Haloalkanes and Haloarenes +2 Chemistry Test Dashmesh Academy

1 Mark MM. 25
1. Write the structural formula of 4-chloro-2-pentene.

2. How will you obtain 1-bromopane from propene ?

3. Arrange the following in order of increasing boiling point.

(i) CH3 CH2 CH2 CH2 Br (ii) (CH3)3 CBr (iii) (CH3)2 CH CH2 Br

4. What happens when CH3 – Br is treated with KCN ?

5. What do you understand by nucleophilic substitution reaction ?

2 Marks
1. Write two differences between SN1 and SN2 reactions.

2. Write major product

(a) CH3 CH2 CH2 OH + SOCl2 ⟶

(b) CH3 CH = CH2 + H Br

3. Give brief account with one example of each.

(i) Markonikov’s rule (ii) Karasch effect (iii) Swarts reaction (iv) Sandmeyer (v) Balz – Schieman

Reaction 5

4. Write Reaction.

(a) Dow’s process (b) Friedel – crafts alkykation (c) Wurtz – fitting reaction 3

5. Write use of each of following

(a) Chloroform (b) Iodoform (c) DDT 3

6. Why are haloarene less reactive than haloalkanes towards nucleophilic Subs Reaction ? 3

7. Convert

Aniline to Chlorobencene 2