISCIPLINE DOCUMENT TITLE

CONSTRUCTION Work Method Statement for Rubber lining - Tail gas scrubber & Stack

VENDOR Document Number

Q3510-00-SCIFCMI-4500001316/1317-Z-Z01-0024

JESA Document Number


Imm. 5 - Zénith Millenium - Lot. Attaoufik Route Nouaceur - Sidi Mâarouf Casablanca
- 20270 Tél: +212 (0)5 22 87 70 00 / +212 (0)5 22 87 71 50 Fax: +212 (0)5 22 87
72 34
Q3510-00-SCIFCMI-4500001316/1317-Z-Z01-0024

CLIENT Document Number ( if applicable)


JESA
Imm. 5 - Zénith Millenium - Lot. Attaoufik Route Nouaceur - Sidi Mâarouf Casablanca - 20270 Morocco Tél: +212 (0)5 22 87 70 00 / +212 (0)5 22
87 71 50 Fax: +212 (0)5 22 87 72 34

HELP
JESA DOCUMENT NUMBERING SYSTEM Project Nbre Code of Sub-Project Sender Code PO Discipline Code Doc Type Number Order / Rev
Please Refer to Annex Q, L & DC
Procedure . Shall you need help to fill-in
this cover page, please contact JESA
Example (Trigram is unique to each contractor) Q3510 00 SCIFCMI 4500001316/1317 Z Z01 24 01
Project :
Rubber Lining - Tail Gas Scrubber & Stack
ISBL DAP - JORF LASFAR
Contract No.:
SCIF-15762

METHOD STATEMENT
RUBBER LINING
WITH KERABUTYL BS
Tail Gas Scrubber & Stack
PROCEDURES & SEQUENCES
Rev. 1.1

GREAT SKILLS AND GREAT ACQUIRED KNOW-HOW


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

CONTENT

A PURPOSE AND SCOPE

B PRODUCT DESCRIPTION

C EXECUTION PROCEDURES

D THE PROCEDURE SEQUENCES

E TOOLS AND EQUIPMENT

F QUALITY CONTROL

G HEALTH, SAFETY, ENVIRONMENT


RISK IDENTIFICATION
RISK PREVENTION
GENERAL SAFETY PRECAUTIONS

ANNEXES

STEULER FORMSHEET-020
DATA SHEETS
APPLICATION INSTRUCTIONS

Ref. : STEULER-SCIF-MST01 1 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

A PURPOSE AND SCOPE

 this document defines the procedures for Rubber Lining with KERABUTYL BS, as part
of the project:

Project :
Rubber Lining - Tail Gas Scrubber & Stack
ISBL DAP - JORF LASFAR
Contract No.:
SCIF-15762

Location: PROJET DAP - JORF LASFAR

 The experienced STEULER supervisors intervene with their know-how and provide

advice and support by adopting the latest coating application methods for the

success of the procedure described in this Method statement.

 The execution procedures of this document are described as precisely as possible,


but cannot cover all variations in field conditions.

 Therefore, experienced STEULER supervisors can sometimes give advice that is

slightly different from the published procedures, in order to ensure a better

installation adapted to the specific conditions of the field and in accordance with the

technical specifications of the project.

 All work performed must comply with Customer specifications, as well as


compliance with STEULER solutions and specifications.

Ref. : STEULER-SCIF-MST01 2 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

B PRODUCT DESCRIPTION

1. TECHNICAL INFORMATIONS,
2. APPLICATION INSTRUCTIONS, MSDS:
Please refer to the following data sheets:

• KERABUTYL BS
• VULCOFERRAN 2194
• KERATEX PRIMER
• SOLUTION BS

3. SHELF LIFE
 Shelf life is the length of time after manufacture that the materials are guaranteed for use.
 Each batch indicates the number and date of manufacture.
 Check the product data sheet and / or label to make sure any new materials are still within the
shelf life.
 Our supervisor should contact STEULER if materials outside the shelf life are found.
 If the expiration date has passed, STEULER will supply new materials with a valid shelf life.
 In this case, STEULER will properly demobilize the expired materials.

4. PREPARATION

 All liquids must be stirred well before being decanted or mixed with other binding components
hardeners, accelerators, inhibitors, powders or others...
 The Shelf life depends on the temperatures of the components and the environment.
 Requirements such as standby times, drying times, pot life must be strictly observed.
 For more details on the application, please refer to the technical information and typical
application instruction sheets attached.

Ref. : STEULER-SCIF-MST01 3 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

C EXECUTION PROCEDURES
4
1.1 TYPICAL SCHEMA - KERABUTYL BS 3

STEEL SUPPORT
1 PRIMER Layer on sandblasted Support

2 BS Solution (adhesive) layer on Support

3 BS Solution (adhesive) layer on the KERABUTYL BS SHEET

4 KERABUTYL BS SHEET

1.2 TYPICAL BUILT

Hard RUBBER Plate

KERABUTYL BS 6mm

Ref. : STEULER-SCIF-MST01 4 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

2 SUPPORT INSPECTION

 Inspect and analyze the substrate to be coated


 The support must meet the standards and requirements in accordance with the STEULER-
FormSheet-20 for the steel support, or the STEULER-FormSheet-10 for the concrete support
(attached).
 Perform a media condition analysis using the STEULER-003 control protocol

Ref. : STEULER-SCIF-MST01 5 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

3 SURFACE PREPARATION
 The substrate must be pre-treated in order to get rid of loose and friable particles, structural
defects and release agents.
 The substrate or surface to be coated requires 100% brushing, sanding or sandblasting in
order to get rid of rust debris, encrustation and all other impurities.
 preparation is an important step and plays a key role in the application of the coating.
 A good preparation will promote the cohesion of the coating used and will guarantee the anti-
corrosion protection of the structure over time.
 During installation work, the relative humidity should not exceed 70%.
 The temperature of the substrate can be between 10 ° C and 35 ° C (relevant for all jobs) at a
dew point distance of at least 5K.
 The temperature and climate data recording document will be available on site and will be
provided on request.

4 APPLICATION OF THE PRIMER


 Surfaces prepared by sandblasting must receive a primer on the same day, either by brushing
or spraying with KERATEX Primer.
 The Product should be applied at optimum temperatures between 15 and 35 ° C.

 Waiting time:
The waiting time between the different coats depends on the temperature and is:
at 20°C - maximum 48 h
The maximum waiting time until the application of the next coat
(for example KERATEX primer) is 24 hours at 20 ° C.

Ref. : STEULER-SCIF-MST01 6 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

5 PRIMER LAYER INSPECTION


 Perform visual checks to check the correct application of the PRIMER Layer, thus the
absence of any defects
 Check if the Primer products have been applied effectively over the entire surface to be
coated.
 Perform a substrate condition analysis after the PRIMER layer using the STEULER-005a
control protocol.

Ref. : STEULER-SCIF-MST01 7 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

6 APPLICATION OF THE ADHESIVE LAYER BS


 Clean the KERABUTYL BS sheets thoroughly with KCH-Cleaner 1 using linen cloths and
change them frequently.
 Apply the adhesive layer Colle-BS/ KERATEX Solution to the KERABUTYL BS rubber
sheet.
 Apply two coats of adhesive BS to both the substrate and the KERABUTYL BS rubber
sheet.

7 COATING APPLICATION: KERABUTYL BS

 Product Description KERABUTYL BS:


• Soft rubber for the protection of steel structures.
• Protective waterproofing membrane for concrete structures with approval certificate No.
Z.59.21-64 from the Construction Control Institute.
 Utilisation:
• KERABUTYL BS is used to protect steel and concrete structures which are exposed to
chemical attacks.
• It is mainly used in absorbers, ducts, storage and feed tanks in flue gas desulfurization units
as well as in other gas purification units. Run times of over 100,000 hours have been
achieved with KERABUTYL BS.
• KERABUTYL BS is used as a waterproofing membrane in wells, sumps and containments
and as a waterproofing layer under ceramic slabs.
• In addition to its resistance to a wide range of chemicals, KERABUTYL BS has good
mechanical properties.
• KERABUTYL BS enjoys the advantages of pre-vulcanized rubber, such as easy storage
and transport without refrigeration for at least 24 months.
• KERABUTYL BS can be exposed to attack immediately after installation without
vulcanization being necessary.

Ref. : STEULER-SCIF-MST01 8 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

 Application:
 Layer thickness to apply : According to Client requirements from 2mm to 6mm

 Instructions:

 For a secure application, the indications on the labels, the instructions for use as well as
the information contained in the safety data sheets must be observed.
 KERABUTYL BS sheets should be thoroughly cleaned with KCH-Cleaner 1 using linen
cloths and changed frequently.
 Apply the adhesive BS / KERATEX Solution layer to the KERABUTYL BS rubber sheet.
 Apply the adhesive BS / KERATEX Solution layer as well on the support.

 Gluing of the KERABUTYL BS sheets:

 After respecting the Application Instructions and the prescribed waiting times, apply the
rubber sheets without tension with light support of the hand.
 For a smooth surface, run a rubber roller of approx. 30mm wide on the rubber sheet.
 Roll a roll with rounded edges over the joints, corners and edges (3 mm).

8 INSPECTION OF THE KERABUTYL BS COATING


 Perform visual checks to check the correct application of the KERABUTYL BS coating, thus
the absence of any defects
 Check if the coating has been carried out effectively on the entire surface to be coated.
 visually check the coating for recognizable defects such as e.g. bubbles (blisters), pockets,
bumps, tears, or mechanical damage

Ref. : STEULER-SCIF-MST01 9 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

9 INSPECTION REPORT UPON COMPLETION

Ref. : STEULER-SCIF-MST01 10 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

D THE PROCEDURE SEQUENCES

1 First Assembly of the elements as shown in the following schema

Part 7

Part 6

Part 5

Part 4

Part 2/1

Part 1

2 Rubber lining of the first assembly (By STEULER):


2.1 Installation & Inspection of the internal scaffolding
2.2 Support Preparation by Sandblasting
2.3 Primer application
2.4 Application of adhesive BS-solutions
2.5 Application of KERABUTYL BS rubber sheets
Ref. : STEULER-SCIF-MST01 11 Revision : 1.1 - Date : August 2022
METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

THE PROCEDURE SEQUENCES


3 Rubber lining of the Stack (By STEULER):
3.1 Support Preparation by Sandblasting
3.2 Primer application Stack
3.3 Application of adhesive BS-solutions
3.4 Application of KERABUTYL BS rubber sheets

4 Assembly of the Rubber Lined Stack as shown in the following schema


4.1 The lower part of the Stack will be installed and bolted to the first assembly with Hard
RUBBER plate.

Stack
HARD RUBBER PLATE

Part 7

Part 6

Part 5

Part 4

Part 2/1

Part 1

Ref. : STEULER-SCIF-MST01 12 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

THE PROCEDURE SEQUENCES


5 Formation of the joints:
5.1 Joints are formed as shown in the following drawing (Figure 1)
5.2 Bevel on bevel overlap for sheets (KERABUTYL BS)
5.3 The pointed end of the bevel overlap should be placed so that it does not oppose the direction
of the flow..

