‘GRR ayS webFA-2032 Sealer aA F-08 01. cot(sin~* Vx + sec’ = y@o (b) 00 o% ave Solve: i pt =cott= Wve: cot(sin“* VX + cos“* VX) = cot = 0 aie rt invint ¥@) tant? (b) tan’ 04, sin cos~* tan sec~ vo o= Solve: A eae Lee 5 fy sincos~* tan tan~? es incos 1 EE = sin sin = 7 7 7 05, y = 2tan“!x ume y = 2 cot”? x aamaerares cenit cara? (4) vo(43) oO Solve: y = 2tan~* x = 2cot™?x = tan™*x = cot”? x = tan™ Eox=tan® =2tantx=2 => tan’ Fox=tand=1ery=2tan?x=5 06. y = cot"? x sae cera? &) Fa eT aS STI ComSee agra -08 Y(@Qx=4y @x-y=0 (costssing) — [(cost-sins)® (cost+sins)' + [(cos3—sin’3)" 08. sin? 20 ~ 3 cos? 0 = 0, (cos 0 + 0) teres area aR CHR? @2nn t= ¥(b) 2nn +5 (nn-* @antt Solve: 4sin? @ - cos? 8 —3.cos? = 0 cos? @ (4 sin? @ — 3) cos 8 #0 icp at sing = +8 ‘eat, cos@ = tVI— sin? 0 = + /1 cos = +> cos 8 = 33,0 = 2nn += cos = —2 en, 0 = 2nnt 09, tan? 0+ 2sec? 6 = 5 alten 0° < @ < 360° arafire mare ab? @it 28 (38 yY@ae Solve: tan? @ + 2 + 2tan?@ = 5 = tan?0 + 2tan?9—3=0 = 3tan?@=3 3 tand= +15 0=nntt man Sx Te p Pp P 10. [Lp pe) Retreta ara? 1p? pt (@pa—pr@?-1)— )p*t—P*)H?- 1) YOPFA-pFO*-1) PA -p? +1) Ip PP it. a 0 0 aes sowve:{1 p p|=p]i p P')=pa-p)*| 1 Bai | [tees 1p? pt 1p? pt +p pe+p) pi] C2 =C2— Gs = p(1—p)? [1+ p)p?—p (1 +p) = P*A—P)? @—D) 11, A= [08 ~SIN®) eae g = Se, A [ine cosa] “2 = 3 2 ve 2 piel © a volt ol of 3 @ Fam caret ae ace aT 20 Aaa STN PaSiGe ay areT-2038 Stef ng y-04 sélve [2 nd —sinnd) sinn® — cosné 3. [cos30 —sin3@ sin3@ cos38 or( ol 1 3° 5 | 13 15 Stace are? 2020 2022 2024! (@) 2021 (b) 2022 (©) 2023 Yd) RRR AH 1 3 8 1 23 LLL. [5 18 17 |=| 13 2 2|=0.[% ara 2020 2022 2024! 2020 2 2 ie) = C2 — Cy. 1B. = 1am, B=? 1 2 ape 3 of? ol =] ¥(@) Both b and ¢ 4. @+2 @3 Solve: kVEE.K2 — 16 = 0 > k* = 16 2k = 42 fe, kd = V8 sores 15, 3.x 3 sreten coma aia A corwofe Somes oe 3V3 wm, |(V31—A)"| ea esr 2 (@)3v3 (b) 24v3 veo @) 12v3 3 7 Fi solve: |(V31 - A)"| = safe 1 |- =0 0 0 i 3 a fa » 16. afr genom = hx = wee, |Al craw? x w Pl v(ayo (0) @? +b? -c? +a—p)e (©) g(ew— 68) + (ag — bp)c @) coe a aa Solve: cy = cy oP exrcra mH ae Ror [Al = ja 4 3 17. [2 4 9/=0mm,aspeaxaae 2 6 7 @a=1,B=3 V(b)a=2,B=4 (a=4,p=2 @a=0,8=0 Solve: a = 2, = 4M, Cy = 2X Cy Wa) Oe fares mT EA Fegan Sree ao co 2 iaatear eT PT ROT.SRA aS ortTA-2032 Stee aaa qe-04 abo 18. fa? b? 2) =7 la? bs? (a) abe(a — b)(c — b)(c— a) (b) (a — b)(b - c)(a—c)abe (©) abe (a — b)(b — c)(e-a) ¥(@) both b&c 1 bot 0 0 4 saber bc seas bec la? b? ci le®—b? pec? 2 0 0 * =abe(a—b)(b-c)| 1 £ ch ath bte cA =abe(a-bo-9|, 4, 4 steer = abe(a— b)(b —c)(b +c —a—b) = abe(a— b)(b— (ea) 19. cater roth sores few vient corm etomtee BIH 29,099 Jmol “eee wep [ort = 1 atm] @ 1051. (2391, (©) 3.1591 (8) 6.203L Solve: PV = nRT => PdV + VaP = nRaT. «Pd ip = 0] + dV = BRST _ SSNS _ 53.159 x 10-2m? = 3.1591, 101325, CpdT; du = nCydT Alternative: dQ dW = pdv dW = dQ—du = n(C, —C,)aT = nRaT « pdv = nRdT = dv = 3.159 L 20. cena care ar we CRE SITE, ARETEG CHCA UE IR CERAM ATE 30° cal GIT ATA (@oK ¥(b)270.5K (0) 2755K @6055K Solve: C + 30° = F Ee 4 £= 5 5 9¢ = sc- 109 c= -25° K=273+C=2705K 21. 100°C wrrman aiee ws See cece CRT at 10% arAtgS ee ATA? (@) 12.17 km (b) 7.302 km ¥ (6) 23.14 km (@) 3.428 km Solve: mgh = m'ly => 10 gh = ly => h = SEO? sh = 23142857 m 22, cre fica Beara raat 9BO.6°F a FET 40% TE, TR ITA? (@) 588,36°F (b) 392.24°F (c) 204.6°F ¥(d) 404.6°F Solve: (225% x 5) +273 = 800K #1 = 480K = (8223 x 9) +32 = 404.6°F 23, cron create a are FET oe ATR 6 1 fe Da MRETOH AfHS eI 350) Rem, aE Bom FARES wie. (@) 58.33) ¥(b) 50) (© 60} (@ 79 =62 + Q =6W Qo = 350] > Q, + W = 350] > 7W = 350) « W= 50] Fa eT as SFR TE 2 fats ere PRE TT. Solve:Sate aS areterA-2023 See ga yR04 24, CHT eR Te TAR ASE 2 x LOS]KQ? 1 ae 3 keg ae etre rete 122°F ae wis eRe at STARE 12°F Be, SR SHE RATE TA 21 2°F Fc etafna ATST 406.476 JK~* | eae RT TER (a) 2500 JKg“2K-* ¥(b) 5000 JKg-K (c) 3500 JKg-?K? (@) 7000 Jkg~*K™* Solve: 122°F = 323K ; 212°F 73K 28S = 22204 3 x Sx in 4016476 = 22008 asin 22 «5 ~ 5000 JKg*K 25, 3m? eran ren ee cate ate mas RETA SEMA ATT TOR 7? a ROA A ACTS ST MMT ‘ee ea xm? a eee armel AIT a AP Om? A [ee eTAA = A TTA] x =? (@) 27m? (b) 3m? ¥(c) 21m? (@) 7m* adiabatic | isothermal 4 adiabatic 23m? Solve: 3m 7m a ope E=6)™ sez, @)=@" 2ox=21m! 26, Sg era ead Ad 250 ms? ceo RAR MCE UTE eH a CHER CHT AT | 30% MAS wert weTChTS REM, TEP STATA HS fe ae [steers Set = 120 JKgK-}] (@) 68.125 K ¥(b) 78.125 K (0) 88.125 K (@) 98.125 K solve: (!mv2) x 0:3 = msa = a0 = 770" — 70,125 k 27. cme erent Bere ret Beer 3,5 atm BIE 2.5 CaM OTT SCE TA STE 1SL ae Ste KS S atm Be, 17L WAAR S CTT spree [rer ec eo tae Ree oT FY (a) 35.21% (b) 11.03% ¥(c) 19.05% (@ 80.95% Solve: T; 2 PaV> _ $17 _ 17 Rn; RMS OR he an= (1-2) x 100% = 19.0476% 28, eer aoa GACT stone wr RET el KE, GRATE MOTE eR? [y = 1.67] (a) 55.38% (b) 44.62% ¥(c) 35.65% (d) 64.35% Solve: P, = = TRY =TP,” [y= 167] Ge = (3)"167 = 0.6435 % + (1-P) x 100% = 35.65% 29, caret weed Drancan Foor ar DIN 3 atm ora BoA GOOF | UN Sea wl OME cer wierat we we? [y = 1.4] (a) 249.134K (b) 49.68°F ¥(©214.07K (d) 223.06K Solve: y = 14,1, = 68°F = 20°C = 293K heh ® Y = 293,(3) 30. eb Pres eet atm fe rer ISL omPT en stem Fone at RO | CR FORTS. (a) 1013.25) (b) 3039.75 J (©) 1519.875 J (@ 4559625) Solve: 2701% etre, 2. W= PAV = 101325 x (15 x2 x 10-8) = 3039.75 | Fae aera aot TE 23 Hato sore GANT 214.0658K‘afta ays FrFA-2022 Stele ara yP-09 31. 32. 33. 34, 35. 36. 37. 