t min Ca, mol/It Orden 0 Orden 1 Orden 2 Orden 2.5 Orden 0.5 Orden 1.

5
0 0.195 0 0 0 0 0 0
5 0.17 -0.025 -0.13720112 0.75414781 22.892528 0.05855496 0.32160436
10 0.145 -0.05 -0.29626582 1.7683466 64.3842296 0.12159878 0.72314918
15 0.12 -0.075 -0.48550782 3.20512821 147.946555 0.19035576 1.24439456
20 0.105 -0.09 -0.61903921 4.3956044 242.991186 0.23510202 1.64302586
25 0.09 -0.105 -0.77318989 5.98290598 412.292691 0.28317609 2.13755853
30 0.075 -0.12 -0.95551145 8.20512821 745.168777 0.33545353 2.7738593
35 0.065 -0.13 -1.09861229 10.2564103 1168.82168 0.37327414 3.31553727
40 0.055 -0.14 -1.26566637 13.0536131 1958.55146 0.41413451 3.99892052
45 0.045 -0.15 -1.46633707 17.0940171 3613.02429 0.45891202 4.89898228

ORDEN 1
Orden 2 k=-0.0323
18
16
14 f(x) = 0.362387915661012 x − 1.68219794220163
Orden
R² = 0.949051540142468
12 4000

10 3500
8 3000
6
2500
4 f(x) = 64.909074550698
2000
2 R² = 0.72107614866241
1500
0
0 5 10 15 20 25 30 35 40 45 50
1000

500

0
0 5 10 15 20

Orden 1.5
6

f(x) = 0.106517479922494 x − 0.290940113062985

4 R² = 0.983974216183347

0
0 5 10 15 20 25 30 35 40 45 50
 Orden 3
0
Orden 0
4.15179414
0
10.6319689 0 5 10 15 20 25 30 35 40 45 50
21.5729783 -0.02 f(x) = − 0.00327878787878788 x − 0.0147272727272727
32.20223 R² = 0.966029976268513
-0.04
48.5791511
75.739645 -0.06
105.193951 -0.08
152.140012
-0.1
233.764336
-0.12

-0.14

-0.16

Orden 2.5 Orden 0.5

0.5
0.45 f(x) = 0.010134556567054 x + 0.0190286569970941
R² = 0.992146487846985
0.4
0.35
0.3
f(x) = 64.9090745506986 x − 622.846838434389
R² = 0.721076148662411 0.25
0.2
0.15
0.1
0.05
5 10 15 20 25 30 35 40 45 50 0
0 5 10 15 20 25 30 35

Orden 3
250

200

f(x) = 4.5957374389931 x − 35.0064856328306

150 R² = 0.840879534180206

100

50

45 50
0
0 5 10 15 20 25 30 35 40 45 50
50

0
0 5 10 15 20 25 30 35 40 45 50
 Orden 1
0
40 45 50 0 f(x) =5− 0.0323299203782479
10 15 x20 25 30
+ 0.0176901059207466 35 40 45 50
-0.2 R² = 0.998901992031609

-0.4

-0.6

-0.8

-1

-1.2

-1.4

-1.6

Orden 0.5

x + 0.0190286569970941

20 25 30 35 40 45 50
t min Ca, mol/It Orden 0 Orden 1 Orden 2 Orden 3 Orden 0.5 Orden 1.5
0 2 0 0 0 0 0 0
5 1.6 -0.4 0.22314355 0.125 0.0703125 0.298605 0.16692527
9 1.35 -0.65 0.39304259 0.24074074 0.14934842 0.50463712 0.30711237
15 1.1 -0.9 0.597837 0.40909091 0.28822314 0.73080943 0.49271162
22 0.87 -1.13 0.83240925 0.64942529 0.53558925 0.96295131 0.73001151
30 0.7 -1.3 1.04982212 0.92857143 0.89540816 1.15510707 0.97624366
40 0.53 -1.47 1.32802545 1.38679245 1.65499288 1.37240515 1.33299772
60 0.35 -1.65 1.74296931 2.35714286 3.95663265 1.64521117 1.96640346

