Jee Material DPP

INORGANIC CHEMISTRY
TARGET : JEE (ADVANCED) 2018

 

INFORMA TIO
E EST
DPPDAILY PRACTICE PROBLEMS
Course : VIJETA & VIJAY (ADP & ADR) Date : 16.04.2018

NO. 2
TEST INFORMATION
DATE : 17.04.2018 PART TEST (PT)-02
Syllabus: Inorganic Nomenclature, Periodic table, Chemical Bonding & Coordination Compounds.
DPP Syllabus : Inorganic Nomenclature, Periodic table, Chemical Bonding & Coordination Compounds.
DPP No. # 2
Total Marks: 183 Max. Time: 118 min.
Single correct Objective ('–1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [27, 14]
One or more correct objective (no negative marking) Q.8 to Q.20 (4 marks, 2 min.) [52, 26]
Assertion and Reason ('–1' negative marking) Q.21 to Q.23 (3 marks, 3 min.) [09, 09]
Comprehension ('–1' negative marking) Q.24 to Q.32 (3 marks, 2 min.) [27, 18]
Integer type ('–1' negative marking) Q.33 to Q.41 (4 marks, 3 min.) [36, 27]
Match the Following (no negative marking) Q.42 to Q.45 (8 marks, 6 min.) [32, 24]
ANSWER KEY
DPP No. # 2
1. (C) 2. (B) 3. (C) 4. (C) 5. (C) 6. (C) 7. (C)
8.* (ABD) 9.* (ABD) 10.* (ABD) 11.* (ABC) 12.* (BD) 13.* (AC) 14.* (BCD)
15.* (ABC) 16.* (ABCD) 17.* (CD) 18.* (AD) 19.* (AB) 20.* (AD) 21. (A)
22. (B) 23. (C) 24.* (AD) 25.* (B) 26.* (BCD) 27.* (C) 28.* (C)
29.* (ABC) 30. (D) 31. (D) 32. (C) 33. 3 34. 6 (a, b, e, g, h, i)
35. 6 36. 4 (d, e, g, h) 37. 9 38. 3 39. 4 40. 6
41. 7 42. (A)  r ; (B)  p ; (C)  q ; (D)  s
43. (A  q , t ); (B  p, q); (C  p, r, s, t ) ; (D  r , s , t )
44. (A  q , s ); (B  p, s); (C  r , s ) ; (D  q , t )
45. (A)  p, t ; (B)  r, s ; (C)  p, q, t ; (D)  p, q, t
1. What is the maximum number of electrons which can be accommodated in an atom in which the
highest principal quantum number of subshell is 4?
,d ijek.kq esa vf/kdre bysDVªkWukss dh la[;k D;k gksxh ftldh midks"k mPPkre eq[; DokUVe la[;k 4 gS\
(A) 10 (B) 18 (C*) 36 (D) 54
2. The ligand N(CH2CH2NH2)3 is :
(A) tridentate (B*) tetradentate (C) didentate (D) pentadentate
fyxs.M N(CH2CH2NH2)3 gS &
(A) f=knUrqd (B*) prq"dnUrdq (C) f}nUrqd (D) iap nUrqd
Sol. As it has 4 properly oriented N atoms.
pw¡fd blds ikl pkj iw.kZr% vfHkfoU;kflr N ijek.kq gSaA
3. The correct IUPAC name for the complex [Pt(NH3)2Cl4], which has maximum planes of symmetry is :
(A) cis-platinum tetrachlorodiammine (B) trans-platinum tetrachlorodiammine
(C*) trans-Diamminetetrachloroplatinum(IV) (D) cis-Diammine tetrachloroplatinum (IV)
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Page No. - 1
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ladqy [Pt(NH3)2Cl4] ds fy, lgh IUPAC uke dkSu lk gS] ftlesa vf/kdre lefefr ry gS\
(A) lei{k-IysfVueVsVªkDyksjksMkbZ,Eehu (B) foi{k-IysfVueVsVªkDyksjksMkbZ,Eehu
(C*) foi{k- MkbZ,EehuVsVªkDyksjksIysfVue (IV) (D) lei{k-MkbZ,EehuVsVªkDyksjksIysfVue (IV)
Sol. For Name, check rules from notes. uke ds fy, uksV~l ls fu;e ns[ksa
5-planes of symmetry 2-planes of symmetry

5-lefefr dk ry 2-lefefr dk ry
4–
4. The correct electronic configuration for [CrF6] will be :
4–
[CrF6] ds fy, lgh bysDVªkWfud foU;kl gksxk&
4 2 2 3 1 4
(A) t2g eg° (B) eg t2g (C*) t2g eg (D) eg t2g°
Sol. As octahedral field is present so their will be octahedral splitting.
–
Further, F is a weak field ligand. so pairing will not take place unless all orbital are half fillled.
v"VQydh; {ks=k mifLFkr gksrk gS blfy, budk v"VQydh; foikVu gksrk gSA pw¡fd F– ,d nqcZy {kS=k fyxs.M gS]
vr% ;qXeu rc rd ugha gksxk tc rd fd lHkh d{kd v)Z Hkjs gq, uk gksA
5. 4-nitrophenyl hydrazine is an example of :
(A) a tridentate ligand (B) a bidentate ligand
(C*) a monodentate ligand (D) a tetradentate ligand
4-ukbVªksQsfuy gkbMªsthu fuEu dk ,d mnkgj.k gS&
(A) ,d f=knUrqd fyxs.M (B) ,d f}nUrqd fyxs.M
(C*) ,d ,dynUrqd fyxs.M (D) ,d prq"dnUrqd fyxs.M
O2N
Sol.
NH–NH2
(1) (2)
Either nitrogen (1) or nitrogen (2) can donote lone pair
;k rks ukbVªkstu (1) ;k ukbVªkstu (2) ,dkdh ;qXe nku dj ldrk gSA
6. What is the coordination number of La in the compound [La(EDTA) (H2O)4]. 3H2O
;kSfxd [La(EDTA) (H2O)4]. 3H2O esa La dh leUo; la[;k D;k gS \
(A) 6 (B) 8 (C*) 10 (D) 12
7. Which among the following will be named as dibromobis(ethylenediamine)chromium (III) bromide ?

