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1 26-06-2023 Material Safety Data Sheet

Material Safety Data Sheet


Product: ADDNox-FR-910-PT
1. Identification of the substance/ preparation and of the company/ undertaking

Trade name FRP Masterbatch ADDNox-FR-910-PT


Chemical Name Master recipe based on Additives
Company ALOK MASTERBATCHES PVT.LTD
Emergency phone No: 91-11-41612244

2. Composition / Ingredients information.

Main components Polyester Additives


Pigments CAS numbers N/A N/A
Substances presenting a health hazard None to our Knowledge
Chemical family Concentrated mixture of pigments and/or additives
encapsulated during a heat process into a carrier
resin which is then cooled and cut into a granular

3. Hazards Identification:

Main hazards None to our Knowledge


Symptoms related to use. If heated to more than 250 °C
Inhalation The product may form vapours of fumes which
may cause irritation of respiratory tract and cause
coughing and sensation of shortness of breath.

Skin Contact In contact with hot material, may cause severe


thermal bums.

Physico- chemical hazards Combustible if exposed to flames flowing product


can create electrical charge, resulting sparks may
ignite dust or cause an explosion in some
concentration ranges.

4. First Aid Measures:

Route of exposure Exposure to fumes and vapours produced by heated


inhalation or burned product in case of severe exposure to
fumes or vapours move the affected person into fresh
air Get medical advice if the symptoms continue

Skin Contact Exposure to splashing of hot product treat the


affected part with cold water (by spraying or
immersion) no attempt should be made to detach
molten product adhering to the skin or to remove
clothing attached with molten material, the injured
body part would risk being pulled out, usually the
layer detaches itself after a few days.
In case of severe bum, seek medical advice
Eye contact immediately exposure to splashing of hot product
treat the eyes with cold water Seek immediately
special attention at hospital or medical center Fine
dust may cause irritation to ocular mucous. In case
of irritation caused by fine dust: wash with
copious volumes of water, until the irritation
disappears. Ingestion during handling is not likely.

Ingestion In case of ingestion of small quantities, no


import effect observed, in case if ingestion of
larger amounts: abdominal pain, diarrhea..

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5. Fire -fighting measures

Technical measures Stop the fire spreading. Call the fire brigade
immediately. Evacuate non-essential personnel.
Protective clothing, goggles and self-contained
breathing equipment should be made available for
foremen.

Extinguishing media -Suitable Stop the fire spreading. Call the fire brigade
immediately. Evacuate non-essential personnel.
Protective clothing, goggles and self-contained
breathing equipment should be made available for
foremen.

Not to be used Do not use water jets (stick jets) in the early
stages of extinguishing fire since they could help
to spread the flames.

Combustion products Complete combustion, with an excess of oxygen


forms: carbon dioxide and water vapor partial
combustion, forms also : carbon monoxide, soot
and cracked products: aldehydes. Ketones,
hydrocarbons and volatile fatty acids.

Protective equipment for firefighters Wear suitable breathing equipment, in case of risk
of exposure to vapor or fumes.
6. Accidental release measure

See also chapters 8 and 13 after spillage Granules spilled on the floor can cause a risk of
/ leakage- on slipping on smooth surface. Recover the spilled
product by sweeping or suction, put it in
containers to facilitate its disposal.
soil Dispose safely in accordance with local or
national regulations. Prevent the spilled material
from spreading.
In water If the material has been discharged into a stream
or a sewer , inform the authorities of the possible
presence of floating materials. Clean up the water
surface by creaming off debris from the top.
Refer to a specialist for waste disposal in a safe
manner in accordance with local or national
regulations.

7. Handling and Storage

Technical protective measures Handling Storage All pneumatic transport equipment must be
electrically earthed. Store at ambient temperature
and at atmospheric pressure in original packaging
(plastic or cardboard boxes) or in silo made
appropriate material aluminium, stainless steel,)
Do not store near highly flammable materials,
store away from heating source, avoid static
electricity build up with connection to earth. Store
in dry, well –ventilated area. Avoid dust
accumulation by use of filters in the pneumatic
transport equipment

(VbF- Klasses Germany ) see also chapter 8 Not applicable

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8. Exposure controls / personal protection:

Respiratory protection In case of risk of overexposure to dust, vapor or


fumes (during product processing) it is
recommended that a local exhaust system is
placed above the conversion equipment (a fume
hood) and the working area must be properly
ventilated.

