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A RENEWABLE
PATHWAY TOWARDS
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BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
Challenge
In the long run, bioLPG has
the potential to become
carbon neutral depending
on the development of new
production processes.
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BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
TABLE OF
CONTENTS
Our
Vision
The ambition of the European Union is to be climate
neutral by 2050. The European LPG industry is 03 OUR VISION
07 TRANSITION TO BIOLPG
08 BIOLPG PRODUCTION
Our industry truly believes 09 LPG AND BIOLPG FOR THE EU
that LPG and bioLPG, as GREEN DEAL
3 4
BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
60%
..........................................................................................................
OR
It is a gaseous fuel that contributes to cleaning the air in Europe’s
countryside and cities. With the right policy environment in place for
Natural Gas Oil Production of all LPG produced
the producers to secure the necessary feedstock and sustain a stable globally derives from
business model, the entire European LPG market can become 100% and thus resource efficient by its very nature natural gas extraction
renewable by 2050. Our industry will be thriving to deliver on this
ambitious objective.
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BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
TRANSITION BIOLPG
TO BIOLPG PRODUCTION
The rest of the produced bioLPG, another 100 kilotonnes Location: Sweden
Location: Finland
Capacity: 180 kt
Capacity: 100 kt
a year, is used today internally as a process fuel. Sometimes
bioLPG is also put on the market without being labelled Location: USA
Location: Finland
Capacity: 80 kt Location: Netherlands
as such. Capacity: 1000 kt Capacity: 260 kt
• ENI (ITALY)
Location: France
• GLOBAL BIOENERGIES (FRANCE) Capacity: 500 kt
Location: Spain
Location: USA Capacity: 125 kt
Capacity: 250 kt
Location: Italy
BIOGAS CONVERSION TO BIOLPG IS (two locations)
Capacity: 550 kt
POTENTIALLY ATTRACTIVE TO ‘STRANDED’ Location: USA
Capacity: 580 kt
..............................................................................................
Location: Brazil
Capacity: 230 kt
Less than 1% of biogas produced in Europe is injected to the
gas grid. Majority of biogas is currently produced in remote
locations which are unlikely to make biomethane injections
in the future. It is reasonable to presume that significant
amounts of biogas will still be stranded from the grid.
Other US projects in Multiple producers
Conversion to bioLPG and distribution using the existing development capacity app. in China capacity:
LPG infrastructure would in many cases be most attractive 1,000 kt 320 kt
economically, if a biogas-to-bioLPG process were
commercialised. This process is being pursued by several
technology suppliers. Source: Atlantic Consulting:
NB. The above refinery capacity figures represent capacities for HVO biodiesel. Most of these plants
produce bioLPG as a co-product at approx. 5-7% by weight of the biodiesel output. These capacities
* Process Technologies and Projects for
reflect the rated amount that a given plant can manufacture per year, actual production can be lower.
BioLPG (2018) E. Johnson
7 8
LPG AND BIOLPG FOR
THE EU GREEN DEAL
Liquid Gas Europe sees a significant role for the
European LPG industry in meeting the EU Green Deal
ambition and achieving climate neutrality by 2050.
ADDED VALUE
POLICY BENEFITS
OF BIOLPG
Renovation Wave BioLPG can turn the existing Scaling up the uptake of
Initiative rural building stock into ‘future- solar thermal and hybrid
proofed’ homes using readily solutions
available, well-established and
affordable heating solutions.
LPG heating solutions also offer
rural communities an opportunity
to invest in common small LPG
networks
9 10
BIOLPG A RENEWABLE PATHWAY TOWARDS 2050
To reap the benefits, LPG and fuel cells and hybrid systems (an electric heat pump
bioLPG must be recognised within with an LPG boiler, for cold days). Hybrid heating
policy frameworks and regulations. systems are the enabler for affordable renewable
The producers need to be able to residential heating and an improvement in the overall
and sustain a stable business model hybrids offer bigger environmental benefits than
11 12
In most cases, bioLPG is produced as a co-product, a minor output of a multi-product process.
