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Moye Moye

Subject : Mathematics, Paper Set : 1


Physics, Chemistry Test Date : 16-02-2024
Standard : 11
Time : 3H:0M
Total Mark : 600

(9) The number of elements in the set


......... Mathematics - Section A (MCQ) .........
{x ∈ R : (|x| − 3)|x + 4| = 6} is equal to
(A) 3 (B) 2
(1) Let S = {1, 2, 3, ....., 100}. The number of non-empty
subsets A of S such that the product of elements in A is (C) 4 (D) 1
even is 
(A) 2100 − 1 (B) 250 (250 − 1) (10) Let S = (x, y) ∈ N × N : 9(x − 3)2 + 16(y − 4)2 ≤ 144
and T = (x, y) ∈ R × R : (x − 7)2 + (y − 4)2 ≤ 36 Then
(C) 250 − 1 (D) 250 + 1 n(S ∩ T ) is equal to ......
(2) Consider the two sets : (A) 27 (B) 26
A = {m ∈ R : both the roots of x2 − (m + 1)x + m + 4 = 0
are real } and B = [−3, 5) (C) 25 (D) 24
Which of the following is not true? S
50 S
n
(11) Let Xi = Yi = T where each Xi contains 10
(A) A − B = (−∞, −3) ∪ (5, ∞) i=1 i=1
elements and each Yi contains 5 elements. If each
(B) A ∩ B = {−3} element of the set T is an element of exactly 20 of sets Xi
(C) B − A = (−3, 5) ’s and exactly 6 of sets Yi ’s, then n is equal to
(D) A ∪ B = R (A) 45 (B) 15
(C) 50 (D) 30
(3) Let X = {n ∈ N : 1 ≤ n ≤ 50}. If
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A = {n ∈ X : n is a multiple of 2} and (12) In a class of 140 students numbered 1 to 140, all even
B = {n ∈ X : n is a multiple of 7}, then the number of numbered students opted Mathematics course, those
elements in the smallest subset of X containing both A whose number is divisible by 3 opted Physics course and
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and B is those whose number is divisible by 5 opted Chemistry


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(A) 29 (B) 26 course. Then the number of students who did not opt for
any of the three courses is
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(C) 31 (D) 34
 √ (A) 102 (B) 42
(4) Let P = θ : sin θ − cos θ = 2 cos θ and
 √
Q = θ : sin θ + cos θ = 2 sin θ be two sets. Then (C) 1 (D) 38
(A) P ⊂ Q and Q − P ̸= ϕ (B) Q ̸⊂ P (13) The number of elements in the set {n ∈ N : 10 ≤ n ≤ 100
and 3n − 3 is a multiple of 7} is .........
(C) P = Q (D) P ̸⊂ Q
(A) 15 (B) 14
(5) Let A = {n ∈ N : H.C.F.(n, 45) = 1} and Let
B = {2k : k ∈ {1, 2, . . . , 100}}. Then the sum of all the (C) 13 (D) 12
elements of A ∩ B is (14) Out of all the patients in a hospital 89 % are found to be
(A) 5264 (B) 5265 suffering from heart ailment and 98 % are suffering from
(C) 5255 (D) 5235 lungs infection. If K % of them are suffering from both
ailments, then K can not belong to the set :
(6) Set A has m elements and Set B has n elements. If the
total number of subsets of A is 112 more than the total (A) {79, 81, 83, 85} (B) {84, 86, 88, 90}
number of subsets of B, then the value of m × n is (C) {80, 83, 86, 89} (D) {84, 87, 90, 93}
(A) 7 (B) 4
(15) The number of 3−digit numbers, that are divisible by either
(C) 28 (D) 24 2 or 3 but not divisible by 7 is ..........

(7) Let A = n ∈ N | n2 ≤ n + 10, 000 , B = {3k + 1 | k ∈ N } (A) 513 (B) 512
and C = {2k | k ∈ N }, then the sum of all the elements of
(C) 514 (D) 511
the set A ∩ (B − C) is equal to .....  √
(A) 832 (B) 412 (16) If A = {x ∈ R : |x − 2| > 1}, B = x ∈ R : x2 − 3 > 1 ,
C = {x ∈ R : |x − 4| ≥ 2} and Z is the set of all integers,
(C) 963 (D) 123 then the number of subsets of the set (A ∩ B ∩ C)c ∩ Z is
(8) Let S = {4, 6, 9} and T = {9, 10, 11, . . . , 1000}. If .... .
A = {a1 + a2 + . . . + a1 : k ∈ N, a1 , a2 , a3 , . . . , a1 ∈ S} (A) 256 (B) 64
then the sum of all the elements in the set T − A is equal
(C) 8 (D) 16
to ......
(A) 10 (B) 9 (17) Let A, B and C be sets such that ϕ ̸= A ∩ B ⊆ C. Then
(C) 11 (D) 12 which of the following statements is not true ?

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(A) If (A − C) ⊆ B then A ⊆ B people read both the newspapers, then a possible value of
x can be
(B) If (A − B) ⊆ C then A ⊆ C (A) 65 (B) 37
(C) (C ∪ A) ∩ (C ∪ B) = C (C) 29 (D) 55
(D) B ∩ C ̸= ϕ (26) Let A = {x ∈ R : |x + 1| < 2} and
(18) In a school, there are three types of games to be played. B = {x ∈ R : |x − 1| ≥ 2}. Then which one of the following
Some of the students play two types of games, but none statements is NOT true ?
play all the three games. Which Venn diagrams can justify (A) A − B = (−1, 1) (B) B − A = R − (−3, 1)
the above statement ? (C) A ∩ B = (−3, −1] (D) A ∪ B = R − [1, 3)
(27) Let A = {1, 2, 3, 4, 5, 6, 7} and B = {3, 6, 7, 9}. Then the
number of elements in the set {C ⊆ A : C ∩ B ̸= ϕ} is
(A) 111 (B) 112
(C) 113 (D) 114
(28) If X = {4 − 3n − 1 : n ∈ N } and Y = {9(n − 1) : n ∈ N },
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(A) P and Q (B) P and R then X ∪ Y = . . . . .


(C) None of these (D) Q and R (A) X (B) Y

(19) In a certain town, 25% of the families own a phone and 15% (C) N (D) None of these
own a car; 65% families own neither a phone nor a car and (29) Let A = {a, b, c} and B = {1, 2, 3, 4} Then the number of
2, 000 families own both a car and a phone. Consider the elements in the set C = {f : A → B | 2 ∈ f (A) and f is
following three statements not one-one } is
(A) 5% families own both a car and a phone
(A) 18 (B) 19
(B) 35% families own either a car or a phone
(C) 40, 000 families live in the town (C) 17 (D) 20
Then,
(30) Two newspaper A and B are published in a city. It is
(A) Only (A) and (C) are correct. known that 25% of the city populations reads A and 20%
(B) Only (B) and (C) are correct reads B while 8% reads both A and B. Further, 30% of
those who read A but not B look into advertisements and
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(C) All (A), (B) and (C) are correct. 40% of those who read B but not A also look into
(D) Only (A) and (B) are correct advertisements, while 50% of those who read both Aand B
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look into advertisements. Then the percentage of the


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(20) The
 number2 of elements in the set population who look into advertisement is
n ∈ Z : n − 10n + 19 < 6 is ........... (A) 12.8 (B) 13.5
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(A) 12 (B) 18
(C) 13.9 (D) 13
(C) 24 (D) 6
(31) Let A : {1, 2, 3, 4, 5, 6, 7}. Define B = {T ⊆ A : either 1 ∈
/T
(21) Let A = {θ : sin (θ) = tan (θ)} and B = {θ : cos (θ) = 1} or 2 ∈ T } and C = {T ⊆ A : T the sum of all the elements
be two sets. Then of T is a prime number }. Then the number of elements in
(A) A = B (B) A ̸⊂ B the set B ∪ C is . . . . . .
(C) B ̸⊂ A (D) A ⊂ B and B − A ̸= ϕ (A) 107 (B) 106

(22) An organization awarded 48 medals in event ’A’,25 in event (C) 105 (D) 108
’B ’ and 18 in event ’ C ’. If these medals went to total 60 (32) A survey shows that 73% of the persons working in an
men and only five men got medals in all the three events, office like coffee, whereas 65% like tea. If x denotes the
then, how many received medals in exactly two of three percentage of them, who like both coffee and tea, then x
events? cannot be
(A) 10 (B) 9 (A) 63 (B) 38
(C) 21 (D) 15 (C) 54 (D) 36
(23) If A = {x ∈ R : |x| < 2} and B = {x ∈ R : |x − 2| ≥ 3} then
(A) A ∪ B = R − (2, 5) (B) A ∩ B = (−2, −1) ............. Physics - Section A (MCQ) .............
(C) B − A = R − (−2, 5) (D) A − B = [−1, 2)
(24) Let√S = {x ∈√R : √
x ≥ 0 and (33) Which of the following physical quantities have the same
2 | x − 3| + x ( x − 6) + 6 = 0} then S : . . . dimensions?


(A) contains exactly one element. (A) Electric displacement ( D ) and surface charge density
(B) contains exactly two elements (B) Displacement current and electric field
(C) contains exactly four element. (C) Current density and surface charge density
(D) is an empty set (D) Electric potential and energy

(25) A survey shows that 63% of the people in a city read (34) If R, XL . and XC represent resistance, inductive
newspaper A whereas 76% read newspaper B. If x% of the reactance and capacitive reactance. Then which of the

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following is dimensionless: and time in two systems respectively are
(A) RXL XC (B) √ R n3 n2
XL XC (A) m3 L1 = L2 and m T1 = T2
XL
(C) XLRXC (D) R X (B) L1 = n4
and T1 = n2
C m2 L2 m T2
(35) A⃗ is a vector quantity such that |A|
⃗ = nonzero constant. n2 n4
⃗? (C) L1 = m L2 and T1 = m 2 T2
Which of the following expressions is true for A
→ −
− → → −
− → n2 n4
(A) A · A = 0 (B) A × A < 0 (D) m L1 = L2 and m2 T1 = T2
→ −
− → → −
− →
(C) A × A = 0 (D) A × A > 0 (44) Given below are two statements: One is labelled as
Assertion A and the other is labelled as Reason R.
(36) A physical quantity of the dimensions of length that can
e2 Assertion A : Product of Pressure (P ) and time (t) has the
be formed out of c, G and 4πε 0
is [c is velocity of light, G is same dimension as that of coefficient of viscosity.
the universal constant of gravitation and e is charge ] Force
q Reason R : Coefficient of viscosity = Velocity gradient
Ge2
(A) 12 e2 (B) c1 4πε Question : Choose the correct answer from the options
c G4πε0 0

q q given below
1 Ge2 Ge2
(C) c2 4πε0 (D) c2 4πε0 (A) Both A and R true, and R is correct explanation of A
(37) The vernier constant of Vernier callipers is 0.1 mm and it (B) Both A and R are true but R is N OT the correct
has zero error of (−0.05) cm. While measuring diameter of explanation of A.
a sphere, the main scale reading is 1.7 cm and coinciding
vernier division is 5. The corrected diameter will be ........... (C) A is true but R is false.
×10−2 cm (D) A is false but R is true.
(A) 160 (B) 150
(45) Which of the following equations is dimensionally
(C) 189 (D) 180 incorrect?
(38) A student measures the time period of 100 oscillations of Where t = time, h = height, s = surface tension, θ = angle,
a simple pendulum four times. The data set is 90 s ,91 s, ρ = density, a, r = radius, g = acceleration due to gravity,
95 s and 92 s. If the minimum division in the measuring v = volume, p = pressure, W = work done, Γ = torque, ε =
clock is 1 s, then the reported mean time should be permittivity, E = electric field, J = current density, L =
(A) 92 ± 2 s (B) 92 ± 3 s length.
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cos θ
(A) v = πpa (B) h = 2sρrg
(C) 92 ± 1.8 s (D) 92 ± 5 s 8ηL
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(39) The following observations were taken for determining (C) J = ε ∂E


∂t (D) W = Γθ
surface tension T of water by capillary method: (46) A ball is dropped from the top of a 100 m high tower on a
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diameter of capillary, D = 1.25 × 10−2 m planet. In the last 21 s before hitting the ground, it covers a
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rise of water, h = 1.45 × 10−2 m distance of 19 m. Acceleration due to gravity (in ms−2 )
Using g = 9.80 m/s2 and the simplified relation near the surface on that planet is
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T = rhg 2 × 10 N /m , the possible error in surface tension


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(A) 6.5 (B) 8
is ........... %
(A) 0.15 (B) 1.5 (C) 10.3 (D) 5.4
(C) 2.4 (D) 10 (47) A, B, C and D are four different physical quantities having
 different dimensions. None of them is dimensionless. But
(40) An expression of energy density is given by u = αβ sin
αx
kt , we know that the equation AD = C ln (BD) holds true.
where α, β are constants, x is displacement, k is Then which of the combination is not a meaningful
Boltzmann constant and t is the temperature. The quantity ?
dimensions of β will be. 2
(B) A2 − B 2 C 2
    C
(A) BD − AD
(A) M L2 T −2 θ−1 (B) M 0 L2 T −2
C

    (C) A
B −C (D) (A−C)
D
(C) M 0 L0 T 0 (D) M 0 L2 T 0
(48) The density of a material in the shape of a cube is
(41) The speed of a wave produced in water is given by determined by measuring three sides of the cube and its
v = λa g b ρc . Where λ, g and ρ are wavelength of wave, mass. If the relative errors in measuring the mass and
acceleration due to gravity and density of water length are respectively 1.5% and 1%, the maximum error in
respectively. The values of a, b and c respectively, are determining the density is ........ %
(A) 12 , 12 , 0 (B) 1, 1, 0 (A) 3.5 (B) 4.5
(C) 1, −1, 0 (D) 1 1
2 , 0, 2 (C) 6 (D) 2.5
(42) A horizontal bridge is built across a river. A student (49) If Surface tension (S), Moment of Inertia (I) and Planck’s
standing on the bridge throws a small ball vertically constant (h), were to be taken as the fundamental units,
upwards with a velocity 4 ms−1 . The ball strikes the water the dimensional formula for linear momentum would be
surface after 4 s. The height of
 bridge above water surface (A) S 1/2 I 1/2 h0 (B) S 1/2 I 3/2 h−1
is ...... m ( Take g = 10 ms−2
(C) S 3/2 I 1/2 h0 (D) S 1/2 I 1/2 h−1
(A) 68 (B) 56
(50) A swimmer can swim with velocity of 12 km/h in still
(C) 60 (D) 64 water. Water flowing in a river has velocity 6 km/h. The
(43) Velocity (v) and acceleration (a) in two systems of units 1 direction with respect to the direction of flow of river water
a1
and 2 are related as V2 = mn2 v1 and a2 = mn respectively. he should swim in order to reach the point on the other
Here m and n are constants. The relations for distance bank just opposite to his starting point is ........◦ . (Round

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off to the Nearest Integer) (find the angle in degree) (A) 25 (B) 20
(A) 30 (B) 120 (C) 35 (D) 30
(C) 60 (D) 150 (55) A ball of mass 0.5 kg is dropped from the height of 10 m.
The height, at which the magnitude of velocity becomes
(51) For a train engine moving with speed of 20 ms−1 . the
equal to the magnitude of acceleration due to gravity, is
driver must apply brakes at a distance of 500 m before the
. . . m. (Use g = 10 m/s2 ).
station for the train to come to rest at the station. If the
brakes were applied at half of this distance,√the train (A) 1 (B) 3
engine would cross the station with speed x ms−1 . The (C) 5 (D) 7
value of x is .............. (Assuming same retardation is
(56) The time
qperiod of a simple pendulum is given by
produced by brakes) ℓ
(A) 100 (B) 101
T = 2π g. The measured value of the length of
pendulum is 10 cm known to a 1 mm accuracy. The time
(C) 520 (D) 200 for 200 oscillations of the pendulum is found to be 100

− → −
− → second using a clock of 1s resolution. The percentage
(52) The angle between vector ( A ) and ( A − B ) is : accuracy in the determination of ′ g ′ using this pendulum is
′ ′
x . The value of ′ x′ to the nearest integer is ...........%
(A) 2 (B) 3
(C) 5 (D) 4
(57) Given below are two statements:
Statement I : Area under velocity- time graph gives the
distance travelled by the body in a given time.
Statement II : Area under acceleration- time graph is
equal to the change in velocity- in the given time.
In the light of given statements, choose the correct answer
from the options given below.
  
