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1. A 6.53-g sample of CaCO3 is treated with excess hydrochloric acid.

The resulting
reaction produces 1.72 L of carbon dioxide gas at 28 oC and 743 torr pressure.
(a) Write balanced chemical equations for the reactions that occur between
hydrochloric acid and CaCO3.

(b) Calculate the total number of moles of carbon dioxide that forms from these
reactions.

2. Helium is collected over water at 25 oC and 1.00 atm total pressure. What total
volume of gas must be collected to obtain 0.586 g of helium? (At 25 oC the vapor
pressure of water is 23.8 torr.)

3. Ammonium nitrite, NH4NO2, decomposes on heating to form N2 gas:


NH4NO2 (s)à N2(g) + 2 H2O(l)
When a sample of NH4NO2 is decomposed, 511 mL of N2 gas is collected over
water at 28 oC and 745 torr total pressure. How many grams of NH4NO2 were
decomposed?

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