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Plastic recycling
Plastic recycling is the process of recovering scrap or waste plastic and reprocessing the
material into useful products. Since the majority of plastic is non-biodegradable, recycling
is a part of global efforts to reduce plastic in the waste stream, especially the
approximately 8 million metric tonnes of waste plastic that enters the Earth's ocean every
year.[1][2]
Compared with lucrative recycling of metal, and similar to the low value of glass recycling,
plastic polymers recycling is often more challenging because of low density and low
value. There are also numerous technical hurdles to overcome when recycling plastic.
Materials recovery facilities are responsible for sorting and processing plastics. As of
2019, due to limitations in their economic viability, these facilities have struggled to make
a meaningful contribution to the plastic supply chain.[3]
When different types of plastics are melted together, they tend to phase-separate, like oil
and water, and set in these layers. The phase boundaries cause structural weakness in
the resulting material, meaning that polymer blends are useful in only limited applications.
The two most widely manufactured plastics, polypropylene and polyethylene, behave this
way, which limits their utility for recycling. Each time plastic is recycled, additional virgin
materials must be added to help improve the integrity of the material. So, even recycled
plastic has new plastic material added in. The same piece of plastic can only be recycled
about 2–3 times before its quality decreases to the point where it can no longer be used.
[4]
The use of biodegradable plastics or plastics which can be organically recycled or can be
composted in industrial composting is increasing for certain short-lived packaging
applications.[9]
The percentage of plastic that can be fully recycled, rather than downcycled or go to
waste, can be increased when manufacturers of packaged goods minimize mixing of
packaging materials and eliminate contaminants. The Association of Plastics Recyclers
has issued a "Design Guide for Recyclability".[10]
Methods
Broadly, there are two major ways to recycle plastic:[11] (1) mechanical recycling ("chop
and wash"[12]), where the plastic is washed, ground into powders and melted, and (2)
chemical recycling, where the plastic is broken down into basic components.
Before recycling, most plastics are sorted according to their resin type. In the past, plastic
reclaimers used the resin identification code (RIC), a method of categorization of polymer
types, which was developed by the Society of the Plastics Industry in 1988.[citation
needed]Polyethylene terephthalate, commonly referred to as PET, for instance, has a resin
code of 1. Most plastic reclaimers do not rely on the RIC now; they use various sorting
systems to identify the resin, ranging from manual sorting and picking of plastic materials
to mechanized automation processes that involve shredding, sieving, separation by rates
of density i.e. air, liquid, or magnetic, and complex spectrophotometric distribution
technologies e.g. UV/VIS, NIR, Laser, etc.[13][Dead Link] Some plastic products are also
separated by color before they are recycled.
After sorting, for mechanical recycling the plastic recyclables are then shredded. These
shredded fragments then undergo processes to eliminate impurities like paper labels.
This material is melted and often extruded into the form of pellets which are then used to
manufacture other products. The highest quality purification may be referred to as
"regeneration".[14]
Thermal depolymerization
Main articles: Depolymerization and Thermal depolymerization
Scientists have estimated that the potential commodity value of waste plastic may be in
excess of $300 per ton when used in process pathways yielding high-value chemical
products or to produce electricity in efficient IGCC (Integrated Gasification Combined
Cycle) processes.[15]
Plastic pyrolysis can convert petroleum-based waste streams such as plastics into fuels
and carbons. [16]
[17]
[18]
[19]
[20]
Given below is the list of suitable plastic raw materials for pyrolysis:
Mixed plastic (HDPE, LDPE, PE, PP, Nylon, Teflon, PS, ABS, FRP etc.)
Mixed-waste plastic from waste paper mill
Multi-layered plastic.
