TARGET: JEE (Main + Advanced) 2022 Course: VIKAAS (JA) NO. C1

DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY
P - C H E M I S T RY
TARGET : JEE (Main + Advanced) 2022


EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
Course : VIKAAS(JA) NO. C1

1. Course of the week as per plan :
2. Course covered till previous week :
3. Target of the current week :
4. DPP Syllabus :
DPP No. # C1 (JEE-ADVANCED)
Total Marks : 47 Max. Time : 31 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.9 (3 marks, 2 min.) [27, 18]
Multiple choice objective ('–1' negative marking) Q.10 & Q. 11 (4 marks, 2 min.) [08, 04]
Integer type Questions ('–1' negative marking) Q.12 to Q.14 (4 marks, 3 min.) [12, 09]
ANSWER KEY
1. (C) 2. (A) 3. (D) 4. (C) 5. (A) 6. (C) 7. (D)
8. (D) 9. (A) 10. (ABD) 11. (ACD)
12. State function : a, b, c, d, g, h, j ; Path function : e, f, i, k
13. Intensive : a, c, d, f, g, h, i, k ; Extensive : b, e, j, l
14. Open system : b, f, g, i, j ; Closed system : a, c, h ; Isolated system : d, e
1. In thermodynamics, a process is called reversible when :
(A) surrounding and system change into each other.
(B) there is no real boundary between system and surrounding.
(C*) the surrounding is always in equilibrium with the system.
(D) the system changes into the surrounding spontaneously.
Å"ekxfrdh esa] ,d çØe mÙØe.kh; dgykrk gS] tc %
(A) ifjos'k rFkk fudk;] ,d nwljs esa ifjofrZr gksaA
(B) ifjos'k rFkk fudk; ds e/; dksbZ okLrfod ifjlhek ugha gksA
(C*) ifjos'k lnSo] fudk; ds lkFk lkE; esa jgsA
(D) fudk;] ifjos'k esa Lor% ifjofrZr gksA
2. A thermodynamic system goes in cyclic reversible process as represented in the following P–V
diagram:
,d Å"ekxfrdh ra=k] uhps n'kkZ;s P–V vkjs[k ds vuqlkj] ,d pfØ; mRØe.kh; izØe esa Hkkx ysrk gS %
The net work done during the complete cycle is given by the area :
pØ iw.kZ djus ds nkSjku fd;k x;k ifj.kkeh dk;Z] fuEu {ks=k }kjk fn;k tkrk gS %
(A*) cycle ACBDA (B) AA1B1BDA (C) AA2B2B (D) AA1B1BCA
(A*) pØ ACBDA (B) AA1B1BDA (C) AA2B2B (D) AA1B1BCA
Reg. & Corp. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.-1
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3. Which of the following are not state functions?
(I) E (II) q (III) W (IV) G
(A) (I)and (IV) (B) (II) (III) and (IV) (C) (I), (II)and (III) (D*) (II) and (III)
fuEu esa ls voLFkkQyu dkSulk ugha gS ?
(I) E (II) q (III) W (IV) G
(A) (I)vkSj (IV) (B) (II) (III) vkSj (IV) (C) (I), (II)vkSj (III) (D*) (II) vkSj (III)
Sol. q, w are at path functions. q, w iFk Qyu ij gSA
4. A well stoppered thermoflask contains some ice cubes. For small time duration, this is an example of a-
,d vPNh rjg cUn FkeZl ¶ykLd esa dqN cQZ ds VqdM+s gSaA de le; vUrjky ds fy;s ;g ......... mnkgj.k gS&
(A) Closed system (B) Open system (C*) Isolated system (D)Non-thermodynamic
system
(A) cUn fudk; dk (B) [kqys fudk; dk (C*) foyfxr fudk; dk (D) ukWu&Å"ekxfrdh; fudk; dk
5. When ammonium chloride is dissolved in water, the solution becomes cold. The dissolution process is -
tc veksfu;e DyksjkbM dks ty esa feyk;k tkrk gS] rks foy;u B.Mk gks tkrk gSA ?kqyus dk izØe gS –
(A*) Endothermic (B) Exothermic (C) Supercooling (D) None of the above
(A*) Å"ek'kks"kh (B) Å"ek{ksih (C) vfr'khru (D) buesa ls dksbZ ugha
6. Statement-1 : T, P & V are state functions.

Statement-2 : The value of state function depends on the state of the system & how it is reached.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C*) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
dFku-1 : T, P rFkk V voLFkk Qyu gSA
dFku-2 : voLFkk Qyu ds eku] ra=k dh voLFkk rFkk og voLFkk dSls izkIr dh xbZ] ij fuHkZj djrs gSaA
(A) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS ; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C*) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
7. Which of the following is an intensive property ?

(A) Temperature (B) Viscosity (C) Surface tension (D*) All of these
fuEu esa ls dkSulk ek=kk LorU=k xq.k/keZ gS\
(A) rkieku (B) ';kurk (C) i`"Bh; ruko (D*) mijksDr lHkh
Sol. The properties of the system value of which is independent of the amount of substance present in the
system are called intensive properties e.g., viscosity, surface tension temperature, pressure etc.
Sol. ra=k dk og xq.k/keZ ftldk eku blesa mifLFkr inkFkZ dh ek=kk ls Lora=k gks ek=kk Lora=k xq.k/keZ dgykrk gSA
mnkgj.k ';kurk i`"Bh; ruko] nkc bR;kfnA
8. Thermodynamic equilibrium involves

(A) Chemical equilibrium (B) Thermal equilibrium
(C) Mechanical (D*) All the above
Å"ekxfrdh; lkE; fuEu ls lEcfU/kr gSA
(A) jklk;fud lkE; ls (B) Å"eh; lkE; ls
(C) ;kaf=kdh lkE; ls (D*) mijksDr lHkh
9. Among the following, the respective number of closed, open and isolated systems is:
(a) Boiler (b) coolant system in a nuclear reactor
(c) Thermos flask (d) Universe
(e) Living things (f) Human body
(g) A cup of tea (h) A closely packed room in which a split air-conditioner is working.
PAGE NO.-2
fuEu esa ls can] [kqys] rFkk foyfxr fudk;ksa dh Øe'k% la[;k D;k&D;k gS %
(a) ckW;yj (b) 'khryu fudk; ¼ra=k½ esa ukfHkdh; izfrdkjh (nuclear reactor)
(c) rkiLFkk;h ik=k (d) czãk.M
(e) thfor çk.kh (f) ekuo 'kjhj
(g) ,d I;kyk pk; (h) ,d can dejk] ftlesa ijrh; ok;q ç'khrd (split air-conditioner) dk;Z dj jgk gSA
(A*) 1, 5, 2 (B) 1, 6, 1 (C) 2, 4, 2 (D) 2, 5, 1
10.* Which of the following is/are extensive properties ?

(A*) Enthalpy (B*) Entropy (C) Specific heat (D*) Volume
fuEu esa ls dkSulk@dkSuls ek=kkRed xq.k/keZ gS@gSa \
(A*) ,UFkSYih (B*) ,UVªkih (C) fof'k"V Å"ek (D*) vk;ru
Sol. Intensive property : Specific heat
Extensive property : Enthalpy, entropy, volume.
gy. ek=kk Lora=k xq.k/keZ : fof'k"V Å"ek
ek=kkRed xq.k/keZ : ,UFkSYih] ,UVªkWih] vk;ru
11.* Which of the following is/are thermodynamic function ?

(A*) Internal energy (B) Work done (C*) Enthalpy (D*) Entropy
fuEu esa ls dkSulk ,d Å"ekxfrdh; Qyu a gS \
(A*) vkUrfjd ÅtkZ (B) fd;k x;k dk;Z (C*) ,UFkSYih (D*) ,UVªkWih
Sol. Thermodynamic functions are : Internal energy, enthalpy, entropy, pressure, volume, temperature, free
energy, number of moles.
gy. Å"ekxfrdh; Qyu % vkUrfjd ÅtkZ] ,UFkSYih] ,UVªkWih] nkc] vk;ru] rkieku] eqDr ÅtkZ] eksyksa dh la[;k gksrs gSaA
12. Categorise the following into state and path functions :

(a) Internal energy (b) Pressure (c) Volume (d) Temperature (e) Heat
(f) Work (g) Free energy (h) Entropy (i) Molar heat Capacity (j) Height of a hill
(k) Distance travelled in climbing the hill
fuEu dks voLFkk rFkk iFk Qyuksa esa oxhZd`r dhft;s %
(a) vkUrfjd ÅtkZ (b) nkc (c) vk;ru (d) rkieku (e) Å"ek (f) dk;Z
(g) eqDr ÅtkZ (h) ,UVªkWih (i) eksyj Å"ek /kkfjrk (j) igkM+ dh Å¡pkbZ
(k) igkM+ ij p<+us esa r; dh xbZ nwjhA
Sol. State function : a, b, c, d, g, h, j ; Path function : e, f, i, k
Sol. voLFkk Qyu: a, b, c, d, g, h, j ; iFk Qyu : e, f, i, k
13. Categorise these properties into extensive and intensive property :

(a) Pressure of gas (b) Volume (c) Density
(d) Temperature (e) Heat capacity (f) Specific heat capacity
(g) Molar heat capacity (h) Molarity (i) Dielectric constant
(j) Internal energy (k) Specific internal energy
(l) Mass
fuEu xq.kksa dks ek=kkRed rFkk ek=kkLora=k xq.kkas esa oxhZd`r dhft;ss %
(a) xSl dk nkc (b) vk;ru (c) ?kuRo (d) rkieku
(e) Å"ek /kkfjrk (f) fof'k"V Å"ek /kkfjrk (g) eksyj Å"ek /kkfjrk (h) eksyjrk
(i) ijkoS|qr fu;rkad (j) vkarfjd ÅtkZ (k) fof'k"V vkarfjd ÅtkZ (l) nzO;eku
Sol. Intensive ¼ladh.kZ½ : a, c, d, f, g, h, i, k ; Extensive ¼foLrh.kZ½ : b, e, j, l
14. Classify the following among closed, open and isolated system :
(a) Pressure cooker (b) Boiler
(c) Liquid cooling system of an automobile (d) Thermos flask
(e) Universe (f) Living things
(g) Human body (h) Electrochemical cells
(i) A cup of tea
(j) A closely packed room in which a split air-conditioner is working.
PAGE NO.-3
fuEu dks can] [kqys] rFkk foyfxr fudk;ksa esa oxhZd`r dhft;s %
(a) çs'kj dqdj (b) ckW;yj
(c) ,d Lopfyr okgu dk nzo 'khryu fudk; ¼ra=k½ (d) rkiLFkk;h ik=k
(e) czãk.M (f) thfor çk.kh
(g) ekuo 'kjhj (h) fo|qr jklk;fud lsy
(i) ,d I;kyk pk;
(j) ,d can dejk] ftlesa ijrh; ok;q ç'khrd (split air-conditioner) dk;Z dj jgk gSA
Sol. Open system : b, f, g, i, j ; Closed system : a, c, h ; Isolated system : d, e
Sol. [kqyh fudk; : b, f, g, i, j ; cUn fudk; : a, c, h ; i`Fkd fudk; : d, e
P - C H E M I S T RY


EST INFORM AT IO
DPP

1. Course of the week as per plan : 2. Course covered till previous week :
3. Target of the current week : 4. DPP Syllabus :
Multiple choice objective ('–1' negative marking) Q.14 (4 marks, 2 min.) [04, 02]
Match the column (no negative marking) Q.18 (8 marks, 6 min.) [08, 06]
ANSWER KEY
1. (B) 2. (D) 3. (B) 4. (A) 5. (D) 6. (C) 7. (A)
8. (D) 9. (A) 10. (A) 11. (B) 12. (D) 13.* (BC) 14.* (BD)
15. 80 J, –90 J 16. 6 kJ 17. 0 18. (Ap, s); (Bp,r,s) ; (C  q); (D  p, r, s)
1. The work done during the expansion of a gas from a volume of 4 dm 3 to 6 dm3 against a constant
external pressure of 3 atm, is :
(A) – 6 J (B*) – 608 J (C) + 304 J (D) – 304 J
fdlh xSl ds 4 Mseh3 vk;ru ds 6 Mseh3 vk;ru esa izlkj ds nkSjku 3 ok;qe.Myh; cká nkc ds fo:) fd;k x;k
dk;Z gksxk
(A) – 6 twy (B*) – 608 twy (C) + 304 twy (D) – 304 twy
Sol. Work done fd;k x;k dk;Z (W) = – Pext (V2 – V1)
= – 3 x (6 – 4) = – 6 L-atm
= – 6 x 101.32 J
( 1 L-atm = 101.32 J)
= – 607.92  608 J
2. Three moles of an ideal gas expanded spontaneously into vacuum. The work done will be:
(A) Infinite (B) 3 Joules (C) 9 Joules (D*) Zero
,d vkn'kZ xSl ds rhu eksy fuokZr esa Lor% izlkfjr gksrs gSaA fd;k x;k dk;Z fuEu gksxk %
(A) vuUr (B) 3 twy (C) 9 twy (D*) 'kwU;
Sol. Since the ideal gas expands spontaneously into vacuum, Pext = 0, hence work done is also zero.
gy pwafd fuokZr esa vkn'kZ xSl Lor% izlkfjr gksrh gS blfy, Pext = 0 vr% fd;k x;k dk;Z Hkh 'kwU; gksrk gSA
3. Which of the following is not a thermodynamic function ?
(A) Internal energy (B*) Work done (C) Enthalpy (D) Entropy
PAGE NO.-4
fuEu esa ls ,d Å"ekxfrdh; Qyu dkSulk ugha gS \
(A) vkUrfjd ÅtkZ (B*) fd;k x;k dk;Z (C) ,UFkSYih (D) ,UVªkWih
Sol. Thermodynamic functions are : Internal energy, enthalpy, entropy, pressure, volume, temperature, free
energy, number of moles.
Sol. Å"ekxfrdh; Qyu % vkUrfjd ÅtkZ] ,UFkSYih] ,UVªkWih] nkc] vk;ru] rkieku] eqDr ÅtkZ] eksyksa dh la[;k gksrs gSaA
4. For a reversible process, calculate magnitude of work done from the
following PV diagram :
(A*) 4
(B) 6
(C) 2
(D) 0
4. ,d mRØe.kh; çØe ds fy,] fuEu P-V vkjs[k ds vk/kkj ij] fd;s x;s
dk;Z ds ifjek.k dh x.kuk dhft;s %
(A*) 4
(B) 6
(C) 2
(D) 0
5. The internal energy change when a system goes from state A to B is 40 kJ/mol. If the system goes from
A to B by a reversible path and returns to state A by an irreversible path, what would be the net change
in internal energy ?
,d ra=k voLFkk A ls B esa tkrk gS rks vkUrfjd ÅtkZ ifjorZu 40 kJ/mol gSaA ;fn ra=k ,d mRØe.kh; iFk }kjk A
ls B dh vksj tkrk gS o ,d vuqRØe.kh; iFk }kjk voLFkk A dh vksj iqu% tkrk gS] rks vkUrfjd ÅtkZ esa dqy
ifjorZu D;k gS \
(A) 40 kJ (B) > 40 kJ (C) < 40 kJ (D*) Zero‘’¼'kwU;½
Sol. E = 0, in a cyclic process. (E = 0,,d pØh; izØe gSA)
6. In a system, a piston caused an expansion against an external pressure of 1.2 atm giving a change in
volume of 32 L for which E = –51 kJ. What was the value of heat involved : (Take 1 L atm = 100 J)
,d ra=k esa ,d fiLVu] 1.2 atm ds ckg~; nkc ds fo:) izlkfjr gksdj] vk;ru esa 32 L dk ifjorZu nsrk gS] ftlds
fy, E = –51 kJ gSA ifjorZu ds fy, Å"ek dk eku D;k gksxk % (yhft, 1 L atm = 100 J)
(A) –36 kJ (B) –13 kJ (C*) –47 kJ (D) 24 kJ
Sol. w = Pext V
w = – 1.2 × 32 = – 38.4 lt atm.
= – 38.4 × 100 J = – 3840 J = – 3.84 kJ
E = q + w
so, q = E – w = – 51 + 3.84 = – 47.16.
7. In a closed insulated container a liquid is stirred with a paddle to increase the temperature, which of the
following is true ?
,d Å"ekjks/kh ik=k esa rki c<+kus ds fy;s nzo dks isMy ls foMksfyr fd;k tkrk gSaA fuEu esa ls dkSu&lk lgh gSa %
(A*) E = W  0, q = 0 (B) E = W = 0, q  0
(C) E = 0, W = q  0 (D) W = 0, E = q  0
Sol. In closed insulated contianer a liquid is stirred with a paddle to increase the temprature, therefore No
heat exchange with surrounding, so for it q = 0.
Hence, from first law of thermodynamics
cUn dqpkyd ik=k esa ,d isaMy ds lkFk ,d nzo dks fgyk;k tkrk gS rkfd rkieku esa o`f) dh tk lds vr% ifjos'k
ds lkFk dksbZ Å"eh; fofues; ugha gksrk gSA q = 0.
vr% Å"ekxfrdh ds izFke fu;e ls
E = q + W
if ;fn, q = 0
 E = W but not equal to zero.
PAGE NO.-5
 E = W 'kwU; ds cjkcj ugha gSA
8. 2 mole of an ideal gas expands isothermally and reversibly from 1 L to 10 L at 300 K. What is the
internal energy change :
300 K ij ,d vkn'kZ xSl ds 2 eksy] 1 L ls 10 L rd lerkih; rFkk mRØe.kh; :i ls çlkfjr gksrs gSaA bl çØe esa
vkarfjd ÅtkZ ifjorZu D;k gS %
(A) 4.98 kJ (B) 11.47 kJ (C) –11.47 kJ (D*) 0 kJ
9. If 1 mole of an ideal gas expands isothermally at 37ºC from 15 litres to 25 litres, the maximum work
obtained is:
;fn 37ºC ij lerkih; :i ls ,d vkn'kZ xSl ds 1 eksy dks çlkfjr djus ij vk;ru 15 yhVj ls 25 yhVj gks
tkrk gS rks çkIr vf/kdre dk;Z fuEu gS %
(A*) 12.87 L atm (B) 6.43 L atm (C) 8.57 L atm (D) 2.92 L atm
V2 25
Sol. W max, iso = – 2.303 nRT log = – 2.303 × 1 × 0.0821 × 310 × log
V1 15
= – 58.61 × 0.22 = – 12.87 L atm
(–ve sign shows work of expansion i.e. work done by the system)
V
gy- W vf/kdre]lerkih; = – 2.303 nRT log 2
V1
25
= – 2.303 × 1 × 0.0821 × 310 × log
15
= – 58.61 × 0.22 = – 12.87 L atm
(–ve fpUg dk;Z çlkj dks n'kkZrk gS vFkkZr~ fudk; }kjk fd;k x;k dk;Z)
10. The q value and work done in isothermal reversible expansion of one mole of an ideal gas from initial
pressure of 1 bar to final pressure of 0.1 bar at constant temperature 273 K are:
1 eksy vkn'kZ xSl ds fy;s fu;r rki 273 K ij izkjfEHkd nkc 1 ckj ls vfUre nkc 0.1 ckj rd mRØe.kh;
lerkih; izlkj esa q dk eku rFkk fd;k x;k dk;Z fuEu gS %
(A*) 5.22 kJ, –5.22 kJ (B) –5.22 kJ, 5.22 kJ (C) 5.22 kJ, 5.22 kJ (D) –5.22 kJ, –5.22 kJ
11. Select the incorrect statement :
(A) A continuous curve can be plotted between thermodynamic parameters for a reversible process.
(B*) An irreversible process takes infinite time for completion.
(C) There is an infinitesimal difference between driving force and opposing force in a reversible
process.
(D) None of these
vlR; dFku dk p;u dhft;s :
(A) ,d mRØe.kh; izØe ds fy;s] Å"ekxfrdh; izkpyksa esa ,d lrr~ oØ cuk;k tk ldrk gSA
(B*) ,d vuqRØe.kh; izØe] iwjk gksus ds fy;s vuUr le; ysrk gSA
(C) ,d mRØe.kh; izØe esa] pykus okys cy o foijhr cy esa vuUr lw{e vUrj gksrk gSA
(D) buesa ls dksbZ ugha
12. Choose the incorrect statement :
(A) system and surrounding are always separated by a real or imaginary boundary.
(B) perfectly isolated system can never be created.
(C) in reversible process, energy change in each step can be reversed.
(D*) irreversible process is also called quasi-equilibrium state.
xyr dFku dk p;u dhft;s %
(A) fudk; rFkk ifjos'k ges'kk] okLrfod vFkok dkYifud ifjlhek }kjk i`Fkd jgrs gSaA
(B) iw.kZr% foyfxr fudk; dk fuekZ.k dHkh ugha fd;k tk ldrk gSA
(C) mÙØe.kh; çØe esa çR;sd in esa ÅtkZ ifjorZu] mÙØe.kh; gks ldrk gSA
(D*) vuqÙØe.kh; çØe dks Doklh lkE;okLFkk (quasi-equilibrium state) Hkh dgk tkrk gSA
13.* 1 mole of argon gas is expanded isothermally and reversibly from 10L to 100L. Which of the following
options is/are incorrect for the process :
(A) E = 0 (B*) W = 0 (C*) heat supplied (q) = 0(D) T = 0
PAGE NO.-6
1 eksy vkxZu xSl] 10 L ls 100 L rd lerkih; rFkk mRØe.kh; :i ls izlkfjr gksrh gSA izØe ds fy, fuEu esa ls
dkSulk@dkSuls fodYi xyr gS@gSa %
(A) E = 0 (B*) W = 0 (C*) nh xbZ Å"ek (q) = 0 (D) T = 0
14.* For isothermal expansion of an ideal gas sample, the correct relation(s) is/are : (Consider all quantities
with sign according to IUPAC convention and the reversible and irreversible processes are carried out
between same initial and final states.)
(A) W rev > W irrev (B*) W irrev > W rev (C) qrev < qirrev (D*) Erev = Eirrev
vkn'kZ xSl ds ,d uewus ds lerkih; izlkj ds lanHkZ esa lgh lEcU/k fuEu gS@gSa % ¼ IUPAC fu;eksa ds vuqlkj lHkh
inksa dks fpUg ds lkFk ysa rFkk mRØe.kh; o vuqRØe.kh; izØe] leku izkjfEHkd rFkk vfUre voLFkk ds e/; lEiUu
fd;s tkrs gSaA½
(A) W mRØe.kh; > W vuqRØe.kh; (B*) W vuqRØe.kh; > W mRØe.kh;
(C) qmRØe.kh; < qvuqRØe.kh; (D*) EmRØe.kh; = EvuqRØe.kh;
15. When a system is taken from state 'a' to state 'b' in fig. along path 'acb', 100 J
of heat flows into the system and the system does 40 J of work. How much
heat flows into the system along path 'aeb' if work done by the system is 20 J?
The system returns from 'b' to 'a' along path 'bda'. If the work done on the
system is 30 J, does the system absorb or liberate heat ? How much ?
15. tc ,d ra=k ¼fudk;½] fp=kkuqlkj] iFk 'acb' ds vuqlkj voLFkk&'a' ls voLFkk&'b' rd ys

tk;k tkrk gS] rc blesa fudk; dks 100J dh ÅtkZ nh tkrh gS rFkk fudk; 40 J dk dk;Z
djrk gSA iFk& 'aeb' ds vuqlkj ra=k esa fdruh ek=kk esa Å"ek nh tkrh gS] ;fn ra=k }kjk
20 J dk dk;Z fd;k tkrk gS\ ra=k ¼fudk;½ iFk 'bda' ds vuqlkj iqu% voLFkk&'b' ls
voLFkk&'a' rd vkrk gSA ;fn fudk; ij 30 J dk;Z fd;k tkrk gS] rc fudk; Å"ek dk
vo'kks"k.k djsxk vFkok mRltZu djsxk \ fdruh ek=kk esa \
Ans. 80 J, –90 J
Sol.  Uab = Qabc + W abc
 or Uab = 100 – 40 = 60 J
 Uab = Qaeb + W aeb
 or 60 = Qaeb – 20
or Qaeb = 80 J Ans.
 Uba = – 60 J
  W bda = 30 J
 Uba = Qbda + W bda
 or Qbda = Uba – W bda
or Qbda = – 60 – 30 = – 90 J Ans.

