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Eco Friendly Innovation - Effectiveness of Oil Absorbent Pads Utilizing Processed Peanut Shells
Eco Friendly Innovation - Effectiveness of Oil Absorbent Pads Utilizing Processed Peanut Shells
Oil spill is a crucial problem to our environment right now, crude oil and
petroleum products are widespread water and soil pollutants resulting from marine and
terrestrial spillagest ( Kuyukina, et al., 2018). International statistics of oil spill sizes
for all incidents indicate that the majority of oil spills are small (less than 7 tonnes).
The major accidents that happen in the oil industry contribute only a small fraction of
the total oil which enters the environment (Ившина, Ivshina et al., 2018). Furthermore,
according to Hodson et al., (2016), large amount of oil spreads at a depth of 1100–1300
m, polluting and harming deepwater habitats. Coastal oiling was decreased by reaction
many coastal habitats and more than 2100 kilometers of shoreline were impacted.
Despite the fact that worst-case impact scenarios did not come to pass, research
indicates that oiling has a wide range of biological impacts. In comparison to population
However, the oil spill poses direct threats to human health from inhalation or
dermal contact with the oil and dispersant chemicals, and indirect threats to seafood
safety and mental health. Physicians should be familiar with health effects from oil
spills to appropriately advise, diagnose, and treat patients wherever a major oil spill
occurs (Solomon, 2017). In response, according to the Governments and the Oil
Industry, they must have preparedness plans in place and understand what to do when
an oil spill happens. Equally important is conducting regular spill response training
exercises. The quicker and better prepared the reaction the less the environmental
impact. Oil spill response can be tiered so that small spills are handled at a local level,
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larger spills are handled on a national level and major spills call on an international
response (United Nations Environment Programme, n.d.). In the same study, it is stated
that the Sri Lanka case also demonstrates the growing risks of growing global container
shipping, and the need to prepare for complex incidents involving oil, hazardous
associated with oil spills. This approach not only transforms discarded peanut shells
into a valuable resource but also highlights the potential for creating a cost-effective
and efficient absorbent from our agricultural waste (Dai et al., 2022). Waste papers
based oil absorbent (mixed kraft cuttings) are capable to absorb engine oil, kerosene,
and xylene. The adsorbent had an excellent performance with a high absorbing ability
of 16 to 28 times its own weight. Up to 92.8% of the oil in the adsorbents could be
easily recycled and collected by manual squeezing. The adsorbent could be reused over
eight cycles, and the sorption capacity remained constant (Wang 2019). The study of
Zhao et al., (2020) emphasizes the critical necessity of developing a viable and
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attributes. Similarly, according to the findings of Malawade et al., (2021), the appeal of
context.
The researchers will conduct a study on an oil absorbent made from Peanut
(Arachis hypogaea) shells. This study will determine how effective Peanut (Arachis
hypogaea) shells are in absorbing oils. Over the years, utilization of agricultural waste
such as peanut shells, has garnered significant attention in recent studies due to their
belonging to the Fabaceae family and are valuable food items used extensively
worldwide in various ways (Çelebi et al., 2022). The peanut shell is an agricultural
byproduct that requires immediate utilization (Gao et al., 2022). This research is
Peanut shells are a type of agricultural waste containing meso- and micropores, and
were employed as an evaporator for interfacial solar steam generation (ISSG). Despite
being rich in protein, fat, and fiber, peanut shells are typically thrown away after being
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Specifically, the researchers aim the following objectives:
Oil spills are a significant issue affecting our environment, the researchers
conducted this study to investigate the effectiveness of utilizing processed peanut shells
as a sustainable alternative oil absorbent pad for oil spills. Specifically, this study
1. How may the Arachis hypogaea shells be processed and developed as an oil
absorbent pad?