38. CO, TCR wert re @ RTD OTN Diem PMS Fa? @ we voz @ slope of adiabatie curv Solve: Zope ofadiabatic curve _ '* Slope ofisothermal curve ~ Y CO. Pr tafe mag ReRTH FonaRRTATee TCIM BERRI y BAY =14 rare eft 1 atm Dre LOL sme oi fee et et 1 fen cai wren ofA a? (a) $702.33] (b) +803.21J ¥ (0) 702.33} (@ -803.21) Solve: ware effars, dQ = dW = ARTIns# >, In e) = -702.33] sre et feast com cr et (@) AS = ncn ¥(b) AS = ynCy In (AS= nein @o Solve: AS = nCp ne = ynty Ine: c has v ca eee ay fie fra TER @BoA Y@)B>C (C+A (@) crt ae Solve: B > C weet fige tment ore af sre coy P ox T ert wretmtats Be oA) MU esa = AUcsp + Up. <0 Chemistry Cay an eet RRA ATR Fe? AHIR, SOT TT See ¥(@) 0.74 (bose (0.36 © 026 Solve: CaCz + 2H,0—> CH=CH. + Ca(OH)z: ‘Main product = tele | ee {otal product ~ 100 cars C8 Boy Ferma TENT Kp = Ke TAY ¥(a)n=0 (yan >0 (an Kes Patra stroneher ets RF ATER TS FATT 100°C crsrmrarn sia raf ete 7.5 x 107 | 2 ovata Rane wre at pHa (a)7 ~(b) 6.56 (7.44 @s Solve: [H*] = (Kw = V75 x 10-* + pH = —log[H*] = - log v7.5 x 10 = 6.56 Say GREAT oS GER CRITE 24 ARETE SET PRA NT.ae aa orEA-2022 Reefer MAPA Te-04 39, 2HI(g) = Ha(g) + Ia(g) ferme ommree K 12H2(e) + Fle(e) = HI(g) fran amare Kye, Foe CoB ae? @R= Ok =2 YOK=% R= Fe Solve: 2HI(g) + H2(g) + ln(¢) Ka Halted cy Ha (@) + Fla(@) = HI) wu yz tert lal 40, Rea cnt aera rt? (a) 0.5M 50mL CHjCOOK +0.5M 60mL NaOH —(b) 0.2M 100ml HCI + 0.1M 200ml, NaOH (©) 0.2M 25mL CH;COOH +0.25M 200mL NaOH (4) 0.5M 30mL, CHyCOOH + 0.3M 10 mL NaOH Solve: TH B44 RORT BT Spcid X Vactd > Space * Vaase AL, 25°C erMraTare N20,(g) & 2NO2(g) fatten arrrTE 25% NzOq Renfree ae ca vie 3 atm | Ke FAS FE? (@) 0.8 atm (6) 3.23 x 10-4 moll (@) 0.87 atm ¥(d) 0.033 molL* sate _ 402553 _ 9g atm 1028 K 2 4 Kp = Ke(RT)? > Ke = BE = saeteiag = 0.033 moll? 42. 0.1M SO mL CH,COOH «0.05 M 100 mL CH,COONasata feet afefie 2 mL 0.2M HCE cma ey, fleets pH #w 2a? [Ka = 1.8 x 10-5] 1 Solve: Kp = (a) 4.745 ¥(b) 4.675 ()4.783, @5 Solve: pH = pKa + log acon Us = —log(1.0 x 10°*) + log *Sentto_ 22 = 4.675 43, 25°C errmrary, 0.1M HCOOH S#t % 0.1M CHsCOOH fetes fiers H* srcra weet #22 [Kacucoow = 1.8% 10%, Kaccrycoorp = 1.8 x 10°*} (a) 2.37 x 10-* (b) 2.87 x 10° ¥() 5.58 x 10-3 (@) 885 x 1073 Solve: pH = —log(VO.1™ 18% 10" + VOIX 18x 10) = 2.253 [H*] = 10-P# = 5.58 x 10° 44, 298K wrnnane LL error aa oom A(g) + B(g) = C(g) + D(g) Fetters simaeae 100 1 fefarare siftce afi Fetter ae See TAT AM, SRT ATTA D EAT FS? (@o0.182M V(b) 1818M (@0si8M @im Rg oD Solve: Initially(mol): 1 1 a 1 AtEquilibrium(mol): 1-x 1-x 0 1+x 1 +x Ke = 22% = 100 1 +x = 10(1 -¥) x= 0818 arapagn D we often = (1 + 0.818)mol = 1.818 mol -. [D] = 1.818 M 45, 25°C eremtara 10-® M win H, SO, a SATA pOH Fe eA? (8 (6) 7.69 (©)692 Y(d) 7.08 Solve: pH = —log(2 x 10~® + 1077) = 6.92 pOH = 14—6.92 = 7.08 Ta carstiw ae aster Grae 3 fates Soren a OT.‘BEST aS arFA-Q0R2 See gra ye-04 46. 41. 48. 49, 50, ol. 02. 03, BRP ian ata POH TAU 3 ox 6 | RET ERO PT eT ae Toor GEA? (a) 10.04 (b) 103 oF ¥ (0) 107? ot (d) 10? wt Solve: pOH, = 3; pOH, = 6 PH; = 11; pH, + [H*), = 107M [H+], = 10-°M suet argaet gra sh = 2 or = 10-9 oF | 4.00 pH oa ae are get ewe wate CH,COOH a CH,COONa ex SyMTe Fw BA? [Ky = 1.8 x 1075] Y(@)5.56:1 (b) 6.97:1 (15.56 (1697 Solve 4.00 = ~Iog(.8x 10°) tog SHAE, EEDOHL 5.55 35°C errata cote Boa Rtema TaTe 2.4 x 1051 as for ofeadt we eat [kJmol-? were] (@) 3761936 (b) -37619.36 ¥(@)-37.619 (37.619 Solve: AG = —RTInk = —8.314 x 308 x In(2.4 x 10°) Jmol“? = —37.619 kjmol~* Togk, say 2 x cerca rere Fiera Ss rT 1H an an YO) Foan (© za0a ©) oan slogk, = aH 240 Y= f itm = att Solve:logk, = OH .24¢; Y= mx+ Canaee gre vet m = SA CH,COOH Bett H,0# farce are aa? (@) Acid V(b) Base (©)Neutral (@) None Salve: CH;COOH + H20 CH;COO~ + H30*; H,0, Ht tee ae PR Base | MCC 5 Math sin (tan-*2 + cot-*3) Oy (b)1 @ Solve: sin (tan-2 + tan" 2) = sin(tan“*1) = poos"hx =? (@) sin™ (©) tant [= Y(@ or Solve: +cos?x = 8%, x = cos 28 sea WMUTITS x Replace re ACHES @ THLE cot~*(tan 2x) + cot~1(- tan 3x Y@)x wvi-# (©)3x @o Solve: cot~1(tan 2x) — cot~¥(tan 3x) ~ tan¥(tan 2x) — $+ tan™(tan 3x) ~2x—F 43x = 3x—2x=x Tam arte as action come 26 iano corn aga OT.Rflafk aad erira-208 ‘Seer AGA TF-04 04. cotcos*sintan~* )vi- © J2s =? @1- | ey Solve: a h 212 coteos“ sin (sin? 2) = coteos-1 zg = coteot“1x “@x 05. y= 2cos™?x amy = 2sin” x waemerecrs cneg Cote Cw) o GA) 10 G4 6G Solve: y = 2.cos~ 2sin?x > cos*x = sin" x 4x <9 2sinx=% a 1 E sin Aewy = 25in 06. y = sin“ xem ota oa? eG oe Yo) : 1 [Tesine- vimana] ee (@x=2y @x=4y ()x+2y=0 Y@x-y=0 | eosnctaint— (eases) _ /(cosxsin x)= + (cosx-sinx)?) = tan (tanx) > y=x-x-y=0 Solve: y = tan“ (nn-F (antt Y@anit 09, tan? 0 + cot? @ = 2%, 0° < 0 < 360° waite 6 a -FA WH stem TTR? Yas (b)2 ©3 @5 Solve: tan? 6+ = 2 tan*@— 2tan?@+1=0 = (tan?0—- 1)? ma Stand = 41> 6=neit ne Z] «6 =nx 180? 4 45° n= 08m, 6 = 45°,-45° n= 1, 6 = 135°,225° n= 2 &m, 0 = 315°,0 = 405° 0° <0 < 360° rafts, 6 = 45°, 135°, 225°, 315° Ga crite as ae come 27 fardors sree PGA NPM.ARR ayS wREFA-2022 Seehe HAPT F-04 a 2 10. |1 pp?) facta ater sea et @Q+PG—P) — @p-PAA-p) — @pA-P|G+M? —-¥@ PCL-pF@*- a. +t 0 0 £ Solve:}1 pb pil=|1—p oo p—p? pth =C, - C2, = CC toot ot] fee pap peo , oO 0 + =a-py) 2 bo pi] = G@—p)? p22 + p) — pa +p) = p(t —p? 2 Lap pete) pC. + p)] =p —p)? (p?— 1) [cos® —sind) a) wu. a= [Sino cosa | A= [7 @F 5 @z 6 an = feosnd —sinnt Selves A = ne coon af = [eos sinew sin4® cos4@ 2 =sin4@ = 1 2 40 = | i - ae as 12] 13 18 17 | aa fifa 2002 ax reese we? 2001 2002 20031 ¥(a) 48 (b) 48 () 46 @50 Solve: 2002 aa 7eer = +s Ble -(17 -5x 13) =48 b.a=[2 S)e=[2 gx cat ay = 1p4s 1 ap4s 1 ap44 1 ay44 1 ool a) sls Al eke Al vost, 7) epa=l2 1). q@ayte 2 44-2 sowverBA= [ay gal OO "=F [251 9 a-k 9 4, a-[1f (12) MRE A? ate kaaares: (a2 (b)-2 ©4 Yd) Both b&c Solve: (1—k)?-9 =0 > (1-K)? =9 > k=434+1=-24 15. 4 x 4ssreere come ray A wea Gammon oem 4 wm, |(V2I — A)" | exes? (@) v2 (b) 24v2 y@O0 (@ -2vz 100 oj) f2 9 09 0 sove:|(vai—a)'|= 121) 9 ‘Hf: vw olt|-" 000 1 0 0 0 v2 16. A=[2 3 B)evat ames o4K F 2 Y@ Sree Solve: Am? erace weer anim ATE AT Taga ace ae aE Cra 28 ieee ao AGT NET,PARR aa ortET-208R ‘SteferrerA geOF 25 a Is 1 12 Ip 6 20] Y@)a=8,8=5 ©) Ban B= 5-H, cy 2a 2a b-t—a 2b 2c 2c c-a-bl @@+b-o @) @+b+o* ©@atb+0? Yd) @tb+oF = Le = 2 «a heimen am ffs era et (a+b +c)? ae (at b+) o 2a atb+c —-@+b+c) 2b 0 atb+c c¢—a-—bl -1 0 a a. = 2b 0 1 c-a-bl =(@tb+c@t+b+c)=(atb+c) 17. = OTF, a8 RENT? 5,B=8 (a=3,p=5 X cy ROMA RRA AM | Solve: Alternative: a =(@+bto? =(atb+o)*{-1(a + b—c) + 2b +0 + 2a(1 + 0)} Physics 19, corer a To Fie HO a 2,5 CHP eT 7K EHC rE ea freA 440.89 J ee, OTA () se rate (0) Reventee VO) TEU (@) None Solve: Fes SIRE dQ = du feastno, dv = 0. dw = 0) adu= dQ == {nRaT 4.440.89x2=1%25X8314X7 a f= 6 20, cerca gat abe ence ee Fg 13°C sem mmr Fg 89°C | Be | S1°C tera OTE eee ETA (a) 106°F ¥(b) 12°F (©176°F (@ 128°F Solve: Se = Gag = 122F 21. O°C trata 10 kg Sere 7000 m By Rw exe, Hei UE A TTA (a) 2.04 ke (b) 4.08 kg (©) 102 kg (2) 8.02 kg, Solve: 10 x 9,8 x 7000 = x x 336000 « x = 2.04167 kg 22, crea crn ROT ZH TEC teat 7OK a wT 3 | wT TT N- (@) 105K ¥(b) 175K (210k (a) 315K Mies Solve: 1-7 = mae ay Et, 70) = > = 210K = 2, ome rr crate aTIR cere eT ef Or 260] wr Ta Ha ae WEE Ce 300] wi ake Em ree “erat 10°C we, ae cles. (a) 303.46°C (©) 303.46°F (©) 30.46K “(@ 30.46°C Solve: Q, = 260}, Q2 = 300] , T, = (273 — 10)K = 263K & 7 303.46K Tan Gants as acer oa w Re GTGRR gS orFA-2022 Seok RAPA H-04 24. 