Paper-1 Chemistry PC

CHEMISTRY
PART : III CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION-1 (Maximum Marks : 12)
 This section contains FOUR (04) questions.
 Each question has FOUR options ONLY ONE of these four options is the correct answer.
 For each question, choose the correct option corresponding to the correct answer.
 Marking scheme :
 Full Marks : +3 If ONLY the correct option is chosen.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases.
[kaM 1 ¼vf/kdre vad% 12½

 bl [kaM esa pkj (04) iz'u gSA
 izR;sd iz'u ds fy, lgh pkj fodYi fn, x, gSaA bu pkj fodYiksa esa ls dsoy ,d gh fodYi lgh mÙkj gSA
 izR;sd iz'u ds fy, fn, gq, fodYiksa esa ls lgh mÙkj ls lacf/kr fodYi dks pqfu,A
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
iw.kZ vad % +3 ;fn flQZ lgh fodYi gh pquk x;k gSA
'kwU; vad % 0 ;fn dksbZ Hkh fodYi ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
_.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
37. Consider the following two carbonyl compounds:

(i) [Tc(CO)6]+ and (ii) [Nb(CO)6]–1 [Atomic number Tc = 43, Nb = 41]
Select correct statement for given carbonyl compounds:
(A) [Tc(CO)6]+ acts as a reducing agent and [Nb(CO)6]–1 acts as oxidizing agent
(B) Bond order of C–O bond in both [Tc(CO)6]+ and [Nb(CO)6]–1 is 3
(C) Nb–C bond order in [Nb(CO)6]–1 is greater than Tc–C bond order in [Tc(CO)6]+1
(D) C–O bond order is greater in [Nb(CO)6]–1 than in [Tc(CO)6]+1
Space for Rough Work / (dPps dk;Z ds fy, LFkku)
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CHEMISTRY
fuEu nks dkcksZfuy ;kSfxdks dk voyksdu dhft,&
(i) [Tc(CO)6]+ rFkk (ii) [Nb(CO)6]–1 [ijek.kq Øekad Tc = 43, Nb = 41]
CHEMISTRY
fn;s x;s dkcksZfuy ;kSfxdks ds fy, lgh dFku dk p;u dhft,&
(A) [Tc(CO)6]+ vipk;d ds leku rFkk [Nb(CO)6]–1 vkWDlhdkjd ds leku dk;Z djrk gSA
(B) nksuks [Tc(CO)6]+ rFkk [Nb(CO)6]–1 es C–O ca/k dk ca/k Øe 3 gSA
(C) [Nb(CO)6]–1 es Nb–C ca/k Øe [Tc(CO)6]+1 es Tc–C ca/k Øe ls vf/kd gksrk gSA
(D) [Nb(CO)6]–1 es C–O ca/k Øe [Tc(CO)6]+1 ls vf/kd gksrk gSA
38. The first, second and third ionization energies of an element 'X' are 7 eV, 12 eV and 42.5 eV
respectively. The energy required in eV/atom to transform X(g) into its gaseous ion having most
stable oxidation state is :
,d rRo 'X' dh izFke] f}rh; rFkk r`rh; vk;uu ÅtkZ;s Øe'k% 7 eV, 12 eV rFkk 42.5 eV gSaA X(g) dks
lokZf/kd LFkk;h vkWDlhdj.k voLFkk j[kus okys blds xSlh; vk;u es :ikUrfjr djus ds fy, eV@ijek.kq esa
vko';d ÅtkZ gS&
(A) 19 (B) 7 (C) 12 (D) 42.5
39. Which of the following reactions not represent the major product.
fuEu esa ls dkSulh vfHkfØ;k,sa eq[; mRikn dks iznf'kZr ugha djrh gS \
– –
CH3 CH2O /  CH3 CH2O / 
(A)   (B)  
DMSO DMF
–
(CH3 )3 C–O / 
(C) 
H2 O
 (D)  
CHEMISTRY
40. How many of the following are less basic than Aniline.
fuEu esa ls fdrus ,fuyhu ls de {kkjh; gSa\
CHEMISTRY
NH2
H CH3
N
NH2
NH3 CH3–NH2 (CH3)2NH N
(i) , (ii) , (iii) , (iv) , (v) , (vi) ,
CH3 Cl
NH2 H3C NH2 NH2 NH2
(vii) , (viii) , (ix) , (x)
(A) 1 (B) 2 (C) 3 (D) 4