2. What is the ideal grams of processed Arachis hypogaea shells are needed to
a.100 grams
b.200 grams
c.300 grams
a. Absorbency
b. Cost-Effectiveness
4. How much oil will the Arachis hypogaea shells’ oil absorbent pads absorb
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a. 0-25 ml
b. 25-50 ml
c. 50-75 ml
d. 75-100 ml
5. How well does the Arachis hypogaea shell-based oil absorbent pads absorb
a. Gasoline (Premium)
b. Kerosene
c. Diesel
6. How does the thickness of the pads influence the speed and quantity of oil
a. 0.5 mm
b. 1 mm
c. 1.5 mm
Hypotheses
H0: The oil absorbent pads using the Arachis hypogaea shells will be effective on
Ha: The oil absorbent pads using the Arachis hypogaea shells will not be effective on
Ha: The oil absorbent pads will absorb the oil slowly.
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Significance of the Study
solution for cleaning up oil spills. The biodegradable nature peanut shell, coupled with
their status as a renewable resource, make them as one of the options. This approach
supports local sourcing, minimizes waste and avoids the introduction of synthetic
materials into ecosystems. Industries can benefit from using peanut shells as cost-
effective, environmentally friendly oil absorbent pads. This approach aligns with
This study will also help to preserve and recycle the peanut shells that are
usually perceived as waste. This will also provide the community a product that is more
reliable and less expensive than branded absorbent pads. This research promotes peanut
shell-based oil absorbent pads to enhance environmental compliance, minimize oil spill
emergency response plans, collaborate with industries, and raise public awareness
Lastly, this study provides information that could guide future studies about
effectiveness of oil absorbent pads utilizing processed peanut shells. This study
provides a precise, reliable and credible set of information that could lead to deeper
hypogaea) Shells as an Oil Absorbent Pads by processing the peanut shells to create
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identical pads from peanut shell-based and traditional materials and conduct oil
absorption tests, measuring time and quantity absorbed. It will mainly involve peanut
shells as the main component of the production of the alternative absorbent papers. This
study aims to determine the absorption of Peanut Shells as an Oil Absorbent Pads. This
study is limited only to the different types of crude oils such as Kerosene, Gasoline, and
Diesel and will not cover the other types of oils such as cooking oils. The study will be
conducted in the second quarter of the second semester of the school year 2023-2024
Conceptual Framework
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This diagram outlines the systematic process of utilizing peanut shells as an oil
absorbent material and assessing their effectiveness in cleaning oil spills. The process
involves material preparation, data analysis, and weight measurements. It starts with
the occurrence of an oil spill, which prompts the need for an effective cleanup solution.
Then, peanut shells are identified as a potential natural absorbent due to their high
porosity and absorption capabilities. The amount of blended peanut shells, ranging from
Next, it evaluates the oil absorption capacity of the peanut shell-based absorbent
pads over different time intervals (5, 10, and 15 minutes) for various types of oils,
including gasoline, kerosene, and diesel. This evaluation involves measuring the weight
of the pads before and after exposure to oil, allowing for the calculation of the absorbed
oil volume. This conceptual framework guides the researchers through each step of the
Definition of Terms
showcases the absorbent nature of peanut shells in capturing and containing oil,
used for oil absorption, can release harmful chemicals into the environment
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c. Oil absorbent pads - This refers to the pads used to absorb oil and other
pads, which may involve treating the shells to improve their absorbency and
d. Oil spills - This refers to the environmental disasters that occur when crude oil
or refined petroleum products are released into the environment, typically into
bodies of water like oceans, seas, or rivers. These spills have detrimental effects
livelihoods.
oil absorbent pads, considering different types of oils and time interval.
f. Peanut shells - It refers to a raw material for creating oil absorbent pads, which
h. Waste disposal - This refers to the process of disposing of the processed peanut
shell oil absorbent pads after they have need utilized for absorbing oil.
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REVIEW OF RELATED LITERATURES
Oil Spills
Number of large oil spills have come down over the years, possibly due to an
/governments. The study also found out that numerous physical countermeasures have
been developed targeting the different stages in a typical clean-up operation, and can
be categorized into the following two types based on their modes of action: active and
passive techniques. Passive measures, such as booms and barriers, entail containment
on water surface to restrain the spread of oil and to facilitate its recovery at a later stage.
