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MATHEMATICS
1. If ( x x 1) is a factor of f(x)= ax3 bx 2 cx d where a 0 and a,b,c,d are real, then
2
1 3i
2. If is a root of the equation x 4 x3 x 1 0 then its real roots are
2
1)1,1 2)-1,-1 3)1,2 4)1,-1
3. If the sum of two roots of the equation x 4 px 3 qx 2 rx s 0 equals to the sum of the
1 1 3 1
1) 2) 3) 4)
10 5 10 2
6. If (x)=0 has a repeated root " " , then another equation having " " as root is
1)f(2x)=0 2)f(3x)=0 3) f 1 ( x) 0 4) f 11 ( x) 0
7. Statement-I-The equation of lowest degree with rational coefficients, one of whose roots is
7 3 is x 4 20 x 2 16 0
Statement-II-The equation of lowest degree with rational coefficients. One of whose roots is
2 i 3 is x 4 2 x2 25 0
1)only I is true 2)only II is true 3)both I and II are true 4)neither I nor II true
8. If the roots of ax3 bx2 cx d 0 are in H.P. then the roots of dx3 cs 2 bx a 0 are in
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1)A.P. 2)G.P. 3)H.P. 4)A.G.P.
9. If f(x)=0 is a R.E. of second type and seventh degree then a factor of f(x) is
1)x-2 2)x-1 3)x 4)x+1
2 4 1 3 x 1
10. The transformed equation of x x 0 with integral coefficeients and
3 4 768 256
unity for the coefficient of the first term is
1) x4 3x3 x 1 0 2) x4 3x3 x 1 0
3) x 4 3x3 x 24 0 4) x4 3x3 x 1 0
11. Assertion(A):One root of x3 2 x2 1 0 lies between 2 and 3
Reason(R ):If f(x) is continuous function and f(a),f(b),have opposite signs then atleast one
(or) odd number of roots of f(x) =0 lies between a and b
1)Both A and R are true and R is the correct explationa of A
2)Both A and R are true but R is not the correct explanation of A
3)A is true but R is false
4)A is false but R is true
2
3
12. The degree of the equation x 2 2 (3 x 1)2 is
1)3 2)4 3)5 4)6
13. Number of positive roots of x 4 3x3 2 x 2 3 0 is
1)zero 2)2 3)1 4)3
14. If , , , are the roots of x 4 x3 7 x2 x 6 0 then 4 4 4 4
1)99 2)101 3)100 4)98
15. For ABC , , R, r , r1 , r2 , r3 , s have the usual meanings, then if the cubic equation with roots
r1 , r2 , r3 is x3 lx 2 mx n 0 , then l
1) (4 R r ) 2) 1 r / R 3) 2( R r ) 4) (4R r )
2 3 is
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1) x2 x 1 0 2) x2 x 1 0 3) x2 x 1 0 4) x2 x 1 0
19. Origin is the centre of circle passing through the vertices of an equilateral triangle whose
median is of length 3a then equation of the circle is
1) x 2 y 2 a 2 2) x 2 y 2 2a 2 3) x 2 y 2 3a 2 4) x 2 y 2 4a 2
20. The diameters of a circle are along 2x+y-7=0 and x+3y-11=0.Then the equation of this
circle which also passes through (5,7) is
1) x 2 y 2 4 x 6 y 16 0 2) x 2 y 2 4 x 6 y 20 0
3) x 2 y 2 4 x 6 y 12 0 4) x 2 y 2 4 x 6 y 12 0
21. Centre and radius of the circle with segment of the line x+y=1 cut off by coordinate axes as
diameter is
1 1 1 1 1 1 1 1 1 1 1 1
1) , , 2) , , 3) , , 4) , ,
2 2 2 2 2 2 2 2 2 2 2 2
22. The abscissae of two points A and B are the roots of the equation x2 2ax b2 0 and their
ordinates are the roots of the equation y 2 2 py q 2 0 then the radius of the circle with
AB as diameter is
1) a 2 b 2 p 2 q 2 2) a2 p2 3) b2 q2 4) a 2 b2 p 2 q2
23. The equation of the image of the circle x 2 y 2 6 x 4 y 12 0 by the mirror x+y-1=0 is
1) x 2 y 2 2 x 4 y 4 0 2) x 2 y 2 2 x 4 y 4 0