Skin protection If contact with hot materials is possible, wear


heat-insulating and chemical proof gloves as well
as a face shield.
Eye protection When the splashing of molten droplets may occur,
Other personal protection wearing goggles / spectacles
Safety non-slip shoes in areas where spills or
leaks can occur

9. Physical and Chemical properties


Appearance Granules
Physical state at 20 oC Granules
Melting range(oC) Related to polymer using (250⁰C)
Flash Point (ASTM D 1929) (o C) >340
Auto ignition temperature (o C) >350
Explosion Limits )kg/ ( M 3 ) -lower 0.015 (for polymer dust <100 urn)
Mm ignition energy at 20o C (mJ) N/A
Vapor pressure at 20o C (hPa) N/A
Solubility in water (% weight) Insoluble
Viscosity (mmÙ s) N/A

10 Stability and reactivity

Stability Stable under operating conditions


Conditions to avoid Avoid contact with strong oxidizing materials and
fluorine. Avoid proximity or contact with flames
or sparks. do not heat to temperatures exceeding
300oC.

Hazardous reactions Referring to point No3

Advice to prevent explosion Avoid dust accumulation by use of filters in the


pneumatic transport equipment. Thoroughly
ventilate the working place. Use explosion proof
electrical equipment. All conductive materials
must be electrically earthed. In case of pneumatic
alimentation, feed the extruders by aspiration. Use
nitrogen as carrier gas.

11. Toxicological information

Symptoms related to use inhalation Low risk for temperatures below 40oC
If heated more than the heat stability (TDS), the
product may form vapours or fumes which may
cause irritation of respiratory tract and cause
coughing and sensation of shortness of breath.
Dust may cause irritation on respiratory system.

Skin Contact No risk for temperatures below 40oC. in contact with


hot material, may cause severe thermal bums.
Eye Contact Fine dust may cause irritation to ocular mucous.
Splashing of molten droplets cause ocular tissues injury

Ingestion Minimal toxicity

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Rat oral LD50 (mg/Kg) No Information

Carcinogenicity IARC (International Agency on Research on


Cancer): category 3 the agent is not classifiable as

12. Ecological information

Information on ecological effects Avoid losses to the environment whenever possible.


Air There is a slow loss by evaporation.
Mobility The product generally has a low soil mobility.
Water The product should not be dangerous for aquatic life.
Persistence and degradability Persistent in the environment.
Biodegradation This substance is non-biodegradable.
Bio accumulative potential Bioaccumulation in environment is very low
Ecotoxicity Non ecotoxic
BOD 5 Below the detection limit

13. Disposal Considerations


Disposal According to local regulations
Authorized disposal. As refuse
For reprocessing
Do not dispose off by means of sinks, drains or
into the immediate environment may be used as
fuel in suitably designed installations. Incinerate
with household refuse in a municipal solid waste
incinerator plan.
Industrial waste number symbol Referring to Polymer (TDS)
14. Transportation Information

Road (ADR) / Rail (RID). ADNR Not restricted for transport


Marine (IMO- IMDG Airline Not restricted for transport
(ICAO/ IATA) Not restricted for transport

15. Regulatory information


EU Norms Complying the RoHS Norms

16. Other information

Further information No information available

Revised: 01.04.2020
This data sheet conforms to standards defined by directives 91/155 & 93/112/EEC

IMPORTANT:

The information in this Data Sheet applies only to the products designated herein and produced or supplied by us it is
based on our experience and on the data available to us at the time of its issue and is accurate to the best of our
knowledge. The customer is strongly advised to observe and ensure that its employees and customers observe all
direction contained herein. However, no warranty is made or implied that the information is accurate or complete and
no liability will be accepted whatsoever arising out of the use of the information or the products designated herein .
Where third party products are used in conjunction with or instead of products produced or supplied, customers should
themselves obtain all necessary technical, health and safety information about such product from the third party.
ALOK MASTERBATCHES PVT.LTD
S-14, SIPCOT Industrial Complex, Phase-3
Mukundarayapuram, Ranipet-632405, Vellore Dist. Tamilnadu
Phones- 7094400118
e-mail:qaattd@alokindustries.com

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