fuEu esa ls fdldk uke MkbZczkseksfcl¼,sFkhyhuMkb,sehu½Øksfe;e (III)½ czksekbM gS\
(A) [Cr(en)2Br2] Br2 (B) [Cr(en)2Br2]Br3 (C*) [Cr(en)2 Br2] Br (D) [Cr(en)2Br3]
+3 –
Sol. Cr and 2Br in the bracket, so one Br will remain outside the bracket to balance total positive charge.
dks"Bd esa Cr+3 o 2Br gS vr% dqy /kukRed vkos'k lUrqfyr djus ds fy, dks"Bd ds ckgj ,d Br¯ 'ks"k jgsxkA
8.* During the complete combustion of ethene C2H4, which of the following do not represent change in
hybridisation of carbon atom?
3 3 2 2 2 3
(A*) sp to sp (B*) sp to sp (C) sp to sp (D*) sp to sp
C2H4 ¼,Fkhu½ ds iw.kZ ngu ds nkSjku dkcZu ijek.kq ds ladj.k esa fuEu eas ls dkSulk ifjorZu ugha gksrk gS@gSa \
3 3
(A*) sp ls sp (B*) sp ls sp2 (C) sp
2
ls sp (D*) sp
2
ls sp3
Sol. C2H4 + 3O2  2CO2 + 2H2O
2
sp sp
Page No. - 2
9.* Which of the following substances exhibit H-bonding with water?
fuEu esa ls dkSulk inkFkZ ty ds lkFk H-cU/k cukrk gS\
(A*) CH3CH2OH (B*) (C) CH3 – CH2 – CH3 (D*) N(CH3)3

Sol. Each of given species except CH3CH2CH3 contain either H bonded to EN atom or lone pair containing
EN atom.
CH3CH2CH3 dks NksM+dj nh xbZ izR;sd Lih'kht esa ;k rks mPp EN ijek.kq ls gkbMªkstu cfU/kr gS ;k mPp EN
ijek.kq ij ,dkadh e– ;qXe mifLFkr gSA
10.* In which of the following pairs, the number of lone pair(s) over central atom and molecular geometry
is/are different?
fuEu esa ls fdl ;qXe esa dsUæh; ijek.kq ij ,dkadh ;qXeksa dh la[;k rFkk vkf.od T;kfefr leku ugha gS\
+ – –
(A*) TeCl4, PCl4 (B*) CIF3, PCl3 (C) SiCl4, BF4 (D*) BrF5, XeF5
Sol. (A) (B)
(C) (D)
gy- (A) (B)
(C) (D)
11.* In which of the following, the -bonds cannot lie in same plane?
fuEu esa ls fdles] -ca/k ,d gh ry esa fLFkr ugha gks ldrs ?
(A*) Cl–CC–Cl (B*) O=C=O (C*) N2 (D)
Sol. In triple bond,  bond is formed by px–px and py–py. Hence perpendicular to each other. In consecutive
double bond, if px–px overlap form one  bond, then py–py form other  bond. Hence perpendicular to
each other. (Here Z axis is taken as internuclear axis).
gy- f=kca/k esa,  ca/k px–px ,oa py–py vfrO;kiu }kjk curs gSA vr% ,d nwljs ds yEcor~ gksrs gSA Øekxr f}ca/k esa ;fn
,d  ca/k px–px vfrO;kiu ls curk gS rks nwljk  ca/k py–py vfrO;kiu ls curk gSA vr% ,d nwljs ds yEcor~ gSA
(;gk¡ Z v{k vUrjukfHkdh; ds :i esa fy;k tkrk gSA)
12.* Which of the following pairs of coordination compound show same type of isomerism?
(A) [Co(NH3)5Br] SO4 and [Ni(dmg)2] (B*) [Pt(NH3)2Cl2] and [Co(en)2BrCl]Cl
2+ 3–
(C) [Co(NH3)6][Cr(CN)6] and K[PtCl3(C2H4)] (D*) [Ni(en)3] and [Co(ox)3]
Page No. - 3
milgla;kstd ;kSfxdks dk fuEu esa ls dkSulk ;qXe leku izdkj dh leko;ork n'kkZrk gS\
(A) [Co(NH3)5Br] SO4 vkSj [Ni(dmg)2] (B*) [Pt(NH3)2Cl2] vkSj [Co(en)2BrCl]Cl
2+ 3–
(C) [Co(NH3)6][Cr(CN)6] vkSj K[PtCl3(C2H4)] (D*) [Ni(en)3] vkSj [Co(ox)3]
Sol. (A) [Co(NH3)5Br] SO4 can show ionization isomerism only But [Ni(dmg)2] can’t
(B) [Pt(NH3)2Cl2] is square planar and hence can show cis-trans isomerism.
[Co(en)2ClBr]Cl can show ionisation isomerism as well as cis-trans isomerism in octahedral complexes.
(C) [Co(NH3)6][Cr(CN)6] can show coordination isomerism where as K[PtCl3(C2H4)] can’t show any
isomerism.
2+ 3–
(D) [Ni(en)3] and [Co(ox)3] are optically active .
Sol. (A) [Co(NH3)5Br] SO4 vk;uu leko;ork n'kkZrk gS ysfdu [Ni(dmg)2] ugha n'kkZrk gSA
(B) [Pt(NH3)2Cl2] oxZ
leryh; gS o blfy, lei{k&foi{k leko;ork n'kkZrk gSA
[Co(en)2ClBr]Cl v"VQydh; ladqy esa vk;uu leko;ork ds lkFk&lkFk lei{k&foi{k leko;ork Hkh n'kkZrk gSA
(C) [Co(NH3)6][Cr(CN)6] milgla;ksth leko;ork n'kkZ ldrk gS tcfd K[PtCl3(C2H4)] dksbZ Hkh leko;ork ugha
n'kkZ ldrk gSA
2+
(D) [Ni(en)3] rFkk [Co(ox)3]3– izdkf'kd lfØ; gSA
O O
–
13.* C6H5–C–CH–C–CH3 is called benzoylacetonato. Bis(Benzoylacetonato)beryllium will show :
O O
–
C6H5–C–CH–C–CH3 dks csUtkWby,lhVksusVks dgrs gSA fcl ¼csUtkWby,lhVksusVks½ csfjfy;e fuEu dks n'kkZ;sxk &
(A*) structural isomerism lajpukRed leko;ork (B) geometrical isomerism T;kferh; leko;ork
(C*) optical isomerism izdkf'kd leko;ork (D) None of these buesa ls dksbZ ugha
3
Sol. Benzoylacetonato is non-symmetrical didentate ligand and beryllium can only use sp orbitals (as it has
no d-orbital). So Be forms tetrahedral complex with it.
csUtkWby,lhVksusVks vlefefr f}nUrqd fyxs.M gS o csjhfy;e dsoy sp3 d{kd dk mi;ksx dj ldrk gS ¼blesa d-
d{kd ugha gksrk gS½A vr% Be blds lkFk prq"Qydh; ladqy cukrk gSA
A
A
Hence vr% Be
B
B
Where A B is a representation of non-symmetrical didentate ligand.
This structure has no plane of symmetry. so it is optically active.
tgk¡ A B vlefefr f}nUrqd fyxs.M dks iznf'kZr djrk gSA

