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Chapter-4
LASER
dN 21
N2
dt spontaneous emission
= A21N2 (2)
But the induced emission depends on the energy density U() of
the radiation field also.
dN
21 N2U()
dt induced emission
= B21N2U() (3)
The coefficients A21, B21 and B12 are known as Einstein’s
coefficients. At thermal equilibrium the rate of upward transition
is equal to the rate of net downward transition. That is,
B12 N1U() = A21N2 + B21N2U()
i.e. U()[B12 N1 − B21N2] = A21N2
A 21 N 2
U() =
B12 N1 − B21N 2
A 21
= (4)
N
B12 1 − B21
N2
According to Boltzmann’s distribution formula,
2 E −E
1 ћω
N1 k BT
= e = e k BT (5)
N2
where, kB is the Boltzmann’s constant and ћ = h = E2 − E1.
Then eqn.4 becomes,
A 21 1
U() = ћω
= ћω
(6)
B B
B12e k BT − B21 12
e B − 21
k T
A 21 A 21
144
E2 E2 E2 E2
E1 E1 E1 E1
Metastable state Metastable state
h=E1−E0
E0 E0 E0 E0
photon h =E1− E0
causes emission of
laser beam. Five
Triggering with a
Photons not in
metastable state.
inverted state
Population
Transition
phase
phase
phase
passed through the assembly, there will be more induced
emissions from the atoms in the higher level than induced
absorptions by atoms in the lower level. The result will be an
amplification of the incident original light. This is the concept that
underlies the operation of a laser.
In a three level laser more
E3 Excited state
than half the atoms must be in
the metastable state for Metastable state
Pumping transition
E2
induced emission. In a four
level laser there are four
h=E2−E1
levels- excited state,
metastable state, intermediate E1
Intermediate state
state and the ground state.
The intermediate state is E0 Ground state
unstable. The laser transition
146
crystal lattice are replaced by Cr3+ ions. The pink color of Ruby
is due to the presence of chromium ions. The length of the ruby
rod is an integral number of half wavelengths of the laser light, so
that the radiation trapped in it forms an optical standing wave
which will stimulate the induced emission. The ruby rod is
surrounded by a glass tube. The optical pumping is achieved by a
helical Xenon flash lamp surrounding glass tube containing the
ruby rod.
The characteristic Excited state
Optical pumping 550nm photons
energy levels of Cr3+ E3 2.25eV
ions are shown in the Metastable state
figure below. The E2 1.79eV
lifetime of the atoms
in the energy level
labeled as E3 is of the
694.3nm
order of 10−8 second input 694.3nm laser
whereas that at the output
metastable state E2 is E1
about 0.003s. The Cr3+ Ground state
ions are excited from the ground state E1 to the state E3 by
absorbing light of wavelength 550 nm from the xenon flash lamp.
Since the lifetime at E3 is very small, the ions quickly undergo
nonradiative transitions and fall to the metastable state. When the
number of ions in the level E2 is greater than that of E1 the
population inversion is achieved. Then photons of wavelength
694.3 nm produced by a spontaneous decay of some Cr3+ ions are
reflected back and forth between the silvered ends of the ruby rod
and stimulated other ions to radiate. As a result a large pulse of
monochromatic coherent red light is emerged out through the
partially silvered end of the rod. Once all the chromium ions in
the metastable state have returned to the ground state the laser
action stops. It is then necessary to send one more flash of
pumping radiation from the xenon tube. Thus the ruby laser
operates in pulses.
151
Laser
He + Ne
beam
Discharge electrodes
Fig.a Partially transmitting mirror
Collision 20.66eV
20.61eV
Metastable state 632.8nm
Laser
18.70eV
Spontaneous emission
Electron collision
Radiationless transition
n type
Optically flat face
Fig.b
Stimulated
due to electrons and emission
holes. As the bias
increases, the current
also increases. Figure
shows the typical
output of a Spontaneous
semiconductor laser emission
versus the current
flowing the
semiconductor laser. Ith Current
Two cases may arise.
1. Current is low: For low currents (below the threshold
current), incoherent light (due to the spontaneous
emission) is emitted from the junction when the
recombination process occurs. This is the light associated
with the light-emitting diodes (LED).
2. High currents: If the current is high enough (above the
threshold current) there are more electrons in the
conduction band at a given energy than in the valance
band and thus the population inversion is achieved. When
the current reaches the threshold value the stimulated
157
ћω3μ 30 1
But, U() = (4)
π 2 c3 kћω
e BT − 1
A 21 ћω3μ 30
And, = (5)
B21 π 2 c3
kћωT
ћω μ e B − 1
3 3 ћω
i.e. = 0
= U ( ω ) e k BT − 1
π c kћω
2 3
e BT
− 1
ћω
Spontaneous emission rate A 21
= = e k BT
−1
Induced emission rate B21U ( ω )
hc 6.6210−34 3108
= e λk BT
−1 = e 60010−9 1.3810−23 2500
−1
= e9.5942 = 14678.394
2. Calculate the ratio between Einstein coefficients for
spontaneous emission A21 and stimulated emission B21 in free
space when the energy difference between the states is 2.2 eV.
Energy difference, E = h = ћω = 2.2 eV
= 2.21.6021910−19 J
E E3
= or, 3
= 3
ћ ћ
E3
ћω3 =
ћ2
A 21 ћω3μ 30 E3 μ30
= =
B21 π 2 c3 ћ 2 π2c3
=
( 2.2 1.60219 10 ) −19 3
= 1.481110−14
162
4.13 Problems
1. Calculate the ratio of the number of spontaneous to stimulated
emissions for an optical source of temperature 1000 K with
angular frequency = 31015 sec−1. Given ħ = 1.05410−34
and kB = 1.3810−23 SI units. [Ans. 0.89331010]
2. Calculate the ratio of the stimulated emission rate to the
spontaneous emission rate for an incandescent lamp operating
at a temperature of 1000 K. It may be assumed that the average
operating wavelength is 0.5 m. [Ans. 3.02710−13]