Figure 1

5.4 Installation of a joints cover (width 10 cm) with KERABUTYL BS.

N.B For more details, see the Technical Data Sheets and Application Instructions attached to this
Method Statement.

Ref. : STEULER-SCIF-MST01 13 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

E TOOLS AND EQUIPMENT

For the installation of the coating systems, special installation equipment, measuring devices,
specific tools and consumables are required.
STEULER provides all the tools, Manpower, site services and associated equipment, which are
necessary for the support coatings:

General, but not limited to:

 ELECTRICITY, WATER
 COMPRESSOR
 APPROPRIATE LIGHT FOR INSTALLATION
 MANUAL TOOLS FOR REMOVING PACKAGING MATERIALS
 TROWELS, JOINT TROWELS AND FLOATS
 ROLLERS AND BRUSHES
 MARKING CHALK
 WHEELBARROW
 LEVELING INSTRUMENT
 ALL THE NECESSARY CARPENTER TOOLS
 ALL NECESSARY SMALL CLEANING TOOLS
 HAND SAW
 MIXERS
 BUCKETS AND BUCKS / MEASURING CUPS
 aspirator
 ALL TYPES OF PERSONNEL PROTECTIVE TOOLS SUCH AS GLOVES ETC.
 BLASTING EQUIPMENT
 TILE CUTTING MACHINE
 RIGHT ANGLE GRINDING MACHINE WITH SUITABLE CUTTING AND GRINDING
BLADES
 RUBBER KNIVES AND ROLLERS
 SMOOTHING TOOL
 PAINT ROLLER
 BRUSH

Ref. : STEULER-SCIF-MST01 14 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

F QUALITY CONTROL

1. SUPPORT / SUBSTRATE REQUIREMENTS

• Refer to DIN EN14879-1 as well as to STEULER 020 form.

• 100% of the steel surface must be pre-sanded to SA 2,5 readiness.


• During installation work, the relative humidity should not exceed 70% (relevant for priming and

sandblasting work) or 80% (relevant for rubber coating work) or 70% (relevant for work coating of

bricks).

• The substrate temperature can be between 10 ° C and 35 ° C (relevant for priming and

sandblasting work) or 15 ° C and 35 ° C (relevant for rubber coating work) or 10 ° C at 35 ° C

(relevant for brick cladding) at a dew point distance of at least 5Km.

• The temperature and climate data recording document will be available on site and will be

submitted upon request.

• Before applying the Primer coat, the sanded surface should be cleaned thoroughly, the preferred

method is with vacuum cleaners.

• To achieve sufficient adhesive tensile strength, the substrate should generally be pre-treated so

as to be free from cement slurry, cement skin, loose and friable particles, structural imperfections

and release substances.


• We recommend preparation by sweeping or milling, smaller areas can be prepared by grinding.
• During application, the substrate must be kept consciously dry, also against moisture

condensation, if the relative humidity falls below dew, the condition of the substrate must be

checked and documented regularly.

• The repair of the substrate if necessary, and the coating must comply with DIN EN 14879-1 as

well as with the sheet STEULER-Form 010 / STEULER-Form 020

Ref. : STEULER-SCIF-MST01 15 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

2. QUALITY CONTROL AND TESTS


 As a general rule, permanent quality control should be considered during all phases of all coating
work.
 A detailed and approved inspection and test plan (ITP) will be the basic document for the control
of the coating work. For more details, please consult the Inspection and Test Plans (ITP),
 The associated test and control protocols are listed in the ITPs and are attached to this
document.

 The system should be inspected in the following steps:

 Upon receipt of the material:


 Check that the materials received at the site are the same as those approved or specified.
 These checks should include verification of labels, delivery receipts, dimensions, etc.
 Unspecified, unapproved or damaged materials should be removed from the site.
 Before applying the materials:
 make sure that the storage of the materials will protect them from damage caused by
humidity, wind or other atmospheric factors.
 Application in progress:
 make sure that the specified materials are used during application.
 Make sure these materials are applied according to specifications and application
instructions.
 Final inspection:
 Make sure the coating is properly applied, as well as the sealant on all joints, surface finish,
etc….
 on the outer surface. No cracks / voids / gaps should be visible on the surface.

3. REPAIR
In the event of repair of installed coating systems, for example due to damage to coating systems,
repairs should be carried out following the instructions and advice given in the material data sheets
and application instructions.
Depending on the individual repair case, STEULER is entitled to decide on a case-by-case basis the
individual repair method to be undertaken.

Ref. : STEULER-SCIF-MST01 16 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

G HEALTH, SAFETY, ENVIRONMENT


 The principles of the STEULER concerning health, safety at work and environmental
protection comply with contractual annex S, and give high priority to the protection of life and
health at work and aim to prevent physical injury and psychological damage to people during
work.
 These STEULER principles also aim to continuously improve safety and health protection at
work as well as environmental protection.
 STEULER will respect these principles during the execution of the project.
 In this context, it is about the safety of all its employees including the subcontractors, visitors
and other people who work on behalf of STEULER MAROC for the project.
 In addition, the protection of the environment and the economic use of resources are
pursued as a central objective..
 In all works, negative effects on the environment must be minimized.
 Any violation of HSE rules will be penalized.
 These regulations are binding on all employees (including subcontractors) who are
responsible for fulfilling delivery and service obligations.

For more details, please refer to the following documents:

 STEULER HSE policies


 HSE PLAN
 Risk analysis - Brick cladding
 Risk Analysis - Rubber Coating
 Scaffolding procedure
 Sandblasting procedure
 Waste Management

Ref. : STEULER-SCIF-MST01 17 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

RISK IDENTIFICATION

N° RISKS Presence DESCRIPTION


YES NO
01 The risks of traffic X  circulations and displacements inside the factory
and displacements  missteps, trips, bumps,
 Height falls
 collisions of people with machinery or handling
equipment
 falling objects
02 The risks of manual and X  risks associated with the use of handling equipment
mechanical handling  manual handling of loads
 Transport or support of a load, by one or more
employees
 carrying or moving a load
 Hitting or colliding with gear or equipment
03 Physical risks X the use of professional machines or equipment (press,
tools, saw, various equipment, including knives, cutting
machines, ovens ...)
the use of additional equipment (scaffolding, ladder,
stepladder, ...)
04 Electrical risks X the risk of contact, direct or not, with a naked live part, the
risk of short-circuit, and the risk of electric arc ...

05 Risk of fire and explosion X Presence of products:


 Fuel: capable of burning itself (construction material,
wood, petrol, etc.),
 Oxidizer which, by combining with the fuel, allows
combustion (oxygen, air, etc.)
 Ignition source that will trigger the combustion reaction
(electricity, open flame, cigarette, etc.).
06 Chemical risks X All dangerous situations involving chemicals, under
conditions of use and / or exposure.

07 Confined spaces X the risks generated by an oxygen-depleted, toxic or


explosive atmosphere are very real, and are added to
other serious risks such as those from falling from a height

08 Work at height X Falls can occur from:


 roofs, frames, building terraces…
 means of access to elevated areas: ladders, stairs,
walkways ...
 pylons or other work equipment (scaffolding, tanker
truck, etc.)

These accidents occur in all sectors of activity

Ref. : STEULER-SCIF-MST01 18 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

RISK PREVENTION
N° RISKS PREVENTION ACTIONS ENVISAGED
01 The risks of traffic  Respect the OCP security instructions
and displacements  Delimit traffic areas

02 The risks of manual and  Adequate means of communication between the crane operator and the
mechanical handling supervisor
 Signaling, marking and surveillance of the handling field
 Use of correct handling accessories, in good condition and within
standards
 The lifting means (hoist, strong shot ...) must have regulatory control
certificates issued by an organization approved by the state.

03 Physical risks  Use safe working methods


 Training workers: work methods, safety risks, use and maintenance of
PPE
 Provide the required PPE and ensure that it is used, maintained and
stored properly

04 Electrical risks  Isolate accessible live components


 Use compliant electrical equipment installed in accordance with
standards
 Use insulated tools and equipment, fuse handling equipment and
protective screens
 Reduce the accumulation of electrostatic charges by earthing
 Display the presence of equipment and power lines and the risks
associated with them
 Establish safety perimeters during electrical work
 Develop and implement an electrical safety program
 Train workers on the electrical safety program and on safe working
methods
 Restrict access to electrical equipment
 Provide the required PPE and ensure that it is used, maintained and
stored properly

05 Risk of fire and explosion  Ensure adequate ventilation of the premises


 Install alarms (e.g. alarm, poster, safety data sheets or product data
sheets)
 Use safe working methods
 Train workers on safe working methods, health and safety risks, and
emergency measures plan
 Maintain the premises to avoid the accumulation of flammable products
on surfaces and ventilation ducts
 Store flammable products according to standards
 Provide the required PPE and ensure that it is used, maintained and
stored properly

Ref. : STEULER-SCIF-MST01 19 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

N° Risques Actions de prévention envisagées


06 Chemical risks  Provide adequate ventilation
 Display the procedures to be followed (e.g. start ventilation before
starting the task)
 Use safety data sheets or material safety data sheets and labels
 Use safe working methods
 Ensure equipment and containers are in good condition to prevent
leaks, spills and emissions
 Maintain the premises to avoid the accumulation of contaminants on
surfaces and in the ventilation system
 Plan emergency measures, including the installation of emergency
equipment (eye showers, emergency showers and fire extinguishers),
an evacuation plan and the
 Presence of rescuers
 Provide required PPE and ensure it is used, maintained and stored
properly

07 Confined spaces  Make sure to respect the regulations and standards in force for confined
spaces
 Install adequate ventilation
 Use a gas detection system before entering confined spaces
 Install alarms (e.g. alarms, posters)
 Develop and implement a confined space management program
including entry permits
 Provide continuous monitoring, put in place a rescue procedure and
lockout procedures
 Train workers on the confined space management program, safe
working methods, lockout procedures and health and safety risks
 Provide required PPE and ensure it is used, maintained and stored
properly

08 Work at height  Plan a maximum of ground operations to reduce the workload carried
out at height
 make sure that the climatic conditions allow you to work in complete
safety (thunderstorm, strong winds, frost, extreme temperatures ...)
 ensure that the agent has no contraindications for working at height.
 the establishment of collective protection aimed at preventing falls.
 Master the regulations regarding the use of ladders, scaffolding,
nacelles, etc.
 Give appropriate instructions to workers
 Provide required PPE and ensure it is used, maintained and stored
properly

Ref. : STEULER-SCIF-MST01 20 Revision : 1.1 - Date : August 2022


METHOD STATEMENT
RUBBER LINING - TAIL GAS SCRUBBER & STACK

GENERAL SAFETY PRECAUTIONS


 All workers must wear an appropriate uniform, hard hat and hand gloves when on duty,

 Do not enter any work area or equipment without proper authorization,

 The materials used in the factory like chemicals are very expensive and dangerous, make sure

there is no spillage and waste.