Booms are the most widely used ones, although they are sensitive to water currents,
Peanut Shells
are chickpeas, lentils, beans, and peas. It is originally from South America and is used
mainly for culinary purposes, in confectionery products, or as a nut as well as for the
production of biscuits, breads, sweets, cereals, and salads. (Perea-Moreno et al., 2018).
veins and peanut peel covering the seeds. There are more than 100 nations in the globe
where peanuts are grown, with Asia and Africa having the highest concentrations
(Akram et al., 2018). China is a major producer of peanuts, and the country has
abundant resources of peanut shells, which include lignin, cellulose, hemicellulose, and
other organic materials as well as trace metal elements (Duc et al., 2019).
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According to the study of Setyawan et al (2023), the chemical composition of
peanut shells is a combination of lignin (36.1 wt%), cellulose (44.8 wt%), proteins (5.4
wt%), hemicellulose biopolymers (5.6 wt%), and other compounds such as minerals,
pectin, and tannins with several polar functional groups i.e. hydroxyl, methoxy, and
the form of waste peanut shells (Moreno et al., 2018). Most of the national peanut
production, estimated at 900,000 tons per year, is processed in several cities in the
accumulate in the environment and pollute it. However, there are alternative strategies
for mitigating these effects. According to Yang Qu et al. (2023), one approach is to
transform peanut shells into bio-pellets that can be used as fuel, reducing reliance on
help minimize waste and foster a circular economy (Novianto et al., 2020).
a beneficial substrate for the growth of probiotic bacteria (Suwasdi et al., 2019). The
research findings illustrate the ability of peanut shell waste to be converted into valuable
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Natural Absorbent
means. Investigating natural absorbents has gained a lot of attention as a viable answer
absorbents are frequently utilized in industries and spill cleanup operations, although
they have been linked to problematic disposal and negative environmental effects
(Absorbents, GlobalSpec). Finding alternative resources that are efficient and eco-
friendly has therefore become progressively more important. Researchers are turning
their attention to natural sources as a result of Tolkou et al., (2024) emphasizing the
need for sustainable solutions. Since they were numerous, low-cost, and biodegradable,
characterized by having high porosity, which means water, oils, and other types of
products can be easily absorbed (Bobet et al., 2019). Peanut shells have a great capacity
to adsorb a wide range of contaminants, such as organic chemicals, dyes, and heavy
metals. The study of Pessôa et al., (2024) showed the usefulness of peanut shells in
increase their adsorption capacity and range of applications, researchers found that by
treating peanut shells with chemicals or changing their surface, they can soak up more
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METHODS AND MATERIALS
Collection of Materials
Peanut shells will be acquired from the Public Market in Gapan City, Nueva
Ecija. Upon collection, the peanut shells will be thoroughly cleaned to remove any
contaminants that may affect the outcome of the research. Subsequently, the cleaned
peanut shells will be cooked by the researchers to prepare them for the experimental
procedures. In addition to the peanut shells, various oils such as kerosene, gasoline, and
diesel will be obtained from Gapan City Gas, located at 386 Tinio Street, Gapan City,
Nueva Ecija.
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Preparation of Materials
The Peanut Shells will be thoroughly cleaned by brushing off the dirt on its
surface using a cleaning brush. The Peanut Shells will be crushed into small pieces and
put in a casserole for cooking. About 4 kilograms of caustic soda will be mixed with 16
liters of water. The cooking process will prepare a 1 set of mixtures. The mixtures will
be placed in the casserole and pre-heated for about a half hour. The 8kg Peanut Shells
and pre heated mixtures will be mixed and boiled for about two hours. The softened
raw materials will be placed in a screen or cloth and washed with water.