3) x 2 y 2 2 x 4 y 4 0 4) x 2 y 2 2 x 4 y 4 0
24. The line x+y=1 cuts the coordinate axes at P and Q and a line perpendicular to it meet the
axes in R and S.The equation to the locus of the point of intersection of the lines PS and QR
is
1) x 2 y 2 1 2) x 2 y 2 2 x 2 y 0
3) x 2 y 2 x y 0 4) x 2 y 2 x y 0
25. A chord of length 24 units is at a distance of 5 nits from the center of a circle then its radius
is
1)5 2)12 3)13 4)10
26. If the chord y=mx+1 of the circle x 2 y 2 1 subtends an angle of measure 450 at the major
segment of the circle then m=
1)-1 2)-2 3)-4 4)-8
27. If a straight line through C ( 8, 8) making an angle 1350 with the x-axis and cuts the
circle x 5cos , y 5sin in points A and B then AB=
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1)5 2)10 3)15 4)20
2a(1 t 2 ) 4at
28. The parametric equations x and y represents a circle whose radius is
1 t 2
1 t2
1)a 2)2a 3)3a 4)4a
29. If y=3x is a tangent to a circle with centre (1,1) then the other tangent drawn through (0,0)
to the circle is
1)3y=x 2)y=-3x 3)y=2x 4)3y=-2x
30. ‘O’ is the origin and Ak ( xk , yk ) where k= 1,2 are two points. If the circles are described on
OA1 and OA2 as diameters, then the length of their common chord is equal to
1 1 x1 y2 x2 y1
1) x1 y2 x2 y1 2) x1 y2 x2 y1 3) A1 A2 4)
2 2 A1 A2
31. If the line y=x touches the circle x 2 y 2 2 gx 2 fy c 0 at P where OP= 6 2 then c=
1)72 2)36 3)108 4)130
32. The condition that the pair of tangents drawn from origin to circle
x 2 y 2 2 gx 2 fy c 0 may be at right angle is
1) g2 f 2 c 2) g 2 f 2 2c 3) g 2 f 2 2c 0 4) g 2 f 2 2c
33. The locus of the point of intersection of the two tangents drawn to the circle x 2 y 2 a 2
which include and angle is
1) x 2 y 2 a 2 cos ec 2 / 2 2) x 2 y 2 a 2 cot 2 / 2
3) x 2 y 2 a 2 tan 4) x 2 y 2 a 2 tan / 2
34. The locus of the point of intersection of the tangents to the circle x r cos , y r sin at
the points whose parametric angles differ by is
3
1) x 2 y 2 r 2 2) x 2 y 2 2r 2 3) 3( x 2 y 2 ) 2r 2 4) 3( x 2 y 2 ) 4r 2
35. The circle with centre (4,-1) and touching x-axis is
1) x 2 y 2 8 x 2 y 16 0 2) x 2 y 2 18 x 2 y 16 0
3) x 2 y 2 4 x y 4 0 4) x 2 y 2 14 x y 4 0
36. The intercept made by the circle with centre (2,3) and radius 6 on y-axis is
1) 18 2 2) 12 2 3) 8 2 4) 6 2
37. The centre of the circle passing through origin and making intercepts 8 and -4 on x and y-
axes respectively is
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1)(4,-2) 2)(-2,4) 3)(8,-4) 4)both (1) & (2)
38. If the line hx+ky=1/a touches the circle x 2 y 2 a 2 then the locus of (h,k) is circle of
radius
1 1
1) 2) a2 3)a 4)
a a2
39. If a circle of radius 2 touches X-axis at (1,0) then its centre may be
1)(1,2)(1,-2) 2)(1,2(2,1) 3)(-1,2)(1,-2) 4)(-1,2)(-1,-2)
x y
40. Radius of a circle which touch the both axes and the line 1 being the centre lies in
a b
first quadrant
ab ab ab ab
1) 2 2
2) 3) 4)
a b ab a b ab a b a 2 b2 a 2 b2 a 2 b2
41. Pole of diameter of a circle w.r.to the same circle lies
1)inside of the circle 2)outside of the circle 3)on the circle 4)Does not exist
Q.The tangents of this circle at P,Q meet on the circle x 2 y 2 b 2 then the equation of
concentric circle is
a