Orden 2 ORDEN 1.5

2.5 K=0.0328

f(x) = 0.0390207086698327 x − 0.12074807418841

2 R² = 0.985234183936897

1.5
O
4.5
1 4
3.5
0.5 3 f(x) = 0.0629218341624854
R² = 0.895538662624221
2.5
0
0 10 20 30 40 50 60 70 2
1.5
1
Orden 1.5 0.5
2.5 0
0 10 20 30

2
f(x) = 0.0328083033253591 x + 0.0042628359942104
R² = 0.999813339350836
1.5
9
8
1
7

0.5 6
f(x) = 0.11709524708
5 R² = 0.793190615963
0 4
0 10 20 30 40 50 60 70
3
2
1
0
0 10 20
 Orden 2.5
0 Orden 0
0.03971354 0 2
0.09381404 0 10 20 30 40 50 60 70
-0.2 1.8 f(x) = 0.028935142
0.2087716 R² = 0.9821042523
1.6
0.46453199 -0.4 f(x) = − 0.0260020390974777 x − 0.349203865419566
R² = 0.862080672706839 1.4
0.93015063 -0.6
1.2
2.19731809 -0.8
1
7.73287172
-1 0.8
-1.2 0.6

-1.4 0.4
0.2
-1.6
0
-1.8 0 10

Orden 3 Orden 0.5

1.8
f(x) = 0.0267889042038871 x + 0.227616822744796
1.6 R² = 0.932991219497362

1.4
f(x) = 0.0629218341624854 x − 0.479793122306916
R² = 0.895538662624221 1.2
1
0.8
0.6
0.4
0.2

10 20 30 40 50 60 70 0
0 10 20 30 40 50

Orden 2.5
9
8
7
6
f(x) = 0.117095247084869 x − 1.1908835144673
5 R² = 0.793190615963863
4
3
2
1
0
0 10 20 30 40 50 60 70
 Orden 1
2
1.8 f(x) = 0.0289351424885665 x + 0.116248560024446
1.6 R² = 0.982104252301534

1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 10 20 30 40 50 60 70

Orden 0.5
1 x + 0.227616822744796

30 40 50 60 70
t, min Ca, mol/It Ca' mol/it (1/2) t medio Log 10 t medio Log 10 Ca
0 0.195 0.0975 25 1.397940008672 -0.70996539
5 0.17 0.085 30 1.4771212547197 -0.76955108
10 0.145 0.0725 35 1.5440680443503 -0.838632
15 0.12 0.06 40 1.602059991328 -0.92081875
20 0.105 0.0525 45 1.6532125137753 -0.9788107
25 0.09 0.045
30 0.075 0.0375
35 0.065 0.0325
40 0.055 0.0275
45 0.045 0.0225

Ca, mol/It
0.25

0.2

0.15

0.1

0.05

0
0 5 10 15 20 25 30 35 40 45 50
 Alfa K
2.0745 -2.73632568

LOGARITMO
0
1.35 1.4 1.45 1.5 1.55 1.6 1.65 1.7

-0.2

-0.4

-0.6

f(x) = − 1.07446369118074 x + 0.805617635905446

-0.8 R² = 0.986626644027195

-1

-1.2

45 50
Tiempo (h) PAS/mg PAS' /mg t medio Log 10 t medio Log 10 Pas /mas
0 100 50 16 1.20411998265592 2
2 94 47 17 1.23044892137827 1.9731278535997
4 88 44 18 1.25527250510331 1.94448267215017
8 75 37.5
12 63 31.5
16 52 26
20 40 20

Log 10 t medio 120

2.01
2 100
f(x) = − 1.08467608529613 x + 3.30663108692556
1.99 R² = 0.998745552933344
80
1.98
1.97 60
1.96
1.95 40

