86 GIAO DUC VA DAO TAO KY THI TUYEN SINH VAO LOP 10 CHUYEN TINH DONG THAP NAM HQC 2020 - 2021 . Bs Mén: HOA HOC bE CHINH THUC Neay thi: 24/7/2020 (Dé gom 6 02 trang) Thdi gan lam ba: 120 pit, ing ké thai gian phat dé Cho nguyén tie khdi: Na =23; Ba =137; Al =27; C Cu 1. (2,0 diém) 1a) Viét cde phuong trinh héa hye hodn thin chudi bién hoa sau: (0; C=12; O=16; H=1; Cl =35,5. FexO; "> FeCh —2> MgC —2-> Mg(OH), —“> MgO b) Viét phuong trinh héa hye cho so dé phan img sau: A1+ NaOH —> CaCO3 + Az + H20 a) A3 + Ag —> BaSO,+As+H20+CO2 (2) Biét Ai, Aa, As, Ag, As déu la cdc mudi tan. 2. a) Cho so dé cate phan ting sau: Xt 5 Xz 2 5X3 8 4 Xq 45 Xp 85 Xp 5 Xy Biét ring X1 dén X¢ déu li cc hgp chat hau co, X1 a tinh b6t hose xenlulozo, Xs la etyl axetat, Xée dinh cong thite héa hge cde chat X2, X3, X4, Xo. rg b) Cho nhém cacbua, etilen, tinh bot va chit béo 6 cOng thite hoa hioe(3{ GIA (CiHs3COO)s trén déu phan tng véi nude 6d thich hop. Viét cdc phuong \* Vat trinh héa hge xy ra. Cfu 2. (2,0 diém) 1. Khong ding thém héa chat nao khdc, hay phn bigt cée dung dich chira trong cae | mit nhan riéng biét: axit axetie, glucozo, natri cacbonat, axit sunfuric, bari clorua. V’ cde phurong trinh héa hge xay ra. 2, Cho cae dung dich mudi v6 co A, B, C, D chia cée géc axit khéc nhau. Biét A va D 1a mudi cia kim loai bari, B va C la mudi cia natri ‘Tin hanh céc thi nghigm - A tde dung véi B tao két tia tring (khéng tan trong nude va axit manh), khi khong mau, khong mdi va nang hon khéng khi - B tac dung voi C thu duge dung dich déng nhat va khi khong mau, mdi hdc, nang hon khong khi ~ A tac dung vi C tao két ta tring tan duge trong axit - D tae dung véi dung dich AgNOs thu duge két tia tring. Xac dinh cng thite héa hg ciia cde dung dich mudi trén. Cu 3. (2,0 diém) 1. a) Khi dun s6i nude giéng (nude cimg) & mét sd ving, lu ngay c6 I6p can dudi day dung cy dun. Giai thich va néu phuong phap lam sach. b) Dé do d9 6 nhiém khng khi tir cde khu cOng nghigp thai ra mdi trudg, tién hanh ly mau khi thai dem phan tich, 06 chia cde khi de sau: COs, $Oz, Ha8. Neu eéch dé logi bo cfc khi trén va viét phuong trinh hoa hoe xay ra (néu 6). 2. a) Cho hinh anh vé céc logi thye vat sau: tS ah A.Caymia —B, Khoailang —C. Nho D. Soi béng Xée dinh hop chat hitu co chinh trong cdc loai thyc vat trén.b) Cho hinh vé m6 ta thi nghiém diéu ché khi Y tir dung dich X (c6 xtc tae thich hgp): Biét Y 1a mot trong cde khi sau: CHa, NH3, HCl, CoH. X la chat hitu co ehinh dé diéu é khi ¥. Xéc dinh X, ¥ va viét phuong trinh héa hoe xay ra, Caiu 4. (2,0 diém) 1. Hén hop X gdm Al, Ba va Na (trong d6, s6 mol Al ban dau gp 2 lin tng sé mol cia hai kim logi Na va Ba). Cho m gam hén hgp X vao nuée du, sau khi phin img hodn toan thu duge 3,584 lit khi Hz, Mat khdc, héa tan hoan toan m gam X bing dung dich NaOH, thu dugc 4,928 lit khi Ho. Biét thé tich cde khi do 6 digu kign tigu chudn, a) Viét cae phuong