Since Qbda is (–)ve  Heat is liberated from the system.
¼ pwafd Qbda _.kkRed gS blfy;s Å”"ek fudk; ls eqDr gks tkrh gS½
16. In a system, where E = – 15 kJ, a piston expanded against a external pressure of 1.2 atm giving a
change in volume of 75 lt. What was the magnitude of change in heat energy of this system (in kJ) ?
(Take 1 lt atm = 100 J).
,d ra=k esa] tgk¡ E = – 15 kJ gS ,d fiLVu] 1.2 atm ds ckg~; nkc ds fo:) izlkfjr gksdj] 75 lt dk vk;ru esa
ifjorZu n'kkZrk gS bl ra=k ds fy, Å"ek esa ifjorZu dk ifjek.k D;k gS \ (1 lt atm = 100 J).
Ans. 6 kJ
PAGE NO.-7
Sol. q = E – W
1.2  75  100
= – 15 + = – 6 kJ
1000
17. A thermodynamic system undergoes cyclic process ABCDA as shown in figure. Calculate the value of
work done.
vkd`fr esa n'kkZ;s vuqlkj pØh; izØe ABCDA ij ls ,d Å"ekxfrdh; ra=k xqtjrk gSA fd;s x;s dk;Z dh x.kuk
dhft;s
P
C B
3P0
2P0 O
P0 A D
V
V0 2V0
Ans. 0
Sol. Work done by the gas = Work done on the gas = POVO / 2.
So, total work done = 0.
Sol. xSl }kjk fd;k x;k dk;Z = xSl ij fd;k x;k dk;Z = POVO / 2.
blfy,] fd;k x;k dqy dk;Z = 0.
18. Match the column :
Column I Column II
P
B
(A) A (p) Temperature is increasing
V
V
A B
(B) (q) Temperature is constant
T
P A
(C) (r) Volume is constant

B
T
P
B
(D) A (s) Pressure is increasing
fuEu dks lqesfyr dhft,&

LrEHk I LrEHk II
P
B
(A) A (p) rkieku esa o`f) gksrh gSA
V
V
A B
(B) (q) rkieku fu;r jgrk gS
T
PAGE NO.-8
P A
(C) (r) vk;ru fu;r g

B
T
P
B
(D) A (s) nkc esa o`f) gksrh gSA
T
Ans. (A  p, s) ; (B  p, r, s) ; (C  q) ; (D  p, r, s)
P / I-CHEMISTRY


EST INFORM AT IO
DPP

DPP No. # C3 (JEE-MAIN)
ANSWER KEY
1. (C) 2. (A) 3. (B) 4. (D) 5. (D)
6. (D) 7. (B) 8. (B) 9. (A) 10. (A)
11. (A) 12. (C) 13. (A) 14. (B) 15. (C)
16. (B) 17. (C) 18. (B)
1. Which of the following is correct option for free expansion of an ideal gas under adiabatic condition ?
:)ks"e fLFkfr esa ,d vkn'kZ xSl ds eqDr izlkj ds fy, fuEu esa ls dkSu lk fodYi lgh gS \
(A) q = 0, T  0, w = 0 (B) q  0, T = 0, w = 0
(C*) q = 0, T = 0, w = 0 (D) q = 0, T < 0, w  0
Sol. For free expansion of an Ideal gas under adiabatic condition q = 0 T = 0 W = 0.
:)ks"eh; ifjfLFkfr;ksa esa ,d vkn'kZ xSl ds eqDr izlkj ds fy, q = 0 T = 0 W = 0 gSA
2. 20 g Ar gas is allowed to expand reversibly and isothermally at 300 K from 5 L to 10 L. Calculate the
approximate value of work done. (Take R = 25/3 J/K/mole, at.wt of Ar = 40 u)
300 K ij 20 g Ar xSl dks 5 L ls 10 L rd mRØe.kh; rFkk lerkih; :i ls çlkfjr fd;k x;kA rc fd;s x;s
dk;Z ds yxHkx eku dh x.kuk dhft;sA (R dks 25/3 J/K/mole rFkk Ar dk ijek.kq nzO;eku = 40 u ysa)
(A*) – 862.5 J (B) – 375 J (C) – 1437.5 J (D) – 1250 J
V2 20 10
Sol. W = – 2.303 nRT log  W = – 2.3 × × 25/3 × 300 log = – 862.5 J.
V1 40 5
3. The work done in an adiabatic process on an ideal gas by a constant external pressure would be :
,d :)ks"eh; izØe esa fu;r ckâ; nkc }kjk ,d vkn'kZ xSl ij fd;k x;k dk;Z fuEu ds cjkcj gksxk %
(A) Zero ('kwU;) (B*) E (C) H (D) q
Sol. From I law of thermodynamics E = Q + W
where Q = 0 for adiabatic process.
gy. Å"ekxfrdh ds izFke fu;e ds vuqlkj E = Q + W
tgk¡ Q = 0 gS :)ks"eh; izØe ds fy,A
PAGE NO.-9
4. P–V plots for two gases during an adiabatic process are given in the figure :
uhps n'kkZ;s fp=k esa] nks xSlksa ds fy,] ,d :)ks"eh; izØe ds nkSjku P–V vkjs[k fn;s x;s gSa %
nkc
Volume vk;ru
Plot A and plot B should correspond to : (Assume ideal behaviour)
vkjs[k A rFkk vkjs[k B, fuEu xSlksa ls lEcfU/kr gksus pkfg;s % (vkn'kZ O;ogkj ekusa)
(A) He and O2 (B) SO2 and Ar (C) O2 and He (D*) Both (B) and (C)
(A) He rFkk O2 (B) SO2 rFkk Ar (C) O2 rFkk He (D*) (B) o (C) nksuksa
Sol.  for O2 = 1.44  for He = 1.66.
5. For an ideal gas having molar mass M, specific heat at constant pressure can be given as :
,d vkn'kZ xSl] ftldk eksyj nzO;eku M gS] ds fy, fu;r nkc ij fof'k"V Å"ek] fuEu izdkj ls nh tk ldrh gS %
 RM R RM R
(A) (B) (C) (D*)
 –1 M(   1)  –1 M(   1)
6. Equal volumes of two monoatomic gases, A and B, at same temperature and pressure are mixed. The
ratio of specific heats (Cp/Cv) of the mixture will be :
nks eksuks,VkWfed xSlksa] A rFkk B ds cjkcj vk;ru] leku rki vkSj nkc ij feyk;s tkrs gSaA feJ.k dh vkisf{kd Å"ek
(Cp/Cv) dk vuqikr fuEu gksxk %
(A) 0.83 (B)1.50 (C) 3.3 (D*) 1.67
CP 5 R 5
Sol. = 32 = = 1.67
CV 2R 3
7. An ideal gas with Cv = 3R expands adiabatically into a vacuum thus doubling its volume. The final
temperatue is given by :
,d Cv = 3R dh vkn'kZ xSl dks fuokZr esa :)ks"eh; :i ls izlkfjr fd;k tkrk gS rks bldk vk;ru nqxquk gks tkrk
gS rks vfUre rkieku fn;k tk ldrk gSA
T1
(A) T2 = T1[2–1/3] (B*) T2 = T1 (C) T2 = 2T1 (D) T2 =
2
Sol. It is free expansion where T = 0 ;g eqDr izlkj gSA tgk¡ T = 0
8. What is the difference between change in enthalpy and change in internal energy at constant volume :
fu;r vk;ru ij ,UFkSYih ifjorZu rFkk vkarfjd ÅtkZ ifjorZu esa vUrj D;k gS %
(A) 0 (B*) VdP (C) –VdP (D) PdV
9. In the balanced chemical reaction, O3– + a– + bH+ CH2O + d2

a, b, c and d respectively correspond to
larqfyr jklk;fud vfHkfØ;k] O3– + a– + bH+ cH2O + d2
a, b, c o d Øe'k% fuEu gS %
(A*) 5, 6, 3, 3 (B) 5, 3, 6, 3 (C) 3, 5, 3, 6 (D) 5, 6, 5,5
PAGE NO.-10
10. % yield of the following reaction is plotted against pressure at a definite temperature.
,d fuf'pr rkikeu ij fuEu vfHkfØ;k dh % yfC/k o nkc ds chp vkjs[k [khpk¡ x;k gSA
2SO2(g) +O2(g)  2SO3(g)
Which of the following reaction is correct ? fuEu esa ls dkSulh vfHkfØ;k lgh gS \
T3
%
yield T2
T1
P
(A*) T1 > T2 > T3 (B) T3 > T2 > T1 (C) T1 = T2 = T3 (D) T1 < T2 < T3
Sol. Reaction is exothermic, therefore, yield will decreases with increase in temperature.
vfHkfØ;k Å"ek{ksih gS] vr% rkieku esa o`f) ds lkFk yfC?k esa deh vk tk,sxhA
11. N2O4(g)  2NO2(g) at a constant temperature, vapour density of N2O4 is found to be 30. Calculate %
dissociation of N2O4.
N2O4(g)  2NO2(g) fu;r rkieku ij N2O4 ok"i ?kuRo 30 ik;k tkrk gSA N2O4 dh % fo;kstu dh x.kuk
dhft,A
(A*) 53.3% (B) 46.7% (C) 16.7% (D) 83.3%
12. What can be said about work done in going through the cyclic process shown in the adjacent figure :
(A) Magnitude = 4L atm; work is done by the system.

(B) Magnitude = 16L atm; work is done on the system.
(C*) Magnitude = 4L atm; work is done on the system.
(D) No work is done
lkFk fn;s x;s fp=k esa fn[kk;s x;s pfØ; izØe ls tkus ij fd;s x;s dk;Z ds ckjs esa D;k dgk tk ldrk gS %
(A) ifjek.k = 4L atm; ra=k ds }kjk dk;Z fd;k x;k gSA
(B) ifjek.k = 16L atm; ra=k ij dk;Z fd;k x;k gSA
(C*) ifjek.k = 4L atm; ra=k ij dk;Z fd;k x;k gSA
(D) dksbZ dk;Z ugha fd;k x;k gSA
13. Calculate the heat needed to raise the temperature of 20 g iron from 25ºC to 500ºC, if specific heat
capacity of iron is 0.45 JK–1g–1.
20 g vk;ju dk rki 25ºC ls 500ºC rd c<+kus ds fy, vko';d Å"ek dh x.kuk dhft;s] ;fn vk;ju dh fof'k"V
Å"ek /kkfjrk 0.45 JK–1g–1 gSA
(A*) 4275 J (B) 225 J (C) 15.66 J (D) 2250 J
14. The energy required to vapourise one mole of benzene at it's boiling point is 31.2 kJ. For how long a
100 W electric heater has to be operated in order to vaporize a 100 g sample of benzene at it's boiling
temperature?
csUthu ds ,d eksy dks blds DoFkaukd fcUnq ij ok"ihd`r djus ds fy, vko';d ÅtkZ 31.2 kJ gSA blds DoFkaukd
fcUnq ij csUthu ds 100 xzke çkn'kZ dkss ok"ihd`r djus ds fy, 100 W ds ,d fo|qr ghVj dks fdrus le; ds fy,
dk;Z djuk iM+sxk\
(A) 743 sec (B*) 400 sec (C) 3.12 × 104 sec (D) 371 sec
PAGE NO.-11
15. Predict which of the following reaction(s) have a positive entropy change ?
I. Ba2+ (aq) + SO42– (aq)  BaSO4 (s)
II. CaCO3 (s)  CaO (s) + CO2 (g)
III. 2SO3 (g)  2SO2 (g) + O2 (g)
(A) I and II (B) III (C*) II and III (D) II
crkb;s fd fuEu eas ls dkSulh vfHkfØ;k ,d /kukRed ,UVªkWih ifjorZu j[krh gS %
I. Ba2+ (aq) + SO42– (aq)  BaSO4 (s)
II. CaCO3 (s)  CaO (s) + CO2 (g)
III. 2SO3 (g)  2SO2 (g) + O2 (g)
(A) I rFkk II (B) III (C*) II rFkk III (D) II
Sol. ng is + ve (ng /kukRed gSA½
16. The positive value of S indicates that-
(A) The system becomes less disordered (B*) The system becomes more disordered
(C) The system is in equilibrium position (D) The system tends to reach at equilibrium position
S ds /kukRed eku ls izdV gksrk gS fd &
(A) fudk; de vO;ofLFkr gks tkrk gSA (B*) fudk; vf/kd vO;ofLFkr gks tkrk gSA
(C) fudk; lkE; dh fLFkfr esa gSA (D) fudk; lkE; dh fLFkfr ds igq¡pus dks izfs jr gksrk gSA
17. If there are two compartments in a container of equal volume. 1L each, if one compartment is
containing 4 gm of He and in other there is vaccum, then the S when the separator between the
compartments has been removed, will be
;fn ,d daVsuj es leku vk;ru 1L çR;sd ds nks daikVZesaV gSA ;fn ,d daikVZesaV esa 4 xzke He gS rFkk nwljs esa
fuokZr gS rks tc daikVZesaV ds e/; esa ls i`Fkd~dkjh dks gVk nsrs gS rks S gksxkA
(A) 0 (B) – R ln 2 (C*) R ln 2 (D) 2 R ln 4
18. One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state
when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as
(R = 2 calories/mol/K)
,d eksy vkn'kZ f}ijek.oh; xSl (Cv = 5 cal) dks] izkjfEHkd 25°C rFkk 1 L ls ml voLFkk esa :ikUrfjr fd;k x;k
tc rki 100°C o 10 L vk;ru gSA izØe dk ,UVªkWih ifjorZu fuEu izdkj O;Dr fd;k tk ldrk gSA
298 373
(A) 3 ln + 2 ln 10 (B*) 5 ln + 2 ln 10
373 298
373 1 373 1
(C) 7 ln + 2 ln (D) 5 ln + 2 ln
298 10 298 10
 Tf   Vf 
Sol. S = nCV ln   + nR ln  
 Ti   Vi 
PAGE NO.-12
P / I-CHEMISTRY


EST INFORM AT IO
DPP

Multiple choice objective ('–1' negative marking) Q.8 to Q.12 (4 marks, 2 min.) [20, 10]
Comprehension ('–1' negative marking) Q.13 to Q.15 (3 marks, 2 min.) [09, 06]
Integer type Questions ('–1' negative marking) Q.16 to Q.18 (4 marks 3 min.) [12, 09]
Match the Following (no negative marking) Q.19 to Q.20 (8 marks, 6 min.) [16, 12]
ANSWER KEY
1. (C) 2. (D) 3. (B) 4. (D) 5. (B)
6. (A) 7. (D) 8.* (BD) 9.* (ABD) 10.* (ABD)
11.* (ABC) 12.* (AC) 13. (D) 14. (B) 15. (A)
16. 8 17. 7 18. 1
19. (A)  p, s, t ; (B)  p, r, s, t ; (C)  q, r; (D)  p,r,s,t 20. (A) – r; (B)–p; (C)–(r),(D)–q.
1. Two moles of an ideal gas undergo the following process :
(a) a reversible isobaric expansion from (P atm, V L) to (P atm, 2V L).
(b) a reversible isochoric change of state from (P atm, 2V L) to (P/2 atm, 2V L).
(c) a reversible isothermal compression from (P/2 atm, 2V L) to (P atm, V L).
Sketch with labels each of the processes on the same P-V diagram.
,d vkn'kZ xSl ds nks eksy fuEu izØe ds vUrxZr vkrs gS %
(a) (P atm, V L) ls (P atm, 2V L) rd ,d mRØe.kh; lenkch; izlkj
(b) (P atm, 2V L) ls (P/2 atm, 2V L) rd ,d mRØe.kh; levk;ruh; ifjorZu
(c) (P/2 atm, 2V L) ls (P atm, V L) rd ,d mRØe.kh; lerkih; lEihM+u
leku P-V js[kkfp=k ij izR;sd izØe dk js[kkfp=k cukb;sA
(A) (B) (C) (D)
2. If a chemical reaction is non-spontaneous at high temperatures and spontaneous at low temperatures,

then:
(A) H > 0 and S > 0 (B) H > 0 andS < 0 (C) H < 0 and S > 0 (D*) H < 0 and S < 0
;fn ,d jklk;fud vfHkfØ;k] mPp rki ij vLor% gksrh gS rFkk fuEu rki ij Lor% gksrh gS] rc
(A) H > 0 rFkk S > 0 (B) H > 0 rFkk S < 0 (C) H < 0 rFkk S > 0 (D*) H < 0 rFkk S < 0
Sol. If H < 0 and S < 0, then reaction is non-spontaneous at high temperatures and spontaneous at low
temperatures.
Sol. ;fn H < 0 rFkk S < 0, rc] vfHkfØ;k mPp rki ij] vLor% gksrh gS rFkk fuEu rki ij Lor% gksrh gSA
PAGE NO.-13
3. A child bought a balloon which became very small in size the next day. Which is correct statement
about ballon?
(A) It is isolated system (B*) It is an open system.
(C) It is a closed system (D) It exchanges only energy with the surrounding.
,d ckyd ,d xqCckjk yk;k tks fd vxys fnu cgqr NksVk gks x;kA xqCckjs ds laca/k esa dkSulk dFku lgh gS\
(A) ;g ,d foyfxr ra=k gSA (B*) ;g [kqyh ra=k (open system) gSA
(C) ;g cUn ra=k gSA (D) ;g okrkoj.k ls dsoy ÅtkZ dk fofu;e djrk gSA
Sol. Due to leakage of gas i.e. mass transfer from system to surrounding.
xSl ds /kheh xfr ls folj.k ds dkj.k vFkkZr~ ra=k ls okrkoj.k esa nzO;eku LFkkukUrj.k gksrk gSA
4. Some statements are given for the following equilibrium.
NH4HS(s) NH3(g) + H2S(g) ; H = +ve
S1 : On increase in temperature, equilibrium pressure of ammonia increases.
S2 : On increase in volume of container at constant temperature, equilibrium pressure of ammonia
increases.
S3 : On increase in mass of NH4HS(s) in the container at constant temperature, equilibrium pressure of
ammonia increases.
(A) T T T (B) F F F (C) T T F (D*) T F F
fuEufyf[kr lkE; ds fy, dqN dFku fn;s x;s gaS&
NH4HS(s) NH3(g) + H2S(g) ; H = +ve
S1 : rki esa o`f} djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
S2 : fu;r rki ij] ik=k ds vk;ru esa o`f) djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
S3 : fu;r rki ij] ik=k esa] NH4HS(s) ds nzO;eku esa o`f) djus ij] veksfu;k ds lkE; nkc esa o`f) gksrh gSA
(A) T T T (B) F F F (C) T T F (D*) T F F
5. 7.5 KJ heat is added to a closed system and its internal energy decreases by 12 KJ. So, ____ of work
is done ____ the system. For a new process, if the work is zero, then ____ of heat is ____ for the
same changes in state of system.
(A) 4.5 KJ, on, 12 KJ, released (B*) 19.5 KJ, by, 12 KJ, released
(C) 4.5 KJ, by, 12 KJ, absorbed (D) 19.5 KJ, on, 12 KJ, released
,d can fudk; esa Å"ek dh 7.5 KJ ek=kk nh tkrh gS rFkk bldh vkUrfjd ÅtkZ esa 12 KJ ls deh vkrh gSA vr%
voLFkk ifjorZu esa fudk; ____ , ____ dk dk;Z gksrk gSA ,d vU; leku voLFkk ifjorZu ds fy,] çØe esa ____
dh ÅtkZ ____ gksrh gS] ;fn bl çØe ds fy, dk;Z 'kwU; gSA
(A) ij] 4.5 KJ, 12 KJ, mRlftZr (B*) }kjk] 19.5 KJ, 12 KJ, mRlftZr
(C) }kjk] 4.5 KJ, 12 KJ, vo'kksf"kr (D) ij] 19.5 KJ, 12 KJ, mRlftZr
Sol. Q = 7.5 KJ
U = – 12 KJ
U = Q + W
W = –12 – 7.5 = –19.5 KJ. Ans.
Now vc W = 0,
 U = Q  Q = U = – 12 KJ Ans
6. For a reaction to occur spontaneously-
(A*) (H – TS) must be negative (B) (H + TS) must be negative
(C) H must be negative (D) S must be negative
fdlh vfHkfØ;k ds Lor% pkfyr gksus ds fy;s vko';d gS]
(A*) (H – TS) _.kkRed gksuk pkfg, (B) (H + TS) _.kkRed gksuk pkfg,
(C) H _.kkRed gksuk pkfg, (D) S _.kkRed gksuk pkfg,
7. For the reaction, C3H8(g) + 5O2(g)  3CO2(g) + 4H2O()
at constant temperature, H – E is :
vfHkfØ;k C3H8(g) + 5O2(g)  3CO2(g) + 4H2O() ds fy, fLFkj rki ij] H – E gSa &
(A) + 3RT (B) – RT (C) + RT (D*) – 3RT
PAGE NO.-14
8.* A sample of ideal gas is compressed from an initial volume of 2v0 to v0 using three different processes
(from same initial state).
First : Reversible isothermal process
Second : Reversible adiabatic process
Third : Irreversible adiabatic process by a constant external pressure
Then :
(A) Work done in first process will be greater than in second process.
(B*) Final pressure of gas will be minimum in first process.
(C) Enthalpy change of sample will be highest in isothermal process.
(D*) Final temperature of gas will be highest in third process.
rhu fofHkUu izØeksa dks iz;qDr dj izkjafHkd vk;ru 2v0 ls v0 rd ,d vkn'kZ xSl ds uewus dks laihfMr fd;k tkrk
gSA (leku izkjfEHkd voLFkk ls)
izFke : mRØe.kh; lerkih; izØe
f}rh; : mRØe.kh; :)ks"eh; izØe
r`rh; : ,d fu;r ckâ; nkc }kjk vuqRØe.kh; :)ks"e izØe
rc %
(A) izFke izØe esa fd;k x;k dk;Z] f}rh; izØe ls mPp gksxkA
(B*) izFke izØe esa xSl dk vfUre nkc fuEure gksxkA
(C) lerkih; izØe esa uewus dk ,UFkSYih ifjorZu mPpre gksxkA
(D*) r`rh; izØe esa xSl dk vfUre rkieku mPpre gksxkA
Sol. (A) Work done in first process will be lesser than in second process
(since W isothermal (lesser area under PV graph) < W reversible adiabatic (greater area under PV graph)).
(B) Tf(isothermal) < Tf(reversible adiabatic) < Tf(irreversible adiabatic). So, for same final volume vo, Pf(isothermal) < Pf(reversible
adiabatic) < Pf(irreversible adiabatic).
(C) Enthalpy change of sample will be zero in isothermal process, while it will be greater than zero in
reversible adiabatic as well as irreversible adiabatic process (since temperature increases in both).
gy. (A) izFke izØe esa fd;k x;k dk;Z] f}rh; izØe ls fuEu gksxkA
(pw¡fd W lerkih; (PV vkjs[k ds vUrxZr U;wu {ks=kQy) < W mRØe.kh; :)ks"eh; (PV vkjs[k ds vUrxZr mPp {ks=kQy)).
(B) Tf(lerkih;) < Tf(mRØe.kh; :)ks"eh;) < Tf(vuqRØe.kh; :)ks"eh;). vr%, leku vfUre vk;ru vo ds fy;s, Pf(lerkih;) < Pf(mRØe.kh;
:)ks"eh;) < Pf(vuqRØe.kh; :)ks"eh;).
(C) uewus dk ,UFkSYih ifjorZu lerkih; izØe esa 'kwU; gksxk] tcfd ;g mRØe.kh; :)ks"eh; izØe rFkk lkFk gh
vuqRØe.kh; :)ks"eh; izØe esa 'kwU; ls vf/kd gksxk (pw¡fd nksuksa esa rkieku c<+ jgk gS)A
9.* Which of the following occurs with increase in entropy.
(A*) Disolution of salt (B*) Egg boiling
(C) Adsorption of gas on solid surface (D*) Diffusion of gas
fuEufyf[kr izØeks esa ls dkSulk ,UVªksih esa o`f) ds lkFk lEiUu gksrk gSA
(A*) yo.k dk foys; gksuk (B*) v.Ms dk mcyuk
(C) Bksl lrg ij xSl dk vf/k'kks"k.k (D*) xSl dk folj.k
10.* Which statement regarding entropy is/are incorrect ?
(A*) A completely ordered deck of cards has more entropy than a shuffled deck in which cards are
arranged randomly.
(B*) A perfect ordered crystal of solid nitrous oxide has more entropy than a disordered crystal in which
the molecules are oriented randomly.
(C) 1 mole N2 gas at STP has more entropy than 1 mole N2 gas at 273 K in a volume of 11.2 litre.
(D*) 1 mole N2 gas at STP has more entropy than 1 mole N2 gas at 273 K and 0.25 atm.
,UVªksih ds fo"k; esa fuEu esa ls dkSulk dFku vlR; gS \
(A*) iw.kZr% O;ofLFkr rk'k ds iÙkksa dh xM~Mh dh ,UVªksih] vfu;fer :i ls O;ofLFkr rk'k ds iÙkkas dh xM~Mh dh
rqyuk esa vfèkd gksrh gSA
(B*) iw.kZ :i ls O;ofLFkr Bksl ukbVªl vkWDlkbM fØLVy dh ,UVªksih] fØLVy esa vfu;fer :i ls O;ofLFkr v.kqvksa
ds fØLVy dh vis{kk vf/kd gksrh gSA
(C) STP ij 1 eksy N2 xSl dh ,UVªksih] 11.2 yhVj vk;ru ,oa 273 K rki ij mifLFkr 1 eksy N2 xSl dh rqyuk
esa vfèkd gksrh gSA
PAGE NO.-15
(D*) STP ij 1 eksy N2 xSl dh ,UVªksih] 273 K rFkk 0.25 atm ij mifLFkr 1 eksy N2 xSl dh vis{kk vf/kd gksrh gSA
Sol. For same amount of gas at constant temperature, lesser is the volume, lower will be the entropy.
fu;r rki ij xSl leku ek=kk ds fy, vk;ru de gksus ij ,sUVªkWih Hkh de gksxhA
11.* For the process H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), the correct set of thermodynamic
parameters is:
izØe H2O() (1 bar, 373 K) H2O(g) (1 bar, 373 K), ds fy;s Å"ekxfrdh iSjkehVj dk lgh leqPp; gS %
(A*) G = 0 (B*)S > 0 (C*) H > 0 (D) G = –ve
Sol. H2O(,1bar, 373K)  H2O(g, 1bar, 373 K)
S > 0
H > 0
G = 0
12.* At 300 K, the reaction which have the following values of thermodynamic parameter, occur
spontaneously.
300 K ij] ,d vfHkfØ;k] Å"ekxfrdh ekiØeksa ds fuEu eku j[krh gS] rc vfHkfØ;k Lor% gksxh ;fn vfHkfØ;k fuEu
esa ls dkSuls eku j[krh gS %
(A*)Gº = – 400 kJ mol–1 (B)Hº = 200 kJ mol–1, Sº = – 4 JK–1 mol–1
(C*)Hº = –200 kJ mol , Sº = 4 JK mol
–1 –1 –1 (D)Hº = 200 kJ mol–1, Sº = –40 JK–1 mol–1
Sol. Gº = Hº – TSº; In case of options (A) & (C), Gº is negative.
gy- Gº = Hº – TSº; fodYi (A) rFkk (C) dh ifjfLFkfr esa] Gº _.kkRed gSA
Comprehension # (13 to 15)
One mole of Helium gas undergoes a reversible cyclic process ABCDA as shown in the figure.
Assuming gas to be ideal, answer the following questions :
vuqPNsn # (13 to 15)