 For handling chemicals, workers should use face shield and goggles,

 Mix and apply material only in well ventilated areas.

 Provide adequate ventilation for conditions when working in pits or tanks.


 It is strictly forbidden to smoke in the work areas,

 Do not expose materials to heat or open flame.

 Do not carry out any welding work near the actual work area (weld seams).

 Avoid contact with skin or eyes, Wash hands with soap and water, do not clean the skin with

solvents, Use barrier soap and protective creams on exposed skin areas.

 In all other respects comply with the regulations in force for the prevention of accidents.

 Refer to material safety data sheets.

 Report any abnormal condition, anomalies or incidents to your HSE manager.

Ref. : STEULER-SCIF-MST01 21 Revision : 1.1 - Date : August 2022


STEULER-FormSheet
Form Sheet 020
Issue 09/2019
Specification for Steel Vessels
to be Acid Brick Lined

The basis for this Specification for Steel Ves- ing beads from vessel welding work or
sels to be Acid Brick Lined are the following grooves from plate joints not re-welded inside
standards and guidelines: the vessel).
DIN EN 14879 Immediately prior to start of the acid-resistant
lining, the steel surfaces must be sandblasted
Organic coating systems and linings for pro- down to white metal. The sandblasting has to
tection of industrial apparatus and plants be coordinated with the start of the installation
against corrosion caused by aggressive me- work, since the steel substrate surfaces need
dia to be primed directly after sandblasting.
DIN EN 14879-1 Admissible dimensional tolerances of round
steel vessels to be lined with acid-resistant
Terminology, design and preparation of sub-
brick are specified in DIN EN 14879-6. Ac-
strate. Issue: December 2005
cording to this standard, roundness of the
Replaces DIN 28051 and 28053 vessels is to be determined by measuring the
radii. After the vessels have been placed in
DIN EN 14879-6 their final position, the radii in their cylindrical
Combined linings with tile and brick layers; section must not deviate by more than ± 0.4%
Issue: April 2010 from the mean value.
Replaces DIN 28060 Deviations in measurements are to be
checked acc. to Test record 002 and/or 001
DIN EN ISO 12944-4 (latter applicable to plane, rectangular ves-
sels).
Paints and varnishes; Corrosion protection of
steel structures by protective paint systems; Please manufacture nozzles only after our de-
Types of surface and surface preparation Is- tailed drawings have been made available.
sue: April 2018
Any damages due to non-observance of these
requirements are beyond our responsibility.
1 Requirements for the lining of steel
vessels 2 Requirements to be met by steel
The following requirements have to be met by
substrates
steel substrates to be lined in order to ensure
durability of the acid resistant lining. 2.1 The structural elements to be protected must
be designed and manufactured that they do
The steel vessels have to be designed and not require any subsequent correction work
provided in a statically correct condition. After after being provided with a surface protection.
installation of the acid resistant brick lining no Their dimensions and individual weights must
deformations or deflections are allowed comply with the possibilities of the surface
caused by the weight of the brick lining, ther- protection. The substrates to be protected
mal expansion, pressure, vessel contents and must be easily accessible.
operating conditions etc.
All connections, transitions, etc. must be de-
Steel vessels must be welded liquid-tight. All signed in such a way that the surface protec-
welds where the lining will be applied must be tion can be applied without any discontinui-
ground flush and smooth. Sharp edged transi- ties.
tions at nozzles and vessel edges must be Any work on the structure which might dam-
well rounded. The steel substrate must be age the protective coating must be completed
free from surface irregularities (such as weld- prior to application.

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Formsheet 020 Issue 09/2019

For example, surfaces requiring corrective After sandblasting, the substrate must be pro-
machining after the installation of the corro- tected with a primer to prevent surface oxida-
sion protection system should be executed tion.
properly prior to application of the protective
coating so that an adequate and uniformly 2.6 Corners and edges must be executed and
thick protection is maintained. It is prohibited rounded off neatly acc. DIN EN 14879-1.
to heat up the steel shell from outside (by
welding, soldering) or mechanically deform it
during or after application of the lining.

2.2 The steel substrate must be as new, and free


from irregularities as well as imperfections
such as burrs, welding beads, pores, grooves,
cracks, etc.

2.3 Vessels must be welded liquid-tight. A leak or


pressure test has to be carried out before
starting the lining work.

2.4 All weld seams where the lining has to be


applied must show a continuous solid weld
and ground flush and smooth.

to be ground flush
radius 5 m m at least

wrong

2.5 The steel substrate to be lined must be sand-


blasted prior to start of the lining work. Blast-
ing should be made using pure sharp-edged
grit. Compressed air must be free of water
and oil.

If silica sand is used (prohibited in some


countries), it is to be used only once and must Internal corners have to be re-welded and
not contain any corrosion-developing materi- to be ground as a cove
als such as chlorides, sulphates, etc.
The steel substrate must be blasted to at least
grade Sa 2 ½ and surface metallic grey (tol-
erable rust grade A or B acc. to DIN 12944
Part 4 and DIN EN ISO 8501-1. Rust grade C
has to be discussed and agreed between the
involved parties.
The roughness of the steel surfaces shall
have minimum 50 µm for rubber linings and
minimum 70 µm for coatings.

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Formsheet 020 Issue 09/2019

3 Dimensioning and special struc-


tural design features for vessels to
be brick-lined

3.1 Sheet thickness of the cylindrical shell

When roughly estimating the shell thickness no inside bulging


of cylindrical or spherical vessels, the effect of perm issible
the brick lining may be taken into account as
follows:

3.1.1 For vessels with an outside diameter of up to


3000 mm operating at a pressure of up to 3
bar and an internal temperature of up to
100°C, it is sufficient to design the shell thick-
ness for an additional stress of 25 to
30N/mm².
3.2.3 Flatness
3.1.2 For vessels with an outside diameter of above
3000 mm operating at a pressure of up to 10 The permissible deviation from the flatness is
bar and an internal temperature of up to ± 5 mm with a distance of 900 to 1500 mm
200°C, it is sufficient to design the shell thick- between measuring points.
ness for an additional stress of 30 to
The deviation from one measuring point to the
50N/mm².
next must not exceed half of the maximum
permissible deviation. The bottom must not be
3.2 Flat bottoms resilient on its support.
3.2.1 Standard design grid structure on foundation
3.3 Deflection of the vessel

A deflection of l/1000 may be assumed as an


indicative value when calculating the dimen-
sions of vessel components.

3.4 Vessel heads

3.4.1 When heads are to be brick-lined, they must


be dished and also provide a proper support
for the brick lining.

3.5 Internals and attachments

3.5.1 If forces are transmitted into the steel shell,


adequate reinforcement has to be provided to
take up such forces.
3.2.2 Direct support on foundation is only permitted
in exceptional cases.
Overall support, cavity-free and movement not
restricted.

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Formsheet 020 Issue 09/2019
Example:

grid system reinforcement


The maximum deviation of + 0,4 % or - 0,4 %
may not occur on a shorter distance than 1/16
respectively maximum 1500 mm of the cir-
3.5.2 The forces from internals or nozzles thus cumference. The distance between planes of
transferred into the steel shell must not lead to measuring shall be between 1000 mm and
any virtually measurable extension and 2500 mm. Measurements are necessary at
movements (extension < 0.1 mm). minimum two levels. Measuring points must
3.5.3 Connection of pipes to brick-lined nozzles be beyond welding areas. If for instance a di-
must be made without stresses. Uncontrolla- mensional deviation of + 0,4 % of the mean
ble strains from ladders and/or accessible radius occurs at test point 2 of a test circle,
gangways are not allowed. then the dimensional deviation at the immedi-
ately adjacent test points (test point 1 or test
point 3 or 1/16 division) may not equal - 0,4%;
4 Tolerances of cylindrical vessels it shall be equal to or greater than 0.

4.1 Cylindrical section, tolerances of At each measuring plane, the mean value of
roundness the radii is calculated as follows:

After final erection, the radii in the cylindrical radius1  radius 2  ...  radius16
section must not deviate from the mean value
radius middle 
16
by more than ± 0.4 %; for vessel diameters
above 7500 mm, max. deviation is set to ± 15 The interval between measuring planes is
mm. 1000 to 2500 mm. These measuring planes,
perpendicular to the axis of the vessel, must
In general, the circumference of the meas- be 100 mm away from the weld seams of the
urement circle (U) is to be subdivided into 16 cylindrical sections. At least 2 measuring
equal sections (U/16) to set the measuring planes are needed.
points. Gradual adjustment of the deviation to
the normal circle must at least extend over
1/16 of the circumferential length or have a
length of at least 1500 mm in vessels with a
diameter above 7500 mm.

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Formsheet 020 Issue 09/2019

On each measuring plane, measurements Vertical measuring plane b = 900 to max. 1500 mm

acc. to test record 002 must be carried out.


Location and number of measuring planes: 1 2 3 4
b b b
A
level A
for vessel heights up to
2000 mm: at least 2

100 mm
planes
level B

level C

for vessels heights above


2000 mm: 100 mm B

Vertical measuring plane to be alternated on


and between bracing frame
as specified under a) here
above, and in addition 1
plane per horizontal weld, I II III
max. interval 2500 mm a

Measuring plane 100 mm


below or above weld

c
4.2 Tolerances walls

The permissible deviation from the flatness of


walls is ± 5 mm with a distance of 900 to

c
1500mm between measuring points.
The deviation from one measuring point to the
next must not exceed half of the maximum
permissible deviation. b
b

Section A - B
Horizontal measuring planes at least 2 planes c = 0,9 m to max. 1,5 m
5 Tolerances for flat rectangular ves-
sels

5.1 Flat walls Vessel rim

Maximum deviation from the ideal line of the


vessel wall is ± 5 mm with a spacing between
measuring points of 900 to 1500 mm.

5.2 Flat bottoms

Permissible deviation from the flatness is ± 5


mm with a spacing between measuring points
b b Tensioning wire
of 900 to 1500 mm.
b = 0,9 m to max. 1,5 m
5.3 Sequence of permissible deviations
Horizontal measuring planes at least 2 planes c = 0,9 m to max. 1,5 m

Deviation from one measuring point to the


next must not exceed half of the maximum
permissible deviation. Measurements to be
carried out acc. to test record 001.

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DATA SHEETS
TI 109K Technical Information Surface Protection Linings
Issue 18.09.2019

KERABUTYL BB S
Soft rubber lining to protect steel components

Base
Bromobutyl rubber (BIIR)

Material Group
Workshop rubber linings
On-site rubber lining

Description
Self-vulcanizing soft rubber lining based on bromobutyl rubber (BIIR) for protection of steel components. Depending on the require-
ments, the layer thickness of the rubber sheet can be 2-6 mm.