 This section contains EIGHT (08) questions.
 Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is (are)
correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
 Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
 Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both
of which are correct.
 Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option.
 Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
 Negative Marks : –1 In all other cases.
 For example, in a question, if (A),(B) and (D) are the ONLY three options corresponding to correct
answers, then :
 Choosing ONLY (A),(B) and (D) will get +4 marks
 Choosing ONLY (A) and (B) will get +2 marks
 Choosing ONLY (A)Space and (D)for
willRough
get +2 marks
Work / (dPps dk;Z ds fy, LFkku)
 Choosing ONLY (B) and (D) will get +2 marks
 Choosing ONLY (A) will get +1 marks
 Choosing ONLY (B) will get +1 marks
 Choosing ONLY (D) will get +1 marks
 Choosing no option (i.e. the question is unanswered) will get 0 marks, and
 Choosing any other combination of options will get –1 mark
CHEMISTRY

 bl [kaM esa vkB (08) iz'u gSA
CHEMISTRY
 izR;sd iz'u ds fy, pkj fodYi fn, x, gSaA bu pkj fodYiksa esa ls ,d ;k ,d ls vf/kd fodYi lgh gS¼gSa½A
 izR;sd iz'u ds fy,] fn, gq, fodYiksa esa ls lgh mÙkj ¼mÙkjksa½ ls lacf/kr fodYi ¼fodYiksa½ dks pqfu,A
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %
iw.kZ vad % +4 ;fn dsoy ¼lkjs½ lgh fodYi ¼fodYiksa½ dks pquk x;k gSA
vkaf'kd vad % +3 ;fn pkjksa fodYi lgh gSa ijUrq dsoy rhu fodYiksa dks pquk x;k gSA
vkaf'kd vad % +2 ;fn rhu ;k rhu ls vf/kd fodYi lgh gS ijUrq dsoy nks fodYiksa dks pquk x;k gS vkSj
nksauks pqus gq, fodYi lgh fodYi gSaA
vkaf'kd vad % +1 ;fn nks ;k nks ls vf/kd fodYi lgh gSa ijUrq dsoy ,d fodYi dks pquk x;k gS vkSj pquk
gqvk fodYi lgh fodYi gSA
'kwU; vad % 0 ;fn fdlh Hkh fodYi dks ugha pquk x;k gS ¼vFkkZr~ iz'u vuqÙkfjr gS½A
_.k vad % –1 vU; lHkh ifjfLFkfr;ksa esaA
mnkgj.k% ;fn fdlh iz'u ds fy, dsoy fodYi (A),(B) vkSj (D) lgh fodYi gS] rc %
dsoy fodYi (A),(B) vkSj (D) pquus ij +4 vad feysaxs ’
dsoy fodYi (A) vkSj (B) pquus ij +2 vad feysaxs ’
dsoy fodYi (A) vkSj (D) pquus ij +2 vad feysaxs ’
dsoy fodYi (B) vkSj (D) pquus ij +2 vad feysaxs ’
41. Select correct statement(s):