(A) tan−1
−B
2 √
(B) tan−1 A
0.7B
(A) Both Statement I and Statement II are true.
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A−B 2
    (B) Statement I is correct but Statement II is false.

−1 3B −1 B cos θ
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(C) tan 2A−B (D) tan A−B sin θ (C) Statement I is incorrect but Statement II is true.

(53) A particle starts from origin O from rest and moves with a (D) Both Statement I and Statement II are False.
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uniform acceleration along the positive x− axis. Identify (58) The percentage errors in quantities P, Q, R and S are
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all figures that correctly represent the motion qualitatively. 0.5%, 1%, 3% and 1.5% respectively in the measurement of
(a = acceleration, v = velocity, x = displacement, t = 3 2
a physical quantity A = P√RQS . the maximum percentage
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time)
error in the value of A will be ........... %
(A) 8.5 (B) 6.0
(C) 7.5 (D) 6.5
(59) The density of a material in SI units is 128 kg m−3 . In
certain units in which the unit of length is 25 cm and the
unit of mass 50 g, the numerical value of density of the
material is
(A) 40 (B) 16
(C) 640 (D) 410
(60) Time (T ), velocity (C) and angular momentum (h) are
chosen as fundamental quantities instead of mass, length
and time. In terms of these, the dimensions of mass
(A) a, b, c (B) a would be    
(A) [M ] = T −1 C −2 h (B) [M ] = T −1 C 2 h
(C) b, c (D) a, b, d    
(C) [M ] = T −1 C −2 h−1 (D) [M ] = T C −2 h
(54) The speed verses time graph for a particle is shown in the
(61) Which of the following relations is true for two unit vectors
figure. The distance travelled (in m ) by the particle during
 and B̂ making an angle θ to each other?
the time interval t = 0 to t = 5 s will be
(A) |Â + B̂| = |Â − B̂| tan θ2
(B) |Â − B̂| = |Â + B̂| tan θ2
(C) |Â + B̂| = |Â − B̂| cos θ2

− →

(D) | A − B̂| = | A + B̂| cos θ2
(62) In an experiment with Vernier callipers of least count
0.1 mm, when two jaws are joined together the zero of
Vernier scale lies right to the zero of the main scale and

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6th division of Vernier scale coincides with the main scale (67) In an octagon ABCDEF GH of equal side, what is the
−−→ −→ −−→ −→ −→ −→ −−→
division. While measuring the diameter of a spherical bob, sum of AB + AC + AD + AE + AF + AG + AH if,
−→
the zero of vernier scale lies in between 3.2 cm and 3.3 cm AO = 2î + 3ĵ − 4k̂
marks, and 4th division of vernier scale coincides with the
main scale division. The diameter of bob is measured as
....... cm
(A) 3.18 (B) 3.25
(C) 3.26 (D) 3.22
(A) −16î − 24ĵ + 32k̂ (B) 16î + 24ĵ − 32k̂
(63) The position, velocity and acceleration of a particle moving
with a constant acceleration can be represented by (C) 16î + 24ĵ + 32k̂ (D) 16î − 24ĵ + 32k̂
(A) (68) The dimension of stopping potential V0 in photoelectric
effect in units of Planck’s constant h, speed of light c and
Gravitational constant G and ampere A is
(A) h2 G3/2 C1/3 A−1 (B) h−2/3 c−1/3 G4/3 A−1
(C) h1/3 G2/3 c1/3 A−1 (D) h0 c5 G−1 A−1
(69) The velocity-time graphs of a car and a scooter are shown
(B) in the figure. (i) the difference between the distance
travelled by the car and the scooter in 15 s and (ii) the time
at which the car will catch up with the scooter are,
respectively

(C)
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(D)
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(A) 337.5 m ��� 25 s (B) 225.5 m ��� 10 s


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(C) 112.5 m ��� 22.5 s (D) 112.5 m ��� 15 s


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(70) The speed of a swimmer in still water is 20 m/s. The


speed of river water is 10 m/s and is flowing due east. If
he is standing on the south bank and wishes to cross the
river along the shortest path, the angle at which he should
(64) A person moved from A to B on a circular path as shown make his strokes w.r.t. north is given by ......o west
in figure. If the distance travelled by him is 60 m, then the
(A) 30 (B) 0
magnitude of displacement would be..... m (Given
cos 135◦ = −0.7) (C) 60 (D) 45
(71) A ball is released from a height h. If t1 and t2 be the time
required to complete first half and second half of the
distance respectively. Then, choose the correct relation
between t1 and t2 .
√ √
(A) t1 = ( 2)t2 (B) t1 = ( 2 − 1)t2
√ √
(C) t2 = ( 2 + 1)t1 (D) t2 = ( 2 − 1)t1
(A) 42 (B) 47
(72) Match List I with List II :
(C) 19 (D) 4 List I (Physical Quan- List II (Dimensional
(65) Let A = (î + ĵ) and B = (2î − ĵ) . The magnitude of a
⃗ ⃗ tity) Formula)
⃗·C
⃗ such that A ⃗ = B ⃗ ·C ⃗·B
⃗ =A ⃗ is [ ]
coplanar vector C (A) Pressure gradient (I) M 0 L2 T −2
given by [ ]
q q (B) Energy density (II) M 1 L−1 T −2
(A) 5
(B) 10 [ ]
9 9 (C) Electric Field (III) M 1 L−2 T −2
q q [ ]
(C) 20
(D) 9 (D) Latent heat (IV ) M 1 L1 T −3 A−1
9 12
(66) Time intervals measured by a clock give the following Choose the correct answer from the options given below:
readings : (A) (A) − (III), (B) − (II), (C) − (I), (D) − (IV )
1.25 s, 1.24 s, 1.27 s, 1.21 s and 1.28 s
(B) (A) − (II), (B) − (III), (C) − (IV ), (D) − (I)
What is the percentage relative error of the observations?
(A) 1.6 (B) 2 (C) (A) − (III), (B) − (II), (C) − (IV ), (D) − (I)

(C) 4 (D) 16 (D) (A) − (II), (B) − (III), (C) − (I), (D) − (IV )

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(73) The quantities x = √µ10 ϵ0 , y = B
E
and z = CR l
are defined (A) (B)
where C− capacitance R−Resistance, l−length,
E−Electric field, B−magnetic field and ε0 , µ0 , -free space
permittivity and permeability respectively. Then....
(A) Only x and y have the same dimension
(B) x, y and z have the same dimension
(C) Only x and z have the same dimension
(D) Only y and z have the same dimension (C) (D)

(74) From the following combinations of physical constants


(expressed through their usual symbols) the only
combination, that would have the same value in different
systems of units, is
2
ch
(A) 2πε 2 (B) 2πε0eGm2
0 e

µ0 ε0 G 2π µ0 ε0 h
(C) c2 he2 (D) ce2 G
q
(75) In SI units, the dimensions of µε00 is ........... Chemistry - Section A (MCQ) ...........

(A) AT −3 M L3/2 (B) A−1 T M L3


(83) If the concentration of glucose (C6 H12 O6 ) in blood is
(C) A2 T 3 M −1 L−2 (D) AT 2 M −1 L−1 0.72 g L−1 , the molarity of glucose in blood is
..... × 10−3 M. (Nearest integer)
(76) In a vernier callipers, each cm on the main scale is divided
(Given: Atomic mass of C = 12, H = 1, O = 16u )
into 20 equal parts. If tenth vernier scale division
coincides with nineth main scale division. Then the value (A) 4 (B) 7
of vernier constant will be . . . × 10−2 mm (C) 9 (D) 11
(A) 3 (B) 5
(84) A metal chloride contains 55.0% of chlorine by
(C) 7 (D) 9 weight.100 mL vapours of the metal chloride at ST P
(77) If force [F ], acceleration [A] and time [T ] are chosen as weigh 0.57 g. The molecular formula of the metal chloride
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the fundamental physical quantities. Find the dimensions is ....(Given : Atomic mass of chlorine is 35.5 u )
of energy. (A) M Cl2 (B) M Cl4
 
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(A) [F][A][T] (B) [F][A] T2 (C) M Cl3 (D) M Cl


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(C) [F ][A] T−1 (D) [F] A−1 [T] (85) The moles of methane required to produce 81 g of water
after complete combustion is .... × 10−2 mol. [nearest
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(78) From the top of a tower, a ball is thrown vertically upward integer]
which reaches the ground in 6 s. A second ball thrown
(A) 780 (B) 225
vertically downward from the same position with the same
speed reaches the ground in 1.5 s. A third ball released, (C) 652 (D) 456
from the rest from the same location, will reach the ground
(86) The reaction of sulphur in alkaline medium is the below
in........ s. −
S8(s) + aOH(aq) → bS(aq)
2−
+ cS2 O3 2− (aq) + dH2 O(ℓ)
(A) 38 (B) 7 ′ ′
The values of a is ............ (Integer answer)
(C) 8 (D) 3 (A) 29 (B) 17
(79) Electric field in acertain region is given by
→ A
− (C) 11 (D) 22
E = x2 î + yB3 ĵ . The SI unit of A and B are
(87) Consider the reaction
(A) N m3 C −1 ; N m2 C −1 (B) N m2 C −1 ; N m3 C −1 4HN O3 (l) + 3KCl(s) →
Cl2 (g) + N OCl(g) + 2H2 O(g) + 3KN O3 (s)
(C) N m3 C; N m2 C (D) N m2 C; N m3 C
The amount of HN O3 required to produce 110.0 g of
(80) A physical quantity y is represented by the formula KN O3 is ...... g
y = m2 r−4 g x l− 2 . If the percentage error found in y, m, r, l
3
(Given : Atomic masses of H, O, N and K are 1, 16, 14 and
and g are 18, 1, 0.5, 4 and p respectively, then find the value 39 respectively.)
of x and p. (A) 32.2 (B) 69.4
(A) 4 and ±3 (B) 5 and ±2
(C) 91.5 (D) 162.5
(C) 8 and ±2 (D) 16
and ± 32
3 (88) To inhibit the growth of tumours, identify the compounds
(81) Two resistors R1 = (4 ± 0.8)Ω and R2 = (4 ± 0.4) Ω are used from the following:
connected in parallel. The equivalent resistance of their (A) EDT A
parallel combination will be (B) Coordination Compounds of P t
(A) (4 ± 0.4) Ω (B) (2 ± 0.4) Ω (C) D−Penicillamine
(D) Cis - Platin
(C) (2 ± 0.3) Ω (D) (4 ± 0.3) Ω Choose the correct answer from the option given below:
(82) Which graph corresponds to an object moving with a (A) B and D Only (B) C and D Only
constant negative acceleration and a positive velocity? (C) A and B Only (D) A and C Only

6
(89) Methylation of 10 g of benzene gave 9.2 g of toluene. (Rounded off to the nearest integer) [Given : Atomic
Calculate the percentage yield of toluene ....... (Nearest weight in g mol−1 − N a : 23; N : 14; O : 16]
integer) (A) 19 (B) 13
(A) 75 (B) 78
(C) 13 (D) 10
(C) 81 (D) 96 (99) An unknown chlorohydrocarbon has 3.55% of chlorine. If
(90) For a reaction, N2 (g) + 3H2 (g) → 2N H3 (g) ; identify each molecule of the hydrocarbon has one chlorine atom
dihydrogen (H2 ) as a limiting reagent in the following only, chlorine atoms present in 1 g of chlorohydrocarbon
reaction mixtures are (Atomic wt. of Cl = 35.5 u; Avogadro constant
(A) 14 g of N2 + 4 g of H2 (B) 56 g of N2 + 10 g of H2 = 6.023 × 1023 mol−1 )
(C) 28 g of N2 + 6 g of H2 (D) 35 g of N2 + 8 g of H2 (A) 6.023 × 109 (B) 6.023 × 1023
(91) 4.5 g of compound A(M W = 90) was used to make (C) 6.023 × 1021 (D) 6.023 × 1020
250 mL of its aqueous solution. The molarity of the (100) Which one of the following has maximum number of
solution in M is x × 10−1 . The value of x is ............ atoms?
(Rounded off to the nearest integer) (A) 1g of Li(s) [Atomic mass of Li = 7]
(A) 1 (B) 2
(B) 1g of Ag(s) [Atomic mass of Ag = 108]
(C) 3 (D) 4
(C) 1g of M g(s) [Atomic mass of M g = 24]
(92) If Avogadro number NA , is changed from
6.022 × 1023 mol−1 to 6.022 × 1020 mol−1 , this would (D) 1g of O2 (g) [Atomic mass of O = 16]
change (101) 250 g solution of D − glucose in water contains 10.8% of
(A) the mass of one mole of carbon carbon by weight. The molality of the solution is nearest
to(Given: Atomic Weights are H, 1 u; C, 12 u; O, 16 u)
(B) the ratio of chemical species to each other in a
balanced equation (A) 1.03 (B) 2.06

(C) the ratio of elements to each other in a compound (C) 3.09 (D) 5.40
(102) 116 g of a substance upon dissociation reaction, yields
(D) the definition of mass in units of grams.
7.5 g of hydrogen, 60 g of oxygen and 48.5 g of carbon.
(93) 100 mL of Na3 PO4 solution contains 3.45 g of sodium. Given that the atomic masses of H, O and C are 1, 16 and
The molarity of the solution is ..... × 10−2 mol L−1 · ( 12 respectively. The data agrees with how many formulae
Us

Nearest integer ) of the following?


[Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u] (A) CH3 COOH
o

(A) 500 (B) 50 (B) HCHO


Br

(C) CH3 OOCH3


(C) 5 (D) 0.50 (D) CH3 CHO
(94) 25 mL of the given HCl solution requires 30 mL of 0.1 M
Us

(A) 4 (B) 3
sodium carbonate solution. What is the volume of this
HCl solution required to titrate 30 mL of 0.2 M aqueous (C) 2 (D) 1
N aOH solution? .............. mL (103) The amount of BaSO4 formed upon mixing 100 mL of
(A) 25 (B) 75 20.8% BaCl2 solution with 50 mL of 9.8% H2 SO4 solution
will be ............. g
(C) 50 (D) 12.5
( Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16 )
(95) The mole fraction of a solute in a 100 molal aqueous
(A) 23.3 (B) 11.65
solution .......... ×10−2
(Round off to the Nearest Integer). (C) 30.6 (D) 33.2
[Given : Atomic masses : H : 1.0 u, O : 16.0 u] (104) The neutralization occurs when 10 mL of 0.1 M acid ′ A′ is
(A) 64 (B) 52 allowed to react with 30 mL of 0.05 M base M (OH)2 . The
basicity of the acid ′ A′ is ... [M is a metal ]
(C) 44 (D) 62
(A) 265 (B) 0.45
(96) When 35 mL of 0.15 M lead nitrate solution is mixed with
20 mL of 0.12 M chromic sulphate solution, ....... ×10−5 (C) 30 (D) 3
moles of lead sulphate precipitate out. (Round off to the (105) The volume of 0.1 N dibasic acid sufficient to neutralize
Nearest Integer). 1 g of a base that furnishes 0.04 mole of OH − in aqueous
(A) 565 (B) 525 solution is ............ mL
(A) 400 (B) 600
(C) 235 (D) 412
(97) The density of NaOH solution is 1.2gcm−3 . The molality of (C) 200 (D) 800
this solution is .... m (106) In the following reactions, the total number of oxygen
(Round off to the NearestInteger) atoms in X and Y is .........
[Use:Atomicmasses:N a : 23.0 uO : 16.0 u H : 1.0 u, N a2 O + H2 O → 2X
Density of H2 O : 1.0 g cm−3 ] Cl2 O7 + H2 O → 2Y
(A) 6 (B) 5 (A) 4 (B) 5
(C) 4 (D) 1 (C) 3 (D) 2
(98) The N aN O3 weighed out to make 50 mL of an aqueous (107) The amount of arsenic pentasulphide that can be obtained
solution containing 70.0 mg N a+ per mL is ...... g. when 35.5 g arsenic acid is treated with excess H2 S in the

