JEE Advanced, Main 2023

#11

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: 19

1. Identify the group which exert -I, -M & +M effect

(a) -NO2 (c) -SO2H

]
(b) -NO (d) -C≡N

TB
2. Identify the group which exert -I, -M & +M effect
(a) -C=CH2
(b) -C≡CH
(c) -Ph
[II
(d) All of these
NA
3. Which of the following is the strongest withdrawing group?
(a) -F (c) -N+H3
(b) -O+H2 (d) -NH-COCH3
RA

4. Group showing the strongest +M effect:

(a) -NH2 (c) -NH-CH3
(b) -N(CH3)2 (d) -O-
IN

5. Which of the following is correct order of +M effect?

(a) NH2 > -OH (c) -O-COCH3 > -OH
CH

(b) -OH > -O -

(d) -NH-COCH3 > -NH2

6. Which of the following show both +M and -M effect?

SA

(a) -Cl (c) -F

(b) -CH=CH2 (d) -Ph

Page No. 1
7. Which of the following is showing greater +M effect?
(a) F (c) Br
(b) Cl (d) I

8. Which of the following group when attached to benzene ring

show withdrawing effect?
(a) -N+R3 (c) -C2H5
(b) -P+R3 (d) -OCH3

9. What is the correct order of +R effect?

(A) -O- (C) -NH2
(B) -COOR (D) -OH

]
TB
(a) A>D>C>B (c) A>C>D>B
(b) A>B>C>D (d) A>D>B>C

(b) -N R3
+
[II
10. Which of the following is releasing group when in resonance?
(a) -N+H3 (c) -NH-COCH3
(d) -F
NA
RA
IN
CH
SA

Page No. 2
 ANSWERS

1. bc
2. d
3. c
4. d
5. a
6. abd
7. a
8. ab
9. c
10. cd

]
TB
[II
NA
RA
IN
CH
SA

Page No. 3
 JEE 2022, 2023

Class XI Organic Chemistry #12

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Sl. Compound Huckel’s All carbon of Cyclic Complete Nature

]
No. Rule the ring is Delocalisation

TB
(4n + 2)π e-
sp or sp
2

1.

2. [II
NA
N OH

3.
RA

4.
IN
CH

5.
SA

Page No. 1
Sl. Compound Huckel’s All carbon of Cyclic Complete Nature
No. Rule the ring is Delocalisation
(4n + 2)π e-
sp or sp
2

6.
NH

7. NH

]
8.

TB
NH O

9.

[II
N
NA
N

10. BH
RA
IN
CH
SA

Page No. 2
 ANSWERS

1. ✕, ✕, ✓, ✕, Non-Aromatic

2. 6π, ✓, ✓, ✓, Aromatic

3. ✕, ✕, ✓, ✕, Non-Aromatic
4. 6π, ✓, ✓, ✓, Aromatic

5. ✕, ✓, ✓, ✓, Anti-Aromatic

]
6. ✕, ✕, ✓, ✕, Non-Aromatic

TB
7. 6π, ✓, ✓, ✓, Aromatic

8. 6π, ✓, ✓, ✓, Aromatic
9. 6π, ✓, ✓, ✓, Aromatic

10. ✕, ✓, ✓, ✕, Anti-Aromatic [II

NA
RA
IN
CH
SA

Page No. 3
 JEE 2022, 2023

Class XI Organic Chemistry #13

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Q. Classify the following compounds as Aromatic (Aro), Anti-

Aromatic (AA) or Non-Aromatic (NA):

]
TB
1.
8.
–
HC

[II
–
CH
2.

HC
+ 9.
NA
3. +
CH

+
CH
RA

10.
4.
+
CH
BH
–
CH
IN

– 11.
5. CH

+
CH
CH

O
6. O

12.
SA

BH
7. O O
O

13.

Page No. 1
 ANSWERS

1. NA
2. AA
3. Aro
4. Aro
5. Aro

]
6. NA

TB
7. NA
8. NA
9. Aro
10. AA
11. AA
[II
NA
12. Aro
13. Aro
RA
IN
CH
SA

Page No. 2
 JEE 2022, 2023

Class XI Organic Chemistry #14

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Q. Classify the following compounds as Aromatic (Aro), Anti-

Aromatic (AA) or Non-Aromatic (NA):

]
TB
1.

7. O

[II
O

2. 8.
NA
+
CH
S

3.

9.
RA

NH

4.
IN

10.

5. O
CH

+
CH
11. O O
SA

6. O

Page No. 1
 ANSWERS

1. AA
2. Aro
3. Aro
4. Aro
5. NA
6. Aro

]
7. NA

TB
8. NA
9. Aro
10. NA
11. Aro [II
NA
RA
IN
CH
SA

Page No. 2
 JEE 2022, 2023

Class XI Organic Chemistry #15

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Q. Classify the following compounds as Aromatic (Aro), Anti-

Aromatic (AA) or Non-Aromatic (NA):

]
O N

TB
N
5.

1. O

[II
NA
6. NH

2. NH O
RA

7.
+
NH

N
IN

NH
3. NH
8.
N
CH

+
HN
NH

9.
4. N
SA

Page No. 1
 ANSWERS

1. Aro
2. Aro
3. Aro
4. Aro
5. Aro
6. NA

]
7. Aro

TB
8. Aro
9. Aro

[II
NA
RA
IN
CH
SA

Page No. 2
 JEE 2022, 2023

Class XI Organic Chemistry #16

DPP NO. (JEE MAIN+ADVANCED)

Max Marks: Max Time:

Q. Classify the following compounds as Aromatic (Aro), Anti-

Aromatic (AA) or Non-Aromatic (NA):

]
TB
– –
CH N

1.

O
[II
5.
NA
6. NH
2.
RA

S
N
7.
IN

3. O
CH

8.
H3C

B N
SA

N N

9. HN N

4.

Page No. 1
 ANSWERS

1. Aro
2. AA
3. Aro
4. Aro
5. Aro
6. NA

]
7. Aro

TB
8. Aro
9. Aro

[II
NA
RA
IN
CH
SA

Page No. 2