;g lajpuk dksbZ lefefr ry ugha j[krh gS] blfy, ;g izdkf'kd lfØ; gksrk gSA
Page No. - 4
14.* In which of the following pairs of elements the electronegativity of the first element is more than that of
second element ?
fuEu esa ls rRoksa ds dkSu ls ;qXe esa izFke rRo dh oS|qr _.krk] f}rh; rRo dh vis{kk vfèkd gksrh gS\
(A) Al, Ga (B*) Li, K (C*) Cl, S (D*) F, Cl
Sol. Al = 1.61 Due to d-contraction d-ladqpu ds dkj.k
Ga = 1.81
15.* Which of the following can show linkage isomerism?
fuEu esa ls dkSu fyadst leko;ork iznf'kZr dj ldrk gS\
NH2
– – –
(A*) (B*) NO2 (C*) OCN (D) N3
S–
Sol. –1 +1 –1
N=N=N
The two nitrogen atoms are equivalent. nks ukbVªkstu ijek.kq rqY; gSaA
16.* Which among the following is stronger lewis bases than HN(SiH3)2?
fuEu esa ls dkSulh Lih'kht HN(SiH3)2 dh vis{kk izcy yqbZl {kkj gS\
(A*) NH3 (B*) H2N(CH3) (C*) H2N(SiH3) (D*)
Sol. In HN(SiH3)2, lone pair of N is delocalized by back bonding in d-orbitals of 2 silicons. So it is very poor
base.
NH3, NH2(CH3), and H2N (SiH3) are hence better bases than HN(SiH3)2 .
gy- HN(SiH3)2 esa nks flfydksu ds d-d{kdkssa esa i'p vkca/ku ds }kjk N dk ,dkdh bysDVªkWu ;qXe foLFkkuhd`r gksrk gSA
blfy;s ;g vfr nqcZy {kkj gSA
NH3, NH2(CH3), rFkk H2N(SiH3), HN (SiH3)2 dh vis{kk mÙke {kkj gSA
17.* In which of following silicate(s), the number of corners shared per tetrahedron is  2?
(A*) Four membered cylic silicate (B) Pyrosilicate
(C*) Chain silicate (D*) 2-D silicate
fuEu esa ls fdl flfydsV@flfydsVksa esa izfr prq"Qyd lk¡f>r dksuksa dh la[;k  2 gksrh gS\
(A*) pkj lnL;h; pfØ; flfydsV (B) ik;jksflfydsV
(C*) J`a[kyk flfydsV (D*) 2-D flfydsV
Sol. four membered cyclic silicate pkj lnL;h; pfØ; flfydsV
18.* Which of the following is/are correct?

(A*) vander Waal’s radius of iodine is more than its covalent radius
(B) All isoelectronic ions belong to the same period of periodic table
(C) First ionisation energy of Be is more than that of C
(D*) Electron affinity of N as well as noble gases is negative.
fuEu esa ls dkSulk@dkSuls lgh gS@gSa \
(A*) vk;ksMhu dh ok.MjokYl f=kT;k bldh lgla;kstd f=kT;k ls vf/kd gksrh gSaA
(B) lHkh lebysDVªkWfud vk;u vkorZ lkj.kh ds leku vkorZ ls lEcfU/kr gksrs gaSA
(C) Be dh izFke vk;uu ÅtkZ C dh vis{kk vf/kd gksrh gaSA
(D*) N ds lkFk&lkFk mRd`"V xSl dh bysDVªkWu cU/kqrk _.kkRed gksrh gSaA
Page No. - 5
Sol. Refer notes uksV~l ns[ksaA
19.* How many nodal suface can be present in the molecular orbital formed by the overlap of s and px
(X axis is the molecular axis)?
(A*) 2 (B*) 1 (C) 3 (D) None of these
s o px ds vfrO;kiu ls fufeZr vkf.od d{kd esa fdruh uksMy lrg mifLFkr gks ldrh gSa ¼X v{k] vkf.od v{k gSA½\
(A*) 2 (B*) 1 (C) 3 (D) buesa ls dksbZ ugha
Sol.
20.* Which of the following show intramolecular hydrogen bonding?

(A*) salicylaldehyde (B) o-nitrotoluene
COOH
(C) p-nitrophenol (D*) hydrogenpthalate ion
–
COO
fuEu esa ls dkSu vUr%vkf.od gkbMªkstu cU/ku n'kkZrk gS \
(A*) lsyhflysfYMgkbM (B) o-ukbVªksVkWyqbZu
COOH
(C) p-ukbVªksfQuksy (D*) gkbMªkstu FkSysV vk;u
–
COO
CH3 NO2
NO2
Sol. (A) (B) (C) (D)
OH
21. Statement-1: K3[Fe(CN)6] is an inner orbital complex where as K3[FeF6] is an outer orbital complex.
– 3+ 2 3 –
Statement-2: CN being a strong ligand, pairs electrons of Fe and we get d sp hybridization. But F
3+
being weak ligand do not pair electrons in Fe .
(A*) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
dFku-1: K3[Fe(CN)6] ,d vkUrfjd d{kd ladqy gS tcfd K3[FeF6] ,d ckº~; d{kd ladqy gSA
dFku-2: CN– ,d izcy fyxs.M gS o Fe3+ ds bysDVªkWu dk ;qXeu djrk gS ftlls d2sp3 ladj.k izkIr gksrk gSA
ysfdu F– nqcZy fyxs.M gS tks Fe3+ esa bysDVªkWu ;qXeu ugha djrk gSA
(A*) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
22. Statement-1 : H2S is less acidic than H2Te.