trinh héa hoe xay ra. b) Tinh m. 2. Diin tir tir CO2 vao 100 ml dung dich Y gdm NaOH x mol/lit, Ca(OH): y mol/lit, Két qua thi nghiém duge biéu dién theo dé thi sau: cl Neaco, 0 0,05 ol Aco, n a) Viét cdc phuong trinh héa hge xay ra. ees b) Tinh gia trj cita x, y Cau 5. (2,0 diém) 1. Sn xudt xi phang tir mt logi chat béo 6 dng thite (CisHs1COO)sCaHs voi dung dich NaOH vira di. Viét phuong trinh héa hoe va tinh khdi Iugng xa phong tgo thanh tir 150 kg béo (chira 19,4% tap chat tro, khong phan img). Biét sy hao hut trong qué trinh sin 20%. 2. Cho rugu X cé cbng thie héa hoc CyHan-iOH. Tién hanh cde thi nghigm sau: = Thi nghiém 1: Cho 7,36 gam rugu X tae dyng voi m gam Na, sau phan tmg duge 1,344 lit khi tb. - Thi nghiém 2: Cho 7,36 gam rurgu X tée dung véi 1,5m gam Na, sau phan tg duge 1,792 lit khi Ha. - Thi nghiém 3: Dun néng 10,8 gam axit axetic v6i 9,2 gam rugu X (xtic tae HoSOx dic), sau mOt thdi gian thu duge 11,88 gam este. Biét thé tich cdc khi do 6 diéu kign tiéu chuan a) Xée dinh céng thie cia rugu X. ‘Tinh higu suat ciia phan tmg este héa. - HET: Ho vd tén thi sinh. S6 béo danh: Chie kj CBCTI: 7 Chit hoy CBCT2:s6 GIAO DUC VA DAO TAO KY THI TUYEN SINH VAO LOP 10 CHUYEN TINH DONG THAP NAM HQC 2020 - 2021 Samael Mén: HOA HOC HUONG DAN CHAM Negay thi: 24/7/2020 (HDC gom c6 05 trang) I. Huéng din chung 1. Néu hoe sinh kim bai Kh6ng theo each néu (rong dp sn nhung ding, chinh xéc, chat che thi cho 2. Vige chi tit hoa (néu c6) thang diém trong hudng din chim phai bio dim khong lam sai Igch huéng din ch4m va phai durgc théng nhat thyc hién trong t6 cham IL Dap 4n va thang diém Cf 1. (2,0 diém) 1. a) Viét cdc phuong trinh héa hgc hoan thanh chudi bién héa sau: Fe304 —Y> FeCh —25 MgCh —°-> Mg(OH): —“-> MgO b) Viét phuong trinh héa hge cho so dé phan img sau: Ai +NaOH —+ CaCO; + A2 +120 (1) Ag+ Ay —> BaSOy + As +120 + CO (2) Biét Ai, Az, As, Ag, As déu la cde mudi tan. 2.a) Cho so ah cac phan img sau: x, — 4X5 8X4 9 9 Xs 2 9 Xo 9-4 Xy f Biét rang x dén Xs déu la cac hop chat hitu co, Xi Li tinh bot hode xenluloze, Xs la AO] cetyl axetat, Xae dinh cdng thie héa hgc cae chat X2, X3, Xa, Xo. b) Cho eae hgp chat sau: nhom cacbua, etilen, tinh b6t va (CHasCOO)3C3Hs. Cae chat trén déu phan img vi nude dis trinh héa hoe xay ra. béo c6 cong thite héa hoe ign thich hgp. Viet cac phuong, NOI DUNG | | prEM | 1. i 1.0 I) r a pera 0,5 (1) FesOs + 81ICI > 2FeCls + FeCh + 4120 0,125 (2) Mg + FeCh -> MeCh+ Fe pve et Mg(OH)2 + 2NaCl 0,125 (4) Mg@H)) —*>MgO + H20 _ 0,125 b) re 05 Ca(HCO,): + 2NaOH > CaCO; + NaxCOs +210 (1) bas Ho&e_Ca(HCOs)2 + NaOH ~» CaCOs + NaHCO3+H20__(1) : 2NaHSOs + Ba(HCOs)2—> BaSOx + NazSO4+ 2H20 + 2CO2 (2) 0.25 2; 1,0 DE 0,5 X X% Xa Xe Celis GHsOH | CHkCOOH | CisCOONa. | 0,125x4 b) Tee Preereeeet 05 AlaCs + 12120 —> 4AIOH)s + 3CHs ai 0.125 Cola + F20 "> CoHsOH 0,125 (-CeHioOs-)p + nO —**> nCalti206 ~0,125 (CiH33COO)3C3Hs + 3H20 