3 kg “fis ciate 206.6°F are 60.8°F ear ae, a oieen wo? (a) 2207.3 JK~* (b) -7301.7 JK~? (o) 3113.16 JK ¥ (a) -3113.16 JK? Solve: m = 3 kg S = 4200 JKg-1K~1,T, = 206.6°F = 370K, T, = 60.8°F = 289K 4S = msIn# = -3113.16 JK 25. 27°C wtaras Fg of Fer soem se eet era Feet at Kt | HA eT @ CE wR BR TEE fer einret- (@) 17.81% (b) 57.13% ¥ (©) 35.56% (@ 33.33% Solve: T, = 300K, V2 = 3V, 1.64439; fy = 1.4] tr a= (1-2) x 100% = 35.56% [2 = (1-20 > 13.63% = (1 ee) 100% + nz = 19.998 mol = 20 mol 28, amor saree coon ag sree TCR TER 50% af eae, wlaTat we RA? [state IATA 27°C] ¥ (a) 262.43 K () 221.3 K (€)22337K @ 300K Solve: T, = 300K a(t = V2 = 1.5, “ Tan)” = 262420 iy a 29, wert effaeate fing fet Tee wrereteT feet Far AIA, BT Fest AA? [y = 1.4] (0) 7.392 ¥(b) 11.3137 (©) 1.569 (@) 2341 Sovet =2T a Es TP,” =TP, ae =#=() 2 Py = 11.3137 Py 30. STP ce 10 mol “IPT SITE ST Re cae SoH wR RE Ree TE FEATS EP (0 (b)11348.4) (©) 22696.8] (@ 45393.6) Solve: AV = 10 x 22.4 x 10-%m? P= Latm = 101325 Pa 2. W= PAV = 2696.8} 31, Op om ea CATO @ PRCT CTCAT TT TE @ vos wt @! _slopeoftsnthermal curve, 1 Solve: opeofadiabaticcurve ¥ 5 me EG STS a ae CORT 30 atin ere AGE ROT.PRR eS arA-2022 Stef napa gP-04 32, sare ef 1.5 atin Biot ZL tore TET Re aaT BOAT ¥(@) 210.7) (6) 140.6) (©) 2.079] (@) 200), Solve: W = aRTIng? = Py ing .5 X 2 X (In2) x 101325 x 107? = 210.699 J 33, sees eftear orca if, AS =? (akin (©) nCyInZé Y(@) nly in = @ms aT Solve: 7aTKe7 fem dW = PdV = 0 + dQ= du = ncyaT; $0,d8 = 2 = ncy f= as = nCyIn () 34. ic has v GH PCE TET FST TIT? (@BoA )C>A Y@)A>B @BoC Solve: A B oe fige viet stmera sft rare; OTE ATT Chemistry 35. Sa er eenet Dae SO A BGT a I (AE) ro ee a (©) 60.76% Leabietae. Solve: P,S3 +80, ~ PyOyo + 380, AB wae * 100% = 40.34% 36. eon cor Pe Kp # Kee? ¥ (a) 2C(s) + O2(g) + 2C0(g) (b) 2HI(g) = Hy (@) + 12(g) (©) NOz(g) + SO, (g) = NO(g) + $03(g) (@2NO(g) = Nal) + 02(8) >] Solve: An # 0% K, # Ke 37. 2NHg(G) = No(G) + 3Hg(@); rer ee ee Re oToR NHN, aH, a cr MeO MEER 2, 1.03 | Rta a Ke = 8 2, Pe aurea era wa core eae ER eer SEA 1 a] Y@retice (b) sree (6) Feteent arama re (@) cceteat fice caps acs ome Solve: Q¢ = 34 = 6.75,Ke = 8 7, Qe < Kes ome race seer eer EET rs eC 38. 25°C wremmarn aa Hy aPRET Ky = 1.8 x 10-6 am, on waTe wee PK, ae ew? 7 ¥() 8.25 (os 432 Solve: Ky X Kp = Kw: Ky = 2 = 5.56 x 107° Px, = — log(5.56 x 107°) = 8.255 ‘WET, pK = 5.745 py = 14—pK, = 8255 aa aes as ae Come 31 a oer Fag AO.‘RGR ag erFA-2082 Stef ngRA F-04 39. 2ABS(8) = Aa(e) + 3Bz(g) Rs sranree Ky a1 A2(g) + Ba(g) = 2AB,(g) Pear mee K, ee, Rest cat were ote Y (a) KiK3 = ) KK, @k=- Solve: 2AB3(g) == A (g) + 3B. (g) [aal(B27? K [ABs 3A2(B) + B(@) = 2ABs(e) K, = BRE 55 Kg =1 PB) 40. Fens co Fert Stn arse ee HP (a) CHyCOOH + CH,COONa (b) NaH, PO, +Na,HPO, ¥(c) Na,CO; + NaHCO; (@) Botha&b 41. 27°C rare PCls (g) = PCls(g) + Cl (g); feats aranrcute cx ora 2 atm exe Farm ATT 40% eM, Ke ae TP (a) 0.381 atm (b) 1.53 x 10-* molL=* (©) 0.45 atm: ¥(d) 0.0155 molL-* fi ie oe Solve: K, = (33 = 0381 atm; an=1 Kp = Ke(RT) 9 Ke = Soeaag = 0.0155 moll? 42. 0.1M SOmL CH;COOH 4 0.05M 100mL CH,COONa axes feet WER 1 mL 0.4M NaOH Ett cmt zat em, ‘fects pH ¥e wa? [K, = 1.8 x 10-5] (a) 4.745 (b) 4.675 (©) 4.833 (4) 4.814 Solve: pH = pK, + Tog netacoona eo, = —log(1.8 x 10°) + log "COOH = 4.914 43. 25°C errant 0.5M frets eficen Facet Wat 0.3% wer, aPireR FarER re 7 ¥(a) 2.7 x 10% (b) 4.5 x 107 (9x 105 (@) 6.75 x 10-9 HA = 2Ht + AR Solve: — Initially(mol): c 0 0 AtEquilibrium(mol): (1 —a)C 2aC aC K,= (H*Px[a?-] _ (2acy2ac _ 403c? [HA] (ac a «15K, = 403C? a Kp =4C2q? = 2 r 8 + Ky = 40a? = 4.x 0.5? x (23)" = 2.710 44. 298 K errs IL erreera ee arom A(g) + B(g) = C(g) + D(g) fetmre ATE 100 1 a ema sce eR Faeere eR Sete eT IM By, OT ATTEN B as oe se? (a) 0.182 mol (b) 1818 mol (©0818 mol (@) 1 mol a--# Ra. © + 2B Solve: _ Initially (mol): 1 L 1 1 At Equilibrium (mol ast _ de - Ke = Gor = 100 FE = 10x = 0818 B aa off = (1 — 0.818) = 0.182 mol U-x 1-x 0 dtx 14x Tega erate as ae Coat 3 taeda ore PAGE NT.aca aa TeiTA-20Rz Stole AGMA F-04 45, 25°C ertaam 10-°M warren NaOH «a watt aac pH Fe? @ 65 (©) 6.9586 (7 1) 7041 Solve: pOH = ~log(10-? + 107) = 6.9586 pH = 14—pOH = 7.041 46, BRE SBT atta pH THIET 2 em 5 | eer ERT ERAT RE eA ees SEIT? @) 10et () 103 4 Ye) 10 et (@) 107s Solve: pH, = 2 ; pit [H*], = 10-?M; [H*], = 10-5 sre are pra afte = 2 = 19° oe) 47. 9.74 pH om oro areta ae tg eae NH4OH oR NH, Cl aa septte ye ata? [Ky = 5.5 x 1075] (2:1 Vb) a1 (©3.78:1 @4.79:1 Solve: pk, = ~logk, = 9.74 = pKy = 14~9.74 = 4.26 + pOH = 14—pH = 4.26 « pOH = pKy Hog ey [NH OH]: [NH,CI] = 1:1 48. 2S02(g) + O2(8) = 2503 (g) Rftrmibre 25°C errare aan yHeR aaeT —35.287 kjmol-? eer, ataReACN A eS m= (@) 1.65 x 10° ¥(b) 153 x 10 (1.29 x 106 (a) 138 x 10° Solve: AG? = -RTInk = k= e 153 x 108 49, South Aue Berors WHET fee exe ENP wo A? (@)} times (b)} times (©) 2times ¥(@) Same as before Solve: wana red Amma RET AAT | 50. NHy 300" HyO Peace aera? (a) Acid (6) Base (©) Neutral element (None Solve: NH +H;0 ~ NH? (aq) + OH” (aq); HzO, H* atte eI Acid Ot, sin sin tS @)o Solve: By Calculator 33 feeders acerca PT TOT...Raa ered wRbrA-202 Seale AEH Fe-09 03. tan(cos~*x) = sin(tan“? 