Use
Rubber is used to protect chemical-loaded steel parts, primarily on absorbers, channels, storage and reservoir tanks in flue gas des-
ulphurisation units, and tanks in the chemical industry. It is also used in the phosphoric acid industry. The coating is also suitable for
use under vacuum.

Properties
The material stands out for its excellent chemical resistance and a high resistance to diffusion, especially to steam.
In addition, it offers all the advantages of a non-vulcanized rubber sheet, such as problem-free application with difficult geometries
and high adhesion to steel substrates.
The rubber coating is bonded to the substrate using an elastomeric adhesive based on butyl rubber. Even at high operating temper-
atures the adhesion is excellent, so that the rubber sheet can be used without problems under vacuum stress.

Physical Data
Property (unit), Test method Value
Density [g/cm³], DIN EN ISO 1183-1, ASTM D 792 1.25 ± 0.02
Tensile strength [MPa], DIN 53504 >5
Elongation at tear [%], DIN EN ISO 527, ASTM C 307 ≥ 300
Peeling strength [N/mm], DIN EN 14879-4 ≥4
max. surface pressure [MPa] 2
Temperature resistance [°C] 110
72057596213923339 • V 9 • en

Shore A hardness, DIN 53505, ASTM D 2240 60 ± 5


Data are mean values
*) The values were determined at 4 mm thick rubber samples.

Chemical Resistance
Information on the chemical resistance properties will be provided on request.

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Technical Information Surface Protection Linings
KERABUTYL BB S │ TI 109K │ Issue 18.09.2019

Substrate
The substrate should have a temperature of approx. 10–30 °C.
Refer to DIN EN 14879-1 as well as to STEULER-KCH-Formsheet 030.
The steel surface shall be sandblasted to a metallic bright finish. A preparation degree of Sa 2 ½ as specified in DIN EN ISO
12944-4 and a roughness grade “medium (G)” as specified in DIN EN ISO 8503-1 must be achieved; minimum surface roughness
Rz = 50 µm. After blasting, the formation of new rust must be prevented by suitable measures, e. g. priming directly.
The condition of the substrate must be documented by STEULER-KCH-Test-Record 003 (Steel) or STEULER-KCH-Test-Record 004
(Inspection of Grit Blasting Works).
During application, the substrate must be kept absolutely dry. Uncured material has to be protected from any kind of moisture (con-
densation, fog, precipitation or other water source).
Large scale objects must be air conditioned.
Requirement during and after blasting and by applying Primer 1
Relative Humidity of air: ≤ 40 %
Requirement for the application of Primer 2, the bonding solutions and during rubber lining
Relative Humidity of air: ≤ 60 %
Dew point distance: ≥5K

Packaging / Shelf life


All components must be stored and transported dry and frost-free. Unless otherwise specified, the minimum shelf life applies to a
storage temperature of 20 °C. Higher temperatures reduce, lower temperatures increase the shelf life. The use of refrigerated con-
tainers should be considered on a project-by-project basis, especially when components are stored at temperatures below 20 °C in
order to extend their shelf life. Keep the containers tightly closed (especially after material removal).
Components Item number Package Content Shelf life
Kerabutyl-BB-S-Sheet 2 - 6 mm 6076300200–600 Roll 2 Months
8 Months < 15 °C
Primer 1 5040271039 Drum 23 kg 12 Months
Primer 2 5040274001 Drum 25 kg 12 Months
Adhesion-Solution 2206/L1 5040751020 Drum 16 kg 12 Months
Adhesion-Solution 2206/L2 5040759020 Drum 16 kg 12 Months
Vulcodurite-Adhesive LS3A 5040253020 Drum 16 kg 6 Months
Accelerator 2206/L1 5040781081 Bottle 0.036 kg ** 24 Months
Interleaving linen 9012015
KCH-Cleaner 1 5040016068 Drum 8.5 kg 24 Months
For handling, transport and storage observe the relevant material safety data sheets.

Application
The KERABUTYL BB S rubber coating consists of the one-component primer Primer 1, the one-component primer Primer 2, the two-
component adhesive (adhesive solution and accelerator) 2206/L1 and the Kerabutyl BB-S sheet.
Adhesive application
Mixing Ratio Parts by weight (kg)
Adhesion-Solution 2206/L1 16
72057596213923339 • V 9 • en

Accelerator 2206/L1 0.036


Spread the Primer 1 on the steel substrate. Then apply one layer of Primer 2 and two layers of adhesive. Spread the adhesive on the
rubber sheet.
The rubber sheets are firmly bonded to the substrate by pressing as specified in DIN EN 14879-4.

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Technical Information Surface Protection Linings
KERABUTYL BB S │ TI 109K │ Issue 18.09.2019

Consumption
Primer 1 in kg/m² (approx.): 0.15
Primer 2 in kg/m² (approx.): 0.20
Adhesive in kg/m² per work step (approx.): 0.20
In exceptional cases the curing of the adhesive can be accelerated. The application technology department must be contacted for
this purpose.

Safety and Disposal


● Sufficient aeration and de-aeration (especially in tanks and pits).
● No smoking/no fire
● Refer to the Safety Data Sheets
● Observe danger references and safety recommendation labels.
● Wear required personal protective equipment (avoid skin contact with materials)
● Clean and protect hands with skin protective soap and skin protection cream (no solvents)
● Wear a dust mask when sanding (e.g. for repairs).
● Instructions as per § 14 of GefahrstoffV (Toxic Substances Act) and TRGS 507 (Technical regulations for Hazardous Sub-
stances - Germany)
● Accident precautions issued by the Liability Insurance Association for the Chemical Industries (Germany)
Do not expose materials to heat or open flame, this applies in particular to welding works (weld beads).
Preferably consume residual quantities. Do not pour into a spout or dustbin! Collect separately for disposal in durable, lockable and
labeled containers.

Cleaning of Equipment
Tools soiled with uncured materials can be cleaned with KCH Cleaner 1. Only clean in well ventilated areas.
72057596213923339 • V 9 • en

All information contained in this Technical Information is based on the present state of our knowledge and practical experience. All
data are approximate values for guidance only. A legally binding warranty of certain characteristics or the suitability for a certain pur-
pose of use cannot be derived from this.
The information given in this Technical Information is our intellectual property. The Technical Information may neither be copied nor
used by unauthorized parties, nor professionally distributed or otherwise made accessible to third parties without our prior consent.
This issue replaces all previous versions.

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TI 152K Technical Information Surface Protection Linings
Issue 18.09.2019

VULCOFERRAN 2194
Hard rubber lining for the protection of steel components. General construction regulation approval by DIBt, Berlin: Z-59.22-24.

Base
Natural rubber / styrene-butadiene rubber (NR / SBR)

Material Group
Workshop rubber linings
On-site rubber lining

Description
Graphite-filled hard rubber lining based on natural rubber / styrene-butadiene rubber (NR/SBR) that may also be applied on site and
vulcanised using hot water or steam. Depending on the requirements, the layer thickness of the rubber sheet can be 3 - 6 mm.

Use
VULCOFERRAN 2194 is recommended as a protective lining for structural components made of steel that are subjected to chemical
exposure. Its primary spectrum of application includes the lining of flue gas scrubbers in garbage incineration plants, as well as stor-
age tanks and reaction vessels that are operated at high temperature ranges.
For VULCOFERRAN 2194 a general construction supervision is required. Approval of the DIBt according to the approval principles
as lining of steel containers for the storage of water-polluting liquids.

Properties
VULCOFERRAN 2194 is characterised by its excellent chemical resistance to alkaline and acidic media, with the exception of oxid-
ising media.

Physical Data
Property (unit), Test method Value
Density [g/cm³], DIN EN ISO 1183-1, ASTM D 792 1.25 ± 0.02
Shore D hardness, DIN 53505, ASTM D 2240 (autoclave vulcanization) 78 ± 5 **
Shore D hardness, DIN 53505, ASTM D 2240(hot water / steam vulcanization) > 65
Tensile strength [MPa], DIN 53504 ≥ 30 **
Elongation at tear [%], DIN EN ISO 527, ASTM C 307 > 2 **
Adherence [N/mm²], DIN EN ISO 4624 ≥6
max. surface pressure [MPa] 10
27021599949100299 • V 4 • en

Temperature resistance [°C] 100


Data are mean values
*) The values were determined at 4 mm thick rubber samples.
**) Vulcanized in press (2 h /+ 145 °C)

Chemical Resistance
Information on the chemical resistance properties will be provided on request.

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Technical Information Surface Protection Linings
VULCOFERRAN 2194 │ TI 152K │ Issue 18.09.2019

Substrate
Steel
Refer to DIN EN14879-1 as well as to STEULER-KCH-Formblatt 020.
The steel surface shall be sandblasted to a metallic bright finish. A preparation degree of SA 2 ½ as specified in DIN EN ISO
12944-4 and a roughness grade “medium (G)” as specified in DIN EN ISO 8503-1 must be achieved; minimum surface roughness Rz
= 50 μm. After blasting, the formation of new rust must be prevented by suitable measures, e.g. immediate application of a primer.
Grey cast iron must be tempered in the autoclave prior to blast cleaning, in order to expel any inclusions of moisture.
The substrate should have a temperature of approx. 10 – 30 °C, dew point distance min. 5 K.
With object temperatures below +10 °C rubber lining work must not be carried out.
During application, the substrate must be kept absolutely dry. Uncured material has to be protected from any kind of moisture (con-
densation, fog, precipitation or other water source).

Packaging / Shelf life


All components must be stored and transported dry and frost-free. Unless otherwise specified, the minimum shelf life applies to a
storage temperature of 20 °C. Higher temperatures reduce, lower temperatures increase the shelf life. The use of refrigerated con-
tainers should be considered on a project-by-project basis, especially when components are stored at temperatures below 20 °C in
order to extend their shelf life. Keep the containers tightly closed (especially after material removal).
Components Item number Package Content Shelf life
Primer 1 5040271039 Drum 23 kg 12 Months
Primer 2 5040274001 Drum 25 kg 12 Months
Vulcodurite-Adhesive LS3A 5040253020 Drum 16 kg 6 Months
Kerabutyl-cleansing agent 5040020041 Canister 8 kg 24 Months
KCH-Cleaner 1 5040016068 Drum 8.5 kg 24 Months
KCH-Diluent 9 5040015005 Canister 4 kg 24 Months
Vulcoferran-2194-sheet 2-6 mm 6071610200–600 Roll 2 Months
9 Months < 15 °C
For handling, transport and storage observe the relevant material safety data sheets.

