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POLYMERS

POLYMER
1. Which of the following are addition copolymers? 5. Given below are two statements:
Statement I : Teflon is chemically inert and not
A. Polyacrylonitrile B. Nylon – 6
resistant to attack by corrosive reagents.
C. Buna – S D. Buna – N Statement II : Teflon is used in making oil seals
(1) A, C, D (2) A, B, D and gaskets and also used for non-stick surface
coated utensils.
(3) C and D (4) B and C In the light of the above statements, choose the
2. Match the column most appropriate answer from the options given
below:
Column – I Column – II
(1) Statement – I is correct and statement – II is
(Polymer) (Type of Polymer) incorrect.
(a) Low density (p) Addition (2) Statement – I and statement – II both are
polythene homopolymer correct.
(b) Nylon – 6 (q) Addition copolymer (3) Statement – I and statemnt – II both are
incorrect.
(c) Dacron (r) Condensation (4) Statement – I is incorrect and statement – II
homopolymer is correct.
(d) Buna-S Rubber (s) Condensation 6. Given below are two statements; one is labelled
copolymer as Assertion (A) and the other is labelled as
(1) a – p, b – s, c – q, d – r Reason(R) .
(2) a – p, b – r, c – s, d – q Assertion : HDP is chemically inert and tough
(3) a – q, b – s, c – r, d – p but flexible and a poor conductor of electricity.
(4) a – q, b – r, c – p, d – s Reason : HDP is used in insulation of electricity
3. Match the column carrying wires and manufacture of squeeze
Column – I Column – II bottles, toys and flexible pipes.
(Polymer) (Monomeric unit) In the light of the above statements, choose the
(a) Nylon – 6 (p) Terephthalic acid most appropriate answer from the options
given below :
(b) Dacron (q) Styrene (1) Both (A) and (R) are correct but (R) is not the
(c) Buna – S (r) Cellulose acetate correct explanation of (A).
(d) Rayon (s) Caprolactum (2) Both (A) and (R) are correct and (R) is the
(1) a – s, b – p, c – q, d – r correct explanation of (A).
(2) a – s, b – q, c – r, d – p (3) (A) is correct but (R) is not correct.
(3) a – p, b – r, c – s, d – q (4) (A) is not correct but (R) is correct.
(4) a – p, b – s, c – q, d – r 7. Given below are two statements:
4. Match the coloumn Statement-I : The polymers made by addition
Column – I Column – II polymerisation from two different monomers
(Polymer) (Uses of polymer) along with elimination of small molecules like
H2O, HCl etc., are termed as homopolymers.
(a) Polytetra In making
(p) Statement-II : The addition polymers formed by
Fluoroethene commercial fibers
the polymerisation of a single monomeric species
(b) High density (q) Tyre cords, Fabrics, are known as copolymers.
polythene ropes In the light of the above statements, choose the
(c) Nylon – 6 (r) Non-stick surface most appropriate answer from the options given
coated utensils below:
(d) Poly (s) Dustbins, buckets, (1) Statement-I is correct and statement-II is
incorrect.
acrylonitrile pipes
(2) Statement-I and statement-II both are
(1) a – p, b – q, c – r, d – s incorrect.
(2) a – p, b – r, c – s, d – q (3) Statement-I is incorrect and statement-II is
(3) a – r, b – s, c – q, d – p correct.
(4) a – r, b – p, c – s, d – q (4) Statement-I and statement-II both are
correct.