7
presence of cone. HCl (assuming 100% conversion) is ............(Nearest integer)
.... mol (A) 2 (B) 3
(A) 0.25 (B) 0.50
(C) 4 (D) 1
(C) 0.333 (D) 0.125
(117) 25 g of an unknown hydrocarbon upon burning produces
(108) A chloro compound ′ A′ . 88 g of CO2 and 9 g of H2 O. This unknown hydrocarbon
(i) forms aldehydes on ozonolysis followed by the contains.
hydrolysis. (A) 24 g of carbon and 1 g of hydrogen
(ii) when vaporized completely 1.53 g of A, gives 448 mL
of vapour at ST P. (B) 22 g of carbon and 3 g of hydrogen
The number of carbon atoms in a molecule of compound (C) 18 g of carbon and 7 g of hydrogen
A is ...... .
(A) 30 (B) 3 (D) 20 g of carbon and 5 g of hydrogen

(C) 0.3 (D) 4 (118) A sample of a hydrate of barium chloride weighing 61 g


was heated until all the water of hydration is removed. The
(109) SO2 Cl2 on reaction with excess of water results into
dried sample weight is 52 g. The formula of the hydrated
acidic mixture
salt is : ( atomic mass, Ba = 137 amu, Cl = 35.5 amu )
SO2 Cl2 + 2H2 O → H2 SO4 + 2HCl 16 moles of N aOH is
required for the complete neutralisation of the resultant (A) BaCl2 .4H2 O (B) BaCl2 .3H2 O
acidic mixture. The number of moles of SO2 Cl2 used is. (C) BaCl2 .H2 O (D) BaCl2 .2H2 O
(A) 16 (B) 8 (119) A 100 mL solution of CH3 CH2 M gBr on treatment with
(C) 4 (D) 2 methanol produces 2.24 mL of a gas at ST P . The weight
of gas produced is ......mg. [nearest integer]
(110) Using the rules for significant figures, the correct answer
for the expression 0.02858×0.112 will be .... . (A) 2 (B) 1
0.5702
(A) 0.005613 (B) 0.00561 (C) 3 (D) 4
(C) 0.0056 (D) 0.006 (120) In one molal solution that contains 0.5 mole of a solute,
there is
(111) A commercially sold conc. HCl is 35%HCl by mass. If the (A) 500 g of solvent (B) 100 mL of solvent
density of this commercial acid is 1.46 g/mL, the molarity
of this solution is ....M (C) 1000 g of solvent (D) 500 mL of solvent
Us

(Atomic mass : Cl = 35.5 amu, H = 1 amu ) (121) A 10 g effervescent tablet containing sodium bicarbonate
(A) 10.2 (B) 12.5 and oxalic acid releases 0.25 ml of CO2 at T = 298.15 K
o

and p = 1 bar. If molar volume of CO2 is 25.0 L under such


(C) 14.0 (D) 18.2
Br

condition, what is the percentage of sodium bicarbonate


(112) The molarity of HNO3 in a sample which has density in each tablet? [Molar mass of N aHCO3 = 84 g mol−1 ]
1.4 g/mL and mass percentage of 63% is ______ M ���.
Us

(A) 0.84 (B) 33.6


(Molecular Weight of HNO3 = 63 )
(A) 22 (B) 19 (C) 16.8 (D) 8.4
(122) If a rocket runs on a fuel (C15 H30 ) and liquid oxygen, the
(C) 17 (D) 14
weight of oxygen required and CO2 released for every litre
(113) For per gram of reactant, the maximwn quantity of N2 gas of fuel respectively are: (Given: density of the fuel is
is produced in which of the following thermal 0.756 g/mL )
decomposition reactions? (Given: Atomic wt. : (A) 1188 g and 1296 g (B) 2376 g and 2592 g
Cr = 52 u, Ba = 137 u).
(C) 2592 g and 2376 g (D) 3429 g and 3142 g
(A) Ba(N3 )2 (s) → Ba(C) + 3N2 (g)
(123) On complete combustion, 0.492 g of an organic compound
(B) (N H4 )2 Cr2 O7 (s) → N2 (g) + 4H2 O(g) + Cr2 O3 (s) gave 0.792 g of CO2 .The % of carbon in the organic
(C) 2N H3 (g) → N2 (g) + 3H2 (g) compound is .................. (Nearest integer)
(A) 42 (B) 43
(D) 2N H4 N O3 (s) → 2N2 (g) + 4H2 O(g) + O2 (g)
(C) 48 (D) 44
(114) At 300 K and 1 atmospheric pressure, 10 mL of a
hydrocarbon required 55 mL of O2 for complete (124) Hemoglobin contains 0.34% of iron by mass. The number
combustion, and 40 mL of CO2 is formed. The formula of of F e atoms in 3.3g of hemoglobin is.(Given: Atomic
the hydrocarbon is mass of F e is 56 u, NA in 6.022 ×1023 mol−1
(A) C4 H10 (B) C4 H6 (A) 1.21 × 105 (B) 12.0 × 1016

(C) C4 H7 Cl (D) C4 H8 (C) 1.21 × 1020 (D) 3.4 × 1022


(115) The strength of 50 volume solution of hydrogen peroxide (125) Sodium oxide reacts with water to produce sodium
is ......g/L (Nearest integer).Given: Molar mass of H2 O2 is hydroxide. 20.0 g of sodium oxide is dissolved in 500 mL
34 g mol−1 Molar volume of gas at ST P = 22.7 L. of water. Neglecting the change in volume, the
(A) 149 (B) 148 concentration of the resulting NaOH solution is
........ × 10−1 M. (Nearest integer)
(C) 146 (D) 150 [Atomic mass : Na = 23.0, O = 16.0, H = 1.0]
(116) If 5 moles of BaCl2 is mixed with 2 moles of N a3 P O4 , the (A) 62 (B) 13
maximum number of moles of Ba3 (P O4 )2 formed is (C) 20 (D) 10

8
(126) The strengths of 5.6 volume hydrogen peroxide (of density
1 g/mL ) in terms of mass percentage and molarity (M ),
respectively, are:
(Take molar mass of hydrogen peroxide as 34 g/mol)
(A) 1.7 and 0.25 (B) 1.7 and 0.5
(C) 0.85 and 0.5 (D) 0.85 and 0.25
(127) The volume (in mL ) of 0.1 N N aOH required to neutralise
10 mL of 0.1 N phosphinic acid is........
(A) 15 (B) 18
(C) 10 (D) 5
(128) The percentage composition of carbon by mole in
methane is ........... %
(A) 80 (B) 20
(C) 75 (D) 25
(129) The number of molecules and moles in 2.8375 litres of O2
at STP are respectively
(A) 7.527 × 1022 and (B) 1.505 × 1023 and
0.250 mol 0.250 mol
(C) 7.527 × 1023 and (D) 7.527 × 1022 and
0.125 mol 0.125 mol
(130) 1 L aqueous solution of H2 SO4 contains 0.02 m mol
H2 SO4 .50 % of this solution is diluted with deionized water
to give 1 L solution (A). In solution (A), 0.01 m mol of
H2 SO4 are added. Total m mols of H2 SO4 in the final
solution is ...... × 103 m mols.
(A) 3 (B) 1
(C) 2 (D) 0
Us

(131) 10 mL of 1 mM surfactant solution forms a monolayer


covering 0.24 cm2 on a polar substrate. If the polar head is
o

approximated as cube, what is its edge length ?


Br

(A) 2.0 pm (B) 2.0 nm


Us

(C) 1.0 pm (D) 0.1 nm


(132) A hydrocarbon contains 85.7 %C. If 42 mg of the
compound contains 3.01 × 1020 molecules, the molecular
formula of the compound will be
(A) C3 H6 (B) C6 H12
(C) C12 H24 (D) C2 H4

9
Moye Moye

Subject : Mathematics, Paper Set : 1


Physics, Chemistry Test
Date : 16-02-2024
Standard : 11
(Answer Key) Time : 3H:0M
Total Mark : 600

Mathematics - Section A (MCQ)

1-B 2-A 3-A 4-C 5-A 6-C 7-A 8-C 9-B 10 - A


11 - D 12 - D 13 - A 14 - A 15 - C 16 - A 17 - A 18 - C 19 - C 20 - D
21 - B 22 - C 23 - C 24 - B 25 - D 26 - B 27 - B 28 - B 29 - B 30 - C
31 - A 32 - D

Physics - Section A (MCQ)

33 - A 34 - B 35 - C 36 - C 37 - D 38 - A 39 - B 40 - D 41 - A 42 - D
43 - A 44 - C 45 - A 46 - B 47 - D 48 - B 49 - A 50 - B 51 - D 52 - C
53 - D 54 - B 55 - C 56 - B 57 - C 58 - D 59 - A 60 - A 61 - B 62 - A
63 - B 64 - B 65 - A 66 - A 67 - B 68 - D 69 - C 70 - A 71 - D 72 - C
73 - B 74 - B 75 - C 76 - B 77 - B 78 - D 79 - B 80 - D 81 - C 82 - C
Us

Chemistry - Section A (MCQ)


o
Br

83 - A 84 - A 85 - B 86 - C 87 - C 88 - A 89 - B 90 - B 91 - B 92 - A
Us

93 - B 94 - A 95 - A 96 - B 97 - B 98 - B 99 - D 100 - A 101 - B 102 - C


103 - A 104 - D 105 - A 106 - B 107 - D 108 - B 109 - C 110 - B 111 - C 112 - D
113 - C 114 - B 115 - D 116 - D 117 - A 118 - D 119 - C 120 - A 121 - A 122 - C
123 - D 124 - C 125 - B 126 - B 127 - C 128 - B 129 - D 130 - D 131 - A 132 - B

10
Moye Moye

Subject : Mathematics, Paper Set : 1


Physics, Chemistry Test
Date : 16-02-2024
Standard : 11
(Solutions) Time : 3H:0M
Total Mark : 600

MAIN 2016]
......... Mathematics - Section A (MCQ) .........
(A) P ⊂ Q and Q − P ̸= ϕ (B) Q ̸⊂ P
(1) Let S = {1, 2, 3, ....., 100}. The number of non-empty (C) P = Q (D) P ̸⊂ Q
subsets A of S such that the product of elements in A is
even is [JEE MAIN 2019] Solution:(Correct Answer:C)

(A) 2100 − 1 (B) 250 (250 − 1) sin θ − cos θ = 2 √ cos θ
⇒ sin θ = cos θ +  2 cosθ
(C) 250 − 1 (D) 250 + 1 √
= ( 2 + 1) cos θ = √22−−11 cos θ
Solution:(Correct Answer:B) √
⇒ ( 2 − 1) sin θ = cos
√ θ
Product is even when atleast one element of subset is ⇒ sin θ + cos θ = 2 cos θ
even Hence required number of subsets = total subsets ∴ P = Q
-number of subsets all whose elements are odd
= 2100 − 250 (5) Let A = {n ∈ N : H.C.F.(n, 45) = 1} and Let
B = {2k : k ∈ {1, 2, . . . , 100}}. Then the sum of all the
(2) Consider the two sets :
elements of A ∩ B is [JEE MAIN 2022]
A = {m ∈ R : both the roots of x2 − (m + 1)x + m + 4 = 0
(A) 5264 (B) 5265
are real } and B = [−3, 5)
Which of the following is not true? [JEE MAIN 2020] (C) 5255 (D) 5235
(A) A − B = (−∞, −3) ∪ (5, ∞)
Solution:(Correct Answer:A)
s

(B) A ∩ B = {−3} Sum of elements in A ∩ B


as

(C) B − A = (−3, 5) = (2 + 4 + 6 + . . . + 200) − (6 + 12 + . . . + 198)


| {z } | {z }
l
dc

Multiple of 2 Multiple of 2 and 3 i.e. 6


(D) A ∪ B = R
− (10 + 20 + . . . + 200) + (30 + 60 + . . . + 180)
| {z } | {z }
Ve

Solution:(Correct Answer:A) Multiple of 5 and 2 i.e. 10 Multiple of 2,5 and 3 i.e. 30


A:D≥0 = 5264
⇒ (m + 1)2 − 4(m + 4) ≥ 0
⇒ m2 + 2m + 1 − 4m − 16 ≥ 0 (6) Set A has m elements and Set B has n elements. If the
⇒ m2 − 2m − 15 ≥ 0 total number of subsets of A is 112 more than the total
⇒ (m − 5)(m + 3) ≥ 0 number of subsets of B, then the value of m × n is [JEE MAIN
⇒ m ∈ (−∞, −3] ∪ [5, ∞) 2020]
∴ A = (−∞, −3] ∪ [5, ∞) (A) 7 (B) 4
B = [−3, 5)
(C) 28 (D) 24
A − B = (−∞, −3) ∪ [5, ∞)
A ∩ B = {−3} Solution:(Correct Answer:C)
B − A = (−3, 5)
Zm − 2n = 112
A∪B =R
m = 7, n = 4 
27 − 24 = 112
(3) Let X = {n ∈ N : 1 ≤ n ≤ 50}. If
m × n = 7 × 4 = 28
A = {n ∈ X : n is a multiple of 2} and
B = {n ∈ X : n is a multiple of 7}, then the number of 
elements in the smallest subset of X containing both A (7) Let A = n ∈ N | n2 ≤ n + 10, 000 , B = {3k + 1 | k ∈ N }
and B is [JEE MAIN 2020] and C = {2k | k ∈ N }, then the sum of all the elements of
(A) 29 (B) 26 the set A ∩ (B − C) is equal to ..... [JEE MAIN 2021]
(A) 832 (B) 412
(C) 31 (D) 34
(C) 963 (D) 123
Solution:(Correct Answer:A)
n(A) = 25 Solution:(Correct Answer:A)
n(B) = 7 B − C ≡ {7, 13, 19, . . . 97, . . .}
n(A ∩ B) = 3 Now, n2 − n ≤ 100 × 100
n(A ∪ B) = 25 + 7 − 3 = 29 ⇒ n(n − 1) ≤ 100 × 100
 √ ⇒ A = {1, 2, . . . , 100}
(4) Let P = θ : sin θ − cos θ = 2 cos θ and So, A ∩ (B − C) = {7, 13, 19, . . . , 97}
 √
Q = θ : sin θ + cos θ = 2 sin θ be two sets. Then [JEE Hence, sum = 16 2 (7 + 97) = 832

11
(8) Let S = {4, 6, 9} and T = {9, 10, 11, . . . , 1000}. If (−1, −2), (0, −2), (1, −2), (2, −2) → (4)
A = {a1 + a2 + . . . + a1 : k ∈ N, a1 , a2 , a3 , . . . , a1 ∈ S} (0, 3)(0, −3) → (2)
then the sum of all the elements in the set T − A is equal
to ...... [JEE MAIN 2022] S
50 S
n
(11) Let Xi = Yi = T where each Xi contains 10
(A) 10 (B) 9 i=1 i=1
elements and each Yi contains 5 elements. If each
(C) 11 (D) 12 element of the set T is an element of exactly 20 of sets Xi
’s and exactly 6 of sets Yi ’s, then n is equal to [JEE MAIN 2020]
Solution:(Correct Answer:C)
(A) 45 (B) 15
S = {4, 6, 9} T = {9, 10, 11 . . . 1000}
A {a1 + a2 + . . . .. + ak : K ∈ N } and ai ∈ S (C) 50 (D) 30
Here by the definition of set ’A’ Solution:(Correct Answer:D)
A = {a : a = 4x + 6y + 9z}
n (Xi ) = 10. U Xi = T, ⇒ n(T ) = 500
Except the element 11,every element of set T is of of the i=1
form 4x + 6y + 9z for some x, y, z ∈ W each element of T belongs to exactly 20
∴ T − A = {11} elements of Xi ⇒ 500
20 = 25 distinct elements
6 = 25 ⇒ n = 30
so 5n
(9) The number of elements in the set
(12) In a class of 140 students numbered 1 to 140, all even
{x ∈ R : (|x| − 3)|x + 4| = 6} is equal to [JEE MAIN 2021]
numbered students opted Mathematics course, those
(A) 3 (B) 2 whose number is divisible by 3 opted Physics course and
(C) 4 (D) 1 those whose number is divisible by 5 opted Chemistry
course. Then the number of students who did not opt for
Solution:(Correct Answer:B) any of the three courses is [JEE MAIN 2019]
(A) 102 (B) 42
(C) 1 (D) 38
s Solution:(Correct Answer:D)
as

x ̸= −4  
l

 140  n(p) = 140 = 46


dc

3
(|x| − 3)(|x + 4|) = 6 n(C) =  5  = 28
⇒ |x| − 3 = |x+4| 6
n(M ) = 140 = 70
Ve

2
No. of solutions = 2 n(p ∪ C ∪ M ) = n(P ) + n(C) + n(M )
 − n(P ∩ C) − n(C ∩ M )−  140∩ P ) +
 n(M  ∩ 140
n(P M ∩ C)
(10) Let S = (x, y) ∈ N × N : 9(x − 3)2 + 16(y − 4)2 ≤ 144 = 46 + 28 + 70 − 140 − − 140
+
15 10 6 30
and T = (x, y) ∈ R × R : (x − 7)2 + (y − 4)2 ≤ 36 Then = 144 − 9 − 14 − 23 + 4 = 102
n(S ∩ T ) is equal to ...... [JEE MAIN 2022] So required number of student = 140 − 102 = 38
(A) 27 (B) 26
(13) The number of elements in the set {n ∈ N : 10 ≤ n ≤ 100
(C) 25 (D) 24 and 3n − 3 is a multiple of 7} is ......... [JEE MAIN 2023]
Solution:(Correct Answer:A) (A) 15 (B) 14
(C) 13 (D) 12
Solution:(Correct Answer:A)
n ∈ [10, 100]
3n − 3 is multiple of 7
3n = 7λ + 3
n = 1, 7, 13, 20, . . . .97
Number of possible values of n = 15

