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1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Main use category : Consumer use,Professional use
Use of the substance/mixture : Engine oil
GHS07
Signal word (CLP) : Warning
Contains : Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivs., calcium salts; Alkyl
(C18-C28) toluenesulfonic acid, calcium salts, borated
Hazard statements (CLP) : H317 - May cause an allergic skin reaction.
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P501 - Dispose of contents/container to properly labelled waste containers according to the
national law.
3.1. Substances
Not applicable
3.2. Mixtures
Alkyl (C18-C28) toluenesulfonic acid, calcium salts, CAS-No.: 953-650-0 0.77 – 1.54 Skin Sens. 1B, H317
borated Repr. 2, H361d
Benzenesulfonic acid, methyl-, mono-C20-24- CAS-No.: 722503-68-6 0.154 – 0.77 Skin Sens. 1B, H317
branched alkyl derivs., calcium salts EC-No.: 682-816-2
Alkyl (C18-C28) toluenesulfonic acid, calcium salts, CAS-No.: 953-650-0 ( 17.15 ≤C < 100) Repr. 2, H361d
borated
Full text of H- and EUH-statements: see section 16
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Take off contaminated clothing. After contact with skin, wash immediately with plenty of
water and soap. If irritation persists, consult a doctor. Wash skin with plenty of water. Take
off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention.
First-aid measures after eye contact : In case of eye contact, immediately rinse with clean water for 10-15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If irritation persists, consult a
doctor. Rinse eyes with water as a precaution.
First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/effects after inhalation : May cause headache, nausea and irritation of respiratory tract.
Symptoms/effects after skin contact : May cause an allergic skin reaction.
Symptoms/effects after eye contact : redness, itching, tears.
Symptoms/effects after ingestion : Abdominal pain, nausea.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Protection during firefighting : Do not attempt to take action without suitable protective equipment . Self-contained
breathing apparatus. Complete protective clothing.
Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Avoid
breathing dust/fume/gas/mist/vapours/spray. Wear personal protective equipment.
Hygiene measures : Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reuse. Do not eat, drink or smoke when using this product.
Always wash hands after handling the product.
PNEC (Oral)
Eye protection:
Safety glasses (EN 166). Safety glasses
Hand protection:
Protective gloves
Respiratory protection:
In case of insufficient ventilation, wear suitable respiratory equipment
10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
None under recommended storage and handling conditions (see section 7).
Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts (68784-31-6)
LD50 dermal rabbit > 5000 mg/kg bodyweight Animal: rabbit, Guideline: OECD Guideline 402 (Acute Dermal
Toxicity)
Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts (68784-31-6)
Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts (68784-31-6)
pH ≈ 7 Temp.: 25 °C Concentration: (≈)0,00116 other: Remarks on result: 'other:'
Respiratory or skin sensitisation : May cause an allergic skin reaction. (based on the data for the individual components of the
product)
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts (68784-31-6)
NOAEL (oral, rat, 90 days) 125 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 407 (Repeated Dose 28-
Day Oral Toxicity Study in Rodents)
Aspiration hazard : Not classified (Kinematic viscosity at 40˚C >20.5 mm2/s)
12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Not classified
(chronic)
Not rapidly degradable
Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts (68784-31-6)
LC50 - Fish [1] 46 mg/l Test organisms (species): Cyprinodon variegatus
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Rail transport
Not applicable
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
EN European Standard
Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]:
Skin Sens. 1 H317 Calculation method
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.