js[kkfp=k esa n'kkZ;s vuqlkj ghfy;e dk ,d eksy] ,d mRØe.kh; pØh; izØe ABCDA esa ç;qDr gksrk gaSA xSl dks
vkn'kZ ekurs gq, fuEu ç'uksa ds mÙkj nhft, %
13. What is the value of H for the overall cyclic process :

mijksDr lEiw.kZ pfØ; çØe ds fy, H dk eku D;k gksxk %
(A) – 100 Rn2 (B) +100Rn2 (C) +200Rn2 (D*) Zero
Sol. Since, H is a state function, and the final state attained by the gas is same as its initial state, so value
of H = 0.
gy- pw¡fd H ,d voLFkk Qyu gS rFkk xSl dh vfUre voLFkk] bldh çkjfEHkd voLFkk ds leku gS] blfy, H dk eku
0 gksxkA
14. What is the value of 'q' for the overall cyclic process :
lEiw.kZ pfØ; çØe ds fy, 'q' dk eku D;k gksxk %
(A) – 100 Rn2 (B*) +100Rn2 (C) +200Rn2 (D) –200Rn2
Sol. q = qAB + qBC + qCD + qDA
5R 5R
= – 1R × 300n2 + 1 × × (400 – 300) + 1R × 400n2 + 1 × × (300 – 400)
2 2
( qAB = – W AB = – 1R × 300n2 since process is reversible isothermal for which U = 0).
PAGE NO.-16
5R
( qBC = HBC = 1 × × (400 – 300) since process is reversible isobaric).
2
( qCD = – W CD = 1R × 300n2 since process is reversible isothermal for which U = 0).
5R
( qDA = HAB = 1 × × (300 – 400) since process is reversible isobaric).
2
So, q = 100 Rn2.
gy- q = qAB + qBC + qCD + qDA
5R 5R
= – 1R × 300n2 + 1 × × (400 – 300) + 1R × 400n2 + 1 × × (300 – 400)
2 2
( qAB = – W AB = – 1R × 300n2 pw¡fd çØe mRØe.kh; lerkih; gS] ftlds fy, U = 0).
5R
( qBC = HBC = 1 × × (400 – 300) pw¡fd çØe mRØe.kh; lenkch; gS )
2
( qCD = – W CD = 1R × 300n2 pw¡fd çØe mRØe.kh; lerkih; gS] ftlds fy, U = 0)
5R
( qDA = HAB = 1 × × (300 – 400) pw¡fd çØe mRØe.kh; lenkch; gS )
2
vr%, q = 100 Rn2.
15. What is the net work involved in the process A to C :
A ls C izØe esa lEcfU/kr dqy dk;Z D;k gS %
(A*) – 100 R(1–n8) (B) 300Rn2 (C) – 100 R(1+n8) (D) 200 J
16. An orbital has the difference in angular and radial nodes as 2 and radial nodes equal to 1. Find the sum
of principal quantum number and azimuthal quantum number.
,d d{kd ds fy, dks.kh; rFkk f=kT;h; uksM+ ds e/; vUrj nks gS rFkk f=kT;h; uksM+ dh la[;k ,d gS rc eq[;
DokaVe la[;k rFkk f}xa'kh DokaVe la[;k ds ;ksx dk eku Kkr dhft,A
Ans. 8
17. If the change in entropy of the system when 2 moles of an ideal diatomic gas ( = 1.4) is heated from
400 K to 800 K under constant pressure conditions is xR ln 2, find the value of x.
tc ,d f}ijek.ohd vkn'kZ xSl ( = 1.4) ds 2 eksy dks fu;r nkc ifjfLFkfr esa 400 K ls 800 K rd xeZ fd;k
tkrk gSA rc ;fn ra=k dh ,UVªksih esa ifjorZu xR ln2 gS rc X dk eku Kkr dhft;s \
Ans. 7
V1 V
Sol. = 2 ( P = constant) ( P = fu;r)
T1 T2
T2 V
 = 2 =2
T1 V1
T  V 
 S = nCV ln  2  + nR ln  2  = 5R ln 2 + 2R ln 2 = 7 R ln 2 x = 7.
 T1   V1 
18. For a perfectly crystalline solid, (CP)m = aT3, where a is a constant. If (CP)m at 10K is 0.375 J/K-mol,
then find the value of molar entropy at 20K (in J/K-mol).
,d Li"V% fØLVyh; Bksl ds fy, (CP)m = aT3 gS tgk¡ a ] ,d fu;rkad gS ;fn 10K ij] (CP)m dk eku 0.375 J/K-
mol gS rc] 20K ij eksyj ,sUVªksih dk eku (J/K-mol esa) Kkr dhft;s \
Ans. 1
3
Sol. (Cp)m = aT3  0.375 = a (10)3  a = × 10–3
8
20 20 20
(CP )m dT aT3 8000a 8000 3
  
2
Sm = = aT dT = = × × 10–3 = 1J/K–mol3
0
T 0
3 3 3 8
0
PAGE NO.-17
19. Match the processes given in column-I performed on an ideal gas sample with changes in column-II :
Column I Column II
(A) Isothermal expansion against constant external pressure (p) Suniv > 0
(B) Free expansion against vacuum under isothermal conditions. (q) Ssys = 0
(C) Reversible adiabatic compression (r) Ssurr = 0
(D) Free expansion against vacuum under adiabatic conditions. (s) Ssys > 0
(t) Gsys < 0
LrEHk I esa fn;s x;s ,d vkn'kZ xSl ds izkn'kZ ij fd;s x;s izØeksa dks] LrEHk II esa fn;s x;s ifjorZuksa ls lqesfyr
dhft,A
LrEHk I LrEHk II
(A) fu;r ckg~; nkc ds fo:) lerkih; izlkj (p) SczEgk.M > 0
(B) lerkih; ifjfLFkfr;ksa esa fuokZr ds fo:) eqDr izlkj (q) Sfudk; = 0
(C) mRØe.kh; :)ks"eh; lEihMu (r) Sifjos'k = 0
(D) :)ks"eh; ifjfLFkfr;ksa esa] fuokZr ds fo:) eqDr izlkj (s) Sfudk; > 0
(t) Gfudk; < 0
Ans. (A)  p, s, t (B)  p, r, s, t (C)  q,r (D)  p,r,s,t
20.
Column I
Column II
(Thermodynamic properties of
(Condition for spontaneity of chemical reaction)
chemical reaction)
(A) H < O , S < O (p) Chemical reaction is spontaneous at all temperatures.
Chemical reaction is spontaneous at high temperature
(B) H < O, S > O (q)
and non spontaneous at low temperatures.
Chemical reaction is non spontaneous at high
(C) H > O, S < O (r)
temperatures and spontaneous at low temperatures.
Chemical reaction is non spontaneous at all
(D) H > O, S > O (s)
temperatures.
LrEHk I
LrEHk II
(jklk;fud vfHkfØ;k ds
(jklk;fud vfHkfØ;k dh Lor% çofrZrk dh 'krZ)
Å"ekxfrdh; y{k.k)
(A) H < O , S < O (p) jklk;fud vfHkfØ;k leLr rkiksa ij Lor% çofrZZr gSaA
jklk;fud vfHkfØ;k mPp rki ij Lor% çofrZr gS rFkk fuEu rki
(B) H < O, S > O (q)
ij vLor% çofrZr gSaA
jklk;fud vfHkfØ;k mPp rki ij vLor% çofrZr gS rFkk fuEu
(C) H > O, S < O (r)
rki ij Lor% çofrZr gSaA
(D) H > O, S > O (s) jklk;fud vfHkfØ;k leLr rkiksa ij vLor% çofrZr gSaA
Ans. (A) – r ; (B) – p ; (C) – (r) , (D) – q.
PAGE NO.-18
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
ANSWER KEY
1. (D) 2. (A) 3. (A) 4. (B) 5. (D)
6. (B) 7. (C) 8. (B) 9. (A) 10. (C)
11. (C) 12. (C) 13. (D) 14. (D) 15. (B)
16. (A) 17. (A) 18. (C) 19. (D) 20. (C)
1. Consider the following changes :
fuEu ifjorZuksa ij fopkj dhft, %
1
(i) H2(g) + aq.  H+(aq.) (ii) 2O(g)  O2(g)
2
(iii) NH4+(g) + Cl–(g)  NH4Cl(s) (iv) P4 (black) + 5O2(g)  P4O10(s)
Which of the above does not represent H°formation of the product :
mijksDr esa ls dkSulk] mRikn ds H°lEHkou dks iznf'kZr ugha djrk gS %
(A) II, III (B) I, IV (C) I, II, III (D*) II , III, IV
3
2. Given that S(s) + O2(g)  SO3(g) + 2x KCal
2
1
SO2(g) + O2(g)  SO3(g) + y KCal
2
What would be the enthalpy of formation of SO2 :
3
fn;k x;k gS fd S(s) + O2(g)  SO3(g) + 2x KCal
2
1
SO2(g) + O2(g) SO3(g) + y KCal
2
SO2 ds laHkou dh ,UFkSYih D;k gksxh %
(A*) – 2x + y (B) 2x – y (C) – x + y (D) x – y
3. For the two reactions given below :
H2(g) + ½O2(g)  H2O () + x1 kJ mol–1
H2(g) + ½O2(g) H2O (g) + x2 kJ mol–1
Compare the magnitude of x1 and x2 : (x1 and x2 are the heat released in above two processes)
uhps nh xbZ nks vfHkfØ;kvksa ds fy, %
H2(g) + ½O2(g) H2O () + x1 kJ mol–1
H2(g) + ½O2(g)  H2O (g) + x2 kJ mol–1
x1 rFkk x2 ds ifjek.k dh rqyuk dhft, % (x1 rFkk x2, mijksDr nksuksa izØeksa esa fu"dkflr Å"ek gSA)
(A*) x1 > x2 (B) x1 < x2
(C) x1 = x2 (D) cannot be compared rqyuk ugha dh tk ldrh
PAGE NO.-19
Sol. Some of the heat is used to vaporise the H2O ()
(H2O () dks ok"ihd`r djus ds fy, dqN ek=kk esa Å"ek iz;qDr gksrh gSA)
4. The combustion of 0.2 mole of liquid carbon disulphide CS2 at constant pressure to give CO2(g) and
SO2(g) releases 215 kJ of heat. What is Ho for CS2(l) in kJ mol–1 :
fu;r nkc ij nzo dkcZu MkbZlYQkbM CS2 ds 0.2 eksy ds ngu ij CO2(g) rFkk SO2(g) fu"dkflr gksrh gS rFkk
215 kJ Å"ek fu"dkflr gksrh gSA CS2(l) ds fy, Ho dk eku kJ mol–1 esa fuEu gksxk %
Hfº kJ mol–1
CO2(g) –393.5
SO2(g) –296.8
(A) 772.1 (B*) 87.9 (C) 384.7 (D) – 2062.1
Sol. CS2() + 3O2(g)  CO2 (g) + 2SO2(g) ; Hºrxn. = 5 × – 215 = – 1075 kJ
Hºrxn. = Hºf (CO2) + 2 × Hºf (SO2) – Hºf (CS2)
Hºf (CS2) = (– 393.5 – 2 × 296.8) – (–1075)
Hºf (CS2) = 87.9
5. Calculate the heat of combustion of carbon monoxide at 17ºC at constant volume from the given
enthalpy of reactions at 17ºC :
fu;r vk;ru ij 17ºC ij dkcZu eksuksvkWDlkbM ds ngu dh Å"ek dh x.kuk dhft,] ;fn 17ºC rki ij
fuEufyf[kr vfHkfØ;kvksa ds fy, vfHkfØ;k dh ,UFkSYih ds eku fn;s x;s gSa %
(i) C (s) + O2 (g)  CO2 (g) ;  H1 =  97000 Cal
(ii) CO2 (g) + C (s)  2CO (g) ;  H2 = 39000 Cal
(A) –136000 Cal (B) –135420 Cal (C) –68000 Cal (D*) –67710 Cal
6. In the combustion of 2.0 g of methane 25 kcal heat is liberated, heat of combustion of methane would
be-
(A) 100 kcal (B*) 200 kcal (C) 300 kcal (D) 400 kcal
2.0 xzke esFksu dks tykus ij 25 fdyks dSyksjh rki mRiUu gksrk gS] esFksu dh ngu Å"ek gksxh&
(A) 100 fdyks dSyksjh (B*) 200 fdyks dSyksjh (C) 300 fdyks dSyksjh (D) 400 fdyks dSyksjh
7. The value of heat of formation of SO2 and SO3 are –298.2 kJ and –98.2 kJ. The heat of reaction of the
following reaction will be :
1
SO2 + O2 SO3
2
SO2 rFkk SO3 dh laHkou Å"ek dk eku –298.2 kJ rFkk –98.2 kJ gSA rc fuEu fØ;k dh vfHkfØ;k Å"ek gksxh&
1
SO2 + O2 SO3
2
(A) –200 kJ (B) –356.2 kJ (C*) +200 kJ (D) –396.2 kJ
8. For the equations :
C(diamond) + 2H2(g) CH4(g) ;H1 and C(g) + 4H(g) CH4(g) ; H2
Select the correct option :
(A) H1 = H2 (B*) H1 > H2
(C) H1 < H2 (D) Nothing can be said with certainty
fuEu lehdj.kksa ds fy, %
C(ghjk) + 2H2(g) CH4(g) ;H1 rFkk C(g) + 4H(g) CH4(g) ; H2
lgh fodYi dk p;u dhft;s %
(A) H1 = H2 (B*) H1 > H2
(C) H1 < H2 (D) fuf'pr :i ls dqN dgk ugha tk ldrk gSA
9. Consider the following reactions :
fuEu vfHkfØ;kvksa dk voyksdu dhft, :
(i) H+(aq) + OH–(aq) = H2O()– x1 kJ mol–1
1
(ii) H2(g) + O2 (g) = H2O() – x2 kJ mol–1
2
(iii) CO2(g) + H2(g) = CO(g) + H2O() – x3 kJ mol–1
PAGE NO.-20
5
(iv) C2H2(g) + O2 (g) = 2CO2(g) + H2O() + x4 kJ mol–1
2
Enthalpy of formation of H2O () is :
H2O () ds fy, lEHkou ,UFkSYih fuEu gS %
(A*) + x2 kJ mol–1 (B) + x3 kJ mol–1 (C) – x4 kJ mol–1 (D) + x1 kJ mol–1
Sol. Enthalpy of formation : The amount of heat evolved or absorbed during the formation of 1 mole of a
compound for its constituent elements is known as heat of formation. So, the correct answer is :
lEHkou dh Å"ek : 1 eksy ;kSfxd ds fuekZ.k ds nkSjku blds vo;oh rRoksa ls mRlftZr ;k vo'kksf"kr Å"ek dh ek=kk
lEHkou dh Å"ek ls tkuh tkrh gSA blfy, lgh mÙkj fuEu gS :
1
H2(g) + O2 (g)  H2O() ,  H = + x2 kJ mol–1
2
10. The enthalpy of neutralization of a strong base and strong acid is 57.0 kJ eq –1. The heat evolved when
0.5 mole of HNO3 are added to 1 L of 0.2 M NaOH solution is :
izcy {kkj o izcy vEy ds mnklhuhdj.k dh ,UFkSYih 57.0 kJ eq–1 gSA HNO3 ds 0.5 eksy dks 1 L, 0.2M NaOH
foy;u esa feykus ij] mRlftZr Å"ek fuEu gS %
(A)  20 kJ (B) 28.5 kJ (C*) 11.4 kJ (D) 34.9 kJ
11. The heat evolved in neutralizing a solution containing 1 mole of HCN with a strong alkali is 3 KCal. The
enthalpy of dissociation of HCN is :
,d izcy {kkj ds lkFk HCN ds ,d eksy ;qDr foy;u ds mnklhuhdj.k esa mRlftZr Å"ek 3 KCal gSA HCN ds
fo;kstu dh ,UFkSYih dk eku fuEu gksxk %
(A) 54.1 KCal/mol (B) 60.1 KCal/mol (C*) 10.7 KCal/mol (D) 16.7 KCal/mol
Sol. enthalpy of dissociation = (13.7 – 3) KCal = 10.7 KCal
12. The rates of diffusion of two gases A and B are in the ratio 1 : 4. Then the ratio of molecular masses :
A rFkk B nks xSlksa ds folj.k dh nj dk vuqikr 1 : 4 gSA rks buds vkf.od Hkkjks dk vuqikr %
(A) 1/12 (B) 5/24 (C*) 16 (D) 1/6
r1 1 w1 2
Sol.  , 
r2 4 w2 3
r1 M2 M2
  = 16 : 1
r2 M1 M1
13. Calculate the molality of one litre solution of 49% H2SO4 (weight/volume). The density of the solution is
1.49 g/ml.
49% H2SO4 (Hkkj/vk;ru) ds ,d yhVj foy;u dh eksyyrk dh x.kuk dhft,A foy;u dk ?kuRo 1.49 g/ml gSA
(A) 2.5 (B)10 (C) 2 (D*) 5
Sol. 49%(w/v) H2SO4 means 49g of H2SO4 is present in 100 ml of solution.
So mass of solution is = v × d
= 100 × 1.49 = 149 gram
Now mass of solvent = 149 – 49 = 100 g
49
/
So molality = 100 98 = 5m
/1000
Sol. 49%(w/v) H2SO4 dk vFkZ gS fd 49g H2SO4, 100 ml foy;u esa mifLFkr gSA
vr% foy;u dk Hkkj gS =v×d
= 100 × 1.49 = 149 xzke
vc foyk;d dk Hkkj = 149 – 49 = 100 g
49
/ 98
vr% eksyyrk = 100
= 5m
/1000
PAGE NO.-21
14. Which of the following option is correct :
(A) When a liquid and its vapour are at equilibrium and the pressure is suddenly increased, cooling
occurs.
(B) N2(g) + O2(g) 2NO(g)–Heat; the equilibrium shifts in backward direction on increasing the
temperature.
(C) Vapour pressure of particular liquid at a particular temperature depends upon surface area of liquid
exposed.
(D*) None of these
fuEu esa ls lgh fodYi dkSulk gS %
(A) tc nzo o bldh ok"i lkE;koLFkk esa gS rc] vpkud nkc c<+kus ij 'khryu gks tkrk gSA
(B) N2(g) + O2(g) 2NO(g)–Å"ek; rkieku c<+kus ij vfHkfØ;k] i'p fn'kk esa LFkkukUrfjr gksrh gSA
(C) fuf'pr rkieku ij fuf'pr nzo dk ok"i nkc [kqys gq, nzo ds i`"Bh; {ks=kQy ij fuHkZj djrk gSA
(D*) buesas ls dksbZ ugha
Sol. (A) Due to condensation of vapour , heat is liberated.
(A) ok"i ds la?kuu ds dkj.k] Å"ek eqDr gksrh gSA
Sol. (B) Reaction goes in forward direction.
(B) vfHkfØ;k vxz fn'kk esa LFkkukUrfjr gksrh gSA
15. For the reaction PCl5(g) PCl3(g) + Cl2(g) ; H = +ve, taking place in a closed container, initially
starting with only PCl5, the value of observed vapour density at equilibrium ______ with decrease in
temperature.
(A) Decreases (B*) Increases
(C) Remains constant (D) First decreases, then increases
vfHkfØ;k PCl5(g) PCl3(g) + Cl2(g) ; H = +ve, dks ,d can ik=k esa djk;k tkrk gSA izkjEHk esa dsoy] PCl5
dks fy;k tkrk gSA rc rkieku esa deh ds lkFk lkE; ij izsf{kr ok"i ?kuRo ds eku esa _________ gksrh gSA
(A) deh (B*) o`f)
(C) eku fu;r jgrk gS (D) igys deh rFkk fQj o`f)
Sol. As temperature is decreased, the equilibrium will shift in backward direction according to Le-Chatelier's
(Vd)Th
principle, leading to an decrease in value of  (degree of dissociation). Now, (V.D.)obs =
1 
so, as  decreases, (V.D.)obs increases.
Sol. rkieku esa deh ds lkFk] yh&'ksrsfy, fl)kUr ds vuqlkj] lkE; i'p fn'kk esa foLFkkfir gksrk gS] rFkk (fo;kstu dh
(Vd)lS)kfUrd
ek=kk) esa Hkh deh gksxh] vr% (VD)izsf{kr =
1 
vr%,  esa deh ds lkFk (VD)izsf{kr esa o`f) gksrh gSA
3
16. A monoatomic ideal gas (CV = R) is allowed to expand adiabatically and reversibly from initial
2
volume of 8 L at 300 K to a volume of V2 at 250 K. V2 is : (Given (4.8)1/2 = 2.2)
(A*) 10.56 L (B) 17.6 L
(C) 11.52 L (D) Expansion not possible since temperature has decreased
3
,d ,dy ijek.kfod xSl (CV = R) dks :)ks"e rFkk mRØe.kh; :i ls 300 K rki ij izkjfEHkd vk;ru 8 L ls]
2
250 K ij vfUre vk;ru V2 rd izlkfjr gksus fn;k tkrk gSA rc V2 fuEu gS % (fn;k x;k gS % (4.8)1/2 = 2.2)
(A*) 10.56 L (B) 17.6 L
(C) 11.52 L (D) izlkj laHko ugha gS] D;kssafd rkieku ?kV x;k gSaA
Sol. TV–1 = constant (fu;rkad)
5 2
=  –1=
3 3
 300 × (8)2/3 = 250 × (V2)2/3  (V2)2/3 = 4.8
 V2 = (4.8)  4.8 × 2.2 = 10.5 L
3/2
PAGE NO.-22
17. An ideal gas is expanded from volume V0 to 4V0 by following two ways : (from same initial state)
(a) st using reversible isothermal expansion from V0 to 2V0 , then using reversible adiabatic expansion
from 2V0 to 4V0 .
(b) st using reversible adiabatic expansion from V0 to 2V0, then from 2V0 to 4V0 using reversible
isothermal expansion.
Then which of the following options is correct :
(A*) Work done in (a) process > work done in (b) process
(B) Work done in (b) process > work done in (a) process
(C) Work done in (b) process = work done in (a) process
(D) Work done in both processes cannot be compared
,d xSl dks fuEu nks iFkkas ls vk;ru V0 ls 4V0 rd izlkfjr fd;k x;k gS % (leku izkjfEHkd voLFkk ls)
(a) st esa V0 ls 2V0 rd mRØe.kh; lerkih izlkj dk mi;ksx fd;k x;k rFkk fQj 2V0 ls 4V0 rd mRØe.kh;
:)ks"e izlkj dk mi;ksx fd;k x;kA
(b) st esa V0 ls 2V0 rd mRØe.kh; :)ks"e izlkj dk mi;ksx fd;k x;k rFkk fQj 2V0 ls 4V0 ls mRØe.kh; lerkih
izlkj dk mi;ksx fd;k x;kA
rc fuEu esa ls dkSulk dFku lgh gS %
(A*) izØe (a) esa fd;k x;k dk;Z > izØe (b) esa fd;k x;k dk;Z
(B) izØe (b) esa fd;k x;k dk;Z > izØe (a) esa fd;k x;k dk;Z
(C) izØe (b) esa fd;k x;k dk;Z = izØe (a) esa fd;k x;k dk;Z
(D) nksuksa izdzeksa esa fd;s x;s dk;Z dh rqyuk ugha dh tk ldrh
18. The average energy required to break a P – P bond in P4 (s) into gaseous atoms is 53.2 kcal mol–1. The
bond dissociation energy of H2(g) is 104.2 kcal mol–1; Hf0 of PH3(g) from P4(s) is 5.5 kcal mol–1. The P-
H bond energy in kcal mol–1 is [Neglect presence of Van der Waals forces in P4(s)]
P4 (s) v.kq esa P–P ca/k dks rksM+us ds fy,] xSlh; ijek.kqvksa esa fo;kstu ds fy, vko';d] vkSlr ÅtkZ 53.2 kcal
mol–1 gSA H2(g) dh ca/k fo;kstu ÅtkZ 104.2 kcal mol–1 gSA P4(s) ls PH3(g) dh Hf0 5.5 kcal mol–1 gSA P-H ca/k
ÅtkZ kcal mol–1 esa gSA [P4(s) esa ok.Mjoky cyksa dh mifLFkfr dks ux.; eku dj]
(A) 85.2 (B) 57.6 (C*) 76.9 (D) 63.3
Sol. P4(s)  4P(g) H = 53.2 × 6
H2(g) 2H(g) H = 104.2
1 3
P4(s) + H2(g)  PH3(g) H = 5.5
4 2
1 3
× 6 × 53.2 + × 104.2 – 3P–H = 5.5  P–H = 76.866 i.e. 76.9 kcal mol–1
4 2
19. Heat of atomisation of NH3 and N2H4 are x kcal mol–1 and y kcal mol–1 respectively. Calculate average
bond energy of N—N bond.
NH3 o N2H4 ds ijek.kohdj.k dh m"ek (heat of atomisation) Øe'k% x kcal mol–1 o y kcal mol–1 gSaA N—N
cU/k dh vkSlr cU/k ÅtkZ ifjdfyr dhft,A
4y  3x 2y  3x 4y  3x 3y  4x
(A) kcal mol–1 (B) kcal mol–1 (C) kcal mol–1 (D*) kcal mol–1
3 3 4 3
20. Consider the following changes :
fuEu ifjorZuksa dk voyksdu dhft;s %
Na+(g)  Na+(aq) H1 .... (1)
Na(s)  Na+(g) H2 .... (2)
Cl–(g)  Cl–(aq) H3 .... (3)
Cl2(g)  2Cl–(g) H4 .... (4)
Na+(g) + Cl–(g) NaCl(s)  H5 .... (5)
NaCl(s)  Na+(aq) + Cl–(aq) H6 .... (6)
Hydration enthalpy of NaCl can be defined by sum of the following :
NaCl dh ty;kstu ,UFkSYih dks fuEu esa ls fdlds ;ksx }kjk ifjHkkf"kr fd;k tk ldrk gS %
(A) H1 + H2 +H3 +H4/2 (B) dsoy H6 only
(C*) H1 + H3 (D) H2 +H4/2 +H5 + H6
PAGE NO.-23
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
Subjective Questions ('-1' negative marking) Q.16 (3 marks, 3 min.) [03, 03]
Match the Following (no negative marking) Q.17 (8 marks, 6 min.) [08, 06]
ChemINFO : 3 Questions ('–1' negative marking) Q.18 to Q.20 (4 marks, 2 min.) [12, 08]
ANSWER KEY
1. (B) 2. (D) 3. (D) 4. (A) 5. (C)
6. (B) 7. (C) 8. (C) 9. (C) 10. (D)
11. (D) 12. (C) 13. (C) 14. (D) 15. (B)
16. (i) 2NaOH + 2NO2  NaNO2 + NaNO3 + H2O (ii) 6NaOH + 3Br2  5NaBr + NaBrO3 + 3H2O.
(iii) 6NaOH + 4S  2Na2S + Na2S2O3 + 3H2O (iv) 4NaOH + 2F2  4NaF + O2 + 2H2O.
(v) PbO + 2NaOH  Na2PbO2 + H2O
17. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r) 18. (D) 19. (B) 20. (A)
1. Which of the following gives propyne on hydrolysis ?
fuEu esa ls dkSu] ty vi?kVu }kjk izksikbu cukrk gS \
(A) Al4C3 (B*) Mg2C3 (C) B4C (D) La4C3
2. Which of the following compounds on thermal decomposition yields a basic as well as an acidic oxide ?
fuEu esa ls fdl ;kSfxd ds rkih; vi?kV~u ij ,d {kkjh; vkWDlkbM ds lkFk&lkFk ,d vEyh; vkWDlkbM Hkh izkIr
gksrk gS \
(A) KClO3 (B) NaNO3 (C) K2CO3 (D*) MgCO3