(14) Out of all the patients in a hospital 89 % are found to be


suffering from heart ailment and 98 % are suffering from
S: lungs infection. If K % of them are suffering from both
(x−3)2 2

16 + (y−4)
9 ≤ 1; x, y ∈ {1, 2, 3, . . . . . .} ailments, then K can not belong to the set : [JEE MAIN 2021]
T : (x − 7)2 + (y − 4)2 ≤ 36x, y ∈ R (A) {79, 81, 83, 85} (B) {84, 86, 88, 90}
Let x − 3 = x : y − 4 = y
2 2 (C) {80, 83, 86, 89} (D) {84, 87, 90, 93}
S : x16 + y9 ≤ 1; x ∈ {−2, −1, 0, 1, . . . . . .}
T : (x − 4)2 + y 2 ≤ 36; y ∈ {−3, −2, −1, 0, . . . . . .} Solution:(Correct Answer:A)
S ∩ T = (−2, 0), (−1, 0), . . . .(4, 0) → (7) n(A ∪ B) ≥ n(A) + n(B) − n(A ∩ B)
(−1, 1), (0, 1), . . . . . . (3, 1) → (5) 100 ≥ 89 + 98 − n(A ∩ B)
(−1, −1), (0, −1), . . . . . . (3, −1) → (5) n(A ∩ B) ≥ 87
(−1, 2), (0, 2), (1, 2), (2, 2) → (4) 87 ≤ n(A ∩ B) ≤ 89

12
(15) The number of 3−digit numbers, that are divisible by either ⇒ from (1) and (2)
2 or 3 but not divisible by 7 is .......... [JEE MAIN 2023] C = (C ∪ A) ∩ (C ∪ B)
(A) 513 (B) 512 ⇒ option B is true
Let x ∈ A and x ∈/ B
(C) 514 (D) 511 ⇒ x ∈ (A − B)
Solution:(Correct Answer:C) ⇒ x ∈ C (as A − B ⊆ C )
Let x ∈ A and x ∈ B
Divisible by 2 → 450
⇒ x ∈ (A ∩ B)
Divisible by 3 → 300
⇒ x ∈ C (as A ∩ B ⊆ C )
Divisible by 7 → 128
Hence x ∈ A ⇒ x ∈ C
Divisible by 2 and 7 → 64
⇒A ⊆ C
Divisible by 3 and 7 → 43
⇒ option C is true
Divisible by 2 and 3 → 150
As C ⊇ (A ∩ B)
Divisible by 2, 3 and 7 → 21
⇒ B ∩ C ⊇ (A ∩ B)
∴ Total numbers = 450 + 300 − 150 − 64 − 43 + 21 = 514
As A ∩ B ̸= ϕ
 √ ⇒ B ∩ C ̸= ϕ
(16) If A = {x ∈ R : |x − 2| > 1}, B = x ∈ R : x2 − 3 > 1 ,
Hence the correct answer is option (A)
C = {x ∈ R : |x − 4| ≥ 2} and Z is the set of all integers,
then the number of subsets of the set (A ∩ B ∩ C)c ∩ Z is (18) In a school, there are three types of games to be played.
.... . [JEE MAIN 2021] Some of the students play two types of games, but none
(A) 256 (B) 64 play all the three games. Which Venn diagrams can justify
(C) 8 (D) 16 the above statement ? [JEE MAIN 2021]

Solution:(Correct Answer:A)
A = (−∞, 1) ∪ (3, ∞)
B = (−∞, −2) ∪ (2, ∞)
C = (−∞, 2] ∪ [6, ∞)
So, A ∩ B ∩ C = (−∞, −2) ∪ [6, ∞)
z ∩ (A ∩ B ∩ C)′ = {−2, −1, 0, −1, 2, 3, 4, 5}
Hence no. of its subsets = 28 = 256. (A) P and Q (B) P and R
(C) None of these (D) Q and R
(17) Let A, B and C be sets such that ϕ ̸= A ∩ B ⊆ C. Then
s
as

which of the following statements is not true ? [JEE MAIN 2019] Solution:(Correct Answer:C)
(A) If (A − C) ⊆ B then A ⊆ B A ∩ B ∩ C is visible in all three venn diagram
l
dc

(B) If (A − B) ⊆ C then A ⊆ C (19) In a certain town, 25% of the families own a phone and 15%
own a car; 65% families own neither a phone nor a car and
Ve

(C) (C ∪ A) ∩ (C ∪ B) = C
2, 000 families own both a car and a phone. Consider the
(D) B ∩ C ̸= ϕ following three statements
(A) 5% families own both a car and a phone
Solution:(Correct Answer:A) (B) 35% families own either a car or a phone
(C) 40, 000 families live in the town
Then, [JEE MAIN 2015]
(A) Only (A) and (C) are correct.
(B) Only (B) and (C) are correct
(C) All (A), (B) and (C) are correct.
(D) Only (A) and (B) are correct

Solution:(Correct Answer:C)
n(P ) = 25 %
For n(C) = 15 %
A = C, A − C = ϕ n(P ′ ∪ C ′ ) = 65 %
⇒ϕ ⊆ B ⇒ n(P ∪ C ′ ) = 65 %
But A ⊆ B n(P ∪ C) = 35 %
⇒ option A is NOT true n(P ∩ C) = n(P ) + n(C) − n(P ∪ C)
Let x ∈ (C x ∈ (C ∪ A) ∩ (C ∪ B) ) 25 + 15 − 35 = 5%
⇒ x (C ∪ A) and x ∈ (C ∪ B) x × 5 % = 2000
⇒ (x ∈ C or x ∈ A) and (x ∈ C or x ∈ B) x = 40, 000
⇒ (x ∈ C or x ∈ (A ∩ B)
⇒ (x ∈ C or x ∈ C (as A ∪ B ⊆ C ) (20) The
 number2 of elements in the set
⇒ x ∈ C n ∈ Z : n − 10n + 19 < 6 is ........... [JEE MAIN 2023]
⇒ (C ∪ A) ∩ (C ∪ B) ⊆ C (1) (A) 12 (B) 18
Now x ∈ C ⇒ x ∈ (C ∪ A) and x ∈ (C ∪ B )
(C) 24 (D) 6
⇒ x ∈ (C ∪ A) ∩ (C ∪ B)
⇒ C ⊆ (C ∪ A) ∩ (C ∪ B) ⊆ C (2) Solution:(Correct Answer:D)

13
−6 < n2 − 10n + 19 < 6 Solution:(Correct Answer:B)
⇒ n2 √− 10n + 25 √ > 0 and n − 10n + 13 < (n − 5) > 0n ∈
2 2
Case -√I : x ∈ [0, 9]√
[5 − 2 3, 5 + 2 3] 2(3 − x)√+ x − 6 x + 6 √= 0
n ∈ R − [5] ⇒ x − 8 x + 12 = 0 ⇒ x = 4, 2 ⇒ x = 16, 4
∴ n ∈ [1.3, 8.3] Since x ∈ [0, 9]
⇒ n = 2, 3, 4, 6, 7, 8 ∴ x = 4

(21) Let A = {θ : sin (θ) = tan (θ)} and B = {θ : cos (θ) = 1} √ - II : x ∈ [9, ∞]
Case √
2( x − 3)√+ x − 6 x + 6 = 0
be two sets. Then [JEE MAIN 2013] ⇒ x − 4 x = 0 ⇒ x = 16, 0
(A) A = B (B) A ̸⊂ B Since x ∈ [9, ∞]
(C) B ̸⊂ A (D) A ⊂ B and B − A ̸= ϕ ∴ x = 16
Hence , x = 4 and 16
Solution:(Correct Answer:B)
(25) A survey shows that 63% of the people in a city read
Let A = {θ : sin θ = tan θ}
newspaper A whereas 76% read newspaper B. If x% of the
and B = {θ : cos θ = 1}
sin θ people read both the newspapers, then a possible value of
Now, A = θ : sin θ = cos θ x can be [JEE MAIN 2020]
= {θ : sin θ (cos θ − 1) = 0}
(A) 65 (B) 37
= {θ = 0 , π , 2π , 3π, .....}
For B : cos θ = 1 ⇒ θ = π , 2π , 4π , ..... (C) 29 (D) 55
This showns that A is not contained in B i.e.
Solution:(Correct Answer:D)
A ̸⊂ B but B ⊂ A.
n(B) ≤ n(A ∪ B) ≤ n(U )
(22) An organization awarded 48 medals in event ’A’,25 in event ⇒ 76 ≤ 76 + 63 − x ≤ 100
’B ’ and 18 in event ’ C ’. If these medals went to total 60 ⇒ −63 ≤ −x ≤ −39
men and only five men got medals in all the three events, ⇒ 63 ≥ x ≥ 39
then, how many received medals in exactly two of three (26) Let A = {x ∈ R : |x + 1| < 2} and
events? [JEE MAIN 2023] B = {x ∈ R : |x − 1| ≥ 2}. Then which one of the following
(A) 10 (B) 9 statements is NOT true ? [JEE MAIN 2022]
(C) 21 (D) 15 (A) A − B = (−1, 1) (B) B − A = R − (−3, 1)

Solution:(Correct Answer:C) (C) A ∩ B = (−3, −1] (D) A ∪ B = R − [1, 3)


s

|A| = 48 Solution:(Correct Answer:B)


as

|B| = 25 A : x ∈ (−3, 1) B : x ∈ (−∞, −1] ∪ [3, ∞)


|C| = 18 B − A = (−∞, −3] ∪ [3, ∞) = R − (−3, 3)
l
dc

|A ∪ B ∪ C| = 60 [ Total ]
|A ∩ B ∩ C| = 5P (27) Let A = {1, 2, 3, 4, 5, 6, 7} and B = {3, 6, 7, 9}. Then the
P
Ve

|A ∪ number of elements in the set {C ⊆ A : C ∩ B ̸= ϕ} is [JEE


PB ∪ C| = |A| − |A ∩ B| + |A ∩ B ∩ C|
MAIN 2022]
⇒ |A ∩ B| = 48 + 25 + 18 + 5 − 60
= 36 (A) 111 (B) 112
No.Pof men who received exactly 2 medals (C) 113 (D) 114
= |A ∩ B| − 3|A ∩ B ∩ C|
Solution:(Correct Answer:B)
= 36 − 15
= 21 A = {1, 2, 3, 4, 5, 6, 7} and
B = {3, 6, 7, 9}
(23) If A = {x ∈ R : |x| < 2} and B = {x ∈ R : |x − 2| ≥ 3} then Total subset of A = 27 = 128
[JEE MAIN 2020] C ∩ B = ϕ when set C contains the element 1, 2, 4, 5
(A) A ∪ B = R − (2, 5) (B) A ∩ B = (−2, −1) ∴ S = {C ⊆ A; C ∩ B ̸= ϕ}
= Total −(C ∩ B = ϕ)
(C) B − A = R − (−2, 5) (D) A − B = [−1, 2) = 128 − 24 = 112
Solution:(Correct Answer:C) (28) If X = {4n − 3n − 1 : n ∈ N } and Y = {9(n − 1) : n ∈ N },
then X ∪ Y = . . . . . [JEE MAIN 2014]
(A) X (B) Y
(C) N (D) None of these
Solution:(Correct Answer:B)
A:x∈
(−2, 2); B : x ∈ (−∞, −1] ∪ [5, ∞) x = {4n − 3n − 1}
⇒ B − A = R − (−2, 5) = {0, 9, 54, . . .}
Y = {9(n − 1)}
(24) Let√S = {x ∈√R : √
x ≥ 0 and = {0, 9, 18, 27, . . .}
2 | x − 3| + x ( x − 6) + 6 = 0} then S : . . . [JEE MAIN 2018] ∴ XU Y = Y
(A) contains exactly one element. (29) Let A = {a, b, c} and B = {1, 2, 3, 4} Then the number of
elements in the set C = {f : A → B | 2 ∈ f (A) and f is
(B) contains exactly two elements
not one-one } is [JEE MAIN 2020]
(C) contains exactly four element. (A) 18 (B) 19
(D) is an empty set (C) 17 (D) 20

14
Solution:(Correct Answer:B) percentage of them, who like both coffee and tea, then x
C = {f : A → B | 2 ∈ f (A) and f is not one-one } cannot be [JEE MAIN 2020]
Case-I : If f (x) = 2∀x ∈ A then number of function = 1 (A) 63 (B) 38
Case-II : If f (x) = 2 for exactly two elements then total
(C) 54 (D) 36
number of many-one function = 3 C2 3 C1 = 9
Case-III : If f (x) = 2 for exactly one element then total Solution:(Correct Answer:D)
number of many-one functions = 3 C1 3 C1 = 9
Total = 19

(30) Two newspaper A and B are published in a city. It is


known that 25% of the city populations reads A and 20%
reads B while 8% reads both A and B. Further, 30% of
those who read A but not B look into advertisements and C → person like coffee
40% of those who read B but not A also look into T → person like Tea
advertisements, while 50% of those who read both Aand B n(C) = 73
look into advertisements. Then the percentage of the n(T ) = 65
population who look into advertisement is [JEE MAIN 2019] n(C ∪ T ) ≤ 100
(A) 12.8 (B) 13.5 n(C) + n(T ) − n(C ∩ T ) ≤ 100
73 + 65 − x ≤ 100
(C) 13.9 (D) 13 x ≥ 38
Solution:(Correct Answer:C) 73 − x ≥ 0 ⇒ x ≤ 73
65 − x ≥ 0 ⇒ x ≤ 65
38 ≤ x ≤ 65

............. Physics - Section A (MCQ) .............

