#1

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Identify +I or -I effect of the encircled group in Q.1 to Q.20

O

]
OH + –
N O

TB
1.
6.
O
OH
[II NH3
+
NA
2. 7.

CH3
8. H3C CH2
RA

3. H3C CH

9.
O
IN

CH3
H2C
CH

4. 10. CH
SA

CH D

5. 11. D CH2

Page No. 1
 NH2

O
OH
12. S
O

17.
+
13. H3C CH2

18. H3C CH3

O
+ –
– N CH2

]
14. O
CH3

TB
19.
–
Cl CH2
15.

[II
CH3

Cl
20.
NA
16.
RA
IN
CH
SA

Page No. 2
 ANSWERS

1. +I
2. -I
3. +I
4. -I
5. -I
6. -I
7. +I
8. +I

]
TB
9. +I
10. -I
11. +I
12. -I
13. +I
14. -I
15. -I
[II
NA
16. -I
17. -I
18. None
19. +I
RA

20. None
IN
CH
SA

Page No. 3
 #2
DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Identify the inductive effect of each atom/group of the

encircled group.

]
TB
CH3 F

1.
CH3
6.

[II CH2
NA
2.
CH3 CH3 7.
RA

8.
HO
OH
P
3. O
O
IN

O
9.
CH

Cl
O S O
4.
SA

H3C
O
10.

5.

Page No. 1
 F N
F F
O S O

19.
11.
CH

20.

12.

]
OH

TB
21.
13.
CH3
SH

14. 22.
[II
NA
Br O

HN CH3

15.
RA

Cl
23.
O
NH2
16.
IN

CH3

24.
CH

O
17. N
F
F F
SA

25.
O
S OH
18.
26. O

Page No. 2
 – CH2
C
N
+ 36. H2C

37. H2C CH3

CH3
27.
O O
CH3 CH3

38. CH3

28.
O

]
39.

TB
O
CH3
29.
O
CH3
40.

30.
CH2
[II CH3
NA
41.
31. HC CH3
O
CH3
H2C
32.
RA

H2C
42.
N

33. CH3
IN

43.
H2C
CH3
34. N O
CH

O 44.
H2C

NH2
35.
SA

Page No. 3
 ANSWERS

1. +I 33. +I
2. +I 34. +I
3. +I 35. +I
4. -I 36. None
5. -I 37. +I
6. -I 38. +I
7. +I 39. -I
8. None 40. -I

]
9. -I 41. +I

TB
10. -I 42. +I
11. -I 43. -I
12. -I 44. -I
13. -I
14. -I
15. -I [II
NA
16. -I
17. +I
18. -I
19. -I
RA

20. +I
21. +I
22. +I
23. -I
IN

24. -I
25. -I
CH

26. -I
27. -I
28. -I
SA

29. -I
30. None
31. -I
32. +I

Page No. 4
 #3
DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Draw resonance hybrid of the following structures:

+ +
CH CH

]
TB
1. 8.
+
CH +
9. H2C CH2

2.

+
[II
10. H3C
CH
+

CH3
NA
HC
CH3
3.
11. H2C

+
CH
RA

+
12. H2C CH2

4.
+
CH
+ H3C CH3
CH
IN

5. 13. CH3

+
14. H2C
CH

CH2

6.
+
H2C C CH2
+
CH2
SA

15. CH2

7.

Page No. 1
 +
PH3

+
C

16. 25.

H2C +
CH

26.
+
C
+
17. CH

27.

]
+

TB
+ CH
CH
18.

CH
+ 28.

19.
[II H3C
CH
+
NA
20. 29.
CH2
+
CH
21.
RA

+
HC

+
CH
+
22. CH
30.
IN

+
CH +
CH CH2
+
CH
23.
31.
CH

+
NH3
SA

24.

Page No. 2
 ANSWERS

]
TB
[II
NA
RA
IN
CH
SA

Page No. 3
 SA

Page No. 4
CH
IN
RA
NA
[II
TB
]
 #4
DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Draw Resonating structures and resonance hybrid of the

following species:

]
TB
–
– CH
H2C CH2
1.

7.

[II
O
H3C
– O
2. O
NA
– –
NH2 8. O O

O
CH3
RA

3.
9.
–
CH
Cl

4.
IN

10.
NH2
CH

–
H2C CH3
O 11.
5.

O
H3C
–
SA

C
NH2
12.
6.

Page No. 1
 –
CH

13.

–
CH

14.

CH3
O

]
TB
15. O

16.
H3C O

CH3

[II
NA
–
O

17.
RA

18. H3C OH
IN
CH
SA

Page No. 2
 ANSWERS

]
TB
[II
NA
RA
IN
CH
SA

Page No. 3
 #5
DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Draw Resonance Hybrid of the following compounds:

]
TB
CH3 O
6. H2C

1. H2C OH CH3

2. H3C
CH3

[II
7. H2C

O
NH

CH3
NA
CH3
H3C –
CH

3. O 8.
RA

NH2
NH2
IN

4.
–
CH

9. H O
SA

10. H2N O

5. O CH3

Page No. 1
 – –
O O O O
N

19. O

–
11. O O
20. O C O

H O
O N
21. H3C
–
12. O
H2N NH2

HC

]
22. NH

TB
13.
23.
+
CH
+
CH2

[II
O

14. 24. H3C OH

NA
S O O
+
15. H2C CH3

–
O 25. CH
RA

+ +
N CH
–
16. H3C O

–
CH2
IN

26.
–
CH
CH

27.
+
N
SA

–
17. O O

18. H2N C N

Page No. 2
 O –
O O

–
30. O

–
28. CH

]
TB
–
29. O

[II
NA
RA
IN
CH
SA

Page No. 3
 ANSWERS

]
TB
[II
NA
RA
IN
CH
SA

Page No. 4
 SA

Page No. 5
CH
IN
RA
NA
[II
TB
]