Ol. tan A axa fice corm, OR mare vo ot 8s Solve: tanA = 224 = 2. 2 tana = 02. cot {SE + (1) 3} ax ara leer, n eZ} @-1 wo vot 03 Solve: n = 2m a1 cay &, cot = +Cn§ = cot{mn +3} = cot = 4 [mez] [pS sem eres PES] n= 2m +1 feemnp zm, cot{(2m + 1) 2+ (1) = cot{(2m + 1) 1 03. cosa + sin@Z? + A) — sin (22"— A) + cos(t7m +A) =? v(ayo (1 (2 @-1 Solve: cosA + sin (23 x=+ A) —sin(23 x ¥— A) + cos(17# + A) = cosA ~cosA + cos — cosA = 0 04, sin@ = $2, cos28 =? @-2 vo-Z oz Solve: 2 sin? @ = 1 — cos2@ = cos20 = 1 ~ 2sin* 6 = cos20 @zZ 05, cos?Z + cos?S? + cos? + cos? =? @o 4 y(o2 @3 2 cos? 24 cos? + costar — 22) 2(n—™) Solve: cos? + cos? = + cos?(n— =) + cos? (n—2) an = cos?= ase 23m PE = of 22 + cos? { 2 2(3-2)} = cos*= + cos’ gt cos’ gt COs’ a 2} cos’ gt cos’ icos* 5 + cos* (5-5 = 2{cos?E + sin?Z} = 2.1 = 2 Or, Use calculator in radian Mode 06. sin(2022x) + cos(2022x) «a wr Fase conte (@ v2sin(2022x) V(b) V2cos (2022x-3) (c) —F-cos(2022x) (@ Vin (2022x + F Solve: sin(2022x) + cos(2022x) = sin(2022x) + sin(- 2022x) [+ cos0 = sin(2—0)] | (2oaaxs$2022K) (zozaxB2022) © ® ae = 2sin (EP) og NE) ~ 2 sin cos (2022-2) = VB cos (2022x—3) [+ sin = 7] 07. cosxsin(y — 2) + cosysin (z — x) + coszsin (x—y) =? v@o ()3 ©-3 @1 Solve: cosx(sinycosz — cosysinz) + cosy (sinzcosx ~ coszsinx) + cosz (sinxcosy — cosxsiny) = 0 [+ sin(A — B) = sin AcosB — cosAsinB] Ea ame ae ae OTT 7 SAR Soren Rae OT.Saat ay weirT-202R Sof napa yE-O8 08, sec( +6) sec(¥- 0) =7 (a) sec26 (b) 2cos20 < 2sec20 @3 zseez0 1 2 [r eos(A + B)cos(A ~B) = cos? A~ sin? B a 1-2in? A= c052A]) 09, 2 ae ara Fieoa orb? Solve: sec(= + 0) sec(# iremza (a) cota ¥(b) tana (© secA (@ None Solve: 224. = tanA rene zx ? 10. pres” (a) sec4x (b) cos4x. ¥(c) sec2x (@) cos2x Solve: 2 = = a = - = : = 2. =~ = sec2x ver = = : TEER Ta fares | Venvazerae Vivecomn SaGsomn) — ViraenTm — Zoek =? 11. cos? B(1 + tanB)? — (@)sin3 (b) sinB ¥(d) sin2B Solve: (cosB + cosB tanB)? ~ 1 = (cos B + cosB 2sinB- cosB = sin2B = (cosB + sinB)? — 1 = sin? B + cos*B + 2sinBeosB 12, 2c0s3f sara feo cr? vofo+ 248 wfe- 2438 oer wpe Solve: 2cos*& = ja cos? (2) = |2.2.cos? (=) = f2C + cos 15%) = V2 + Veo? 15° = J2+/2@ Fe0s30) = [2+ J2t2(2)=J24v20 Or, Calculator eq 1 13. A+B+C= 12M, cot cotB + cotB cotC + cotC cota =? @o v)1 @2 (3 Solve: A+B+C=1=>A+B=n—C = cot(A +B) = cot(n—c) SBA — _eotC = cota cotB + cotB cotC + cotC cota = 14, AABC 9A = 30° 6 C = 90° em, arb (@) 1:v2 (b) V2:1 ¥()1:V3 @ve1 = 180° — (30° + 90°) = 60° boa Sind = ans 15. sinA + sinB + sinC ex 7m Foo RB? v@e = @% Solve: sind + sinB + sinc = 242 + iatesbe fas re A sinB wee ROR gn Girehag as ae TE 18 AEA LTT TR OTSee TEFA T-oy 17. ‘Were: aS orFA-2022 16, x=4sin(t+2),y= 2cost mA, x—y =? [0 (@? +b? +c2) = (yZab) ote s V2 abt 2ab pe cosC = +4 = cos[n—(A+B)] = = —cos(A +B) = £5 = costa +B) fy 4 a=6,c=10 an cosB =2em, b=? @7 v8 (12 @13 . Stet? 3 Ht deg pe Solve: cosB = “#2 5 2 = SHOE 5h? = 64 b= Physies STP cB 4.Skg Sew semen SOC wat TH TT HS a, AM hoc NCAT CHTCAT TBST TM er AT CTT ¥(a) 5.6m? (b) 5.6 x 10%m® ()5.6x 109m? (@ 5.6 x 107m? Solve: V = SRE = —_45x8.314%278 6m? P Texa0-x101 325 OE aE tiem P BTC iT CATR | AA TTA CID IE TAT BAAS cas He gota SA BLE WT CATT AA AAR WIT rms ‘feos em Gy, RT BI BE RTA? v(@2 wp ©: @ar Solve: P = 25% x Cling = P! = 2x 2X EX (2C rng)? = 2P GEA SITETR HEE Comms = 300 m/s 1 FR oe IMRT TSE AT RE ee I FRO GA A, TRIM Coons FE ALA? (a) 75 ms~* ¥(b) 150 ms* (c) 300 ms~* (4) 600 ms~1 :300= PEs Come [Read 1 = 150ms~ Solve: 300 = JF = Crms = ysqt = 3% 300ms~! = 150ms"? aT OPT O, 4% RMS GM Hy 4a RMS ACH wot aay @1er (der Y@ie (oder far 1 Solve: Vo,!Viig = JRE [A= 1:4:Voq = Vin ‘FRB rer TTA AAAI PRCT RTE HfoMeT ATE FOP @4:1 (b) 1:3 (21 ¥@)3:5 19 eae RTT AGT NORR aad errE-RORR Seeel NEPA y-ow 24, 25. 26. 21. 28. 29. 30, 31. 32. 33. 34, ag ued OPTS 2m? IEEE HT stn 40K wrt @ ZAP BIE AT A | AH AAT Rt Rr Ter TAT a A TET ‘wrest 100K Be BS TS (a) 60Pa (b) 48Pa (©) 100Pa (@)40Pa Solve Bobom= x 100 = 60Pa ab eR TER CHEAT UTORR BIO FRO AT RE aR ae SAAT 127°C CLF 227°C 4 Bas eH, TRA IF ATER (ores (Zea Valera PV PU T Te 400 300K errata RICE EA rms GH EP ¥(@) 517 m/s (b) 498 m/s (©) 312 m/s (©) 626 m/s c= PR = fzasiece0 _ Solve: Crms = |= | es = 517 m/s ore so aT HTS HEM G X 10% we wae 2.5 x 10-2 | BoE AA TA fs AH EH TT OT (a)2 x 10% m7? (b) 3 x 10-5m-3 ¥(0) 6 x 10°>m~ (@) 5 x 1075m-3 . 2 —l = ee 25-3 Solve: = gi Finch ~ Fieaaawa10 xaos ~ 0% 10m 68% “tem 3 cater ATEGICr wa S cater cafe SOOK wrerarats aac | A Rect Cd cravat ie (a) 83140) (49884) () 16628} Y(d) 62355 J x BRT +2 x SRT = 15 RT = 62355] 100°C ererRTRTe 20g FBC «rH 20 cm Bee IT EER |e CAT ROA BH 32g | ACER STON PST Het FEY Solve: Solve: (a) 7800 kPa ¥(b) 242.275 kPa (©) 65.64 kPa (@ 12.34kPa Solve: P = BEE = 2283-097? _ 949.075 kPa v oa Fis OPE mo cra A GRBa atte? ; j ' tH @ x. © 7) @ P e Pe Solve: P p 30°C wrerrae ef any ey Referee eR (@) 7544.7 Jmol-* ¥(b) 3778.71 Jmol" (©) 1676.6 Jmol™* (@) None Solve: Ey = nRT = 3x 1x 8314 x (30 + 273) = 3778.71 Jmol STP ce 5 mol Op *stors aid fis Fe? (@) 1300} (b) 27000) ¥(e) 28371) (@ 34051) Solve: E = 2x nRT = 2x 5 x 8.314 x 273 = 28371.525] eo ra RT OCT coe Bac Be a as TE PO ee | TATOO we HF Soret aOR OT AP LE Sire? @H (&) 3H @sH “(7H Solve: P,V, = P,V2 Hpg + hpg = 8 x Hog «hh = 7H Famer A @ BYR orem TERA ETE 1: 21 eT TT ty Aha ETS ee? (@) 1 14 (1:v2 ¥(@)v21 Solve: 2222 = [2 - 2:1 Crmsz Ps Tain asthe as astern COTE 20 ofa cira Tore FRY eT.RR ered er-2028 Se IGM Hoy 35. 36. 37. 38. 39. 40. 4L. 42. 43, ase 2 ‘Chemistry Sacer seuany Gear Frese CRA ier (a) Lit > K* > Ca?* > Mg?* ¥(b) H* > Pb2* > Sn?* > Ni?* (©) Agt > Au > Cu?+ > Pb?t (d) ree aT 30°C errata eae cores cote Rea ae? 2n(s)/Zn?* (0.1M)||Ag* (0.1M)/Ag(s); Ey = 1.5V (@)-147V (b) -1.42V. (©) 1.42V ¥@147V Solve: Ee = Egy +2tIn a 1470 mrefre fe hese 3 min 48 154 fage arate A STP CowS THER H OT SRT ES? (a) 0.313 mL (b) 0.054 mL (©) 0.014L ¥@0313L te _ asxaxt 2 Solve: n = J = rey = 0.014 mole [H,0-—>H, +202] 1 mole = 22.41L é 0.014 mole = 0.313 L AP afar fee 8 fo oti sce oe we? @56¢ ¥(b) 18.62 g (0) 28g (@ 28.66 g Solve: Fe** + 3p” > Fe a + 1F = fmol Fes* = 18.62g Firms Carat CARS CHIT ME CTETS TAGS BH? S508 2 (a) NH,NOs (&) Kel (©) KNO3 ¥(d) Ret O.SL srrecrt 3M Ni(NO,), aati Bar fren 3.7A fps S wr wae SPM aT em wie Renae oe WTTET SE Ee? (@) 29M (b) 31M (©) 23M (023M sua 222528600 296500 M = 23M Solve: os Alz(SO,)s oreo Fas erence A 10g Al FICRICH rat a | es TS FES eR TT ace DIT CT Corea wreate FAcATS ‘nga 36.38 g rt er ere eng eT @ Mg () Fe ¥(0)2n (@) Mn Solve: #85 = 3 = x = 65.484 = 65.5 « «gf Zn 25°C erin 001M NaCl axes cre @t 2000 1 tferereer carreta Cae AIH oe wae RE, Hania CHEE AFeEOI STP ¥(a) 5 x 107 ohm=*cm? mol~? (b) 10 x 10? ohm™? cm? g. eqy-* (c) 5 x 10? ohm=! cm? g.eqv~* (d) 10 x 10? ohm=* cm? mol-* Solve: AM = K x 422 = 5 x 10%ohm~tem? mol sfre CaCl, cece fp ree eas 20.0 g is arg Frere CF ee FS eT et? (a) 48250C (b) 650000¢ ¥(c) 96500C (@ 1930006 Solve: Ca** + 2e” ——> Ca 40g Ca 2 x 96500€ 20g Ca i eenene = 96500CRGR aS THHFA-2082 See AGMA Fe-ob 44, CuSO4 ¢ NaCl arena Ro en ne fa Fes rae een craTATE 190.5g Cu Sat ee, Ow aacE we Na ANT ANTS BT ar ¥(a) 3.61 x 1074 (b) 6.02 x 1074 (c) 1.8 x 1074 (d) 6.02 x 1073 Solve: nye; = nzez > Ex 2 = Hy N= 361 x 10% 45, 35°C erastare 60 atm BiC% 4.75 mole He ‘1 SO min era car RCT CM Ora aes FART TR Bey RTO weet a SO min AO CuSO, Betas we few Ber TAT RH LACT AIFS Cu MT 0.5 cm GPs ARV ewer AoE AC sempre 0.01 cm pm aR ae CHOATE AE 7 [Cu we WAR 8.96 gm/em] ¥(@) 1050 (b) 9508 (10408 (9408 Solve: cx? erate wef = (4.75 x 2)F = 9.5 F 9.5 Fa wergs Cu args afar, $5 x 9.5 gm = 301.625 gm fe ae aemnea ecatatty, Cu = Sn(0.513 = 0.5%) x 8.96 = 0.28715 gm 301.625 2 PRATT = Se = 1050.41 wee, 1050 18 aa artes eet nem TTA) 46. 