(A) The dissolution of CaCl2.6H2O in a large volume of water is endothermic to the extent of
3.5 kcal/mol. If H = –23.2 kcal for the reaction, CaCl2(s) + 6H2O(l)  CaCl2.6H2O(s) then heat
of solution of CaCl2 (anhydrous) in a large volume of water is –19.7 kcal/mol
(B) If the equilibrium constant for the reaction A2 2A at 500 K and 700 K are 10–10 and 10–5
respectively, then reaction is exothermic
207
(C) In the nuclear reaction 92 U 
235
82 Pb , the total number of  and  particles emitted would be 11
(D) An aqueous solution of an alcohol (B.P. = 64.7ºC) in water (B.P. = 100ºC) has vapour pressure
more than that of water
CHEMISTRY
lgh dFku@dFkuksa dk p;u dhft,&
(A) ty ds vf/kd vk;ru es CaCl2.6H2O dk ?kqyuk 3.5 kcal/mol dh lhek rd Å"ek'kks"kh gksrk gSA ;fn
CHEMISTRY
vfHkfØ;k CaCl2(s) + 6H2O(l)  CaCl2.6H2O(s) ds fy, H = –23.2 kcal gS] rks ty ds vf/kd vk;ru
es CaCl2 ¼futZy½ ds foy;u dh Å"ek –19.7 kcal/mol gSA
(B) ;fn 500 K rFkk 700 K ij vfHkfØ;k A2 2A ds fy, lkE; fu;rkad Øe'k% 10–10 rFkk 10–5 gS] rks
vfHkfØ;k Å"ek{ksih gSA
207
(C) ukfHkdh; vfHkfØ;k 92 U 
235
82 Pb es] mRlftZr  rFkk  d.kks dh dqy la[;k 11 gksxhA
(D) ty (B.P. = 100ºC) es ,d ,Ydksgy (B.P. = 64.7ºC) dk tyh; foy;u ty dh vis{kk vf/kd ok"inkc
j[krk gSA
d
42. For a gas, plot between v/s p, where (d= density of gas in g/L and p = pressure in atm) at 300 K
p
temperature was obtained as :
d
 
P
P
Which of the following statement(s) is/are incorrect about the gas?
(A) The gas shows non ideal behaviour
(B) The curve should have positive slope for an ideal gas
(C) The curve should be parallel to pressure axis for an ideal gas
d
(D) The plot of   v/s temperature for an ideal gas should have a positive slope
p
CHEMISTRY
d
,d xSl ds fy,] v/s p ds e/; vkys[k] tgk¡ (d= g/L es xSl dk ?kuRo rFkk p = atm es nkc) 300 K rki
p
CHEMISTRY
ij fuEu izdkj izkIr gqvk&
d
 
P
P
fuEu es ls dkSulk@dkSuls dFku xSl ds ckjs es xyr gS@gSa\
(A) xSl vuvkn'kZ O;ogkj n'kkZrh gSA
(B) oØ vkn'kZ xSl ds fy, /kukRed <+ky j[kuk pkfg,A
(C) oØ ,d vkn'kZ xSl ds fy, nkc v{k ds lekUrj gksuk pkfg,A
d
(D) ,d vkn'kZ xSl ds fy,   v/s rki dk vkys[k /kukRed <+ky j[kuk pkfg,A
p
43. Choose the correct statement(s) amongs the following:

(A) Radial distribution function (4r22dr) gives probability at a particular distance along one
chosen direction
(B) 2(r) give probability density at a particular distance
(C) For s orbitals (r, ) is independent of  and 
(D) 2p orbital with quantum numbers n =2  =1, m = 0 also shows angular dependence
fuEu es ls lgh dFku@dFkuksa dk p;u dhft,&
(A) f=kT;h; forj.k Qyu (4r22dr) ,d p;fur fn'kk ds vuqfn'k ,d fof'k"V nwjh ij izkf;drk nsrk gSA
(B) 2(r) ,d fof'k"V nwjh ij izkf;drk ?kuRo nsrk gSA
(C) s d{kdks ds fy, (r, )  rFkk ls LorU=k gksrk gSA
(D) Dok.Ve la[;k n =2  =1, m = 0 ;qDr 2p d{kd Hkh dks.kh; fuHkZjrk n'kkZrk gSA
CHEMISTRY
44. 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2 is taken. The A+)
pKa of –COOH group in methionine is 2.8 and pKb of basic group is 4.8. Pick out the correct
CHEMISTRY
statement(s) amongs the following [Use log 2 = 0.3, log 5 = 0.7]:
(A) pH of original amino acid solution was ~2.05
(B) pH of solution was ~2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution was ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D) pH of solution was 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
,d -,ehuks vEy esfFk;ksfuu (H2A+) ds la;qXeh vEy ds 0.05 M foy;u dk 20 ml fy;k tkrk gSA esfFk;ksfuu
esa –COOH lewg dk pKa 2.8 gS rFkk {kkjh; lewg dk pKb dk 4.8 gSA fuEu es ls lgh dFku@dFkuksa dk p;u
dhft,&[iz;qDr djsa log 2 = 0.3, log 5 = 0.7]
(A) okLrfod ,ehuks vEy foy;u dh pH ~2.05 FkhA
(B) foy;u dh pH ~2.8 Fkh tc 10 ml 0.05 M NaOH foy;u dks okLrfod foy;u es feyk;k tkrk gSA
(C) foy;u dh pH ~6 Fkh tc 20 ml 0.05 M NaOH foy;u dks okLrfod foy;u es feyk;k tkrk gSA
(D) foy;u dh pH 3.8 Fkh tc 20 ml 0.05 M NaOH foy;u dks okLrfod foy;u es feyk;k tkrk gSA
45. Which of the following is/are correct for a non-ideal solution of liquids A and B, showing negative
deviation?
(A) Vmix = –ve, as interaction between molecule A and B is low
(B) Vmix = –ve, as interaction between molecule A and B is high
(C) Gmix = –ve, as mixing is spontaneous
(D)Ssurrounding = +ve, as Hmix is negative
_.kkRed fopyu n'kkZus okys nzoks A rFkk B ds vuvkn'kZ foy;u ds fy, fuEu es ls dkSulk@dkSuls lgh
gS@gSa\
(A) Vmix = –ve D;ksfd v.kq A rFkk B ds e/; vU;ksU; fØ;k U;wu gSA
(B)Vmix = –ve D;ksfd v.kq A rFkk B ds e/; vU;ksU; fØ;k mPp gSA
(C) Gmix = –ve D;ksafd lfEeJ.k Lor% gksrk gSA
(D)Sifjos'k = +ve D;ksafdHmix _.kkRed gSA
CHEMISTRY
46. The correct statements about the following reaction are
CH3
CHEMISTRY
H O
 (Y) 
(1)B H CH COCl / Pyridine
2 6
(2)H O /OH–
(X) 
3
 3
(Z) + Acetic acid.
2 2
(A) (X) is trans isomer of 2-Methylcyclopentan-1-ol.

(B) (Y) is Cis isomer of ester.
(C) (Z) is geometrical isomers of (X)
(D) (X) and (Z) have identical boiling point
fuEu vfHkfØ;k ds lUnHkZ esa lgh dFku gS&

CH3
CH3 COCl / fifjMhu H3O

 (Y) 
(1)B2H6

(2)H O /OH–
(X)  (Z) + ,lhfVd vEy
2 2
(A) ;kSfxd (X), 2-esfFkylkbDyksisUVsu-1-vkWy dk foi{k leko;oh gSA

(B) ;kSfxd (Y), ,LVj dk lei{k leko;oh gSA
(C) ;kSfxd (Z), (X) dk T;kferh; leko;oh gS
(D) ;kSfxd (X) o (Z) le:i DoFkukad j[krs gSaA
47. The possible products in the following sequence of reaction is/are :

fuEufyf[kr vfHkfØ;k vuqØe ds lEHkkfor mRikn dkSuls gSa \
OH H O
CH3–CH=O + HCHO(1 eq.)    3 
(i)KCN

ii H
OH
|
(A) CH3 – CH – CH – COOH (B) CH2 – CH2 – CH – COOH
| | |
OH OH OH
(C) CH2 – CH – COOH (D) CH3 – CH – CH2 – CH – COOH
| | | |
OH OH OH OH
CHEMISTRY
48. Which of the following reactions will generate 3° alcohol ?
CHEMISTRY
(i)CH3MgBr(excess)/dry ether dil.H2SO4
(A) (B)
(ii) aq. NH4Cl
O
(C) (D) (i) Mg/dry ether
Cl
(ii) aq. NH4Cl
fuEufyf[kr esa ls fdu vfHkfØ;ksa esa 3° ,YdksgkWy curk gS \
(i)CH3MgBr(vkf/kD;)/ 'kq"d bZFkj ruq H2SO4