Statement-2 : As the size of Te is more than S, the bond Te–H is weaker than S–H.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B*) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
Page No. - 6
dFku-1: H2S dh vEyh; lkeF;Z H2Te ls de gksrh gSA
dFku-2: Te dk vkdkj S ls vf/kd gksrk gS vr% Te–H cU/k S–H ls nqcZy gksrk gSA
(A) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B*) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C) dFku&1 lR; gS] dFku&2 vlR; gSA
Sol. Self explanatory Lor% le>us ;ksX;
23. Statement-1 : Atomic size in Na is larger than Al.

Statement-2 : Number of shells in Na are more than in Al.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C*) Statement-1 is True, Statement-2 is False. (D) Statement-1 is False, Statement-2 is True.
dFku-1: Na dk ijek.oh; vkdkj Al ls cM+k gksrk gSA
dFku-2: Na esa dks'kksa dh la[;k Al ls vf/kd gksrh gSA
(A) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C*) dFku&1 lR; gS] dFku&2 vlR; gSA
Sol. The valence shell of sodium as well as aluminium is 3.
lksfM;e rFkk ,Y;qfefu;e nksuksa esa la;ksth dks'k dh la[;k 3 gSA
Comprehension # 1 (One or more than one correct options)
Answer the questions based on the following reactions :
CuSO4 + NH3 (excess)  X
CuSO4 + KCl (excess)  Y
vuqPNsn # 1 (,d ;k ,d ls vf/kd lgh fodYi)
fuEu vfHkfØ;k ij vk/kkfjr iz'uksa ds mÙkj nhft, %
CuSO4 + NH3 ¼vkf/kD;½  X
CuSO4 + KCl ¼vkf/kD;½  Y
24.* Which of the following is/are correct ?

(A*) color of X = Deep blue (B) color of X = sky blue
2+ 3 2+ 2
(C) hybridization of Cu in X = sp (D*) hybridization of Cu in X = dsp
fuEu esa ls dkSuls dFku lR; gS@gSa \
(A*) X dk jax = xgjk uhyk (B) X dk jax = vklekuh uhyk
2+ 3 2+ 2
(C) X esa Cu dk ladj.k sp gSA (D*) X esa Cu dk ladj.k dsp gSA
2+
Sol. X = [Cu(NH3)4]
2+ 9 2
Cu = d , one electron is excited so we get dsp hybridization.
2+
Sol. X = [Cu(NH3)4]
pwafd Cu2+ = d9, ,d bysDVªkWu mÙksftr gksrk gS vr% ges dsp2 ladj.k izkIr gksrk gSA
25.* IUPAC name of Y is :
(A) Potassium (tetrachloride) disulphate copper (II) (B*) Potassium tetrachloridocuprate (II)
(C) Potassium tetrachloridocopper (II) (D) Dipotassiumcuprate(II) chloride
Y dk IUPAC uke gS &
(A) iksVsf'k;e¼VsVªkDyksjkbM½MkblYQsVdkWij (II) (B*) iksVsf'k;e VsVªkDyksjkbMksD;wizsV (II)
(C) iksVsf'k;e VsVªkDyksjkbMksdkWij (II) (D) MkbiksVsf'k;eD;wizsV(II)DyksjkbM
Sol. Y is K2[CuCl4]
Sol. Y, K2[CuCl4] gSA
Page No. - 7
26.* To Y, excess KCN is added due to which :
2–
(A) A highly stable complex [Cu(CN)4] is formed which remains in solution even after long time
(B*) A gas is produced
3–
(C*) A highly stable complex[Cu(CN)4] is formed which remains in solution even after long time
(D*) The products are diamagnetic
Y esa] KCN ¼vkf/kD;½ feykrs gS ftlds dkj.k &
(A) ,d mPp LFkk;h ladqy [Cu(CN)4]2– curk gS tks dkQh yEcs le; rd foy;u esa jgrk gSA
(B*) ;g xSl dk fuekZ.k djrk gSA
3–
(C*) ,d mPp LFkk;h ladqy [Cu(CN)4] curk gS tks dkQh yEcs le; rd foy;u esa jgrk gSA
(D*) mRikn izfrpqEcdh; gSA
2– – 3– –
Sol. [Cu Cl4] + CN (excess)  [Cu(CN4)] + (CN)2 + Cl
2– – 3– –
Sol. [Cu Cl4] + CN (vkf/kD;)  [Cu(CN4)] + (CN)2 + Cl
Comprehension # 2 (One or more than one correct options)

Sulphur forms numerous compounds and show variety of oxidation states. It also exhibit a good
tendency of catenation. It forms variety of oxoacids and oxoanions also. Sulphur also occur in several
biomolecules and is also used in chemotherapy as sulphadrugs.
vuqPNsn # 2 (,d ;k ,d ls vf/kd lgh fodYi)
lYQj dbZ ;kSfxd cukrk gS o fofHkUu vkWDlhdj.k voLFkk,¡ n'kkZrk gSA ;g J`a[kyu dh ,d vPNh izo`fr n'kkZrk gSA
;g fofHké‰ izdkj ds vkWDlh vEy o vkWDlh_.kk;u Hkh cukrk gSA lYQj dbZ tSfod v.kqvksa esa Hkh ik;k tkrk gS rFkk
;g vkS"k/kh ds :i esa jlk;u fpfdRlk esa Hkh iz;qDr gksrk gSA
27.* Sulphapyridine was shown to be effective drug against pneumonia
What is the hybridization of ‘S’ in this compound.

lYQkfijhMhu U;weksfu;k ds fo:ð izHkkoh vkS"kèkh gSA
bl ;kSfxd esa ' S' dk ladj.k D;k gS\

