MCQ on poentiometry

1. The electrode potentials are calculated by

A. Ilkovic equation B. Nernst equation C. Randles equation
D. Ohm's law
2. The electrochemical analysis, in which the current is measured by
keeping potential constant is
A. Potentiometric titration B. Coductometric titrations
C . Amperometric titrations D. Voltammetry

3. All of the following statements are correct regarding

potentiometric titrations, except

(A) They are suitable for colored or turbid reactions

(B) The emf of the cell is zero at the equivalence point

(C) These are not suitable for analysis of dilute solutions less than 0.001M

(D) Liquid junction potentials will not influence the study

4. In an electrolytic cell, metal passes in to ions at

(A) Cathode (B) Anode (C) Salt bridge (B) No oxidation or reduction

5. The expressions valid in potentiometry are

(A) E Cell =E ERE - E ISE (B) E Cell =E ISE – E ERE + E J

(C) E ISE =E IRE – E membrane (D) E ISE =E IRE – E J

6. An electrode has the standard electrode potential as +2.50V. The

electrode will be
(A) P,S (B) Q,R (C) P,R (D) Q,

7. Standard hydrogen electrode

(A) Can’t be easily prepared (B) Doesn’t go reduction

(C) Indicator electrode (D) All of the above

8. The electrochemical analysis which measures the current generated

at the electrode in an ionic solution by application of potential is
known as
9. Calculate logarithm of the equilibrium constant of following redox
cell

(A) 10 (B) 15 (C) 20 (D) 30

10. Voltammetry belongs to the group of electrochemical analysis of

(A) Steady-state methods (B) Transient methods

(C) Controlled potential methods (D) Charge transfer by migration

11. Select the true statements regarding glass electrode.

(A) Q (B) R (C) P,S (D) P,Q

12. Ion-selective potentiometry involves

(A) Measurement of electrode potential at zero current

(B) Measurement of electrode potential as a function of volume of titrant at

zero current

(C) Measurement of current as a function of volume of titrant at constant

potential difference

(D) Addition or deletion of analyte to null the potential difference at zero

current

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