1) x 2 y 2 a 2 b 2 2) x 2 y 2 ab 3) x 2 y 2 a 2 b 2 4) x 2 y 2
b
44. The pair of tangents from origin to the circle x 2 y 2 4 x 2 y 3 0 is
1) (2 x y ) 2 3( x 2 y 2 ) 2) (4 x 2 y )2 3( x 2 y 2 )
3) (2 x y ) 2 3( x 2 y 2 ) 4)not existing
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1 1 1 1 1 1 1 1
1) , 2) , 3) , 4) ,
2 2 2 2 2 2 2 2
49. The centre of the circle circumscribing the square whose three sides are
3x y 22, x 3 y 14 and 3x y 62 is:
3 27 2
1) , 2) (16, 6) 3) (27,3) 4) (1, )
2 2 3
50. If the points (0,0),(2,0),(0,-2),and (k,-2) are concylic then k=
1)1 2)2 3)3 4)4
51. A square is inscribed in the circle x 2 y 2 2 x 8 y 8 0 whose diagonals are parallel to
axes and a vertex in the first quadrant is A then OA is
1)1 2) 2 3) 2 2 4)3
52. ABCD is square of unit area.A circle is tangent to two sides of ABCD and passes through
exactly one of its vertices.The radius of the circle is
1 1
1) 2 2 2) 2 1 3) 4)
2 2
53. The circles x 2 y 2 2 x 4 y 20 0 , x 2 y 2 4 x 2 y 4 0 are
1)one lies out side the other 2)one lies completely inside the other
3)touch externally 4)touch internally
54. The external centre of similitude of the circle x 2 y 2 12 x 8 y 48 0 and
1) x 2 y 2 2a 2 2) x 2 y 2 4a 2 3) x 2 y 2 3a 2 4) x 2 y 2 a 2
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59. Locus of the point of intersection of perpendicular tangents to the circle x 2 y 2 10 is
1) x 2 y 2 5 2) x 2 y 2 20 3) x 2 y 2 10 4) x 2 y 2 100
60. Two rods of lengths ‘a’ and ‘b’ slide along coordinate axes such that their ends are
concylic.Locus of the centre of the circle is
1) 4( x 2 y 2 ) a 2 b 2 2) 4( x 2 y 2 ) a 2 b 2
3) 4( x 2 y 2 ) a 2 b 2 4)xy=ab
61. If radii of two circles are 4 and 3 and distance between centres is 37 then angle between
the circles is
1) 300 2) 450 3) 600 4) 900
62. Two circles of radii r and R intersect at an acute angle .The length of their common chord
is
2rR sin 2rR sin
1) 2)
2 2
r R 2rR cos r 2 R2
2rR sin 2rR sin
3) 4)
2 2
R r r R 2 2rR cos
2
( x 1)2 ( y 1)2 25 is
1)0.25 2)0.10 3)0.50 4)0.60
65. The perpendicular distance from the origin to the radical axis of the circles
2 x 2 2 y 2 3 x y 3 0 and 3 x 2 3 y 2 x y 1 0 is
11 5 5
1) 2 2) 3) 4)
74 2 2
66. (a,c) and (b,c) are the centres of two circles whose radical axis is the y-axis.If the radius of
first circle is r then the diameter of the other circle is
1) 2 r 2 b 2 a 2 2) r 2 a2 b2 3)( r 2 b2 a2 ) 4)( r 2 a 2 b2 )
67. The number of points such that the tangents from it to three given circles are equal in
length, is
1)1 2)2 3)3 4)4
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68. If S1 0, S 2 0 and S3 0 are the three circles whose radical centre is the point P, then the
lengths l1 , l2 , l3 of the tangents from P to the three circles are such that
1) l1 2l2 3l3 2) l1 l2 l3 3) l1 l2 l3 4) l1 l2 l3
x 2 y 2 2 x 3 y 9 0 is
1)(2,3) 2)(3,2) 3)(-2,3) 4)(-3,-2)
70. A:The radical centre of the circles x 2 y 2 4, x 2 y 2 3x 4, x 2 y 2 4 y 4 is (0,0)
R:Radical centre of three circles is the point of concurrence of the radical axes of the circles
taken in pairs
1)Both A and R are true and R is the correct explanation of A
2)Both A and R are true but R is not the correct explanation of A
3)A is true but R is false
4)A is false but R is true