1.94
20
1.93
1.92 0
0 5
1.91
1.2 1.21 1.22 1.23 1.24 1.25 1.26
 ALFA K
2.0847 -1864.38606

PAS/mg
120

100

80

60

40

20

0
0 5 10 15 20 25
alfa Orden 1 Orden 0 Orden 2 Orden 2.5 Orden 1.5 Orden 0.5 Orden 3
0 Err:502 0 #NUM! #NUM! #NUM! 0.6931472 #NUM!
0.1 0.8340324 -0.1053605 2.1972246 3.016279 1.4643093 0.3130168 3.9019727
0.2 0.475885 -0.2231436 1.3862944 1.9149933 0.9050825 0.1003636 2.4849066
0.3 0.1856268 -0.3566749 0.8472979 1.2209885 0.5016741 -0.1003123 1.6204877
0.4 -0.0874216 -0.5108256 0.4054651 0.6773047 0.1503816 -0.3077638 0.9650809
0.5 -0.3665129 -0.6931472 0 0.197991 -0.1882264 -0.5348 0.4054651
0.6 -0.671727 -0.9162907 -0.4054651 -0.264263 -0.5413039 -0.7967167 -0.117783
0.7 -1.0309304 -1.2039728 -0.8472979 -0.751526 -0.9404369 -1.1187743 -0.6531418
0.8 -1.49994 -1.6094379 -1.3862944 -1.3279186 -1.4436355 -1.5552073 -1.2685113
0.9 -2.2503673 -2.3025851 -2.1972246 -2.1703065 -2.2239116 -2.2765918 -2.1431574
1 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502

0.9

0.8

0.7
Ord
0.6
Ord
Ord
0.5
Alfa

Ord
Ord
0.4
Ord
Ord
0.3
Ord
Eje
0.2

0.1

0
-3 -2 -1 0 1 2 3 4 5 6 7

LN Fi
 Orden 3.5 Orden 4 tiempo, s 0
#NUM! #NUM! Caf *10, mol/it 18.5
4.8370047 5.8081425 x 0
3.0892536 3.7216693 a 1
2.0430898 2.4859349 Ln Ca 2.9177707
1.2677493 1.5841201 Depende de la linea Int Err:502
0.6220494 0.8472979 Donde quede la linea ejemplo 1/Ca^(n-1) 0.2324953
0.0338586 0.1905183 1/Ca 0.0540541
-0.5521741 -0.4486587
-1.2080771 -1.1466215
-2.1157775 -2.0881672 In Ca - Tiempo
Err:502 Err:502 3.5

3
f(x) = − 0.00661336126783604 x + 2.91615888241711
2.5 R² = 0.99996843936781

1.5

Orden 1 1
Orden 0
Orden 2 0.5
Orden 2.5
Orden 1.5 0
0 50 100 150 200 250 300
Orden 0.5
Orden 3
Orden 4
Ejemplo

6 7
 25 50 75 100 200 250
15.7 13.3 11.2 9.48 4.93 3.54
2.8 5.2 7.3 9.02 13.57 14.96
0.8486486 0.7189189 0.6054054 0.5124324 0.2664865 0.1913514
2.7536607 2.587764 2.4159138 2.2491843 1.595339 1.2641267
-1.7811242 -1.087977 -0.6825119 -0.3948298 0.2983174 0.5214609
0.2523772 0.2742042 0.2988072 0.3247849 0.4503773 0.531494
0.0636943 0.075188 0.0892857 0.1054852 0.2028398 0.2824859