3Ci7H33COOH + C3Hs(OH)s 0,125CAu 2. (2,0 diém) 1. Khong ding thém héa chit nao khée, hay phan bigt cée dung dich chita trong cée lo mat nhan riéng biét: axit axetic, glucozo, natri cacbonat, axit sunfuric, bari clorua. Viét cée phuong trinh héa hoe xay ra, 2. Cho cdc dung dich mudi v6 co A, B, C, D chita cée gée axit khée nhau. Biét A va D Ia muéi ca kim logi bari. B va C la mudi cia natri. Tién hanh cdc thi nghiém sau - A tic dung véi B tao két tia tring (kh6ng tan trong mrde va axit manh), khi khong mau, khng mui va ngng hon khong khi. - B tic dung vi C thu durge dung dich déng nhat va khi khdng mau, mii hic, ning hon khong khi. - A tac dung voi C tao két tia tring tan duge trong axit. = D tée dung voi dung dich AgNOs thu duge két tia tring Xée dinh cong thire héa hoe cua cde dung dich mudi trén, NOI DUNG dy mi lo mOt it dem di thir. Lay m@t héa chat lan lugt cho vaio ede mau edn lai két qua ghi theo bang sau: CHsCOOH |_CallizOs | NaxCO3; | HpSO. | BaCh — CHsCOOH sii bot CoH NaxCOs sii bot sii bot Két tia tring k& tha tring 0,125x5 || HeSOa Két tia i] tring dt hign I lan sli bot két ludn axit axetic. - Khong thay hign tong két ludn glucozo. - Néu thdy xudt hign 2 lan sti bot, 1 in két tia tring két lun natri cacbonat. - Néu thay xuét hign 1 Lin sti bot, 1 lan két tia tring két luan axit sunfuric. = Néu thay xudt hign 2 lan két tia tring két lugn bari clorua. if 2CHyCOOH + NayCO; —> 2CHsCOONa + COp + HhO _| 0,125 NagCO3 + HeSO4 —> NapSOs + CO? + H20 coe NaxCO3 + BaCle —> BaCOs + 2NaCl i | H$Ou + BaClh ——> BaSO4 + 2HCL | 0,125 Luu y: Nin biét moi chat la 0,125 diém. Viét ding 3 ~ 4 phuong trinh dat 0,375. 2. 10 ‘A: Ba(HCOs)2 B: NalISOx C:NaxSOs faa D: BaCleCafu 3. (2,0 diém) 1. a) Khi dun s6i nude giéng (nude cimg) 6 mot sé ving, lau ngay c6 Iép can dudi day dung eu dun. Giai thich ya néu phong phap lim sach. b) Dé do dd 6 nhiém khdng khi tir céc khu cng nghigp thai ra m6i trong, tién hanh lay mau khf thai dem phan tich, e6 chita cae khi dc sau: COx, SO2, H2S. Neu cdch dé logi bé cic khi trén va viét phuong trinh héa hoc xay ra (néu ¢6). 2. a) Cho hinh anh vé cdc loai thye vat sau: A. Cay mia B. Khoai lang Cc. Nho D. Soi bong Xée dinh hgp chit hau co chinh trong cae Logi thye vat trén. b) Cho hinh vé mé ta thi nghiém diéu ché khi ¥ tir dung dich X (c6 xite tac thich hgp): Vi trong nude eimg e6 chita mudi Ca(HCOs)2 hove Ma(FCOs)z khi dun sé nhigt | phan tg0 thanh CaCOs hofie MgCOs dang két tiia tring nén c6 lop fin durdi day | 0,25 dung ey dun. | Ca(HCO3)2 —"-> CaCO3 + CO2 + H20 oe Oe eee ee ———— 125 Hoic_Mg(HCOs)) —*-> MgCOs + CO2 + HO Phuong phap lam sach Ip ein nay 14 ding gidm an hoge nude edt chanh 0,125 b) | 6055 Dang héa chat c6 tinh kiém nhu: Ca(OH), NaOH... 1125 CO2 + Ca(OH)2 ——» CaCO; + H20 0,125 SOn + Ca(OH)2 —» CaSOs + HO. poo ed a9. HS + Ca(OH), —> CaS + 210. 