(33) Which of the following physical quantities have the same


dimensions? [JEE MAIN 2022]


Let population = 100 (A) Electric displacement ( D ) and surface charge density
n(A) = 25 (B) Displacement current and electric field
s

n(B) = 20
as

n(A ∩ B) = 8 (C) Current density and surface charge density


n(A ∩ B̄) = 17 (D) Electric potential and energy
l

n(Ā ∩ B) = 12
dc

Now % of th population who look advertisement Solution:(Correct Answer:A)


Ve

30
= 100 × 17 + 100
40
× 12 + 100
50
×8 Electric displacement
= 13.9 →
− →

D = ϵ0 E h i
(31) Let A : {1, 2, 3, 4, 5, 6, 7}. Define B = {T ⊆ A : either 1 ∈
/T [D] = [ϵ0 E] = ϵ0 ϵσ0
or 2 ∈ T } and C = {T ⊆ A : T the sum of all the elements [D] = [σ]
of T is a prime number }. Then the number of elements in → Surface change density = σ.
the set B ∪ C is . . . . . . [JEE MAIN 2022]
(A) 107 (B) 106 (34) If R, XL . and XC represent resistance, inductive
reactance and capacitive reactance. Then which of the
(C) 105 (D) 108 following is dimensionless: [JEE MAIN 2023]
Solution:(Correct Answer:A) (A) RXL XC (B) √XRX
L C
B ′ is a set containing sub sets of A containing element 1 R XL
and not containing 2 . (C) XL XC (D) RX C

And C ′ is a set containing subsets of A whose sum of Solution:(Correct Answer:B)


elements is not prime.
All three have same dimension therefore √ R is
So, we need to calculate number of subsets of XL XC
{3, 4, 5, 6, 7} whose sum of elements plus 1 is composite. dimensionless.
Number of such 54 elements subset = 1
⃗ is a vector quantity such that |A|
(35) A ⃗ = nonzero constant.
Number of such 4 elements subset = 3 (except selecting 3
⃗ ? [JEE MAIN
Which of the following expressions is true for A
or 7 )
Number of such 3 elements subset = 6 (except selecting 2022]
→ −
− → → −
− →
{3, 4, 5}, {3, 6, 7}, {4, 5, 7} or {5, 6, 7} ) (A) A · A = 0 (B) A × A < 0
Number of such 2 elements subset = 7 (except selecting → −
− → → −
− →
(C) A × A = 0 (D) A × A > 0
{3, 7}, {4, 6}, {5, 7})
Number of such 1 elements subset = 3 (except selecting Solution:(Correct Answer:C)
{4} or {6} ) →

| A | ̸= 0
Number of such 0 elements subset = 1 → −
− → → −
− →
n (B ′ ∩ C ′ ) = 21 ⇒ n(B ∪ C) = 27 − 21 = 107 A × A = | A || A | sin 0◦ n̂ = 0

(32) A survey shows that 73% of the persons working in an (36) A physical quantity of the dimensions of length that can be
e2
office like coffee, whereas 65% like tea. If x denotes the formed out of c, G and 4πε 0
is [c is velocity of light, G is the

15

universal constant of gravitation and e is charge ] [NEET 2017] (40) An expression of energy density is given by u = αβ sin
αx
,
q kt
Ge2 where α, β are constants, x is displacement, k is
e2
(A) c12 G4πε (B) c1 4πε 0
0
q q Boltzmann constant and t is the temperature. The
Ge2
(C) c12 4πε (D) c2 4πε Ge2 dimensions of β will be. [JEE MAIN 2022]
   
(A) M L2 T −2 θ−1 (B) M 0 L2 T −2
0 0

Solution:(Correct Answer:C)    
(C) M 0 L0 T 0 (D) M 0 L2 T 0
Dimensions of
e2
   3 −2

Solution:(Correct Answer:D)
4πε0 = F × d
2
= M L−1
T   0 0 0
Dimensions of G = M L3 T −2 ,
α[L]
[M L2T −2 ] = M L T
−1
Dimensions
  of c = LT p
α = M L1 T −2
2
l ∝ 4πε e
Gq c r [M L2 T −2 ] [M L1 T −2 ][L3 ]
 1 o  p  q  r
α
β = [L3 ] ⇒ β = M L2 T −2
∴ L = M L3 T −2 M −1 L3 T −2 LT −1
On comparing both sides and solving, we get (41) The speed of a wave produced in water is given by
P = 21 , q = 12 and r = −2 v = λa g b ρc . Where λ, g and ρ are wavelength of wave,
h 2 i1/2 acceleration due to gravity and density of water
∴ l = c12 4πε
Ge
0 respectively. The values of a, b and c respectively, are [JEE
MAIN 2023]
(37) The vernier constant of Vernier callipers is 0.1 mm and it (A) 1 1
(B) 1, 1, 0
2, 2, 0
has zero error of (−0.05) cm. While measuring diameter of
a sphere, the main scale reading is 1.7 cm and coinciding (C) 1, −1, 0 (D) 1 1
2 , 0, 2
vernier division is 5. The corrected diameter will be ........... Solution:(Correct Answer:A)
×10−2 cm [JEE MAIN 2022] v = λ a g b ρc
(A) 160 (B) 150 using dimension formula
   a  1 −2 b  1 −3 c
(C) 189 (D) 180 ⇒ M 0 L1 T −1  = L1 L T M
 L
⇒ M 0 L1 T −1 = M c La+b−3c T −2b
Solution:(Correct Answer:D) ∴ c = 0, a + b − 3c = 1, −2b = −1 ⇒ b = 21
Measured diameter = M SR + V SR × V C Now a + b − 3c = 1
= 1.7 + 0.01 × 5 ⇒ a + 21 − 0 = 1
= 1.75 ⇒ a = 21
Corrected = Measured - Error ∴ a = 12 , b = 21 , c = 0
s

= 1.75 − (−0.05)
as

= 1.80 cm (42) A horizontal bridge is built across a river. A student


= 180 × 10−2 cm standing on the bridge throws a small ball vertically
l

upwards with a velocity 4 ms−1 . The ball strikes the water


dc

180
surface after 4 s. The height of
 bridge above water surface
is ...... m ( Take g = 10 ms−2 [NEET 2023]
Ve

(38) A student measures the time period of 100 oscillations of a


simple pendulum four times. The data set is 90 s ,91 s, 95 s (A) 68 (B) 56
and 92 s. If the minimum division in the measuring clock is
1 s, then the reported mean time should be [JEE MAIN 2016] (C) 60 (D) 64
(A) 92 ± 2 s (B) 92 ± 3 s Solution:(Correct Answer:D)
(C) 92 ± 1.8 s (D) 92 ± 5 s
Solution:(Correct Answer:A)
∆T = [∆T1 |+|∆T2 |+|∆T
4
3 |+|∆T4 ]

= 2+1+3+0
4 = 1.5
As the resolutions of measuring clock is 1.5 theref ore the mean
time should be 92 ± 1.5
but Least count is 1 sec
then answer should be 92 ± 2 sec
S = ut + 21 at2
(39) The following observations were taken for determining −H = 4 × 4 − 1
2 × 10 × 42
surface tension T of water by capillary method: −H = 16 − 80
diameter of capillary, D = 1.25 × 10−2 m −H = −64
rise of water, h = 1.45 × 10−2 m H = 64 m
Using g = 9.80 m/s2 and the simplified relation
(43) Velocity (v) and acceleration (a) in two systems of units 1
T = rhg 2 × 10 N /m , the possible error in surface tension
3
a1
is ........... % [JEE MAIN 2017] and 2 are related as V2 = mn2 v1 and a2 = mn respectively.
Here m and n are constants. The relations for distance
(A) 0.15 (B) 1.5
and time in two systems respectively are [JEE MAIN 2022]
(C) 2.4 (D) 10 n3 n2
(A) m3 L1 = L2 and m T1 = T2
Solution:(Correct Answer:B) n4 n2
rhg (B) L1 = m2 L2 and T1 = m T2
T= 2 × 103 N/m
n2 n4
∆T
= ∆r
+ ∆h
= 0.01 0.01 (C) L1 = m L2 and T1 = m 2 T2
T r h 1.25 + 1.45
% error = ∆T
T × 100 1
= 1.25 1
+ 1.45 = 0.8 + 0.69 = 1.5% (D) n2
m L1 = L2 and n4
m2 T1 = T2

16
q
Solution:(Correct Answer:A) 1
= 2
2 a
L2 n L2
T2 = m2 T1 a = 8m/s2
L2
T2
= T 2L 1
×mn
2 1
T22
(47) A, B, C and D are four different physical quantities having
n
m2 × T2
T1 = T12 ×mn different dimensions. None of them is dimensionless. But
n2 T2 we know that the equation AD = C ln (BD) holds true.
m = T1
n4 Then which of the combination is not a meaningful
L2
= m2 × 1
L1 mn quantity ? [JEE MAIN 2016]
L2 n5
L1 = m3 C
(A) BD − AD
2
(B) A2 − B 2 C 2
C
(A−C)
(44) Given below are two statements: One is labelled as (C) A
B −C (D) D
Assertion A and the other is labelled as Reason R. Solution:(Correct Answer:D)
Assertion A : Product of Pressure (P ) and time (t) has the
Dimension of A ̸= dimension of (C) Hence A − C is not
same dimension as that of coefficient of viscosity.
Force possible
Reason R : Coefficient of viscosity = Velocity gradient
Question : Choose the correct answer from the options (48) The density of a material in the shape of a cube is
given below [JEE MAIN 2022] determined by measuring three sides of the cube and its
(A) Both A and R true, and R is correct explanation of A mass. If the relative errors in measuring the mass and
length are respectively 1.5% and 1%, the maximum error in
(B) Both A and R are true but R is N OT the correct determining the density is ........ % [JEE MAIN 2018]
explanation of A. (A) 3.5 (B) 4.5
(C) A is true but R is false. (C) 6 (D) 2.5
(D) A is false but R is true. Solution:(Correct Answer:B)
mass(M ) M
Density (d) = volume(V ) = L3
Solution:(Correct Answer:C)
∴ Error in density, d = M +
∆d ∆M 3∆L
Pressure and time L
N = 1.5% + 3 (1%) = 4.5%
P :m 2 , Time : Sec

P t = Nmsec
2 (49) If Surface tension (S), Moment of Inertia (I) and Planck’s
F N
η = 6πrv : m·m/sec : Nmsec
2 constant (h), were to be taken as the fundamental units,
the dimensional formula for linear momentum would be
s

(45) Which of the following equations is dimensionally [JEE MAIN 2019]


as

incorrect? (A) S 1/2 I 1/2 h0 (B) S 1/2 I 3/2 h−1


Where t = time, h = height, s = surface tension, θ = angle,
l

(C) S 3/2 I 1/2 h0 (D) S 1/2 I 1/2 h−1


dc

ρ = density, a, r = radius, g = acceleration due to gravity,


v = volume, p = pressure, W = work done, Γ = torque, ε = Solution:(Correct Answer:A)
Ve

permittivity, E = electric field, J = current density, L = P = k s a i b hc


length. [JEE MAIN 2021] W here k is dimensionless
a constant
 c
M LT −1 = M T −2 M L2 M L2 T −1
4
cos θ
(A) v = πpa8ηL
(B) h = 2sρrg
a+b+c=1
(C) J = ε ∂E
∂t (D) W = Γθ 2b + 2c = 1
− 2a − c = −1
Solution:(Correct Answer:A) a = 12 b = 21 c = 0
4
(i) πpa dv
8ηL = dt = Volumetric flow rate S 1/2 i1/2 h0
(poiseuille’s law)
(ii) hρg = 2s (50) A swimmer can swim with velocity of 12 km/h in still
r cos θ
−2 water. Water flowing in a river has velocity 6 km/h. The
(iii) RHS ⇒ ε × 4πε 1 a
2 × ε = t × r2 =
1 q 1 I
L2 = IL
0 r direction with respect to the direction of flow of river water
LHS
he should swim in order to reach the point on the other
T =A I
= IL−2
bank just opposite to his starting point is ........◦ . (Round
(iv) W = τ θ
off to the Nearest Integer) (find the angle in degree) [JEE
MAIN 2021]
(46) A ball is dropped from the top of a 100 m high tower on a
planet. In the last 21 s before hitting the ground, it covers a (A) 30 (B) 120
distance of 19 m. Acceleration due to gravity (in ms−2 ) (C) 60 (D) 150
near the surface on that planet is [JEE MAIN 2020]
Solution:(Correct Answer:B)
(A) 6.5 (B) 8
(C) 10.3 (D) 5.4

Solution:(Correct Answer:B)
Time to travel 81m is t sec.
Time to travel 100m is t + 12 sec
q Vsw sin θ = vr
81 = 21 × a × t2 ⇒ t = 9 2a 12 sin θ = 6
2 q
100 = 12 × a × t + 21 ⇒ t + 12 = 10 2a sin θ = 12
q q θ = 30◦
9 a2 + 12 = 10 a2 ∴ α = 120◦

17
(51) For a train engine moving with speed of 20 ms−1 . the
driver must apply brakes at a distance of 500 m before the
station for the train to come to rest at the station. If the
brakes were applied at half of this distance,√the train
engine would cross the station with speed x ms−1 . The
value of x is .............. (Assuming same retardation is
produced by brakes) [JEE MAIN 2023]
(A) 100 (B) 101
(C) 520 (D) 200

Solution:(Correct Answer:D)
u = 20 m/s, S1 = 500m, v = 0
By third equation of mation (A) a, b, c (B) a
0 = (20)2 − 2a.500 ⇒ a = 104
m/s2 (C) b, c (D) a, b, d
u = 20 m/s, S2 = 250m, v =?
√ − 2a.250
v 2 = (20) 2 Solution:(Correct Answer:D)
= v = 200 m/s
x = 200


− → −
− →
(52) The angle between vector ( A ) and ( A − B ) is : [JEE MAIN
2021]

s
l as

 
dc


(A) tan−1
−B
2 √
(B) tan−1 A
0.7B
3
Ve

A−B 2
 √   
(C) tan−1 3B
2A−B (D) tan−1 B cos θ
A−B sin θ

Solution:(Correct Answer:C) Give initial velocity u = 0 and accele


is constant
At time t
v = 0 + at
⇒ v = at
Also X = 0 (t) + 12 at2
⇒ X = 12 at2
Graph (a) , (b) and (d) are correct.

(54) The speed verses time graph for a particle is shown in the
figure. The distance travelled (in m ) by the particle during
the time interval t = 0 to t = 5 s will be [JEE MAIN 2020]


Angle between A and


B , θ = 60◦

− → −
− →
Angle betwenn A and A − B
B sin θ
tan α = A−B
√3 cos θ
B
= A−B×21 2
2√
3B
tan α = 2A−B

(53) A particle starts from origin O from rest and moves with a (A) 25 (B) 20
uniform acceleration along the positive x− axis. Identify (C) 35 (D) 30
all figures that correctly represent the motion qualitatively.
(a = acceleration, v = velocity, x = displacement, t = Solution:(Correct Answer:B)
time) [JEE MAIN 2019]

18
error in the value of A will be ........... % [JEE MAIN 2018]
(A) 8.5 (B) 6.0
(C) 7.5 (D) 6.5
Solution:(Correct Answer:D)
M aximum percentage error in A
= 3 (% error in p) + 2 (% error in Q)
R + 12 (% error in R) + 1 (% error in S)
Distance = v dt = 3 × 0.5 + 2 × 1 = 21 × 3 + 1 × 1.5
Area under graph = 1
2 × 5 × 8 = 20 = 1.5 + 2 + 1.5 + 1.5 = 6.5%
(55) A ball of mass 0.5 kg is dropped from the height of 10 m. (59) The density of a material in SI units is 128 kg m−3 . In
The height, at which the magnitude of velocity becomes certain units in which the unit of length is 25 cm and the
equal to the magnitude of acceleration due to gravity, is unit of mass 50 g, the numerical value of density of the
. . . m. (Use g = 10 m/s2 ). [JEE MAIN 2022] material is [JEE MAIN 2019]
(A) 1 (B) 3 (A) 40 (B) 16
(C) 5 (D) 7 (C) 640 (D) 410

Solution:(Correct Answer:C) Solution:(Correct Answer:A)


128kg 125(50g)(20)
v 2 = u2 + 2as m3 = (25cm)3 (4)3
100 = 0 + 2(10) s = 128
64 (20) units
s = 5m = 40units
Height from ground = 10 − 5 = 5 m
(60) Time (T ), velocity (C) and angular momentum (h) are
(56) The time chosen as fundamental quantities instead of mass, length
qperiod of a simple pendulum is given by and time. In terms of these, the dimensions of mass

T = 2π g. The measured value of the length of pendulum
would be [JEE
is 10 cm known to a 1 mm accuracy. The time for 200  MAIN 2017]   
(A) [M ] = T −1 C −2 h (B) [M ] = T −1 C 2 h
oscillations of the pendulum is found to be 100 second    
using a clock of 1s resolution. The percentage accuracy in (C) [M ] = T −1 C −2 h−1 (D) [M ] = T C −2 h
the determination of ′ g ′ using this pendulum is ′ x′ . The Solution:(Correct Answer:A)
value of ′ x′ to the nearest integer is ...........% [JEE MAIN 2021]
s

Let mass, related as M ∝  T x C y hz 


as

(A) 2 (B) 3 y
M 1 L0 T 0 = (T ) L1 T −1 M 1 L2 T −1
x z

(C) 5 (D) 4 M 1 L0 T 0 = M z Ly+2z + T x−y−z


l
dc

z=1
Solution:(Correct Answer:B) y + 2z = 0x − y − z = 0
Ve

g= 4π 2 ℓ y = −2x
 +2−1=  0
T2  1
 M = T −1 C −2 h1
∆g ∆ℓ ∆T 0.1
g = ℓ +2 T = +2 200
10 0.5
∆g 1 1 (61) Which of the following relations is true for two unit vectors
g = 100 + 50
 and B̂ making an angle θ to each other? [JEE MAIN 2022]
g × 100 = 3%
∆g