10-°M Fe®* ag sete zac wafer wa Hg Mt FHT TET 25°C OPA ATM 5% Fe?* area EReitjpett = 0.770 UA ERs ig FE? ¥(a) +0.7926V () -0.5926v (0) +0.5926V (@) +0.4926V Hg + 2Fe3* 2 Hg?* + 2Fe*+ t=0 0 10-7 0 0 Solve: Sane wo 3 = Ba t 0 (Bx) eto - 5x10 =a750- =95x10-4 x = Hele — o7s47s area E = 0 = £°— Tink =P as14x298 3 BO = Sink = SSR x In(0,171475) Engytigtt + Epestype2+ = —0.0226 4 Bags = —0.7926V + Edt ng = +0.7926V 47, ef cage RUD wget 2 ates S A GRATE ORT TATE 4.65 g aT TT ae | eee eAreR arteR wa ee rlengA TAS = = 108) Ma) 11.54% (b) 10.54% © 55% (d) 10.5% Solve: cafes wfgres vam 28% = (2 x 3600)s = 7200s Agt +e” Ag Mit __108%5%7200 a egrat es, W = Mit = E2SHI20 = 40.295 «erate wiron merat = AS yp = 11.54% 2 eGR ARR 11.54% 48, corr wien fee core Fane Bota Fits eR? (@ errmm or Oa ¥(@) =A 49. ERT art ETOH Cat TAS Face ATED CHA? (@ BHT (&) BHQ (©) TBHQ Y(@ EDTA 50. Es famrtefion feos eqs mete aPirET pH Fe? (a) 3.74, ¥(b) 3.14 (©) 4.74 4.14 eGR 5] ERGOT PTGna ra ertA-2022 on. 02. 03. 04, 05. 07. Sa cm ae ERA CFE 23 SEPA TEP FF-oy Math tan B ea ata Ross core? Om oma: ota Ofme Solve: tanB = Pept po tombe tan {n¥ + (-1) 5} carson eZ) @2-4 vovad O13 @3-4 Solve:n = 2mm, n cory mez we, tan {227 + (-1)™ 5) ein = 2m+1 em, nest, meZ veg, tan {(2m-+ DE+ Certs} = tan {(2m +1)3- sind + cos@=1 + A) — cos ("— A) + sin(17n +A) araarer (@ sina ¥(b) 2sind (6) 4sina, @o Solve: sinA + cos (22m + A) ~ cos (22m—A) + sin(171 +A) = sinA + sinA + sinA— sin = 2sinA cos0 = 2x0", cos20 =? Zz 2 7 3 @z ow “oz @2 Solve: cos 20 = 2.cos? 0 ~1 = sin? + sin? + sin? 4 sin? = @o (b)1 ¥@2 (@)3 ati? E dont tein 2p) +: eat Cre ens anton a® sm Solve: sin? 4-sin?ZE + sin? (e+ 5) + sin® (m~ 71) = sin?5+ sin? SE-+ sin? 2 + sin? 22 4+ cos?) (sin? + cos? =2 sin? = + sin? -5} = “Use calculator in radian mode; ». sin(2023x) — cos(2023x) =? (@)—V2eos(t—2023x) v(b) V2sin(2023x-2) (@) V2sin(2022x + 3) © VEcos(2023x) Solve: cos (5 ~ 2023x) — cos(2023x) [:. sin@ = cos (3—0)] ozaxtz0zsx) _ /2uesx—Z42023% s = 2sin (EE) sin A ) = 2in(2) sin (2023-2) = sin (2023x 3) cos(x — 60°) cos(x — 30°) — sin(x — 60°) sin(x + 330°) =? ¥ (a) sin 2x (b) cos2x (c) sin4x (a) cosx Solve: cos(x — 60°) cos(x — 30°) — sin(x — 60°) sin{360° + (x — 30°)} = cos(x — 60°) cos(x — 30°) — sin(x — 60°) sin(x — 30°) = cos(x — 60° + x — 30°) = cos(2x — 90°) = cos(90° — 2x) = sin2x ‘fom: x oa aa aT Fat Option test. iretora sore Page OT.RGR reS FrA-20R Stef TEPA FP-O8 08. deec(E#a)see( (a) } seca V(b) sec2a (©) 2sec2a (d) 4sec2a 1 2* cone) sccosBtsin§ _ > Solve: = sec2a [: 2 cos Acos B = cos(A + B) + cos(A — B)] ) cosEtcosza ~ costa 09. ‘LecosBt: (b) tan2p v(e)tan$ (@) 1+ cotB asintBrasinBcost — zainBisinbecos®) aeostbeasind cost ~ Zoosk snbreandy 202 1-cosA = 2sin?4 fandsinA = 2sin4cos4 1+cosA = 2cos?4 ase 7 Va+vae2cos4x (a) secx (b) 2secx (©) 3secx @deosx 2 2 2 2 Solve: == = ss = Se ia Pe a = a laawcarimy | Vievizeostax VEzam falrrensax) VaRcasTx 24 ay 1. cos?4(1+tan4)’ =? (@) 1+ cosa (&) 1-cosA Y(o)1+ sind (@1-sina A a? is ay? solve: cos?2(1+tan4)’ = {cos*(1 + tan4)} 2 = (cos +sin4)’ = (sin?4+ cos*4) + 2sin$ cos = 1+ sina 12. 2sin 3 aa am centr Ya) J2—V24V2 (b) J2+¥2 +2 © J2+V¥2-V2 @ Jj2-v2-v2 Solve: 2sin = [asin Z= fo(1 cost) = a frcose3= 2 fp(t+eos’) = [2 Jarv Or, calculator «# *TaIcr option test. 13, A+B+C= 1x, tan3A + tan3B + tan3C =? (@) tan tanBtanC (b) tan2A tan2Btan2C —-¥(c) tan3Attan3Btan3C(d) None Solve:A+B+C=1>A+B=n-C => 3A + 3B = 3n— 3C = tan(3A + 3B) = tan(3m— 3C) tandAtanaa Seance ‘I-tan3Atan3B gene = tan3A + tan3B = —tan3C + tan3A tan3B tan3C + tan3A + tan3B + tan3C = tan3Atan3B tan3C 14. ABC fice: A = 75°, B = 45° er c:b =? @ V3: v5 ¥(b) VB: V2 (v2: v3 @V5: V3 Solve: 75° 445° + 2C = 180° = £C = 60° sist _ ge yas sins = V2: V5 ‘sineo" Bry avo THT PAGE NeesSlee SYS arterR-g02 Bee APA F-0y heost?Aain2B, i 15. 2cos?4 +4 c0522 4 bcos22 = 300875 + fcos?S + Leos? =7 OF oe os Wz Betoat) eae w(t 26 _ atebt-c4zab cos? S = eebenctezab 2 ‘abe atebiectizabszbeszea _ (atbig? aneeg ‘abe ‘abe -~ 2 38 Box ty = 2V3sint an yer mneerleR0 < ts 2) ¥(c)2 cost @ 2sint (sintS—eost2) = 2v3 sint— 2 cost 16. x= 4sin( (@)sint (©) cost Solve: x = 4sin(t— 3) = 4(sint cos — costsinZ) axty=2v3sint «y= 2eost 17. SABC 4, a* + b* +.c* = 2c?(a? + b?) wer, cos(A + B) a ats tea cara OF v3 @-% Solve: at + bt + c* = 2c?a® + 2bc? = (a2)? + (02)? + (-c?)? + 2.0% (=0*) + 2.b?, (—c?) + 2a7b? = 2a7b? = (a? +b? +02) = (V2ab) > = cosC = +45 cosa ~(A+B)] = 45 9 —cos(A+B) = 45> cos(A +B) = 45 ¥(d)a&c Bek 18. AABC @ a= 6,b= 8 «Rc = 10 BM, cosB at FE? 2 2 5 a @ we o: ve F+ch—b? _ 674107. Solva;‘cosB. 2ca ‘2x6x10_ 5 Physics 19, STP co 6.5 kg BAe Ara eTeT WAT STE TET Se, UA YA HUT CHEAT TTT TE HT TY (a) 5.6 m3 (b) 8.9 m3 ¥(c) 8.1 m3 (@) 6.5 m3 yc ORT _—65x09160273__ og sas Solve: V = "5" = sazaazaaotaaexio7? 01 ™ 20. ei orem Bat Bem amen | ME aT a ee ME a OMT HE Se SCH CHAT rR TEMA rms C4 OTT HEM BA, OA HY FS UA? | @éatm (b) 12 atm (© 14am ¥(@) 16 atm Solve: P= 2x52 x Clings Pe = 1x 16x 3 = 16 atm ICAL SITE BEE Cymg = 600 mm/s | ce am ra aT RE MR TAS SH REO AT EE, IR Cems 4. ¥(a) 245 m/s (b) 300 m/s (©) 400 m/s (€) 345 m/s Solve: 600 =, [28 «. Cems = a = 2 x 6002 = 244.95 = 245 ms? i 3 Serre oe PGT OT. OM eR as ach CoAT23. 24, 25. 26. 21. 28. 29. 30. 