71. In (n 3) circles the centres of no three circles are collinear.If the number of the radical
axes of the circles is equal to the number of the radical centres of the circles then
n2 4n 5
1)0 2)1 3)2 4)3
72. If Q is the radical centre of the three circles x 2 y 2 a 2 , ( x g )2 y 2 a 2 and
x 2 ( y f ) 2 a 2 then Qx Qy
g f g f
1)g+f 2) 3) 2 g 2 f 4)
2 2
73. A,B,C are the centres of three circles which cut each other orthogonally.The radical centre
of the three circles is…… of the ABC
1)Incentre 2)centroid 3)Ortho centre 4)Circum centre
74. If a b then the length of common chord of the circles ( x a )2 ( y b)2 c 2 and
( x b) 2 ( y a) 2 c 2
1) 4c 2 2(a b)2 2) c 2 ( a b) 2 3) 3c 2 (a b) 2 4) 2c 2 ( a b ) 2
75. If 3,4 are the radii and 5 is the distance between the centres of two intersecting circles then
the length of the common chord of the circles is
1)4.8 2)5.2 3)6.2 4)7.8
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76. x 2 y 2 a 2 and ( x c)2 y 2 b 2 are two intersecting circles.If a,b,c are the sides
BC,CA,CA of ABC .If p1 , p2 , p3 are the altitudes through A,B,C respectively then the
x 2 y 2 2 g1 x 2 f1 y c1 0 then
1) 2 g1 ( g g1 ) 2 f1 ( f f1 ) c c1 2) 2 g1 ( g g1 ) 2 f1 ( f f1 ) c c1 0
3) g1 ( g g1 ) f1 ( f f1 ) c c1 4) 2 g ( g g1 ) 2 f1 ( f f1 ) c c1
78. B and C are points on the circle x 2 y 2 a 2 , A point A(b,c) lies on that circle such that
AB=AC=d.The equation to BC is
1) bx ay a 2 d 2 2) bx ay d 2 a 2 3) bx cy 2a 2 d 2 4) 2(bx cy ) 2a 2 d 2
1) 5 2) 7 3) 2 5 4) 4 5
PHYSICS
2
81. In the equation y A sin x bt
a
1)speed of wave is a 2)speed of wave is b
3)wavelength of wave is a/b 4)wavelength of wave is b/a
3 1
82. Two sound waves are represented by y1 sin t cos t and y2 sin t cos t
2 2
The ratio of their amplitudes is
1)1:1 2) 3 : 2 3) 2 : 3 4) 2 :1
83. A wave has a frequency of 120 Hz. two points at a distance of 9m apart have phase
difference of 10800. The velocity of the wave is
1)340 m/s 2)300 m/s 3)330 m/s 4)360 m/s
84. If Young’s modulus of the material of a rod is Y and density is then time taken by sound
wave to travel l length from bottom is
Y 1 Y 1
1) l 2) l 3) 4)
Y l l Y
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85. The equation of a wave on a string of linear mass density 0.04 kg m 1 is given
t x
y 0.02 sin 2 , the tension in the string is
0.04( s) 0.50(m)
1)6.25N 2)4.0 N 3)12.5 N 4)0.5 N
86. Two waves are approaching each other with a velocity of 20 m/s and frequency n.The
distance between two consecutive nodes is
20 10 5 n
1) 2) 3) 4)
n n n 10
87. In a stationary wave along a string the strain is
1)zero at the antinodes 2)maximum at the antinodes
3)zero at the nodes 4)maximum at the nodes
88. A string length ‘ l ’ is fixed at both ends.It is vibrating in its 3rd overtone with maximum
amplitude ‘a’. The amplitude at a distance l /3 from one end is
3a a
1)a 2)0 3) 4)
2 2
89. The fundamental frequency of a stretched string with a weight of 9 kg is 289 Hz.The weight
required to produce its octave is
1)9 kg wt 2)16 kg wt 3)25 kg wt 4)36 kg wt
90. A knife-edge divides a sonometer wire into two parts.The fundamental frequencies of the
two parts are n1 and n2 .The fundamental frequency of the sonometer wire when the knife-