Paper Making
The Peanut shells will be mashed and blended. The blended Peanut shells will
be put into water. The blended Peanut shells (100, 200, and 300 g) will be set into the
screen to determine the desired measurements of the blended Peanut shell to create a
sheet of paper. Once a stack of damp sheets assembled between boards, pressing of the
entire pile would follow and will dry to cut into varying sizes.
Risk Involve
Peanuts are prone to fungal disease and farmers use pesticides to fight against
it. Exposure to pesticides can lead to a range of health issues, including respiratory
problems, skin irritation, and even cancer (Weber M, 2024). Also, according to Yeung
A.A., (2023), peanut allergies are common and can cause severe reactions. Even if
you’re not allergic to peanuts themselves, the shells could still trigger a reaction due to
cross-contamination and peanut shells are high in fiber and can be difficult to digest for
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Determining the Ideal Grams Needed for a Single Sheet of Oil Absorbent Pads
necessary to assess the pads' efficacy. The primary determinants of quality are the
absorption capacity, wet back, liquid strike through time, and retention capacity of the
Type of Oils
One (1) sheet of Peanut Shells with varying sizes of (100g, 200g, 300g) will be
predetermined by its mass. To determine the starting mass, 100mL of each test oil
(Kerosene, Gasoline, Diesel) will be measured and placed into the three (3) transparent
containers with 1L capacity. After predetermining the weight of samples (100g, 200g,
300g), the samples will be placed into each container. The introduced samples with the
test oils will be observed by the researchers. To determine the absorbency of the peanut
shells’ oil absorbent pads, the researcher will use the formula:
Initial weight of oils in a container Final weight of oils in a container after pad
Risk Involved
Crude Oil is toxic and can cause many health complications for humans. Crude oil
contains chemicals that some people can be extremely sensitive to, it can cause eye
irritation, eye redness, diarrhea, vomiting, and even respiratory problems. Long-term
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exposure to crude oil can increase the risk of cancer, damage blood and organs, and can
Determining How Much Oil will the Peanut Shells’ Oil Absorbent Pads Absorb
A total of nine (9) 100g thick oil absorbent pads will be used. On the three (3)
containers, each contains the sample of oils (Kerosene, Gasoline, Diesel) with an
amount of 100ml. One 100g thick oil absorbent pad will be put on each container for 5
minutes. After 5 minutes, the pads will be removed from the containers, the pads will
then be weighed for the second time to determine how much (a. 0-25 ml, b. 25-50 ml,
c. 50-75 ml, d. 75-100 ml) they absorb from each oil . Another one 100g thick oil
absorbent pad will be put on each of the three (3) containers, each containing the sample
of oils (Kerosene, Gasoline, Diesel) with an amount of 100ml this time for 10 minutes.
After 10 minutes, the pads will be removed from the containers, the pads will then be
weighed to know how much (a. 0-25 ml, b. 25-50 ml, c. 50-75 ml, d. 75-100 ml) they
absorbed from each oil. One 100g thick oil absorbent pad will be put on each of the
three (3) containers, each containing the sample of oils (Kerosene, Gasoline, Diesel)
with an amount of 100ml for 15 minutes. After 10 minutes, the pads will be removed
from the containers, the pads will be weighed to know how much (a. 0-25 ml, b. 25-50
ml, c. 50-75 ml, d. 75-100 ml) they absorbed from each oil.
Nine (9) 200g thick oil absorbent pads will be used. On the three (3) containers,
each contains the sample of oils (Kerosene, Gasoline, Diesel) with an amount of 100ml.
One 200g thick oil absorbent pad will be put on each container for 5 minutes. After 5
minutes, the pads will be removed from the containers, the pads will then be weighed
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to determine how much (a. 0-25 ml, b. 25-50 ml, c. 50-75 ml, d. 75-100 ml) they absorb
from each oil . Again, One 200g thick oil absorbent pad will be put on each of the three
(3) containers, each containing the sample of oils (Kerosene, Gasoline, Diesel) with an
amount of 100 ml, this time for 10 minutes. After 10 minutes, the pads will be removed
from the containers, the pads will be weighed to know how much (a. 0-25 ml, b. 25-50
ml, c. 50-75 ml, d. 75-100 ml) they absorbed from each oil. And again, One 200g thick
oil absorbent pad will be put on each of the three (3) containers, each containing the
sample of oils (Kerosene, Gasoline, Diesel) with an amount of 100ml for 15 minutes.