31. ‘See AGHA FF-0b @} Solve: Vy,:Vo, = {Ex Es. Vy {6 eran om Se RTO eRe oon eT EP @u2 (4:3 (0) 5:21 (3:38 ‘Fog sr sore 4m? sree rem SOK wrest a 25Pa pre aa MT | A ste Rte Rhee wher eat ea RN TRL STAT 200K %H, FRE Fit FS RA? (@) 50Pa (b) 60Pa (©) 80Pa ¥(@) 100Pa =P; = 22x 25Pa = 100Pa “fhe 0 CCT Te, Ao 2 PEEP, RG TOT ¥ (0) ierert (genera @ Zeta )¥, saat = V, v2 = (1-2) = SOOK errata eremTfen ge STA we? (@) 516 m/s ¥(b) 204.15 m/s (©) 312 m/s (@) 399.2 m/s _ ft [wastes Solve: Vavg = at = aviazato=tag = 204.15 m/s TET ATH VOM TG AS TW 7 X LO~Fm © See TH 3.6 x 107M m 1 rete ata ET ee ARTA wa ae 787 (a) 7.8 x 1076 Y(b) 2.5 x 1075 (©) 8.7 x 1078 (@) 8.8 x 107° " 4 a 25) -3 Solve: n = Fai ~ Franoeia aro ~ 25% 10m cA one 3 CET ART ee, SCT TF SOK TMT eH | TEA AR cn ETE (a) 83140) (b) 49884) (©) 16628) ¥(@) 62355 | solve: U = Sn,RT + 2n,RT = $x 3RT+3x SRT = 15 RT = 62355] 2 a 200°C wrrrmTATT 40g Nz et 30cm PITM com a eH | CCAR STETA No SICH BI ee? (a) 7800Pa (b) 242Pa (©) 49673Pa (@ 39674Pa art _ xea14xe73 Solve: P = == Eoar Par 49673Pa Re wps CRT TTR CTT OTe He? x P Pp @| © 1) @ i= T 2 T Solve: gx wry, P « T 40°C wire ef ar ay Bae TEAR CaS se are? (@) 7505.7) ¥(b) 6505.7) (©) 7000.2} (d) 6000.2) Solve: E = SnRT = =x 1x 8.314 x 313] = 6505.7] 2 4am consis ae acto come 6 ATS ETH ARG oTSa ay anda 2022 Stele nA How 32. STP 086 mol CH, smrore cx mesa? (@) 50020.2) (b) 47664.162) Solve: E = SnRT = $x 6 x 8.314 x 273] = 40855) 33, ap gra RENR wer cae Boer Beh TT a ATEN 10 OTHE MACH wrt H Hib Ewe A OA HN RO srSiaet we? @H (b) 4H Solve: P,V, = P,V; => Hpg +hpg = 10Hpg «. h = 9H 34, Fmoet C-s D gi sera wagA e_eTE 2:3 | wl ES Hg ACN TE FEY (a) V2:V3 ¥ (b) V3:v2 (©) V2:v7 (@) v7:v8 (0) 45664.34] ¥(d@) 40855} (c) 10H, ¥(d) 9H Chemistry 35. ety feeted wets cow oepaTea Frcs Comnid abe? Y(a) Li> K> Ca > Na > Mg (0) H> Pb > Sn>Ni>Al (©) Cu> Hg > Ag > Au> Mn (@)Al> Mn > Cr > Zn > Mg 36, 35°C wrosrarn fiers carats oe ER FE? ‘Zn(s)/Zn?* (0.1M)||Cu?*(0.01M) /Cu(s); Eg.y = 1.11V (@)-1.06V ()-1.08V (©) 1.082V ¥(@)1.079V Solve: Ecenn = E2,y + Hine - 1,079 37, afre Re ofics 10A Fege 250 sec IM ees as wa A IT Op N91 Dery aA? (a) 6.476 x 10-%g ¥(b) 0.2073 g (©) 04145 g (@) 0542, a Solve: 2H,0 —> 2H, + 02 n= # = 10825 _ 6.476 x 10"? mole eF ~ 4x96500 1 mole = 32.0, 6.476 x 107% mole = 0.2073 g 0, 38, 1F afar wie iat Fe g CRAP OTT BRAS way (@) 55.85 ¥(b) 27.93 g (©) 18.62 (@) 28.66g Solve: 2F faays wat feefae er 55.85 ¢ AF faqs wat fronts eH 27.925 g 39. FICoH HATE fs CoICRR Mae CARTE TARE BAT? (a) NHyNO3 (») KCl ¥(o) NaNO; (@) KNO; 40. Au eigearas a0 for AuCly ars wae Regs rare Brera sat ee 10 FARA ora errCeITEA Be 1.314 g af Crm | Fags aE AT 5 2[Mgy = 197] (a) 4A ¥(0) 3.224 @5A | Solve: It =nan@auF = = 3.22A 41. efips Ficaretorer crrAT CuSO, att Fae siatcen wer Sg Cu war xe 1 ek sao Fe wee AT AT ae Ee TE fecareht EH 1.417 g OMe) eae ere aT Y@al () Ni (Mg (@ Fe Solve: Y = $5 = x = 27g (Al) ? Ser asia ae aeirn come a aaa C ea SICH RGR TAT.Sarena SUS TRIFA-R0Rg See AGRA T-O8 42, 25°C erenrare 1M H2S0, sre sierfiew aftateer 16 x 10-2 ohm~fem=! ea, «ee rma Hea Gar ofere Fo? 4B. 45, 46. 47. (a) 180 ohm~tem?mol~? (c) 20 ohm~*cm?mol™* 00a _ sononroeto? () 40 ohm~tem? molt ¥(d) 80 ohm? cm?(g. eqv)-? Solve: A 7 = 80 ohm-tcm?(g.eqy)"* et ncifteccer 1.60245 x 107°C fags fae eer | a ange oe cae STI St oiftart Regs oa aT? (a) 9.6499 x 10°C (b) 9.649539 x 10°C —_-¥(c) 96499.539¢ (a) 4.69 x 107¢ Solve: sercwtsh area art faepe otfteR rr 1.60245 x 10-19C 6.022 x 108 1B eewcxiSh eer OREN sifeeR wR, 9.6499539 x 101C Rye! CuSO, © NaCl artis ace Fron awe afar wig eee wer oy ANCE 127g Cu Bar en, Sw AAT Te Na HALTS BET? ¥(a)4Nq (b)2Nq ()3 Ng (G)5.3Nq N = ne, 2 22 a. = Solve: nyej = me, = EX 2= Ex 1 > N= AN, 35°C wiemtara 60 atm Be 4.75 mole Hy °F 50 min Kea corm ARE REA OAC eC fae aC Beg PTT sen aH 50 min et CuSO, eae wer Frew bier eat aE TREE MATES Cu TE 0.5 cm TPE FAA HM CHT AE ‘eft 0.01 cm ter aR ect creat BA 2 [Cu ae TAF 8.96 gm") (a) 1050 (b) 950 (10408 (9408 Solve: cid staifee vis = (4.75 x 2)F = 9.SF 9.5 F a earge Cu aga aft, S* x 9.5 gm = 301.625 gm cafe or eercra carer, Ci = in(os1? = 0.5%) x 8.96 = 0.28715 gm 2 FCT we = 1050.41 a4 1050 aa mempfera ete Gem ITT 25°C wimaty wai ceagiee wives sas wbrer pH 41 worms elenabe wet Redow? ¥(a) 0.2365 V (b) 1.236 (c) 0.635 V (d) 2365V. Solve: Hy scars fitters, He -e + Ht © aout . En.sat = Enasut — — log[H*) _ 2R0RKR314298 Sy =log{H*] = 0 ee allt ] = 0.0591 pH [ore —logH*] = pH! = 0.0591 x 4 = 0.2365 volt ‘eer racer wpe Facet Bee emamT aes feeb: 2CHsCOO™ > CHs ~ CH + 2CO, + 2e~ Cohen Beas HATA Hat 2 wT 20 FARE TRS 1.5 A wee STR HAT FAT RH | 35°C SrtA wey 761 mm(Hg) Ber Berey Bee STO SEH Fe? (@)3.298L (b) 2.298L ¥(0) 1.6491, (@) 4.2981 Solve: eats wf Q = It = {(2 x 60 + 20) x 60} x 1.5 C = 12600C «fafa ace oi, 1 mol Beer oT Beers ZF Fe eT * 2 x 96500C fas ag viet CH3CH; 1% 1 mol 00 + 12600€ fegp ere peer CHaCHg “eR wR, = Heer mol = 0.0653 mol View, v = MRE = Sosezengonaes = 16491, 48. fe Fact career STEATEUT CRC FET AT CTAB? (@) eePRR et ow (b) eae eT (©) ae ie ee ¥@) SIF UI SIGE BT 49. crate erate army Hees? (@) Fri (b) arenes BIS HME (0) aire Fae Yd) cater arate SO. gs Gemretter feos ares entire oficem pH aT FS? (2) 3.74 3.14 (4.74 (a 444 Ea corstieg os aa Come 28 fied aera Pray sea,‘UR aS TRFA-2022 SRele HEA FE-Oy Math O1. cos(45*~ a) (a) V2 (sina + cosa) (6) % (ina — cosa) v%©) Flsina + cosa) (@cosa+sina Solve: cos(45° — a) = cos45°cosa + sin45°sina = cosa + sina = Z (sina + cosa) 02. cot {+ (—1)° 3} waa wor fren ZI @2¥3 YO (1431-8 @+% = 2m, [n= ore] mez cot(2 + (-1)°™ 5 = cot (mn +2 2m +1 &, [n = Reeny] me Z cot {(2m-+1) 3+ (-ayema3] Solve: 03, sinB +cos (n+ B) +cos(2n—B) +sin(191 +B) =? @)sinB (&) 2sinB (©) 4sinB y¥@o Solve: sinB + cos (2 + B) + cos (2 — B) + sin(19x +B) = sinB + sinB — sinB ~ sinB = 0 04. cos@ = 2 we c0s28 ot woe o# oz Solve: cos2 = 2cos*@-1=2 “(2p e # 05, sec? AE — sec? 3 + cot? it — cot? St y@o 1 (2 (@3 Solve: sec? (1 sec? (2n+ ) + cot? (28-38) — cot? (2+ 3) = sec? sect + tan? 3 — tan? iF = (sec? $— tan? $8) ~ (sec? ~ tan?) =1~1=0 6 ee caloultor fran ode, 06, x ee cate WIFE BAF cos(2024x) — sin(2024x) ata ara ace RA? “O) go36 OF © aose Om Solve: cos(2024x) — sin(2024%). = sin (S — 2024x) — sin(2024x) = 2.cos (ae) in 2eos%- sin (=—2024x) 2024x) archos et wT, 2 nate 8 EME GH yet ® we Gnton = eaons” #028" #2024 42028" F207 nm Se on 130 17m (andi) ‘os6” 8096’ 6096” 8096" 8096 “""" 9096 Sao amare as ache CATE 29 Aaneere eaTee GT TH.SRR ere arr-20Re Sear NEA w-08 07. sinx sin (x + 30°) + cosx sin(x + 120°) =? @} os voe @-1 Solve: sinxsin(x + 30°) + cosxsin(90° + x + 30°) = sinxsin(x + 30°) + cosx cos(x + 30°) = cos(x + 30° x) = c0s30° = 08, 2sec(= +B) sec (=—B) =7 (@secB (6) 2sec28 (o)4sec2B (@) —secB ~— 2 4 a Solve: (EB )cost=B) ~ Deos(1B)eon(=8) ~ cosEcosan ~ #52678 [s 2cos(A + B) cos(A —B) = cos2A + cos2B] A-costatsinze _4 09. yeoszarsinza @sina (b) cose (tana (@ seca Solve: 22107 8#2sinacosa _ Zina (sine#e088) tang * 2eos# aezsinacosa ~ 2cosa(cosw+sina) — 10. Terre (a) secx (b) secax (©) coseck (@) cosec2x Z pg aS el SI Solve: aes Ve azcastn VE tamnat ~ Jaco) ~ Vizai im = COOH 28 BN 2 11. sin?2 (1+ cot§) -1 (a) cosB (b) cos ¥(c) sinB @ sing 2 2 solve: {sin (1 +cot3)}' ~1 =(sin+cos;) -1=sin*2-+ cost2 + 2sinzcoss—1 = sinB 12. 2cos for cone ma? (a) f2+V24+V2 fo-J2r op+a-e @e-vaee Solve: 2cos== [2.2cos*£ = J2(1+cost)= |2+ 2(1+cos8) = 2+ /24V2 Or, calculator «# aac option check. 