Hint : MgCO3  MgO + CO2
(Basic) (Acidic)
3. Which of the following statements is incorrrect ?
(A) The superoxide ion (i.e. O2–) is stable only in presence of larger cations such as K+, Rb+, Cs+.
(B) Alkali metals are normally kept in kerosene oil.
(C) All the alkali metal hydrides are ionic solids with high melting points.
(D*) The concentrated solution of alkali metals in liquid ammonia is paramagnetic in nature.
fuEu esa ls dkSulk dFku vlR; gS %
(A) lqijvkWDlkbM vk;u (O2–), cM+s /kuk;uksa tSls K+, Rb+, Cs+ ds lkFk gh LFkk;h gksrk gSA
(B) {kkjh; /kkrqvksa dks lkekU;r% dSjkslhu esa j[kk tkrk gSA
(C) lHkh {kkjh; /kkrqvksa ds gkbMªkbM] vk;fud Bksl gksrs gS rFkk mPp xyukad j[krs gSaA
(D*) {kkjh; /kkrqvksa dk nzo veksfu;k esa lkUnz foy;u] çd`fr esa vuqpqEcdh; gksrk gSA
Sol. (A) Bigger anion is stabilised by bigger cation through lattice energy effect.
(B) Because of their high reactivity towards air and water.
(C) True Statement
(D) In concentrated solution, unpaired electrons with opposite spins paired up – forming the solution
diamagnetic.
PAGE NO.-24
Sol. (A) cM+s _.kk;u tkyd ÅtkZ izHkko ls cM+s /kuk;u }kjk LFkk;hd`r jgrk gSA
(B) D;ksafd budh ok;q o ty ds izfr mPpfØ;k'khyrk gksrh gSA
(C) lR; dFku
(D) lkfUnzr foy;u esa fopfjr pØ.k ;qDr v;qfXer bysDVªkWu ;qfXer gksdj fopyu dks izfrpqEcdh; cukrs gSA
4. The pair of compounds which cannot exist together in solution is :
(A*) NaHCO3 and NaOH (B) Na2CO3 and NaHCO3
(C) Na2CO3 and NaOH (D) NaHCO3 and NaCI
;kSfxdks dk dkSulk ;qXe] foy;u esa ,d lkFk ugha jg ldrk gS %
(A*) NaHCO3 o NaOH (B) Na2CO3 o NaHCO3
(C) Na2CO3 o NaOH (D) NaHCO3 o NaCI
Sol. Since NaHCO3 is an acid salt of H2CO3. it reacts with NaOH to form Na2CO3 and H2O.
NaHCO3 + NaOH  Na2CO3 + H2O.
gy- pwafd NaHCO3, H2CO3 dk ,d vEy yo.k gSA ;g NaOH ds lkFk vfHkfØ;k dj Na2CO3 o H2O cukrk gSA
NaHCO3+ NaOH  Na2CO3 + H2O.
5. Which of the following statements is true for all the alkali metals ?
(A) Their nitrates decompose on heating to give the corresponding nitrites and oxygen.
(B) Their chlorides are deliquescent and crystallise as hydrates.
(C*) They react with water to form hydroxide and hydrogen.
(D) They readily react with halogens to form ionic halides, M+X–.
lHkh {kkjh; /kkrqvksa ds fy, fuEu esa ls dkSulk dFku lR; gS \
(A) buds ukbVªsV] xeZ djus ij fo?kfVr gksdj lacaf/kr ukbVªkbV rFkk vkWDlhtu nsrs gSA
(B) buds DyksjkbM] izLosn~d ¼deliquescent½ gksrs gaS rFkk ty;ksftr :i esa fØLVyhd`r gksrs gSaA
(C*) ;s ty ds lkFk fØ;k djds gkbMªksDlkbM rFkk gkbMªkstu cukrs gaSA
(D) ;s gSykstu ds lkFk rqjUr fØ;k djds vk;fud gSykbM, M+X– cukrs gaSA
Sol. (A) 4 LiNO3  2Li2O + 4NO2 + O2
2NaNO3  2NaNO2 + O2 (similar decomposition with the nitrates of K, Rb and Cs)
(B) Only LiCl is deliquescent and crystallises as a hydrate LiCl.2H2O
(C) 2M + 2H2O  2M+ + 2OH– + H2 (M = an alkali metal)
(D) Halides of Li are covalent in nature.
(A) 4 LiNO3  2Li2O + 4NO2 + O2
2NaNO3  2NaNO2 + O2 (ukbVªkbV K, Rb rFkk Cs ds lkFk lkeu fo?kVu)
(B) dosy LiCl izLos|; gS rFkk gkbVªsV LiCl.2H2O ds :i esa fØLVyhd`r jgrk gSA
(C) 2M + 2H2O  2M+ + 2OH– + H2 (M = ,d {kkj /kkrq)
(D) Li ds gSykbM lgla;ksth izd`fr ds gksrs gSA
6. Which of the following reactions of potassium superoxide supply oxygen gas in the breathing
equipments used in space and submarines ?
(1) reaction of superoxide with nitrogen in the exhaled air
(2) reaction of superoxide with moisture in the exhaled air
(3) reaction of superoxide with carbon dioxide in the exhaled air
(A) (1), (2) and (3) (B*) (2) and (3) only (C) (2) only (D) (1) and (2) only
varfj{k rFkk iaMqfCc;ksa esa fuEu esa ls iksVsf'k;e lqij vkWDlkbM dh dkSulh vfHkfØ;k] 'olu ;a=k esa vkWDlhtu xSl ds
çokg ds fy, iz;qDr dh tkrh gS \
(1) fu"dkflr ok;q esa ukbVªkstu dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(2) fu"dkflr ok;q esa ueh dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(3) fu"dkflr ok;q esa dkcZuMkbZvkWDlkbM dh lqij vkWDlkbM ds lkFk vfHkfØ;kA
(A) (1), (2) rFkk (3) (B*) dsoy (2) rFkk (3) (C) dsoy (2) (D) dsoy (1) rFkk (2)
Sol. (2) KO2 + 2H2O  KOH + H2O2 + 1/2O2
(3) 4KO2 + 2CO2  2K2CO3 + 3O2
PAGE NO.-25
7. Statement-1 : Lithium is the most powerful reducing agent and sodium is the least powerful reducing
agent amongst the alkali metals in aqueous solutions.
Statement-2 : Lithium has the highest hydration enthalpy and the sodium the least value.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C*) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
dFku-1 : tyh; foy;u esa] {kkjh; /kkrqvksa esa yhfFk;e lcls çcy vipk;d dkjd gS rFkk lksfM;e lcls nqcZy
vipk;d gSA
dFku-2 : yhfFk;e mPpre foyk;du ,UFkSYih j[krk gS rFkk lksfM;e] lcls deA
(A) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k gSA
(B) dFku&1 lR; gS] dFku&2 lR; gS; dFku&2, dFku&1 dk lgh Li"Vhdj.k ugha gSA
(C*) dFku&1 lR; gS] dFku&2 vlR; gSA
(D) dFku&1 vlR; gS] dFku&2 lR; gSA
Sol. (i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 which is least among the alkali metals.
(ii) Hydration enthalpy / KJ mol–1
Li = – 506 ; Na = – 406 ; Cs has the least Hhyd = – 276
Sol. (i) E Li+/Li = –3.04 ; Na+ / Na = – 2.71 tks {kkjh; /kkrqvksa esa lcls de gSA
(ii) foyk;du ÅtkZ / KJ mol–1
Li = – 506 ; Na = – 406 ; Cs , Hfoyk;du = – 276 dk eku de j[krk gSA
8. Which of the following statements is not true about the dilute solutions of alkali metals in liquid
ammonia?
(A) They are deep blue coloured solutions.
(B) They are highly conducting in nature.
(C*) They are diamagnetic in nature.
(D) Ammoniated cation and solvated electron are formed in the solution.
nzo veksfu;k esa {kkjh; /kkrqvksa ds ruq foy;u ds fy, fuEu esa ls dkSulk dFku lR; ugha gS \
(A) ;g xgjs uhys jax dk foy;u gSA
(B) ;g izd`fr esa vR;f/kd pkyd gksrk gSA
(C*) ;g izd`fr esa izfrpqEcdh; gksrk gSA
(D) foy;u esa veksfud`r /kuk;u rFkk foy;hd`r bysDVªkWu curk gSA
Sol. M + (x + y)NH3  [M(NH3)x]+ + [e(NH3)y]–
It is paramagnetic due to the presence of the unpaired electrons
v;qfXer bysDVªkWu dh mifLFkfr ds dkj.k ;g izfrpqEcdh; gksrk gSA
9. Which of the following has the highest solubility in water ?
fuEu esa ls fdldh] ty esa foys;rk lokZfèkd gksrh gS \
(A) LiOH (B) KOH (C*) CsOH (D) RbOH
10. Which is correct order of ionic mobility in aqueous medium –
(A) Li(aq )  Na(aq )  Rb(aq ) 
(B) Al (3aq 2 
)  Mg ( aq )  Na( aq )
(C) Li(aq )  Na(aq )  K (aq ) (D*) Both (A) & (B)

Tkyh; ek/;e es vk;fud xfr'khyrk dk lgh Øe gS %
(A) Li(aq )  Na(aq )  Rb(aq ) 
(B) Al (3aq 2 
)  Mg ( aq )  Na( aq )
(C) Li(aq )  Na(aq )  K (aq ) (D*) (A) o (B) nksuksa

Sol. Smaller the ion, higher the hydration, lower the mobility.
vk;u ftruk NksVk gksrk gS] mruk gh ty&vi?kVu mPp gksrk gS] xfr'khyrk mruh gh de gksrh gSA
11. Which of the following statement is incorrect about the alkali metals ?
(A) All alkali-metal salts impart a characteristic colour to the Bunsen flame.
(B) The correct order of increasing thermal stability of the carbonates of alkali metals is Li 2CO3 <
Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3 .
(C) Among the alkali metals, cesium is the most reactive.
(D*) All are incorrect.
PAGE NO.-26
{kkjh; /kkrqvksa ds fy, fuEu ess ls dkSulk dFku vlR; gS \
(A) lHkh {kkjh; /kkrqvksa ds yo.k] cqUlsu Tokyk dks ,d ykf{.kd jax iznku djrs gaSA
(B) {kkjh; /kkrqvksa ds dkcksZusV ds rkih; LFkkf;Ro dk lgh c<+rk gqvk Øe Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3
< Cs2CO3 gSA
(C) lHkh {kkjh; /kkrqvksa esa ls lhft+;e lokZfèkd fØ;k'khy gSA
(D*) lHkh xyr gSaA
12. HCl is added to following oxides. Which one would give H2O2?
HCl dks fuEu esa ls dkSuls vkWDlkbM esa feykus ij H2O2 izkIr gksrk gS ?
(A) MnO2 (B) PbO2 (C*) BaO2.8H2O (D) NO2
Sol. BaO2.8H2O + 2HCl  BaCl2 + H2O2 + 8H2O
13. S1 : Plaster of paris is a hemihydrate of calcium sulphate obtained by heating the gypsum above 393 K.
S2 : Sodium carbonate is used in water softening.
S3 : The order of mobilities of the alkali metal ions in aqueous solutions is Li+ > Na+ > K+ > Rb+ > Cs+.
S1 : ftIle dks 393 K ds Åij xeZ djus ij dSfYl;e lYQsV dk gsehgkbMªsM izkIr gksrk gS] mls IykLVj vkWQ isfjl
dgrs gaSA
S2 : lksfM;e dkcksZusV dk mi;ksx] ty dks e`nw cukus esa fd;k tkrk gSA
S3 : tyh; foy;u esa {kkjh; /kkrq vk;u dh xfr'khyrk dk Øe Li+ > Na+ > K+ > Rb+ > Cs+ gSA
(A) T T F (B) T T T (C*) F T F (D) F F F
Sol. S1 : (2 CaSO4.2H2O)  2 (CaSO4). H2O + 3H2O ; above 393 K dead burnt plaster is obtained.
393 K
S2 : Ca2+ + Na2CO3  CaCO3 + 2Na+

S3 : Li+ < Na+ < K+ < Kb+ < Cs+
Bigger hydrated ion moves slower in aqueous solution.
gy- S1 : (2 CaSO4.2H2O)   2 (CaSO4). H2O + 3H2O ; 393 K ds
393 K
Åij e`r tfyr IykLVj izkIr gksrk gSA
S2 : Ca2+ + Na2CO3  CaCO3 + 2Na+
S3 : Li+ < Na+ < K+ < Kb+ < Cs+
tyh; foy;u esa cM+k tyk;ksftr vk;u /khjs ls xfr djrk gSA
14. An inorganic compound (X) which produces brick red coloration as flame when (X) dissolves in water
produces alkaline solution and a combustible gas (Y). (X) and (Y) are respectively.
,d dkcZfud ;kSfxd (X) Tokyk esa bZV tSlk yky jax mRiUu djrk gSA tc (X) dks ty esa foys; fd;k tkrk gS rks
nks {kkjh; foy;u rFkk ,d ngu’khy xSl (Y) curh gSA (X) rFkk (Y) Øe'k% gSA
(A) CaO, O2 (B) Ca3N2, NH3 (C) CaCO3, CO2 (D*) CaH2, H2
Sol. CaH2 + H2O  Ca(OH)2 + H2
15. Select the INCORRECT order from the following according to the property mentioned along with :
(A) F– > Cl– > Br– > I– ; ionic mobility in water
(B*) CsCl > RbCl > KCl > NaCl > LiCl ; lattice energy.
(C) Li2CO3 < Na2CO3< K2CO3 < Rb2CO3 ; solubility in water.
(D) CsF > CsCl > CsBr > CsI ; melting point.
v|ksfyf[kr esa ls dkSulk Øe fn;s x;s xq.k ds vk/kkj ij xyr gS %
(A) F– > Cl– > Br– > I– ; ty esa vk;fud xfr'khyrk (B*) CsCl > RbCl > KCl > NaCl > LiCl; tkyd ÅtkZ
(C) Li2CO3 < Na2CO3< K2CO3 < Rb2CO3; ty esa foys;rk (D) CsF > CsCl > CsBr > CsI; xyukad fcUnq
1
Sol. (B) Correct order is LiCl > NaCl > KCl > RbCl > CsCl. lattice energy 
size of cation
1
(B) lgh Øe gS % LiCl > NaCl > KCl > RbCl > CsCl. tkyd ÅtkZ 
/kuk;u dk vkdkj
16. COMPLETE THE FOLLOWING REACTIONS :
fuEu vfHkfØ;vksa dks iw.kZ dhft, %
(i) NaOH + NO2 
Ans. 2NaOH + 2NO2  NaNO2 + NaNO3 + H2O
(ii) NaOH (hot & conc.) (xeZ rFkk lkUnz) + Br2 
PAGE NO.-27
Ans. 6NaOH + 3Br2  5NaBr + NaBrO3 + 3H2O.
(iii) NaOH + S 
Ans. 6NaOH + 4S  2Na2S + Na2S2O3 + 3H2O.
(iv) NaOH (hot & conc.) (xeZ rFkk lkUnz) + F2 
Ans. 4NaOH + 2F2  4NaF + O2 + 2H2O.
(v) PbO + NaOH 
Ans. PbO + 2NaOH  Na2PbO2 + H2O
17. Match the compounds listed in column-I with the characteristic(s) listed in column-II.
Column-I Column-II
(A) BeO (s) (p) Amphoteric in nature
(B) NaHCO3 (crystalline) (q) Imparts characteristic colour to Bunsen flame.
(C) BeCl2(s) (r) Produce H2O2 and O2 on reaction with water.
(D) CsO2(s) (s) Shows hydrogen bonding
(t) Has a chain structure
LrEHk-I esa fn;s x;s ;kSfxdksa dks LrEHk-II esa fn;s x;s vfHky{k.kksa ds lkFk lqesfyr fdft,A
LrEHk-I LrEHk-II
(A) BeO (s) (p) mHk;/kehZ izo`fr
(B) NaHCO3 (fØLVyh;) (q) cqulsu Tokyk esa vfHkyk{k.khd jax n'kkZrs gSA
(C) BeCl2(s) (r) ty ds lkFk vfHkfØ;k dj H2O2 o O2 nsrs gSA
(D) CsO2(s) (s) gkbMªkstu ca/k n'kkZrs gSA
(t) Jà[kyk ljapuk j[krk gSA
Ans. (A – p) ; (B – q, s, t) ; (C – t) ; (D – q, r)
Sol. (A) BeO is amphoteric in nature becuase it reacts with acid as well as base.
(B) Hydrogen bonding; HCO3– ions are linked into an infinite chain through H-bonding.
(C)
(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2

Sol. (A) BeO mHk;/kehZ izd`fr dk gksrk gS D;ksafd ;g vEy lkFk gh lkFk {kkj ds lkFk vfHkfØ;k djrk gSA
(B) gkbMªkstu ca/k; HCO3– vk;u H-ca/k }kjk vUur% J`[kayk esa tqM+s gksrs gSA
(C)
(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2
PAGE NO.-28
ChemINFO s-BLOCK ELEMENT

Daily Self-Study Dosage for mastering Chemistry Calcium oxide & Hydroxide
Reactions Charts (Quick Revision) :

Cl2 CaOCl2
(Bleaching powder)
Na2CO3 NaOH
(Castic-soda)
+ H2O Ca(OH)2
(slaked lime) 1 part slaked lime + 3 or 4 parts silica + water
SiO2
(mortar)
used as a building material
CaO
Quicklime Absorbs CO2 gas
+ Slaking with NaOH + Ca(OH)2

NaOH solution (Soda lime)
CaCN2 + C
+ Coke N2 H2O
CaC2 (Nitrolium) NH3
Heated in electric use as a fertilizer
furnace at 20000C
H2O
C2H2
(Acetylene)
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
ChemINFO s-BLOCK ELEMENT

Daily Self-Study Dosage for mastering Chemistry Calcium oxide & Hydroxide
vfHkfØ;k pkVZ ¼'kh?kz iquZjkoyksdu½ :

Cl2 CaOCl2
(fojatd pw.kZ)
Na2CO3 NaOH
(dkWfLVd&lksMk)
+ HO
2 Ca(OH)2
(cw>k pwuk) 1 Hkkx cw>k pwuk + 3 ;k 4 Hkkx flfydk + ty
SiO2
(eksVkZV)
bldk mi;ksx Hkou fuekZ.k djus okys
inkFkksZ esa fd;k tkrk gSA
CaO
(fcuk cw>k CO2 xSl dk vo’kks"k.k
gqvk pwuk)
NaOH foy;u NaOH + Ca(OH)2

ds lkFk cw>kuk (lksMkykbZe)
CaCN2+ C
+ dksd N2 HO
CaC2 (ukbZVªkfs y;e) 2
NH3
2000ºC rki ij oS|qr moZjd dh rjg iz;qDRk
HkV~Vh esa xeZ djuk
HO
2
C2H2
¼,sflfVyhu½
PAGE NO.-29
18. Which hydrocarbon obtained by the hydrolysis of calcium carbide?