Orden 1.5
0.6

0.5 f(x) = 0.0011981194927228 x + 0.217979502832278

R² = 0.99000778671645
0.4

0.3

0.2

0.1

250 300 0
0 50 100 150 200 250 300
alfa Orden 1 Orden 0 Orden 2 Orden 2.5 Orden 1.5 Orden 0.5 Orden 3
0 Err:502 0 #NUM! #NUM! #NUM! 0.6931472 #NUM!
0.1 0.8340324 -0.1053605 2.1972246 3.016279 1.4643093 0.3130168 3.9019727
0.2 0.475885 -0.2231436 1.3862944 1.9149933 0.9050825 0.1003636 2.4849066
0.3 0.1856268 -0.3566749 0.8472979 1.2209885 0.5016741 -0.1003123 1.6204877
0.4 -0.0874216 -0.5108256 0.4054651 0.6773047 0.1503816 -0.3077638 0.9650809
0.5 -0.3665129 -0.6931472 0 0.197991 -0.1882264 -0.5348 0.4054651
0.6 -0.671727 -0.9162907 -0.4054651 -0.264263 -0.5413039 -0.7967167 -0.117783
0.7 -1.0309304 -1.2039728 -0.8472979 -0.751526 -0.9404369 -1.1187743 -0.6531418
0.8 -1.49994 -1.6094379 -1.3862944 -1.3279186 -1.4436355 -1.5552073 -1.2685113
0.9 -2.2503673 -2.3025851 -2.1972246 -2.1703065 -2.2239116 -2.2765918 -2.1431574
1 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502 Err:502

1.2

0.8
Ord
Ord
Ord
0.6
Alfa

Ord
Ord
Ord
0.4 Ord
Ord
Eje
0.2

0
-6 -4 -2 0 2 4 6 8

LN Fi
 Orden 3.5 Orden 4 tiempo, s 0
#NUM! #NUM! (Gluc) *10, M 5.66
4.8370047 5.8081425 x 0
3.0892536 3.7216693 a 1
2.0430898 2.4859349 Ln Ca 1.7334239
1.2677493 1.5841201 Depende de la linea Int Err:502
0.6220494 0.8472979 Donde quede la linea ejemplo 1/Ca^(n-1) 2.3790755
0.0338586 0.1905183 1/Ca 0.1766784
-0.5521741 -0.4486587
-1.2080771 -1.1466215
-2.1157775 -2.0881672 In Ca -Tiempo
Err:502 Err:502
2
1.8
1.6 f(x) = − 0.0272333396949731 x + 1.73396240620658
R² = 0.990359779825942
1.4
1.2
1
0.8
Orden 1 0.6
Orden 0 0.4
Orden 2
Orden 2.5 0.2
Orden 1.5 0
0 2 4 6 8 10 12 14
Orden 0.5
Orden 3
Orden 4
Ejemplo

6 8
 0.5 2 3 4 6 8 12
5.52 5.42 5.32 5.02 4.8 4.52 4.1
0.14 0.24 0.34 0.64 0.86 1.14 1.56
0.975265 0.9575972 0.9399293 0.8869258 0.8480565 0.7985866 0.7243816
1.7083779 1.6900958 1.6714733 1.6134299 1.5686159 1.508512 1.410987
-4.2931472 -2.9068528 -2.5013877 -2.2137056 -1.8082405 -1.5205585 -1.1150934
2.349468 2.3280893 2.3065125 2.2405357 2.1908902 2.1260292 2.0248457
0.1811594 0.1845018 0.1879699 0.1992032 0.2083333 0.2212389 0.2439024

Orden 0.5
2.5

2.4
f(x) = − 0.0299744099691908 x + 2.37619220121416
2.3 R² = 0.989046344668473

2.2

2.1

1.9
10 12 14
1.8
0 2 4 6 8 10 12 14
T(K) k 1/T Ink
600 1.87E+03 0.00166667 7.53369371
650 1.13E+04 0.00153846 9.332558
700 5.69E+04 0.00142857 10.9490506 Gráfica 1
750 2.44E+05 0.00133333 12.4049235 14

12 f(x) = − 14604.6089303494 x + 31.8416021992394

R² = 0.999631383633679
InK= InA-Ea/R*1/T 10
y=a+bx
8

LNA= 31.842 6
(-Ea/R*1/T) (-14605x)
4

A 6.74E+13 2
Ea 1015.53743 Lt*atm/Kelvin
0
0.0013 0.00135 0.0014 0.00145 0.0015 0.00155 0.0016 0.00
Gráfica 1

x + 31.8416021992394

0.0015 0.00155 0.0016 0.00165 0.0017