13, sin2A—sin2B + sin2C =? [ WH#A+B+C=n] (@) 2cosA sinB cosC V(b) 4cosAsinBcosC ——_(¢) cos sinB cosC (@) cosA tanB cosC Solve: sin2A — sin2B + sin2C = sin2A + sin2C— sin2B ‘sin(A + C)cos (A —C) — 2sinB cosB = 2sin(n — B)cos(A — C) — 2sinB cosB sinB{cos(A — C) — cosB} = 2sinB [cos(A — C) ~ cos(n— (A+ C)}] sinB {cos(A — C) + cos(A + C)} = 4 cosA sinB cosC 14, AABC 4 B = 45° ex C = 105° @, a:b =? (a) 1:V3 (V3: Solve: A = 180° — (45° + 105°) = 30° ~ (@)v2:1 sina sinB Taga arrehe ae eho Cre 30 ae Sore ET PA OT‘MRR ag oriA-2032 Stele AQHA FF-08 1s. 16. 17. 18, 19. 20. 21. 2, on arnt ae aa GE 31 3 sinA+2 sinB +2 sinc 4 A a Ox “Os ox OxR Solve: FbesinA = A= sind = # center, sinB = sinc = 2 sweeten tay bay emt x= 4c0s(t+3) any = dsint,0 —cos(A+B) = 1 Aa = cos(A +B) = te = cos = 44> cost —(A+B)] = a= 6,b = B84 cosB = 2am, ¢ =? @s 7 (12 v(@ 10 Solve: cosB = S#2-** , 2 S48 5-2 36¢—140= 0 aT Sa, c= 10 Bxexe Physics STP co ee Sra SANT acs STAT WT TRH STEN Bm Ty, A LSTA ALAT CAT TRIE TERS aT AT? (a) 6.13 kg (6) 5.85 kg (6.93 kg ¥(d) 6.43 kg Solve: PV = 2 RT = m = SUM = MURAD ABAT 6.43 kg oA ER hat BT OPH | MA ATE CMS Ge RT I MAAES ACN ROT AE © OH HL OAT RH eR CHO I 9 atm ea BH, We WICH CH ww OF RA? (204 V(b) 304 (joe @ser Solve: PV = 1m NCing = (ins)? md «Chime = 3 Cems AT OTT HT Cems = 700 m/s 1 FH ot FAT SreisTa SLE Fal A, SH, Crome =? (a) 500 m/s. ¥(b) 494.97 m/s (©) 595.97 m/s (@ None FET a Solve: Crms = [pe =? Crm $* 700 = 494.97 m/s Fae wrest Hy 6a RMS Gt aa Ne aE GORE SPE wo RA? (=) 1:2.17 (b) 2.45:1 ¥()4.06:1 (0) 3.83:1 Solves te = = 4.06 + Coming Cavan, = 4.06:PR Gefe Sea ATIBA-RO Stale HEPA FO 23, Ae orerara aH PRATT NH me COg TET a Heelies ETE SS A? Y(@) 3:2 (b) 2:3 @ut @24 a Solve: t a EE, =3:2 24, 70K wrermtat ae SO Pa Bie FR ee spe ATER Sm} | wrerara Fes cae ICA BI 2B Pa FAT RI, LHS AEH FS? (@) 9.83 m3 (b) 8.33 m> ¥(c) 8.93 m> (@) 8.39 m3 Solve: P,Vy = P2V2 = Vz = 223 = 8.93 m3 25. MRE CTE MTR HTT Foro at a oe WTAE 27°C cee 127°C A RH, HR HT Y@) Sere (b) Zee arg (© peers (3 ermwe sete 20 Bap, =o, R= Qa -$)r, =5h 26. GOK wrrare cece rs eT CM HP Y (a) $12.39 m/s {b) 612.39 m/s ()617.4m/s (@) 714.12 m/s Solve: Cups = & = [PRSHA mm/s = 512.39 m/s 27. CHET to wate stp TE 7 x 10-Fm, WTP 3.6 x 10-1 ATOR ER CERT, cE WAT SH TS? (a) 7.8 x 1076 ¥(b) 2.5 x 1075 (©) 8.7 x 108 (@) 8.8 x 107? aah = Trae = 248 X 10% 28, Tera was a eo ATG AKT + C.| g APA HORT AT | MTT STN FT aE K, CT] @} V(b) 3 (@ crater Solve: Fo P & Cine & Ta q= 1 29, 400°C eiratan Sg Hy Se r = 0.3m apts h = 0.2m Bee sce cere ATE CHER ETE DIN FY (a) 7.8 x 10°Pa ¥(b) 7.42. x 10°Pa (©)7.9 x 10°Pa (@) None _ant _ Srostaners Vv ~ axostso2 30, fis errant cae Cort atte? Solve: n = Solve: P 7.42 x 105Pa v@? SS o? @? Ny V v Vv Solve: K, w sfeqe faott ac) 31, 60°C errr ce ee TREO TICE CHE re? (a) 1.15 x 10-7 J (b) 1.51 x 107°] (0) 1.15 x 10-29) (151 x 1079] Solve: E = S27 = 2 x 8344 x 333 = 1.15 x 10-7] INq = 2™ Bo2x105 32, T corr N care Feat pre re eeeaTEST TSTMTAT VMAAATSS aATAT GT OPT Ae emTESS AT | TE CHB oT fiero? (@0 (b) ZaRT ¥(@)—nRT (inet Solve (N= n)RT + $nRT—2NRT = —nRT Taw aay as acon om 32 PRT AT PRGRRA oS wrbT-2038 eve agra FP-08 33, elt conreera gram Erna wane cece Gogh eb I eI 4 waa IERTMT Bo H Ha Boer ere DN AT arn tne 757 (@) 16H ¥(b) 63H @4H (@3H Solve: P,V, = P,V2 = (Hpg + hpg)V, = 42V;(Hpg) = Hpg + hpg = 64Hpg > h = 63 H 34, 02 9 CO, 7 mere HCPA WANTS 3:2 | CIE DIT ARIA ET BI APACS SPE SP Y@QVENS (0) Visv2 (© Vav5 (vive Solve: 7 = f= fi Chemistry 35, Frooe afore fiface comtt abe? (@) Al> C > Cr> Mn (b) Cd > Co> Sn >Hg> Pb () Mn > Zn > Fe > Cd > Cr ¥(d) Cu> Hg > Ag > Pt > Au 36. Cr/Cr3+(0,2M) |[Fe®*(0.1M)/Fe waft wit core fer wa we wteatare Pa EMF 2? [E21 = 0.28V] ¥ (a) 0.2642V (b) 0.3346V_ (c) 0.2132V. (d) 0.295V Solve: Eee = Ey — vog t = 0.2642V 37. ME HSO, Ries onfte Ter fer 2.5A fees woe ete saee Boe wreaTat 6 Bie GOOML Hew Serie A? (a) 54.46 min (b) 43.64 min ¥(c) 3446 min, (@) 41.22 min Solve: 2H* + 2e~ —>H2 2 x 96500C fags tat eat eT = 22400mL Hz 25 x tC Rage wat eat et = 2202S mL = 600 mL > t = 34.46 min 38. AgNO S90 1A faqs 2 min ex erat Facer aTTNTCS APRS eR TE (a) 0.0134 g Y¥(b) 0.134g (©4132¢ (134g Soh ME = MERGES g = 011348 39, Fras carat sar cee Fear? (@) HF ¥(b) KOH a ©) CraHz20. Bt (@ feow af 40. 1L saTerrs 1M Ni(NO3)2 Beet 2F aps Bera aac wipe Acareee oe MTT HE ACT @ 05M (b) 0.25M vom (01M Solve: Ni? + 207+ Ni QF Fae Be BAC ICE BT BA 1 mol Ni 1 ware TARE Ay AT BO mol | Hehe aT VATA O ALE 41, att ateq sacra START O.5A Regs 5 min a seafee Farr TATE BA 0.168 g BH Crt | TEA eIMes wa 108 TTT TETET FS? @4 Y0)1 @2 @3 Mit _ 108%0.5x5%60 Solve: n= = ee = 42. 1M SO, etre erenfs card 6.25 ohm cm Rem, wee wey after ws? ¥(a) 80 ohm~*em?(g — equiv)“* (b) 40 ohmtcm?(g - equiv)* (© 20 ohm~*cm?(g — equiv)~* (@ 100 ohm~tcm?(g — equiv)-* itetera aor PGE OT. Sam erate ae asin me 3sar ag eiN-20%8 Ste nar gP-o8 Solve: 1M H2S0, a1 S48, 98g HSO, sive 1L BCT 4% FT ET HSO, = = 49g wrong 222° = 500 cm? weer = 500 cm? “a =) ohm cm ene 3 aag Ohm™* em™* = 0.16 ohm™1cm™> + wr ataeeT = A = KV eq = 0.16 x 500 = 80 ohm-tcem?(g — equiv)-* 43, area ae wentcue core § SH 250mL MECHA CuSO, FRE RTA OneT O.3M We O.1SM wet ee CARTS Zn AT wr eehe RT? (a) 1.3625 g (b) 2.083 x 10-6 g ¥(¢) 1.3625 x 107 g (d) 2.083 g Solve: Wretata Sats CoP MeTTT otfeTsT = 5 SST Zn ALOR SEEPT | “a, (250 x 10-9 x 0.3 — 250 x 107 x 0,15) = 5 x 3600 sec 4 SAT! + Lsec 40H 88.8% = 2,083 x 10-© mol = 2.083 x 10-° x 65.5 = 1.3625 x10 g 44, Gren wn watt 160 mA “flea Fey, 40 min 4x BerT eat eT | RRC AAS Cu MIRTT TFS? (a) 1.194 x 1074 (b) 9.36 x 1076 (©) 4.68 x 10"* @ 11.94 x 10% Solve: N = Hx Nq = XO AOE 5 6.03 x 10 = 1.194 x 107 45. Cues way 9.58 gcm-?, 10 x 10 cm? crmecra onosa Be 10-2cm Fares Cu vim errs FES CuSO, TARE AM, ACMA werner #57 (@) 272924 (b) 30478.4¢ ¥(o) 2911717 C (@ 2971117 Solve: Q =“ = psexaoxtoxdo _ 99117.17C 46. we Sra Pt, H(g) (Ibar)/H*(1M)||M4*/M?*, Pt cere Been) = 0.092V, Eiger pygas = 0.15 VI wt = 10% ey om xen ate? @1 1 ()-2 “(2 Solve: cere fara: M** + H(g) ——» M?* + 2H* 2200 og MIME jog 108 = + Beat = Ea) — era 47, aera ere fp ere re to ea 2CHCOO™ + CH3 ~ CH, + 2CO, + 2e~ ea Rares war ATT 2 ST 20 AAPA IAS 1.5 A ARS ATR DieAT aI | 35°C rTM aa 761 mm(Hg) Bier Gerry Ber OTC SITE FE? (a) 3.298L (b) 2.298L, ¥(c) 1.649L @ 4.298L Solve: eatfee wige, Q = It = {(2 x 60 + 20) x 60} x 1.5 C = 12600C + faftear aoe 7%, 1 mol Roe PT BeoTTR ZF Fee TAT 2x 96500C fegycrae HHA CHCHs “1% 1 mol 2600 + 12600€ Rage ere Data CHsCH, sent aes, = =Zer mol = 0.0653 mol 2x=2 ‘tort semen V we, V = PRE = See = 1.6491, 48, crm oeta ory ATE At Hy Sn Gi ae baer ean Pe woe, @asto ¥ (b) Sproat ort (©) ees @ srr oe 49, cos cmt fare corer smPbafCEs? (@) canner ste V(b) Vit-C (©) EDTA (@ BHA 50, aiken wedtcen zenfearena SHEE pH aA eo? (45-55 (b) 55-65 (0) 65-75 @75-85 faa earn ae aon come 34 fase eT PRE AT.‘aa awd erirA-202 Sere TEP F-ow o1. 02. 03. 04, Mat eI FH GH, cos” A + cos? B—cos*C = 1 — 2sinA sinB cosC PN#,A+B+C =n) Solve: L.H.S = cos® A + cos? B —cos?C = 31 + cos2A) +5(1 + cos2B) ~ cos? ¢ = 1— cos? C+ 2 (cos2A + cos2B) 1 =1-cos*C+ 72 cos(A + B) cos(A — B)} = 1 — cos? C + cos(m — C) cos(A— B) = 1-cos?