3) =, x =? @ JF me OVE Ox @s S08 = cos 20 = cos? 0 — sin? =E-Z52 ‘seat, tan 8 = 05, y= tant x rey = 2 cot-hc rarer cent cote @ (1.2) vo) (1,3) (@ (v3.3) Solve 2tan™ x = 2cot™? x = tan~ y LF @) TT (@x-y=0 = cos (0-2) = cos? > 09. cotx + cot2x + cot3x = cotx - cot 2x: cot 3x 8A, x =2nn +2 in@ = 1 > cos cos 8 + sin¢sin® = ¥@) 2nn4E 2 x x weak @@nt DF vO) Gnt DE ©@@nty5 @5nnt? Solve: cotx + cot2x = (cotx: cot2x — 1) cot 3x = SE cot aed Ta ie a dc = > cot?3x= 15 3x=nnttox=inntS=(4nt1)S 34 area ETCH FARA MOM, Fan ernie os aang ourGARR AUS aePTT-2OR See eH Tv-04 [ ai 10. |i 3 9) =-12 am, xara ve? 1 9 x3 @4 ()0 “3 @t aaa o o 1 sabe 3 9)=-125|-2 -6 9/=-12 1 9 x3 -8 9-x? x3 > -2(9- x3) - 48 = -12. x =3 (Ans.) = [e050 -sin®) ae g — Sam, A? 1, A= [08 SUP] 0 = Fe, at arate vs os orl ekg oY] cosn€ = —sinn6) sinn@ —cosn0 cos38 —sin3 sin3@cos30 Solve: A = x 0 =1) jewel Ol a 3 5 12, | 13 15 17 | fdrece, 2008 aa Ree eer 2003 2002 2008! (a) -48 ¥(b) -22 @o @s50 Solve: 2008 aemmeag=|1, 3 |=17-3 «13 =—22 1 ay BE FE = te axe eaweer (@)(-21,3,1/2) ) (2,-13,- M0) (24, @(-20,3 0) sowe:[2 7] & 2]= (5 {]ap-rena=a7y 94 A-(F 1 ] 2 2 l-3 11> [3/2 -1/2| a 3 5 14. [: 16 87 |=sst0m =r I9 2 1-kl @-4 ()-3 YO-8 (@) corte ae 13° 5 1 0 0 dees ~ae, save i 16 #7 |-[ 4 67 He 2 ‘| Io 2 aK !9 —25 K-44] 169 = 63 ~ Seu {4(—k — 44) + 25 x 67}- 0+ 1675 — 4(k + 44) 75-1519 +1675 —4(k + 44) = 1519 k= Or, option test by calculator . 15. 4 <4 orem cons mf A ee eo Soma eer 4 ee, |(V2I — A)" | examen @ wz (©) 24v2 Y(o)0 (-22 ; 10 0 o [v2 0 0 oj)" solve: |(v2t—a)*| =|{yz]2 1 9 O|_]o vZ 0 o = ve: | y| 00 1 Ol-lo 9 yz off |=° 00 OU Lo 0 0 yal Eg aaa a6 SFr 35 ioe ea GT TM.RRR eS TrtER-20RR SRoFe TEMA gP-04 123 1 c=|4 5 6 ee P a 9 [eet 10 1112 aes 2 =3/11 13/10 -5/2 9/13 of! i 2] omens 1 0) 12fl Solve: C~? erece ecm, [C] Frere ere ace eae Fifi of acs aT | a 5 8 17, [3 1 | = ORM, ae Baa Fe? IS 6 B (a)a=2,B=15 )a=3,R=5 Y¥()a=2,8=20 @a=s, Solve: = 2.4m B = 208A, cg = 4% c, Wear AACE TAT TT x ye mee? 18. Jetty? x |=? xy yPtyz 2? (a) 4xyz? (b) 4xy?2? (©) 4x2y2z, ¥(d) 4x2y22? Solve: x= 3,y = 1,2 = 2 er Peter ay 4x2 222 eer ERT TL Physics 19, ee mes 2 cme RT LK ers TAR are wey [BI fet, > = 8165.47 Pa mol K] 1.67) (a) 0.641 x 10-*m? (b) 2.641 x 107¢m3 ¥ (©) 1.641 x 104m? (3m? Solve: nC,dT = nCydT + PAV = nydT = ndT +Zav = 2y=2 +Eav = AV = 1.641 x 10~m? 20. 176°F wretarars carer wrormtine srares rors ares re 13.2 aes xem, ener oa Regre a ea (2) 851 ave (©) 20.475 are (0) 10.214 ave (@ 17.07 «xe Solve: Tyr = 273.15 K,T = 176°F = 353 K Take. Xy = 10.214 unit XO Kee 21, 3800m Barer zee 20°C wrrmata SL ott ret ear, se IT eS BH OTC (@) 367K () 10.33K ¥(c) 8.167K (2K Solve: 3500 x 9.8 x m = m x 4200 x AO «. AO = 8.167K 22, ei ier arsenate AAT | eta 1 200K @ SOOK aH weer Rents | FREE RerR Gera wrt 620.6°F Rr sec evra (a) -9.4°F (b) 2132.6°F (©) 1440K (@ 250°F Solve: 620.6°F = 600K soo x o Ear) 250K = —9.4°F 23. cre RA cai TI aT aT 79°C ae ARE IMT 47°C ee, wr PE CIA A? @5 6 ¥@7 @s Tar Saisie a ators OT 35 aT OTT TE TT.2298 TERROR Stele agra yH08 ‘Sorat Bas war Re | BON 24, Ug Aes 127°C ee 147°C wrmar rat RTA | TATA Keg dQ= 0+ awl aT =o} 9 dQ = dW = dQ = oRTInZ Ve ds = nRInZz nRIng? + dS = ning AIR, PiVy = PV 2 7 dS = nRin2t 34. c Zp Vv arto cad oration aferss (—)ve? @A+C Y@)C+A (@A>B @ak&e Solve: C > A co srHTeH wae bie TUR A CATS | WL OTTATELAPT MERE, TT FATT dU @ dW SORE TTR, we dQ(—ve) | Chemistr 35, KI-+ AgNO, — Agl (tre Bem) +KNO5; Mtns abs ear we? (a) 69.94% (b) 66.46% (©) 96.46% @ 93.64% Solve: aba Rear = —2— x 100% = 69.94% 36, Reva com fear Kp @ Ke ae ame 2 ar (a) CaCO5(s) # Ca0(s) + C02(g) ¥(b) 2502(g) + 02(g) = 2805(g) (©) N2(g) + 3H2(g) = 2NH (2) (d) N2(g) + O2(g) = 2NO(e) Solve: CaCO, (s) = Ca0(s) + CO, (g) 2 fer An 2802(g) + 02(g) = 280, (g) «& feftae An = 1; No(@) + 3H2(g) = 2NHs(g) «8 fare An Na(g) + 02(g) = 2NO(g) «@ Rr AN = 0 + 2802(g) + 02(g) + 2803(g) cw, Ke(RI) 9 = Rt Gaia areas ae acts Come 38 iets I PAGE AT.AUR erg eRFN-2ORe Seo AGA FF-04 37. A+ 2B 2 C+ 3D fefeute eter IL ax ote 3 mol D,2-mol C, Smol A se 2 mol B AR Ke FATT HE ANOTTET Scr we feats aye ere? (@)27 V(b) 3.7 (17 @23 Solve: Qc = 23 = 27737>27:Ke=37 38. O°C wrmatare ae gars HOF exe Heat 10-7 Rem, Hea gE. [Ky = 2.92 x 10775] (@) Prrere Yor our (@ crea Solve: [H*] = Kw = V2.92 x 10-8 = 5.4 x 10-8 rioaet H* Sea weratet > 5.4 x 10-8 M 39. $A2(e) +3B2(g) = ABs(g); Rita ommnree K x, ZAz(g) + 2B2(g) = 2AB, (g) Rtas aTEEee wo? @s vv) VR? ow @K Solve: K = 48, @K, = 48, = fe) Ve axe AgKBE EXE, 40. con® area are? (a) CH3CO,H + CH, COz Sn (b) NazCO3 + HCOs str (0) H,P03 + HPO}- sre ¥(@ Ba OT Al, 25°C wrtatat ear 2.5 atm dite PCls 65% Facmifire eer aTaTTe RMT PCl; 1 Cl, Dee aT a FaferaA K., ae AT - V(a)7.475x10-M ——_(b) 8.101. x 10-*M (©6239 x 107M, (@ 7.263 x 107M a2? _ (06925 _ 1 999 am Solve: Ky, a ny x = Ke 1829 oa Ky = Ke (RT) = Ke = Ps = saat = 7.475 x 102M 42, eee arent gact fe Fides 0.56 mol NH,OH © 1.01 mol NH,Cl 789m | ef Fores seg GEFEN 0.02 mol HC] amet pH ¥e ea? [K, = 1.8 x 1075] (a) 5.065 ¥(b) 8975 (4.752 (@) 5.025 Solve: pH = 14 (pK + log PHS) = 14 + log(.8 x 10-5) — log S20 — 8.975 43, ef rere ear 4 x 10-* 1 IN ET 4% HAE RTA Fe? (@0.6M (b) 0.48M (0) 0.55M ¥(@) 025M Solve: K, = a? C= C= 44, SO2(g) + NO; (g) = SO3(g) + NO(g) Fafarura smears ws 4911 L wre oem 2 mol ser effete Sonera Re CET RSOFEETT SOy CATT FT - ¥(@) 05 mol (&)1.5 mol (©1mol @25 mol Solve: S02(g) + NO(g) = S05(g) + NO(g) Initially: 2 2 2 2 ‘Avequilorium: a ax Bx $0, 44 RA eH = 2— 1.5 = 0.5 mol Tan aaa ae aT COT 39 ee Ter GE A.Fa gS MreAT-203 ‘Sie ag ye-04 45. 25°C errant 10-7 M wratara HCl at ATA pH Fo? @7 0) 73 YO6T @s Solve: pH = — log{H*] = —log(10~? + 10-7) = 6.7 46. Gab Ete mara pH TUR 2 aR SR EAC PE Teh Feed a? (@) 1064 (b) 103 st ¥(0) 107 «4 @10 Solve: pHy = 2; pH = 5 (H*], = 107M ; [H*], = EUS KER BAA GE = 47, “ioe orem areR Tet ax are abuse MTATURT IEPTE Te? [pK, = 6.1] (@) 13:1 (b) 0.05:1 (0) 20:1 424 [Hco31 THac0s ACOH) = 20:1 Solve: pH = pK, + Oran > 74= 6.1 +log al 48. oft Gout ferua Kp = 40.5, K, = 5.51 An = 5 a, we winters fat eww arare? [R = 0.082 LatmK~ mol] ¥(@) 661.26 K (b) 330.63 K 179K Solve: Kp = K_(RT)® « T= 661.26 K 49, South Fears Rarer eam Bite HEH TPT ee eA? @ 16 64 404 VO wa Solve: wnat afiaser aruraTen ofeasy VAT 50. HClawet H,0 feats areres (@) Acid Y(b) Base (©) Neutral element Solve: HCl + H,0 > Cl- + H,0*;H,0,H* ser #r B12 base, Math (@ 256K (a) Roars wera Bor Foe (@) None W ofan eRe SOTeE FRET TOM...Sire aS FRFA-RORe Seefe TAPIA F-09 Rem mes 6 si? 2— cot 22 tan 128 ess, sin”? — cot“? 