2 3 3 3 2
(A) sp (B) sp d (C*) sp (D) sp d
Sol.
3 3
S.N of S = 4. so sp (S dk S.N = 4. vr% sp )
28.* NH2–SO3H is called as sulphamic acid.NH2–CO2H is called as carbamic acid. Using this knowledge,
find which formula/formulae is/are correctly matched with name ?
(A) Calcium sulphamate  Ca(N–SO3H) (B) Aluminum pyrophosphate  Al2(P2O7)3
(C*) Sodium carbamate  Na(NH2–COO) (D) Ammomium thiosulphate  (NH4)S2O3
Page No. - 8
NH2–SO3H dks lYQsfed vEy dgrs gSA NH2–CO2H dks dkcsZfed vEy dgrs gSaA bl tkudkjh dk mi;ksx dj
Kkr dhft, fd dkSu lk@ls lw=k uke ds lkFk lgh rjg ls lqesfyr gS@gSa\
(A) dSfY'k;e lYQkesV – Ca(N–SO3H) (B) ,Y;qfefu;e ik;jksQkWLQsV – Al2(P2O7)3
(C*) lksfM;e dkcsZesV Na(NH2–COO) (D) veksfu;e Fkk;kslYQsV (NH4)S2O3
–
Sol. sulphamate  NH2 – SO3
–
Carbamate  NH2 – CO2
4–
Pyrophosphate  (P2O7)
2–
Thiosulphate  S2O3
–
Sol. lYQkesV   NH2 – SO3
–
dkcsZesV   NH2 – CO2
4–
ik;jksQkWLQsV   (P2O7)
2–
Fkk;kslYQsV   S2O3
29.* Among the following compounds of sulphur, which contain sulphur–sulphur bond?
lYQj ds fuEu ;kSfxdksa esa ls fdlesa S–S cU/k mifLFkr gS\
(A*) H2S2O5 (B*) H2S2O3 (C*) Na2S4O6 (D) CaS2O7
Sol. Refer class notes. uksV~l ns[ksa
Comprehension # 3
Electronegativity is a feature which is relative and depends on several factor like oxidation number,
hybridizations etc.
For instance, the electronegativity of differently hybridized carbon are :
sp 2.99
2
sp 2.66
3
sp 2.48
vuqPNsn # 3
fo|qr _.krk ,d y{k.k gS tks fd dbZ dkjdkas tSls fd vkWDlhdj.k la[;k] ladj.k bR;kfn ij fuHkZj djrk gSA
mnkgj.k ds fy,] dkcZu dh fofHké ladj.k voLFkkvksa dh oS|qr _.krk fuEu gS&
sp 2.99
2
sp 2.66
3
sp 2.48
30. Which of the following contain all carbon of equal electronegativity ?

(A) Propene (B) Propadiene (C) Cyclopropene (D*) Cyclopropane
fuEu esa ls dkSu ls ;kSfxd esa lHkh dkcZu leku oS|qr _.krk j[krs gSa\
(A) izksihu (B) izksikMkbbZu (C) lkbDyksizksihu (D*) lkbDyksizksisu
Sol. All C are equivalent in Cyclopropane
lkbDyksizksisu esa lHkh C rqY; jgrs gSA
31. Which of the following is correct ?
H3C – CH3 , H2C = CH2 , HC  CH
(a) (b) (c)
(A) The C–C  bond is of equal strength in (a) and (b)
(B) The C–C  bond is stronger in (a) than (c)
(C) The C–C  bond is stronger in (b) than (c)
(D*) The C–C  bond is stronger in (c) than (a)
fuEu esa ls dkSu lgh gS \
H3C – CH3 , H2C = CH2 , HC  CH
(a) (b) (c)
(A) (a) o (b) esa] C – C  cU/k lkeF;Z leku gSA (B) (a) esa] C – C  cU/k (c) ls izcy gksrk gSA
Page No. - 9
(C) (b) esa] C – C  cU/k (c) ls izcy gksrk gSA (D*) (c) esa] C – C  cU/k (a) ls izcy gksrk gSA
Sol. more is s-character in the hybridized orbital involved, stronger is the bond.
lEcfU/kr ladfjr d{kd esa s-vfHky{k.k ftruk vf/kd gS mruk gh cU/k izcy gksrk gSA
32. The direction of dipole of C  O is from O to C. This means there is slight positive charge on O. This
can be explained by :
(A) higher electronegativity of O (B) sp hybrization of C
(C*) positive formal charge on O (D) All of these
C O esa f}/kzqo vk?kw.kZ dh fn'kk O ls C dh vksj gSA bldk vFkZ gS fd O ij vkaf'kd :i ls /kukos'k gksrk gSA bls
fuEu }kjk le>k;k tk ldrk gS &
(A) O dh mPp oS|qr _.krk (B) C dk sp ladj.k
(C*) O ij /kukRed vkSipkfjd vkos'k (D) mijksDr lHkh
Sol.
Although Oxygen is highly electronegative in comparison of sp hybridized carbon, here the direction of
dipole is decided by the above canonical structure which is stable due to complete octet of both atoms.
;|fi vkWDlhtu] sp ladfjr dkcZu dh rqyuk esa mPp oS|qr _.kh gSA ;gk¡ f}/kzqo dh fn'kk dks mijksDr vuquknh
lajpuk }kjk fu/kkZfjr fd;k tkrk gS tks fd nksuksa ijek.kqvksa ds iw.kZ v"Vd ds dkj.k LFkk;h gksrk gSA
O O
|| ||
33. How many types of C–O bond length are present in CH3 – C – CH2 – CH – C – O ?
|
OH
O O
|| ||
CH3 – C – CH2 – CH – C – O esa fdrus izdkj dh C–O ca/k yEckbZ;k¡ mifLFkr gS?
|
OH
Ans. 3
Sol. So, vr%
O O
1 3
CH3–C–CH2–CH–C–O
2
OH
34. How many of the following compound can be optically active?
+ +
(a) [Co(en)2ClBr] (b) [Co(en)(NH3)2Cl2] (c) [Cr(NH3)4Cl2] (d) [Co(NH3)3Cl3]
3+ 2– 2–
(e) [Co(en)3] (f) [Ni(dmg)2] (g) [Pb(EDTA)] (h) [Cr(ox)2(dmg)]
(i) [Cr(dmg)3]
fuEu esa ls fdrus ;kSfxd izdkf'kd :i ls lfØ; gks ldrs gS\
+ +
(a) [Co(en)2ClBr] (b) [Co(en)(NH3)2Cl2] (c) [Cr(NH3)4Cl2] (d) [Co(NH3)3Cl3]
3+ 2– 2–
(e) [Co(en)3] (f) [Ni(dmg)2] (g) [Pb(EDTA)] (h) [Cr(ox)2(dmg)]
(i) [Cr(dmg)3]
Ans. 6 (a, b, e, g, h, i)
NH3
NH3
Sol. (a) cis-isomer is optically active. (b) en Co is op. active
Cl
Cl
(c) optically inactive (d) optically inactive
(e) always optically active. (f) square planar, optically inactive
(g) EDTA complexes are optically active (h) 3 didentate ligands are always optically active
Page No. - 10
(i) same as (h)
NH3
NH3
(a) lei{k- leko;oh izdkf'kd lfØ; gksrs gSA (b) en Co izdkf'kd lfØ; gSA
Cl
Cl
(c) izdkf'kd vfØ;A (d) izdkf'kd vfØ;A
(e) ges'kk izdkf'kd lfØ;A (f) oxZ leryh;] izdkf'kd vfØ;A
(g) EDTA ladqy izdkf'kd lfØ; gksrs gSaA (h) 3 f}nUrqd fyxs.M ges'kk izdkf'kd lfØ; gksrs gSA
(i) (h) ds lekuA
35. The sum of oxidation state of Co and Cr in the following complex is :