edge is removed will be
1 n1n2
1) n1 n2 2) n1 n2 3) n1n2 4)
2 n1 n2
91. The ratio of speed of sound in Nitrogen gas to that in Helium gas at 300 K is (assume both
gases to be ideal)
1) 2 : 7 2) 1: 7 3) 3 : 5 4) 6 : 5
92. sound signal is send through a composite tube as shown in figure.The radius of the
semicircle is r.Speed of sound in air is V.The source of sound is capable to generate
frequencies in the range f1 to f 2 ( f 2 f1 ) .If n is an integer then frequency for maximum
intensity is given by
nV nV nV nV
1) 2) 3) 4)
r r ( 2) r (r 2)
93. An open pipe length ‘ l ’ vibrates in fundamental mode.The pressure variation is maximum at
1)1/4 from ends 2)the middle of pipe
3)the ends of pipe 4)1/8 from ends of pipe
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94. A cylindrical resonance tube open at both ends has a fundamental frequency ‘f’ in air.If half
of the length is dipped vertically in water, the fundamental frequency of the air column will
be
1)f/2 2)f 3)3f/2 4)2f
95. A closed organ pipe is vibrating in first over tone and is in resonance with another open
organ pipe vibrating third harmonic.The ratio of lengths of the pipes respectively is
1)1:2 2)4:1 3)8:3 4)3:8
96. The frequency of B is 3% greater than that of A.The frequency of C is 2% less than that of
A.If B and C produce 8 beats/s,then the frequency of A is
1)136 Hz 2)168Hz 3)164Hz 4)160 Hz
97. When a source moves away from stationary observer with velocity v then apparent change in
frequency is n1. When an observer approaches the stationary source with same velocity v
then change in frequency is n2 . then
n1
1) n1 n2 2) n1 n2 3) n1 n2 4) 1
n2
98. A vehicle, with a horn of frequency n is moving with a velocity of 30 m/s in a direction
perpendicular to the straight line joining the observer and the vehicle.The observer perceives
the sound to have a frequency n n1 .If the velocity of sound in air is 300 m/s, then
1) n1 10n 2) n1 0 3) n1 0.1n 4) n1 0.1n
99. A rod PQ of length ‘L’ is hung from two identical wires A and B.A block of mass ‘m’ is
hung at point R of the rod as shown in figure.The value of ‘x’ so that the fundamental mode
in wire A is in resonance with first overtone of B is
4L L L 2L
1) 2) 3) 4)
5 4 5 3
100. An open pipe resonates to a frequency f1 and a closed pipe resonated to a frequency f 2 .If
they are joined together to form a longer tube, then it will resonate to a frequency of (neglect
end corrections)
f1 f 2 f1 f 2 2 f1 f 2 f 2 f2
1) 2) 3) 4) 1
2 f 2 f1 f 2 2 f1 f 2 f1 f1 f 2
101. Two charges are separated by a distance 1m. When a dielectric slab of thickness 40cm is
introduced between them, the force becomes half its previous value.The dielectric constant
of medium is
1)2 2)4 3)6 4)8
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102. Electrical force between two point charges is 200 N.If we increase 10% charge on one of the
charges and decrease 10% charge on the other, then electrical force between them for the
same distance becomes
1)198 N 2)100 N 3)200 N 4)99 N
103. N fundamental charges each of charge ‘q’ are to be distributed as two point charges
separated by a fixed distance, then the maximum to minimum force bears a ratio (N is even
and greater than 2)