Application
The VULCOFERRAN-2194-rubber-lining system is composed of the single-component Primer 1, the single-component Primer 2, the
single-component Vulkodurit-adhesive LS3A and the Vulcoferran-2194-rubber sheet.
Spread Primer 1 and Primer 2 on the substrate. Then apply two coats of the Vulkodurit -adhesive LS3A.
The rubber sheets are coated with the Vulkodurit adhesive LS3A and bonded to the substrate in accordance with the specifications
contained in DIN EN 14879-4. A durable and solid bonding will be achieved by firmly pressing down the rubber sheet and the sub-
sequent vulcanisation process.
Consumption
Primer 1 approx. 0.15 kg/m²
Primer 2 approx. 0.20 kg/m²
Vulcodurite-Adhesive LS3A approx. 0.25 kg/m² per coat
Kerabutyl-cleansing agent approx. 0.05 kg/m²
27021599949100299 • V 4 • en

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Technical Information Surface Protection Linings
VULCOFERRAN 2194 │ TI 152K │ Issue 18.09.2019

Safety and Disposal


● Sufficient aeration and de-aeration (especially in tanks and pits).
● No smoking/no fire
● Refer to the Safety Data Sheets
● Observe danger references and safety recommendation labels.
● Wear required personal protective equipment (avoid skin contact with materials)
● Clean and protect hands with skin protective soap and skin protection cream (no solvents)
● Wear a dust mask when sanding (e.g. for repairs).
● Instructions as per § 14 of GefahrstoffV (Toxic Substances Act) and TRGS 507 (Technical regulations for Hazardous Sub-
stances - Germany)
● Accident precautions issued by the Liability Insurance Association for the Chemical Industries (Germany)
Do not expose materials to heat or open flame, this applies in particular to welding works (weld beads).
Preferably consume residual quantities. Do not pour into a spout or dustbin! Collect separately for disposal in durable, lockable and
labeled containers.

Cleaning of Equipment
The tools are cleaned with Kerabutyl cleaning agent or STEULER UNIVERSAL CLEANER. Cleaning must be carried out prior to
hardening of the material.
27021599949100299 • V 4 • en

All information contained in this Technical Information is based on the present state of our knowledge and practical experience. All
data are approximate values for guidance only. A legally binding warranty of certain characteristics or the suitability for a certain pur-
pose of use cannot be derived from this.
The information given in this Technical Information is our intellectual property. The Technical Information may neither be copied nor
used by unauthorized parties, nor professionally distributed or otherwise made accessible to third parties without our prior consent.
This issue replaces all previous versions.

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Safety Data Sheet
according to Regulation (EC) No 1907/2006
Solution BS
Revision date: 07.02.2019 Product code: 5040328003 Page 1 of 14

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Solution BS
Further trade names
valid for all package sizes
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Adhesives, sealants
Reserved for industrial and professional use.
Uses advised against
The product is intended for professional use.
1.3. Details of the supplier of the safety data sheet
Company name: STEULER-KCH GmbH
Siershahn
Street: Berggarten 1
Place: D-56427 Siershahn
Telephone: +49 2623 600 0 Telefax: +49 2623 600 513
e-mail: info@steuler-kch.de
Contact person: Labor COS/RUL
e-mail: msds@steuler-kch.de
Internet: www.steuler-kch.de
Responsible Department: +49 2624 13 507
+49 2623 600 535
1.4. Emergency telephone number: (001) 352 3233500 Emtel-Customer-No. 99496
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories:
Flammable liquid: Flam. Liq. 2
Skin corrosion/irritation: Skin Irrit. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Carcinogenicity: Carc. 2
Reproductive toxicity: Repr. 2
Specific target organ toxicity - single exposure: STOT SE 3
Specific target organ toxicity - repeated exposure: STOT RE 2
Hazardous to the aquatic environment: Aquatic Chronic 3
Hazard Statements:
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
Suspected of causing cancer.
Suspected of damaging the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Harmful to aquatic life with long lasting effects.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
toluene
butanone; ethyl methyl ketone
dichloromethane
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
Signal word: Danger
Pictograms:

Hazard statements
H225 Highly flammable liquid and vapour.

Revision No: 2,02 - Replaces version: 2,01 GB - EN Print date: 07.02.2019


Safety Data Sheet
according to Regulation (EC) No 1907/2006
Solution BS
Revision date: 07.02.2019 Product code: 5040328003 Page 2 of 14

H315 Causes skin irritation.


H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P260 Do not breathe vapour/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P403+P235 Store in a well-ventilated place. Keep cool.
Additional advice on labelling
On basis of test data. Calculation method.
2.3. Other hazards
Highly flammable. Vapours can form explosive mixtures with air. The vapour of the product is heavier than air and may
accumulate below ground level, in pits, channels and basements in higher concentration. Vapours can travel considerable
distances to a source of ignition where they can ignite, flash back, or explode.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Chemical characterization
Mixture related information:
Solvent-preparation.

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
GHS Classification
108-88-3 toluene 30 - < 35 %
203-625-9 601-021-00-3 01-2119471310-51
Flam. Liq. 2, Repr. 2, Skin Irrit. 2, STOT SE 3, STOT RE 2, Asp. Tox. 1, Aquatic Chronic 3; H225 H361d H315
H336 H373 H304 H412
78-93-3 butanone; ethyl methyl ketone 30 - < 35 %
201-159-0 606-002-00-3 01-2119457290-43
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066
75-09-2 dichloromethane 5 - < 10 %
200-838-9 602-004-00-3 01-2119480404-41
Carc. 2, Skin Irrit. 2, Eye Irrit. 2, STOT SE 3, STOT SE 3; H351 H315 H319 H335 H336
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane 5 - < 10 %
921-024-6 01-2119475514-35
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304 H411
67-64-1 acetone; propan-2-one; propanone 5 - < 10 %
200-662-2 606-001-00-8 01-2119471330-49
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066
110-82-7 cyclohexane <1 %
203-806-2 601-017-00-1 01-2119463273-41
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Acute 1, Aquatic Chronic 1; H225 H315 H336 H304
H400 H410
110-54-3 n-hexane < 0,5 %
203-777-6 601-037-00-0 01-2119480412-44
Flam. Liq. 2, Repr. 2, Acute Tox. 4, Skin Irrit. 2, STOT SE 3, STOT RE 2, Asp. Tox. 1, Aquatic Chronic 2;
H225 H361f H332 H315 H336 H373 H304 H411
Full text of H and EUH statements: see section 16.

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SECTION 4: First aid measures


4.1. Description of first aid measures
General information
Move victim out of danger zone. In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible). Remove contaminated, saturated clothing immediately.
After inhalation
Provide fresh air. Medical treatment necessary.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
Take off immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
advice/attention.
After contact with eyes
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an
ophthalmologist immediately.
After ingestion
Rinse mouth immediately and drink plenty of water. Observe risk of aspiration if vomiting occurs. Medical treatment
necessary.
4.2. Most important symptoms and effects, both acute and delayed
The following symptoms may occur: Asthmatic complaints. difficulties of breathing. Coughing.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically. Symptoms of poisoning may develop several hours following exposure. Victim should be under
medical observation for at least 48 hours after exposure.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray jet, Carbon dioxide (CO2), Foam, Extinguishing powder.
Co-ordinate fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
Highly flammable. Vapours can form explosive mixtures with air.
The vapour of the product is heavier than air and may accumulate below ground level, in pits, channels and basements in
higher concentration. Vapours can travel considerable distances to a source of ignition where they can ignite, flash back,
or explode.
In case of fire may be liberated:
Hydrogen chloride (HCl), Carbon monoxide, Carbon dioxide., Pyrolysis products, toxic.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Co-ordinate fire-fighting measures to the fire surroundings.
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists with water
spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with
skin, eyes and clothes. Use personal protection equipment.
6.2. Environmental precautions
Do not allow uncontrolled discharge of product into the environment. Danger of explosion
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered
material as prescribed in the section on waste disposal.
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling

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Advice on safe handling


If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Vapours can
form explosive mixtures with air. Vapours can travel considerable distances to a source of ignition where they can ignite,
flash back, or explode. The vapour of the product is heavier than air and may accumulate below ground level, in pits,
channels and basements in higher concentration.
Further information on handling
Avoid contact with skin and eyes.
When using do not eat, drink, smoke, sniff.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Store in a place accessible by authorized persons only. Provide adequate ventilation as
well as local exhaustion at critical locations. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Floors should be impervious, resistant to liquids and easy to
clean. Observe in addition any national regulations!
Hints on joint storage
Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.
7.3. Specific end use(s)
for professional use only Observe technical data sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

67-64-1 Acetone 500 1210 TWA (8 h) WEL


1500 3620 STEL (15 min) WEL
78-93-3 Butan-2-one (methyl ethyl ketone) 200 600 TWA (8 h) WEL
300 899 STEL (15 min) WEL
110-82-7 Cyclohexane 100 350 TWA (8 h) WEL
300 1050 STEL (15 min) WEL
75-09-2 Dichloromethane 100 350 TWA (8 h) WEL
300 1060 STEL (15 min) WEL
108-88-3 Toluene 50 191 TWA (8 h) WEL
100 384 STEL (15 min) WEL
110-54-3 n-Hexane 20 72 TWA (8 h) WEL

Biological Monitoring Guidance Values (EH40)

CAS No Substance Parameter Value Test material Sampling time

78-93-3 Butan-2-one butan-2-one 70 µmol/L urine Post shift


75-09-2 Dichloromethane carbon monoxide 30 ppm end-tidal breath Post shift

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DNEL/DMEL values
CAS No Substance
DNEL type Exposure route Effect Value
108-88-3 toluene
Consumer DNEL, long-term oral systemic 8,13 mg/kg bw/day
Consumer DNEL, long-term dermal systemic 384 mg/kg bw/day
Consumer DNEL, acute inhalation local 226 mg/m³
Worker DNEL, acute inhalation local 384 mg/m³
Consumer DNEL, acute inhalation systemic 226 mg/m³
Worker DNEL, acute inhalation systemic 384 mg/m³
Worker DNEL, long-term inhalation local 192 mg/m³
Consumer DNEL, long-term inhalation systemic 56,5 mg/m³
Worker DNEL, long-term inhalation systemic 192 mg/m³
78-93-3 butanone; ethyl methyl ketone
Worker DNEL, long-term dermal systemic 1161 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 600 mg/m³
Consumer DNEL, long-term inhalation systemic 106 mg/m³
Consumer DNEL, long-term oral systemic 31 mg/kg bw/day
Consumer DNEL, acute dermal systemic 412 mg/kg bw/day
75-09-2 dichloromethane
Worker DNEL, long-term inhalation systemic 353 mg/m³
Worker DNEL, long-term dermal systemic 12 mg/kg bw/day
Worker DNEL, acute inhalation systemic 706 mg/m³
Consumer DNEL, long-term inhalation systemic 88,3 mg/m³
Consumer DNEL, long-term dermal systemic 5,82 mg/kg bw/day
Consumer DNEL, acute inhalation systemic 353 mg/m³
Consumer DNEL, long-term oral systemic 0,06 mg/kg bw/day
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
Worker DNEL, long-term dermal systemic 773 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 2035 mg/m³
Consumer DNEL, long-term dermal systemic 699 mg/kg bw/day
Consumer DNEL, long-term inhalation systemic 608 mg/m³
Consumer DNEL, long-term oral systemic 699 mg/kg bw/day
67-64-1 acetone; propan-2-one; propanone
Worker DNEL, long-term dermal systemic 186 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 1210 mg/m³
Worker DNEL, acute inhalation local 2420 mg/m³
Consumer DNEL, long-term dermal systemic 62 mg/kg bw/day
Consumer DNEL, long-term inhalation systemic 200 mg/m³
Consumer DNEL, long-term oral systemic 62 mg/kg bw/day