(A) Methane (B) Ethane (C) Ethene (D*) Ethyne
dSfY'k;e dkckZbM ds tyvi?kVu ij fuEu esa ls dkSulk gkbMªksdkcZu IkzkIr gksrk gS ?
(A) eSFksu (B) ,sFksu (C) ,sFkhu (D*) ,sFkkbZu
19. What will obtained when slaked lime react with Na2CO3 ?
fuEu esa ls dkSulk mRikn izkIr gksrk gS tc cw>s gq,s pwus dh vfHkfØ;k Na2CO3 ds lkFk djkrs gS ?
(A) Na2O2 (B*) NaOH (C) NaNH2 (D) NaNO3
20. Which product will obtain when CaC2 react with N2 ?

fuEu esa ls dkSulk mRikn izkIr gksrk gS tc CaC2 dh vfHkfØ;k N2 ds lkFk djkrs gS ?
(A*) CaCN2 + C (B) Ca(CN)2 (C) Ca(OH)2 (D) CaO
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
ANSWER KEY
1. (B) 2. (B) 3. (B) 4. (C) 5. (D) 6. (C) 7.* (AB)
8.* (ACD) 9.* (AB) 10.* (ABC) 11. 5 12. 4 13. 4 14. 1
1. BC3 is more stable than TC3 because :

(A) The difference between electronegativity of B and C is larger than that of T and C.
(B*) The higher oxidation state of T (+ 3) is less stable than that of B (+ 3).
(C) Thallium being larger in size is able to accomodate more C atoms around it.
(D) B3+ is more easily formed than T3+.
BC3, TC3 dh vis{kk vf/kd LFkk;h gksrk gS] D;kasfd :
(A) B rFkk C dh fo|qr_.krk ds e/; vUrj T rFkk C dh vis{kk vf/kd gksrk gSA
(B*) T (+ 3) dh mPpre vkWDLkhdj.k voLFkk B (+ 3) dh vis{kk de LFkk;h gksrh gSA
(C) FkSfy;e vkdkj esa cM+k gksrk gS] rFkk blds pkjks vksj vf/kd C ijek.kq fLFkr gksrs gSA
(D) B3+, T3+ dh vis{kk vf/kd ljyrk ls curk gSA
Sol. Refer notes (uksV~l ns[ksa)
PAGE NO.-30
2. The function of fluorspar in the electrolytic reduction of alumina dissolved is fused cryolite (Na 3AlF6) is
(A) as a catalyst
(B*) to lower the temperature of the melt and to make the fused mixture very conducting
(C) to decrease the rate of oxidation of carbon at the anode
(D) none of these above
laxfyr Øk;ksykbV (Na3AlF6) esa ?kqfyr ,sY;qfeuk ds oS|qr vi?kVuh; viPk;u esa ¶yksjLikj dk dk;Z gksrk gSA
(A) mRizsjd ds :i esa gSA
(B*) xfyr dk rki de djuk rFkk laxfyr feJ.k dks vfrpkyd cukuk
(C) ,uksM+ ij dkcZu dh vkWDlhdj.k dh nj dks ?kVkuk
(D) buesa ls dksbZ ugha
3. Aqueous solution of potash alum is :
(A) alkalline (B*) acidic (C) neutral (D) soapy
iksVk'k ,sye~ dk tyh; foy;u fuEu gksrk gS %
(A) {kkjh; (B*) vEyh; (C) mnklhu (D) lkcquhd`r
Sol. It is acidic because of the hydrolysis of Al2(SO4)3 according to the following reaction.
Al2 (SO4)3 + 6H2O 2Al(OH)3 + 3H2SO4.
gy- fuEufyf[kr vfHkfØ;k ds vuqlkj Al2(SO4)3 ds ty vi?kVu ds dkj.k ;g vEyh; gSA
Al2 (SO4)3 + 6H2O 2Al(OH)3 + 3H2SO4.
4. From B2H6, all the following can be prepared except :

B2H6 ls fuEu esa ls fdl ,d ds vfrfjDr lHkh dks cuk;k tk ldrk gS %
(A) H3BO3 (B) [BH2(NH3)2]+ [BH4]– (C*) B2(CH3)6 (D) NaBH4
Sol. (C) CH3 group being larger can not form a bridge between two small sized boron atoms.
gy- (C) CH3 lewg dk cM+k vkdkj gksus ds dkj.k ;g nks NksVs vkdkj ds cksjkWu ijek.kqvksa ds e/; lsrq ugha cuk ldrk
gSA
5. Which of the following is bauxite?
fuEu esa ls dkSulk ckWDlkbV gS \
(A) Al(NO3)3 (B) AlCl3 (C) Al2(SO4)3.xH2O (D*) Al2O3.xH2O
6. Which of the following is formed when aluminium oxide and carbon is strongly heated in dry chlorine
gas ?
(A) Aliminium chloride (B) Hydrated aluminium chloride
(C*) Anhydrous aluminium chloride (D) None of these
fuEu esa ls D;k fufeZr gksxk tc ,Y;qfefu;e vkWDlkbM rFkk dkcZu dks 'kq"d Dyksfju xSl ess izcyrj :i ls xeZ
fd;k tkrk gS?
(A) ,Y;qfefu;e DyksjkbM (B) gkbMªsV ,Y;qfefu;e DyksjkbM
(C*) futZy ,Y;qfefu;e DyksjkbM (D) buesa ls dksbZ ugha
7.* Which of the following are correct

(A*) B2H6 reacts with excess of ammonia at low temperature to form an ionic compound.
(B*) Borax, when heated with oxides of certain transition metals, forms coloured beads.
(C) One mole borax in aqueous solution will require one mole HCl for titration.
(D) B2H6 can be methylated completely to give B2(CH3)6.
fuEu esa dkSuls dFku lR; gSa \
(A*) B2H6 fuEu rki ij veksfu;k ds vkf/kD; ls fØ;k djds ,d vk;fud ;kSfxd cukrk gSA
(B*) tc cksjsDl dks dqN laØe.k /kkrq vkWDlkbMksa ds lkFk xeZ fd;k tkrk gS rks jaxhu eudk curk gSA
(C) tyh; foy;u esa ,d eksy cksjsDl ds vuqekiu ds fy, 1 eksy HCl dh vko';drk gksxhA
(D) B2H6 dks iw.kZr% esfFkyhd`r djds B2(CH3)6 mRiUu fd;k tk ldrk gSA
Sol. (C) One mole borax will require two moles of HCl for complete reaction.
(D) The bridging hydrogens can not be methylated in B 2H6.
gy (C) iw.kZ vfHkfØ;k ds fy, ,d eksy cksjsDl dks 2 eksy HCl dh vko';drk gksxhA
(D) B2H6 esa lsrq gkbMªkstuksa dks esfFkyhÑr ugha dj ldrs gSaA
PAGE NO.-31
8.* Which of the following can produce B2O3 ?
(A*) Heating borax with conc. H2SO4 (B) Passing CO2 through aq. NaBO2
(C*) Combustion of diborane, B2H6. (D*) Warming H3BO3 crystals till red hot.
fuEu esa ls dkSu B2O3 dks mRikfnr dj ldrk gS\
(A*) lkUnz H2SO4 ds lkFk cksjsDl dks xeZ dj (B) tyh; NaBO2 esa ls CO2 izokfgr dj
(C*) Mkbcksjsu, B2H6 dk ngu dj (D*) H3BO3 fØLVy dks yky rIr rd xeZ djds
9.* Which of the following are correct about B2H6 ?
(A*) each ‘B’ atom is sp3 hybridised
(B*) It consists of two-”3 centre 2 electron bonds”
(C) The two bridging H-atoms are in the plane of the molecules
(D) All of these
B2H6 ds ckjs esa fuEu esa ls lgh gS \
(A*) izR;sd ‘B’ ijek.kq sp3 ladfjr voLFkk esa gSA (B*) blesa nks] rhu dsUnz-nks-bysDVªkWu cU/k gksrs gSaA
(C) nks lsrq H-ijek.kq v.kq ds ry esa gh gksrs gSaA (D) mijksDr lHkh
Sol. ‘A’ and ‘B’ are correct on the basis of structure of B2H6.
B2H6 dh lajpuk ds vk/kkj ij ‘A’ o ‘B’ lgh gSaA
10.* Which of the following hydrides react with water ?
fuEu esa ls dkSuls gkbMªkbM ty ds lkFk vfHkfØ;k djrs gS \
(A*) B2H6 (B*) NH3 (C*) NaH (D) C2H6
Sol. B2H6 + H2O  H3BO3 + H2
NH3 + H2O  NH4OH
NaH + H2O  NaOH + H2
C2H6 + H2O  no reaction. vfHkfØ;k ugha gksrhA
11. In borax ion how many B–O–B bonds present :
cksjsDl vk;u esa fdrusa B–O–B caèk gS %
Ans. 5
12. In diborane maximum how many 2c – 2e bonds present :
MkbZcksjsu esa vf/kdre fdrus 2c – 2e caèk gS %
Ans. 4
13. How many oxides in the following are basic in water:
fuEu esa ls fdrus vkWDlkbM ty esa {kkjh; gksrs gS %+
B2O3, Al2O3, CO2, SO2, NO2, CaO, Na2O, K2O, Cs2O, CaO
Ans. 4
14. Basicity of H3BO3 is
H3BO3 dh {kkjdrk gS %
Ans. 1
PAGE NO.-32
P / I-CHEMISTRY

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EST INFORM AT IO
DPP

ANSWER KEY
1. (B) 2. (D) 3. (B) 4. (D) 5. (A) 6. (B) 7. (C)
8. (A) 9. (B) 10. (D) 11. (A) 12.* (CD)
1. The following structures represent various silicate anions. Their formulas are respectively
fuEu lajpuk,¡ fofHkUu flfydsV _.kk;uksa dks iznf'kZr djrh gSA muds lw=k Øe'k% fuEu gSa %
O
O = Oxygen
= Silicon
O O
(A) SiO44– & Si3O88– (B*) SiO44– & Si3O108– (C) SiO42– & Si3O92– (D) SiO34– & Si3O108–
(A) SiO44– o Si3O88– (B*) SiO44– o Si3O108– (C) SiO42– o Si3O92– (D) SiO34– o Si3O108–
2. Select the correct statements

(A) Oxides of boron (B2O3) and silicon (SiO2) are acidic in nature.
(B) Oxides of aluminium (Al2O3) and gallium (Ga2O3) are amphoteric in nature.
(C) Oxides of germanium (GeO2) and tin (SnO2) are acidic in nature.
(D*) both (A) and (B)
lgh dFkuksa dk p;u dhft;sA
(A) cksjksu (B2O3) rFkk flfydkWu (SiO2) ds vkWDlkbM vEyh; izd`fr ds gksrs gSA
(B) ,yqehfu;e (Al2O3) rFkk xsfy;e (Ga2O3) ds vkWDlkbM mHk;/kehZ izd`fr ds gksrs gSA
(C) tesZfu;e (GeO2) rFkk fVu (SnO2) ds vkWDlkbM vEyh; izd`fr ds gksrs gSA
(D*) (A) rFkk (B) nksuksa
Sol. S1 and S2 are correct statements.
S3 : GeO2 is acidic while SnO2 is amphoteric in nature.
gy % S1 o S2 lgh dFku gSaA
S3 : GeO2 vEyh; gS tcfd SnO2 mHk;/kehZ izd`fr dk gSA
3. Moderate electrical conductivity is shown by :

(A) silica (B*) graphite (C) diamond (D) (BN)X
fuEu esa ls fdlds }kjk e/;e fo|qrpkydrk n'kk;h tkrh gS %
(A) flfydk (B*) xzsQkbV (C) ghjk (diamond) (D) (BN)X
4. Which case of the following halides is least stable and has doubtful existence?
fuEu esa ls dkSulk gSykbM lcls de LFkk;h rFkk langsiw.kZ vfLrRo j[krk gS \
(A) C4 (B) Ge4 (C) Sn4 (D*) Pb4
PAGE NO.-33
5. Which one of the following oxides is neutral ?
fuEu esa ls dkSulk mnklhu vkWDlkbM gS \
(A*) CO (B) SnO2 (C) ZnO (D) SiO2
6. The straight chain polymer is formed by :

(A) hydrolysis of (CH3)3 SiCl followed by condensation polymerization.
(B*) hydrolysis of (CH3)2 SiCl2 followed by condensation polymerization.
(C) hydrolysis of (CH3) SiCl3 followed by condensation polymerization.
(D) hydrolysis of (CH3)4 Si followed by condensation polymerization.
lh/kh Jà[kyh; cgqyd dk fuekZ.k fd;k tk ldrk gS %
(A) (CH3)3 SiCl dk ty&vi?kVu rRi'pkr~ la?kuu cgqydhdj.k }kjk
(B*) (CH3)2 SiCl2 dk ty&vi?kVu rRi'pkr~ la?kuu cgqydhdj.k }kjk
(C) (CH3) SiCl3 dk ty&vi?kVu rRi'pkr~ la?kuu cgqydhdj.k }kjk
(D) (CH3)4 Si dk ty&vi?kVu rRi'pkr~ la?kuu cgqydhdj.k }kjk
7. Which gas is formed when CaC2 is allowed to react with dilute HCl ?
(A) Ethane (B) Ethene (C*) Ethyne (D) Methane
tc CaC2 dks ruq HCl ds lkFk vfHkd`r fd;k tkrk gS] rks dkSulh xSl curh gS \
(A) ,sFksu (B) ,Fkhu (C*) ,Fkkbu (D) esFksu
Sol. CaC2 + 2HCl  CaCl2 + HCCH
Ethyne
,Fkkbu
8. Which of the following oxidation states are the most characterstics for lead and tin, respectively ?
ySM o fVu ds fy, fuEu esa ls dkSulh vkWDlhdj.k voLFkk Øe'k% lokZf/kd :i ls vfHkyk{kf.kd gSa \
(A*) + 2 , + 4 (B) + 4 , + 4 (C) + 2 , + 2 (D) + 4 , + 2
9. Which of the following anions is present in the chain structure of silicates ?

flfydsV dh Jà[kyk lajpuk esa fuEu esa ls dkSulk _.kk;u mifLFkr gksrk gS \

(A) Si2O52 
n 
(B*) SiO32 n (C) SiO44 (D) Si2O76 
10. Glass reacts with HF to produce

Xykl] HF ds lkFk fØ;k dj fuEu mRikn curk gSA
(A) H2SIO3 (B) SiF4 (C) Na3AlF6 (D*) H2SiF6
11. The oxide which is not a reducing agent is :

(A*) CO2 (B) CO (C) SO2 (D) Both (A) & (C)
og vkWDlkbM tks fd vipk;d ugha gS] fuEu gS %
(A*) CO2 (B) CO (C) SO2 (D) nksuks (A) rFkk (C)
Sol. CO2 can not act as reducing agent because carbon is in its highest oxidation state, i.e., +4.
gy- CO2 vipk;d ds :i esa dk;Z ugha djrk gS D;ksafd dkcZu bldh mPpre vkWDlhdj.k voLFkk +4 esa gSaA
12.* Which of the following oxides are acidic :

fuEu esa ls dkSuls vkWDlkbM vEyh; gSa %
(A) CaO (B) Na2O (C*) B2O3 (D*) CO2
PAGE NO.-34
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :

ANSWER KEY
1. (A) 2. (B) 3. (D) 4. (A) 5. (B)
6. (A) 7. (C) 8. (B) 9. (C) 10. (C)
11.* (BCD) 12. 49 13. 42 14. 10 15. 17
16. 56 17. 36 18. 19
1. If for reaction N2 (g) + 3H2 (g)  2NH3 (g), H1º = – 30 kJ/mole at temperature 300 K and if specific
heat capacities of different species are sP, N2 = 1 J/gºC, sP, H2 = 10 J/gºC and sP, NH3 = 2 J/g ºC, then
H2º at 400 K for the same reaction will be : (assume heat capacities to be constant in given
temperature range)
;fn vfHkfØ;k N2 (g) + 3H2 (g)  2NH3 (g) ds fy, 300 K rki ij H1º = – 30 kJ/mole gS rFkk ;fn fofHkUu
Lih'kht dh fof'k"V Å"ek /kkfjrk,¡ sP, N2 = 1 J/gºC, sP, H2 = 10 J/gºC rFkk sP, NH3 = 2 J/g ºC gSa] rks leku
vfHkfØ;k ds fy, 400 K ij H2º fuEu gksxk % (nh gqbZ rki ijkl esa Å"ek /kkfjrk,¡ fu;r ekfu,)
(A*) – 32 kJ/mole (B) – 28 kJ/mole (C) – 32.7 kJ/mole (D) – 27.3 kJ/mole
Sol. H02 = [–30 kJ/mole] + [{2 × 2 × 17 – 28 – 3 × 2 × 10} (100) J/mole]
= (–30 kJ/mole) + (–2000 J/mole) = –32 kJ/mole.
2. A sample contain Fe2(SO4)3, FeSO4 and impurities. A 600 g sample contains 48 g impurities and equal
moles of Fe2(SO4)3 and FeSO4. The % of Fe2(SO4)3 in the mixture is :
(A) 33.33% (B*) 66.7% (C) 83.33% (D) none of these
,d uewus esa Fe2(SO4)3, FeSO4 rFkk v'kqf);k¡ fo|eku gSaA 600 xzke uewus esa 48 xzke v'kqf) rFkk Fe2(SO4)3 ,oe~
FeSO4 ds cjkcj eksy ik;s tkrs gaSA vr%] bl feJ.k esa Fe2(SO4)3 dk izfr'kr fuEu gS&
(A) 33.33% (B*) 66.7% (C) 83.33% (D) buesa ls dksbZ ugha
3. What volume of air at STP containing 21% of oxygen by volume is required to completely burn sulphur
(S8) present in 200 g of sample, which contains 20% inert material which does not burn. Sulphur burns
1
according to the reaction: S8 (s) + O2 (s)  SO2 (s)
8
(A) 23.52 litre (B) 320 litre (C) 112 litre (D*) 533.33 litre
ok;q] tks vk;ru dk 21% vkWDlhtu ;qDr gSa STP ij] bldk vk;ru D;k gSa tcfd ;g 200 g izkn'kZ esa mifLFkr
lYQj (S8) dks iw.kZ :i ls tykus ds fy, vko';d gksa] tks fd 20% vfØ; inkFkZ j[krk gSa tks fd ugha tyk;k
1
tkrk gSaA fuEu vfHkfØ;k ds vuqlkj lYQj tyk;k tkrk gSa % S8 (s) + O2 (s)  SO2 (s)
8
(A) 23.52 yhVj (B) 320 yhVj (C) 112 yhVj (D*) 533.33 yhVj
PAGE NO.-35
Sol. Wt. of S8 in sample = 160 g ;

160
Moles of S8 = = 0.625
32  8
Number of moles O2 required = 0.625 × 8
Volume of O2 required at STP = 22.4 × 5
100
 Volume of air required at STP = 22.4 × 5 × = 533.33
21
gy- izkn'kZ esa S8 dk Hkkj = 160 g ;
160
S8 ds eksy = = 0.625
32  8
vko';d O2 ds eksyksa dh la[;k = 0.625 × 8
STP ij O2 dk vko';d vk;ru = 22.4 × 5
100
 STP ij ok;q dk vko';d vk;ru = 22.4 × 5 × = 533.33
21
4. For a fixed amount of ideal gas at constant temperature, which of the following plots is correct :
fLFkj rki ij ,d vkn'kZ xSl dh fuf'pr ek=kk ds fy, fuEu esa ls dkSulk vkjs[k lgh gS %
(A*) (B) (C) (D)
5. If the density of a gas sample is 4 g/L at pressure 1.2  105 Pa, the value of vrms will be :
;fn 2  105 Pa nkc ij xSl ds ,d uewus dk ?kuRo 4 g/L gks] rks vrms dk eku fuEu gksxk %
(A) 600 m/s (B*) 300 m/s (C) 150 m/s (D) 450 m/s
3RT 3P 3 1.2  105
Sol. vRMS = = = = 300 m/s
M  4
6. A 4 : 1 molar ratio mixture of helium and methane is contained in a vessel at 10 bar pressure. Due to a
hole in the vessel, the gas mixture leaks out. The molar ratio composition of the mixture effusing out
initially is :
10 bar nkc ij ,d ik=k esa ghfy;e o esFksu ds 4 : 1 eksyj vuqikr okys feJ.k dks j[kk tkrk gSA ik=k esa fNnz gksus
ds dkj.k xSlh; feJ.k dk fjlko gksrk gSA izkjEHk esa fulfjr gksus okys feJ.k dk eksyj vuqikr laxBu fuEu gS %
(A*) 8 : 1 (B) 16 : 1 (C) 32 : 1 (D) 6 : 1
Sol. Pressure of helium = 8 bar
Pressure of CH4 = 2 bar
rHe P MCH4 8 16 8
= 1 = = =8:1
rCH4 P2 MHe 2 4 1
gy- ghyh;e dk nkc = 8 bar
CH4 dk nkc = 2 bar
rHe P MCH4 8 16 8
= 1 = = =8:1
rCH4 P2 MHe 2 4 1
7. The weakest Bronsted base among the following is :

fuEu esa ls nqcZyre czkWUlVsM {kkj dkSulk gS %
(A) Cl (B) HS (C*) ClO4 (D) NH3
8. Several acids are listed below with their respective equilibrium constants :
HF(aq) + H2O() H3O+ (aq) + F (aq) Ka = 7.2 × 104
 
