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(q) Explain principle of differential pulse potaro-
gaphy. 5 AQ _ ser
(r) Calculate diffrrsion cuncnt for an experiment Third SemesEr M. Sc. (part _ ID (CBCS)
if concentration of elcctroactive species is Cheotistry Examination
3mM, capillary characteristics are 1.35 and ANALYITCAI, CIIEMISTRY
difft.lsiotr curent constart is 1.56. 5
-I
paper _ X
(Thermal and Elecrroanalytical
Merhods)
5. (a) Write Randles's Sercik equation for reversible P. P!8es :4
prooess. How can it be used b determine
rev€rsibility of electode prccess ?
Tima: Thr€e HouN] tMar. Merla : go
6
(b) Give principle and tcchnique of anodic sri_ NotG I (l) All questions are coopulsory and
car4r
pping voltammetry. 5 equal marks.
(c) Explain arDperometsic titration of pb} (2) The use of log tablcVcalcuiator is
with
so'n- 5
permitt€d

OR l. (a) Explain the principte ard instrumentation

of
G) Explain application of cyclic voltammeEy TGA.
in adsorption studies. 6
6

(q) Discuss principle of

(b) What is DTA ? What are its applications
chronopotendometry. ?
_
5 5
G) Wbat isorganic polarography ? Name (c) Give comparison of DTA and DSC. 5
various reducible goups in organic com_
pounds. 5
OR
(p) Describe the TGA in case of rhermal
de{omposition of CuSOa.5H2O and
CaC2Oa
'H:o. 6
(q) Write explanatory note on Etermome&ic
ti&ations. 5

AQ -998 4 330 AQ -e9E

P.T.O.

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-of
G) The EMF following cell is 0.1182 V
Explain factors affecting DTA curvcs' Calculati PH of the solution.
5
(r)
Pt/Q, Hr Q, H*ll KCI (sat). Hg, Clr/Hg
2. (a) What are conductometric titrations'? ExPlail Given : Efi=06994v
conductometric titration'of mixh're
of acetic Eio.=o'Z4zzv' s
acid and oxalic acid with std NaOH (c) Give adYantages and applications of ISE.
6
solution. 5
o) Give advantages of coulometic titrations OR
over visual titrations.
5
(p) What are electochemical sensors ? How
(c) Explain the role of electrogravimetry
ir
enzyme elcchodes can be used as sensos ?
seParation and estimation of
metal ions-,
6
(q) Explain construction' working alrd app ti-
OR cability of glass electr6de. 5
What are high froquency titrations ?
How
(p) G) Explain estimation of Cl and I in a
canthey be carried out without dipping mixhfe using protenriometric titrations. 5
electodes in the solution 't 6

Calculate the amount of copper

in a solution
(q)
of
1 AmPere for 4. (a) Explain various tyPes of currents in
that requfues a cufient polarographY. 6
(Given
izO rnin. fo, comPlete etectrolysis" With suitable diagram, explain experimental
aLwt .of Cu = 63.5). 5 O)
set up of potarographic experiment. 5
Define overpotential What are tbe
factors
G) (c) What are reversible and irreversible proc-
affecting it ?
5
esses in PolarograPhY ? 5
OR
Write Nernst equation How is it applied
to
3. (a) in I (P) Write short notes on:-
determine number of electrons involved
cell reaction 2
6 I (i) PotarograPhic Maxima.
I
I
(ii) Half waYe Potential. 6
I
i AQ -998 3 P.T.O.
AQ -99E

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