€ — cos cos(A — B) = 1 — cosC{cosC + cos(A — B)} = 1~cosC[cos{n — (A + B)} + cos(A ~ B)] 1 —cosC{~cos(A + B) + cos(A ~B)} = 1 — cost: (2 sinA sinB) = 1 ~ 2sinA sinB cosC = R.H.S (Proved) cosa + cosB = am sina + sinB =b = area at, cos(a— f) = 5(a? +b? — 2) Solve: orst} az, cosa + cosB = a = (cosa + cosB)* = cos? a + cos? B + 2cosacosp ‘aia, sina + sing =b => sin? a + sin? B + 2sina sinB = b? ~~ (ii) @) + Gi) cea, (sin? a + cos? a) + (sin? B + cos?) + 2 (cosacosB + sinasinB) = a? + b? > 141+ 2cos(a—B) =a? +b? = 2cos(a—f) =a? +b? -2 + cos(a~ B) = # (a? +b? - 2)(Showed) arene ct, cos20° cos40° cos60"cosB0° = + 2 ~@ Solve: L..H.S = cos20°cos40°cos60°cos80" __28in20® cos 20° cos 40% cos60° cos80® _ 2sin40 cos 40 cos 60" cosa0? _ 2sin80°'cos80° cos60° . 2sinZ0° 2x2sin 20° *pxbxz sin 20° 0 cos60® _ sin(180°-20°) sin20° 1 ~“gsinz0® ~~ gsin20° ~ iesin209 ~ 16 ~ RLS (Showed) £(8) = tand re 4n6 = rae crete cH, £(8)E(2O)F (38) +++» fE(2n — 1)8} = Solve: £(0)f(26)£(36) ---~ f{(2n — 1)8) = tand tanz0 tan30----~tan(2n— 18 se, rm = An — 1, CET eT | AE = ox em ROH) mat = tan(n8) = tant =1[+ 4n8 =n) tan8, tan(2n — 1)9 = tan8, tan(2n8 — 8) = tan8.tan (5 — 8) [+ 4n9 = x] = tan@. cot = 1 sta, tan28.tan(2n — 2)8 = tan20 tan(2n8 — 20) = tan2e, tan wee misery Bw TAS ot BRIA OT = 1 +£(0)f(20)f(30) ~-f {(2n — 1)8) = 1(Showed) = 20) = tan 2..cot26 = 1 2 Som apie as aster Come 35 Sere ST AGT POM.‘Raa ara eREPA-202R eee AGMA FF-Ow 05. at +b*+ct = 2c2(a? + b?) roms @, C= 45° wat, 135° 1 Solve: rom wie, at + bt +ct = 2c? (a? +b?) > at + bt +c* = 2c7a + 2c7b* = (a2)? + (b?)? + (2)? + 2a?b? + 2b2(—c?) + 2a?(—c?) = 2a?b? = (a2 +b? = c2)? = Zab? > a? + b*— c? = AVZab 3 SP C= 45° am, 135°(Showed) 06. tane = 2 Texcos@ xsing _, sin@ __xsing = Fxcos@ ~ cos — T-xcos@ eR tan = Solve: tan > sin@ (1 — xcos) = xsing cos @ > —xsin@ cos + sin@ = xsin«p cosO > sin@ = xsin cos 0 +xsin@ cos p= sin = xsin( + 6)... (i) ysin®__, sing __ysind F-ycos6 ~ cos T-yeos6 > sing —ysin@cos8 = ysin® cos@ = sing = ysin8.cos@ +ysingcos® > sing = ysin(8 +)... (i) sing @+@ss5= Fi [Proved] tang = Physi 07, ge een re cae are ar AT FAD PV INS ce ST | SHSTRSRT TE a (HTH IR) I ML | [mrors ere arte at) SS rs =F eeatuety P+A)V=RT SPV +S = RTS PV=—FtRT (athe, y = PVR X= TG, y = mx + c SAE Aateat see ATT ons, Sree oT et, m = —a wr m= 2220-15 sas 1S5atmL? mol? 08, coteat wren aTEH OITATAT 26°C ae PifPare 19,6°C | scans fer Fei a 1 20°C, 22°C ae 26°C wrerararn FPS TAT mers IY Ate 17.54, 19.83 xee 25.21 mm eH OT 22 — 20)°C = 2°C est ry HE BA ATCT CE HT 19.83 — 17.54)mmlg = 2.29 mmHg (20 — 19,6)°C = 0.4°C ~93 Bea Hemp we Ter IN TTT = BEC mmHg = 0.458 mmHg «. Pras 19.69C eromtare APES wa TIM Be, F = (17.54 — 0.458)mmHg = 17.082 mmHg ‘rate, 26°C wreratare Hye wal ae rt, F = 25.21 mmHg carat ef, seer se, R = £ x 100% = 22982 x 100% = 67.76% Taga erie as ctor Git 36 “ae aT AGA NTRae eS aTN-2028 geese 09, 10. Tt im, Sbar 43m’, Tbar | one A 400K 300K| —tree B Dra O,sra| AS B Sree art eb mR FRR Ie eee POOR AAT | Repeater Ae | ATT ON A ae TET FOR? Solve: Py = 5 x 105Pa,V, = 1m3,Ty = 400K Py = 105Pa, Va = 3m, Ty = 300K we SetoKd 10553 aooR ’"B = “so0R HOTT wre, Va = (1 +x); Vg = (3—x) ATTRA, Py = Pa, Ta = Ty aie ag wy 5 3 > jaoasa) ~ 5005 3 %x=113x=2 oVst+2e2 2.22 m3 3 15-Sx=444x doa gneearsper aver ore Eg SER FRET, ATCA Sehocorie R.M, S, Cat CRA Solve: m = 0,203 gm, V = 1000 em? ACSTP, P = 1.013 x 105Pa T=04273 = 273K Now, p = + Vas = PR = er m/s = 1223.54:m/s cf ras ter Tae erate TAT STO SP aT TCR | MR Tet Fg Ae aM scr RETR | ATA ATC SOTO RMS com UH ATCA SITAR AG CAT AT BH, IRCA BE ATM PATA TTA TS SLA BTS Pie a | Solve: On the left side, vams = ser On the right side, Vmean = a 985), (Vams)ueft = (Vmean right’ (T Fe] RT _ [amt MM; yaa = = 28 = 1.18 (Ans.) 2 8 eGo TA TT OT Tam Sense as Gehan Come 7BGfremfee af THAFA-2OVW_ Saale AEA FF-O8 12, Soar POA PRICE TET ETT 1.5 x 10! Bax age atamafes An = 2 x 10-%m ¢ errata 00°C ey, af CATS PE IY FSA WAT HH ALY TT Ca? Solve: n = 1.5 x 10!°/em$ = 1.5 x 10?5/m3 o = (2x 10x 2)m = 4x 10-°m oman wif, A= at Fut + A= Fame piasnton M = 9.38 x 107m, é Pmt faxostex00r27), rms = 32x10 776.21 ms“ 8.275 x 10" (Ans.) Chemistry. 13, cf urea rere Ni(NOs)2 Eat Ce 3.5 A wie erate wrt wea Cem BHT Ni MBH eC CHET RT| 1600 cm? CRITE sport Ba 9.5 x 10-3 mm sprcpE eters Te ee ANCE eTATERT A FAT eA (NE 9a *E 8.8 gcm~) Solve: stent FF = 9.5 x 10-$mm = 9.5 x 10-¢em 2. MOORS Ni TER BITE = (1600 x 9.5 x 10~*)em? = 1.52 cm? 2. Ni Miga eH = (1.52 x 88)g = 13.376 Ni** + 2e" > Ni Niae gore e = 2 ecmrerta at yom, W = Mo = ME 13.376K2K96500 . _ 17565,432 s = 3.49 hr MT 58735 14, Bub Al (51202) om 200 mi IM O10 Ane Bo ‘Bon, care Fate sear cere TMT CFATTAT ENC | 10 FRAG ote Cre co B tome Gee Cr+ rea MTA ACH 0.75 M RAM cerca Al 90 ge Fa a ee ater wat RO, AL ALOT SAFE RE B NN CL ACT A Solve: Al + Cr? 4 Al?+ + Cr 20g Al Reea wes Al oor crm aecot = 22 mol = 0.741 mol eefice erage Cr3+ aa cater meet = (200 x 10-$ x 1 mol) = 0.2 mol 10 ARE oa Cr+ a rer AUT = (200 x 1078 x 0.75)mol = 0.15 mol Teme oes at Rett Cr aH “fA = (0.2 — 0.15)mol = 0.05 mol ‘84s, 0.05 mol afta Al erg wifes eer Al? fe EE + Al pron en = (0.741 — 0.05) x 27 = 18.668 CIO er Fairs et rR | IR MERTTAT GRATES TT | + Boe CI> ermae wrarat (1x 3) = 3M Som agetie as action cra 38 ‘ofeeetae STA RYT OT,RaSeafte ara oREFA-2022 Seo MGMT T-08 15, Fw wiser Ca wARRTATE 0.02M CASO, Has FATA ACAI | wd wa ete Pe asHCATTE Hy OTH RAR wat RO AT Ht TCA FATT O.2M aes mae wat Hy TIO wT FO TLERyycger = OAV, Ecen) = 0.41982] Solve: sortatce =eafbe frm: Cd + Ca?* + 2e7 ees see fAfisat: ZH* + 2e~ > Ha(g) C+ 24+ Ca? + H(g) = po, — 2808RT fea" ) log noe = 0.67 = Py, = P02? atm = 0.42759 atm ~ 0.43 atm 16, RTE errs core aeeNE wea Betta re SAT ATCA? GEE 20 min aTeART AH are eer ete aCe PT eA | Cr/Cr* (0.3M)||Cu?* (0.15M)/Cu [Egat = 0.74V RES, qyor = —0.34V] Solve: aman size: 2Cr > 2Cr* + Ge ayrune fret: 3Cu*t + 6e~ > 3Cu ‘want core faieut: 2Cr + 3Cu** > 2Cr3* + 3Cu - 2303RT) fere*P 303x8314%x200) (0:3) 6. Bega = Egy — 22ST t= 0.74 + 0.34 — BORSA jog OOK = 1.0660 eh a = ota yw APSA = —AG? = NFE cen = (6 x 96500 x 1.066)] = 617214] cred ene eye = S72 = 514.3450 17. 20g wera sols crrera Drees Som Ag Mien eae TATA SRT ace AgNO, a wey Bec 2 WOT-waR S A efyR cate BTA aT RAT | ees BARTER HITT 28.86% WM, 2 FO oT OA SE eS RA? Solve: gars states wigren afta = It = 5 x 2 x 3600C = 36000 C 2 ates wfg = SSPRRAZONE ¢ = 10389,66 Agt +e" =p Ag 2 LF, 96500C Faas BT HER TITANS aT ZT 108 g Ag, 5 10389.6C PRS eae BAT ATH ATICE BT BA, We ae 11.63g 2 arene Drapiba we BA = (20 + 11.63)g = 31.635, 18, 38 Rear cafe co Fico Frmermte re eT | CyzHz20q1 + > C6Hy205 + @ G2H20n +[ ‘sH1205 co (ii) Ce Hi2 6 et 1 + 2p Gi) + 02 ——> CH, COOH +| invertase Solve: (i) C1zH2031 + HzO > CoHs2¢ + CoHy205 aymase aceto hactor (i) Coty205 > 2CH,CHOH + 2.COp (lil) CHyCH,OH +0," cH,cooH + Ha0 Tair aaieaae ae aT Te 9 RATATAT NTeats aca S TrfeFA-2022 Sea AAPA ov wed Math Ol, srarta, sin? A — sin? B + sin? C = 2sinAcosB sin€ fw, A+ B+ C= nl Solve: L. H.S.