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Geology 2010 Davies 963 6
Geology 2010 Davies 963 6
1500 m
1000 m
Sh
200 m
100 m
2000 m
500 m
© 2010 Geological Society of America. For permission to copy, contact Copyright Permissions, GSA, or editing@geosociety.org.
GEOLOGY,
Geology, November
November 2010
2010; v. 38; no. 11; p. 963–966; doi: 10.1130/G31058.1; 5 figures; Data Repository item 2010269 963
Figure 2. A: Representa- n = 348 40 400 m
neys (Figs. 1B and 2A) penetrate low-amplitude We examined 102 amplitude anomalies located assumes seawater salinity in the pores; Kven-
or anomalously high-amplitude reflections within an interval 200 m below the BHSZ and volden, 1993), a geothermal gradient of ~33 °C/
(herein termed amplitude anomalies) below covering areas of 0.75–269 km2. Here we high- km, and a seabed temperature of ~7 °C. Results,
the BHSZ. The anomalies occur throughout the light four representative examples (Fig. 4) that shown in Figures 2C and 2D, indicate that the
study area below and outside the region covered are spatially extensive features that have vertical BHSZ intersects the seabed at ~600 m and deep-
by the hydrate (e.g., marked Y in Fig. 2A). The extents of 140–340 m. Most of the updip termina- ens to ~200 m below the seabed with increasing
chimneys are closely associated with the anoma- tions of the anomalies are marked by reductions water depth, which is what we observe in the
lies but only occur where a BHSZ reflection is in reflection amplitude that are not coincident seismic reflection data. The curved shape of the
mapped, and rarely outside this area (examples with the BHSZ (e.g., accumulation D in Fig. 4). reflection (Figs. 2A and 2B), which intersects
are marked X Fig. 2A). A graph of the frequency the seabed as the depth of the seabed decreases,
of chimney tops against depth below seabed INTERPRETATION conforms to the theoretically predicted shape of
(calculating depth using a velocity for the sedi- The reflection BHSZ clearly crosscuts stratal the hydrate stability curve (Milkov and Sassen,
ment of 1700 ms-1) (inset in Fig. 2A) shows that reflections, and therefore it does not represent 2002). This is a rarely documented characteris-
they cluster at specific depths: 60% cluster at a palaeo-seabed or an unconformity (Fig. 2B). tic of BHSZs (e.g., Tréhu et al., 1995; Milkov
~220 mbsf (meters below sea floor) which is There are no accurate seabed temperatures or and Sassen, 2002; Viola et al., 2005)
the present maximum depth of the BHS; 37% geothermal gradients for this region, but a tem- Based upon standard geophysical and geolog-
cluster at deeper levels. 97% have “blind” upper perature profile with increasing depth can be esti- ical criteria for recognizing gas-charged sands
terminations with no evidence for an erosional mated for locations on the seismic line by using versus other lithology-related effects (Brown,
depression indicative of a pockmark at the sea- a generalized hydrate stability curve (which 2004), 56 of the amplitude anomalies are inter-
bed; 3% of chimneys (12) show good evidence preted to be gas filled. They probably represent
for pockmark development, indicative of vent- 1
thin deepwater sands or silts that have been
GSA Data Repository item 2010269, Figure DR1
ing to the contemporaneous seabed (Fig. DR1 in (dip and strike seismic across erosional depressions reported from commercial boreholes along this
the GSA Data Repository1). and dip map showing cluster of 12 pockmarks) and part of the margin (Vear, 2005), most of which
Some of the chimneys terminate at the anoma- Table DR1 (calculations of the mass of methane are below tuning thickness (< 10 m). Only two
lies (marked X in Fig. 3) and a map of one such trapped stratigraphically and in the free gas zone), is terminate at the present position of the BHSZ,
available online at www.geosociety.org/pubs/ft2010.
feature, which is located immediately below htm, or on request from editing@geosociety.org or
indicating active sealing by the hydrate (e.g.,
the BHSZ, shows it has an elongate form that is Documents Secretary, GSA, P.O. Box 9140, Boulder, accumulation E in Fig. 4A); the other 54 accu-
parallel to the dip of the slope (inset, Fig. 3A). CO 80301, USA. mulations are stratigraphically trapped indepen-
1400 1400
LP in Data Repository). The absolute mass of meth-
1600 10 15 20 25
BA 1400 TA ane is not of particular importance here, but the
HP
E
1800
15 1600 TA percentage of methane held beneath the BHSZ
5 10 20
HP
800
D LP
is significant, as it is only 5% compared to 95%
1800
1000 in the stratigraphic traps.