PATHWAYS TO BIOLPG
All possible synthesis routes to bioLPG (and their development status): conventional and advanced
chemical processes, biological processes, and other, are described below. Only one process is
already commercial: the HVO diesel production.
VEGETABLE OIL
ANIMAL FATS
TALLOW LIPID HYDROTREATMENT HVO DIESEL JET FUEL CO-PRODUCT
USED COOKING OIL
BIOLPG
BIOREFINING TRANSESTERIFICATION FAME DIESEL GLYCERINE GYCERINE-TO-BIOLPG
LIGNOCELLULOSIC BIOMASS
SEWAGE
BIOGAS
OLIGIMERISATION OF BIOGAS
ANAEROBIC DIGESTION UPGRADING OF BIOGAS BIOMETHANE
SYNGAS SYNTHESIS
RENEWABLE ELECTRICITY,
POWER-TO-X FT SYNTHESIS OF SYNGAS DIESEL JET FUEL CO-PRODUCT
WATER AND CAPTURED CO2 RENEWABLE
LPG
METHANATION OF CO2 SYNTHETIC METHANE SYNTHESIS
BY ELECTROLYTICALLY
OBTAINED HYDROGEN
13 14
POTENTIAL BIOLPG TECHNOLOGY EXAMPLES OF EXISTING
TECHNOLOGIES & PROCESS
YIELD (OF TOTAL FUEL) READINESS PRODUCERS OR PROJECTS*
BIOREFINING
Most bioLPG today is produced as a co-product of the hydrogenated vegetable oil (HVO) process,
Transesterification 70% Commercial phase Hulteberg (Sweden)
where vegetable oils are treated with hydrogen to produce renewable diesel or aviation fuel.
FAME biodiesel and glycerine can be produced through transesterification of oils. Glycerine Byogy (USA), Gevo (USA), UOP
Fermentation 100% Pilot phase
can be used as a feedstock and reacted with hydrogen to yield bioLPG and water. (USA), Vertimass (USA)
PYROLYSIS
Pyrolysis is a process of thermal decomposition in the absence of oxygen. In fast pyrolysis, biomass
BTG (the Netherlands),
rapidly decomposes to generate vapours, aerosols, gases, including bioLPG, and some charcoal.
5% Demonstration phase Gas Technology Institute
At the next step, after cooling and collection, a dark brown mobile liquid is formed, pyrolysis oil.
(India), UPM (Sweden)
Through catalysis cracking, it can be transformed into bioLPG.
GASIFICATION
Gasification is a complete thermal breakdown of the biomass particles into syngas, volatiles and
Thermal gasification of biomass ash in an enclosed reactor (gasifier) in the presence of any externally supplied oxidizing agent
20%
(followed by methanation) (air, O2, H2O, CO2, etc.). Syngas through methanation is transformed to SNG, which can be futher
synthesised to bioLPG.
BioTFuel project by
Total (France),
Alternatively, syngas goes through a cleaning stage to remove impurities before the gas can be used Commercial
Cadent (UK),
in Fischer-Tropsch (FT) synthesis. The FT process means producing liquid fuels from syngas using /demonstration
Fischer-Tropsch (FT) synthesis of Enerkem (the Netherlands),
catalysts. The intermediate product is a solid mixture of hydrocarbons, known as FT wax. It then goes 5% phase
syngas followed by hydrocracking Fulcrum (USA),
through a process of catalytic cracking to produce drop-in fuels such as petrol, diesel and jet fuel, as
Red Rock (USA)
well as LPG.
Syngas can be also synthesised to methanol. In the next step, methanol can be used to produce
Methanol synthesis from syngas 8%
gasoline. BioLPG would be a co-product in significant quantities of this process.
ANAEROBIC DIGESTION
Anaerobic digestion is a fermentation process, which takes place in a closed airtight digester where Research
Oligimerisation of biogas Alkcon (USA),
organic raw materials such as manure, food waste, sewage sludge and organic industrial waste are 90% & development
PlasMerica (USA)
converted into biogas and digestate as products. phase
POWER-TO-X
Methanation of CO2 by Power-to-x is a technology that converts captured CO2 and hydrogen made from water by electrolysis
electrolytically obtained hydrogen using renewable electricity into gas or, after further synthesis, fuel. Both syngas and synthetic methane 10% Research [Nordic Blue Crude (Norway),
can be further synthesised to renewable LPG.