= sin? A — sin? B + sin? C (1 —cos2A) + 3a — cos2C) — sin? B 1 a - — }¢082A — 3 cos2C ~ sin? B= 1 — sin? B ~2 (cos2A + cos2C) 1 = cos” B 5 {2cos(A + C) cos(A — C)} = cos” B ~ cos(n — B) cos(A —C) = cos? B + cosB cos(A—C) = cos B[cosB + cos(A ~ C)] = cosB [cos{m — (A + C)} + cos (A—C)] = cosB [cos(A - C) — cos(A+€)] = cosB(2sinA sin) = 2sinA cosB sinC = R.H.S (Proved) 02. tang =e ar orts cr, tan(a — B) + (n—1)tana=0. asinacore Solves tan B= ee tan = ae > tan = Seema > M8 Gaetan ate ana-tanp _ 8M GseaGSa) _ tanattan? a a, tan(a— B) = Se = ee Sena aetanteCi-mentan a tanattan?e-ntan? a-ntang _ tana(iHtan?a~ntan? a~n) = tan(a B) = “pant ocntan?aentanta Tanta = tanaltvtant acn(1itan?o)} _ tanati-m(14tan") tan(q— g) = tana —n) = —(n— 1)tana Tran? Tatan?a + tan(a—B) + (n— 1) tana = 0 [Showed] 03. sinx + siny = a 4% cosx + cosy = b &, sos ea cH, sin e& Solve: cent SIR, sinx + siny = (sinx + siny)? = a? @ > sin? x + sin?y + 2sinxsiny = 2, cosx + cosy = b = cos? x + cos? y + 2cosx cosy = b? G+ Gi) we one, (sin? x + cos? x) + (sin y + cosy) + 2 (cosx cosy + sinxsiny) 1414 2cos(x—y) = a? + b? > 2(1 + cos(x -¥)) =a? +b? 4 9 2.2c0s? C52) = a? +b? [v1 + cosA= 2c0s?4] a eee] 3 4{1—sint S2)} 2 at +b? 4 — asin? =a +b? z = 4sin? ( sin? (© 4-2 —b? = sin(&2) = +ivi—a=BF (Proved) Sager eee ae oT CRT 0 Aeaeins eer PageRSs era erfA-R032 Stee AEA Fe-o8 nanan? 04. sinZ-sin®® sin" sin2 ea am Petra sind sin3sin sin x 1 Smo 7m 16 os(eri)} ©) = 4 (cos —0) (costo) afees 5-3) ~ 25 (G5 +3) (e085 -Z) - 2 30 ( T £055) (cos 5 — cos OS. ft off fingcern EAR x? + x-+ 1, 2x + 1x? Solve: ff, [RET Cat = A = xtDF+O8 1)" (9244)? 2 COSA = SS leweeg, x? 4x41 FER) at rantida aoe ont nt anata an? aan 2GxHGE) 2G) Berne a) + cos A = cos 120° «- A = 120° (Ans.] =1(28 4224-1) tan Serene, cos = ae 28 etant® Astan?Z _ 1-e-tan#f-eran? x a= 2 > cosy = Tetan$ ~ tmestantStetante > cos = "2 | = cosy = °° [Showed] aunt recon “rant Physies 07. ee ora oe care TC a Few PY aeTe © cree tet et | STMTSTTORTAR ee a (CTL TA) aT TH AE (omore sree ser] £216] 3 201 z Tete 23 Sy (mol lit! Solve: P+S)V=RT= Pvt? RT PV=—24RT- () eR, y = PV an x = 2 a, y= mx + c BRC aes mem are cranes, eres oe, m = —a 216-204 aoe +a = 15atm L? mol? oR, m = Taga aaetie ae aero Come 4 Ser GT‘Raaae seed FriA-2022 Seale AEP FOS 08, cera aft fire © om ary Efe TER Om ATCA MT 30°C wae Pre aT Ie 28°C | STE fer Pf eH 30°C ~4 RATA Bee 1.65 HR 26°C, 28°C eee 30°C wrt Hye ATM et TAT 25.25 x 10-3, 28.45 x 10~3m ae 30 x 107m *t BI Solve: «21, t, = 30°C, tz = 28°C, G = 1.65 ‘wat ify, ty = t+ G(ty — ta) > t= ty — G(t ty) = 30 — 1.65(30 - 28) = 26.7°C oe, Para AH IMDM, F = 26.37 x LOM oem Bit ‘ _ 267° COANE PTET SRR ER = a * 100% 1oa7 10 2932200" «100% = x 100% = 09, fins Shar E39, Iban ame a | 400K Ef 300K | once Dyson | AG B Drea area ered wer Ras te atts Peo rence Faget oe Pree Tee eR | TTA Bree B ae SITET wom? Solve: Py = 5 X 105Pa,V, = 1m?,T, = 400K Pp = 105Pa, Vp = 3m*, Ts = 300K “pata | _ 10h “Da = “aor "8 = Goon TAT STE, Vi = (14+); Vp = 3-9) SIRT, Py = Poy Ta = Ta wit, 08 Va 3 5 > go0(as) ~ 3006-8) 3 ox =11Sx= 3 15-5x=4+4x ovp=3-2 1.78 m? 9 ° 10. 0.421 gm wera mas apr aie 10°Pa Bi 6 273 K wierriae 1000 cm? Sem HUT HL, OTR TT Selec hee TST Ca ‘Prefer | Solve: m = 0.421 gm, V = 1000 cm? 05Pa AtSTP,P T= 273K = PVenkT= 2-2 oM= oznxa3145075 _ M= 105xI000x10-6 255) a vapy = & PABA m/s = 689.445 m/s 1 ee ay ony eer ora ta tee ear zen 1 ST FSF wr ra ERA TN TCA RMS cam re cos TAT A TA, RH ee FATT ATT Ew ge FT| fi Solve: ara, vans = [Se SRM, Yury = [Ae GR _ fiat (Wamsduet = ourv)nigme > f= ft Fe eet as eh CART mT Pv falta ‘eto OTC ASE stomRae eS areRA-2032 ‘Stele AGMA F-0y 12, ef m3 a Rage Ea FUT 2.5 x 1029 Bem ae THE = 3.x 10-8m Ty, ER wa aS CMATT 2.4 x 10° Fee a aT CCT TER Toren fe aa . = 1 * 4 Solve: Steet eI, A= = am = 25 x 107% (Ans.) Crms = (2.5 x 1076 x 2.4 x 10®)ms~} = 600 ms~> - Preset Come = Fr = 600 = RESIST 1" 29,867 K (Ans.) Chemistry 13, #6 300 cm? corer FAB Tee otcwR Bore ame MTA eet TUT BT 4 WET 52 FRAAD ATER 1.25 A OTR aT BAT SA RT | Sa MTOR BoE Betis AES ACTIN FH HT Re PH AER WAY 8.96 g/cm) Solver aes sm arg or, W = SE t= (4x 3600 + 52 x 60)s = 17520s firs eer EH GOAT, = 2 3.51. 25%17520 296500 nas 72054 3 = 3 soe cm? = 0.8042 cm’ . “volume _ 0.8042, 5 2. ron ep = ORE = Soom = 2,68 x 10-9 cm 14, ub Za (0132.78) cum 200 al 1M CuSO, et ate Ae bran, cre Fafa eR eretice TR Creat Rea | 10 FRAG ote nT CT B etme wart Cu? rece Vana FH O.75 M RHR Ora Zn 79 OM PACH a oH ATM A, Zn HRT SH HE RR? B EH SOF TET wea cae | [Zn a TARE SH 5.4] 2 Solve: Zn + Cu?* —— Cu + Zn?* =0.5 mol 32,69g Zn AUER HORT Zn a OTT ARNT = orate rear Cu2* em GaP ART = (200 x 1073 x 1 mol) = 10 SIE ore Cu?* 9a cam RATT = (200 x 1078 x 0.75)mol = 0.15 mol quae SITS BAT BEM Cu SH -aftart = (0.2 — 0.15)mol = 0.05 mol ‘gare 0.05 mol Aart Zn ig aie Re Zn?* «@ few eT fs Zn Wer oF = (0.5 — 0.05) X 65.4g = 29.43 SO3> err fafa rer HAA | re STAN etaaAET eter | 2B sma SO}™ Secs SrraTaT 1M | ).2 mol Fae aeiceie we ae CoN aB faeteae Ser PRT TM. |SaAufie aS arrA-2082 Ste ERR FF-Ob 15, SR CMTE Ge fererae tere 0.06 M ZnSO, acre wees care AGRA THA FAT LAT | BATA ZnSO, 95% Recaere ee fee efgaaenn of Freren 4 #8 87 [E8229 = —0.76V] Solve: Fatt ZnSO, at 95% facafere ex | = was fs [Zn2*] = “o .057M 303RT, F 2 Ezn/an?* = Egypt — log{Zn?*] ‘eter, Zn —— Zn?* + 2e- 2 = 0.76 — 2308x8.814x298 _ » Egpyantt = 0.76 — EOPESH28 5 109(0.057) V = 0.797V 16, 25°C wetmtara Pt, Sn2*(0.2M) /Sn** (0.02M)||Fe** (0.3M)/Fe cere ere ems em TOR ATA HE 2+ syst = 0.15 Volt #%t Ef,s+ pe = 0.036 Volt] Solve: smtats: 38n?* ~ 6e” > 3Sn¢* “sae: 2Fe?* + 6e” —>2Fe syaat cere Faint: 3Sn2+ + 2Fe3+ = 3sntt + 2Fe bE = Boy — 230381}, —_[Sattl? ++ Bea = Bean oP Oe ES = Ee o |, 2803RT, Isnt)? = Bgnaesntt + Epes* pe ne 8 ere ate ce _2303x0.316x290 (0.02) _, = 0.15 + 0.036 — Log Gamage = 00947 2 AG = —nFEgqi1 = 6 X 96500 x (—0.0947)] = 548313] ee, seas Rs Mm ae Ta es TR FRET TORE TH | ERR AE CHT CFT TAT TEL ANT ACA AT | 17. 300 mLO.5 M NaCl aera wa fer 2.54 fags 4 FaFAD Hem era eS FAT eT | emTRS SERTET TST 90% WH SER RATT ‘sequTe pH eS? z = 2SxG4x60)x90 Solve: seofee wigs ni as often = BSAC = 540C cette fen ecm: 2NaCl + 2H,0—~> 2Na* + 20H" + Cl, +H, ‘aftente ewere NaCl an oar >ReTT = =S2- mol = 5.596 x 10° mol Seeqy OH~ stat ear 5.596 x 1073 mol |» 2 mol NaCl = 2 mol H,0 = {oH-) M = 0.0187M pOH = —log{OH~] = — log(0.0187) = 1.73 = pH = 14-173 = 12.27 18, 556 Rete tate csr Foe Fatemrerea TRTROEAT EA OCH me CoH206 +] Gi) CoH 06 St +2 Gil) +0, ——> CH, COOH +, Invertase Solve: (i) CyzH22041 + H, 120 reg? CoH206 + CeHi205 mol Nat = 2 mol OH“ Gil) CeH126 = 2CHsCHOH + 2.CO, (iii) CHaCH,OH + 0, <2 *""5 cH,cooH + H20 Fg aes as acter come rySBR aad oRFA-ROR o1 02. 