-

( volume of HUT ¥w)

NaOH t HU → Naut H2O

can
if 1- HU T
Naut Hzcoz
• →
Nanao ,

( Ig ) Nacl Ph )
Matteo , -1
( Ig)aIazWz t HU →

• if Nancy
t KU → Naut Haws ( Meon)
.

a)
Methylorange
HU → Nau t
thug
NaHWzt
µ,

Nacht
Nazcoggt Hee → Hoo,

-
 gmeqtlce =
gmeg of Natwest gmegrft
Narco>
grof
( XV =
I + 1×2 +
I NaOH

84 106 40

|YV=0.05
(b) phenolic only .

NaOH THU → Nacl -17120

\ I
-
-

Nazoozt HU → Nacl
Naltcozt

gmeq of HU =
gmeg .

of NaOH t gmg
Naw

IXV = I t I
40 106

µ=o-o3
HU
(C) Na
Hwy t → Nacl 1-
thug
( Ig)
Nacl Hzug
Na Hwy 'T HU → t
 of tea gmeg of Nancy
guy
= -

( original)
+ gmycfNauw@
IXV = I A-
gut

room gmegofwauw,
=

gneqofnatiw
,
 (9) 0.055 L

(b) O 034L
-

(C) o - 021 L

- -

Hz soy =
NaOH

NXV =
g-
C-quit

2.5112N XV =
I
40

v=
Iii !
=
i⑦
-

Al
gmeg of Hgsoy gmeg of
-
=
-

2×4-2 Xv =
×③→nf
27
a-

÷
.

.
. .
. .
. .

- -
Back Titration
-

To
gases /
→ estimate solids

which can't be titrated

directly
→ Tn this an excess of a
reagent
is taken

a Lexus

NaOH t Hel
t a

⑨ ? ⑤
IL 3L

Igmeq 5gnxq .

Excess ha is Heated with another

E)NaOH solution (eN )

Excess HU = NaOH (2)

-

IN XV = 2X D. 5

VI IL

original NaOH
original KU =

IXN N=2N
2X IN =
 a-T
I
CMTt

m, 2.5M NaOH
←
t H2 Y
( Mu)
M ?
v
,
← 100mL .

90mL
( vz )

d
expats v
of NaOH Cs )

37 XO 48-
= M XV,
,

37×0-48 =
2.5×3

Vz = 7.104mL

nfXMzVz = M
, ( Vi -

vz ) X1

( Huson)

2 X MX 90 = 2.5 ( 92.89
)
|M=lu29MJ
 en or
O

Nazcoz NAH coz

d
t

ngm ( 1.2 - n ) g .

#h
Alina →
Nancy -1 Na

417 tell Naut

Nancy Haug myeon
t →

B .

Nancy T HU → Nacl tha coz Meon

✓

gmeg of
gmeqofrvazlozo
KU =

-5×15 =
n
"
-

1000
to

n= 0.79

%= 66% →
Nag cos