(A) |Â + B̂| = |Â − B̂| tan θ2


(57) Given below are two statements:
(B) |Â − B̂| = |Â + B̂| tan θ2
Statement I : Area under velocity- time graph gives the
distance travelled by the body in a given time. (C) |Â + B̂| = |Â − B̂| cos θ2
Statement II : Area under acceleration- time graph is →
− →

equal to the change in velocity- in the given time. (D) | A − B̂| = | A + B̂| cos θ2
In the light of given statements, choose the correct answer
Solution:(Correct Answer:B)
from the options given below. [JEE MAIN 2023] q
(A) Both Statement I and Statement II are true. |Â + B̂| = |Â|2 + |B̂|2 + 2|Â∥B̂| cos θ

= p1 + 1 + 2 cos θ
(B) Statement I is correct but Statement II is false.
= q2(1 + cos θ)
(C) Statement I is incorrect but Statement II is true.
= 2 × 2 cos2 θ
2
(D) Both Statement I and Statement II are False. = 2 cos θ2
q
Solution:(Correct Answer:C) |Â − B̂| = |Â|2 + |B̂|2 − 2|Â||B̂| cos θ

Area under velocity time graph gives displacement of = 2 − 2 cos θ
body in given time. = 2 sin θ2
Area under acceleration time graph gives change in |Â+B̂|
|Â−B̂|
= cot θ2
velocity in the given time.
So Statement I false,Statement II True. (62) In an experiment with Vernier callipers of least count
0.1 mm, when two jaws are joined together the zero of
(58) The percentage errors in quantities P, Q, R and S are Vernier scale lies right to the zero of the main scale and
0.5%, 1%, 3% and 1.5% respectively in the measurement of 6th division of Vernier scale coincides with the main scale
3 2
a physical quantity A = P√RQS . the maximum percentage division. While measuring the diameter of a spherical bob,

19
the zero of vernier scale lies in between 3.2 cm and 3.3 cm Solution:(Correct Answer:B)
marks, and 4th division of vernier scale coincides with the d = Rθ 
main scale division. The diameter of bob is measured as 60 = R 3π 4
....... cm [JEE MAIN 2023] R = 60×4 80
3π = π m√
(A) 3.18 (B) 3.25 Displacement = R2 + R2 − 2R2 cos 135
p
(C) 3.26 (D) 3.22 ⇒ 2R − 2R
2 2
q(−0.7) 
√ 2
⇒ 3.4R2 = 3.4 80 π
Solution:(Correct Answer:A)
≈ 47 m
LC = 0.1 mm
Zero Error = 6 × LC = 0.6 mm ⃗ = (î + ĵ) and B
(65) Let A ⃗ = (2î − ĵ) . The magnitude of a
Reading = M SR + V SR × LC − Zero Error ⃗
coplanar vector C such that A ⃗·C ⃗ = B ⃗ ·C ⃗·B
⃗ =A ⃗ is
= [32 mm + (0.1)4 mm] − 0.6 mm given
= 31.8 mm qby [JEE MAIN 2018] q
5 10
= 3.18 cm (A) 9 (B) 9
q q
20 9
(63) The position, velocity and acceleration of a particle (C) 9 (D) 12
moving with a constant acceleration can be represented Solution:(Correct Answer:A)
by [JEE MAIN 2021]
If C⃗ = aî + bĵ then A.
⃗C ⃗ = A.
⃗B⃗
(A) a + b = 1 ... (i)
⃗ C
B. ⃗ = A.⃗B⃗
2a − b = 1 ... (ii)
Solving equation (i) and (ii) we get
a = 13 , b = 23
M agnitude
q of coplanar
q vector,

C = 1
+ =4 5
(B) 9 9 9

(66) Time intervals measured by a clock give the following


readings :
1.25 s, 1.24 s, 1.27 s, 1.21 s and 1.28 s
What is the percentage relative error of the observations?
s
as

[NEET 2020]
(A) 1.6 (B) 2
(C)
l
dc

(C) 4 (D) 16
Solution:(Correct Answer:A)
Ve

The arithmetic mean of given values is taken as true value.


tmean = t1 +t2 +t53 +t4 +t5
tmean = 1.25+1.24+1.27+1.21+1.28
5
tmean = 1.25s
(D)
∆tmean = |∆t1 |+|∆t2 |+|∆t5 3 |+|∆t4 |+|∆t5 |
∆tmean = 0+0.01+0.02+0.04+0.03
5 = 0.02s
Percentage error = ∆t mean
tmean × 100 1.25 × 100
= 0.02
= 1.6%

(67) In an octagon ABCDEF GH of equal side, what is the


−−→ −→ −−→ −→ −→ −→ −−→
sum of AB + AC + AD + AE + AF + AG + AH if,
−→
Solution:(Correct Answer:B) AO = 2î + 3ĵ − 4k̂ [JEE MAIN 2021]
Option (2) represent correct graph for particle moving with
constant acceleration, as for constant acceleration
velocity time graph is straight line with positive slope and
x − t graph should be an opening upward parabola.

(64) A person moved from A to B on a circular path as shown (A) −16î − 24ĵ + 32k̂ (B) 16î + 24ĵ − 32k̂
in figure. If the distance travelled by him is 60 m, then the
magnitude of displacement would be..... m (Given (C) 16î + 24ĵ + 32k̂ (D) 16î − 24ĵ + 32k̂
cos 135◦ = −0.7) [JEE MAIN 2022] Solution:(Correct Answer:B)
We know,
−→ −−→ −−→ −−→ −−→ −−→ −−→ −−→ − →
∵ OA + OB + OC + OD + OE + OF + OG + OH = 0
By triangle law of vector addition, we can write
−−→ −→ −−→ −→ −→ −−→
AB = AO + OB; AC = AO + OC
−−→ −→ −−→ −→ −→ −−→
AD = AO + OD; AE = AO + OE
−→ −→ −−→ −→ −→ −−→
AF = AO + OF ; AG = AO + OG
−−→ −→ −−→
(A) 42 (B) 47 AH = AO + OH
(C) 19 (D) 4 Now

20
−−→ −→ −−→ −→ −→ −→ −−→
AB + AC + AD + AE + AF + AG + AH he is standing on the south bank and wishes to cross the
−→ −−→ −−→ −−→ −−→ −−→ −−→ −−→
= (7AO) + OB + OC + OD + OE + OF + OG + OH river along the shortest path, the angle at which he should
−→ → −→
− make his strokes w.r.t. north is given by ......o west [NEET
= (7AO) + 0 − OA
−→ −→ 2019]
= (7AO) + AO
−→ (A) 30 (B) 0
= 8AO = 8(2î + 3ĵ − 4k̂)
= 16î + 24ĵ − 32k̂ (C) 60 (D) 45

(68) The dimension of stopping potential V0 in photoelectric Solution:(Correct Answer:A)


effect in units of Planck’s constant h, speed of light c and
Gravitational constant G and ampere A is [JEE MAIN 2020]
(A) h2 G3/2 C1/3 A−1 (B) h−2/3 c−1/3 G4/3 A−1
(C) h1/3 G2/3 c1/3 A−1 (D) h0 c5 G−1 A−1
Solution:(Correct Answer:D) v = 20m/s
v0 = hx cy Gz Aw u = 10m/s
ML2 T−2
x y z sin θ = uv = 10 1
= ML2 T−1 LT−1 M−1 L3 T−2 Aw 20 = 2
AT
⇒ w = −1 ⇒ θ = 30◦ west
(x − z = 1)
(x − z = 1) (71) A ball is released from a height h. If t1 and t2 be the time
−x − x = 1 − 2z = 2 required to complete first half and second half of the
−x − y − 2z = −3 distance respectively. Then, choose the correct relation
x − 21 x = 0 between t1 and t2 . [JEE MAIN 2022]
√ √
x=0 (A) t1 = ( 2)t2 (B) t1 = ( 2 − 1)t2
x = −1 √ √
(C) t2 = ( 2 + 1)t1 (D) t2 = ( 2 − 1)t1
2 × 0 + y + 3x − 1 = 2
y=5 Solution:(Correct Answer:D)
⇒ v0 = h0 c5 G−1 A−1 For first h2
h 1 2
(69) The velocity-time graphs of a car and a scooter are shown 2 = 2 gt1
For total height h
in the figure. (i) the difference between the distance 2
h = 12 g (t1 + t2 )
s
travelled by the car and the scooter in 15 s and (ii) the time t1
√1 =
as

at which the car will catch up with the scooter are, 2


t2

t1 +t2

respectively [JEE MAIN 2018] 1 + t1 = 2


l

t1 √1
t2 =
dc

√2−1
t2 = ( 2 − 1)t1
Ve

(72) Match List I with List II :


List I (Physical Quan- List II (Dimensional
tity) Formula)
[ ]
(A) Pressure gradient (I) M 0 L2 T −2
[ ]
(B) Energy density (II) M 1 L−1 T −2
[ ]
(C) Electric Field (III) M 1 L−2 T −2
[ ]
(A) 337.5 m ��� 25 s (B) 225.5 m ��� 10 s (D) Latent heat (IV ) M 1 L1 T −3 A−1
Choose the correct answer from the options given below:
(C) 112.5 m ��� 22.5 s (D) 112.5 m ��� 15 s [JEE MAIN 2023]

Solution:(Correct Answer:C) (A) (A) − (III), (B) − (II), (C) − (I), (D) − (IV )
Using equation, a = v−ut and (B) (A) − (II), (B) − (III), (C) − (IV ), (D) − (I)
s = ut + 21 at2
Distance travelled by car in 15 sec (C) (A) − (III), (B) − (II), (C) − (IV ), (D) − (I)
2
= 12 (45)
15 (15) (D) (A) − (II), (B) − (III), (C) − (I), (D) − (IV )
= 6752 m
Distance traveled by scooter in 15 seconds Solution:(Correct Answer:C)
= 30 × 15 = 450 (distance = speed × time) dp [M L−1 T −2 ]
Dif f erence between distance travelled by car Pressure gradient= dx =
  [L]
and scooter in 15 sec, 450 − 337.5 = 112.5 m = M 1 L−2 T −2
Let car catches scooter in time t; energy [M L2 T −2 ]
Energy density = volume =
2 + 45 (t − 15) = 30t
675   [L3 ]
= M 1 L−1 T −2
337.5 + 45t − 675 = 30t
⌊M LT −2 ⌋
⇒ 15t = 337.5 Electric field = chForce =
  arge [A.T ]
⇒ t = 22.5 sec = M 1 L1 T −3 A−1
heat [M L2 T −2 ]
(70) The speed of a swimmer in still water is 20 m/s. The Latent heat = mass =
 0 2 −2  [M ]
speed of river water is 10 m/s and is flowing due east. If = M L T

21
(73) The quantities x = √µ10 ϵ0 , y = B
E
and z = CR l
are defined 10 V SD = 9 M SD
9
where C− capacitance R−Resistance, l−length, 1 V SD = 10 M SD
E−Electric field, B−magnetic field and ε0 , µ0 , -free space = 10 × 20 cm
9 1
9
permittivity and permeability respectively. Then.... [JEE MAIN 1V SD = 200 cm
2020] VC = 1M SD − 1 V SD
1
= 20 cm − 200
9
cm
(A) Only x and y have the same dimension
= 200 × 10 mm
1

(B) x, y and z have the same dimension VC = 5 × 10−2 mm


Ans. 5
(C) Only x and z have the same dimension
(D) Only y and z have the same dimension (77) If force [F ], acceleration [A] and time [T ] are chosen as
the fundamental physical quantities. Find the dimensions
Solution:(Correct Answer:B) of energy. [NEET 2021]
   
x = √µ10 ε0 = speed ⇒ [x] = L1 T −1 (A) [F][A][T] (B) [F][A] T2
     
y=B E
= speed ⇒ [y] = L1 T −1 (C) [F ][A] T−1 (D) [F] A−1 [T]
 
z = RCℓ
= τℓ ⇒ [z] = L1 T −1
So, x, y, z all have the same dimensions. Solution:(Correct Answer:B)
E ∝ Fa Ab Tc
(74) From the following combinations of physical constants  1 2 2   1 1 −2 a  −2 b c
M L T ∝ M L T LT [T]
(expressed through their usual symbols) the only a=1
combination, that would have the same value in different a+b=2⇒b=1
systems of units, is [JEE MAIN 2014] −2a − 2 b + c = −2
2
ch
(A) 2πε 2 (B) 2πε0eGm2 ⇒c=2
0 e

2π µ0 ε0 h
a = 1 b = 1c =
 2
µ0 ε0 G
(C) c2 he2 (D) ce2 G E ∝ [F][A] T2
Solution:(Correct Answer:B) (78) From the top of a tower, a ball is thrown vertically upward
T heDimensional formulae of which reaches the ground in 6 s. A second ball thrown
0 0 1 1
e= M  L T A  vertically downward from the same position with the same
ε0 =  M −1 L−3 T 4A2 speed reaches the ground in 1.5 s. A third ball released,
G = M −1L3 T −2  from the rest from the same location, will reach the ground
s

and me = M 1 L0 T 0 in........ s. [JEE MAIN 2022]


as

2
N ow, 2πε0eGm2 (A) 38 (B) 7
e
2
[ M 0 L 0 T 1 A1 ]
l

(C) 8 (D) 3
dc

= 2π[M −1 L−3 T 4 A2 ][M −1 L3 T −2 ][M 1 L0 T o ]2


2 2
[T A ] Solution:(Correct Answer:D)
= 2π[M −1−1+2 L−3+3 T 4−2 A2 ]
Ve

2 2
[T A ] 1
= 2π[M 0 L0 T 2 A2 ] = 2π
1
2π is2 Dimensionless thus the combination
e
2πε0 Gm2 would d have the same value in dif f ierent systems of units
e

q
ε0
(75) In SI units, the dimensions of µ0 is [JEE MAIN 2019]
(A) AT −3 M L3/2 (B) A−1 T M L3
(C) A2 T 3 M −1 L−2 (D) AT 2 M −1 L−1 Let height of
tower be h and speed of projection in first two cases be u.
Solution:(Correct Answer:C)
q For case-I : 2nd equation s = ut + 12 at 2
Dimension of µε00 h = −u(6) + 12 g(6)2
 
[ε0 ] = M −1 L−3 T 4 A2 H = −6u + 18 g . . . (i)
[µ0 ] = M LT −2 A−2 For case-II : h = u(1.5) + 12 g(1.5)2
q h −1 −3 4 2 i 12 h = 1.5u + 2.25g2 . . . (ii)
Dimension of µε00 = MM LTL −2TA−2 A
Multiplying equation (ii) by 4 we get
 −2 −4 6 4 1/2
= M L T A  4h = 6u + 4.5 g . . . . (iii)
= M −1 L−2 T 3 A2 equation (i) + equation (iii) we get 5h = 22.5g
h = 4.5g . . . (iv)
(76) In a vernier callipers, each cm on the main scale is divided For case−III
into 20 equal parts. If tenth vernier scale division h = 0 + 21 gt2 . . . (v)
coincides with nineth main scale division. Then the value Using equation (4)and equation (5)
of vernier constant will be . . . × 10−2 mm [JEE MAIN 2022] 4.5g = 12 gt2
(A) 3 (B) 5 t2 = 9 ⇒ t = 3s

(C) 7 (D) 9 (79) Electric field in acertain region is given by


→ A

E = x2 î + yB3 ĵ . The SI unit of A and B are [JEE MAIN 2023]
Solution:(Correct Answer:B)
20 M SD = 1 cm (A) N m3 C −1 ; N m2 C −1 (B) N m2 C −1 ; N m3 C −1
1
1 M SD = 20 cm (C) N m3 C; N m2 C (D) N m2 C; N m3 C

