ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE: 2024

TOPIC:ISOMERISM

SECTION–I (Multiple Choice Questions)

This section contains 05 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out which ONLY ONE is correct.

1. Metamer of compound B is:

B: OCH3

CH3

OCH3
H3C OCH3
(a) CH3 (b)
CH3

OCH3 OCH2CH3
(c) (d)

2. Out of the following which are chiral?

H3C H3C Cl

CH3 CH3 CH3

(A) (B) (C) CH3
(a) A,B (b) B,C (c) A,C (d) Only C

3. ( 2R,3R ) − 2,3 bantanediol is:

CH3 OH CH3 CH3
HO H H CH3 H OH HO H
H OH HO H H OH HO H

(a) CH3 (b) CH3 (c) CH3 (d) CH3

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

4. Relate the following compounds:
HO H
CH3 OH
H H3C
C C

C C
H CH3
H3C HO
OH H
(a) Homomers (b) Enantiomers (c) Diastereomers (d) Different compounds

5. Which of the following pairs of structures represents conformation isomers?

H3C
H3C H C
CH and 3
(a) 3

H3C H3C
CH and 3

(b) CH3

H3C CH3 H3C

and

(c) CH3
H3C
C
C and
H3C CH3
(d) CH3

SECTION-II (Multiple Choice Questions)

This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)
for its answer, out which ONE OR MORE is/are correct.

6. In which of the following the enol form is dominant over keto form?
O

O CH3
O

N O
(a) H (b) O (c) (d) OH

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2

7. Which of the following compounds have the plane of symmetry?

Cl

Cl
(a) (b)

O O
(c) (d)

8. Which of the compounds shown below are isomers?

(a) (b) (c) (d)

SECTION – III (Integer Answer Type)

This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging
from 0 to 9. The correct digit below the question number in the ORS is be bubbled.

9. Find out number of stereogenic centers present in following compound ‘simvastatin’

O
OH
H3C O
H3C CH3 O

O
H3C

10. Find out number of compounds those have ‘S’ configuration from following
H CH3
H3C
COOH
CH3 COOH
H3CO
H3C H
H CH2CH2NH CH3

O CF3

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3

 OH H
Cl OH
H H3C CH2OH
CH2CH3 HH3C CH2CH3
CH3 CH3CH2 C
Br H O H
CH3
11. Total number of stereoisomer possible for the compound
H 3C − CH = CH − CH = CH − CH = CH − Ph

12. Find out number of conformation those have Cis geometry.

CH3
H3C CH3 , , Cl
CH3 Cl

Cl
CH3
, ,
Cl
Cl Cl
CH3

13. Find out number of structural isomers possible for C6 H14 .

SECTION – IV (Paragraph Type)

This section contains 2 multiple choice questions relating to 1 paragraph. Each question has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Passage (Que. No.14 to Que. No.15)

Cyclohexane exist as two chair conformation in rapid equilibrium at room temperature.
Each carbon atom on a cyclohexane ring has one axial and one equatorial hydrogen. Ring – flipping
converts axial H’s to equatorial H’s and vice-versa.

Hax
ring-flip
Heq Heq

Hax

In substituted cyclohexane, groups larger than hydrogen are more stable in the equatorial position
The cis isomer has two groups on the same side of the ring, either both up or both down.
The trans isomer has two groups on opposite side of the ring one up and one down.
14. Which of the following is most stable conformer of 1,2 – dichlorocyclohexane?
Cl
Cl

Cl
Cl
(a) Cl (b) (c) Cl (d) All have equal stability

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

15. Find out most stable conformer of cis-3fluorocyclohexanol:
F F
H O OH
F OH F OH

(a) (b) (c) (d)

SECTION - IV (Matrix Match Type)

This section 1 Question. Each question has four statements Given in Column - I and four statements in
Column – II. Any given statement in Column – I can have correct matching with one or more statement
(s) given in column II.

16.
Column – I Column - II
(a) Cl H P. Polar molecule
C C C C
H Cl
(b) H H Q. Optically active
C C C
H Cl
(c) R. Optically incactive
Cl Cl

(d) H S. Symmetry element

H F

H H
H

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 6