& development Sunfire (Germany), Synhelion
phase (Switzerland), Repsol (Spain)]
Renewable LPG would also be a co-product of Fischer-Tropsch synthesis of syngas for synthetic
FT synthesis of syngas 10%
fuels (e-fuels).
Methanol synthesis from syngas Synthetic methanol can be produced using hydrogen made with renewable electricity and captured Pilot/demonstration Carbon Recycling
10%
CO2. Further it can be used as a feedstock to produce gasoline and bioLPG as a co-product. phase International (CRI) (Iceland)
IN 2050 12
3 , 962
K T/ Y E A R
8
3 ,175
Potential future This forecast does not consider the
possibility of LPG displacing competing 6
demand for LPG fuels, thereby gaining market share.
In the next 30 years, the non-chemical However, the European Commission
European LPG demand* will decline by projects heating oil and coal demand in
4
3,258
25-50% from today’s some 16 million building heating to decline by about 70%
tonnes. This drop can be explained from 2020 to 2030. Further decarbonisation
by overall trends in European energy of rural commercial and industrial heating
demand leading to 2050: needs could be achieved with LPG. 2
• Final energy consumption will decline One can imagine that in the short to 2 , 501
by around one-third medium term, LPG could displace heating
oil and coal in off-grid homes, businesses, 0
• Electrification will rise almost as
and industries, due to its lower carbon BIOREFINING G A S I F I C AT I O N , P OW E R -TO -X BIOGAS
sharply, mainly displacing liquid fuels in
footprint and lower air pollutant emissions. (LIPIDS) PY R O LYS I S (O P E R AT E D BY CO N V E R S I O N
transport and space heating and cooling REFINERS)
But for consumers to be able to accept and
• Gaseous fuels’ consumption will decline, participate in the further energy transition,
but not as sharply as liquids they need to have access to renewable LOW L P G D E M A N D HIGH LPG DEMAND
energy sources at an affordable price.
• Solid fuels will mostly disappear
in the short-term and bioLPG in the future renewable energy needed to reach the
climate-neutrality ambition.
Decarbonising off-grid homes, businesses • The upcoming review of the Energy Taxation • European and national R&D funding
and industries, as well as the passenger Directive should continue allowing Member should be made available for low TRL
car park with LPG and through the gradual States to exempt from energy and CO2 processes to obtain bioLPG through
introduction of bioLPG is the best chance taxation LPG and bioLPG Horizon Europe or the LIFE programme
of reaching climate-neutrality cost- • The bioLPG production should be
• The Commission should carefully consider
effectively. Without having to resort to subsidised to allow various technologies
the impact of any new proposals have on low-
expensive upgrading or future retrofitting of to mature
income households in rural areas, which might
the heating systems the European rural areas
be disproportionately affected by policies • Renewable and low-carbon fuel
can lock-into lower CO2 emissions. BioLPG encouraging expensive retrofits producers should be incentivised to
fully complements existing alternative fuel
capture or directly produce bioLPG
infrastructure, not only for new car sales, but • The revision of the Alternative Fuels
also serve to decarbonise and improve the air Infrastructure Directive should maintain the • Generate more research, development
current definition of “alternative fuels”, some and deployment funding for transport
quality from the existing fleet.
of which can easily penetrate the market and modes and alternative fuels if their climate
• The Renovation Wave initiative should are compatible with the internal combustion targets become more ambitious
encourage providing European and national engine (ICE) technologies
incentives for consumers to switch from
high carbon fuels (such as coal or heating oil)
to LPG and bioLPG in the future
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LPG industry’s
Pledge BIO
LPG
Liquid Gas Europe pledges to transition ....................................................................
to 100% renewable bioLPG by 2050. To further grow the
bioLPG market, the
policymakers’ actions
In recent years, the LPG industry has
alone are not sufficient.