Heat compression
Heat compression takes all unsorted, cleaned plastic in all forms, from soft plastic bags
to hard industrial waste, and mixes the load in tumblers (large rotating drums resembling
giant clothes dryers). The most obvious benefit to this method is that all plastic is
recyclable, not just matching forms. However, criticism rises from the energy costs of
rotating the drums, and heating the post-melt pipes.[21]
Distributed recycling
Distributed recycling of plastics using additive manufacturing (or DRAM) can include
mechanical grinding to make granules for 1) fused granular fabrication, 2) heated syringe
printing, 3) 3-D printed molds coupled to injection molding and 4) filament production in a
recyclebot to fused filament fabrication.[22] For some waste plastics, technical devices
called recyclebots[23] enable a form of distributed recycling by making 3-D printing
filament. Preliminary life-cycle analysis (LCA) indicates that such distributed recycling of
HDPE to make filament of 3D printers in rural regions is energetically favorable to either
using virgin resin or conventional recycling processes because of reductions in
transportation energy.[24][25]
Chemical recycling
For some polymers, it is possible to convert them back into monomers, for example, PET
can be treated with an alcohol and a catalyst to form a dialkyl terephthalate. The
terephthalate diester can be used with ethylene glycol to form a new polyester polymer,
thus making it possible to use the pure polymer again.
In 2019, Brightmark Energy in the United States began building a facility to convert
100,000 tons of mixed plastic per into diesel, naphtha blend stocks, and wax;[27] the
company plans to expand into building another plant which can process an additional
800,000 tons of plastic per year.[3] The company has said that the economics have a
significant margin of safety from price declines.[28]
Other processes
A process has also been developed in which many kinds of plastic can be used as a
carbon source (in place of coke) in the recycling of scrap steel.[29] There are also
possibilities for better recycling of mixed plastics, avoiding the need for
expensive/inefficient separation of the plastic waste stream. One such method is called
compatibilization which uses special chemical bridging agents called compatibilizers to
maintain the quality of mixed polymers.[30]
Applications
PET
Main article: PET bottle recycling
One use for this recycled PET is to create fabrics to be used in the clothing industry.[32]
The fabrics are created by spinning the PET flakes into thread and yarn.[31] This is done
just as easily as creating polyester from brand new PET.[33] The recycled PET thread or
yarn can be used either alone or together with other fibers to create a very wide variety of
fabrics. Traditionally these fabrics are used to create strong, durable, rough products,
such as jackets, coats, shoes, bags, hats, and accessories since they are usually too
rough for direct skin contact and can cause irritation.[34] However, these types of fabrics
have become more popular as a result of the public's growing awareness of
environmental issues. Numerous fabric and clothing manufacturers have capitalized on
this trend.[citation needed]
Other major outlets for RPET are new containers (food-contact or non-food-contact)
produced either by (injection stretch blow) moulding into bottles and jars or by
thermoforming APET sheet to produce clamshells, blister packs and collation trays.
These applications used 46% of all RPET produced in Europe in 2010.[citation needed] Other
applications, such as strapping tape, injection-moulded engineering components and
building materials, account for 13% of the 2010 RPET production.[citation needed]
In the United States, the recycling rate for PET packaging was 31% in 2013, according to a
report from The National Association for PET Container Resources (NAPCOR) and The
Association of Postconsumer Plastic Recyclers (APR). A total of 1.798 billion pounds was
collected and 475 million pounds of recycled PET used out of a total of 5.764 billion
pounds of PET bottles.[35]
HDPE
PS
Most polystyrene products are not recycled due to the lack of incentive to invest in the
compactors and logistical systems required. As a result, manufacturers cannot obtain
sufficient scrap. Expanded polystyrene (EPS) scrap can easily be added to products such
as EPS insulation sheets and other EPS materials for construction applications. When it is
not used to make more EPS, foam scrap can be turned into clothes hangers, park
benches, flower pots, toys, rulers, stapler bodies, seedling containers, picture frames, and
architectural molding from recycled PS.[37]
Recycled EPS is also used in many metal casting operations. Rastra is made from EPS
that is combined with cement to be used as an insulating amendment in the making of
concrete foundations and walls. Since 1993, American manufacturers have produced
insulating concrete forms made with approximately 80% recycled EPS.[citation needed]
Other plastics
The white plastic polystyrene foam peanuts used as packing material are often accepted
by shipping stores for reuse.[38]
Successful trials in Israel have shown that plastic films recovered from mixed municipal
waste streams can be recycled into useful household products such as buckets.[39]