(A) (B)
(ii) aq. NH4Cl
O
(C) (D) (i) Mg/'kq"d bZFkj
Cl
(ii) aq. NH4Cl

 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer. If the numerical value has
more than two decimal places truncate/round-off the value to TWO decimal placed.
 Full Marks : +3 If ONLY the correct numerical value is entered.
 Zero Marks : 0 In all other cases.
CHEMISTRY

 bl [kaM esa N% (06) iz'u gSA izR;sd iz'u dk mÙkj ,d la[;kRed eku (NUMERICAL VALUE) gSaA
CHEMISTRY
izR;sd iz'u ds mÙkj ds lgh la[;kRed eku dks ekmt (mouse) vkSj vkWu&LøØhu (on–screen) opZqvy uqesfjd
dhisM (virtaul numeric keypad) ds ç;ksx ls mÙkj ds fy, fpfUgr LFkku ij ntZ djsaA ;fn la[;kRed eku esa
nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM vkWQ
(truncate/round-off) djsaA 
 izR;sd iz'u ds mÙkj dk ewY;kadu fuEu ;kstuk ds vuqlkj gksxk %&
iw.kZ vad % +3 ;fn ntZ fd;k x;k la[;kRed eku (Numerical value) gh lgh mÙkj gSA
'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA
49. Estimate Hºf {pyridine ()] in KJ/mole from the given data.
Compound Hºf 298K in kJ/mole
CH2=N–CH3(g) +44 Resonance energy N = –125kJ/mol

Pyridine
CH3–NH–CH3(g) –18
(g) –37 Hvap.298K N = +40 kJ/mol

Pyridine
(g) –156
N–H(g) –50
CHEMISTRY
fn;s x;s vk¡dMksa ls KJ/eksy es Hºf {fifjMhu ()] dk vk¡dyu dhft,A
CHEMISTRY
kJ/mole es
;kSfxd
Hºf 298K
CH2=N–CH3(g) +44 vuqukn ÅtkZ N = –125kJ/mol

fifjMhu
CH3–NH–CH3(g) –18
(g) –37 Hvap.298K N = +40 kJ/mol

fifjMhu
(g) –156
N–H(g) –50
CHEMISTRY
50. Kinetic data for hydrolysis of a 0.3 M solution of ethyl acetate in presence of HCl as catalyst is
given in the following table. A constant volume of reaction mixture is taken at different time and
titrated against standard alkali solution at different time.
CHEMISTRY
Time / min 0 10 
Vol. of Alkali / ml 25.00 28.00 40.00
If the rate law is given by rate = k[Ester]1 [H+]1, where H+ is a catalyst, find the rate (in M/min) of
ester hydrolysis in a solution which is 0.1 M each in ester and acid HCl.
5
Use: ln   = 0.225. Report your answer by multiplying actual answer by 105.
4
mRiszjd ds :i es HCl dh mifLFkfr es ,fFky ,lhVsV ds 0.3 M foy;u ds tyvi?kVu ds fy, xfrd vk¡dMs
fuEu lkj.kh es fn;s x;s gSA vfHkfØ;k feJ.k dk fLFkj vk;ru fHkUu le; ij fy;k x;k gS rFkk bls fHkUu le;
ij ekud {kkjh; foy;u ds fo:) vuqekfir fd;k tkrk gSA
le; / min 0 10 
{kkj dk vk;ru / ml 25.00 28.00 40.00
;fn nj fu;e dks nj = k[,LVj]1 [H+]1 ds }kjk n'kkZ;k tkrk gS] tgk¡ H+ ,d mRiszjd gS] ,d foy;u tks ,LVj
rFkk vEy HCl izR;sd es 0.1 M gS] es tyvi?kfVr ,LVj dh nj (M/min es) Kkr dhft,A
iz;ksx djs% ln   = 0.225. viuk mÙkj okLrfod mÙkj dks 105 ls xq.kk djus ds i'pkr~ nhft,A
5
4