HS (aq) + H2O() H3O+ (aq) + S2 (aq) Ka = 1.3 × 1011
CH3COOH(aq) + H2O() H3O+(aq) + CH3COO (aq) Ka = 1.8 ×105
Which is the strongest acid and which acid has the strongest conjugate base ?
PAGE NO.-36
(A) HF and HF (B*) HF and HS– (C) HS– and HF (D) HS– and CH3COOH
dqN vEyksa dks muds lEcaf/kr lkE; fLFkjkadksa ds vk/kkj ij uhps lwphc) fd;k x;k gS %
HF(aq) + H2O() H3O+ (aq) + F (aq) Ka = 7.2 × 104
HS(aq) + H2O() H3O+ (aq) + S2  (aq) Ka = 1.3 × 1011
CH3COOH(aq) + H2O() H3O+(aq) + CH3COO (aq) Ka = 1.8 ×105
çcyre vEy dkSulk gS rFkk dkSulk vEy] çcyre la;qXeh {kkj j[krk gS \
(A) HF rFkk HF (B*) HF rFkk HS– (C) HS– rFkk HF (D) HS– rFkk CH3COOH
Ans. Strongest acid HF; weakest acid HS— and weakest acid (HS—) has the stongest conjugate base.
çcyre vEy HF; nqcZy vEy HS— rFkk nqcZyre vEy (HS—) çcyre la;qXeh {kkj j[krk gSA
9. Several bases are listed below with their respective Kb values :
NH3(aq) + H2O () NH4+(aq) + OH– (aq). Kb = 1.8 × 105
C5H5N(aq) + H2O () C5H5NH+(aq) + OH(aq). Kb = 1.5 × 109
N2H4(aq) + H2O() + –
N2H5 (aq) + OH (aq). Kb = 8.5 × 107
Which is the weakest base and which base has the weakest conjugate acid ?
(A) C5H5N and C5H5N (B) NH3 and NH3 (C*) C5H5N and NH3 (D) NH3 and N2H4
dqN {kkjksa dks muds lEcfU/kr lkE; fLFkjkadksa (Kb) ds ekuksa ds vk/kkj ij] uhps lwphc) fd;k x;k gS %
NH3(aq) + H2O () NH4+(aq) + OH– (aq). Kb = 1.8 × 105
C5H5N(aq) + H2O () C5H5NH+(aq) + OH(aq). Kb = 1.5 × 109
N2H4(aq) + H2O() N2H5+(aq) + OH– (aq). Kb = 8.5 × 107
nqcZyre {kkj dkSulk gS rFkk dkSulk {kkj nqcZyre la;qXeh vEy j[krk gS \
(A) C5H5N rFkk C5H5N (B) NH3 rFkk NH3 (C*) C5H5N rFkk NH3 (D) NH3 rFkk N2H4
Ans. strongest base NH3 ; weakest base C5H5N and NH3 has the weakest conjugate acid.
çcyre {kkj NH3 ; nqcZyre {kkj C5H5N rFkk NH3 nqcZyre la;qXeh vEy j[krk gSA
10. What is the Kb of a weak base that can produce one OH ion per molecule, if its 0.04 M solution is 2.5%
ionized :
;fn ,d nqcZy {kkj dk 0.04 M foy;u 2.5% vk;fur gksrk gS] rFkk blds çfr v.kq ls ,d OHmRiUu gksrk gS] rc
nqcZy {kkj dk Kb D;k gksxk %
(A) 2.5 × 104 (B) 2.5 × 106 (C*) 2.5 × 105 (D) 2.5 × 107
11.* For which one of the following equation Hºr not equal to Hºƒ for the product ?
fuEu esa ls fdl vfHkfØ;k ds fy, Hº vfHkdkjd dk eku] mRIkkn ds fy, Hºƒ ds cjkcj ugha gSa %
(A) Xe(g) + 2F2(g)  XeF4(g) (B*) 2CO(g) + O2(g)  2CO2(g)
(C*) N2(g) + O3(g)  N2O3(g) (D*) CH4(g) + 2Cl2(g)  CH2Cl2() + 2HCl(g)
Sol. When one mole of a substance is directly formed from its constituent elements, then the enthalpy
change is called heat of formation.
tc ,d inkFkZ dks ,d eksy blds vkilh rRoksa ls lh/ks curk gS] rks ,UFkSYih ifjorZu dks lEHkou dh Å"ek dgrs gSaA
For the reaction vfHkfØ;k ds fy,
Xe (g) + 2F2 (g) XeF4 (g)
1 mol
H°react = H°f
12. From the following bond energy and standard Hº values for the formation of elements in gaseous
state, calculate the standard enthalpy of formation (in kCal/mol) of acetone(g) :
xSlh; voLFkk esa rRoksa ds fuekZ.k ds fy, ekud Hº ,oa ca/k ÅtkZ ds eku uhps fn;s x;s gSaA buls ,lhVksu(g) ds
laHkou dh ekud ,UFkSYih dh x.kuk (kCal/mol esa) dhft,A
Standard Hº Bond energies
ekud Hº ca/k ÅtkZ
H (g) = 52 kCal/mol C  H = 99 kCal/mol
O (g) = 59 kCal/mol C  C = 80 kCal/mol
C (g) = 171kCal/mol C = O = 81 kCal/mol
Ans. 49
PAGE NO.-37
13. Given the following standard enthalpies of reaction :
(i) Enthalpy of formation of water =  68.3 kCal/mol
(ii) Enthalpy of combustion of acetylene =  310.6 kCal/mol
(iii) Enthalpy of combustion of ethylene =  337.2 kCal/mol
Calculate the heat of reaction for the hydrogenation of acetylene into ethylene (in kCal/mol) at constant
pressure.
Report your answer in terms of magnitude, rounding it off to the nearest whole number.
uhps dqN vfHkfØ;kvksa ds fy, vfHkfØ;k dh ekud ,UFkSfYi;ksa ds eku fn;s x;s gSa %
(i) ty dh laHkou ,UFkSYih =  68.3 kCal/mol
(ii) ,flfVyhu ds ngu dh ,UFkSYih =  310.6 kCal/mol
(iii) ,Fkhyhu ds ngu dh ,UFkSYih =  337.2 kCal/mol
fu;r nkc ij ,flfVyhu ds ,fFkyhu esa gkbMªkstuhdj.k dh Å"Ekk dk eku (kCal/mol esa) Kkr dhft,A
viuk mÙkj ifjek.k ds :i esa fudVre iw.kk±d esa nhft;sA
Ans.  42
14. Estimate rH (in kJ) for 2C4H10(g)  C8H18(g) + H2(g). Given bond energy of CC and CH are 347
and 441 kJmol1. The enthalpy of formation of H(g) atom is 217.5 kJmol 1. Report your answer after
dividing by 10.
2C4H10(g)  C8H18(g) + H2(g) vfHkfØ;k ds fy,] rH dk eku (kJ esa) Kkr dhftc,A CC rFkk CH ca/k dh
ca/k ÅtkZvksads eku Øe'k% 347 rFkk 441 kJmol1 fn;s x;s gSaA H(g) ijek.kq dh laHkou ,UFkSYih dk eku 217.5
kJmol1 gSA viuk mÙkj 10 ls Hkkx nsdj nhft,A
Ans. 10
15. Using the data (all values are in kilocalories per mole at 25ºC) given below, calculate the bond energy
of CH and CC bonds.
 Hºcombustion (ethane) g =  372 ;  Hºcombustion (propane) g =  530
 Hº for C(graphite)  C (g) = 172 ; Bond energy of HH bond = 104
 Hfº of H2O(l) =  68 ;  Hfº of CO2 (g) =  94
Report your answer as the difference of two values.
uhps fn;s x;s vk¡dM+kas (25ºC ij lHkh eku] fdyksdSykjh izfr eksy esa fn;s x;s gaS) dk mi;ksx djrs gq,] CH rFkk
CC caèk dh ca/k ÅtkZvksa dh x.kuk dhft,A
 Hºngu¼,Fksu½ g =  372 ;  Hº ngu ¼izksisu½ g =  530
 Hº for C (xzsQkbV)  C (g) = 172 ; HH ca/k dh ca/k ÅtkZ = 104
H2O(l) ds fy,  Hfº =  68 ; CO2 (g) ds fy,  Hfº =  94
viuk mÙkj nksuksa ekuksa ds vUrj ds :i esa nhft,A
Ans. 17
16. Determine the standard enthalpy change of the reaction: C 3H8(g) + H2(g)  C2H6(g) + CH4(g), using
the given enthalpy of combustion values under standard conditions :
Compound H2 (g) CH4 (g) C2H6 (g) C (graphite)
 Hº (kJ/mole)   286   890   1560   393.5
The standard enthalpy of formation of C3H8 (g) is  104 kJ/mol. Report your answer in terms of
magnitude, rounding it off to the nearest whole number.
C3H8(g) + H2(g)  C2H6(g) + CH4(g) vfHkfØ;k ds fy,] ekud ,UFkSYih ifjorZu dh x.kuk dhft,A ekud
ifjfLFkfr ds vUrxrZ ngu ,UFkSfYi;ksa ds eku fn;s x;s gSa %
;kSfxd H2 (g) CH4 (g) C2H6 (g) C (xzsQkbV)
 Hº (kJ/mole)   286   890   1560   393.5
C3H8(g) dh ekud laHkou ,UFkSYih dk eku 104 kJ/mol gSA viuk mÙkj ifjek.k ds :i esa fudVre iw.kk±d esa
nhft;sA
Ans.  56
17. The standard molar enthalpies of formation of cyclohexane () and benzene () at 25°C are –156 and
+49 KJ mol–1 respectively. The standard enthalpy of hydrogenation of cyclohexene () at 25°C is
–119 KJ mol–1. Use these data to estimate the resonance energy of benzene in KCal mol–1. Report your
answer in terms of magnitude, rounding it off to the nearest whole number.
PAGE NO.-38
25°C rki ij lkbDyksgSDlsu () rFkk csUthu () ds lEHkou dh ekud eksyj ,UFkSYih Øe'k% –156 rFkk +49 KJ
mol–1 eksy gSA 25°C ij lkbDyksgSDlsu () dh gkbMªkstuhdj.k dh ekud ,UFkSYih –119 KJ mol–1 gSA mDr vk¡dM+ksa
dh lgk;rk ls csUthu dh vuquknh ÅtkZ dh KCal mol–1 esa x.kuk dhft;sA viuk mÙkj ifjek.k ds :i esa fudVre
iw.kk±d esa nhft;sA
Ans. 36
Sol. + 3H2  Hcalculated = 3  (–119) = – 357 KJ mol–1
Hexperimental =  (Hf )product –  (Hf )reactant

or Hexpt = – 156 – (49 + 0) = – 205 KJ mol–1
vuquknh ÅtkZ Resonance energy = – 357 – (–205) = – 152 KJ mol–1
18. The enthalpy of solution of anhydrous CuSO 4 is  15.9 kCal/mol and that of CuSO4.5H2O is 2.8
kCal/mol. Calculate the enthalpy of hydration (in kCal/mol) of anhydrous CuSO 4 into CuSO4.5H2O.
Report your answer in terms of magnitude, rounding it off to the nearest whole number.
futZy CuSO4 ds foy;u dh ,UFkSYih dk eku  15.9 kCal/mol rFkk CuSO4.5H2O ds foy;u dh ,UFkSYih dk
eku 2.8 kCal/mol gSA futZy CuSO4 ds CuSO4.5H2O esa ty;kstu dh ,UFkSYih (kCal/mol esa) Kkr dhft,A
viuk mÙkj ifjek.k ds :i esa fudVre iw.kk±d esa nhft;sA
Ans. 19
PAGE NO.-39
P / I-CHEMISTRY


EST INFORM AT IO
DPP

Comprehension ('–1' negative marking) Q.13 (3 marks, 2 min.) [03, 02]
ChemINFO : 4 Questions ('–1' negative marking) Q.16 to Q.19 (4 marks, 2 min.) [16, 08]
ANSWER KEY
1. (C) 2. (B) 3. (A) 4. (C) 5. (B)
6. (C) 7. (B) 8. (B) 9.* (AC) 10.* (ACD)
11.* (BCD) 12.* (ABCD) 13. (C) 14. 8 15. 50
16. (C) 17. (D) 18. (B) 19. (C)
1. Select the correct statement :
(A) Na2HPO3 is an acid salt.
(B) Water acts as a base, when ammonia is dissolved in it.
(C*) All aqueous solutions, whether neutral, acidic or basic, contain both H + & OH ions.
(D) All of these
lR; dFku dk p;u dhft, %
(A) Na2HPO3 ,d vEyh; yo.k gSA
(B) ty ,d {kkj ds :i esa dk;Z djrk gSa tc bles veksfu;k ?kksyh tkrh gSA
(C*) lHkh tyh; foy;u] pkgs mnklhu] vEyh; vFkok {kkjh; gksa] H+ rFkk OH nksuksa vk;u ;qDr gksrs gSaA
(D) mijksDÙk lHkh
2. Aqueous solution of CuSO4 is ______ due to the hydrolysis of ______ ions.
(A) acidic, SO42– (B*) acidic, Cu2+ (C) basic, Cu2+ (D) basic, SO42–
_______ vk;u ds ty&vi?kV~u ds dkj.k CuSO4 dk tyh; foy;u ______ gksrk gSA
(A) SO42–, vEyh; (B*) Cu2+, vEyh; (C) Cu2+, {kkjh; (D) SO42–, {kkjh;
Sol. 2+
[Cu(H2O)6] + H2O +
[Cu(H2O)5(OH)] + H3O +
3. NH4Cl (aq) is :
(A*) acidic due to NH4+ (B) acidic due to Cl– (C) basic due to NH4+ (D) basic due to Cl–
NH4Cl ¼tyh;½ :
(A*) NH4+ ds dkj.k vEyh; gS (B) Cl– ds dkj.k vEyh; gS
(C) NH4+ ds dkj.k {kkjh; gS (D) Cl– ds dkj.k {kkjh; gS
4. Which of the following salts does not undergo hydrolysis :
fuEu esa ls dkSuls yo.k dk ty vi?kVu ugha gksrk gS %
(A) CH3COONH4 (B) FeCl3.6H2O (C*) KCl (D) KCN
5. The pH value will be highest for the aqueous solution of :

fuEu esa ls fdl yo.k ds tyh; foy;u dh pH dk eku vf/kdre gksxk %
(A) NaCl (B*) KCN (C) C6H5NH3+Cl– (D) NaHCO3
PAGE NO.-40
6. In which of the following cases, the aqueous solution is not basic :
I. BeCl2 II. LiCN III. (NH4)2C2O4 IV. C5H6NBr V. NaF
(A) II & V only (B) I & IV only (C*) I, III & IV (D) I & III Only
fuEu esa ls dkSulk tyh; foy;u {kkjh; ugha gS %
I. BeCl2 II. LiCN III. (NH4)2C2O4 IV. C5H6NBr V. NaF
(A) dsoy II rFkk V (B) dsoy I rFkk IV (C*) I, III rFkk IV (D) dsoy I rFkk III
7. The self ionization constant for pure formic acid, K = [ HCOOH 2+ ] [HCOO] has been estimated as 10
6
at room temperature.The density of formic acid is 1.15 g/cm 3. The percentage of formic acid
converted to formate ion is :
dejs ds rki ij 'kq) QkWfeZd vEy ds fy, Lor% vk;uu fLFkjkad K = [ HCOOH2+ ][HCOO] dk eku 10 6
ifjdfyr fd;k x;k gSA QWkfeZd vEy dk ?kuRo 1.15 g/cm3 gSA QWkfeZd vEy dk fdruk çfr'kr QkWesZV vk;u esa
ifjofrZr gS \
(A) 0.002 % (B*) 0.004 % (C) 0.006 % (D) 0.008 %
Sol. K = [HCOOH2+] [HCOO–] = 10–6.
[HCOO–] = 10–3 mol/L.
1 liter solution of HCOOH has = 1150 g mass.
HCOOH dk ,d yhVj foy;u = 1150 xzke æO;eku j[krk gSA
1150
moles of (HCOOH) in 1 litre solution = = 25 mol.
46
,d yhVj foy;u esa (HCOOH) ds eksy = 1150 = 25 mol.
46
out of 25 mol HCOOH 10–3 mol are ionised into HCOO– ions.
25 mol HCOOH esa ls 10–3 mol HCOO– vk;u esa vk;fur gksxsa
10 –3
 % dissociation (izfr'kr fo;kstu) = × 100 = 0.004%
25
8. Match the following forms of Vander waal’s equation for 1 mole of a real gas with given conditions :
(a) high pressure (i) PV = RT + Pb
(b) low pressure (ii) PV = RT – a/V
(c) force of attraction between gas molecules is negligible (iii) PV = RT + a/V
(d) volume of gas molecules is negligible (iv) PV = RT – Pb
(a) mPp nkc (i) PV = RT + Pb
(b) fuEu nkc (ii) PV = RT – a/V
(c) xSl v.kqvksa ds e/; vkd"kZ.k dk cy ux.; gS (iii) PV = RT + a/V
(d) xSl v.kqvksa dk vk;ru ux.; gS (iv) PV = RT – Pb
(A) (a)  (i), (b)  (ii), (c)  (iv), (d)  (iii) (B*) (a)  (i), (b)  (ii), (c)  (i), (d)  (ii)
(C) (a)  (iii), (b)  (iv), (c)  (iv), (d)  (iii) (D) (a)  (iii), (b)  (iv), (c)  (i), (d)  (ii)
9.* When wave length of a small moving particle is equal to four times the distance travelled in one second
then
tc ,d NksVs xfreku d.k dh rjax }S/;Z] mlds }kjk ,d lsd.M esa r; dh xbZ nwjh dh pkj xquk gks rks rjax}S/;Z
dk eku gksxkA
h h h h
(A*)   (B)   (C*)   2 (D)  
mv m m p
h
Sol. =
mV
 = 4V

V=
4
h
2 =
m
PAGE NO.-41
h
=2
m
10.* Which of the following increases with dilution at a given temperature :

fn;s x, rki ij fuEu esa ls fdlesa] ruqrk ds lkFk o`f) gksrh gS %
(A*) pH of 103 M acetic acid solution
(B) pH of 103 M aniline solution
(C*) degree of dissociation of 103 M acetic acid solution
(D*) degree of dissociation of 10–3 M aniline solution
(A*) 103 M ,lhfVd vEy dh pH (B) 103 M ,uhyhu ds foy;u dh pH
(C*) 103 M ,lhfVd vEy ds fo;kstu dh ek=kk (D*) 10–3 M ,uhyhu ds fo;kstu dh ek=kk
Sol. Degree of dissocation of WA & WB will increase.
[H+] in WA and [OH–] in WB will decrease so pH of WA and pOH of WB will increase.
gy % WA rFkk WB ds fo;kstu dh ek=kk] esa o`f) gksxhA
WA esa [H+] rFkk WB esa [OH–] esa deh gksxh blfy,] WA dh pH rFkk WB dh pOH esa o`f) gksxhA
11.* An ideal gas undergoes adiabatic expansion against constant external pressure. Which of the following
are correct :
(A) Internal energy of the gas remains unchanged.
(B*) Temperature of the system decreases.
(C*) E + PV = 0
(D*) Internal energy of the gas decreases.
,d vkn'kZ xSl] fu;r ckg~; nkc ds fo:)] :)ks"eh; izlkj n'kkZrh gSA fuEu esa ls dkSuls dFku lgh gSaA
(A) xSl dh vkUrfjd ÅtkZ vifjofrZr jgrh gSA
(B*) ra=k ds rki esa deh gksrh gSA
(C*) E + PV = 0
(D*) xSl dh vkUrfjd ÅtkZ esa deh gksrh gSA
Sol. In adiabatic expansion q = 0 so E = –Pext V or E + V = 0.
:)ks"eh; izlkj esa q = 0 vr % E = –Pext V o E + V = 0
12.* Which of the following can act both as a Bronsted acid & a Bronsted base (amphiprotic species) :
fuEu esa ls dkSulk¼ls½ czkWUlVsM vEy rFkk czkWUlVsM {kkj nksuksa dh rjg O;ogkj ¼mHk;/kehZ Lih'kht½ dj ldrk¼rs½ gS¼gSa½
(A*) NH3 (B*) H2PO3– (C*) HCO3 (D*) OH
Passage #
Relative strengths of conjugate acid base pairs :
HCIO 4  CIO4 –  very weak bases
 Strong acids 
HCI  CI–  Negligible tendency
Stronger acid  100% dissociated Weaker base
–  to be protonated in
H2SO 4  HSO4 
in aqueous solution
HNO3  NO3 – 
 aqueous solution
H3O+ H2O
PAGE NO.-42
SO24 
HSO 4  
 H2PO4 
H3PO 4  
 NO2 
HNO2  

HF  F 
 Weak acids  Weak bases
CH3COOH CH3CO2 
 Exist in solution as Moderate tendency
H2CO3  HCO3 
a mixtureof HA  to be protonated
H2S  HS  
 A  ,and H3O  in aqueous solution
NH4  NH3 
  
HCN  CN 
  
HCO3  CO32  
H2O   
OH

NH3  Very Weak acids NH2  Strong bases 100%

 
Weaker acid OH  Negligible tendency O2   protonated in Strong base
H2  to dissociate. H 
 aqueous solution
 
vuqPNsn #
la;qXeh vEy {kkj ;qXeksa dh vkisf{kd lkeF;Z %
HCIO 4  CIO4 – 
 izcy vEy  cgqr nqcZy {kkj
HCI  CI– 
izcyre vEy  tyh; foy;u esa –
tyh; foy;u esa izksVksuhd`r nqcZyre {kkj
H2SO 4  HSO4 
100% fo;ksftr gksus dh izo`fÙk ux.;
HNO3  NO3 – 

H3O+ H2O
SO24 
HSO 4  
 
H2PO4 
H3PO 4  
 NO2 
HNO2  

HF  nqcZy vEy F 
 
CH3COOH foy;u esa] HA CH3CO2  nqcZy {kkj tyh; foy;u
 
H2CO3 
 A rFkk H3O ds HCO3  esa izksVksuhd`r gksus dh

H2S  feJ.k ds :i esa HS   izo`fÙk lkekU;
 
NH4  mifLFkr gksrs gS NH3 
  
HCN  CN 
HCO3  2 
 CO3 
 
H2O OH

NH3  cgqr nqcZy vEy NH2 

  izcy {kkj tyh; foy;u
nqcZyre vEy OH  fo;ksftr gksus dh O2   izcy {kkj
H2  izo`fÙk ux.;  esa 100% izksVksuhd`r gksrs gSa
 H 

PAGE NO.-43
13. Reactions proceeding to the right are :

nk¡;h vksj izxfr djus okyh vfHkfØ;k,¡ fuEu gaS %
(A) H2CO3 (aq) + HSO4–(aq) H2SO4(aq) + HCO3– (aq)
–
(B) HF (aq) + Cl (aq) HCl (aq) + F– (aq)
(C*) HF (aq) + NH3 (aq) NH4+ (aq) + F– (aq)
(D) HSO4– (aq) + CN– (aq) HCN (aq) + SO42– (aq)
Sol. (a) Acid strength vEy lkeF;Z H2SO4 > H2CO3.
Basic strength {kkj lkeF;Z HCO3– > HSO4–.
(b) Acid strength vEy lkeF;Z HCl > HF.
Basic strength {kkj lkeF;Z F– > Cl–.
(c) Acid strength vEy lkeF;Z HF > NH4+
Basic strength {kkj lkeF;Z NH3 > F–.
(d) Acid strength vEy lkeF;Z HSO4– > HCN.
Basic strength {kkj lkeF;Z CN– > SO42–.
c and d will move to the right.
c o d nk;ha rjQ xfr djsxkA
14. Calculate the magnitude of work done (in atm lit.) for the given cyclic process involving 1 mole of an
ideal gas. [Given R = 0.08 atm lit./mole-K]
1 eksy vkn'kZ xSl ls lEcfU/kr fn;s x;s pØh; izØe ds fy, fd;s x;s dk;Z (atm lit. esa) ds ifjek.k dks ifjdfyr
dhft,A [fn;k x;k gS R = 0.08 atm lit./mole-K]
D C
20 atm
A B
300 400 600

