Professional Documents
Culture Documents
1. IDENTIFICATION
A. Product name
- UNIPOXY COATING CURING AGENT
C. Supplier information
- Company name : KCC Corporation
- Address : 764, Gwahak-ro, Bongdong-eup, Wanju_Gun, Jeollabuk-do
- Emergency telephone
: 82-63-260-7000
number
2. HAZARD IDENTIFICATION
A. GHS Classification
- Flammable liquids : Category2
- Acute toxicity (oral) : Category5
- Acute toxicity (dermal) : Category5
- Acute toxicity (inhalation: vapor) : Category4
- Skin corrosion/irritation : Category2
- Serious eye damage/irritation : Category2A
- Carcinogenicity : Category2
- Reproductive toxicity : Category2
- Specific target organ toxicity(Single exposure) : Category2
- Specific target organ toxicity(Single exposure) : Category3(Narcotic effects)
- Specific target organ toxicity(Single exposure) : Category3(Respiratory tract irritation)
- Specific target organ toxicity(Repeated exposure) : Category1
- Aspiration hazard : Category1
- Acute aquatic toxicity : Category2
- Chronic aquatic toxicity : Category3
○ Signal words
- Danger
○ Hazard statements
- H225 Highly flammable liquid and vapour
- H303 May harmful if swallowed.
- H304 May be fatal if swallowed and enters airways
- H313 May be harmful if contact with skin.
- H315 Causes skin irritation
- H319 Causes serious eye irritation
- H332 Harmful if inhaled
- H335 May cause respiratory irritation.
- H336 May cause drowsiness and dizziness.
- H351 Suspected of causing cancer
- H361 Suspected of damaging fertility or the unborn child
- H371 May cause damage to organs (Refer Section SDS 11)
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- H372 Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)
- P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
- P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
- P308+P313 If exposed or concerned: Get medical advice/attention.
- P370+P378 In case of fire: Use Suitable extinguishing media for extinction(Refer Section MSDS 5).
3) Storage
- P403+P233 Store in a well-ventilated place. Keep container tightly closed.
- P403+P235 Store in a well-ventilated place. Keep cool.
- P405 Store locked up.
4) Disposal
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3. COMPOSITION/INFORMATION ON INGREDIENTS
- Immediately flush eyes with plenty of water for at least 15 minutes and call a doctor/physician.
B. Skin contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
C. Inhalation contact
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
D. Ingestion contact
- Please be advised by doctor whether induction of vomit is demanded or not.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
- If swallowed, large amounts of water to drink and do not induce vomiting.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
F. Notes to physician
- Notify medical personnel of contaminated situations and have them take appropriate protective measures.
5. FIREFIGHTING MEASURES
A. Suitable (Unsuitable) extinguishing media
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- Dry chemical, carbon dioxide, regular foam extinguishing agent, spray
- Avoid use of water jet for extinguishing
- Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
- Notify your local firestation and inform the location of the fire and characteristics hazard.
- In case of conflagration, use automatic fire sprinkler. Major fire may require withdrawal, allowing the object itself to burn.
- Due to the extremely low flash point, irrigating fire extinguishing may be less effective when put out a fire.
- Handle the damaged containers or spilled material after wearing appropriate protective equipment
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- If large amounts have been spilled, inform the relevant authorities.
- Notify the central and local government if the emission reach the standard threshold.
- Since emptied containers retain product residue(vapor, liquid, solid) follow all MSDS and label warnings even after container is emptied.
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- Avoid contact with heat, sparks, flame or other ignition sources.
- Contaminated work clothing should not be allowed out of the workplace.
B. Engineering controls
- Business owner is recommended to maintain below recommended exposure limits for the working place with general exhaust of
gas/vapour/mist/fume.
- Under conditions of frequent use or heavy exposure, Respiratory protection may be needed.
- Any chemical cartridge respirator with a full facepiece and organic vaporcartridge(s).
- Any air-purifying respirator with a full facepiece and an organic vapor canister.
- For Unknown Concentration or Immediately Dangerous to Life or Health : Any supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a
full facepiece.
○ Eye protection
- Wear primary eye protection such as splash resistant safety goggles with a secondary protection face shield.
- Provide an emergency eye wash station and quick drench shower in the immediate work area.
○ Hand protection
- Wear appropriate chemical resistant glove.
○ Skin protection
- Wear appropriate chemical resistant protective clothing.
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○ Others
- Not available
A. Appearance
- Appearance Liquid(Viscous liquid)
- Color Not available
B. Odor Solvent odor
C. Odor threshold Not available
D. pH Not available
E. Melting point/Freezing point Not available
F. Initial Boiling Point/Boiling Ranges 138 ℃
G. Flash point 19 ℃
H. Evaporation rate Not available
I. Flammability(solid, gas) Not available
J. Upper/Lower Flammability or explosive limits Not available
K. Vapour pressure Not available
L. Solubility Not available
M. Vapour density Not available
N. Specific gravity(Relative density) Not available
O. Partition coefficient of n-octanol/water Not available
P. Autoignition temperature 343
Q. Decomposition temperature Not available
R. Viscosity Not available
S. Molecular weight Not available
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
- Avoid : Accumulation of electrostatic charges, Heating, Flames and hot surfaces
- Avoid contact with heat, sparks, flame or other ignition sources.