2 — tant cla a 5 2 3 sin“?2 4 2cos-t-— cot“ 128 sin“!} + Fcos? 5 — cot" 2 = tan" (Proved) 02. secO ~cosec 0 = 4m, ore cy, 0 = Zsint? aa- wig = 4 > 3Gin 8 — cos 6) = 2sin20 > 9(sin@ — cos)? = 4sin? 20 = 9(1 ~sin20) = 4sin? 20 = 4sin?20+9sin20-9 =0 = 4sin? 20 + 12sin 20 — 3sin 26-9 = 0 = 4sin 20 (sin 26 + 3) — 3(sin26 + 3) =0 = (sin20-+3)(4sin20—3)=0 s sin20+3-%0 4sin26—3 Solve: + 03. Solve: 4 sin 9 - cos 0 — 2cos@ — (1 2sin 8) = 2cos6 (2sin@ — 1) ~ (1—2sin@) =0 = @eos0-+ 1)2sin8—1) = +cos8 = —350= 2nnt = [ne Z| 0 sin@ too=meCayt : 2 -5 3 04, A? 4A+ AB = 188, Banta Pein ex ae A = [2 ; al 2 ; 3] 7 -9 Solve: A? = [23 ; [23 l- [- =| 0 30 a ~anvan 213k Sat edA 10 © 73), (8, 20 [Ms -2e 2 > AB= [ 1 ‘|- [fs 51 =a] 28 4 3 [= —46 2 0 01 -20 30) l20 20 40-29 45-2021 45-20 21 oanns an [aa -46 i ow-wfe 46 2 45 40-29 45 40 —29) a m4 73 De oe [2 -20 21 & 8 3 -22 -46 30/>B=|*% % =2)fansy 45° 40 2] Wy aie at “4575 a RAG OTT PATE TOM.SUR ay FRiFA-2022 Seelel FEPA F-04 b+c cha a+b lq+r r+p p+q| +z z+x x+y 0S, Fara at cm eta a: ja bq pq | Kk y pte cha atbl jb-a cmb atbiy | b—a b-c atb Solve:|q+r r+p p+ql=|q-p r-q p+al[ioc a la-p q-r p+q y+z z+x xtyl ly-x z-y x+y 2 63. y-x y-z x+y! -bta b-c atby |b b-c atby Ja b—c atby =|-a+p q-r p+q/=|-q q-r ptaql+|p q-r pt+q ytx y-z xtyl Ly y-z xtyl |x y-z x+y! jb b-c atb ja b-c a+b jb —c at ja b-c by f q-r ptaq/+|p q-r p+q -[ -r plt+|p q-r q ly y-2 xtyl Ix y-z x+yl ly -2 xl Ik y—z yl jb a cf ja -c by ja bq ab ¢| =e def = sleeane IP 4 tl+lp qt ly x al |x -2 yl x y a ix y al cta atb) [2(atbt+c) cta atd| qtr rtp p+ql y+z z+x x+y! 2(p+q+r) r+p p+q 2e+y+2) 2tx x+y ih=a te: +e3] jatb+e cta atb) Jatb+e —b =q 2 2ptatr rtp ptal=ziptqer -q rh [e =o 7o] Ixty+z ztx x+yl x+ytz -y —z| a= c3—7 4 ab —o 2p -a -rhlej=ate tes) x -y -2l a b ¢ =2]p q 1] [Proved] Ik y zl oo785 0 00-37 2 06. |Al=|2 15 5 12 -2 |enA er, xe a FT A | oo o1 0 —2 3 Tas of oo7o0 Solve: [a] eavpat rea tore, l=] 9 <3 2 1 3 0 4 2 2 | = 294 [een orf W, 2 ne afer emits ware 652.54] a ais eHCe a | 09. O°C Bremer 1 ke Facer Tee 70°C wre 4 keg en car aT xImy, Ferre rRTat eS nit eae Far Solve: ff, ers erraTat = x + (1 x 336000) + (1 x 4200 x x) = (4 x 4200 x (70 —x)) = x = 40°C (Ans.) as = (PS) + (1 x 4200 x In 82) + (4 x 4200 x In22) 348, + OS = 267.38 JK-*(Ans.) 10. 27°C wrermar ae 1 atm BIO 2L sore FTA fon stay Fee ea RUT FORTS Me ass Fete [y = 1. Solve: W = PAV = 101325 x (6 —2) x 10°? = 405.3] (Ans.) Py _ 013zsxaxi0-? Rr" eataxa00— ie he = 0.0812 mol 2.597 JK-* (Ans.) LL, core erent or efor Geo ees 720) wre Few ater 300] wre xe wes | BAe RET Fa | Dee CTATAT 120K ze TA ST 66.67% OT, BT aT TTT 300) Solve: 1 (a ==) X 100% = 58.33% (Ans.) Fa on oot mache . - 1-2 1-3 Ba S25 = 12 93% = ; te = 9667 St Tyetz0 ~ eo anit qaig =F 1 +120 = 37, 97, +1203, ay a 12, HNO cansave ‘| sro eave) =r [nv coer sa ae et RT] foam erifte enn wore salar eo (sn Renae] Solve: = Work done 9ST, abe et Bi op TATE | wT, Fae ECT ab eee ae ee BIT be ted Tt YES A + 4BE CHT = dQay + UQpe = MC dTay + NC pAToe 'nRdTyy + J MRAT = ZAP Vp +ZAV02P (2P) — Pa)Vy +2 (2Vy —Vp)2Py = Poo -Ferte = orem = (2P4 ~ Po)(2Vp — Vo) = PN + = SHeM® x 100% = 10.53% a ee B ie cere GT OT.trae aS oRiFA-2ORR Chemistry 13, ae ae sttca Hee ACS) = B(g) + C(s) ffteata Kp. Stefi agp ge-04 xatm (22 fafiers aroreate 2P, Stet Bo Benga wae smo meee B(g) = D(g) + E(g) ftome B ai erate ma P, ae ana D «Eafe orem entite oP 1 We Kp, = yatm |e5OHH X-EY = PLP toe, Solve: A(s) = B(g) + C(s) sora: 2P, sommes, Kp, = 2Py 0 ars, Big) = D(g) + E(g) Initially: Py oo AtegullibriumP,-P; Pp Pe ARPT, Kp, = Gi) {OF GD} > niy=an + a 28 aheett _ eisenot xt+y=PR- 14, (5) + 02(g) = S0(g) ftom 6, Kp, = 104 2S(s) + 302 (g) = 2505(g)feftrut wo, Kp, = 10° atm! 2802 (g) + 0;(g) = 2803(g) fafieara ara Peo, = 3 atm ak Peo, = 0.5 atm ey, 0, ax TRE OMT FE? Solve: S(s) + O2(g) = S02(g); Kp, 1 280,(g) = 2S(s) + 202(g);. m0) 2S(s) + 302(g) + 2803(g); Kp, ».» «- (ii) @ eG) Rx, 2p +.02(g) = 2505 (8); Ky a sifeas i 10 -1 =K3 m x Kp, = TF 10° = 10? atm’ e Fz am, Ky = toe =10? = Toy = 10? * Ro, = 0.36 atm Alternative: S(6) + 03(@) # S0,(g) ere mm, Kp, = 22 ote ots B= (108)? = 108 eo (1 ff al 28(s) + 30; (g) = 2503 (g) 4 cram, Kp, = oe = 10 Pho, Pho*Poz 2802(g) + 02(g) + 2803(g) 4 ore, Kp = P2, 30 Po, x10" 32108 2, (1) + (> = GD + > By to, = aor = Ke > Pos = pap aa Garo atM = 0.36 atm gw aerate ae cate Come aRGR erg arFT-20R Seeing ye-04 15, Nz04(B) = 2NO2(g) 27°C rrRRATH 1.5 atm Bic Np 0, a 25% Refine ew Fem rare She ea ca Tea aH BAR fecmrry as fre Ft | a il Sigua Solve: N2Oq(g) = 2NO, (g) fie oven, Kp = $2 = ACHES pr fees warm, P, = 2P = (2 x 1.5)atm = 3atm. 4 atm apr Rents at, Kp = Milt + 04 = Bt = 04 oad = 120} a = [PE = 018 oo + FRCATER wat = 0.18 x 100% = 18% Fecmae RAT MR = 7% 16. 4.6 pH RAR oe area et Volt acs WA 200 cm? NFS 2.3 g CHyCOOH a Aree Fest CSA RAAT COM FALE A? Ik, = 18x 10-5] 2a Solve: nex coor = = 9m, pH = pKa + log ace = 4.6 = —log(1.8 x 10-5) + log “uncon # MeHycoona = 0.0274 mole => “HHE20N = 9.02745 + Weriscoona = 2.25 & 17, sENee (Maleic) aFicex errm fecaTeR FF 1.15 x 10-2 molL-? erae fete eater ae 6.02 x 10-7 molL-? wer, 0.1M Tee fre Bact pH Feit a | Solve: ast", H2X(aq) = H*(aq) + HX~ (aq) = AT Egy, = VETS TO-E XO moll“? = -2 molL-2 gg = RT = gy 2 LAY, = VETS TOP XO moll = 3.39116 x 10-? moll? ‘wa, HX" (aq) = H* (aq) + X~(aq) WOH (H*), =VE02X 10-7 XSI9% 10? moll? = H*], + [H*], = 3.40546 x 10°? moll —loglH*] = 1.46782 = 1.47 18. HsPO, ea aan, fete cae SOe Frcarert era wateTH, 7.5 x 10-3, 6.2 x 10-8 we 4.8 x 10-13 (@) HaPO, fice Fears ae Fee ((b) Frc Frc ser MT Cra OA (0) reba stee Hy SO, er Bawta GIA 1 Solve: (a) HPO, + H2POs +H*:K,, = 7.5 x 10- HPO; + HPO} + Ht; Ky, = 6.2 x 10-° HPO” ~ PO}” + H*;K,, = 4.8 x 10-29 + HgPOq > POS” + 3H*;K, = Ka, X Ka, X Ka, = 7.5 X 107° x 6.2 x 10° x 4.8 x 10-8 = 2.232 x 10-22 (©) H3PO, COT H,POZ © Ht Senay ar | Beoey Ht RMT area HRT Hy POG FRcater Tare eH eR RACaT ETH A A | In APATITE Ky, > Ky, > Ka (©) HyPO, # cra ite ere a = +5 HS, @ Crain citer ora ana = +6 arene Crt core ears aI ara aes et roo SkrsT yf AE | 2 Saw: HyS0, > HyPO, LIT ARC as a OTT 5 Reeeae eT PRT OT .0383 mol -43 x 10-* moll“?