T(K)
Ans. 8
Sol. During process BC (isochoric process)
BC izØe ds nkSjku ¼levk;ruh izØe½
PB PC 20 P
=  = C
TB TC 300 600
PC = 40 atm = PD
During process DA (isochoric process)
DA izØe ds nkSjku ¼levk;ruh izØe½
PD P 40 20
= A  =
TD TA 400 TA
TA = 200 K
W AB = –nRT = – R  100 = –8 L-atm
(isobaric process) ¼lenkch; izØe½
W BC = 0 W DA = 0
W CD = –nRT = – R(400 – 600) = 16 L-atm
(isobaric process) ¼lenkch; izØe½
W Total = 8 L-atm
15. For a 10–3 M solution of a weak monoacidic base (K b = 5 × 10–4), calculate the % ionisation of base.
Report your answer rounding it off to the nearest whole number.
,d nqcZy ,dyvEyh; {kkj (Kb = 5 × 10–4) ds 10–3 M foy;u ds fy,] {kkj dh vk;uu çfr'krrk dh x.kuk
dhft,A
viuk mÙkj fudVre iw.kk±d ds :i esa nhft,A
Ans. 50
PAGE NO.-44
ChemINFO Ionic Equilibrium

Daily Self-Study Dosage for mastering Chemistry Leveling and Differentiating Solvents
In a differentiating solvent, various acids dissociate to different degrees and thus have different strengths. In a
leveling solvent, several acids are completely dissociated and are thus of the same strength. A weakly basic
solvent has less tendency than a strongly basic one to accept a proton. Similarly a weak acid has less tendency
to donate protons than a strong acid. As a result a strong acid such as perchloric acid exhibits more strongly
acidic properties than a weak acid such as acetic acid when dissolved in a weakly basic solvent. On the other
hand, all acids tend to become indistinguishable in strength when dissolved in strongly basic solvents owing to
the same affinity of strong bases for protons release by different acids. This is called the leveling effect. Strong
bases are leveling solvents for acids, weak bases are differentiating solvents for acids. Because of the leveling
effect of common solvents, studies on super acids are conducted in solvents that are very weakly basic such as
sulfur dioxide (liquefied) and SO2CIF.
H3O+ is the strongest acid that can exist in water. This means that all strong acids in water will result in H3O+,
effectively acting as if they have the same acid strength.
If a base is stronger than OH–, it deprotonates H2O to make OH–. This is called the leveling effect.
Example: Acetic acid solvent is less basic than water, so
HClO4 + CH3COOH CH3CO2H2 + ClO4–
K = 1.3×105
HCl + CH3CO2H CH3CO2H2 + Cl–
K = 2.8 ×109
ChemINFO Ionic Equilibrium

Daily Self-Study Dosage for mastering Chemistry levk;uu rFkk fo"kevk;uu foyk;d
fo"ke vk;uu foyk;d esa fofHkUUk vEy] fofHkUu ek=kkvksa esa fo?kfVr gksrs gSa rFkk bl dkj.k ;s fofHkUu lkeF;Z j[krs gSaA
levk;uu foyk;d esa] vusd vEy iw.kZ:i ls fo?kfVr gksrs gaS rFkk bl dkj.k ;s leku lkeF;Z okys gksrs gaSA nqcZy {kkjh;
foyk;d dh ,d çksVkWu xzg.k djus dh ço`fRr]çcy {kkjh; dh vis{kk de gksrh gSA blh çdkj nqcZy vEy dh ,d çksVkWu nku
djus dh ço`fRr] çcy vEy dh vis{kk de gksrh gSA ifj.kkeLo:i] nqcZy {kkj esa çcy vEy tSls ijDyksfjd vEy] nqcZy vEy
tSls ,flfVd vEy dh vis{kk çcyre vEyh; xq.k j[krk gSA nwljs 'kCnksa esa lHkh vEyksa dh lkeF;Zrk esa foHksn ugh fd;k tk
ldrk gS] tc bUgsa çcy {kkjh; foyk;d esa foy; fd;k tkrk gS] ftudh fofHkUu vEyksa ls fudyus okyh çksVkWu ds çfr ca/kqrk
leku gksrh gSA ;g çHkko levk;uu çHkko dgykrk gSA vEyksa ds fy,] çcy {kkj levk;uu foyk;d gksrs gSa] tcfd nqcZy
{kkj fo"ke vk;uu foyk;d gksrs gaSA mHk;fu"B foyk;dksa ds levk;uu çHkko ds dkj.k lwij vEyksa dk vè;;u] vfr nqcZy
{kkjh; foyk;dksa esa fd;k tkrk gSA tSls lYQj MkbZ vkDlkWbM ¼æfor½ rFkk SO2CIF.
H3O+ çcyre vEy gS] tks ty esa vfLRkRo j[krk gSA blls rkRi;Z gS fd lHkh çcy vEy] ty esa H3O+ ds :i esa
ik;s tkrs gS] vr% çHkkoh :i ls ;s leku vEyh; lkeF;Zrk j[krs gSaA ;fn {kkj OH– ls çcy gS] og H2O dks foçksVkWuhÑr dj
OH– cukrk gSA ;g levk;uu çHkko dgykrk gSA
mnkgj.k % ,flfVd vEy foyk;d ty ls de {kkjh; gS] vr%
HClO4 + CH3COOH CH3CO2H2 + ClO4–
K = 1.3×105
HCl + CH3CO2HCH3CO2H2 + Cl–
K = 2.8 ×109
16. The leveling effect of water for acids is due to :
(A) Its high dielectric constant (B) Its high proton affinity
(C*) Both (A) and (B) (D) None of these
vEyksa ds fy, ty ds levk;uu çHkko dk dkj.k fuEu gS %
(A) bldk mPp ijkoS|qrkad fu;rkad (B) bldh mPp çksVkWu cU/kqrk
(C*) (A) rFkk (B) nksuksa (D) buesa ls dksbZ ugaha
PAGE NO.-45
17. Select the correct statement :
(A) NH3 is a differentiating solvent for acids (B) H2O is a differentiating solvent for bases
(C) CH3COOH is a leveling solvents for acids (D*) CH3COOH is a differentiating solvent for acids
lgh dFku dk p;u dhft, %
(A) vEyksa ds fy, NH3 fo"kevk;uu foyk;d gSA
(B) {kkjksa ds fy, H2O fo"kevk;uu foyk;d gSA
(C) vEyksa ds fy, CH3COOH levk;uu foyk;d gSA
(D*) vEyksa ds fy, CH3COOH fo"kevk;uu foyk;d gSA
18. Acidic strength of HClO4 is more than HCl when :
(A) H2O is used as a solvent. (B*) CH3COOH is used as a solvent.
(C) NH3 is used as a solvent. (D) None of these.
HClO4 dh vEyh; lkeF;Zrk] HCl ls vf/kd gksxh %
(A) H2O foyk;d dh Hkk¡fr ç;qDr gksxkA (B*) CH3COOH foyk;d dh Hkk¡fr ç;qDr gksxkA
(C) NH3 foyk;d dh Hkk¡fr ç;qDr gksxkA (D) buesa ls dksbZ ugaha
19. Select the incorrect statement:
(A) H3O+ is the strongest acid in water.
(B) Bases stronger than water are leveling solvent for acids.
(C*) Bases weaker than water are leveling solvent for acids.
(D) Bases weaker than water are differentiating solvent for acids.
xyr dFku dk p;u dhft, %
(A) H3O+ ty esa çcyre vEy gSA
(B) vEyksa ds fy,] ty ls çcy {kkj levk;uu foyk;d gSaA
(C*) vEyksa ds fy,] ty ls nqcZy {kkj levk;uu foyk;d gSaA
(D) vEyksa ds fy,] ty ls nqcZy {kkj fo"kevk;uu foyk;d gSaA
P / I-CHEMISTRY


EST INFORM AT IO
DPP


ANSWER KEY
1. (B) 2. (A) 3. (B) 4. (A) 5. (B)
6. (B) 7. (B) 8. (D) 9. (D) 10. (D)
11. (C) 12. (D) 13.* (AD) 14.* (ABD) 15. 6
16. pH = 6.39 17. (A) - (p, q, s) ; (B) - (p, r) ; (C) - (p, r, s) ; (D) - (q, s)
PAGE NO.-46
1. Solution containing 0.1 N NH4OH and 0.1 N NH4Cl has pH = 9.25.Then find out pKb of NH4OH.
0.1 N NH4OH o 0.1 N NH4Cl ;qDr foy;u dh pH = 9.25 gSA rc NH4OH dk pKb Kkr dhft;sA
(A) 9.25 (B*) 4.75 (C) 3.75 (D) 8.25
 NH4 Cl 
Sol. pOH = pKb + log  
 NH4 OH 
 0.1 
14 – 9.25 = pKb + log    pKb= 4.75.
 0.1 
2. Both conc. being 1 M, the factor by which the percent hydrolysis of CH 3COO– is greater in CH3COONH4
than in CH3COONa is (Ka (CH3COOH) = Kb (NH4OH)).
nksuksa dh lkanzrk 1 M gS fdl dkjd (xq.kkad) ls CH3COO¯ dk ty vi?kVu CH3COONa dh rqyuk esa
CH3COONH4 esa vf/kd gSA (Ka (CH3COOH) = Kb (NH4OH)) .
(A*) 236 (B) 136 (C) 36 (D) 3
3. Calculate the pH of a 0.1 M K3PO4 solution. The third dissociation constant of phosphoric acid is 10 –12.
Given (0.41)1/2 = 0.64 ; log 3 = 0.48
0.1 M K3PO4 foy;u ds pH dh x.kuk dhft;s \ QkWLQksjhd vEy dk r`rh; fo;kstu fu;rkad ()10–12 gSA
fn;k gS (0.41)1/2 = 0.64 ; log 3 = 0.48
(A) 12.5 (B*) 12.44 (C) 12.25 (D) 12
Kw 10 14
Sol. Kh = = = 10–2
K a3 10 12
Ch 2
Kh =
(1  h)
Kh 10 2
as 1 – h = 1, h = = = 0.316
C 0.1
as h > 0.1  1 – h  1
101  h 2
 10–2 = or 0.1 (1 – h) = h2
(1  h )
or, 0.1 – 0.1 h = h2
or, h + 0.1 h – 0.1 = 0
0.1  (0.1)2  4  0.1
or, h = = 0.27
2
as, PO43– + H2O HPO42– + OH–
c(1 – h) ch ch
[OH–] = ch
= 0.1  0.27
= 27  10–3
pOH = 3 – log 27 = 3 log33 = 3 – 3 log 3
= 3 – 3  0.48
= 1.56
pH = 14 – 1.56 = 12.44
4. Two pairs of salts are given, each in 0.1M aqueous solution. Which solution has a higher pH ? The
strength of acids is HF > HOCl > HOBr > HCN.
(A*) NaCN and NaOBr (B) NaF and NaOCl (C) NaF and NaOBr (D) NaCN and NaOCl
yo.kksa ds nks ;qXe fn;s x;s gSa ftuesa izR;sd dh lkUnzrk 0.1 M gS] fuEu esa ls fdl foy;u dk pH mPpre gS \
vEyksa dh lkEFkZ; dk Øe HF > HOCl > HOBr > HCN gSA
(A*) NaCN rFkk NaOBr (B) NaF rFkk NaOCl (C) NaF rFkk NaOBr (D) NaCN rFkk NaOCl
PAGE NO.-47
5. Choose the correct statement(s) :
(A) pH of acidic buffer solution decrease if more salt is added.
(B*) pH of basic buffer solution increases if more base is added.
(C) Both (A) and (B)
(D) None of these
lgh dFku pqfu;s %
(A) ;fn yo.k dh ek=kk c<+k;h tk;s] rks vEyh; cQj foy;u dh pH ?kVrh gSA
(B*) ;fn {kkj dh ek=kk c<+k;h tk;s] rks {kkjh; cQj dh pH c<+rh gSA
(C) (A) o (B) nksuksaA
(D) buesa ls dksbZ ughaA
[Salt]
Sol. (A) is incorrect because pH = pKa + log for acidic buffer.
[Acid]
If [Salt] increases, pH of acidic buffer will increase.
[Salt]
(B) is correct because pOH = pKb + log for basic buffer.
[Base]
If [Base] increases, pOH will decrease, pH will increase as pH = 14 – pOH.
[ yo.k ]
gy- (A) xyr gS D;kasfd vEyh; cQj ds fy, pH = pKa + log .
[ vEy]
;fn [yo.k] esa o`f} gksrh gS] rks vEyh; cQj dk pH esa o`f} gksxh.
[ yo.k ]
(B) lgh gS D;kasfd {kkjh; cQj ds fy, pOH = pKb + log .
[{kkj ]
;fn [{kkj] eas o`f} gksrh gS rks, pOH esa deh gksxh o pH esa o`f) gksxh D;kasfd pH = 14 – pOH.
6. To prepare a buffer solution of pH = 4.04, amount of Barium acetate to be added to 100 mL of 0.1 M
acetic acid solution [pKb(CH3COO–) = 9.26] is :
(A) 0.05 mole (B) 0.025 mole (C*) 0.001 mole (D) 0.005 mole
pH = 4.04 dk cQj cukus ds fy, 0.1 M ,flfVd vEy ds 100 mL ds lkFk csfj;e ,flVsV dh feyk;h xbZ ek=kk
fuEu gS% [pKb (CH3COO–) = 9.26]
(A) 0.05 eksy (B) 0.025 eksy (C*) 0.001 eksy (D) 0.005 eksy
Sol. For the buffer solution of CH3COOH & CH3COO –
[CH3COO– ] m.moles of CH3COO –

pH = pKa + log   4.04 = 4.74 + log 
[CH3COOH] (100  0.1)
  m. moles of CH3COO– = 2   moles of (CH3COO)2Ba required = 0.001
gy. CH3COOH o CH3COO– ds cQj foy;u ds fy,
[CH3COO– ] CH3COO – ds feyheksy
pH = pKa + log   4.04 = 4.74 + log 
[CH3COOH] (100  0.1)
  CH3COO– ds feyh eksy = 2   (CH3COO)2Ba ds vko';d eksy = 0.001
7. The pOH of a basic buffer (e.g. NH4OH/NH4Cl is 5. If the concentration of the salt is tripled whereas that
of base remains same, what is the new value of pOH ? (Given log 3  0.48)
,d {kkjh; cQj (mnk. NH4OH/NH4Cl) dk pOH 5 gSA ;fn yo.k dh lkUnzrk frxquh dh tkrh gks] tgk¡ {kkj leku
jgrk gSA pOH dk u;k eku D;k gS \ (fn;k gS log 3  0.48)
(A) 4.52 (B*) 5.48 (C) 6.48 (D) 3.52
[salt] [ yo.k ]
Sol. pOH = pKb + log ¼ ½=5
[base] [{kkj ]
 3 [salt]   3[ yo.k ]  [salt] [ yo.k ]
pOH = pKb + log   ¼  ½= pKb + log ¼ ½ + log3 = 5 + log3 = 5 + 0.48 = 5.48.
 [base]   [ {kkj ]  [base] [{kkj ]
PAGE NO.-48
8. Which one of the following is not a buffer solution ?
fuEu esa ls cQj foy;u dkSulk ugha gS\

(A) 0.8 M H2S + 0.8M KHS (B) 2M C6H5NH2 + 2M C6H5 N H3Br–
(C) 3M H2CO3 + 3M KHCO3 (D*) 0.05 M KClO4 + 0.05M HClO4
9. The principal buffer present in human blood is :

ekuo jDr esa mifLFkr lS)kfUrd cQj fuEu gS %
(A) NaH2PO4 + Na2HPO4 (B) H3PO4 + NaH2PO4
(C) CH3COOH + CH3COONa (D*) H2CO3 + HCO3–
10. Following is the emission spectrum of He+ ion :

fuEufyf[kr vkjs[k He+ vk;u dk mRltZu LisDVªe gS %
In the above shown energy diagram, the three wavelengths 1, 2 and 3 are in the ratio of ............
respectively.
mijksDr iznf'kZr ÅtkZ vkjs[k es]a rhu rjax-nS/;Z 1, 2 rFkk 3 dk vuqikr Øe'k% ............ gksxk %
(A) 1 : 2 : 3 (B) 1 : 4 : 3 (C) 2 : 3 : 5 (D*) 1 : 3 : 4
1 1 1
Sol. 1 :  2 :  3 = : :
E1 E2 E3
1 1 1
=  : : 1:3:4
40.8 13.6 10.2
11. The vapour density of N2O4 at a certain temperature is 40. What is the percentage dissociation of N 2O4
at this temperature according to the given reaction ? N 2O4(g) 2NO2(g)
,d fuf'pr rkieku ij N2O4 dk ok"i ?kuRo 40 gSA bl rkieku ij nh xbZ vfHkfØ;k ds vuqlkj N2O4 dk %
fo;kstu D;k gksxk ? N2O4(g) 2NO2(g)
(A) 7.5% (B) 95% (C*) 15% (D) 1.5%
12. Which of the given solutions has pOH = pKb (NH3) ?

(A) 10 mL of 0.1 M HCl + 10 mL of 0.2 M NH3 (B) 10 mL of 0.1 M HCl + 20 mL of 0.1 M NH3
(C) 50 mL of 0.2 M HCl + 20 mL of 1M NH3 (D*) All of these
fuEu esa ls fn, x;s fdl foy;u ds fy, pOH = pKb (NH3) gS ?
(A) 0.1 M HCl ds 10 mL + 0.2 M NH3 ds 10 mL (B) 0.1 M HCl ds 10 mL + 0.1 M NH3 ds 20 mL
(C) 0.2 M HCl ds 50 mL + 1M NH3 ds 20 mL (D*) mijksDr lHkh
[salt]
Sol. pOH = pKb + log
[base]
As [salt] = [base]
pOH = pKb
yo.k
Sol. pOH = pKb + log
{kkj
D;kasfd [yo.k] = [{kkj]
pOH = pKb
PAGE NO.-49
13.* Equal volume of 0.1M NaCl and 0.1M FeCl2 are mixed with no change in volume due to mixing. Which
of the following will be true for the final solution. (No precipitation occurs). Assume complete
dissociation of salts and neglect any hydrolysis.
0.1M NaCl vkSj 0.1M FeCl2 ds leku vk;ru dks feykus ij muds vk;ru esa dksbZ ifjorZu ugha gksrk gSA buesa ls
vfUre foy;u ds fy;s dkSulk lR; gSA ¼dksbZ vo{ksi ugha curk½ ekuks yo.k dk iw.kZ fo;kstu gksrk gS vkSj fdlh
ty vi?kVu dks NksM+ nks&
(A*) [Na+] = 0.05 M (B) [Fe2+] = 0.1M (C) [Cl] = 0.3M (D*) [Cl] = 0.15M
14.* The pH values of which of the following solution in general does not depend on the concentration of
solution:
(A*) An aqueous solution of Ammonium formate (HCOONH4)
(B*) An aqueous solution of Sodium bicarbonate (NaHCO3)
(C) An aqueous solution of Potassium sulphide (K2S).
(D*) An aqueous solution of Barium chloride (BaCl2)
fuEu esa ls dkSuls foy;u dk pH eku lkekU;r% foy;u dh lkUnzrk ij fuHkZj ugh djrk gSA
(A*) veksfu;e QkesZV (HCOONH4) dk tyh; foy;u
(B*) lksfM;e ckbZdkcksZusV (NaHCO3) dk tyh; foy;u
(C) iksVsf'k;e lYQkbM (K2S) dk tyh; foy;u
(D*) csjh;e DyksjkbM (BaCl2) dk tyh; foy;u
1
Sol. (A) pH = (pKw + pKa – pKb)
2
pK a1  pK a2
(B) pH =
2
1
(C) pH = (pKw + pKa2 + log10C)
2
(D) pH = 7
15. How many of the following species on mixing with water produce acidic solutions ?
fuEu esa ls fdruh Lih'kht ty ds lkFk fefJr djus ij vEyh; foy;u nsrh gS \
FeCl3 ; CuSO4 ; CO2 ; NaCl ; KCN ;
NH4Cl ; C6H5NH3+Cl– ; BCl3, CaCO3;
Ans. 6
Sol. FeCl3, CuSO4, CO2, NH4Cl ; C6H5NH3+Cl– ; BCl3.
16. Calculate the pH in a 0.1 M solution of NH4OCN. Ka (HOCN) = 3.3 x 104, Kb (NH3) = 1.8 × 105
NH4OCN ds 0.1 M foy;u ds pH dh x.kuk dhft,A Ka (HOCN) = 3.3 x 104, Kb (NH3) = 1.8 × 105
Ans. pH = 6.39
1 1
Sol. pH = (pKw + pKa – pKb) = [14 + 3.4814 – 4.7447] = 6.368.
2 2
PAGE NO.-50
17. Match the column :
Column I Column I I
0.1 M NaHCO3 solution (Ka1 = 5 × 10–7 & % Dissociation of H2O is less than 1.8 × 10–
(A) (p)
Ka2 = 5 × 10–11 for H2CO3) 7 %.
pH of the solution remains unaffected upon