Similarly, agricultural plastics such as mulch film, drip tape and silage bags are being
diverted from the waste stream and successfully recycled[40] into much larger products
for industrial applications such as plastic composite railroad ties.[41] Historically, these
agricultural plastics have primarily been either landfilled or burned on-site in the fields of
individual farms.[42]
CNN reports that Dr. S. Madhu of the Kerala Highway Research Institute, India, has
formulated a road surface that includes recycled plastic: aggregate, bitumen (asphalt)
with plastic that has been shredded and melted at a temperature below 220 °C (428 °F) to
avoid pollution. This road surface is claimed to be very durable and monsoon rain
resistant. The plastic is sorted by hand, which is economical in India. The test road used
60 kg of plastic for an approximately 500-meter-long, 8-meter-wide, two-lane road. The
process chops thin-film road-waste into a light fluff of tiny flakes that hot-mix plants can
uniformly introduce into viscous bitumen with a customized dosing machine. Tests at
both Bangalore and the Indian Road Research Centre indicate that roads built using this
'KK process' will have longer useful lives and better resistance to cold, heat, cracking, and
rutting, by a factor of 3.[43]
Some new innovations propose plastics much easier recycled, like 2019
polydiketoenamines. (PDK)[44]
Equipment vendors
In 2016, startup Precious Plastic created a marketplace called Bazar for selling machines
and products targeted to DIY designers to recycle plastic.[47]
Recycling rates
The quantity of post-consumer plastics recycled has increased every year since at least
1990, but rates lag far behind those of other items, such as newspaper (about 80%) and
corrugated fiberboard (about 70%).[48] Overall, U.S. post-consumer plastic waste for 2008
was estimated at 33.6 million tons; 2.2 million tons (6.5%) were recycled and 2.6 million
tons (8%) were burned for energy; 28.9 million tons, or 86%, were discarded in landfills.[49]
As of 2015, approximately 6.3 billion tons of plastic waste had been generated, around 9%
of which had been recycled, 12% was incinerated, and 79% was accumulated in landfills
or the natural environment.[50] In 2016 only 14% of plastic waste was recycled globally.[51]
According to the EPA, the recycling rate for plastics overall was 9.1% in 2015. Certain
products have higher rates, such as PET bottles and jars at 29.9%, and HDPE natural
bottles at 30.3%. These rates are lower than certain other materials, like steel cans, that
had an estimated recycling rate of 71.3% in 2015.[52][53]
Japan's plastic waste utilization rate stood at 39% in 1996, increasing to 73% in 2006, 77%
in 2011,[54] 83% in 2014[55] and 86% in 2017, according to the nation's Plastic Waste
Management Institute.[56]
Economic and energy potential
This article needs to be updated. The reason given is: Impacts of "National Sword Policy"
on commodity prices. Please update this section to reflect recent events or newly
available information. (December 2018)
In 2008, the price of PET dropped from $370/ton in the US to $20 in November.[57] PET
prices had returned to their long-term averages by May 2009.[58]
Seven groups of plastic polymers,[59] each with specific properties, are used worldwide for
packaging applications (see table below). Each group of plastic polymer can be identified
by its plastic identification code (PIC), usually a number or a letter abbreviation. For
instance, low-density polyethylene can be identified by the number "4" or the letters
"LDPE". The PIC appears inside a three-chasing-arrow recycling symbol. The symbol is
used to indicate whether the plastic can be recycled into new products.[citation needed]
The PIC was introduced by the Society of the Plastics Industry, Inc., to provide a uniform
system for the identification of various polymer types and to help recycling companies
separate various plastics for reprocessing. Manufacturers of plastic products are required
to use PIC labels in some countries/regions and can voluntarily mark their products with
the PIC where there are no requirements.[60] Consumers can identify the plastic types
based on the codes usually found at the base or at the side of the plastic products,
including food/chemical packaging and containers. The PIC is usually not present on
packaging films, since it is not practical to collect and recycle most of this type of waste.
[clarification needed][citation needed]
Melting- and
Plastic Type of Common glass Young's
identification plastic Properties packaging transition modulus
code polymer applications temperatures (GPa)
(°C)
Soft drink, water
Clarity, and salad
strength, dressing bottles;
Polyethylene peanut butter
toughness, Tm = 250;[61]
terephthalate and jam jars; ice Tg = 76[61] 2–2.7[62]
barrier to
(PET, PETE) cream cone lids;
gas and
moisture. small consumer
electronics
Water pipes ,
Gas & Fire
Pipelines ,
Electrical &
Stiffness,
Communications
strength,
conduit,[63] hula
High-density toughness,
hoop rings, five Tm = 130;[64]
polyethylene resistance 0.8[62]
gallon buckets, Tg = −125[65]
(HDPE) to moisture,
milk, juice and
permeability
water bottles;
to gas
grocery bags,
some
shampoo/toiletry
bottles
Blister packaging
for non-food
items; cling films
for non-food use.