fuEu ladqy esa Co o Cr dh vkWDlhdj.k voLFkkvksa dk ;ksx gS &
[Co(NH3)6] [Cr(NH3)2Cl4]3
Ans. 6
Sol. x y
[Co(NH3)6] [Cr(NH3)2Cl4]3
x + 3y – 4 × 3 = 0  x + 3y = 12
common oxidation states of Co are +2 and +3 & same for chromium.
+3 +3
only Co , Cr , satisfy the above equation
Hence x + y = 6
Co rFkk Cr dh lkekU; vkWDlhdj.k voLFkk,sa +2 o +3 gSA
mijksDr lehdj.k dks dsoy Co+3, Cr+3 larq"V djrk gSA
vr% x + y = 6
36. How many of the following species use dz 2 orbital in their hybridization?
fuEu esa ls fdruh Lih'kht ds ladj.k esa dz 2 d{kd iz;qDr gqvk gS\
2– 2–
(a) [Ni(CN)4] (b) [CoBr4] (c) NH4Cl (d) XeF4
2+ 2+ 3– –
(e) [Cr(NH3)6] (f) [Cu(NH3)4] (g) [FeF6] (h) I3
Ans. 4 (d, e, g, h)
2 3 + 3
Sol. (a) dx2 – y 2 (d-sp ) (b) sp (c) NH4 =sp
3 2 2 3
(d) sp d (SN=6) dz 2 and rFkk dx2 – y 2 (e) d sp ( dz 2 and rFkk dx2 – y 2 )
2 3 2
(f) dsp ( dx2 – y 2 ) (g) sp d ( dz 2 and rFkk dx2 – y 2 ) (h) I3– ( dz 2 )
Hence, ans is 4.
blfy, mÙkj 4 gSA
37. Find total number of N-Cr-O angles in tris(glycinato)chromium (III).
fVªl¼XykblhusVks½ Øksfe;e (III) esa dqy N-Cr-O dks.k gSA
Ans. 9
Sol.
38. Find the value of x + y where x and y indicate number of H atoms in HxFe(CO)4 and HyRe(CO)5
respectively. (EAN rule is followed).
x + y dk eku Kkr dhft,] tgk¡ x o y Øe'k% HxFe(CO)4 o HyRe(CO)5 esa H ijek.kqvksa dh la[;k gSA ¼EAN fu;e
ykxw gksrk gSA½
Page No. - 11
Ans. 3
–
Sol. For Hx Fe(CO)4, 18e rule for Fe = 8 – (–x) + 4 × 2 = 18
 x + 8 = 10 x=2
th
Similarly, Re belongs to 7 group
So, 18e rule for Re = 7– (–y) + 10 = 18
7+y=8
y = 1
x+y=3
–
Hx Fe(CO)4 ds fy,] Fe ds fy, 18e fu;e = 8 – (–x) + 4 × 2 = 18
 x + 8 = 10
x=2
blh izdkj Re 7th oxZ ls lEcU/k j[krk gSA
vr % Re ds fy, 18e fu;e = 7– (–y) + 10 = 18
7+y=8 y = 1 x+y=3
39. How many of the following relations is/are correct ?
(a) Mg > Al (electropositive character) (b) Al > Ga (electronegativity)
+
(c) N > N (Ionization energy) (d) Se > S (magnitude of egH)
+
(e) He > H (Atomic size) (f) O2–
2 < O2 (paramagnetic nature)
(g) C2 > N2 (Number of  bonds) (h) F2 > B2 (bond order)
(i) B2 > F2 (bond length) (j) NO2– > NO3– (bond angle)
fuEu esa ls fdrus lEcU/k lgh gSa \
(a) Mg > Al (oS|qr /kukRed vfHky{k.k½ (b) Al > Ga (oS|qr _.krk½
+
(c) N > N ((vk;uu ÅtkZ½ (d) Se > S (egH dk ifjek.k½
+
(e) He > H (ijek.oh; vkdkj½ (f) < O2 (vuqpqEcdh; izd`fr½
(g) C2 > N2 ( cU/k dh la[;k ½ (h) O2–
2 F2 > B2 (cU/k Øe)
(i) B2 > F2 (cU/k yEckbZ) (j) NO2– > NO3– (cU/k dks.k)
Ans. 4
Sol. (a), (c), (f), (i) are correct
(a), (c), (f), (i) lgh gSaA
2
40. How many N atoms in cyanuric amide (melamine) are sp hybridized?
lk;U;wfjd ,ekbM ¼esysekbu½ esa fdrus N ijek.kq sp2 ladfjr gSa\
Ans. 6
Sol. The lone pair on nitrogen of NH2 is in conjugation with the double bond of rings and hence is
delocalized.
NH2 ds ukbVªkstu ij ,dkadh ;qXe oy; ds f}cU/k ds lkFk la;qXeu esa jgrk gS vr% ;g foLFkkuhd`r gksrk gSA
Me O Me
controlled Si Si
41. a (Si(Me)xCly) + water ¼ty½ 
fu;fU=kr
   Me Me
condition ifjfLFkfr;k¡
O O
Si
Me Me
What is the value of a + x + y?
a + x + y dk eku D;k gS?
Page No. - 12
Ans. 7
Page No. - 13
Sol. The product is a silicone in which each Si is bonded to two O atom. This can be achieved by having two
Cl atoms.
bldk mRikn ,d flfydkWu gS ftlesa izR;sd Si nks O ijek.kq ls cfU/kr gksrk gSA bls nks Cl ijek.kq j[kus okys ls
izkIr fd;k tkrk gSA
Me Me
Me Me Me Si
O O
Cl–Si–Cl + 2H2O  HO–Si–OH + 2HCl 3HO–Si–OH  Me + 3H2O
Si Si–Me
Me Me Me O
Me Me
 a=3,x=2,y=2 So vr%, a + x + y = 7
42. Match the following :