succeeded in commercialising and scaling ....................................................................
bioLPG distribution. The industry delivers
a new renewable energy source through It is the industry’s ambition to continue
advancing both bioLPG uptake and
a readily available, well-established and production by:
affordable supply chain to energy-users
• Advising consumers and businesses
who are not connected to the gas grid. on the possibility and advantages of
Nevertheless, rural consumers’ choice of flexible and switching to LPG in the short-term and
affordable energy sources is still limited. The reality of bioLPG in the future
rural private and non-domestic properties is that they • Educating stakeholders and
are often old or historic buildings that are difficult to policymakers about bioLPG
treat and hard-to-decarbonise. There is no one size fits and its potential
all solution to provide sufficient warmth at an affordable
• Approaching investors on possible
price, avoid expensive retrofitting and keep the visual
projects producing bioLPG
integrity of a property.
• Considering investing in the
Liquid Gas Europe advocates a mixed technology
production of bioLPG
approach to the transport sector and heating
technologies in off-grid homes, businesses and • Joining consortia applying for
industries. It is the most effective approach to reduce EU funding of research projects
their carbon and air pollutant emissions today and in • Sponsoring industry-funded PhD,
the future with bioLPG. collaborating with research labs or
offering research grants to look into
Today Autogas is the number one alternative fuel
new technology pathways for bioLPG
in the EU, counting 8 million vehicles and 35,000
fueling stations. Further, converting existing vehicles
to Autogas is affordable for the consumer, and a cost-
effective solution to accelerate road transport emissions
reduction efforts from today’s car park. All these efforts
are a perfect basis for the segment to increase the
uptake of bioLPG.
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ANNEX: TECHNOLOGIES
AND PROCESSES FOR THE
BIOLPG PRODUCTION
Pyrolysis to biofuels/biogases
SUBSTITUTE FOR
HEAVY FUEL OIL
CLEANING PYROLYSIS
H VO DISTILL ATION OIL
B I O P R O PA N E FLUID CAT
CRACKER
OV E R H E A D S
GASOLINE
LPG
BIO-OIL D E D I C AT E D H VO B I O D I E S E L Grinding
H Y D R O T R E AT E R BIOMASS
Drying PY R O LYS E R BIO-ASPHALT TO MARKET
6 0 0 - 9 0 0 OC
N O OX YG E N
H VO
B I O P R O PA N E
CHAR
AIR
COMBUSTION FOR
HEAT AND/OR POWER
DIESEL
AIR GASOLINE
H2
S E PA R AT I O N JET LPG
UNIT
DIGESTER BIOGAS
BIOMASS LPG AND HIGHER
3 5 - 4 0 OC 50% CO2 OLIGOMERISATION HYDROCARBONS
FT WAXES WET
FISCHER HYDRO N O OX YG E N 50%CH4
TROPSCH C 3 -C 12 TREATMENT
OX YG E N STEAM
D I G E S TAT E
Grinding TO S O I L
BIOMASS GAS NATU R AL
Torrefaction CONDITIONING BIOMETHANE
GASIFIER SYNGAS GAS MeOH/DME METHANOL GASOLINE CONDITIONING GAS G RID
6 0 0 - 9 0 0 OC H2 & CO CONDITIONING R E AC T O R DME REACTOR
Sorting
WA S T E
M U N I C I PA L Shredding
OR Drying WA S T E Natural BIOGAS
C O N TA M I N A N T S
INDUSTRAL L A N D F I L L Digestion COLLECTOR
GASOLINE
S L AG C O N TA M I N A N T S
LPG
PLASMA OR METHANE
C ATA LYS I S ETHANE
PROPANE
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Power-to-X
LOW- C A R B O N
P OW E R
WAT E R E L E C T R O LYS E R
LOW- C A R B O N
P OW E R
TO T H E G A S TO B I O M A S S
GRID OR H2/ GASIFIER
GAS GRID
SYNGAS
S TO R AG E
G E N E R ATO R
SYNGAS
H 2 & CO
SYNGAS
G E N E R ATO R
DIESEL
GASOLINE JET
LPG
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