22
Solution:(Correct Answer:B)

− ........... Chemistry - Section A (MCQ) ...........
E = A î + yB3 ĵ
 A  x2 −1 2 −1
h x2 i = N C ⇒ [A] = N m C (83) If the concentration of glucose (C6 H12 O6 ) in blood is
B
y3 = N C
−1
⇒ [B] = N m3 C −1 0.72 g L−1 , the molarity of glucose in blood is
..... × 10−3 M. (Nearest integer)
(Given: Atomic mass of C = 12, H = 1, O = 16u ) [JEE MAIN
(80) A physical quantity y is represented by the formula
2021]
y = m2 r−4 g x l− 2 . If the percentage error found in y, m, r, l
3

and g are 18, 1, 0.5, 4 and p respectively, then find the value (A) 4 (B) 7
of x and p. [JEE MAIN 2021] (C) 9 (D) 11
(A) 4 and ±3 (B) 5 and ±2
Solution:(Correct Answer:A)
(C) 8 and ±2 (D) 16
3 and ± 32
molarty = moles/volume
−3
Solution:(Correct Answer:D) 180 = 4 × 10
= 0.72 =M
∆y 2∆m 4∆r x∆g 3 ∆ℓ
y = m + r + g + 2 ℓ
3 (84) A metal chloride contains 55.0% of chlorine by
18 = 2(1) + 4(0.5) + xp + 2 (4) weight.100 mL vapours of the metal chloride at ST P
8 = xp weigh 0.57 g. The molecular formula of the metal chloride
By checking from options. is ....(Given : Atomic mass of chlorine is 35.5 u ) [JEE MAIN
3 , p = ±2
x = 16 3
2023]
(A) M Cl2 (B) M Cl4
(81) Two resistors R1 = (4 ± 0.8)Ω and R2 = (4 ± 0.4) Ω are
connected in parallel. The equivalent resistance of their (C) M Cl3 (D) M Cl
parallel combination will be [JEE MAIN 2021]
Solution:(Correct Answer:A)
(A) (4 ± 0.4) Ω (B) (2 ± 0.4) Ω
Molecular. weight of metal chloride
(C) (2 ± 0.3) Ω (D) (4 ± 0.3) Ω
100 × 22700
= 0.57
= 129.39
Solution:(Correct Answer:C) weight of Cl = 129.39 × 0.55
1 1 1
Req = R1 + R2 = 71.1645
∴ Mole of Cl = 71.1645 ∼
Req = 4 + 4 ⇒ Req = 2 Ω
1 1 1
35.5 = 2
s

∆Req ∆R1 Hence M Cl2


+ ∆R
as

Also 2
Req = R12 R22
2

∆Req .8 .4 1.2
= 16
+ 16 = 16 (85) The moles of methane required to produce 81 g of water
l

4
dc

≜ Req = 0.3 Ω after complete combustion is .... × 10−2 mol. [nearest


Req = (2 ± 0.3) Ω integer] [JEE MAIN 2022]
Ve

(A) 780 (B) 225


(82) Which graph corresponds to an object moving with a
constant negative acceleration and a positive velocity? [JEE
(C) 652 (D) 456
MAIN 2017]
Solution:(Correct Answer:B)
(A) (B)
CH4 + 2O2 → CO2 + 2H2 O
POAC on H atom
nCH4 × 4 = nH2 O × 2
81
nCH4 = 18 × 2 × 14 = 36
81

nCH4 = 2.25
= 225 × 10−2
Nearest Integers = 225

(C) (D) (86) The reaction of sulphur in alkaline medium is the below

S8(s) + aOH(aq) → bS(aq)2−
+ cS2 O3 2− (aq) + dH2 O(ℓ)
The values of ′ a′ is ............ (Integer answer) [JEE MAIN 2021]
(A) 29 (B) 17
(C) 11 (D) 22

Solution:(Correct Answer:C)
16e⊖ + S8 −→ 8S 2−
12H2 O+S8 −→4S2 O32− +24H + +16e◦
Solution:(Correct Answer:C)
2S8 +12H2 O−→8S 2− +4S2 O32− +24H
According to question, object is moving with for balancing in basic medium add equal number of OH ⊖
constant nagative acceleration i.e., a = −constant (C) that of H +
dx = −C
vdv
2S8 + 12H2 O + 24OH ⊖ −→ 8S 2− + 4S2 O82−
vdv = −Cdx +24H2 O
v2
2 = −Cx +k 2S8 + 24OH ⊖ → 8S 2− + 4S2 O82− + 12H2 O
v2
x = − 2C + Ck S8 + 12OH ⊖ → 4S 2− + 2S2 O82− + 6H2 O
Hence graph (3) represents correctly a = 12

23
(87) Consider the reaction Solution:(Correct Answer:B)
4HN O3 (l) + 3KCl(s) → 4.5/90
M = 250/1000 = 0.2
Cl2 (g) + N OCl(g) + 2H2 O(g) + 3KN O3 (s)
= 2 × 10−1
The amount of HN O3 required to produce 110.0 g of
KN O3 is ...... g (92) If Avogadro number NA , is changed from
(Given : Atomic masses of H, O, N and K are 1, 16, 14 and 6.022 × 1023 mol−1 to 6.022 × 1020 mol−1 , this would
39 respectively.) [JEE MAIN 2022] change [NEET 2015]
(A) 32.2 (B) 69.4 (A) the mass of one mole of carbon
(C) 91.5 (D) 162.5 (B) the ratio of chemical species to each other in a
Solution:(Correct Answer:C) balanced equation
4HN O3 (ℓ) + 3KCl(s) → (C) the ratio of elements to each other in a compound
Cl2 (g) + N OCl(g) + 2H2 O(g) + 3KN O3 (g)
(D) the definition of mass in units of grams.
x gm 110 gm
x 110
63 M ole = 101 Solution:(Correct Answer:A)
4→3 mass of 1mol (6.022 × 1023 atoms) of carbon = 12g
1 → 43 If Avogadro Number (N A) is changed than mass of
63 → 4 × 63 = 101
x 3 x 110
1mol (6.022 × 1020 atom) of carbon.
110×63×4 20
x = 101×3 = 91.5 gm = 12×6.022×10 = 12 × 10−3 g
6.022×1023
Therefore the mass of 1 mol of carbon is changed
(88) To inhibit the growth of tumours, identify the compounds
used from the following: (93) 100 mL of Na3 PO4 solution contains 3.45 g of sodium.
(A) EDT A The molarity of the solution is ..... × 10−2 mol L−1 · (
(B) Coordination Compounds of P t Nearest integer )
(C) D−Penicillamine [Atomic Masses - Na : 23.0 u, O : 16.0 u, P : 31.0 u] [JEE MAIN
(D) Cis - Platin 2021]
Choose the correct answer from the option given below: (A) 500 (B) 50
[JEE MAIN 2023]
(C) 5 (D) 0.50
(A) B and D Only (B) C and D Only
Solution:(Correct Answer:B)
(C) A and B Only (D) A and C Only
Na3 PO4 −→ 3Na
s

3 × 23 mol
1 3.45
Solution:(Correct Answer:A) 3.45 g
as

3.45
Cis - Platin is used in chemotherapy to inhibits the growth 23 mol
therefore molarity of Na3 PO4 Solution =
l

of tumors. ( cis [P t (N H3 )2 Cl2 ] )


dc

nNa3 PO4
volume of solution in L
1
× 3.45 mol
(89) Methylation of 10 g of benzene gave 9.2 g of toluene. = 3 0.1 23
Ve

L
−2
Calculate the percentage yield of toluene ....... (Nearest = 0.5 = 50 × 10
integer) [JEE MAIN 2021]
(94) 25 mL of the given HCl solution requires 30 mL of 0.1 M
(A) 75 (B) 78
sodium carbonate solution. What is the volume of this
(C) 81 (D) 96 HCl solution required to titrate 30 mL of 0.2 M aqueous
N aOH solution? .............. mL [JEE MAIN 2019]
Solution:(Correct Answer:B)
(A) 25 (B) 75
Moles of C6 H6 = 10/78
moles of toluene = 10/78 (C) 50 (D) 12.5
wt of toluene should be = 10/78 × 92 Solution:(Correct Answer:A)
% yield = 109.2
×92
× 100 = 78 % Apply law of equivalence :
78
25 × N = 30 × 0.1 × 2
(90) For a reaction, N2 (g) + 3H2 (g) → 2N H3 (g) ; identify NHCl = 30×0.2 = 65 × 0.2 = 1.2
25 5
dihydrogen (H2 ) as a limiting reagent in the following nd
For the 2 titration
reaction mixtures [JEE MAIN 2019]
5 × VHCl = 30 × 0.2
1.2

(A) 14 g of N2 + 4 g of H2 (B) 56 g of N2 + 10 g of H2 VHCl = 6×5 30


1.2 = 1.2 = 25 ml
(C) 28 g of N2 + 6 g of H2 (D) 35 g of N2 + 8 g of H2 (95) The mole fraction of a solute in a 100 molal aqueous
Solution:(Correct Answer:B) solution .......... ×10−2
(Round off to the Nearest Integer).
56 g of N2 means 2 mole
[Given : Atomic masses : H : 1.0 u, O : 16.0 u] [JEE MAIN 2021]
2 mole of N2 requires 6 mole of H2 for complete reaction
but available H2 is 10 g i.e. 5 mole hence H2 is limiting (A) 64 (B) 52
reagent (C) 44 (D) 62

(91) 4.5 g of compound A(M W = 90) was used to make Solution:(Correct Answer:A)
250 mL of its aqueous solution. The molarity of the 100 molal aqueous solution means there is 100 mole
solution in M is x × 10−1 . The value of x is ............ solute in 1kg = 1000gm water. Now,
(Rounded off to the nearest integer) [JEE MAIN 2021] mole-fraction of solute = nsolutensolute
+nsolvent
100 1800
(A) 1 (B) 2 = 100+ 1000 = 2800 = 0.6428
18

(C) 3 (D) 4 = 64.28 × 10−2

24
(96) When 35 mL of 0.15 M lead nitrate solution is mixed with (100) Which one of the following has maximum number of
20 mL of 0.12 M chromic sulphate solution, ....... ×10−5 atoms? [NEET 2020]
moles of lead sulphate precipitate out. (Round off to the (A) 1g of Li(s) [Atomic mass of Li = 7]
Nearest Integer). [JEE MAIN 2021]
(B) 1g of Ag(s) [Atomic mass of Ag = 108]
(A) 565 (B) 525
(C) 1g of M g(s) [Atomic mass of M g = 24]
(C) 235 (D) 412
Solution:(Correct Answer:B) (D) 1g of O2 (g) [Atomic mass of O = 16]
3P b (N O3 )2 + Cr2 (SO4 )3 → 3P bSO4 + 2Cr (N O3 )3
35 ml 20 ml Solution:(Correct Answer:A)
0.15 M 0.12 M Number of atoms
5.25 m · mol = 2.4 m · mol 5.25 m · mol = molarwmass × NA × atomicity
= 5.25 × 10−3 mol (1) 17 × NA × 1
therefore moles of P bSO4 formed = 5.25 × 10−3 (2) 1081
× NA × 1
= 525 × 10−5 (3) 24 × NA × 1
1

(4) 321
× NA × 2
(97) The density of NaOH solution is 1.2gcm−3 . The molality of
this solution is .... m (101) 250 g solution of D − glucose in water contains 10.8% of
(Round off to the NearestInteger) carbon by weight. The molality of the solution is nearest
[Use:Atomicmasses:N a : 23.0 uO : 16.0 u H : 1.0 u, to(Given: Atomic Weights are H, 1 u; C, 12 u; O, 16 u) [JEE
Density of H2 O : 1.0 g cm−3 ] [JEE MAIN 2021] MAIN 2022]
(A) 6 (B) 5 (A) 1.03 (B) 2.06
(C) 4 (D) 1 (C) 3.09 (D) 5.40
Solution:(Correct Answer:B)
Consider 1 ℓ solution Solution:(Correct Answer:B)
mass of solution = (1.2 × 1000) g C6 H12 O6 → Glucose
mass of C 72
= 1200 gm We know: mass of glucose = 180

of solution × 100
Neglecting volume of NaOH mass of C
Given: %C = 10.8 = mass
Mass of water = 1000 gm 10.8×250
100 = mass of C ⇒ Mass of C = 27 gm
⇒ Mass of NaOH = (1200 − 1000) gm ∴ mass of glucose = 67.5 gm
s

= 200 gm ∴ moles of glucose = 0.375 moles


as

g
⇒ Moles of NaOH = 50200 g/mol = 5 mol Mass of solvent = 250 − 67.5 gm = 182.5 gm
⇒ molality = 5 mol
=5 m ∴ Molality = 0.1825
0.375
= 2.055 ≈ 2.06
l

1 kg
dc

(98) The N aN O3 weighed out to make 50 mL of an aqueous (102) 116 g of a substance upon dissociation reaction, yields
Ve

solution containing 70.0 mg N a+ per mL is ...... g. 7.5 g of hydrogen, 60 g of oxygen and 48.5 g of carbon.
(Rounded off to the nearest integer) [Given : Atomic Given that the atomic masses of H, O and C are 1, 16 and
weight in g mol−1 − N a : 23; N : 14; O : 16] [JEE MAIN 2021] 12 respectively. The data agrees with how many formulae
(A) 19 (B) 13 of the following?
(A) CH3 COOH
(C) 13 (D) 10
(B) HCHO
Solution:(Correct Answer:B) (C) CH3 OOCH3
N a+ present in 50 ml (D) CH3 CHO [JEE MAIN 2022]
1 ml × 50 ml = 3500mg = 3.5 gm
= 70 mg
(A) 4 (B) 3
moles of N a+ = 3.5
23 = moles of N aN O3
(C) 2 (D) 1
23 × 85 = 12.993 gm
weight of N aN O3 = 3.5

(99) An unknown chlorohydrocarbon has 3.55% of chlorine. If Solution:(Correct Answer:C)


each molecule of the hydrocarbon has one chlorine atom %H = 1167.5
× 100 = 6.5
only, chlorine atoms present in 1 g of chlorohydrocarbon %O = 116 × 100 = 51.7
60

116 × 100 = 41.8


%C = 48.5
are (Atomic wt. of Cl = 35.5 u; Avogadro constant
= 6.023 × 1023 mol−1 ) [JEE MAIN 2018] Relative atomicities =
(A) 6.023 × 109 (B) 6.023 × 1023 H ⇒ 6.5
O ⇒ 51.7
16 = 3.25
(C) 6.023 × 1021 (D) 6.023 × 1020 C ⇒ 41.8
12 = 3.5
Solution:(Correct Answer:D) Emperically formula is approx. CH2 O
Given percentage of chlorine in an hydrocarbon = 3.55% (A) C2 H4 O2 (B) CH2 O relate to this formula.
i,e.,
100 g of chlorohydrocarbon has 3.55 g of chlorine. (103) The amount of BaSO4 formed upon mixing 100 mL of
1 g of chlorohydrocarbon will have 3.55
100 = 0.0355 g of 20.8% BaCl2 solution with 50 mL of 9.8% H2 SO4 solution
chlorine. will be ............. g
Atomic wt. of Cl = 35.5 g/mol ( Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16 ) [JEE
0.0355 g
Number of moles of Cl = 35.5 g/mol = 0.001 mole MAIN 2014]
−1
Number of atoms of Cl = 0.001 mole ×6.023 × 10 mol 23 (A) 23.3 (B) 11.65
= 6.023 × 10 20
(C) 30.6 (D) 33.2

25
Solution:(Correct Answer:A) The number of carbon atoms in a molecule of compound
BaCl2 + H2 SO4 → BaSO4 + 2HCl A is ...... . [JEE MAIN 2021]
208 g 98 g 233 g 73 g
7.3 g
(A) 30 (B) 3
20.8 g 9.8 g 23.3 g
(C) 0.3 (D) 4
(104) The neutralization occurs when 10 mL of 0.1 M acid ′ A′ is
allowed to react with 30 mL of 0.05 M base M (OH)2 . The Solution:(Correct Answer:B)
basicity of the acid ′ A′ is ... [M is a metal ] [JEE MAIN 2022] 448 ml of A ⇒ 1.53 gmA
(A) 265 (B) 0.45 22400 ml of A ⇒ 1.53
445 × 22400 gm A = 7650
O
H3 CHC − CH − Cl −−−−3−−→ CH3 − CH = O
(C) 30 (D) 3 Zn/H2 O
It has 3 carbon atoms Aldehyde
Solution:(Correct Answer:D) & mm is 36 + 5 + 35.5 = 76.5
Acid + Base −→ Salt +H2 O
0.1 M M (OH)2 (109) SO2 Cl2 on reaction with excess of water results into
10 ml 0.05 M acidic mixture
30 ml SO2 Cl2 + 2H2 O → H2 SO4 + 2HCl 16 moles of N aOH is
at equivalence point required for the complete neutralisation of the resultant
equivalent of acid = equivalent of base acidic mixture. The number of moles of SO2 Cl2 used is.
0.1 × 10 × n = 30 × 0.05 × 2 [JEE MAIN 2022]
n=3 (A) 16 (B) 8

(105) The volume of 0.1 N dibasic acid sufficient to neutralize (C) 4 (D) 2
1 g of a base that furnishes 0.04 mole of OH − in aqueous Solution:(Correct Answer:C)
solution is ............ mL [JEE MAIN 2016]
Let n (SO2 Cl2 ) = x moles
(A) 400 (B) 600 ∴ n (H2 SO4 ) = x, n(HCl) = 2x
(C) 200 (D) 800 n (H + ) = 4 x
For Neutralisation
Solution:(Correct Answer:A) n (H + ) = n (OH − )
Applying law of equivalence 4x = 16
Equivalence of acid = Equivalence of base x=4
0.1 × v = 0.04 × 1
s

v = 0.4 L = 0.4 × 1000 = 400 ml (110) Using the rules for significant figures, the correct answer
as

for the expression 0.02858×0.112


0.5702 will be .... . [JEE MAIN 2022]
(106) In the following reactions, the total number of oxygen (A) 0.005613 (B) 0.00561
l
dc

atoms in X and Y is .........