51. When 1 mol of A(g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature
the following equlibria are established:
fu;r rki ij ,d can n`< 1 yhVj ik=k es tc 1 eksy A(g) fy;k tkrk gS] rks fuEu lkE; LFkkfir gksrs gSa&
A(g) B(g) + C(g) : K C1
C(g) D(g) + B(g) : K C2
K C2 Ceq 1
The pressure at equilibrium is twice the initial pressure. Calculate the value of if 
K C1 Beq 5
K C2 Ceq 1
lkE; ij nkc izkjfEHkd nkc dk nqxquk gSA dk eku ifjdfyr dhft, ;fn 
K C1 Beq 5
CHEMISTRY
52. Two inter halogen compounds are XYn1 and XYn2 where Y is more electronegative atom than X.
CHEMISTRY
If XYn1 is a non–polar, non planar inter halogen compound and XYn2 is a T–shaped inter halogen
compound then find n1 × n2.

nks vUrj gSykstu ;kSfxd XYn1 rFkk XYn2 gS tgk¡ Y, X ls vf/kd oS|qr_.kh ijek.kq gSA ;fn XYn1 v/kzqoh;]
vleryh; vUrj gSykstu ;kSfxd gS rFkk XYn2 T–vkÑfruqek vUrj gSykstu ;kSfxd gS] rks n1 × n2 Kkr
dhft,A
53. The maximum number of possible isomers (including stereoisomers) which may be formed on
mono-bromination of 1-methylcyclohex-1-ene using Br2 and UV light is _____ .
Br2 rFkk UV izdk'k ds mi;ksx 1-esfFkylkbDyksgsDl-1-bZu ds eksuksczksehuhdj.k ij cuus okys laHko leko;fo;ksa
¼f=kfoe leko;o lfgr½ dh vf/kdre la[;k _____ gks ldrh gSA
54. How many moles of formaldehyde is formed by the complete hydrolysis of following compound
with H3O+.
fuEufyf[kr ;kSfxd ds H3O+ ds lkFk iw.kZ ty vi?kVu ij fdrus eksy QkWesZfYMgkbM curs gS\

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CHEMISTRY

PART : III CHEMISTRY

[kaM 1 ¼vf/kdre vad% 12½

37. Consider the following two carbonyl compounds:

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

NH2 H3C NH2 NH2 NH2

(vii) , (viii) , (ix) , (x)

(A) 1 (B) 2 (C) 3 (D) 4

SECTION-2 (Maximum Marks : 32)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

[kaM 2 ¼vf/kdre vad% 32½

41. Select correct statement(s):

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

43. Choose the correct statement(s) amongs the following:

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

(A) (X) is trans isomer of 2-Methylcyclopentan-1-ol.

fuEu vfHkfØ;k ds lUnHkZ esa lgh dFku gS&

CH3 COCl / fifjMhu H3O

(A) ;kSfxd (X), 2-esfFkylkbDyksisUVsu-1-vkWy dk foi{k leko;oh gSA

47. The possible products in the following sequence of reaction is/are :

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

fuEufyf[kr esa ls fdu vfHkfØ;ksa esa 3° ,YdksgkWy curk gS \

(i)CH3MgBr(vkf/kD;)/ 'kq"d bZFkj ruq H2SO4

SECTION-3 (Maximum Marks : 18)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

[kaM 3 ¼vf/kdre vad% 18½

CH2=N–CH3(g) +44 Resonance energy N = –125kJ/mol

(g) –37 Hvap.298K N = +40 kJ/mol

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

fn;s x;s vk¡dMksa ls KJ/eksy es Hºf {fifjMhu ()] dk vk¡dyu dhft,A

CH2=N–CH3(g) +44 vuqukn ÅtkZ N = –125kJ/mol

(g) –37 Hvap.298K N = +40 kJ/mol

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

compound then find n1 × n2.

Space for Rough Work / (dPps dk;Z ds fy, LFkku)

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