‘OGG aralS TREFA-2022 1 02, Stef rar y-04 n= (2) +tan-* (3) = tan“¥(2) ~ tan (2) + tan“ (2) an-¥(2) (Proved) freer: 695, cos? + tan™*3 = tan” 2ginct, : Esin-? 2 erie aa eee lp eet Saget 12 tant are, cos! Ze + tan” +} —tan™42 = tan! 2 + tan? 5— tan“? 2 we 2 q Solve: <5 — sag = $7 3(sin@ — cos@) = 2sin 28 = 9(sin@ — cos8)? = 4 sin? 20 = 9(1 — sin 20) = 4sin? 26 => 4sin® 20 + 9sin20-9 = 0 = 4sin? 20 + 12sin 20 ~ 3sin20-9 =0 = 4sin 20 (sin 28 + 3) — 3(sin20 +3) = 0 = (sin26 + 3)(4sin20 — 3) =0 sin26+340 4sin20-3=0 sin20 = =; 20 = sin7? sin? (Proved) SG a eT as aT Come 46 eect STE AT TOT.Ra a reerA-ROR Stora y-04 03. >ARTT TR: tan + cotd = 2 cosec, TIO <8 <2n 5 HO ean 2 (See OT ine Ot ene? Solve: 55 + Sno ~ an 7 (Gracara amo) = O° sin*O + cos*0= 1] aaa (gap ~ 2) = 0 = cosecd (45-2) = 0 « cosecd #0 eo) wa o=tin n= 13m, 0=2n20 eter: dS [2 0.< 0 < 2n] 04 A=[} [!]en 4-204 4B = Bem, Barta tren Solve: A — 2A + AB=B _ge2ft yep yp ot ap-pera-wa2 if -B alk a= san-n-[2 Joan-m-f 9 =P Yon-a_p2)% 9 =(-ns- YJoa-a-n78 Y o 4] o_[o 2 of deals 2a 2b a+b 05, ves [ors a-c a b-c atc b lly o-G 3 = -2(a+b)(a—b)?) 2a 2b atb) [2(atb) arb) 2Aatb) Solve:|b+c a-c a {=| b+ce anc a |iientntn) Ib—c atc b bse atc b io ty ‘ 0 o Vie es =2a+b)[b+e anc :|-26+5 p-aze eal OTS] Ib-c ate bl -c @-bte ple 25% =2atb{b-atJa—b+0)—e?} = 2(a + b)fab— a? + ac—b? +ab—be + be—ac +c? —c7} 2(@ + b){-(a— b)?} = 2a + b)@ ~ bY 2s 2.53 YU) xare ttre afew a= (6 2: 5000 0 06. IAIF} 5 4.3 13 -1, 5100 0 1234 6 8722.8 4313-12 100 0 234 6 Solves [A] x fx of ater Frere 3H -12, [A] = 72-3 313 12) (er ee =sx(1 34 6 = 5 x 693 = 3465 le T]soxt3= |A| > 6x43 = 3465 «x orem, [A Taya aacsine ae aoe cons a PASH TOT AGA ROT.BRR ag erteT-2028 ‘See EPA FF-09 Physies 07. Cote RETIRE WHEE RI 7 | ira a CoOCAN cere WIT 7°C Mem ote toa EM 2G TSR Ice faeMTTE rt BF SOO] wt crm xe St ta aes OH BCA? nf afrneabe et = Ts Solve: ae na n % Fon 27 = Go x = 320K = 47°C Ans.) w n= (1-22) x 100% = 12.5% ‘wrionge “fe = 500 — 9 x $00 = 437.5 J (Ans.) 08, 1.2 atm Bret ere SL reese site TET arm @ Heat efeeTs eonfe et ecat rare era ee RCH STO 7SL a 8 tats ate cove ewer afm fears eons TE ee? Ly = 1.4] ) = Pav In (2 (PV; — P2V2) = PV = 509.35 Nm Solve: Wy = nk, In (¥2 = 2465] 1 We ya ARV! = BV! = Pv = S88 ve? x Ppa =v -ftey = eee = 7.78 (Ans.) 09. —30°C wrtwiata 4 kg 8 = -8.5714°C (Ans.) 4s me) 336000 27) _ - SS) + 0.5 x 2100 in( se ) +05 x 0 4.05 x 42001n (#2) = 1216.3 JK (Ans.) 10. 7 mol exe snare sic wraeTA foe IME 3 OT A RAT | UH SITET 47°C RT FT, dS = 0 «. AS = 0 (Ans.) AU = —AW = —14481.95 J (Ans) LL, cores wre Rf aefrareT 40% 1 et 7OOK etree eas FMT 1 Be arco errata Aa ARE 50% FATS RM, Deore wren Hifi ATS RA? [320 - 153.2776] = 14481.95 J (Ans.) Solve: = 40% = 1-72 = 045257 = 04 9 2 = 04; [AT = 700K + T, = 1750K (Ans.) = T, — AT = 1050K (Ans.) 50% > 1-7-0537; = 2100K 1 + OT, = 350K 2 Sea OrTHIAT 350K Af FTE wa | (Ans.) Fan creer ae ashes cea 8 aR SET ATT TOT...‘Seelet AGAA FF-09 2SRaie ag HT-2022 12, GRO carve ‘| ara" APoavo =v [n carr spr areata Fat RATE] fon te erormt wore weer we? oA Ree] work done Solver = Feacreceived eee, abve Ae Tt TE RENT | WE, Fea TCT aby ee Re Fer att be Me wT RTE ST 2 JOE PT = dQan + dQpe = NCyATyp + nC, Toe = EnRdTy, + 2nRdTpe = SAPVo + 2AVo2P) = 32. — Pa)Vo +2 2Vo — Vo)2Po =F PaVo “gears = cet = (2P) — Po)(2V9 — Vo) = PoVo 1 = a * 100% = 10.53% Chemistry 13, RB oir ae aa eres stem Pees Renfree A(s) = B(g) + C(g); Kp, = x atm? D(s) = C(g) + E(@); Kp, = y atm? cra fo ee ra rors Rees em TAT a WO 6 y STAT A | Solve: ex fafa, C sera sere orm P, ce Se ioe, Cottons rere oP FRERTT C so onenere o = Py + Py om, A(s) = B(g)+ C(e) Acquire: Pe Puts Kp, = BR, + P2) =x att? vo) ‘ra, D(s) = C(g) + Ee) Phe Pe HIUTEM, Kp, = P2(Py +P2) = yatmn? ..... (li) @+ @Maxty=H+2AR + Bs K+y)= M+R) + o. fftemenans catd bit = Py +P, +P, +P, = 2/KFY 14, 327°C Berman, 5.1 g NHySH(s) 2.5L wera set onan 40% FRemfire eM NH, aR HyS soe Beery wea ee Fate angers Serre er falar Kp feta ea | Solve: NH,SH #3 oa ae = = mol = 0.1 mol NHSH(s) = NH3(g) + HAS(g) R+h = ery Initially: 0 ° ° Atequllibrium:0-0.%04 aug axa Concentration: ae os ie =0016moll-? —-=0016 molL~* =0024 moll 2 Kg = MuaDelas) _ (oot oa Ke = aga = “gpm = 10.67 x 103 mol?L-? Kp = Ke(RT)" = Kp = Ke(RT)* 2.56 x 10 x (0.0821 x 600)! = «far Kp WF 0.526 atm? Fa aestie as wat Come a ARC TON GE OMT. .526 atm?ROS ag TRiFA-202 Seeker napa I-04 15. PCls(g) = PCla(e) + Cla(@); 30°C wtrmrare 3 atm wet 15.6% PCly ‘Aeearfere aon FRieare ater Re ea | ase eTATATT We IE 25% Fafa Facaiis xe Fer ae | Solve: PCls = PCls + Cl oo @ @P, 2x: ‘eure TAME, Kp = 2 = S583 — 0.0748 atm Ge nd = 0.0748 21.122 atm vie FRemTey MrM 25% zr 16. 25°C ersten 5g CH3COOH ee 7g CHsCOONa fifty ae arate ay tela wat at 1d wr 0,05 Me etreT HCL ‘fear Face stars Gectha srterNTT Hifi aa? Ae eT Solve: arercan ererrer aifiee we, pH = pKa S295, pH = pKa + log SECOON OHS 5 0 = logie MS > 7 ny =F + ng ‘RcHgcoor*Bnct Src = Nyc = #5 = CV = 1.016 x 10-9 = 0.05 x V = 1.016 x 10-* « V = 0.0203 L = 20.3 mL + fafismetan 20.3 mL 0.05 M HCI eas er erercen areata =| 17. cater staat fice 0.02 mol HCN © 0.01 mol NaOH capi ax ater 1 Lat | HCN ea PRcHTOTe See 7.2 x 10729 ae, act Ht erty @ OH rere era Fete er |[2 we pKiy = 13.9] HCN + NaOH + NaCN + H,0 Solve: Initially (mol) 0.02 0.01 0 0 At Equilibrium (mol) 0.01 0 001 0.01 ‘BRM, BACT 0.01 mol NaCN (0.02 — 0.01)mol = 0.01 mol HCN Bafye ereze pH = pK, + log” 1, ~loglH*] = —logk, 98, [OH] = 5 = = Ss = 175 «10° moll“ 18. H3PO, 4 ory, fate are wety PACHTER eee THER, 7.5 X 107°, 6.2 x 10-8 ae 4.8 x 10779) (a) HaPO, afiren Pacer gee Ft eH | () aioe Faerie ere MeMHRPT CHT CRP (©) aPrefta art HySO, 4 Stgert GT FH | Solve: (a) HPO, > H2POz + H*; Ky, = HPO; > HPO}” + H*;K,, = 6.2 x 10 HPO}- > PO}~ + H*;K,, = 4.8 x 10-19 H3PO4 > PO}” + 3H*; Ka = Ka, X Ka, X Kay = 75 x10"? x 6.2 x 10-8 x 4.8 x 10-1 = 2.232 x 10-7? (b) HyPO, com HaPOg @ Ht Seeger | Beg Ht SOIT ereteas Wet HPO PRCA arene ee wre FACET IAT THT | Ka, > Kay > Kay (0) H3P0, 9 Grain ttre ret a = +5 H,SO, 4 cea Gera ora A= +6 Sem aPromaTE PAT cea eae IT Plex ew are PET Seer gee AA . Bkgera aH: H,SO, > HsPO, 5x 10-3 Tega were a action TE 30 FD ET ATRU ag arteT-zoxe SeeftepA T-08 01. cos“*¥ + cos“*2 3B [CDG-B)- 9 B-eo00= [0-)O-B) ae 1- 2xyeos8 = cos? @ + sin@ + sin? @ = Zcos9 (1+ sin0) = (1 +sin 8) —2cos@ (1 + sin8) = 0 [+ cos? 8 + sin?