03. "V2sinA = sinB —sin®B Re TEA P-08 Math etait 4, cos* 2A + cos? 2B + cos* 2C = 1+ 2 cos2A cos2B cos2C| [awt, A+ B+ C= 1) Solve: L. H.S = cos*2A + cos? 2B + cos? 2C 1 1 zt + costa) + 5 (1 + cos4B) + cos? 2C = 145 (costa +cos4B) + cos? 2 = 145 {2c0s2(A + B) cos2(A— B)} + cos? 2¢ = 1+ cos2(m — C)cos2 (A — B) + cos? 2C + cos(2m — 2C) cos2 (A — B) + cos? 2C = 1 + cos2C cos2(A — B) + cos? 2C 1 + cos2C{cos2(A — B) + cos2C} = 1 + cos2C{cos2 (AB) + cos2(n — (A + B))} = 1 + cos2C{cos(2A — 2B) + cos(2A + 2B)} = 1 + cos2C {2 cos 2A cos2B} +2 cos2A cos2B cos2C = RH.S [Proved] V2 cos A = cosB + cos? B a ¥2 sinA = sin B — sin’ B 8, cos B a 3H Fite | i) Solve: V2 cos A = cosB + cos*B.. ai) @? + Gi)? ee, 2cos?A + 2sin? A = cos” B + cos*B + 2cos*B + sin*B + sin® B—2sin*B > 2 = (cos®B + sin? B) + 2(cos* B + sin’ B)(cos? B — sin” B) + cos®B + sin®B = 2=1+2x 1(cos*B- sin? B) + (cos*B)? + (sin? B)? = 1 = 2(cos?B — 1+ cos? B) + (cos? B + sin? B)? — 3 cos” B sin” B (cos? B + sin? B) = 1 = 2(2cos?B—1) 4 19 —3cos*Bsin?Bx1 = 0 = 4cos*B—2—3cos*Bsin?B = 0 = 4cos? B— 2 — 3 cos B(1 — cos” B) = 0 = 4cos?B—2—3cos*B + 3cos*B = 300s B + cos?B-—2 = 0+ cos*B=—1,2 + cos*B # —1 + cos*B => + cosB af [Ans.] gas =F, tan20°tan40° tan60° tan80° = 31 Solve: L. H.§ = tan20° tan40°tan60°tan80° = tan20° tan(60° ~ 20°) x v3 x tan(60° + 20°) ¥ yg tan60*-tan20? | taneo-stan20° 4 Samide eet = V3 tan20° x sFeaneptana0® * i-taneoranzoe = V3 tan20° x [TEST __3-tan? 20" = V5 tan20° Sor YB tan(3 x 20°) = V3 tan60° = V3 x V3 = 3 = R.H.S (Proved) oa ahr as acter come 45 eee ATER PA MTHaare aot wrieA-20R Stetina 04, 05. 06. 07, 0 = X mer cme o, cotd cot3@ cot S8---» cot 198 = —1 Solve: orem SI, Fo p= 108 L.H.S = cot® cot36 cotS0 cot7 8 cot 98 cot 11 8 cot130 cot1S8 cot179 cot190 = cot8cot3AcotSOcot7Acot96 cot(108 + 8) cot(108 + 36) cot(106 + 58) cot(108 + 78) cot(108 + 98) = cotdcot38cotS0cot70 cot 90 cot (= + 0) cot (+30) cot( + 58) cot (F +76) cott + 98) = cot cot 38cot58cot70 cot 96(—tan8)(—tan3@) (—tan5@)(—tan76)(—tan90) . = (-1)5 x (tan 8. cot@) x (tan 38. cot 39) x (tan 50. cot 58). (tan 70 . cot 70). (tan 96. cot98) =-1=RH.S (Showed) AABC 4 a=2,b = v3 + 1 aC = 60° am, fipaia wee aE Ss corseR fae | Solve: ABC & a = 2,b = V3 +1 ee C= 60° fire comma we a, c = a? +b? — ZabcosC = 22+ (V3+1) —2.2(v3 + 1)c0s60° = 6-c= V6 Fagonia ATS ome, = = Sina ~ sind ~ sin 2 Wn. 2 Bing. he nb Fin" sind — 2N2 sina A= 45° 3 24 = 23. B= 75° sinB AST = V6 ae Gore A = 45°¢ B = 75° [Ans.] tand + tan (+0) + tan@2 +0) ce tan30 sarsters eee ra Solve: exe ai = tand + tan ($+ 6) + tan (2+ 8) canfitane tant stand Gitano, -VBstand = tan + et oz iano OO + atone PTs tnd = tama + (VEetan) (14/3 tano)+(-V5+tand)(1—V5tan8) ~tol (i+v3tan 9)(i-V3tand) = tang 4. VitStant/tantostand—/F+stano+tand—VStan20 stand__tand-2tan® os e1and =n (en tandjr—Vstan0) an + tanto 13tanto = 3G3tan0-tan? 0) _ = CRESS = Stan3 6 [Ans.] Physies 27°C wrorayat © 5 atm wrest 1 mol ota Sra OPT sae rR MRT A SOTO SIT SATS TE Re [es TOA TTL RT TE Fete ra TER ATT SAT 0.2 Lmol*) Solve: 1 car apes ster B5, (P+ A)ue-») =RT = P(,—b) = RT [P> BaP + Rr ‘ Meo Seb Gi) ered smo orn, vj = BE... (ii) 02», y,sVy = 1.04121 (Ans.) Tpeaina05 % Fron aaa ga‘WiSnfRe eralS FrEFA-2022 Sere AGA FF-o 08. erat Neaa wtetatat 25°C wae encore cnet 60% 1% ATH ARIA STAT 10°C eae TCA AST 90% | AEE Ea oA BT SC OORT RAT wR A ATO HATTIE 2 [25°C TATA HS AN ACHE Bret 23.52 mmHg 4K 10°C era aps we aI BI 9.22 mmHg] Solve: «ar We, 25°C erste aye Be ATC DIT = x fee apie = 250 SR Sots TAT ea = FSC RE YS SAN STE 1, 60% = Fog UX = 23.52 x 60% 2 x= 14.11 ming sts, MATT, 10°C etorarary TYE Be SICA BI = 2 wrtPre west L0°C OTTER SAPS SAN TT ETT : T= [08 erm MTS SAT ATATT 7, 90% = 5% = y = 9.22 x 90% = 8.298 mmHg RY, x > y, Hoa BA TH eT Free a AT | 09, 6m stSrrer ay cabaret Sem UIC gg Seg eT RCT Mate RST COT ey | aA TATA mea Boca os eH, BER Bra TPT fete Ba | [Py = 105Pa, p,, = 1000 kg/m?; poy = 900 kg/m] Solve: R; = 5mm Phottom = Po + 2hpwe + Zhpong = 10% + (3 x 6 x 1000 x 9.8) + ($x 6x 900 x 9.8) = 156840 Pa (PV)bortom = (PV) surface = 156840 x £n(5 x 10-3)? = 105 x Sn? + Ry = 5.809 x 107m = 5.809 mm 10. 5.1. gm Scaa ste sr aT 105Pa ret © 273K Creare 002m? AER HAT HT, STC TET OCT SCAT FT | Solve: m = 5.1. gm P = 105Pa; V = 0.02m? ; T = 273K e maT _ $.1%8.314%273 = PV=nRT SoD M aot = coeenon = 5-788 font _ [exesiax278 ,.-1 — 999,98 ms~} ~ 1000ms~* am = Ynxszenxi0-3™ 11, cer arce soot ea wear Ata PICT 2 OF eH 296 WT A ace sia Soe eras ae rater FFT eT | = 2x 2x Me = 0.02 Me 5 44H, Rx = 2 Re Solve: (oa 2) ms-2 1 = (|x 11.2 x 10°) ms 1120 ms Ve Pe xExVe 7 ) 901, Vy = Cems = fee T= BE = 1609.36 K scaceretrene 1606.36 Kee ord color oT 300K wrote Fg Sime PT THER | OTA BEETLES THTST sat TP aCe TIE a G x 10-8 s 1 ait wrratt SOOK 12. srt feet ar ea wes STATE Tamia PP mewrs wOTet TH we TA? i I solve: = tas = wept hep Crms % VT (Hi) = 3.8729 x 10-8s Tai GHC aS aE OTT a7 oiedom eterer ag A.Sfefermee ara TrFT-2032 Se EEA Fo Chemistry 13, 90 30 em? emarerea oeH x FACE 0.197 mm TER een TER AM ET HAT 5 TT AT wh Te HT wat WT | BA are a Fae [Cu TE AAR 8, 96gem4] Solve: a14@s Cu «ge ©4 w = pV =p x (Ax 2d) = 8.96 x (30x 2x22) g = 10.592 aut = 83SxIx(5%3600) 85, W =e = 10.59 = Ss = 1.7884 (Ans.) 14. Bulb(s00) —— ee Zam cum 200m 0.10: 250m 05M aa Bow fica, ai core saath sae CRIT RET | S VT ARTA tt CuSO, aa KATA] wy 0.35 M RA | HONE aaa we tos fre onder ee 7S ST eA aca BAC Zn? ITAA TTT SS RA? Solve: 5 = 9H CuSO, Bars cater sear star ze = (250 x 10- x 0. — 250 x 108 x 0.35)mol = (0.125 — 0.0875)mol = 0.0375 mol 10375%2%96500 ‘3600x5 (0,402 x SO)V = 20.1 SWB om A moma matt Zn2+ trea ca RAT = (200 x 10-$ x 0.1 + 0.0375)mol = 0.0575 mol 2 Asta Zn? sacs oat et = POSE M = 0.2875M 15, ee eee AL/AIP*|[Ni* /Ni erate EMP ose C4 1.4247V \ ERs aise = L.66V Get Exar py ‘A= 0.402A cman AL 6 Ni? carmen MRA HOT A BI A Solve: surrars: 2Al > 2AI** + 6e~ = po _2303RT, fart]? 2 iF 0591) faite? Bea = Baay ~ 222¢8T jog ATL, = 1.4247 = (1.66 - 0.25) - SI fe cell — = log MT 4.49 = [als*]? = 107? x [NP] « [AP *F = 0.0324 [Ni2*] Ines 16. Zn/Zn?* (0,02M)||Ag* (0.15M)/Ag GIG, ES, zq2 = +0-76V, Ag/Ag* = —0.799V axe errarat = 298K 1 cera Te ufer oftads fora aa | 20 RAD Gaect ee HHS TFA Solve: cere fafermfé em: Zn + 2Ag* — Zn?* + 2Ag 0 RT [zn?*| 0 0 _2303RT) | [0.02] Been = Eoey — 22" log, fe = Boyan + Eagtyag~ “ae 8 ioaet # zavsxesi4x208 [002] _ 1 56 y 0.76 + 0,799 — 2a oo = 156 A —NFEcey) = —2 X 96500 x 1.56] = 301080) Pore = yorfonz = 301178.86] P 30117886 te + ee met = SE w = 250.98W = 251 W Tia anche as ace Come a ARSE SOT PRGA NIRakin aed wrira-202z Sere EPA Fos 17. AgNOs Batt 1.754 SARs > WOT Aca DIT aT co RATS STMT SranhS ee wT aH eee tw ASA CuSO, BT 6 TE H2SO, RSS once oer Fat eT, Sa ARS Cu MET oat a erat STATE te Hp MOT MET TS 7 Solve: aie wie, Q 1.75 x 3600C = 6300C [Ag > Ag* + e7] Cu sea coma Cu?