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PNEC values
CAS No Substance
Environmental compartment Value
108-88-3 toluene
Freshwater 0,68 mg/l
Marine water 0,68 mg/l
Freshwater sediment 16,39 mg/kg
Marine sediment 16,39 mg/kg
Micro-organisms in sewage treatment plants (STP) 13,61 mg/l
Soil 2,89 mg/kg
78-93-3 butanone; ethyl methyl ketone
Freshwater 55,8 mg/l
Freshwater (intermittent releases) 55,8 mg/l
Marine water 55,8 mg/l
Marine water (intermittent releases) 55,8 mg/l
Freshwater sediment 284,7 mg/kg
Marine sediment 284,7 mg/kg
Secondary poisoning 1000 mg/kg
Micro-organisms in sewage treatment plants (STP) 709 mg/l
Soil 22,5 mg/kg
75-09-2 dichloromethane
Freshwater 0,31 mg/l
Freshwater (intermittent releases) 0,27 mg/l
Marine water 0,031 mg/l
Freshwater sediment 2,57 mg/kg
Marine sediment 0,262 mg/kg
Micro-organisms in sewage treatment plants (STP) 26 mg/l
Soil 0,33 mg/kg
67-64-1 acetone; propan-2-one; propanone
Freshwater 10,6 mg/l
Marine water 1,06 mg/l
Freshwater sediment 30,4 mg/kg
Marine sediment 3,04 mg/kg
Micro-organisms in sewage treatment plants (STP) 100 mg/l
Soil 29,5 mg/kg

8.2. Exposure controls

Appropriate engineering controls


If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands
and face before breaks and after work and take a shower if necessary. When using do not eat or drink.
Eye/face protection
Suitable eye protection:
Eye glasses with side protection, goggles.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control
digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the

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resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Suitable material:
FKM (fluororubber). Limited splash-tight.
PVA (Polyvinyl alcohol). Limited splash-tight.
Avoid contact with water.
Before using check leak tightness / impermeability. Breakthrough times and swelling properties of the material must be
taken into consideration.
Skin protection
Wear anti-static footwear and clothing
Respiratory protection
Respiratory protection necessary at: insufficient ventilation. insufficient absorbtion.
Suitable respiratory protective equipment: Protective respiration apparatus not using surrounding air (breathing apparatus)
(DIN EN 133).
Use only respiratory protection equipment with CE-symbol including four digit test number.
Environmental exposure controls
See chapter 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: liquid
Colour: colourless
Odour: characteristic
Test method
pH-Value: not applicable
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: 40 - 111 °C
Sublimation point: not applicable
Softening point: not applicable
Flash point: - 15 °C DIN EN ISO 2719
Sustaining combustion: Sustaining combustion
Flammability
Solid: not applicable
Gas: not applicable
Explosive properties
This material is combustible and can be ignited by heat, sparks, flames, or other sources of ignition (e.g. static electricity,
pilot lights, or mechanical/electrical equipment). In use, may form flammable/explosive vapour-air mixture.
Lower explosion limits: 1 vol. %
Upper explosion limits: 14,3 vol. %
Ignition temperature: > 200 °C DIN 51794
Auto-ignition temperature
Solid: not applicable
Gas: not applicable
Decomposition temperature: not determined
Oxidizing properties
Not oxidising.
Vapour pressure: 246 hPa
(at 20 °C)
Vapour pressure: 360 hPa
(at 50 °C)
Density (at 23 °C): 0,90 g/cm³ ISO 2811
Water solubility: not determined
Solubility in other solvents
miscible with most organic solvents
Partition coefficient: not determined
Viscosity / dynamic: not determined
Flow time: 135 - 165 s 4 DIN 53211
(at 23 °C)

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Vapour density: not determined


Evaporation rate: not determined
Solvent content: 84,82 %
9.2. Other information
Solid content: not determined
none
SECTION 10: Stability and reactivity
10.1. Reactivity
Highly flammable. Ignition hazard.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
Exothermic reactions with: Oxidizing agents, strong. Strong acid
In use may form flammable/explosive vapour-air mixture.
10.4. Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive mixtures with
air. The vapour of the product is heavier than air and may accumulate below ground level, in pits, channels and
basements in higher concentration.
10.5. Incompatible materials
Oxidizing agents, strong. Strong acid
10.6. Hazardous decomposition products
In case of fire may be liberated:
Carbon monoxide, Carbon dioxide (CO2), Hydrogen chloride (HCl), Pyrolysis products, toxic.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.

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CAS No Chemical name


Exposure route Dose Species Source Method
108-88-3 toluene
oral LD50 5000 Rat
mg/kg
dermal LD50 12124 Rabbit
mg/kg
inhalation (4 h) vapour LC50 31 mg/l Rat
78-93-3 butanone; ethyl methyl ketone
oral LD50 > 2193 Rat OECD 423
mg/kg
dermal LD50 > 5000 Rabbit OECD 402
mg/kg
inhalation (4 h) vapour LC50 34 mg/l Rat
75-09-2 dichloromethane
oral LD50 2136 Rat
mg/kg
dermal LD50 > 2000 Rat
mg/kg
inhalation (4 h) vapour LC50 88 mg/l Rat
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
oral LD50 > 5000 Rat OECD 401
mg/kg
dermal LD50 > 2000 Rat OECD 402
mg/kg
inhalation (4 h) vapour LC50 > 20 mg/l Rat OECD 403
67-64-1 acetone; propan-2-one; propanone
oral LD50 5800 Rat OECD 401
mg/kg
dermal LD50 20000 Rabbit IUCLID
mg/kg
inhalation (4 h) vapour LC50 76 mg/l Rat
110-82-7 cyclohexane
oral LD50 > 5000 Rat Safety Data Sheet
mg/kg
dermal LD50 > 2000 Rabbit Safety Data Sheet
mg/kg
110-54-3 n-hexane
dermal LD50 > 2000 Rabbit Safety Data Sheet
mg/kg
inhalation vapour ATE 11 mg/l
inhalation (1 h) aerosol LC50 17,4 mg/l Rat Safety Data Sheet

Irritation and corrosivity


Causes skin irritation.
Causes serious eye irritation.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Suspected of causing cancer. (dichloromethane)
Suspected of damaging the unborn child. (toluene)
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
STOT-single exposure
May cause drowsiness or dizziness. (toluene; butanone; ethyl methyl ketone)
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure. (toluene)
Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP]. Special hazards arising from the
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substance or mixture!
SECTION 12: Ecological information
12.1. Toxicity
Harmful to aquatic life with long lasting effects.
CAS No Chemical name
Aquatic toxicity Dose [h] | [d] Species Source Method
108-88-3 toluene
Acute fish toxicity LC50 5,8 mg/l 96 h Oncorhynchus mykiss
(Rainbow trout)
Acute crustacea toxicity EC50 3,78 mg/l 48 h Ceriodaphnia spec
Crustacea toxicity NOEC 0,74 mg/l 7 d Ceriodaphnia spec
78-93-3 butanone; ethyl methyl ketone
Acute fish toxicity LC50 2993 mg/l 96 h Pimephales promelas OECD 203
(fathead minnow)
Acute algae toxicity ErC50 2029 mg/l 72 h Pseudokirchneriella OECD 201
subcapitata
Acute crustacea toxicity EC50 308 mg/l 48 h Daphnia magna (Big OECD 202
water flea)
75-09-2 dichloromethane
Acute fish toxicity LC50 193 mg/l 96 h Pimephales promelas
Acute algae toxicity ErC50 > 660 96 h Pseudokirchneriella
mg/l subcapitata
Acute crustacea toxicity EC50 220 mg/l 48 h Daphnia magna
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
Acute fish toxicity LC50 11,4 mg/l 96 h Oncorhynchus mykiss OECD 203
(Rainbow trout)
Acute algae toxicity ErC50 30 mg/l 72 h Pseudokirchneriella OECD 201.
subcapitata
Acute crustacea toxicity EC50 3 mg/l 48 h Daphnia magna OECD 202
67-64-1 acetone; propan-2-one; propanone
Acute fish toxicity LC50 5540 mg/l 96 h Oncorhynchus mykiss
(Rainbow trout)
Acute crustacea toxicity EC50 6100 mg/l 48 h Daphnia magna (Big
water flea)
Acute bacteria toxicity (1000 mg/l) 0,5 h Activated sludge OECD 209
110-82-7 cyclohexane
Acute crustacea toxicity EC50 0,9 mg/l 48 h Daphnia magna (Big Safety Data Sheet OECD 202
water flea)

12.2. Persistence and degradability


There are no data available on the mixture itself.
CAS No Chemical name
Method Value d Source
Evaluation
108-88-3 toluene
86% 20
Easily biodegradable (concerning to the criteria of the OECD)
78-93-3 butanone; ethyl methyl ketone
OECD 301D/ EEC 92/69/V, C.4-E 98 % 28
Easily biodegradable (concerning to the criteria of the OECD)
67-64-1 acetone; propan-2-one; propanone
OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C 91 % 28
Easily biodegradable (concerning to the criteria of the OECD)

12.3. Bioaccumulative potential

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There are no data available on the mixture itself.


Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
108-88-3 toluene 2,65
78-93-3 butanone; ethyl methyl ketone 0,3
75-09-2 dichloromethane 1,25
67-64-1 acetone; propan-2-one; propanone -0,24
110-54-3 n-hexane 3,9

BCF
CAS No Chemical name BCF Species Source
108-88-3 toluene 90
67-64-1 acetone; propan-2-one; propanone < 10

12.4. Mobility in soil


No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No information available.
Further information
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Advice on disposal
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to
applicable legislation.
Waste disposal number of waste from residues/unused products
080409 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes
from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants
containing organic solvents or other hazardous substances; hazardous waste
Waste disposal number of contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging
waste); packaging containing residues of or contaminated by hazardous substances; hazardous waste
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the same way
as the substance itself. Completely emptied packages can be recycled.
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Special Provisions: 640D
Limited quantity: 5L
Excepted quantity: E2
Transport category: 2
Hazard No: 33
Tunnel restriction code: D/E
Inland waterways transport (ADN)

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14.1. UN number: UN 1133


14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Special Provisions: 640D
Limited quantity: 5L
Excepted quantity: E2
Marine transport (IMDG)
14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Marine pollutant: no
Special Provisions: -
Limited quantity: 5L
Excepted quantity: E2
EmS: F-E, S-D
Segregation group: IMDG-Code segregation group not applicable
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1133
14.2. UN proper shipping name: Adhesives
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Special Provisions: A3
Limited quantity Passenger: 1L
Passenger LQ: Y341
Excepted quantity: E2
IATA-packing instructions - Passenger: 353
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 364
IATA-max. quantity - Cargo: 60 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Warning: Combustible liquid.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information

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Restrictions on use (REACH, annex XVII):


Entry 3: n-hexane
Entry 48: toluene
Entry 57: cyclohexane
Entry 59: dichloromethane
2010/75/EU (VOC): 85,5 % (769,5 g/l)
2004/42/EC (VOC): 85,5 % (769,5 g/l)
Information according to 2012/18/EU P5c FLAMMABLE LIQUIDS
(SEVESO III):
National regulatory information
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile work
protection guideline' (94/33/EC). Observe employment restrictions under the
Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Water contaminating class (D): 2 - clearly water contaminating
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
toluene
butanone; ethyl methyl ketone
dichloromethane
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
acetone; propan-2-one; propanone
SECTION 16: Other information
Changes
This data sheet contains changes from the previous version in section(s): 9.
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
VOC: Volatile Organic Compounds (USA, EU, CH)
DNEL: Derived No-Effect Levels
PNEC: Predicted No-Effect Concentration
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Flam. Liq. 2; H225 On basis of test data
Skin Irrit. 2; H315 Calculation method
Eye Irrit. 2; H319 Calculation method
Carc. 2; H351 Calculation method
Repr. 2; H361d Calculation method
STOT SE 3; H336 Calculation method
STOT RE 2; H373 Calculation method
Aquatic Chronic 3; H412 Calculation method
Relevant H and EUH statements (number and full text)
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.

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Solution BS
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H335 May cause respiratory irritation.


H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety
data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the
case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not
necessarily valid for the new made-up material. The information is based on present level of our knowledge. It does not,
however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is
singulary responsible for adhering to existing laws and regulations.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

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according to Regulation (EC) No 1907/2006
Keratex-Primer
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SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Keratex-Primer
Further trade names
valid for all package sizes
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Adhesives, sealants
Reserved for industrial and professional use.
Uses advised against
The product is intended for professional use.
1.3. Details of the supplier of the safety data sheet
Company name: STEULER-KCH GmbH
Siershahn
Street: Berggarten 1
Place: D-56427 Siershahn
Telephone: +49 2623 600 0 Telefax: +49 2623 600 513
e-mail: info@steuler-kch.de
Contact person: Labor COS/RUL
e-mail: msds@steuler-kch.de
Internet: www.steuler-kch.de
Responsible Department: +49 2624 13 507
+49 2623 600 535
1.4. Emergency telephone number: (001) 352 3233500 Emtel-Customer-No. 99496
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Hazard categories:
Flammable liquid: Flam. Liq. 2
Aspiration hazard: Asp. Tox. 1
Skin corrosion/irritation: Skin Irrit. 2
Serious eye damage/eye irritation: Eye Irrit. 2
Reproductive toxicity: Repr. 2
Specific target organ toxicity - single exposure: STOT SE 3
Specific target organ toxicity - repeated exposure: STOT RE 2
Hazardous to the aquatic environment: Aquatic Chronic 2
Hazard Statements:
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
Suspected of damaging the unborn child.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Toxic to aquatic life with long lasting effects.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
ethyl acetate
toluene
cyclohexane
Signal word: Danger
Pictograms:

Hazard statements
H225 Highly flammable liquid and vapour.

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H304 May be fatal if swallowed and enters airways.


H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 Do not breathe vapour/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P331 Do NOT induce vomiting.
P403+P235 Store in a well-ventilated place. Keep cool.
Additional advice on labelling
On basis of test data. Calculation method.
2.3. Other hazards
Highly flammable. Vapours can form explosive mixtures with air. The vapour of the product is heavier than air and may
accumulate below ground level, in pits, channels and basements in higher concentration. Vapours can travel considerable
distances to a source of ignition where they can ignite, flash back, or explode.
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

SECTION 3: Composition/information on ingredients


3.2. Mixtures
Chemical characterization
Mixture related information:
Solvent-preparation.

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
GHS Classification
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane 30 - < 35 %
921-024-6 01-2119475514-35
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304 H411
141-78-6 ethyl acetate 25 - < 30 %
205-500-4 607-022-00-5 01-2119475103-46
Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066
108-88-3 toluene 20 - < 25 %
203-625-9 601-021-00-3 01-2119471310-51
Flam. Liq. 2, Repr. 2, Skin Irrit. 2, STOT SE 3, STOT RE 2, Asp. Tox. 1, Aquatic Chronic 3; H225 H361d H315
H336 H373 H304 H412
110-82-7 cyclohexane 1-<5%
203-806-2 601-017-00-1 01-2119463273-41
Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Acute 1, Aquatic Chronic 1; H225 H315 H336 H304
H400 H410
110-54-3 n-hexane 1-<5%
203-777-6 601-037-00-0 01-2119480412-44
Flam. Liq. 2, Repr. 2, Acute Tox. 4, Skin Irrit. 2, STOT SE 3, STOT RE 2, Asp. Tox. 1, Aquatic Chronic 2;
H225 H361f H332 H315 H336 H373 H304 H411
Full text of H and EUH statements: see section 16.
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
Move victim out of danger zone. In case of accident or unwellness, seek medical advice immediately (show directions for
use or safety data sheet if possible). Remove contaminated, saturated clothing immediately.

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After inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
After contact with skin
After contact with skin, wash immediately with plenty of water and soap.
Take off immediately all contaminated clothing and wash it before reuse. Medical treatment necessary.
After contact with eyes
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an
ophthalmologist immediately.
After ingestion
Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water. Medical treatment
necessary.
4.2. Most important symptoms and effects, both acute and delayed
The following symptoms may occur: Asthmatic complaints. difficulties of breathing. Coughing.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically. Symptoms of poisoning may develop several hours following exposure. Victim should be under
medical observation for at least 48 hours after exposure.
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray jet, Carbon dioxide (CO2), Foam, Extinguishing powder.
Co-ordinate fire-fighting measures to the fire surroundings.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
Highly flammable. Vapours can form explosive mixtures with air.
The vapour of the product is heavier than air and may accumulate below ground level, in pits, channels and basements in
higher concentration. Vapours can travel considerable distances to a source of ignition where they can ignite, flash back,
or explode.
In case of fire may be liberated:
Pyrolysis products, toxic. Carbon monoxide Carbon dioxide.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Co-ordinate fire-fighting measures to the fire surroundings.
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Suppress gases/vapours/mists with water
spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Remove all sources of ignition. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes and clothes. Use
personal protection equipment.
6.2. Environmental precautions
Do not allow uncontrolled discharge of product into the environment. Danger of explosion
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered
material as prescribed in the section on waste disposal.
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advice on safe handling
If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Advice on protection against fire and explosion
Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. Vapours can
form explosive mixtures with air. Vapours can travel considerable distances to a source of ignition where they can ignite,
flash back, or explode. The vapour of the product is heavier than air and may accumulate below ground level, in pits,
channels and basements in higher concentration.

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Further information on handling


Avoid contact with skin and eyes.
When using do not eat, drink, smoke, sniff.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces, sparks, open
flames and other ignition sources. No smoking. Floors should be impervious, resistant to liquids and easy to clean.
Observe in addition any national regulations!
Hints on joint storage
Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.
7.3. Specific end use(s)
for professional use only Observe technical data sheet.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

110-82-7 Cyclohexane 100 350 TWA (8 h) WEL


300 1050 STEL (15 min) WEL
141-78-6 Ethyl acetate 200 - TWA (8 h) WEL
400 - STEL (15 min) WEL
108-88-3 Toluene 50 191 TWA (8 h) WEL
100 384 STEL (15 min) WEL
110-54-3 n-Hexane 20 72 TWA (8 h) WEL

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DNEL/DMEL values
CAS No Substance
DNEL type Exposure route Effect Value
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
Worker DNEL, long-term dermal systemic 773 mg/kg bw/day
Worker DNEL, long-term inhalation systemic 2035 mg/m³
Consumer DNEL, long-term dermal systemic 699 mg/kg bw/day
Consumer DNEL, long-term inhalation systemic 608 mg/m³
Consumer DNEL, long-term oral systemic 699 mg/kg bw/day
141-78-6 ethyl acetate
Worker DNEL, acute inhalation systemic 1468 mg/m³
Worker DNEL, acute inhalation local 1468 mg/m³
Worker DNEL, long-term inhalation systemic 734 mg/m³
Worker DNEL, long-term inhalation local 734 mg/m³
Worker DNEL, long-term dermal systemic 63 mg/kg bw/day
Consumer DNEL, acute inhalation systemic 734 mg/m³
Consumer DNEL, acute inhalation local 734 mg/m³
Consumer DNEL, long-term inhalation systemic 367 mg/m³
Consumer DNEL, long-term inhalation local 367 mg/m³
Consumer DNEL, long-term dermal systemic 37 mg/kg bw/day
Consumer DNEL, long-term oral systemic 4,5 mg/kg bw/day
108-88-3 toluene
Consumer DNEL, long-term oral systemic 8,13 mg/kg bw/day
Consumer DNEL, long-term dermal systemic 384 mg/kg bw/day
Consumer DNEL, acute inhalation local 226 mg/m³
Worker DNEL, acute inhalation local 384 mg/m³
Consumer DNEL, acute inhalation systemic 226 mg/m³
Worker DNEL, acute inhalation systemic 384 mg/m³
Worker DNEL, long-term inhalation local 192 mg/m³
Consumer DNEL, long-term inhalation systemic 56,5 mg/m³
Worker DNEL, long-term inhalation systemic 192 mg/m³

PNEC values
CAS No Substance
Environmental compartment Value
141-78-6 ethyl acetate
Freshwater 0,26 mg/l
Marine water 0,026 mg/l
Freshwater sediment 1,25 mg/kg
Marine sediment 0,125 mg/kg
Micro-organisms in sewage treatment plants (STP) 650 mg/l
Soil 0,24 mg/kg
108-88-3 toluene
Freshwater 0,68 mg/l
Marine water 0,68 mg/l
Freshwater sediment 16,39 mg/kg
Marine sediment 16,39 mg/kg
Micro-organisms in sewage treatment plants (STP) 13,61 mg/l
Soil 2,89 mg/kg