2
1)
N 1 2)
4N 2
3)
N2
4)
2N 2
4N 2 ( N 1) 4( N 1) ( N 1)
104. Two point charges Q and -3Q are placed some distance apart. If the electric field at the
location of Q is E , the field at the location of -3Q is
E E
1) E 2) E 3) 4)
3 3
105. Two point charges of magnitude 4 C and -9 C are 0.5m apart.The electric intensity is
zero at distance ‘x’ m from A’ and ‘y’ m from ‘B’.’x’ and ‘y’ are respectively
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8Q 4Q 4Q 2Q
1) 2) 3) 4)
0 a 4 0 a 3 0 a 0 a
111. A hollow metal sphere of radius 5cm is charged such that the potential on its surface is
10V.The potential at the centre of the sphere us
1)0 V 2)10V
3)same as at point 5cm away from the surface
3)sane as at point 25cm from the surface
112. An electric field is expressed as E 2 i 3 j . The potential difference (VA VB ) between two
points A and B rA i 2 j and rB 2 i j 3 k is __________ V
1)-1 2)-2 3)+1 4)+2
113. The dipole moment of the given system is
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119. The potential at a point x(measured in m )due to some charges situated on the x-axis is
20 V
given by V ( x) volt.The electric field E at x=4 m is given by ________
2
in the
x 4 m
positive x-direction
1)1.11 2)2.34 3)1.81 4)1.61
2 2
120. V 2 x y , the shape of equi potential surface is _________
1)ellipse 2)circle 3)straight line 4)parabola
CHEMISTRY
121. Which of the following solutions in water will have the lowest vapour pressure
1) 0.1M NaCl 2) 0.1M sucrose
122. 10.0 g of glucose 1 , 10.0 g of urea 2 , and 10.0 g of sucrose 3 , are dissolved in
124. The dichromate ion oxidises stannous ions in solutions according to the reaction
3Sn 2 14 H Cr2O72 3Sn 4 2Cr 3 7 H 2 O
How many ml of K 2Cr2 O7 solution of 0.5 M strength will be required to completely react
acid medium is
1)100ml 2)50ml 3)20ml 4)4ml
126. Two elements A and B form compounds of formula AB2 and AB4 .When dissolved in
20.0 g of benzene 1.0 g of AB2 lowers F.Pt. by 2.30 C whereas 1.0 g AB4 lowers F.pt. by
1.30 C. The K f for benzene is 5.4.The atomic masses of A and B are respectively.
Page 14
1) 210.0g mol 1 2) 90.0g mol 1 3) 115.0g mol 1 4) 105.0g mol 1
128. Calculate the amount of ice that will separate out on cooling containing 50g of ethylene
glycol in 200g of water to 9.30 C ( K f for water =1.86K mol 1kg )
132. The freezing point of equimolal aqueous solution will be highest for
1) C6 H 5 NH 3Cl (aniline hydrochloride) 2) Ca( NO3 )2
133. The depression in freezing point of 0.01 m aqueous solution of urea,sodium chloride and
sodium sulphate is in the ratio:
1)1:1:1 2)1:2:3 3)1:2:4 4)3:2:1
134. The Van’t Hoff factor for 0.1 M Ba( NO3 )2 solution is 2.74. The degree of dissociation is
Page 15
mole of B is added to this solution, the vapour pressure of the solution increases by 10 mm
Hg. Determine the vapour pressure of A and B in their pure states (in mm Hg)
1)400,600 2)500,500 3)600,400 4)None of these
136. At a given temperature, total vapour pressure (in torr)of a mixture of volatile componds A
and B given by Ptotal 120 75 X B Hence,vapour pressure of pure A and B respectively (in
torr) are
1)120,75 2)120,195 3)120,45 4)75,45
137. A mixture contains 1 mole of volatile liquid A ( PA0 100 mm Hg ) , and 3 moles of volatile