@ = 1] = (1—2cos6)(1 + siné) =0 ‘Socare aterct 1+ sind #0 eR, 1— 2cosd = 0 = cos = cost 0 = annt5 (ne Z) n=0%m,0=+2% as n=1em, 03. *aMMy ea: sin 8 + sin 26 + sin 38 = 1+ cos@ + cos 26 Solve: (sin 30 + sin6) + sin20 = (1 + cos28) + cos® = 2sin26-cos6 + sin 26 = 2cos*6 + cos = sin 20 (2cos 8 + 1) — cos@(2cos8 + 1) = (2cos0 + 1)(sin20—cos®) = 0 om, a eae Sala 6= ant Eine Z1 wee cos 8 = 0 = 2sin8- cos® = cos@ = cos@(2sin6 — 1) =0 cos8 = 0 6=(2n+1)F (nz) ‘sie, 2sin@ — 1 = 0 = sin® = sin m+ (“°F Inez) Sefer, Qn +28, (2n + 1)5, ant (“Dine Z Sgn eres as aot Cre ST oa ee ear PAGE ROM...SB Rath ae orteT-202 Seen ge-04 k+l 7 ‘| of 4 xt2 4 Rm, x am a Ff | 4 7 2 om esi x+2 04 |-o1¢-c+q+0) 12 xt 1 2 x+3l 5 Sx—xtx? + 2x=0 x? —4x+5=0 ti 10,2 +i,2-i(Ans.) b+? a? 2 be cto 05. x3 — px? + qx — r= O-Atoaca HH a,b,c UH, eM ac, io? 2 @+b)? 2abe (a+b+c)? = 2p'r b+? a? aq be (eta? ob? 2 2 @+by?| b+0)? a-40? a-+0)% vb? (e+a)?—b? 0 e 0 (a+b)? —c?| (b +0)? (a+b+0)(a—b—c) (atb+0(a-b-0) b? (atb+o(at+e-b) 0 a 0 @+b+oO@tb-o) (b+0? a-b-c a-b-q be ate—b 0 2 0 atb—cl abe 2c 2b be cta-b 0 oF 0 atb+d bce -b | Solve: EE el Ch = Cy -G =@+b+o? =(atb+c)? Ih=n-n ts) lb? cta—b oO ie 0 atb-cl lbc 0 0 ° 2 =2a+b+cr |b? cta b/c [ch =cotderics = es +203] 2 8 jc? a tb =2(atb+c) = ath ae, ates cece om, a+b +c = p; ab+be+ca = q abe =r + 2abe (a+b +)? = 2p?r(Ans.) Seger aecehte ae ati Cos 352 ATER STE PATE HM... Jabe(a +b +) (Ans.) 4 = 2be(at+b +)? taereas sea PREFA-2022 ‘Seah AGHA FF-04 (o+o? at a form! bp? (tah DF e 2 ty? (b+ at-G4e? F- +041 A be tab ore ce) 2 0 apr FOG (b +0)? (@+b+0(a-b—o) @+b+O(a—b- 0) be (@tb+c)(ate—b) 0 2 0 @+b+O(a+b-9 (+0)? a-b-c a-b-¢| =(atb+o*| pe atc-b 0 2 0 atb- abc 2c 2b =(atb+c)?|b? c+a-b 0 fh=n-r-r) 0 ath cine Oe e = Se? bebab = BF [Isa taid=o tel cc actbel _ (axbie? bees BE webec)?xbexbel|e+a —b 220 syeiegah | zemegimee rab | = 2abe(a +b + o)?[(c +a) (a+b) — be] = 2abe (a+b +c)*(Ans.) aes, alter cae of, at b +c =p; ab +be+ca=q:abe=r + abe (a+b +0)3 = 2p*r(Ans.) 06. 15x-10y—5z2=6RGR aw TeTA-2038 07. 08. 09, 10. Seale HEPA FP-04 Physi eA 8.6 rT eA caper we ermATT afeoEE 1480 1.8 mole FET OPH ae Rt HR Der ST we ACAD Solve: K = + Q, = 8.6W +1480 = Q, + W = 8.6W+W > W = 154.167) = Qy = 1325.83] nCydT = Q, x 2 318 x2 x aT = Q x 2H OPT RENE, y = 1.671 > dT = 118,716 K (Ans.) THRE TAT HTN TERETE OU RE ST MRO ea GTA WON STAT we SITET 1.9386 REE eM goer Ste feta er [y = 1.67] Solve: P; = 1 atm, V> = 1.93V, Y =P, (3)" = 3am 2x101325 ees = 20.679 m (Ans.) ee anes ancien arg satiny weMERTH 9B°C sR 2.3°C | 1.1 mole ferns nore cra Ber eA FRO 28°C Ke 52°C ware cfr amet Rem, aaa RTE FE? Solve: = = ae = T, = 26.855°C = 299,855K 98 Ty _ srt | ot C Je = E> Th = S1.93°C = 324.93K + AS =nCp nz = 1.1 x JE In FE = 2.57 JK (Ans,) Jerr ac | catrorcabe a Sheer ace fier TET oP, = Pp +hpg=h= rare efter CHT shia S mol CF 270K WAIN MME 2,5 oF eat ZT | Foor, wore fon Gade wee arf ofa Fete aan [y = 1.33] Solve: W = nRTIn¥? = 5 x 8314 x 270 x In2.5 = 10284.36 J (Ans.) AU = 0 [+ T constant] (Ans.) AS = nRin¥ = § x 8.314 x In2.$ = 38.09 JK"! (Ans.) seme efter caren TOT RO 0.8 5 a RT CDI OP [AH BI LS atm] CRT BM ANH Ba BT am Re Bove ‘Fe xa? [p = 13600 kgm] [y = 1.4] », (4)! = 2.05 atm = 207721.7103 Pa (Ans.) = 1.5585 m (Ans) Po ¥~ HPo2ve) a Ln oe reer aT ea] ‘Fr ere erent ora rare 2 [ora RTARTA San SHS Os ae CoE 4 PRET TA TATE NOM.RGRmne erafS TeiFT-2022 Steir TGrA yF-04 work done Solve: = rok done, ee, abe oe ie ot mae di, Fe ET ab “ee oe fer Bret be see eI RTE RT 2 9QE OM = dap + dpe = NEATH + nC pA Tye RATyp +Z0RAT ZARVo + ZAVG2Fo “2 § (2B) — Py Mo +2 (2Vo —Vo)2Po = Poo “ORE = OHM = (2P) — Ph)(2Vo — Vo) = PoYo & n= ONE x 100% = 10.53% Chemistry = 13. 2 Lerner eaft tex 2 mol N20, far 200°C etrmranm fatten sata BA ATE 0.55 mol Nz0,,NOz Ce eRe eT faftenfia AH = +57 kj mol"? eer, Fftemi cae cr log Kp TINT"? cetn Ste a Y once corr FeguE CaN TATA ‘finer ae N204(g) 5 2NO2(8) Initial phase + 2 ° ‘Avequlfortim: 2a te a=0.55 mol Ke = 0.41724 moll? Kp = Ke(RT)*" = 0.41724{0.0821 x (200 + 273)}?-1atm_ * Kp = 16.2028 atm an) yt saw, log Kp = — (sag) pt > log(16:2028) = = (SS) Xana + 08 = 7.5033, orate Y wreCH (0,7.5033) Fraze cer Fact | 14, C(s)-+H,0(@) + CO(g) + Ho(g): 100K werner ferme AME Ky = 2.5 atm WR ete ST Po = atm, Poo = 2.1 atm re By, = 1.37 atm Bt Stace AUTEN TT TE BT CTF | PeoP iy Pao 2 Qp > Kp Sete farm rors | Cs) + H20(@) = CO) + Hale) Initially (mol): 1 24 137 At Equilibrium (mol 14x Qi-x 137-x = 25 > x= 0.0638 atm Solve: Qp = 2.877 atm Puzo = 1 + 0.0638 = 1.0638 atm 2.1 — 0.0638 = 2.0362 atm 1.37 — 0.0638 = 1.3062 atm Tara aareatae ae an mE 35 fader ore Page TOT.aisle aS era 20xe SR TERT yO 15. 450°C eran S L arrecea ae on 3 atm ot PC]; Renfire aru fafewit armege Cate ae faire Ke = 4.2167 x 10-3 ay, ReararT war fata Solve: [PV = nRT > n= t= cE 0.253 mole] PCls = PCL; + Cly Inivatly: 02s ‘At oquilibrium: 0253-% Concentration: Pela, a, Ke = 4.2167 x 10"? = x? +.0.021% — 5.334 x 10-3 “x = 0.0633 mole [+ x > 0] omer at, a = SSE x 100 = 25% 16. 