Column-I Column-II
3
(A) XeO2F4 (p) Central atom is sp hybridized with no lone pair on it.
2
(B) SO2Cl2 (q) Central atom is sp hybridized.
(C) COCl2 (r) Central atom involves dx 2 – y 2 orbital in hybridization.
(D) HClO3 (s) Contain central atom in oxidation state, two less than the highest.
fuEu dks lqesfyr dhft, %

LrEHk&I LrEHk&II
(A) XeO2F4 (p) dsUnzh; ijek.kq sp3 ladfjr gS o bl ij ,dkadh bysDVªkWu ;qXe ugha gSA
(B) SO2Cl2 (q) dsUnzh; ijek.kq sp2 ladfjr gSA
(C) COCl2 (r) dsUnzh; ijek.kq ds ladj.k esa d 2 2 d{kd Hkkx ysrk gSA
x –y
(D) HClO3 (s) dsUnzh; ijek.kq dh vkWDlhdj.k voLFkk blds mPpre ls 2 de gSA
Ans. (A)  r ; (B)  p ; (C)  q ; (D)  s
3 2
Sol. (A) XeO2F4 SN = 6, sp d hybridization dz2 use and dx2 – y2 .
3
(B) SO2Cl2  SN = 4, sp hybridized ‘S’ with no lone pair.
2
(C) COCl2 SN = 3, sp hybridized.
(D) HClO3Oxidation no. of Cl = +5 & highest is +7. It contain one lone pair.
3 2
gy (A) XeO2F4 SN = 6, sp d ladj.k esa dz2 o dx2 – y2 iz;qDr gksrk gSA
3
(B) SO2Cl2  SN = 4, sp ladfjr ‘S’ ds lkFk dksbZ ,dkadh ;qXe ughaA
2
(C) COCl2 SN = 3, sp ladfjr.
(D) HClO3Cl dh vkWDlhdj.k vad = + 5 o mPpre +7 gSA ;g ,d ,dkadh ;qXe j[krk gSA

Column-I Column II
(A) Na3[Co(ox)3] (p) Show geometric isomerism.
(B) [RhCl(CO)(PPh3)(NH3)] (q) Low spin complex.
(C) K[Cr(NH3)2(CN)4] (r) Paramagnetic with more than two unpaired electrons.
(D) Ba[CoBr2Cl2] (s) Show colligative property corresponding of two particles per
formula.
(t) Electrically conducting.
LrEHk-I LrEHk-II
(A) Na3[Co(ox)3] (p) T;kferh; leko;ork n'kkZrk gSA
(B) [RhCl(CO)(PPh3)(NH3)] (q) fuEu pØ.k ladqy gSA
(C) K[Cr(NH3)2(CN)4] (r) nks ls vf/kd v;qfXer bysDVªkWu ds lkFk vuqpqEcdh;
(D) Ba[CoBr2Cl2] (s) izfrlw=k nks d.kksa ds laxr v.kqla[;d xq.k/keZ n'kkZrs gSA
(t) oS|qr vi?kV~;h pkyd
Ans. (A  q , t ); (B  p, q); (C  p, r, s, t ) ; (D  r , s , t )
Page No. - 14
6
Sol. (A) Oxidation number of Co = + 3. It is d , and electrons are paired. It is diamagnetic. It is low spin
complex. It produces four particles per formula.
8
(B) Oxidation number of Rh = + 1. It is 4d and coordination number is 4. It is square planer and
diamagnetic. It shows geometrical isomerism.
3
(C) K[Cr(NH3)2(CN)4] has Cr is in + 3 oxidation state , It shows GI , Cr( +3 ) is d hence paramagnetic
with
3 unpaired electrons.It produces 2 particles per formula and is electrically conducting.
2+ 7
(D) It contains Co which is d and it is tetrahedral. It is paramagnetic with 3 unpaired electron. It also
has 2 particle per formula. It is electrically conducting.
6
gy- (A) Co dk vkW- va- = + 3 gSA ;g d gS o bysDVªkWu ;qfXer gSA ;g izfrpqEcdh; gksrk gSA ;g fuEu pØ.k ladqy j[krk
gSA ;g izfr lw=k pkj d.k mRié djrk gSA
8
(B) Rh dk vkW- va- = + 1 gSA ;g 4d foU;klh gS o leUo; la[;k 4 gSA ;g oxZ leryh; o izfrpqEcdh; gSA ;g
T;kferh; leko;ork n'kkZrk gSA
3
(C) K[Cr(NH3)2(CN)4] esa Cr dk vkW- va- + 3 gSA ;g GI n'kkZrk gS] Cr( +3 ) d foU;klh gS o blfy, 3 v;qfXer
bysDVªkWu ds lkFk vuqpqEcdh; gksrk gSA ;g izfrlw=k 2 d.k mRiUu djrk gS o oS|qrh; :i ls pkyd gksrk gSA
2+ 7
(D) ;g Co j[krk gS tks fd d foU;klh gS o ;g prq"Qydh; gSA ;g 3 v;qfXer bysDVªkWu ds lkFk vuqpqEcdh;
gSA
;g izfrlw=k 2 d.k Hkh j[krk gSA ;g oS|qr :i ls pkydh; gksrk gSA
Column-I Column-II
–
(A) MnO4 (p) Paramagnetic and colored.
2–
(B) MnO4 (q) Diamagnetic and colored.
3–
(C) [Cu(CN)4] (r) Diamagnetic and colorless
(D) Ni(dmg)2 (s) Tetrahedral complex.
(t) Square planar complex.
LrEHk-I LrEHk-II
–
(A) MnO4 (p) vuqpqEcdh; o jaxhu
2–
(B) MnO4 (q) izfrpqEcdh; o jaxhu
3–
(C) [Cu(CN)4] (r) izfrpqEcdh; o jaxghu
(D) Ni(dmg)2 (s) prq"Qydh; ladqy
(t) oxZleryh; ladqy
Ans. (A  q , s ); (B  p, s); (C  r , s ) ; (D  q , t )
– 0
Sol. (A) MnO4 Oxidation no. of Mn = + 7, It is d . It is diamagnetic transfer spectrum. It is tetrahedral.(B)
2– 1
MnO4  Oxidation no. of Mn = + 6, It is d . It is paramagnetic & also colored. It is tetrahedral.
3– 10
(C) [Cu(CN)4] Oxidation no. of Cu = + 1, It is d . It is diamagnetic & colorless. It is tetrahedral.
8
(D) Ni(dmg)2Oxidation no. of Ni = + 2, It is d . It is square planar and diamagnetic but is colored.
gy- (A) MnO4–  Mn dk vkWDlhdj.k vad + 7 gSA blesa d0, foU;kl jgrk gSA ;g izfrpqEcdh; LFkkukUrfjr LisDVªe gS
o prq"Qydh; gksrk gSA
(B) MnO42–Mn dk vkWDlhdj.k vad + 6 gSA blesa d1 foU;kl jgrk gSA ;g vuqpqEcdh; o jaxhu gSA ;g
prq"Qydh; gksrk gSA
(C) [Cu(CN)4]3– Cu dk vkWDlhdj.k vad + 1 gSA blesa d10 foU;kl jgrk gSA ;g izfrpqEcdh; o jaxghu gSA ;g
prq"Qydh; gksrk gSA
(D) Ni(dmg)2Ni dk vkWDlhdj.k vad + 2 gSA blesa d8 foU;kl jgrk gSA ;g oxZ leryh; o izfrpqEcdh; gS
ysfdu jaxhu gSA
Page No. - 15
Column-I Column-II
(A) B > Be > Li (p) Electronegativity
(B) Na < K < Rb (q) Ionization energy
(C) Zn > Ca (r) Atomic radius
(D) S > Se (s) Metallic nature.
(t) Acidic nature of oxide