0,125 7 5 ad thay Ca(OH)2 bing dung dich bazo khdc trong phwong trink hod hoc. 1,0 a cee a He eee EEE] SHOSS A: sacearoza, B: tinh bat, c 20. 0,125x4 pO Bee EEE eee 0,5 X li CHsOH, Y la CHa 0,125x2 CoHsOH 882" 5 Cola + HO. 0,25CA 4, (2,0 diém) 1. Hin hop X gém Al, Ba va Na (trong 46, sé mol Al ban dau g4p 2 in téng s6 mol cia hai kim loai Na va Ba), Cho m gam hén hgp X vao nuée du, sau khi phan ting hoan toin thu duge 3,584 lit khi Ha, Mat khée, hoa tan hoan toan m gam X bling dung dich NaOH, thu duge 4,928 lit kh Hp. Biét thé tich cée khi do 6 digu kign tiéu chudn, a) Viét cée phuong trinh héa hge xay ra. b) Tinh m 2. Dan tir tir COp vao 100 ml dung dich ¥ gdm NaOH x mol/lit, Ca(OH). y mol/lit. Két qua thi nghiém duge biéu dién theo d6 thj sau: 1a) Viét cde phurong trinh héa hge xéy ra. Neo, b) Tinh gia tr} cia x, y. =A aH S : NOQIDUNG DIEM 1. 10 2Na + 210 —> 2NaOH + Ha Ba + 2120 —> Ba(OH) + Hz 0,125x4 2Al + NaOH + 2H20 —> 2NaAlO2 + 3H 2Al + Ba(OH)2 + 2420 —> Ba(AlOp)2 + 3H na an = 2/3(0,22 -0,16) = 0,04 mol. % at 0,125 Goi xy Hn hrgt [a mol cia Na, Ba OSx+y + 1,5x+3y= 0,16 (1) _, [x= 0,04 0,25 x+2y+0,04 = (x+y) @) ly=0,02 m = 0,04.23 + 0,02.137 + 0,12.27 = 6,9 gam 0,125 2, 2 = ae a 10 a) a i a 0,5 C02 + Ca(OH)2 —> CaCO3 +10 COz + 2NaOH —> NaxCO3 + HbO 0,125x4 C02 + NaxCO3 + HO —> 2NaHCOs C02 + CaCOs + HO —> Ca(HCOs) b) E 0,5 1 caforp, = 0,05 mol. 0,125 ‘C con, = Y = 0,05 mol/lit. = 0,125 0,1 = 2.0,05 - 0,02 + Myson => Nyon = 0,02 mol es tae Cron x= 0,2 mol/lit. 0,125Cafu 5. (2,0 diém) 1, San xudt xa phOng tir mOt loai cht béo c6 cOng thize (CisH3;COO)3C3Hs voi dung dich NaOH vita dit, Viét phutong trinh héa hoe va tinh khéi lugng xa phdng tao thanh tir 150 kg chat béo (chita 19,4% tap chat tro, khong phan ting). Biét sy hao hut trong qué trinh sin xuat 1a 20%. 2. Cho rugu X c6 céng thite héa hoe Calae+1OH. ign hanh ede thi nghiém sau: ‘Thi nghiém 1: Cho 7,36 gam rugu X tae dung véi m gam Na, sau phan tmg duge 1,344 lit khi He. - Thi nghigm 2: Cho 7,36 gam rugu X téc dung véi 1,5m gam Na, sau phan img duge 1,792 lit khi Ho. - Thi nghigm 3: Dun néng 10,8 gam axit axetic dae), sau mOt théi gian thu duge 11,88 gam este. Biét thé tich cde khi do 6 didu kign tigu chuan. a) Xae dinh dng thie cha rugu X. b) Tinh hiéu suat ciia phan img este héa. i 9,2 gam rugu X (xtc tae HoSOu a NOI DUNG i DIEM ae ee z 1,0 (Cistl1COO)3CsHs + 3NAOH ——> 3C1sHsiCOONa + C3Hs(OH)s 0,25 mol chit béo = 152-0:806 _ 9.15 mot 0,25 Khdi lugng xa phong = 0,15.3.278 = 125,1kg : 0,25 H = 80% => Khdi lugng xa phong thyc 1é = 125,1.0,8=100,08kg 0,25 \2 2. ee : 1,0 2, sdnh s6 mol He va khdi lugng Na 6 hai thi nghigm ket luan: % ~ Thi nghiém 1 Na hét 0,25 ~ Thi nghigm 2 rugu hét. 2C,H,,,,ONa +H, ‘Thi nghigm 2; 2+HaOH + 2Na — 2CcHaniONe + Hy 0,125 a aan 0,08 => (14n +18).0,16 => COng thife rugu C,H,OH 0,25 ‘Thi nghiém 3 CH,COOH + C,H,OH === CH,COOC,H, + H,0. 0,125 a 0,18 0,2 0,135 Hl 0,135,100 H=——— = 75% => O18 : peeeeEeeeCee 0,25 | HET-