May be used for
food packaging
with the addition
Versatility,
of the
Polyvinyl ease of
plasticisers Tm = 240;[66]
chloride blending, 2.4–4.1[67]
needed to make Tg = 85[66]
(PVC) strength,
natively rigid
toughness.
PVC flexible.
Non-packaging
uses are
electrical cable
insulation; rigid
piping; vinyl
records.
Ease of
Frozen food
processing,
bags;
strength,
squeezable
Low-density toughness,
bottles, e.g. Tm = 120;[68]
polyethylene flexibility, 0.17–0.28[67]
honey, mustard; Tg = −125[69]
(LDPE) ease of
cling films;
sealing,
flexible container
barrier to
lids
moisture.
Reusable
microwaveable
Strength, ware;
toughness, kitchenware;
resistance yogurt
Polypropylene to heat, containers; Tm = 173;[70]
1.5–2[62]
(PP) chemicals, margarine tubs; Tg = −10[70]
grease and microwaveable
oil, versatile, disposable take-
barrier to away containers;
moisture. disposable cups;
soft drink bottle
caps; plates.
Egg cartons;
packing peanuts; Tm = 240 (only
Versatility,
disposable cups, isotactic);[65]
Polystyrene clarity,
plates, trays and Tg = 100 3–3.5[62]
(PS) easily
cutlery; (atactic and
formed
disposable take- isotactic)[65]
away containers
Beverage bottles,
baby milk
bottles. Non-
packaging uses
for
polycarbonate,
compact discs,
"unbreakable"
Dependent glazing,
Other (often on polymers electronic Polycarbonate: Polycarbonate:
polycarbonate or apparatus Tg = 145;[72] 2.6;[62] ABS
or ABS) combination housing, lenses Tm = 225[73] plastics: 2.3
of polymers (including
sunglasses),
prescription
glasses,
automotive
headlamps, riot
shields,
instrument
panels.[71]
The Ocean Conservancy reported that China, Indonesia, Philippines, Thailand, and
Vietnam dump more plastic in the sea than all other countries combined.[74] Scientific
American reported that China dumps 30% of all plastics in the ocean, followed by
Indonesia, the Philippines, Vietnam, Sri Lanka, Thailand, Egypt, Malaysia, Nigeria and
Bangladesh.[75]
United States
In 2015, the United States produced 34.5 million tons of plastic, which was about 13% of
total waste.[76] About 9% of that was recycled. Most of the waste stream is biodegradable
but plastic though only 13% of the waste stream is persistent and accumulates.[76]
Low national plastic recycling rates have been due to the complexity of sorting and
processing, unfavorable economics, and consumer confusion about which plastics can
actually be recycled.[77] Part of the confusion has been due to the use of the resin
identification code,[78] which is only found on a subset of plastic products,[79] and which
includes the recycling symbol as part of its design. The resin identification code is
stamped or printed on the bottom of containers and surrounded by a triangle of arrows.
(See the table in Plastic.) The intent of these symbols was to make it easier to identify the
type of plastics used to make a particular container and to indicate that the plastic is
potentially recyclable. The question that remains is which types of plastics can be
recycled by local recycling centers. In many communities, not all types of plastics are
accepted for sidewalk recycling collection programs due to the high processing costs and
complexity of the equipment required to recycle certain materials. There is also
sometimes a seemingly low demand for the recycled product depending on a recycling
center's proximity to entities seeking recycled materials. Another major barrier is that the
cost to recycle certain materials and the corresponding market price for those materials
sometimes does not present any opportunity for profit. The best example of this is
polystyrene (commonly called styrofoam), although some communities, like Brookline,
Massachusetts, are moving toward banning the distribution of polystyrene containers by
local food and coffee businesses.[80][81]
See also
Environment portal
Baler
Glass recycling
Microplastics
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External links
West, Larry. "Recyclable Plastic: Why are So Few Food Containers Made of Recyclable
Plastic?" . About.com. Retrieved 4 May 2009.
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