Datos experimentales Datos experimentales Valor de T absoluta

(Temperatura °C) (Presión de vapor mmHg) Valor de T absoluta 1/T (K) LnP
25.00 23.76 298.15 0.0033450 3.17
30.00 31.82 303.15 0.0032987 3.46
35.00 42.18 308.15 0.0032452 3.74
40.00 55.32 313.15 0.0031940 4.01
45.00 71.88 318.15 0.0031432 4.28
50.00 92.51 323.15 0.0030945 4.53
60.00 149.38 333.15 0.0030010 5.01
70.00 233.70 343.15 0.0029142 5.45
75.00 289.10 348.15 0.0028723 5.67
80.00 355.10 353.15 0.0028317 5.87
90.00 525.76 363.15 0.0027537 6.26
92.00 566.99 365.15 0.0027386 6.34
92.00 588. 6 366.15 0.0027311 6.38
(Temperatura °C) 1/T (K) LnP
25.00 0.0033450 3.17
30.00 0.0032987 3.46
35.00 0.0032452 3.74
40.00 0.0031940 4.01
45.00 0.0031432 4.28
50.00 0.0030945 4.53
60.00 0.0030010 5.01
70.00 0.0029142 5.45
75.00 0.0028723 5.67
80.00 0.0028317 5.87
90.00 0.0027537 6.26
92.00 0.0027386 6.34
92.00 0.0027311 6.38
 T (°K) vs Presión de vapor (mmHg) LnP
600.00 7.00
6.00
500.00
5.00
400.00 4.00
(Presión de vapor mmHg)
3.00
300.00
2.00
200.00 1.00

100.00 0.00

0 00 0 00 0 00 0 00
0.00 27 28 29 30
00 00 00 00 00
20.00 40.00 60.00 80.00 100.00 0. 0. 0. 0. 0.

LnP vs T (°K)
7.00 LnP=5167.53/T+20.5 valor obtenido
6.00 Formula de la pendiente: m=Hv/R R=
Al despejar Hv: Hv=mR
5.00 Sustituyendo: (5167.53°K)(8.3
LnP Resultado:42.962kJ/mol
4.00
El valor reportado en la literat
3.00 Hv=43.2429kJ/mol
El valor obtenido gráficamente c
2.00 Hv=42.962kJ/mol
1.00 %E=(Vteo-Vexp/Vexp)100%
%E=[(43.24
0.00 42.962kJ/mol)/43.2429kJ/mol]100%
20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00
 LnP vs 1/T (°K)

LnP
Linear (LnP)

0 00 0 00 0 00 0 00 0 00 0 00 0 00
28 29 30 31 32 33 34
00 00 00 00 00 00 00
0. 0. 0. 0. 0. 0.

LnP=5167.53/T+20.5

.53/T+20.5 valor obtenido con la calculadora

a pendiente: m=Hv/R R=8.314J/molK
ar Hv: Hv=mR
tituyendo: (5167.53°K)(8.314J/molK)
2.962kJ/mol
valor reportado en la literatura corresponde a
kJ/mol
or obtenido gráficamente corresponde a
.962kJ/mol
%E=(Vteo-Vexp/Vexp)100%
%E=[(43.2429kJ/mol-
ol)/43.2429kJ/mol]100% %E=0.65]%