BA
SZ
TA 2000 BH
1200 LP
STRATIGRAPHIC RECYCLING MODEL
1400 D The BHSZ has probably been reset from
HP
BA
C deeper levels to its present position, which is
A
B Low seismic
consistent with continuous sedimentation over
amplitude the past 5.2 m.y. The clustering of chimneys
High seismic
amplitude
at specific depth levels may indicate the posi-
E 1 km tion of present and past (deeper) positions of
100 m X X’
the BHSZ or may be coincident with the gas
Z
BHS accumulations. During upward movement of
100 m Updip seal the BHSZ, water and gas dissociated. The gas
Z
BHS against hydrate
TA and phase reversal
migrated vertically upward until it intersected
1 km
permeable and porous sand and silt beds, which
progressively filled until the seal capacity of the
X X′
surrounding fine-grained sediment was reached
Figure 4. A: Representative seismic line showing high-amplitude reflections interpreted to be or exceeded (Figs. 5A and 5B). If the resultant
gas charged sands below the base of the gas hydrate stability zone (BHSZ). B–E: Graphs of blowout pipe did not intersect one of the strati-
hydrostatic (HP), lithostatic (LP), and gas pressures (dashed lines) for amplitude anomalies graphic traps, then gas migrated upward to form
marked on the seismic section. Vertical axis—depth below sea level (m); horizontal axis— gas hydrate at the level of the new BHSZ. A
pressure (MPa). Lithostatic gradient is 0.021 MPa/km, hydrostatic gradient is 0.010 MPa/km,
and gas gradient is 0.00011 MPa/km. TA and BA are top and base accumulation, respectively.
significant number of chimneys terminate at the
Inset (bottom right): Close-up of accumulation (E) that terminates at the BHSZ coincident present BHSZ or penetrate the lower parts of the
with a reflection phase reversal (circled area). Inset (bottom center): Seismic cross section hydrate; this is direct evidence for some con-
and amplitude map of seismic reflection revealing an amplitude anomaly that has a sharp ventional hydrate recycling (e.g., Haacke et al.,
updip termination against the BHSZ and the resulting phase reversal. Inset (top right): Updip 2007). The progressive filling of stratigraphic
terminations to the amplitude anomalies.
traps may be assisted by gas leaks from other
accumulations or deeper thermogenic sources.
dent of it. Seismic amplitude does not discrimi- (Fig. 4A) are marked by the change from high to This is consistent with gas charge in accumu-
nate between high and low gas saturations, but if low seismic amplitude (marked TA in Fig. 4A). lations that lie outside the area of the hydrate.
one assumes that the pores are connected, they Here the buoyancy pressure of the gas would be There is no requirement for overpressure of pore
would represent gas accumulations that have close to lithostatic pressure (Figs. 4B–4E) and water beneath the stratigraphically trapped gas
column heights of between 140 and 340 m. The susceptible to catastrophic leakage. This has columns (cf. Flemings et al., 2003) for criti-
shallowest regions of the gas accumulations been described for sediments that are sealed by cal pressures to be reached. Stress and tensile
HP
BHSZ-I with free gas 1800 Kvenvolden, K.A., 1993, Gas hydrates–geological per-
Hydrate seal - FGZ
spective and global change: Reviews of Geophysics,
2000 v. 31, p. 173–187, doi:10.1029/93RG00268.
Løseth, H., Wensaas, L., Arntsen, B., Hanken, N., Basire,
Figure 5. A: Gas hydrate in fine-grained sediment with beds of deepwater sand and silt. Ma- C., and Graue, K., 2001, 1000 m long gas blow-out
jority of free gas (green) is trapped in stratigraphic traps; small proportion is trapped by the pipes. In: Wensaas, L. (ed.) 63rd EAGE Conference
hydrate as a free gas zone (FGZ). B: Beds become progressively charged as the base of the and Exhibition, Amsterdam, Extended Abstracts.
gas hydrate stability zone (BHSZ) shifts upward (BHSZ I, II and III) due to deposition at the EAGE, Houten, Netherlands, 524.
seabed. Critically pressured gas accumulations below the gas hydrate catastrophically leak, Milkov, A.V., and Sassen, R., 2002, Economic geology of
and gas migrates upward (vertical arrows) to the gas hydrate or intermediate gas accumula- offshore gas hydrate accumulations and provinces:
Marine and Petroleum Geology, v. 19, p. 1–11,
tions. HP—hydrostatic pressure; LP—lithostatic pressure.
doi:10.1016/S0264-8172(01)00047-2.