D. Incompatible materials
- Not available
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- Causes skin irritation
B. Delayed and immediate effects and also chronic effects from short and long term exposure
○ Acute toxicity
* Oral
- Product (ATEmix) : 2000mg/kg < ATEmix <= 5000mg/kg
- [Xylene] : LD50=3523 mg/kg Rat (EU Method B1) (ECHA)
- [2,2,4-Trimethyl-1,3-pentanediolester diisobutyrate] : LD50 > 3200 ㎎/㎏ Rat (SIDS)
- [n-Butyl alcohol] : LD50 = 3430 ㎎/㎏ rabbit (GLP, ECHA)
- [Toluene] : LD50 5580 ㎎/㎏ Rat (EU Method B.1) (ECHA)
- [Ethylbenzene] : LD50 = 3500 ㎎/㎏ Rat (ECHA, HSDB)
- [4-Methyl-2-pentanone] : LD50 2080 ㎎/㎏ Rat (NITE, ECHA)
- [2,4,6-Tris[(dimethylamino)methyl]phenol] : LD50 = 1200 ㎎/㎏ Rat (TOMES;RTECS)
- [Dodecylphenol, branched] : LD50 2100 ㎎/㎏ (ECHA)
* Dermal
- Product (ATEmix) : 2000mg/kg < ATEmix <= 5000mg/kg
- [Xylene] : LD50 ≥1,700mg/kg Rabbit (NIER)
- [2,2,4-Trimethyl-1,3-pentanediolester diisobutyrate] : LC50 Rat >6.49 mg/L 4hr (5.3 mg/L 6hr) (HSDB)
- [Ethylbenzene] : Vapor LC50 17.8 mg/L 4 hr Rat (conversion value of 4000 ppm) (ECHA, HSDB)
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* EU CLP
- Not available
○ Germ cell mutagenicity
- Not available
○ Reproductive toxicity
- Suspected of damaging fertility or the unborn child
○ STOT-single exposure
- May cause damage to organs (Refer Section SDS 11)
- May cause drowsiness and dizziness.
- May cause respiratory irritation.
○ STOT-repeated exposure
- Causes damage to organs through prolonged or repeated exposure (Refer Section SDS 11)
○ Aspiration hazard
- May be fatal if swallowed and enters airways
- [Ethylbenzene] : LC50 2.4 ㎎/ℓ ~ 1.8 ㎎/ℓ 48 hr Mysidopsis bahia(EC50 48hr >5.2mg/L, EPA 1985, GLP)
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○ Degradability
- Not available
C. Bioaccumulative potential
○ Bioaccumulative potential
- [Xylene] : BCF25.9 (ECHA)
- [2,2,4-Trimethyl-1,3-pentanediolester diisobutyrate] : BCF = 5.2 ~ 31 (OECD SIDS)
- [Ethylbenzene] : BCF 1
- [2,4,6-Tris[(dimethylamino)methyl]phenol] : BCF = 3.162 (Estimate)
- [Dodecylphenol, branched] : BCF = 6266 (Estimate)
○ Biodegration
- [Xylene] : 90 % 28 day (OECD TG301F, GLP)(ECHA)
D. Mobility in soil
- [Xylene] : log Kow = 3.12 (measured) (ortho), 3.2 (measured) (meta), 3.15 (measurements) (p) (5)
- Stabilization and minimization treatment by incineration or similar method can be applied, if more than two kinds of designated wastes are in
mixture state and it is impractical to separate them
- Anyone with business license number who generates industrial wastes shall treat the waste by him/herself or by entrusting to the legal entities who
treat the wastes, recycle the wastes of others or install and operate the waste treatment facilities according to the Wastes Control Act
C. Hazard Class
-3
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-Ⅱ
E. Marine pollutant
- Not applicable
- Package and transport follow in accordance with Department of Transportation (DOT) and other regulatory agency requirements.
- Air transport(IATA): This product is NOT classified as dangerous for IATA Transport.
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- The information contained herein is believed to be accurate. It is provided independently of any sale of the product for purpose of hazard
communication. It is not intended to constitute performance information concerning the product. No express warranty, or implied warranty of
merchantability or fitness for a particular purpose is made with respect to the product or the information contained herein.
- This Safety Data Sheet was compiled with data and information from the following sources: KOSHA, NITE, ESIS, NLM, SIDS, IPCS
B. Issue date
- 2017-09-01
D. Other
- This SDS is prepared according to the Globally Harmonized System (GHS).
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