25°C wrrstars Bg NH,Cl 6 SOmL 0.5M NH,OH gece fitcts pH eirra aacr 0.2M WATE Fe we NaOH crt ear pH 0.07 es atgea? [Ky = 1.75 x 10-5] i Solve: pH = 14 — pOH = 14 ~ (pky + log iBase] =14- {- log(1.75 x 10-5) + ota} = 8.466 2, nreES pH = 8.466 + 0.07 = 8536 on, NaOH + NH,Cl > NH,OH + NaCl $x barton? + 8536= 4 f-ogt.7s x 10 ee *) + lo Goose x= 18.2 mL (Ans.) 17, HyA a yg are 1 Pree 100 mL 0.1 M wemtare gare em Fearon wat 10 96 A Sat RAT | AAO TAT we ey IK, =8 x 10-7] Solve: HyA = 3H +A Initially: oo Atoquilibrium:ca-a) 3a ca (aceyca _ 270 - we ate, 1 = Ky = 270804 = 8 x 10? « = 0.0233 + eater wat 10 64 Bf HTM, a” = 0.0233 x 11 = 0.2563 44, 27 C3 x 0.2563" = 8 x 10- = C=44x10-3M Tain ae a et OTT 36 fiers corn PAGE ROT,eae aS THAAA-203R See AA FT-08 18. HgPO4 9 oem, Ft gee PSH facaTO rae WHITH, 7.5 x 1073, 6.2 x 10-8 ame 4.8 x 107% (@) HPO, feca face eae Fein | (b) Pree Recetas are aREPH CoAT CoA? (© Probar ome H,S0, «7 Sao EET Solv # (a) HzPO4 > HyPOg +H*; Ka, = 7.5 x 10-3 H,POg > HPO” + H*;K, = 6.2 x 10° HPO” > PO}" + H*;K,, = 4.8 x 10778 + HyPO4— POS + 3H*;Ky = Ka, XK, x Kay = 751073 x 6.2.x 10-8 x 48x 10-9 = 232 x 10-2? (D) HPO, cor HaPOg «Ht Beemer Beg Ht rerCrE erereR RET HPO care Tey BR wie ARCATA | OH LTR ATA | Ka, > Ka, > Ka, (©) HsPO, 9 cots cer ores IF = +5 HyS0, 4 cette cera wre IH = +6 rca ort tre ae en ee Te ATER SET gE oT | = Cgunt we: H2S0, > HyPO, Math on, exert, sin“! JE = cost fe Solve: #ff, cos 8>x=cos8 @ _ ses am, cos8 = 1 — 2sin? $= sin?2 —— eel wi ty es saced eae! “flocs ‘SIT, cosO = 2cos*2— 1 = cos? = “SSE = cos? 2 =} [iveos® 1 f2HE088 2 oge-ty = eggmt cosm? [ASE° = Fcostx = cos”? | (ax x sin“? = cos" Sgn anata ache cone 7 TEATS PAE OT. 3c0s-x [Proved]‘SRR ace TRIFA-2022 02, cot@ ~tand = $a, eure cH, Stale AEP FF-04 6, £088 _ sing Ive: cot® — tan @ = $ = 088 _ sine oo 57 sin cos0 ~ 5 cos28_ 3 Fainecosd 5 7 560820 = 3sin 20 = 25 cos* 26 = 9 sin? 26 taf eral = 25 cos? 20 = 9(1 — cos? 2) = 25 cos? 20 = 9 — 9 cos? 28 » Pat= poe 34.cos? 20 = 9 = cos20 = & Ieher al 3 = 0 = }cos"* (5) [Proved] 03, sar #x : V3 cosec 2x — sec2: 4 Solve: V3 cosec 2x —sec2x = 4 => Ficos 2x~sin2 ‘ain 2.082 F cos2x — cos: sin 2x = sin 4x = sin 2 2x) = sin 4x = —sin (2x3) = sin 4x > sin 4x + sin (2x— a So Bain(se<8)- Bet =nnx=}(nn+2) ox=(6n4+ DF awa, nez set, cos(x+2) =05x+2=(2n+0)2 sxeannt3—2 sxsom+E= Gn+1)Lowanez K+4 3 8 04, meee: | 3 x44 5 |=0 5 5 xt +4 xis, 3 | 3 Solve: 3 O=|-x-1 x+4 5 |=0[C)=C,-G] 5 0 5 xt ia! 8 tf 2 3 sernfi xt4 5 O>(+1)]0 x+7) 8 |=0f,=n+r) 0 5 x+#ll lo 5x4 => K+ 1K + NK +1) — 40] = 0 > (& + 1)? +Bx- 33) =0 > (+ 1)? + 11x - 3x- 33) = 0 > (+ K+ 11-3) =0 2x=-1,3,-11 + Prefs, x = 1,3, -11 ga aerate as aon oe 3B idea eer PGT.fae es orr-20RR Ste TERR gP-04 = sin) aga? = 2] 2 cose 184 ils 8] seo ara pares Solve: = aan [252 = sin] i=: ~ anil eeteaes ee tsy sind cos@! Ising cose! ~ L2sin@.cos@ cos*@ — sin? @ ae [eae =o sin26 cos28 2 az qn feos28 —sin20) (cos® —sine BASAL sin2g conve ligne wast! _ [ros(20 +8) ~sin(29 + 6) sin(20+0) cos(20 +0) = [20838 nf! Thats 5 QQ we Ty ™ a Tt Bibel eiu_e a tae on a aE oe 370 see Geert g SEH afer aah a oT 11.9 area Bf 27°C TARR TTS ATE wT ae ET 50% (FHT 60 RTO AEH, Bec rma Sh fins rs eH Solve:n, =1-Z => E = 05 >; = 2 = 600k rig s7 stan, = 1-2 B= =2=750K +. Deora errmtat (750 — 600)K *1 150K sIACe TA (Ans.) PV) e020) | Pa aro2V0) = Ln caer sor eer at ee] ‘Bem eis test ara weerer Beta | [afd re-etans| work done eat received ante, abe ste ert ote or |, fa ETH ab stot aa fee oT be ae wrt IS AT # TROT = day + dQpe = NCAT yy + nC ydTyg MRT yp + 3MRATy¢ = ZAPVy + SAvo2P, = 20 — Po +2@V)—Vy)2h = 2PM Solve: y= ‘FoR = CHIT = (2) — Py) (2Vp — Vo) = PV ane a = 2 x 100% = 15.38% (Ans.) Taya ase as ae ra) andere cae TT OM.Refs aS ArEFA-RORe Stele AGMA FF-09 13, 250°C erratara 2L Treen ef ae “TH 1 mol Np ¢ 3 mol Hy “rr Fem ATaTI7wA 0.6 mol NH am Berg ee | afer H = —92.38 kf mol? em, fait otfort at log Kp Sate cerca ere a Yer CIA Frac ORF PACA? fefeeat No(e) + 3H2(g) = 2NH3(g) Solve: ally (mot): 1 3 0 AtEquilibrium(mol): 1-a 3-30 2a 2a=06.a=03 = 0.22213 ? mol? K¢(RT)*" = 0.22213 x {0.0821 x (250 + 273)?“ 2 Kp = 1.2048 x 104 atm? (Gtosa) © = log(1.2048 x 10 log Kp = 1 * soem * SF 14. A (g) + B(g) 5 2C(g) Altera eee SL srueres we 1203 mol A, 2mol Be 2 mol C emer ffeME Ke = BM, rrr fi Soren We FT | Solve: 4-77, Qe = @ = 0.67 < ke + Rieu sapere , AC) + BC) = 2C(&) Initialphase:3 2 2 Equilibrium: (3x) (2%) (22x) rae? erent # Ke = waar = Gaui EE = 8x? — 40x-4 48 = 4x24 8x +45 x’ = 11,1, feex = 1 eeornam 2. ree [A] = 1ax+11=0 0.4 moll-* 5 24a 5 15, 4L SECT ae tor 2 mol Nz ¢ 5 mol Hy Ce Bee eat wt | Hy ae 25% NH, co afore way, rem faftemiba K, Ree $N2(@) +3 H2(8) + NH3(e) + = 0.2 moll; [C] = 2 = 0.8 moll? 3N2(@) + 3HD(g) = NH3(e) Solve: _ Initially (mol): 2 5 0 AtEquilibrium(mol); 2 3 sia « 5, 5 x 25% = 2.0 = 0.83 ¥ ai (NHS) [= = 1 © Ke= ar = Eaghfacgr Lol = 0362 Lol Ta arte as aster Goo ol aera eT AGT AE.SBA SES TRFA-2023 16. 17, See repr gT-o9 SB CHsCOONa a 20 mL. 0.4M CH3COOH sx comm arr 10 mLOAM HCl on sae pH an fiadawe ear fewer [K, = 1.74 x 1075] Solve: sfve, pH = —log(1.74 x 107 HCI cart sate, HCl + CH3COONa ~ CHjCOOH + NaCl setts pH = §-10x0.1%10-* log(1.74 x 10-5 = EEE) Flop erent = SP + pH wféaés = (5.58 — 5.64) = —0.06 (Ans) 0.25M corer ae Breoenoe sea ae ACNE pH wer Fit eH [Ky = 1.73 X10] Solve: H3A s 3H* +A3- Initial phasesc oo Equilibrium(1-ae 34 at ce leg = BEPIA' _ G00 a TA] ic @ «1a, ky = 2704C? +(e «|i _ &= arcs = arxcoasy = 0-253 + pH = —log(H*] = —log[3aC] = —log(3 x 0.253 x 0.25) = 0.7218 [Ans.] Alternate: Ky wre wer = K, [HA] = (H* BKC «pH = —log(H*] = 0.7217 HPO, so ea, RSs ree yEin FACTOR LETH WHEE, 7.5 X 10-3, 6.2 x 10-8 wee 4.8 x 10-7 | (@) HaPO, frees Reema sere Pt eH ((b) ere FRE SF ATA CAAT FR (c) sfrefoa ae HS, 7 SET GAT AT | Solve: (a) HaPO, > HaPO; + H*;K,, = 7.5 x 10-8 HPO; > HPO} + H*; Ky, = 6.2 x 10-° HPO} — PO} + Ht; K,, = 4.8 x 10719 + HgPO, > PO}” + 3H*;K, = Ka, x Ka, X Ka, = 7.5 x 10-3 x 6.2 x 1078 x 4.8 x 10713 = 2.232 x 10-7? (b) HsPO, com HyPOs © Ht Ber er Boog Ht aasTNCRA ctotcee Mat HyPOg Reareer aTeatE EHR ARTES | ATR | 4 Ka, > Kay > Kay (O)HgPO, ¢ coe err OTA A = +5 H,S0, 4 cet chore wre WH = +6 searing co me Re HT a ae a TER TT PE AT 2 Baquia wa: H,SO, > HPO, Fara aecee ae ation rae 2 oiaetinm ctor Fraga Am.