N a2 O + H2 O → 2X (C) 0.0056 (D) 0.006
Ve

Cl2 O7 + H2 O → 2Y [JEE MAIN 2023] Solution:(Correct Answer:B)


(A) 4 (B) 5 Reported answer should not be more precise than least
(C) 3 (D) 2 precise term in calculations, so there should be three
significant figures in reported answer.
Solution:(Correct Answer:B)
N a2 O + H2 O → 2N aOH (111) A commercially sold conc. HCl is 35%HCl by mass. If the
Cl2 O7 + H2 O → 2HClO4 density of this commercial acid is 1.46 g/mL, the molarity
1+4=5 of this solution is ....M
(Atomic mass : Cl = 35.5 amu, H = 1 amu ) [JEE MAIN 2022]
(107) The amount of arsenic pentasulphide that can be obtained (A) 10.2 (B) 12.5
when 35.5 g arsenic acid is treated with excess H2 S in the
(C) 14.0 (D) 18.2
presence of cone. HCl (assuming 100% conversion) is
.... mol [JEE MAIN 2016] Solution:(Correct Answer:C)
(A) 0.25 (B) 0.50 Let total volume = 1000 mL = 1 L
(C) 0.333 (D) 0.125 total mass of solution = 1460 g
mass of HCl = 100 35
× 1460
35×1460
Solution:(Correct Answer:D) moles of HCl = 100×36.5
35×1460
Conc.HCl
2H AsO + 5H S −−−−−−→ As S + 8H O So molarity = 100×36.5 = 14 M
3 4 2 2 5 2
2 moles 1 mole
1 moles 1/2 moles
(112) The molarity of HNO3 in a sample which has density
∴ number of moles of H3 AsO4 1.4 g/mL and mass percentage of 63% is ______ M ���.
= 35.5
142 = 0.25 (Molecular Weight of HNO3 = 63 ) [JEE MAIN 2020]
∴ number of moles of As2 S5
= 0.25 (A) 22 (B) 19
2 = 0.125 mol.
(C) 17 (D) 14
(108) A chloro compound ′ A′ .
(i) forms aldehydes on ozonolysis followed by the Solution:(Correct Answer:D)
hydrolysis. 100 gm soln → 63 gmHNO3
1.4 mL → 1 mole HNO3
100
(ii) when vaporized completely 1.53 g of A, gives 448 mL
of vapour at ST P. Molarity = 100 ×1 1 = 14 M
1.4 1000

26
(113) For per gram of reactant, the maximwn quantity of N2 gas (117) 25 g of an unknown hydrocarbon upon burning produces
is produced in which of the following thermal 88 g of CO2 and 9 g of H2 O. This unknown hydrocarbon
decomposition reactions? (Given: Atomic wt. : contains. [JEE MAIN 2019]
Cr = 52 u, Ba = 137 u). [JEE MAIN 2018] (A) 24 g of carbon and 1 g of hydrogen
(A) Ba(N3 )2 (s) → Ba(C) + 3N2 (g) (B) 22 g of carbon and 3 g of hydrogen
(B) (N H4 )2 Cr2 O7 (s) → N2 (g) + 4H2 O(g) + Cr2 O3 (s) (C) 18 g of carbon and 7 g of hydrogen
(C) 2N H3 (g) → N2 (g) + 3H2 (g) (D) 20 g of carbon and 5 g of hydrogen
(D) 2N H4 N O3 (s) → 2N2 (g) + 4H2 O(g) + O2 (g)
Solution:(Correct Answer:A)
Solution:(Correct Answer:C) 
Cx Hy + x + y4 O2 → xCO2 + y2 H2 O
(a) Molar mass of Ba(N3 )2 (s) = 221 g/mol 25
x× M y
2×M
25
(M
25
)
1 mole of Ba(N3 )2 (s) will give 3 moles of N2 =2 =0.5
hence 221 1g/mol
g
moles of Ba(N3 )2 (s) will give C x× M 25
=2
3 × 221 = 0.014 moles of N2
1 H y× M25
=1
(b) Molar mass of (N H4 )2 Cr2 O7 = 252 g/mol. C2y Hy ≡ 24 y gm C + y gm H
1 mole of (N H4 )2 Cr2 O7 will give 1 mole of N2 or
hence 252 1g/mol
g
moles of (N H4 )2 Cr2 O7 will give 24 : 1 ratio by mass
1 × 252 = 0.0039 moles of N2
1

(c) Molar mass of N H3 = 17 g/mol. (118) A sample of a hydrate of barium chloride weighing 61 g
2 mole of N H3 will give 1 mole of N2 was heated until all the water of hydration is removed. The
1g 1
hence 17 g/mol moles of N H3 will give 2×17 = 0.0297 dried sample weight is 52 g. The formula of the hydrated
moles of N2 . salt is : ( atomic mass, Ba = 137 amu, Cl = 35.5 amu ) [JEE
(d) Molar mass of N H4 N O3 = 80 g/mol. MAIN 2015]
1 mole of N H4 N O3 will give 1 mole of N2 (A) BaCl2 .4H2 O (B) BaCl2 .3H2 O
1g
hence 80 g/mol moles N H4 N O3 will give 1 × 801
= 0.0125
(C) BaCl2 .H2 O (D) BaCl2 .2H2 O
moles of N2
Hence Thermal decomposition of N H3 will produce
Solution:(Correct Answer:D)
maximum amount of N2
Weight of hydrated BaCl2 = 61 g
s

(114) At 300 K and 1 atmospheric pressure, 10 mL of a Weight of anhydrous BaCl2 = 52 g


as

hydrocarbon required 55 mL of O2 for complete Loss in mass = 9 g


combustion, and 40 mL of CO2 is formed. The formula of Assuming BaCl2 .xH2 O as hydrate mass of H2 O = 9 g
l

9
dc

the hydrocarbon is [JEE MAIN 2019] Moles of H2 O = 18 = 0.5


(A) C4 H10 (B) C4 H6 Grass molecular let of BaCl2 = 208
× 100
Ve

9
% of H2 O in this hydrated BaCl2 = 61
(C) C4 H7 Cl (D) C4 H8 = 14.75%
Solution:(Correct Answer:B)
18x
= 208+18x × 100 on solving x = 2
 This percentage is present in BaCl2 .2H2 O
Cx Hy + x + y4 O2 → xCO2 + y2 H2 O
10 10x
10(x+ y4 )

y
By given data, 10 x + 4 = 55....(1) (119) A 100 mL solution of CH3 CH2 M gBr on treatment with
10x = 40....(2) methanol produces 2.24 mL of a gas at ST P . The weight
∴ x = 4, y = 6 ⇒ C4 H6 of gas produced is ......mg. [nearest integer] [JEE MAIN 2022]
(A) 2 (B) 1
(115) The strength of 50 volume solution of hydrogen peroxide
is ......g/L (Nearest integer).Given: Molar mass of H2 O2 is (C) 3 (D) 4
34 g mol−1 Molar volume of gas at ST P = 22.7 L. [JEE MAIN
2023] Solution:(Correct Answer:C)
(A) 149 (B) 148
(C) 146 (D) 150
Solution:(Correct Answer:D) W
50 n×M
Molarity = 11.35
= 10−4 × 30 = 3 mg
∴ Strength in gm/L = 11.35
50
× 34

(116) If 5 moles of BaCl2 is mixed with 2 moles of N a3 P O4 , the (120) In one molal solution that contains 0.5 mole of a solute,
maximum number of moles of Ba3 (P O4 )2 formed is there is [NEET 2022]
............(Nearest integer) [JEE MAIN 2023] (A) 500 g of solvent (B) 100 mL of solvent
(A) 2 (B) 3
(C) 1000 g of solvent (D) 500 mL of solvent
(C) 4 (D) 1
Solution:(Correct Answer:D) Solution:(Correct Answer:A)
of solvent (g) × 1000
Moles of solute
3BaCl2 + 2N a3 P O4 → Ba3 (P O4 )2 + 6N aCl m = Weight
N a3 P O4 is limiting reagent. 1 = Weight of solvent (g) × 1000
0.5

2 mole N a3 P O4 gives 1 mole of Ba3 (P O4 )2 Weight of solvent (g) = 500 g

27
(121) A 10 g effervescent tablet containing sodium bicarbonate Solution:(Correct Answer:B)
and oxalic acid releases 0.25 ml of CO2 at T = 298.15 K Na2 O + H2 O → 2NaOH
and p = 1 bar. If molar volume of CO2 is 25.0 L under such 20
62 moles
condition, what is the percentage of sodium bicarbonate Moles of NaOH formed = 2062 × 2
in each tablet? [Molar mass of N aHCO3 = 84 g mol−1 ] 40
[NaOH] = 62
500 = 1.29 M = 13 × 10−1 M
[JEE MAIN 2019] 1000

(A) 0.84 (B) 33.6 (Nearest integer)

(C) 16.8 (D) 8.4 (126) The strengths of 5.6 volume hydrogen peroxide (of density
1 g/mL ) in terms of mass percentage and molarity (M ),
Solution:(Correct Answer:A) respectively, are:
Let N aHCO3 = x gm (Take molar mass of hydrogen peroxide as 34 g/mol) [JEE
Then, H2 C2 O4 = (10 − x) gm MAIN 2020]
∴ nN aHCO3 = 84 x
(A) 1.7 and 0.25 (B) 1.7 and 0.5
2N aHCO3 → N a2 CO3 + H2 O + CO2
∴ nCO2 = 168x (C) 0.85 and 0.5 (D) 0.85 and 0.25
x
Total CO2 = 168 + 10−x 0.25
90 = 25 Solution:(Correct Answer:B)
′ ′
On solving x
Volume strength = 11.2× molarity
% = 10x
× 100 = 10 x ⇒ molarity = 11.2
5.6
= 0.5
nH2 C2 O4 = 10−x
90 Assuming 1 litre solution;
H2 C2 O4 → H2 O+ CO2 + CO
mass of solution = 1000ml × 1g/ml = 1000g
∴ nCO2 = 10−x 90 mass of solute = moles × molar mass
(122) If a rocket runs on a fuel (C15 H30 ) and liquid oxygen, the = 0.5mol × 34g/mol
weight of oxygen required and CO2 released for every litre = 17gm
of fuel respectively are: (Given: density of the fuel is ⇒ mass % = 100017
× 100 = 1.7%
0.756 g/mL ) [JEE MAIN 2022] (127) The volume (in mL ) of 0.1 N N aOH required to neutralise
(A) 1188 g and 1296 g (B) 2376 g and 2592 g 10 mL of 0.1 N phosphinic acid is........ [JEE MAIN 2020]
(C) 2592 g and 2376 g (D) 3429 g and 3142 g (A) 15 (B) 18
Solution:(Correct Answer:C) (C) 10 (D) 5
2 O2 → 15CO2 + 15H2 O
C15 H30 + 45 Solution:(Correct Answer:C)
s

Mass of fuel = 0.756 × 1000 g H3 P O2 + N aOH → N aH2 P O2 + H2 O


as

No. of moles of fuel = 0.756×1000 nH3 P O2 reacted


210 = nN aOH1reacted
Wt. of oxygen = 0.756×1000 × 45
2 × 32 = 2592 g
1
l

210 ⇒ 1 = 0.1 × VN aOH


0.1×10
dc

Wt of CO2 = 0.756×1000
× 15 × 44 = 2376 g
210 ⇒ VN aOH = 10ml
Ve

(123) On complete combustion, 0.492 g of an organic compound (128) The percentage composition of carbon by mole in
gave 0.792 g of CO2 .The % of carbon in the organic methane is ........... % [JEE MAIN 2019]
compound is .................. (Nearest integer) [JEE MAIN 2023]
(A) 80 (B) 20
(A) 42 (B) 43
(C) 75 (D) 25
(C) 48 (D) 44
Solution:(Correct Answer:B)
Solution:(Correct Answer:D) In CH4
weight of C in 0.792 gmCO2 Mole of carbon nC = 1
= 1244 × 0.792 = 0.216 Mole of hydrogen = nH = 4
% of C in compound = 0.492 0.216
× 100 % of nC = nCn+n C
× 100 = 51 × 100 = 20%
H
= 43.90%
Ans:44 (129) The number of molecules and moles in 2.8375 litres of O2
at STP are respectively [JEE MAIN 2023]
(124) Hemoglobin contains 0.34% of iron by mass. The number
(A) 7.527 × 1022 and (B) 1.505 × 1023 and
of F e atoms in 3.3g of hemoglobin is.(Given: Atomic
0.250 mol 0.250 mol
mass of F e is 56 u, NA in 6.022 ×1023 mol−1 [JEE MAIN 2022]
(A) 1.21 × 105 (B) 12.0 × 1016 (C) 7.527 × 10 and
23
(D) 7.527 × 1022 and
0.125 mol 0.125 mol
(C) 1.21 × 1020 (D) 3.4 × 1022
Solution:(Correct Answer:D)
Solution:(Correct Answer:C) Number of moles of O2 = 2.8375 22.7 = 0.125
No. of Fe atoms = 0.34
100 × 3.3
56 × 6.022 × 10 23
= 1.206 × 10 20
Number of molecules = 0.125 NA
= 7.525 × 1022
(125) Sodium oxide reacts with water to produce sodium
hydroxide. 20.0 g of sodium oxide is dissolved in 500 mL (130) 1 L aqueous solution of H2 SO4 contains 0.02 m mol
of water. Neglecting the change in volume, the H2 SO4 .50 % of this solution is diluted with deionized water
concentration of the resulting NaOH solution is to give 1 L solution (A). In solution (A), 0.01 m mol of
........ × 10−1 M. (Nearest integer) H2 SO4 are added. Total m mols of H2 SO4 in the final
[Atomic mass : Na = 23.0, O = 16.0, H = 1.0] [JEE MAIN 2021] solution is ...... × 103 m mols. [JEE MAIN 2022]
(A) 62 (B) 13 (A) 3 (B) 1
(C) 20 (D) 10 (C) 2 (D) 0

28
Solution:(Correct Answer:D)
nH2 SO4 in Soln A = 50% of original solution
= 0.01 m mol.
nH2 SO4 in Final solution = 0.01 + 0.01
= 0.02 m mol
= 0.00002 × 103 m mol

(131) 10 mL of 1 mM surfactant solution forms a monolayer


covering 0.24 cm2 on a polar substrate. If the polar head is
approximated as cube, what is its edge length ? [JEE MAIN
2019]
(A) 2.0 pm (B) 2.0 nm
(C) 1.0 pm (D) 0.1 nm

Solution:(Correct Answer:A)
−3
×10
M oles = M1000
V ml
= 101000 = 10−5 mole
−5
10 NA molecules covering area = 0.24 cm2
0.24
1 molecules covering area = 10−5 NA
0.24 2
10−5 ×6×1023 = a
a2 = 4 × 10−20 cm2
a = 2 × 10−10 cm
a = 2 × 10−12 cm
a = 2 pm

(132) A hydrocarbon contains 85.7 %C. If 42 mg of the


compound contains 3.01 × 1020 molecules, the molecular
formula of the compound will be [NEET 2017]
(A) C3 H6 (B) C6 H12
(C) C12 H24 (D) C2 H4
s

Solution:(Correct Answer:B)
as

3.01 × 1020 ������ ��= 42 × 10−3 g


∴ 6.02 × 1023 ������ �� = 84 g
l
dc

∴ �������� : C6 H12 (C �� ��� 85.7 )


Ve

29

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