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    4 views3 pages

    2021

    Uploaded by

    Hadi

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    wwwleadtocss.com FEDERAL PUBLIC SERVICE COMMISSION RECRUITMENT TO POSTS IN BS-17 UNDER THE FEDERAL GOVERNMENT, 2021 (COMPETITIVE EXAMINATION FOR Roll Number (CHEMISTRY, PAPER] TIME ALLOWED: [(PART-IMCQs) 30 MINUTES, MAXIMUM MARKS: 20 THREE HOURS __[ (PART-II) 2 HOURS & 30 MINUTES MAXIMUM MARKS: 80, NOTE. Candidate must write Q.No. i the Answer Book in accordance with Q.No. in the Q.Paper. ‘Attempt ONLY FOUR gucstions from PART-I. All questions carry EQUAL marks. Gii)_Use of simple calculator is allowed. iv) Periodic Table is on page-2. (v) Extra attempt of any question or any part of the attempted question will not be considered. os os PART-II (a) Fephin applications of Schdinger wave equation to hydrogen and hydrogen (10) ke Atom () @) Give Mobculhr interpretation of entropy. 0s) a0) i) Exphin factors affecting the rate of a chemical reactions (05) (a) What are the uses of chelates on (b) State and exphin Nomenchure of coordination complexes 7) (©) Explain VBT (Valence Bond Theory) of coordination complexes in detail oo) (a) Explin photweleotric effoct and probabilty density, 0) () @ Explain Figen function & Figen value. (03) (10) Gil) Derive Schitdinger wave equation for a partic in one dimensional box. (OS) (a) Predict molecular shapes using Valence Shell Eketron Pair Repubion (VESPER) (10) model, (b) @ Exphin the experimental techniques for determination of order of reaction. (05) (10) i) Write a note on thermochemistry and calorimetry 05) (a) Derive a relation for dependence of Gibbs free energy on temperature or Gibbs (07) Helmholtz equation. ()) What isothermal process? Exphin work done in isothenmal reversible expansion of (07) an teal gas. (©) Explain fingacity and activity (06) (a) Discuss common ion effect and its industrial applications. in detail 8) (b) Describe significance of pk. pki. pH. 0) (©) Write a note on basic concepts of chemical equilibrium. (06) Write notes on the following (® Debye-Huckel theory. on (i) Nemst’s equation, or) Gi) Pkctrochemic 0) 20) 2 2 20) 2m 20) wwwleadtocss.com FEDERAL PUBLIC SERVICE COMMISSION (COMPETITIVE EXAMINATION FOR Roll Number RECRUITMENT TO POSTS IN BS-17 UNDER THE FEDERAL GOVERNMENT, 2021 CHEMISTRY, PAPER-II TIME ALLOWED: [(PART-1 MCOs) 30 MINUTES MAXIMUM MARKS: 20 HouRS __| (PART-II) 2 HOURS & 30 MINUTI MAXIMUM MARKS: 80 Candidate must write Q.No. i the Answer Book in accordance with Q.No. in the Q.Paper. ‘Attempt ONLY FOUR gucstions from PART-I. All questions carry EQUAL marks. Use of simple calculator is allowed. iv) Periodic Table is on page-2. (v) Extra attempt of any question or any part of the attempted question will not be considered. PART-II 2.2.(@) Describe Gero that influence keto-enol taaomerization Elaborate the statement with the (10) help of examples, io io mmeesenen. tal ee oo FER Sleigh tnd of lipemic Gi) HINOs.FS04 Gi) Conc. HLS0% c i ste cr AICRC eautv)-dien 150, 6) Alkaline KMnOs () Account for the follow (05 marks each) (10) (20) @ Terampkecular H-bonting. is stronger than intermolecular H-bonding Gi) Control of muckophilic substitution reaction over elimination reactions Q4.(@) Write down reagents, reaction conditions and important steps for the following: (10) @ orobervene to 2.4-

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