After 15 minutes, the pads will be removed from the containers, the pads will then be
weighed to know how much (a. 0-25 ml, b. 25-50 ml, c. 50-75 ml, d. 75-100 ml) they
Another total of nine (9) 300g thick oil absorbent pads will be used. On the
three (3) containers, each contains the sample of oils (Kerosene, Gasoline, Diesel) with
an amount of 100ml. One 300g thick oil absorbent pad will be put on each container
for 5 minutes. After 5 minutes, the pads will be removed from the containers, the pads
will then be weighed to determine how much (a. 0-25 ml, b. 25-50 ml, c. 50-75 ml, d.
75-100 ml) they absorbed from each oil . Then, One 300g thick oil absorbent pad will
be put on each of the three (3) containers, each containing the sample of oils (Kerosene,
Gasoline, Diesel) with an amount of 100ml, this time for 10 minutes. After 10 minutes,
the pads will be removed from the containers, the pads will be weighed to know how
much (a. 0-25 ml, b. 25-50 ml, c. 50-75 ml, d. 75-100 ml) they absorbed from each oil.
Then lastly, One 300g thick oil absorbent pad will be put on each of the three (3)
containers, each containing the sample of oils (Kerosene, Gasoline, Diesel) with an
amount of 100ml for 15 minutes. After 15 minutes, the pads will be removed from the
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containers, The pads will be weighed to know how much (a. 0-25 ml, b. 25-50 ml, c.
Risk Factors
(not vehicle exhaust) may cause dizziness, drowsiness headaches. Breathing in large
amounts can result in coma, loss of muscle control, heart and lung problems. Kerosene
can cause the skin to become irritated, dry and cracked; if the skin is exposed for a long
time then burns may develop. Also, Having exposure to gasoline or gasoline vapors in
large amounts or over an extended period of time can cause serious health
complications. Ingesting even a small quantity of gasoline can be fatal (Huizen 2023).
Direct contact with diesel fuel can cause irritation and dryness of the skin. Prolonged
or repeated contact can lead to more severe skin conditions such as dermatitis (Branson
2023).
Determining the Influence of the Thickness of the Pads to the Speed and
The thickness of pads may have a direct influence on the speed and quantity of
oil. It can be faster and have more quantity that could be absorbed. The larger diameter
pad is, the more effective it is, because of the increase in thickness, although the effect
is not as pronounced as with pad height ( Luo et al., 2018). Using a larger diameter pad
focuses the speed and also increases the quantity of it to be absorbed. Based on the
study of Yang et al., (2020) from the Chemical Engineering Journal 401, it stated that
the pace of absorption is dependent on the oil's thickness. Heavy oils take longer to
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absorb than light ones. Oil retention: A sorbent structure may droop and distort due to
Risk Factors
Heavy Fuel Oil is highly concentrated in sulfur (35,000 parts per million). This
means global shipping accounts for 8% of global emissions of sulfur dioxide emissions
(SO2), which is highly acidic when mixed with water making shipping a major
contributor toward acid rain and other respiratory diseases (Degnarain, 2020).
Statistical Analysis
Gasoline, Diesel) with varying time (5 minutes, 10 minutes, 15 minutes) with the help
Waste Disposal
disposal process. Various types of oils, including Kerosene, Gasoline, and Diesel,
alongside oil absorbent pads that have been soaked in these different oils, will be
specifically allocated trash bins that are intended for hazardous wastes. This approach
ensures that all materials used in our research are handled and disposed of in a manner
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that minimizes potential environmental impact, adhering to strict environmental
protection standards.
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Type equation here.
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