Pecher, I.A., Minshull, T.A., Singh, S.C., and von Huene,
R., 1996, Velocity structure of a bottom simulating
reflector offshore Peru: Results from full waveform
strength increase with burial depth and would silts means that gas column heights can readily inversion: Earth and Planetary Science Letters, v. 139,
result in higher seal capacities. Therefore it is become significant enough for critical pressur- p. 459–469, doi: 10.1016/0012-821X(95)00242-5.
possible that the seal capacity for some accu- ization. Such traps can be volumetrically larger Shipley, T.H., Houston, M.H., Buffler, R.T., Shaub, F.J.,
McMillen, K.J., Ladd, J.W., and Worzel, J.L., 1979,
mulations is not exceeded, so the methane could than those trapped below the hydrate (i.e., the Seismic evidence for widespread possible gas hy-
be stored for significant periods of time without free gas zone). Methane exchange is triggered drate horizons on continental slopes and rises: Bulle-
recycling. The absence of chimneys outside the by resetting of the BHSZ and because the free tin of the American Association of Petroleum Geolo-
gists, v. 63, p. 2204–2213.
area of the hydrate shows that these gas accumu- gas reservoirs become critically pressured. Svensen, H., Planke, S., Malthe-Sørenssen, A., Jamtveit, B.,
lations have not become critically charged and The gas in the free gas zone represents a Myklebust, R., Rasmussen Eidem, T., and Rey, S.,
that the hydrate has a direct role in the develop- small fraction of the 1550 Gt methane that has 2004, Release of methane from a volcanic basin as
a mechanism for initial Eocene global warming: Na-
ment of the critically pressured condition. been estimated for free gas zone storage glob- ture, v. 429, p. 542–545, doi:10.1038/nature02566.
Only the cluster of 12 out of the 360 chim- ally (Hornbach et al., 2004). The 3-D seismic Tréhu, A.M., Flemings, P.B., Bangs, N.L., Chevallier, J.,
neys terminate at pockmarks that are indicative data set shows that stratigraphically trapped Gràcia, E., Johnson, J.E., Liu, C.-S., Liu, X., Riedel,
M., and Torres, M.E., 2004, Feeding methane vents
of gas venting at a contemporaneous seabed. free gas could easily be misinterpreted as gas and gas hydrate deposits at south Hydrate Ridge:
This and the presence of 348 other chimneys trapped as a free-gas zone below the hydrate. Geophysical Research Letters, v. 31, p. 23310–
23324, doi:10.1029/2004GL021286.
supports our model of stratigraphic recycling Future 3-D data sets will be a valuable tool for Tréhu, A.M., Lin, G., Maxwell, E., and Goldfinger, C.,
rather than venting as the dominant process. discriminating between free gas trapped by the 1995, A seismic reflection profile across the Cascadia
This could result in methane being removed hydrate and that contained in conventional traps. subduction zone offshore central Oregon: new con-
straints on methane distribution and crustal structure:
from the hydrate-free gas system for significant These data sets will also be important in deter- Journal of Geophysical Research, v. 100, p. 15101–
periods of time. The stratigraphic recycling pro- mining the role of conventional stratigraphic 15116, doi:10.1029/95JB00240.
cess is reversible if the BHSZ deepens. or even structural traps in gas hydrate systems Vear, A., 2005, Deep-water plays of the Mauritanian con-
tinental margin. In: Petroleum Geology: North-West
and determining the mechanisms for methane Europe and Global Perspectives – Proceedings of the
IMPLICATIONS AND CONCLUSIONS exchange between the three storage domains. 6th Petroleum Geology Conference (Eds Doré, A.G.
Methane storage in gas hydrate provinces and Vining B. A.) (The Geological Society London),
ACKNOWLEDGMENTS p. 1217–1232.
may occur in three different domains, conven- Viola, G., Andreoli, M., Ben-Avraham, Z., Stengel, I., and
We thank Darren Gröcke, Neil Goulty and Joe Cartwright
tional stratigraphic (and plausibly structural) for discussion, Dave Stevenson and Gary Wilkinson for man- Reshef, M., 2005, Offshore mud volcanoes and on-
traps (Milkov and Sassen, 2002), the hydrate aging the seismic interpretation facility and Petronas and land faulting in southwestern Africa: Neotectonic
Tullow Oil for permission to use and publish seismic data. implications and constraints on the regional stress
itself, and the free gas zone immediately below field: Earth and Planetary Science Letters, v. 231,
The Landmark University Grant Program is gratefully ac-
it. Deepwater slopes are susceptible to changes knowledged for providing seismic interpretation software. p. 147–160, doi:10.1016/j.epsl.2004.12.001.
Von Huene, R., and Pecher, I.A., 1999, Vertical tectonics
in ambient conditions (Dickens, 2001) but are We also thank Mads Huuse and two anonymous reviewers
and the origins of BSRs along the Peru margin: Earth
for their constructive comments.
also typically characterized by these thin, rela- and Planetary Science Letters, v. 166, p. 47–55, doi:
tively steeply dipping, porous, and permeable 10.1016/S0012-821X(98)00274-X.
REFERENCES CITED
sands and silts encased in low-permeability Brown, A.R., 2004, Interpretation of Three-dimensional Manuscript received 25 January 2010
mudstones, which provide an alternative stor- Seismic Data. American Association of Petroleum Revised manuscript received 30 May 2010
Geologists: 541 p. Manuscript accepted 6 June 2010
age site that would not be affected by changes Cartwright, J.A., 2007, The impact of 3D seismic data on
in ambient conditions. The dip of the sands and the understanding of compaction, fluid flow and dia- Printed in USA