Organic Chemistry Exam

Class Name Roll No Score

I. Choice questions (2×20 = 40 marks)

1. Which set of hybridization states of C1, C2 of the following molecule is correct?

A. C1: sp C2: sp2 C3:sp3 B. C1: sp2 C2: sp3 C3: sp2
C. C1: sp C2: sp2 C3:sp D. C1: sp C2: sp3 C3:sp

2. which compound is NOT a constitutional isomer of but-2-ene, CH3CH=CHCH3 ?

A. B. C. D.

3. Which of the following compounds is NOT Lewis acid?

A. BF3 B. AlCl3 C. HS- D. Ag+

4. Which of A-D is the most stable conformation?

A. B. C. D.

5. Which is the most stable structure of trans-1-isopropyl-4-methylcyclohexane?

A. B. C. D.

6. which of the following compounds can exist as cis-trans isomer?

A. B. C. D.

7. Which of the following equations does not show the correct main products?

A.
B.

C.

D.

8. Which of (a)-(d) is not aromatic?

A. B. C. D.

9. Which of the reagents can distinguish the ethylene and acetylene?

A. Br2/CCl4 B. KMnO4/H+ C. Ag(NH3)2+/OH- D. H2SO4

10. Which of A-D is the CORRECT IUPAC name of the following compound?

A. 2-isopropyl-3-methylheptane B. 3-ethyl-2,4-dimethylheptane
C. 5-ethyl-4,6-dimethylheptane D. 3-methyl -2-isopropylheptane

11. which of the following moleculars is chiral?( )

A CHCl3 B C D

12. Rank the following groups from highest to lowest in priority

(1)-CH2CO2H (2)-CH2NH2 (3) -CHO (4)-COCH3
A (1)>(2)>(3)>(4) B (1)<(2)<(3)<(4) C(3)>(4)>(1)>(2) D(1)>(2)>(3)>(4)

13. Which of the following compounds has an S configuration?

H
COOH
C
D
H OH
Br
A COOCH2CH3 B CH3 C D

14. Which of the following compounds is a meso compound?

A B C D

15. Optical activity molecules which rotate plane- polarized light in a

counterclockwise direction are said to be
A、levorotary B、of R configuration C、dextrorotary D、 of S configuration
16. What is the relationship between the following compounds?

A、enantiomers B、diastereomers
B、constitutional isomers D、conformational isomers

17. Which of the following compounds reacts most rapidly during nitration?

A、 B、 C、 D、

18. Which of the following is the electrophile that attacks the aromatic ring during
nitration?
A NO2 B NO2- C NO2+ D NO3+

19. Which of the following is the ortho/para directing subsituents but deactivating?
A -NHCOR B -R C -OH D -X

20. Which kind of reaction about Halogenation、Nitration、Sulfonation of Benzene?

A. Electrophilic Addition B Electrophilic Substitution
B. C Nucleophilic Substitution D Nuclephilic Addition

II. Ture or False (1×6=6 marks)

1. A secondary radical is more stable than a tertiary radical.
2. If a molecular have chiral carbon,it is a chiral molecular.
3. Alkenes and cycloalkanes show cis-trans isomerism.
4. The foundation for Markovnikov’s rule is the relative stability of carbocation
intermediates.
5. Constitutional isomers have the same molecular formula and the same connectivity
of their atoms.
6. A deactivating group will cause its benzene ring to react slower than benzene
itself.

III. Name this compound according IUPAC (2×2 = 4 marks)

1. 2.