Column-I Column-II
(A) B > Be > Li (p) oS|qr _.krk
(B) Na < K < Rb (q) vk;uu ÅtkZ
(C) Zn > Ca (r) ijek.oh; f=kT;k
(D) S > Se (s) /kkfRod izd`fr
(t) vkWDlkbM dh vEyh; izd`fr
Ans. (A)  p, t ; (B)  r, s ; (C)  p, q, t ; (D)  p, q, t
Sol. (A) Electronegativity increases in going from left to right in period. I.E. of Be > I.E. of B. Atomic radius
decreases in going from left to right in period. Metallic nature decreases in going from left to right in
period.
Acidic nature of oxides increase in going from left to right.
(B) Down the group, electronegativity decreases, ionization energy decreases, Atomic radius increases,
metallic nature increases and acidic nature of oxide decreases.
(C) Calcium & Zn belong same period but Zn is more electronegative has higher I.E. smaller radius,
lesser metallic nature and has amphoteric oxide.
(D) EN, I.E and acidic nature of oxide of S is more than those of Se.
gy (A) vkorZ esa ck;sa ls nk;sa tkus ij oS|qr_.krk c<+rh gSA Be dh vk;uu ÅtkZ > B dh vk;uu ÅtkZ vkorZ esa ck;sa
ls nk;sa tkus ij ijek.oh; f=kT;k ?kVrh gSA vkorZ esa ck;sa ls nk;sa tkus ij /kkfRod izd`fr ?kVrh gSA vkorZ esa ck;sa
ls nk;sa tkus ij vkWDlkbMks dh vEyh; izd`fr c<+rh gSA
(B) oxZ esa uhps tkus ij oS|qr _.krk ?kVrh gS] vk;uu ÅtkZ ?kVrh gS] ijek.oh; f=kT;k Ck<+rh gS] /kkfRod izd`fr
c<+rh gS o vkWDlkbM dh vEyh; izd`fr ?kVrh gSA
(C) dSfY'k;e o Zn leku vkorZ ls lEcfU/kr gksrs gS ysfdu Zn vf/kd oS|qr _.krk]mPp vk;uu ÅtkZ] NksVh f=kT;k]
de /kkfRod izd`fr o mHk;/kehZ vkWDlkbM cukrk gSA
(D) S dh oS|qr _.krk]vk;uu ÅtkZ o vkWDlkbM dh vEyh; izd`fr Se ls vf/kd gksrh gSA
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INORGANIC CHEMISTRY

TARGET : JEE (ADVANCED) 2018

Course : VIJETA & VIJAY (ADP & ADR) Date : 16.04.2018

5-planes of symmetry 2-planes of symmetry

7. Which among the following will be named as dibromobis(ethylenediamine)chromium (III) bromide ?

(A*) CH3CH2OH (B*) (C) CH3 – CH2 – CH3 (D*) N(CH3)3

Sol. (A) (B)

gy- (A) (B)

(A*) Cl–CC–Cl (B*) O=C=O (C*) N2 (D)

tgk¡ A B vlefefr f}nUrqd fyxs.M dks iznf'kZr djrk gSA

(A*) NH3 (B*) H2N(CH3) (C*) H2N(SiH3) (D*)

NH3, NH2(CH3), rFkk H2N(SiH3), HN (SiH3)2 dh vis{kk mÙke {kkj gSA

Sol. four membered cyclic silicate pkj lnL;h; pfØ; flfydsV

18.* Which of the following is/are correct?

20.* Which of the following show intramolecular hydrogen bonding?

22. Statement-1 : H2S is less acidic than H2Te.

23. Statement-1 : Atomic size in Na is larger than Al.

24.* Which of the following is/are correct ?

Comprehension # 2 (One or more than one correct options)

What is the hybridization of ‘S’ in this compound.

bl ;kSfxd esa ' S' dk ladj.k D;k gS\

30. Which of the following contain all carbon of equal electronegativity ?

35. The sum of oxidation state of Co and Cr in the following complex is :

42. Match the following :

fuEu dks lqesfyr dhft, %

43. Match the following :

fuEu dks lqesfyr dhft, %

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(A) CH3CH2OH (B) (C) CH3 – CH2 – CH3 (D*) N(CH3)3

(A) Cl–CC–Cl (B) O=C=O (C*) N2 (D)

(A) NH3 (B) H2N(CH3) (C) H2N(SiH3) (D)