liquid B ( PB0 80 mm Hg ) ,If solution behaves ideally, the total vapour pressure of the
distillate is
1)88 mg Hg 2)85.88mm Hg 3)90mm Hg 4)92mm Hg
138. Relative lowering in vapour pressure of a solution containing 1 mole K 2 SO4 in 54 g H 2O
1 3 3 1
1) 2) 3) 4)
55 55 4 2
139. CH 3CN 2 H 2O X NH 3
The density of a 2M solution of X in water is 1.017 g/ml. The molality of the solution is
1)2 2)1.55 3)2.26 4)1.25
140. Blood cells are isotonic with 0.9% w/v NaCl solution.When blood cells are kept in 1% w/v
NaCl solution
1)water flows into blood cells and cause plasmolysis
2)water flows into blood cells and cause haemolysis
3)water comes out from the blood cells and cause plasmolysis
4) water comes out from the blood cells and cause haemolysis
141. The rate of formation of SO3 in the reaction 2SO2 O2 2SO3 is 100 g min 1 , Hence rate
of disappearance of O2 is
142. In the process 2 N 2O5( g ) 4 NO2( g ) O2( g ) at t=10 rate of reaction w.r.t N 2 O5 NO2 & O2
respectively are
N 2O5 NO2 O2
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2) 1000mm/min 1000mm/min 500mm/min
3) 1000mm/min 2000mm/min 4000mm/min
4) 400mm/min 400mm/min 400mm/min
d
143. For N 2 O5 2 NO2 1/ 2O2 , it is found that N 2O5 K1 N2O5
dt
d d
NO2 K 2 N 2O5 ; [O2 ] K3[ N 2O5 ] then
dt dt
1) K1 2 K 2 3K 3 2) 2 K1 4 K 2 K 3 3) 2 K1 K 2 4 K 3 4) K1 K 2 K 3
O O3 2O2 ( slow)
145. xA yB zC
d [ A] d [ B] d [C ]
If 1.5 then xy and z are
dt dt dt
1)1,1,1 2)3,2,3 3)3,3,2 4)2,2,3
146. The initial rates for gaseous reaction A 3B AB3 are given below
Is given as rate = K [CH 3COOC2 H 5 ][ NaOH ]. If three times water is added to the reaction
mixture, the rate of the reaction compared to the original rate will be
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1 1 1
1) rd 2) th 3) th 4)16 times
3 9 16
149. In 69.3 min,a first order reaction is 50% complete.How much reactants are left after 161
min?
1)80% 2)40% 3)20% 4)60%
150. Half-life periods for a reaction at initial concentrations of 0.1 M and 0.01 are 5 and 50
minutes respectively.Then the order of reaction is
1)zero 2)1 3)2 4)3
151. Give the following data for the reaction: X Y Z
Page 18
156. The rate constant ( K1 ) of one reaction is found to be double that of the rate constant of ( K 2 )
another reaction.Then the relationship between the corresponding activation energies of two
reactions( E1 and E2 )can be represented.
1) E1 E2 2) E1 E2 3) E1 E2 4) E1 4 E2
157. At 300 K rate constant for A products at t 50min is 0.02 s 1 , then 310 K will be
(in s 1 )
0.04 0.02
1) 2) 0.04 25 3) 0.04 4)
25 25
158. The rate constant of a reaction at temperature 200K is 10 time less than the rate constant at
400K.What is the activation energy ( Ea ) of the reaction ?(R=gas constant)
160. consider a first order gas phase decomposition reaction given below A( g ) B( g ) C ( g )
The initial pressure of the system before decomposition of A was p1 after lapse of time ‘t’.
total pressure of the system increased by x units and became p1 .The rate constant k for the
reaction is given as
2.303 p1 2.303 p1
1) k log 2) k log
t p1 x t 2 p1 pt
2.303 p1 2.303 p1
3) k log 4) k log
t 2 p1 pt t p1 x
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