* + 2e” => Cu 2x 96500C fags aatee Cu Ba et = 63.5 g + 6300C Rage erane Cu sare = SSRN, ‘ara, H2SO, Te *ifice wipe oT AE, 4H,0 > 4Ht + 40H7 HUNTS: 4H* + 407 > 2H, ‘urcate: 40H” ~ 4e7 + 21,0 + 0 = 2.07278 2H,0 5 2H, +0 4x 96500C eae H, WHET = 2 x 22.41 + 6300C saree Hy wat ea = 222246500, “496500 18. 3 Reena erator cron For fefermerra STEVIA | 3) GD CoH206 Se AL d+ L=073L @ CaM, +[ CoHi206 + =| Gi) +0, => CH,COOH + Cy2H220.1 + 1,0 = CaHs206 + CoHi206 Solve: aceta bactar (ii) Colts2 05 ane 2CHyCH,OH + 2 CO, (i) CHCHZOH + 0,"“""""° cH,cooH + H,0 Math OL, WRAFB+C= We, SHA, COSA + cosB + cosC = 144sinSsinZsin£) Solve: cos A + cosB + cosC = 2cos“=cos4® + cosc = 2cos($—$) -cos®24cosc [- A+B+C =n] = 2sin$- cos +1-2sin?S [+ cos2$ = 1-2sin?§] cf AWB gs = 2sin’ feos (*—®) — ein — 422) = 2sin£{cos“3*— sin} +1 = 2sin$ {cos ($—2) —sin[E—A)} +1 AB ‘A,B sett seckse a = 2sin£ {cos (F-f)~ cos (G+ F)} +4 = 2sin$- 2sing-sin?+1=14 asin’. sin’ sing 2 cosA+ cosB + cosC = 144sin2-sinz- sin$ [Proved] Ta cain ae aon TF a Tin aTGe erg erce-202 Ste AEA FOS 02. cosa + cosB = aamsina+ sinf = bam, crite ot, cos? (a—B) = 3 Va" +5" Solve: Grewt size, cosa + cosB =a => (cosa + cos)? = a [wf] > cos? a+ cos®B + 2cosacosB = a? (i) aq, sina+sinB=b = (sina +sinB)? =b? [> ea) = sin? a+ sin? B + 2sinasinB = b? -- (ii) @+@) wear, (cos* a + sin? a) + (cos? f + sin” B) + 2(cosacosf + sina sinB) P +b? = 2 [14082 (S)] = = 2.2 c0s? (52) = 2? +b? = cos? (59) 31414 2cos(a—B) = 2 4b G2 +b?) +c0s>(a—8) £3 Va? +B? [Showed] 28 oe cos 8% cog tt . a AAS eg are fata | 03. 16 cos“cos* cos‘® cos “AE wa ed an eat on Solve: 16 cos = cos = cos $= cos 6 cos cos 28 cos 48 - cos 70 [ft, = = 0] = 2p: 2 sin6 cos®) - cos 28 - cos 40+ cos78 = SS (2sin 28 cos 28) - cos 48 « cos 70 [- sin 2A = 2sin Acos A] = sig (@sin40 + cos 40) cos 70 = 2; sin80-cos70 = gig: [sin(80 + 70) + sin(80 — 70)] [+ 2sinA cos B = sin(A + B) + sin(A —B)] = yg (sin 150 + sin6) = (sin 2n + sind) [+ 150 = 2x] = yap (0 + sin€) =04+1=1(Ans.) 04. £(8) = cot 8 ee 4n 6 = 1 ee, em cx, (8) -£(20) £(30) f((2n— 1)8} = 11 Solve: £(8) -f(28) + £(38) {{(2n - 1)8} = cot - cot 20 - cot 30 ------ cot(2n — 198 SMI, PTT = Zn — 1, aT FATT AAT | no oF + ROME aT = f(n8) = cot(nd) = cot(4) = 1 [+ 4n6 =n] oer afta gem 6 cre res wer, cotA - cat(2n — 1)@ = cot8 - cot(2n6 — 6) = cot -cot(E—0) [+ an = =cot@-tan6=1 ‘a, ae FRE FRE one re eA, cot 28 - cat(2n — 2)8 = cot20 -cot(2n 8 ~ 28) = cot 26 cot (E = cot2@-tan20 = 1 [sti more oe ARTE AT OFT = 1 + £(8) - £(28) + £(38) f((2n — 1)6} = 1 [Proved.] Som conse as Gein ae 30 Hee LTH PRG SITGRR era arira-2022 Stole agra y-04 05. AABC 4 a = 2b a A = 3B &, fingers comet fifa a1 Solve: a= 2b => 2 = 2 2[-A=3B] = SNRs Sn'8 = 2 = sin B (3 — 4sin?B—2) = 0 > 3—4sin?B = 2[+ B #0,sinB #0] 1 = 4sin?B=1> sinB=+4 =} tec a, A = 3B we] gsc + sinB => [v sinB : sin B = 3 = sin 30° «. B= 30° + A= 3B=3x30°=90° FEAR, A = 90°, B = 30° sae C = 180° — (90° + 30°) = 60° (Ans. ) sint o+sin?y xsing _ysing_ a = S580 ee tangy = SM, SF iexcos@ P= Fye0s8 A +See) 06. tan xsing _, sind __xsing Texcosg cos6 i=xcos@ Solve: tan 0 = sin@ (1—xcos@) = xsin pcos > sin@ — xsinO cos = xsincos8 = sin = x (sin@ cos @ + cos sin) = sin @ = xsin( +p) ~~ @[+ sin(A + B) = sin Acos B+ cos Asin B] ysind__, sing __ysine_ Sieg ys, T-yeos8 ~ cos@ 1-ycos0 = sin — ysinpcos@ = ysin 8 cosp > sing = y (sin0 cos + cos@sinp) = sing = y- sin(@ +.) ~~ (ii) [+ sin(A + B) = sin cosB + cosAsinB] @? + Gy? wen, sin? 9+ sin? g = x?sin?(6 +) +y? sin’?@ +9) = sin2(@ +9): (x? +y") = sin?@ + sin? p 7 Orsin? @ ox ty = sin2(0+@) Proved] Physics 07, 37°C wera @ 1000 atin vie TAT ATT 1 mol TET APT A AM MIT TMTETA ATS eS Aa? [aa STC HTC sapere sts 0,3 Lmol™4] Solve: 1 crm ston scan we, (P+ ze) (Vj —b) = RT = P(V,—b) =RT [p> gorte=?l av,=Etb~ @feces SB TrAIA-2OVW Save EPA OW 08, corer ae Mra ETeTTTAT 22°C sae reir GST 60% 1 Air GR MCAT SATA ATA CT 12°C RH, eH ATULLE AN TO eM FS Be WANE RE 2 [12°C 6 22°C wrath are DI WIR 10.5 x 10-2 mae 19.8 x 10"? m Hg) Solve: 22°C wim ax 60% SIefiew wEfoHT AES Say AISI = 19.8 X 10-3 x 0.6 = 11.88 x 10% m Hg 12°C wren Ps SAT Tt = 10.5 x 10-3m Hg 2 Whe sc = 0.1162 = 11.62% [Ans] 09, Gm Barer a aA Re eT BT Ce A aR MERE BM ONE PB TPE TE oC TAY [Po = 105Pa, pw = 1000 kg/m?; poy = 900 kg/m] Solve: Phottom = Fo + 2h pwe + Zhpoug = 10° + (2x 6 x 1000 x 9.8) + (Fx 6 x 900 x 9.8) = 156840 Pa (PV)bottom = (PV) surface > 156840 x Snr? = 105 x $nR3 = RP = 1.5684 19 =R=1162r- * = 0.162 = 16.2% s Le2% ger 10. atom pis ee ater StatCR 5.1. gm ATER TAT AGO 1000 ms! we, EHR TT FH Solve: C= /887 = M = 282 = 5,78 x 10°%kg mol”? avs = Sx1077x8314%273 = 9.9198 m? (Ans.) LL, carrera afSede pat 6 rts were Ale STI Gat a TTA Root wee, & se aCe Sofa errr esto ‘Ora Fo RA? GMs Solve: Ry = 2Rei Mx 5g Rea y= fx 11.2 x 10? ms“? = 22.4 x 10%ms™? Me 2 97, Ve = Cems = 2 AIH CPATAT $63278 K et FRED KL aC ATRERTEM TR | 12. SOOK wrerarare rer spre epraLER NeFaET oe gD HCH ITE FAT 1.55 x 10-75 | bi eM al ROT aR wITATAT 300K at eer EPR oo aS ves RAST HT FS A? fin ~ anon V2naP OMe =) My = 8My Mi = 563278 K Solve: “Is rats if memes Tas ITE, t= ae 3 x ty = 155 x 10-7 x [22x 2 = 24x 1077 s (Ans.) 500 Tara aerate as aati coma SE “reer core abe eTWS ag srFA-2022 Sire ITA Fos 13. 14. 15. Chemistry 35°C wremTaR! 60 atm BI 4.75 mol Hy PT SO FAT Mc Corea erect CHE Cc TTC Farm TAC Beet AGS ATT sere MAF 50 FART ecm CuSO, gers wes Fee DT er A OTR TES Cu MEAT 0.5 cm PAE RAE wowTAT ae BC seepferea 0.01em oF axe eet cream mee Ra? [Cu ea WAY = 8.96 g/cm] Solve: ffieurr cas ratio viene = (4.75 x 2)F = 9.5 F 9 9.SF re fren eores Cu amg aftant = 5 x 9,5 g = 301.625 g Ha(g) Ni+ 2Ht+>Ni?* + Ho(g) 303RT, [Ni?*]xPx, Bean = Beas — alos et . za0ant [Ni TPHs = Ecol = Ei + Ents TF To (Ht? [we*lens — 9.25 - 0.278 > tog A = -0.947 =e hog: we = 207887003) stm = 0.3389 atm * 0.34atm => Pu, = 7a 33 inet ear RT NT. Fray aaa as aS aTae era aTEEA-2ORR Stef TEMA gT-o 16. 25°C etemrare, Zn/Zn?* (M,)||Cu2*(M,)/Cu ces core fafteat asf @1 My = 0.04M, Mz = 0.001M 4% My = 0.002M,M, OSM at ey er fi fe es cen LOR BTR, Ezy = —0.76 V SR EL + jy = +0.34V1 Solve: Econ = Ezayant* + E°cut+/cu = (0.76 + 0.34) V = 11V _Batseas 0 “pxses00 "0015 ~ aauax29e) 004 ‘2x96s00 "001 = hOsa6v, AG, — AG, = -2 x 96500(1.0526 — 1.126) = 14166.2] 2 ae Misa sifted ey 14166.2 J (Ans), 17, 400 mL 0.5 M NaCl eats 35 fen 2.54 Page 5S FAD ees ere aT er teres ee RET 85% Ke wf CELE ‘Seq gees pH ase? Solve: sate wigres frat 9, Ey = 11 1.126V Ry=1i- ar aeube faftem' et: ZNaCl + 2H,0—+ 2Nat* + 20H™ + Cl, + Hy ‘feara semeteta NaCl as cur axe = 225 mol = 6.61 x 10% mol +, Beeiq OH rar fat 6.61 x 107? mol eTOH =] xx SSBC ay 8 [OH-] = SS" M = 0.0165 M + pOH = — log{OH™] = —log(0.0165) = 1.78 + pH = 14-178 = 12.22 18, 9B Ferri afer coca rows Fafermreca MATEROCAT AT A | © CoH + J Cotlaz06 + J oo aw CoHi206 ae L + (iii) +02 — CH,COOH +| invertase Solve: (i) CyaHz2013 + HzO? CeHs20 + Colls20e (iH) CoH120¢ = 2CHCH,OH + 2 C02 aceto bactor it) CHjCH,OH + 0, "5 cH,cooH + H20 ga Gee ae acim ae 4 oAaASa TH AGE NTT,