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8.2. Exposure controls

Appropriate engineering controls


If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe
gas/fumes/vapour/spray.
Protective and hygiene measures
Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands
and face before breaks and after work and take a shower if necessary. When using do not eat or drink.
Eye/face protection
Suitable eye protection:
Eye glasses with side protection, goggles.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four control
digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working
place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the
resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Suitable material:
FKM (fluororubber). Limited splash-tight.
PVA (Polyvinyl alcohol). Limited splash-tight.
Avoid contact with water.
Before using check leak tightness / impermeability. Breakthrough times and swelling properties of the material must be
taken into consideration.
Skin protection
Wear anti-static footwear and clothing
Respiratory protection
Respiratory protection necessary at: insufficient ventilation. insufficient absorbtion.
Suitable respiratory protective equipment: Filter respirator (DIN EN 147). A 2
Use only respiratory protection equipment with CE-symbol including four digit test number.
Environmental exposure controls
See chapter 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state: liquid
Colour: clear
Odour: characteristic
Test method
pH-Value: not applicable
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: 77 - 111 °C
Sublimation point: not applicable
Softening point: not applicable
Flash point: - 14 °C DIN EN ISO 2719
Sustaining combustion: Sustaining combustion
Flammability
Solid: not applicable
Gas: not applicable
Explosive properties
This material is combustible and can be ignited by heat, sparks, flames, or other sources of ignition (e.g. static electricity,
pilot lights, or mechanical/electrical equipment). In use, may form flammable/explosive vapour-air mixture.
Lower explosion limits: 0,8 vol. %
Upper explosion limits: 11,5 vol. %
Ignition temperature: 230 °C
Auto-ignition temperature

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Solid: not applicable


Gas: not applicable
Decomposition temperature: not determined
Oxidizing properties
Not oxidising.
Vapour pressure: 96,8 hPa
(at 20 °C)
Vapour pressure: 375,3 hPa
(at 50 °C)
Density (at 23 °C): 0,86 - 0,88 g/cm³ ISO 2811
Water solubility: practically insoluble
(at 20 °C)
Solubility in other solvents
miscible with most organic solvents
Partition coefficient: not determined
Viscosity / dynamic: not determined
Viscosity / kinematic: not determined
Flow time: 13 - 17 s 4 DIN 53211
(at 23 °C)
Vapour density: not determined
Evaporation rate: not determined
Solvent content: 82,71 %
9.2. Other information
Solid content: not determined
none
SECTION 10: Stability and reactivity
10.1. Reactivity
Highly flammable., Ignition hazard.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
Exothermic reactions with: Oxidizing agents, strong. Strong acid
In use may form flammable/explosive vapour-air mixture.
10.4. Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form explosive mixtures with
air. The vapour of the product is heavier than air and may accumulate below ground level, in pits, channels and
basements in higher concentration.
10.5. Incompatible materials
Oxidizing agents, strong. Strong acid
10.6. Hazardous decomposition products
In case of fire may be liberated:
Carbon monoxide Carbon dioxide (CO2). Hydrogen chloride (HCl). Pyrolysis products, toxic.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Based on available data, the classification criteria are not met.

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CAS No Chemical name


Exposure route Dose Species Source Method
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
oral LD50 > 5000 Rat OECD 401
mg/kg
dermal LD50 > 2000 Rat OECD 402
mg/kg
inhalation (4 h) vapour LC50 > 20 mg/l Rat OECD 403
141-78-6 ethyl acetate
oral LD50 5600 Rat
mg/kg
dermal LD50 18000 Rabbit
mg/kg
inhalation (4 h) vapour LC50 58 mg/l Rat
108-88-3 toluene
oral LD50 5000 Rat
mg/kg
dermal LD50 12124 Rabbit
mg/kg
inhalation (4 h) vapour LC50 31 mg/l Rat
110-82-7 cyclohexane
oral LD50 > 5000 Rat Safety Data Sheet
mg/kg
dermal LD50 > 2000 Rabbit Safety Data Sheet
mg/kg
110-54-3 n-hexane
dermal LD50 > 2000 Rabbit Safety Data Sheet
mg/kg
inhalation vapour ATE 11 mg/l
inhalation (1 h) aerosol LC50 17,4 mg/l Rat Safety Data Sheet

Irritation and corrosivity


Causes skin irritation.
Causes serious eye irritation.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Suspected of damaging the unborn child. (toluene)
Germ cell mutagenicity: Based on available data, the classification criteria are not met.
Carcinogenicity: Based on available data, the classification criteria are not met.
STOT-single exposure
May cause drowsiness or dizziness. (Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane; ethyl acetate;
toluene)
STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure. (toluene)
May cause damage to organs through prolonged or repeated exposure.
Aspiration hazard
May be fatal if swallowed and enters airways. (Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane;
toluene; cyclohexane; n-hexane)
Additional information on tests
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP]. Special hazards arising from the
substance or mixture!
SECTION 12: Ecological information
12.1. Toxicity
Toxic to aquatic life with long lasting effects.

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CAS No Chemical name


Aquatic toxicity Dose [h] | [d] Species Source Method
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
Acute fish toxicity LC50 11,4 mg/l 96 h Oncorhynchus mykiss OECD 203
(Rainbow trout)
Acute algae toxicity ErC50 30 mg/l 72 h Pseudokirchneriella OECD 201.
subcapitata
Acute crustacea toxicity EC50 3 mg/l 48 h Daphnia magna OECD 202
141-78-6 ethyl acetate
Acute fish toxicity LC50 >230 mg/l 96 h Oncorhynchus mykiss OECD 203
(Rainbow trout)
Acute algae toxicity ErC50 3300 mg/l 72 h Desmodesmus
subspicatus
Acute crustacea toxicity EC50 610 mg/l 48 h Daphnia magna (Big
water flea)
108-88-3 toluene
Acute fish toxicity LC50 5,8 mg/l 96 h Oncorhynchus mykiss
(Rainbow trout)
Acute crustacea toxicity EC50 3,78 mg/l 48 h Ceriodaphnia spec
Crustacea toxicity NOEC 0,74 mg/l 7 d Ceriodaphnia spec
110-82-7 cyclohexane
Acute crustacea toxicity EC50 0,9 mg/l 48 h Daphnia magna (Big Safety Data Sheet OECD 202
water flea)

12.2. Persistence and degradability


There are no data available on the mixture itself.
CAS No Chemical name
Method Value d Source
Evaluation
141-78-6 ethyl acetate
OECD 301A - OECD 301F > 60 % 28
Readily biodegradable (according to OECD criteria).
108-88-3 toluene
86% 20
Easily biodegradable (concerning to the criteria of the OECD)

12.3. Bioaccumulative potential


There are no data available on the mixture itself.
Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
141-78-6 ethyl acetate 4,8
108-88-3 toluene 2,65
110-54-3 n-hexane 3,9

BCF
CAS No Chemical name BCF Species Source
141-78-6 ethyl acetate 30
108-88-3 toluene 90

12.4. Mobility in soil


No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No information available.
Further information
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

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SECTION 13: Disposal considerations


13.1. Waste treatment methods
Advice on disposal
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to
applicable legislation.
Waste disposal number of waste from residues/unused products
080409 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS; wastes
from MFSU of adhesives and sealants (including waterproofing products); waste adhesives and sealants
containing organic solvents or other hazardous substances; hazardous waste
Waste disposal number of contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE
CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging
waste); packaging containing residues of or contaminated by hazardous substances; hazardous waste
Contaminated packaging
This material and its container must be disposed of as hazardous waste. Handle contaminated packages in the same way
as the substance itself. Completely emptied packages can be recycled.
SECTION 14: Transport information
Land transport (ADR/RID)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Special Provisions: 163 367 640D 650
Limited quantity: 5L
Excepted quantity: E2
Transport category: 2
Hazard No: 33
Tunnel restriction code: D/E
Inland waterways transport (ADN)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Classification code: F1
Special Provisions: 163 367 640D 650
Limited quantity: 5L
Excepted quantity: E2
Marine transport (IMDG)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint
(Ligroin)
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Revision No: 2,02 - Replaces version: 2,01 GB - EN Print date: 07.02.2019


Safety Data Sheet
according to Regulation (EC) No 1907/2006
Keratex-Primer
Revision date: 07.02.2019 Product code: 5040307003 Page 11 of 12

Marine pollutant: yes


Special Provisions: 163, 367
Limited quantity: 5L
Excepted quantity: E2
EmS: F-E, S-E
Segregation group: IMDG-Code segregation group not applicable
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1263
14.2. UN proper shipping name: Paint
14.3. Transport hazard class(es): 3
14.4. Packing group: II
Hazard label: 3

Special Provisions: A3 A72 A192


Limited quantity Passenger: 1L
Passenger LQ: Y341
Excepted quantity: E2
IATA-packing instructions - Passenger: 353
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 364
IATA-max. quantity - Cargo: 60 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: yes

Danger releasing substance: Ligroine; Low boiling point naphtha


14.6. Special precautions for user
Warning: Combustible liquid.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 3: n-hexane
Entry 48: toluene
Entry 57: cyclohexane
2010/75/EU (VOC): 85,145 % (732,247 g/l)
2004/42/EC (VOC): 85,145 % (732,247 g/l)
Information according to 2012/18/EU E2 Hazardous to the Aquatic Environment
(SEVESO III):
Additional information: P5c
National regulatory information
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile work
protection guideline' (94/33/EC). Observe employment restrictions under the
Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Water contaminating class (D): 2 - clearly water contaminating
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:
Hydrocarbons, C6-C7, n-alkanes, Isoalkanes, cyclics, < 5% n-hexane
ethyl acetate

Revision No: 2,02 - Replaces version: 2,01 GB - EN Print date: 07.02.2019


Safety Data Sheet
according to Regulation (EC) No 1907/2006
Keratex-Primer
Revision date: 07.02.2019 Product code: 5040307003 Page 12 of 12

toluene
SECTION 16: Other information
Changes
This data sheet contains changes from the previous version in section(s): 9.
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
VOC: Volatile Organic Compounds (USA, EU, CH)
DNEL: Derived No-Effect Levels
PNEC: Predicted No-Effect Concentration
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Flam. Liq. 2; H225 On basis of test data
Asp. Tox. 1; H304 Calculation method
Skin Irrit. 2; H315 Calculation method
Eye Irrit. 2; H319 Calculation method
Repr. 2; H361d Calculation method
STOT SE 3; H336 Calculation method
STOT RE 2; H373 Calculation method
Aquatic Chronic 2; H411 Calculation method
Relevant H and EUH statements (number and full text)
H225 Highly flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety
data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the
case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not
necessarily valid for the new made-up material. The information is based on present level of our knowledge. It does not,
however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is
singulary responsible for adhering to existing laws and regulations.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data
sheet.)

Revision No: 2,02 - Replaces version: 2,01 GB - EN Print date: 07.02.2019

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