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8. Given below are two statements: 11. Given below are two statements:
Statement I: High density polythene is linear Statement – I : Copolymerisation is a
polymerisation reaction in which a mixture of
polymer.
more than one monomeric species allowed to
Statement II: HDP formed when addition polymerise & form a copolymer.
polymerisation of ethene takes place in Statement – II : Copolymer can be made by
hydrocarbon solvent in presence of Ziegler Natta chain growth & step growth polymerisation.
In the light of the above statements, choose the
catalyst at temperature below 300K and under most appropriate answer from the options given
pressure of 6-7 atomspheres. below :
In the light of the above statements, choose the (1) Statement I & II both are incorrect.
most appropriate answer from the options given (2) Statement I & II both are correct.
(3) Statement I is correct but II is incorrect.
below: (4) Statement I is incorrect but II is correct.
(1) Statement-I is correct and statement-II is 12. Given below are two statements:
incorrect. Statement-I : cis polyisoprene consists of
(2) Statement-I and statement-II are incorrect. various chains helds together by weak
(3) Statement-I and statement-II are correct. vanderwaal’s interactions & has a coiled
structure.
(4) Statement-I is incorrect while statement-II is Statement-II : Natural rubber is insoluble in
correct. non-polar solvents and is resistant to attack by
9. Given below are two statements: oxidising agents.
In the light of the above statements, choose the
Statement-I: The formation of terylene or
most appropriate answer from the options given
dacron by interaction of ethylene glycol and below:
terephthalic acid is an example of condensation (1) Statement-I is incorrect but statement-II is
polymerisation. correct.
(2) Statement-I is correct but statement-II is
Statement-II : Poly condensation reactions may incorrect.
result in the loss of simple molecules as water, (3) Statement I & II both are incorrect.
alcohol, hydrogen chloride etc. and lead to (4) Statement I & II both are correct.
formation of high molecular mass condensation 13. Given below are two statements:
Statement – I : PHBV is a aliphatic polyester
polymer.
polymer as one of the important biodegradable
In the light of the above statements, choose the polymer.
most appropriate answer from the options given Statement – II : PHBV is used in speciality
below: packaging, orthopaedic devices and in controlled
(1) Statement-I and statement-II both are release of drugs.
In the light of the above statements, choose the
correct. most appropriate answer from the options given
(2) Statement-I is correct and statement-II is below:
incorrect. (1) Statement- I is incorrect statement – II is
(3) Statement-I is incorrect and statement-II is correct.
(2) Both statement – I & II are incorrect.
correct. (3) Statement – I is correct but II is incorrect.
(4) Statement-I and statement-II both are (4) Statement I & II both are correct.
incorrect. 14. Given below are two statements:
10. (a) Bakelite obtained by condensation Statement–I: Nylon–2–Nylon–6 is a homopolymer.
Statement–II : It is a biodegradable polymer.
polymerisation of phenol & formaldehyde
In the light of the above statements, choose the
(b) Novolac is non linear initial product of most appropriate answer from the options given
polymerisation. below:
(c) Novolac on heating with formaldehyde (1) Statement – I is incorrect but statement – II is
undergoes cross linking to give bakelite. correct.
(2) Statement – I is correct but statement – II is
Which of the above statement is/are correct? incorrect.
(1) a, c (2) b, c (3) Both statement I & II are correct.
(3) a, b (4) all are correct. (4) Both statement I & II are incorrect.
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15. Match the column- I & II. 17. Match column I & II.
Column – I Column – II Column – I Column – II
(a) Natural (p) Copolymer of 1,3- Polymer Uses
rubber butadiene (a) Polypropene (p) Manufacture of
(b) Vulcanisation (q) Free radical Raincoat, Handbags
of rubber polymerisation of (b) PVC (q) Making ropes, toys,
chloroprene pipes & fibres
(c) Buna–S rubber (r) Cis–1,4 polyisoprene (c) Glyptal (r) Making unbreakable
(d) Neoprene (s) Mixing of sulphur
cups & laminated
(1) a – s, b – r, c – p, d – q
sheets
(2) a – r, b – s, c – p, d – q
(d) Urea (s) Making paints &
(3) a – r, b – p, c – q, d – s
formaldehyde lacqueres
(4) a – q, b – s, c – p, d – q
Resin
16. Match the column – I & II (1) a – s, b – r, c – p, d – q
Column – I Column – II
(2) a – q, b – r, c – p, d – s
Monomer Polymeric structure
(a) Styrene (p) (3) a – r, b – s, c – q, d – p

(b) Urea + (q) (4) a – q, b – p, c – s, d – r


formaldehyde 18. Assertion: Buna – N is an example of copolymer.
(c) Phenol + (r) – OCH2CH2OOC Reason : It is obtained by the polymerisation of
CO –
formaldehyde 1, 3-Butadiene & acrylonitrile in the presence of
peroxide catalyst.
(d) Ethylene (s) (1) Assertion & reason both are true & reason is
glycol + a correct explaination of the assertion.
(2) Assertion & reason both are true but reason
phthalic acid
is not a correct explaination of the assertion.
(1) a – s, b – q, c – p, d – r (3) If both assertion & reason are false.
(2) a – r, b – p, c – q, d – r (4) If both assertion is true but reason is false.
(3) a – s, b – p, c – q, d – r
(4) a – q, b – s, c – r, d – p

ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 2 1 3 4 3 2 1 1 1 2 2 4 1 2
Que. 16 17 18
Ans. 3 4 1

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