(B) 5 × 10–4 M HCOOH solution (Ka = 5 × 10–4) (q)
doubling the volume of solution.
(C) 10–8 M HCl solution (r) pH of the solution is less than 7.
0.02 M CH3COONH4 solution
(D) (Ka = 1.8 × 10–5 for CH3COOH & Kb = 1.8 × (s) The electrolyte is almost 100% ionised.
10–5 for NH4OH)
LrEHk I LrEHk I I
0.1 M NaHCO3 foy;u (H2CO3 ds fy;s
(A) (p) H2O dk % fo;kstu 1.8 × 10–7 ls de gSA
Ka1 = 5 × 10–7 & Ka2 = 5 × 10–11)
5 × 10–4 M HCOOH foy;u foy;u dk vk;ru nksxquk djus ij foy;u dk pH
(B) (q)
(Ka = 5 × 10–4) vizHkkfor jgrk gSA
(C) 10–8 M HCl foy;u (r) foy;u dk pH, 7 ls de gSA
0.02 M CH3COONH4 foy;u
(D) (CH3COOH ds fy;s Ka = 1.8 × 10–5 & (s) fo|qr vi?kV~; 100% fo;ksftr gksrk gSA
(NH4OH ds fy;s Kb = 1.8 × 10–5 )
Ans. (A) - (p, q, s) ; (B) - (p, r) ; (C) - (p, r, s) ; (D) - (q, s)
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
ANSWER KEY
1. (A) 2. (D) 3. (B) 4. (A) 5. (B)
6. (B) 7. (D) 8. (A) 9. (D) 10.* (BCD)
11.* (ABC) 12.* (ABC) 13.* (BCD) 14.* (ABC) 15. 1
16. 2 17. 7 18. 10 19. 28
20. (A – r ; B – s ; C – p ; D – q, r)
1. What is the pH of the solution at half neutralization in the titration of 0.1 N CH3COOH solution by 0.5 M
KOH solution : (Ka of CH3COOH = 1.8  10–5)
(A*) 4.74 (B) 9.26 (C) 4.26 (D) None of these
PAGE NO.-51
0.1 N CH3COOH foy;u ds 0.05 M KOH foy;u ds lkFk vuqekiu esa v)Z mnklhuhdj.k ij foy;u dh pH D;k
gS : ( CH3COOH dk Ka = 1.8  10–5)
(A*) 4.74 (B) 9.26 (C) 4.26 (D) buesa ls dksbZ ugha
Sol. pH = pKa = 4.75
+
2. The neutralisation of a strong acid by a strong base liberates an amount of energy per mole of H that-
(A) Depends upon which acid and base are involved.
(B) Depends upon the temperature at which the reaction takes place.
(C) Depends upon which catalyst is used.
(D*) Is always the same.
izcy vEy dk izcy {kkj }kjk mnklhuhdj.k djus ij H+ ds izfr eksy mRiUu ÅtkZ dh ek=kk&
(A) fuHkZj djrk gS fd dkSulk vEy rFkk {kkj mi;ksx fd;k x;kA
(B) fuHkZj djrk gS fd fdl rki ij vfHkfØ;k dh xbZ
(C) fuHkZj djrk gS fd dkSulk mRizsjd iz;ksx fd;k x;k
(D*) ges'kk leku jgrh gSA
3. The solubility of sparingly soluble electrolyte MmAa (producing Ma+ & Am– ions in aqueous solution) in
water is given by the expression :
vYi foys;h fo|qr vi?kV~; MmAa (tyh; foy;u esa Ma+ o Am– vk;u cukrk gS) dh ty esa foys;rk fdl O;atd
ds }kjk nh tkrh gS %
ma 1/ m  a ma 1/ m  a
 K sp   K sp   K sp   K sp 
(A) s =  m a  (B*) s =  m a  (C) s =  a m  (D) s =  a m 
m a  m a  m a  m a 
4. A particular saturated solution of silver chromate, Ag2CrO4, has [Ag+] = 5 × 10–5 M and [CrO42–] = 4.4 ×
10–4 M. What is value of Ksp for Ag2CrO4 ?
flYoj ØksesV] Ag2CrO4 ds fuf'pr larÌr foy;u esa [Ag+] = 5 × 10–5 M rFkk [CrO42–] = 4.4 × 10–4 M gSaA
Ag2CrO4 ds fy, Ksp dk eku D;k gS \
(A*) 1.1 × 10–12 (B) 2.2 × 10–8 (C) 9.68 × 10–12 (D) 4.4 × 10–12
5. If the solubility of Ag2SO4 in 10–2 M Na2SO4 solution be 2 × 10–8 M, then Ksp of Ag2SO4 will be :
;fn 10–2 M Na2SO4 foy;u esa Ag2SO4 dh foys;rk 2 × 10–8 M gS] rc Ag2SO4 dk Ksp fuEu gksxk %
(A) 32 × 10–24 (B*) 16 × 10–18 (C) 32 × 10–18 (D) 16 × 10–24
Sol. Ag2SO4 +
2Ag + SO4 –2
2s' (s' + 10–2)  0–2

Ksp = (2s')2 (10–2) = (2 × 2 × 10–8)2 (10–2) = 16 × 10–18
6. A student wants to prepare a saturated solution containing Ag + ion. He has got three salts : AgCl (K sp =
10 10), AgBr (Ksp = 1.6 × 10 13) and Ag2CrO4 (Ksp = 3.2 × 10 11). Which of the above compounds will
be used by him in minimum weight to prepare 1 L of saturated solution ?
,d fo|kFkhZ Ag+ vk;u ;qDr ,d larÌr foy;u rS;kj djuk pkgrk gSA mlds ikl rhu yo.k AgCl (Ksp = 10 10),
AgBr (Ksp = 1.6 × 10 13) rFkk Ag2CrO4 (Ksp = 3.2 × 10 11) gSaA larÌr foy;u ds 1 yhVj dks rS;kj djus ds
fy,] U;wure nzO;eku dk mi;ksx djrs gq, ml fo|kFkhZ dks fdl ;kSfxd dks dke esa ysuk pkfg, \
(A) AgCl (B*) AgBr
(C) Ag2 CrO4 (D) any of the above mijksDr esa ls dksbZ Hkh
7. 2Pb(NO3)2(s) 2PbO(s) + 4NO2(g) + O2(g), H > 0
Above equilibrium is established by taking some amount of Pb(NO 3)2 (s) in a closed container at 1600
K. Then which of the following is the INCORRECT option :
(A) Moles of PbO(s) will increase with the increase in temperature.
(B) If two moles of Ne gas is added at constant pressure, then the moles of PbO(s) will increase.
(C) If the volume of the container is halved, partial pressure of O 2(g) at new equilibrium will remain
same.
(D*) If the volume of the container is doubled at equilibrium, then partial pressure of NO 2(g) will change
at new equilibrium.
2Pb(NO3)2(s) 2PbO(s) + 4NO2(g) + O2(g), H > 0
mijksDr lkE; Pb(NO3)2 (s) dh dqN ek=kk dks ,d can ik=k esa 1600 K ij ysus ij izkIr gksrk gSA rc fuEu esa ls
dkSulk dFku xyr gS %
PAGE NO.-52
(A) PbO(s) ds eksy] rki ds c<+us ds lkFk c<+rs gSaA
(B) ;fn Ne xSl ds nks eksy fu;r nkc ij feyk nsa] rc PbO(s) ds eksy c<+ tk;saxsA
(C) ;fn ik=k dk vk;ru vk/kk dj nsa] rks u;s lkE; ij O2(g) dk vkaf'kd nkc leku jgsxkA
(D*) ;fn lkE; ij ik=k ds vk;ru ds nqxquk dj nsa] rc u;s lkE; ij NO2(g) dk vkaf'kd nkc cny tk;sxkA
Sol. (A) As reaction is endothermic therefore it will go in the forward direction hence moles of PbO will
increase.
(B) With the increase or decrease of volume partial pressure of the gases will remain same.
(C) Due to the addition of inert gas at constant pressure reaction will proceed in the direction in which
more number of gaseous moles are formed.
Sol. (A) tSlk fd vfHkfØ;k Å"ek'kks"kh gS ftlls ;g vxz fn'kk esa gksxh blfy, PbO ds eksyksa esa o`f) gksxhA
(B) vk;ru ds ?kVus ;k c<+us ds lkFk xSl dk vkaf'kd nkc leku jgrk gSA
(C) vfHkfØ;k esa fu;r nkc ij vfØ; xSl feykus ds dkj.k vfHkfØ;k ml fn'kk esa gksrh gS tgka xSl ds eksyksa dh
la[;k T;knk gksrh gSA
8. q, W, E and H for the following process ABCD on an ideal monoatomic gas are :
,d vkn'kZ ,dyijek.oh; xSl ij fuEu izØe ABCD ds fy, q, W, E rFkk H Øe'k% fuEu gSa %
(A*) W = – 2 P0 V0 ln 2, q = 2 P0 V0 ln 2,  E = 0, H = 0
(B) W = – P0 V0 ln 2, q = P0 V0 ln 2,   E = 0,   H = 0
–10
(C) W = – 2 P0 V0 ln 2, q = 0,   E = – 2 P0 V0 ln 2,  H = P0 V0 ln 2
3
1 – Po Vo – 5Po Vo
(D) W = – 2 P0 V0 ( + ln 2), q = 2 P0 V0 ln 2,  E = ,  H =
4 2 6
Sol. At A and D the temperatures of the gas will be equal, so
A o B ij xSl dk rki cjkcj gksxkA vr %
E = 0, H = 0
Now vc w = W AB + W BC + W CD = – P0 V0 – 2P0 V0 ln 2 + P0 V0 = – 2P0 V0 ln 2
and rFkk q = – W = 2 P0 V0 ln 2
9. Calculate [H+], [HCOO–] and [OCN–] in a solution that contains 0.1M HCOOH (Ka = 2.4 x 104) and 0.1
M HOCN (Ka = 4 × 104).
0.1M HCOOH (Ka = 2.4 x 10-4) rFkk 0.1 M HOCN (Ka = 4 × 104) ;qDr foy;u eas [H+], [HCOO–] rFkk
[OCN–] dh x.kuk dhft,A
(A) [H+] = (0.1 2.4  104 )  (0.1 4  104 ) 8 × 10–3 M
(B) [HCOO–] = 3 × 10–3 M
(C) [OCN–] = 5 × 10–3 M
(D*) All of these mijksDr lHkh
Sol. [H+] = = 8 × 10–3 M
[H ][HCOO  ]
for HCOOH, Ka = 2.4 × 10–4 =
[HCOOH]
 [HCOO¯] = 3 × 10 M –3
[H ][OCN  ]
for HOCN, Ka = 4 × 10–4 =
[HOCN]
 [OCN¯] = 5 × 10 M–3
10.* The graph given below shows the P-V plot for a process on an ideal gas. Select the incorrect
statement:
PAGE NO.-53
uhps fn;k x;k vkjs[k] ,d vkn'kZ xSl ij ,d izØe ds fy, P-V vkjs[k dks n'kkZrk gSA lgh xyr dk pquko dhft;s%
(A) Enthalpy content of the gas is constantly increasing and the process is carried out slowly.
xSl ds ,UFkSYih in esa fu;r :i ls o`f) gksrh gS rFkk izØe /khjs&/khjs lEiUu gksrk gSA
(B*) Enthalpy content of the gas first increases, then decreases and the process is carried out
quasistaticly.
xSl ds ,UFkSYih in esa igys o`f) rFkk fQj deh gksrh gS rFkk izØe fLFkj&LFkSfrd (quasistaticly) :i ls
lEiUu gksrk gSA
(C*) Enthalpy content of the gas is constant and the process takes infinite time for completion.
xSl dk ,UFkSYih in fu;r jgrk gS rFkk izØe] iw.kZ gksus ds fy, vuUr le; yxkrk gSA
(D*) Enthalpy content first decreases, then increases and the process is reversible.
xSl ds ,UFkSYih in esa igys deh rFkk fQj o`f) gksrh gS rFkk izØe mRØe.kh; gSA
Sol. The product PV is increasing so temperature will keep or increasing in the process, hence H = E +
(PV) will increase constantly
mRikn PV c<+rk gS vr% izØe esa rkieku leku jgsxk ;k c<+sxkA vr% H = E + (PV) fu;r :i ls c<+sxkA
11.* Which of the following statements is/are incorrect at 25°C :
(A*) pKa for H3O+ is 15.74 (B*) Percentage dissociation of water is 1.8 × 10–9 %
(C*) pKa + pKb = pKw for HCl & ClOH (D) pKb for OH– is – 1.74
fuEu esa dkSulk dFku 25ºC ij lR; ugha gS %
(A) H3O+ dk pKa eku 15.74 gksrk gSA (B) ty ds vk;uu dh çfr'krrk 1.8 × 10–9 % gksrh gSA
(C) HCl ,oa ClOH ds fy;s, pKa + pKb = pKw gksxkA (D*) OH– dk pKb eku – 1.74 gksrk gSA
Sol. pKa (H3O+) = –1.74 = pKb of OH–
pKa + pKb = 14 only for conjugate acid base pair.
 = 1.8 × 10–9 or 1.8 × 10–7 % for H2O.
Sol. pKa (H3O ) = –1.74 = OH– dk pKb
+
pKa + pKb = 14 dsoy la;qXeh vEy {kkj ;qXe ds fy,

 = 1.8 × 10–9 vFkok H2O ds fy, 1.8 × 10–7 %
12.* Choose the correct statements :
(A*) pH + pOH = pKW is applicable for dilute acid and dilute base aqueous solutions, as well as for pure
water.
(B*) In acidic/basic aqueous solutions at 25°C, degree of dissociation of water is less than 1.8 × 10 –9.
(C*) No chemical reaction takes place when 0.1 mole of NaH 2PO2 and 0.1 mole of NaOH are mixed in
enough water to form 1 L solution.
(D) Relative acidic strength of HCl, HClO4, HBr and HI can be determined in water.
lgh dFku dk p;u dhft, %
(A*) pH + pOH = pkW dks ruq vEy rFkk ruq {kkj tyh; foy;u ds lkFk lkFk 'kq) ty ds fy, Hkh iz;qDr fd;k
tkrk gSA
(B*) 25°C ij vEyh;@{kkjh; tyh; foy;u esa] ty ds fo;kstu dh ek=kk 1.8 × 10–9 gSA
(C*) tc NaH2PO2 ds 0.1 eksy rFkk NaOH ds 0.1 eksy dks i;kZIr ty esa 1 L foy;u cukus ds fy, feyk;k tkrk
gSA rc fdlh izdkj dh jklk;fud vfHkfØ;k lEiUu ugha gksrh gSA
(D) HCl, HClO4, HBr rFkk HI dh vkisf{kd vEyh; lkeF;Zrk dks ty esa fu/kkZfjr fd;k tk ldrk gSA
Sol. (A) Correct statement
(B) Due to common ion effect on H2O H+ + OH–
PAGE NO.-54
(D) relative strength of strong acids can not be determined in water due to levelling effect.
gy. (A) dFku lgh gSA
(B) H2O 0H+ + OH– ij levk;u izHkko ds dkj.k
(D) levk;uu izHkko (levelling effect) ds dkj.k ty esa] izcy vEyksa ds vkisf{kd lkeF;Zrk dk fu/kkZj.k ugha fd;k
tkrk gSA
13.* When 0.1 mole of NH3 is dissolved in sufficient water to make 1 L of solution, the solution is found to
have a hydroxide ion concentration of 1.2 x 103 M. Then :
(A) pH of the solution is 2.92.
(B*) pH of the solution after 0.1 mole of NaOH is added to it is 13.
(C*) Kb for ammonia is 1.44 × 10–5.
(D*) NaOH added to the solution decreases the extent of dissociation of ammonia.
tc 0.1 eksy NH3 dks i;kZIr ek=kk esa ty esa feykdj 1 yhVj dk foy;u cuk;k tkrk gS] rks bl foy;u esa
gkbMªkWDlkbM vk;uksa dh lkUnzrk 1.2 x 103 M ik;h tkrh gSA rc %
(A) foy;u dh pH = 2.92 gSA
(B) 0.1 eksy NaOH dks blesa feykus ij foy;u dh pH = 13 gksxhA
(C) veksfu;k ds fy, Kb dk eku 1.44 × 10–5 gksxkA
(D) foy;u esa NaOH feyk;s tkus ij veksfu;k ds fo;kstu dh ek=kk ?kV tkrh gSA
Ans. (a) pH = 11.08 (b) pH = 13 (c) Kb = 1.44 × 105 (d) will suppress it. ;g bls
vo:) djsxkA
14.* 100 ml of 0.5M hydrazoic acid (HN3, Ka = 3.6 x 104) and 400ml of 0.1M cyanic acid (HOCN, Ka = 8 x
104) are mixed. Which of the following options is (are) true for the final solution :
0.5M gkbMªstksbd vEy (HN3, Ka = 3.6 x 104) ds 100 ml rFkk 0.1M lk;fud vEy (HOCN, Ka = 8 x 104) ds
400 ml dks fefJr fd;k x;kA vfUre foy;u ds fy, fuEu esa ls dkSulk@dkSuls fodYi lR; gS@gSa %
(A*) [H+] = 102 M (B*) [N3] = 3.6 x 103 M
 3
(C*) [OCN ] = 6.4 x 10 M (D) [H+] = 1.4 x 102 M
 0.5   0.1 
Sol. Total [H+] = K a1C1  K a2C2 =  3.6  104   100   8  104   400
 500   500 
 [H+] = 10–2 M.
K a [HN3 ] 3.6  104  0.5
For HN3, [N3–] = =  100 = 3.6 × 10–3 M.
[H ] 0.01  500
K a [HOCN] 8  10 4  0.1  400
For HOCN, [OCN–] = = = 6.4 × 10–3 M.
[H ] 0.01  500
dqy [H+] = K a1C1  K a2C2 =  3.6  104    

0.5 0.1
Sol.  100   8  104   400
 500   500 
 [H+] = 10–2 M.
K [HN ] 3.6  104  0.5
HN3 ds fy,, [N3–] = a  3 =  100 = 3.6 × 10–3 M.
[H ] 0.01  500
HOCN ds fy,, [OCN–] = = = 6.4 × 10–3 M
15. Solution A contains 0.10 M H2S. Solution B contains 0.10 M H2S and 0.25 M HCl. Calculate the ratios
of concentration of [HS] (p) and [S2] (q) ions in the two solutions. For H2S :
K a1 = 1.0 ×10–7, K a2 =1.3 × 10–13.
Report your answer as p2/q.
foy;u A, 0.10 M H2S j[krk gSA foy;u B, 0.10 M H2S rFkk 0.25 M HCl j[krk gSA foy;uksa esa [HS rFkk
[S 2] vk;u dh lkUnzrk ds vuqikr ¼Øe'k% p o q½ dh x.kuk dhft;sA H2S ds fy, K a = 1.0 ×10–7 rFkk K a =
1 2
1.3 × 10–13.
viuk mÙkj p2/q ds :i esa nhft;sA
Ans. 1
Sol. H2S H+ + HS– .....(i)
PAGE NO.-55
0.1 – x 0.25 x
HS– H+ + S– .....(ii)
x–y 0.25 y
HCl  H+ + Cl– .....(iii)
0.25
0.25  [HS – ]
(i) 10–7 = [HS–] = 4 × 10–8.
0.1– x
0.25  [S2 ]
(ii) 1.3 × 10–13 = [S2–] = 2.08 × 10–20.
4  10–8 – y
16. Saccharin (Ka = 2  1012) is a weak acid represented by formula HSac. A 4 × 104 mole amount of
saccharin is dissolved in a 200 cm 3 solution of pH = 3. Assuming no change in volume, calculate the
concentration of Sac ions in the resulting solution at equilibrium.
If [Sac–] = z × Ka, report your answer as z.
lSdsfju (Ka = 2  1012) ,d nqcZy vEy gS] ftldks HSac lw=k }kjk çnf'kZr djrs gSaA lSdsfju dh 4 × 10 4 eksy
ek=kk dks 200 cm3 foy;u esa foy; fd;k tkrk gS] ftldk pH 3 gSA ;g ekudj fd vk;ru esa dksbZ ifjorZu ugha
gksrk gS] lkE;koLFkk ij ifj.kkehs foy;u esa Sac vk;u dh lkUnzrk dh x.kuk dhft,A
;fn [Sac–] = z × Ka gS, rks viuk mRrj z ds :i esa nhft,A
Ans. 2
Sol. Calculation of [H+] and [HSac] at start
izkjEHk esa [H+] o [HSac] dk ifjdyu
4  10 4  1000
[HSac] = = 0.002 M
200
The dissociation of HSac is as below
HSac dk fo;kstu fuEu izdkj gksrk gS&
HSac H+ + Sac–
At start 0.002 0.001 0
izkjEHk esa
At equi. 0.002-x 0.001 + x x
lkE; ij
[H ][Sac  ] (0.01  x)x
 Ka = = = 2 ×10–12
[HSac] 0.002  x
x = 4 ×10–12 M
[Sac–]equi. = 4 ×10–12 M.
17. Find the concentration of H+ ions in an aqueous solution which is saturated with H2S (0.1 M) as well as
H2CO3 (0.2 M). If [H+] = p × 10–q M, report your answer as (p + q).
Given : Ka1 = 10–7, Ka2 = 10–14 for H2S ; Ka1 = 4 × 10–7, Ka2 = 4 × 10–11 for H2CO3.
H2S (0.1 M) ds lkFk&lkFk H2CO3 (0.2 M) ds lkFk Hkh larÌr tyh; foy;u esa H+ dh lkUnzrk Kkr dhft;sA
fn;k gS % [H2S ds fy, K1 = 10–7, K2 = 10–14 ; H2CO3 ds fy, K1 = 4 × 10–7, K2 = 4 × 10–11] :
Ans. 7
Sol. [H+] = K1C1  K 2C2 = 107  0.1  4  107  0.2 = 3 × 10–4 M
18. At 25ºC, the dissociation constants of CH3COOH and NH4OH in an aqueous solution are almost the
same. Calculate the pH of a solution of 0.01 N CH3COOH is 4 at 25ºC. The pH of 0.01 N NH4OH
solution at the same temperature .
25ºC ij ,d tyh; foy;u esa CH3COOH rFkk NH4OH ds fo;kstu fLFkjkad dk eku yxHkx leku gSSA 25ºC ij
0.01N CH3COOH ds foy;u dh pH 4 gSA leku rki ij 0.01 N NH4OH foy;u dh pH D;k gksxh \
Ans. 10
19. Calculate the hydrogen ion concentration (in mol/dm 3) in a solution containing 0.04 mole of acetic acid
and 0.05 mole of sodium acetate in 500 mL of solution. Dissociation constant for acetic acid is 1.75 
105.
PAGE NO.-56
Report your answer after multiplying by 2 × 106.
0.04 eksy ,flfVd vEy rFkk 0.05 eksy lksfM;e ,lhVsV ;qDr ,d 500 mL foy;u esa gkbMªkstu vk;u lkUnzrk dh
x.kuk (mol/dm3esa) dhft,A ,flfVd vEy ds fy, fo;kstu fLFkjkad = 1.75  10 5 gSA
viuk mRrj] 2 × 106 ls xq.kk djds nhft,A
Ans. 28
20. Match the following :
Column I Column I I
(A) 2 m solution of CaBr2 having density 1.4 g/mL (p) mole fraction of solute is 0.2.
3 M, 100 mL H2SO4 solution is mixed with 1 M, 300
(B) (q) mass of the solute is 160 g.
mL H2SO4 solution.
(C) 3.205 m solution of I2 solute in C6H6 solvent. (r) molarity of solution = 2 M
In 1.5 M, 2 litre solution of NaOH, 40 g NaOH is
(D) (s) molarity of solution = 1.5 M
dissolved.
fuEu dks lqesfyr dhft, %
LrEHk I LrEHk I I
(A) CaBr2 dk 2 m foy;u ¼?kuRo 1.4 g/mL) (p) foys; dk eksy izHkkt 0.2 gSA
3 M, 100 ml H2SO4 dks 1 M, 300 mL
(B) (q) foys; dk nzO;eku 160 g gSA
H2SO4 foy;u ds lkFk feykrs gSaA
3.205 m solution of I2 solute in C6H6
(C) (r) foy;u dh eksyjrk = 2 M
solvent.
In 1.5 M, 2 litre solution of NaOH, 40 g
(D) (s) foy;u dh eksyjrk = 1.5 M
NaOH is dissolved.
Ans. (A – r ; B – s ; C – p ; D – q, r)
Sol. (A) 4.5 m, CaCO3 means
4.5 moles of CaCO3 is present in 1000 g solvent.
mass of solute = 4.5 × 100 = 450 g
mass of solvent = 1000 g.
mass of solution = 1450 g.
Hence molarity = 4.5 M
3  100  1  300 3 14.5
(B) Resultant molarity = = = 1.5 M (C) mole fraction = = 0.2
400 2 14.5  55.5
(D) moles of NaOH in 2 L = 4 × 2 = 8 mole
40
moles of NaOH added = = 1 mole.
40
9
 Molarity = = 4.5 M  mass of NaOH = 9 × 40 = 360 g.
2
(A) 4.5 m, CaCO3 dk vFkZ
4.5 eksy CaCO3 1000 g foyk;d esa mifLFkr gS
foy; dk æO;eku = 4.5 × 100 = 450 g
foyk;d dk æO;eku = 1000 g.
foy;u dk æO;eku = 1450 g.
vr% eksyjrk = 4.5 M
3  100  1  300 3 14.5
(B) ifj.kkeh eksyjrk = = = 1.5 M (C) eksy izHkkt = = 0.2
400 2 14.5  55.5
(D) 2 yhVj esa NaOH ds eksy = 4 × 2 = 8 mole
40
feyk;s x;s NaOH ds eksy = = 1 mole.
40
9
 eksyjrk = = 4.5 M  NaOH dk æO;eku = 9 × 40 = 360 g.
2
PAGE NO.-57
P / I-CHEMISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :

Comprehension ('–1' negative marking) Q.7 to Q.9 (3 marks, 2 min.) [09, 06]
ANSWER KEY
1. (C) 2. (D) 3. (A) 4.* (ABC) 5.* (AD)
6.* (ABC) 7. (D) 8. (A) 9. (B) 10. 5
11. 3 12. 5 13. 3 14. 15 15. 5
16. (A) q,s,t ; (B) p,q,t ; (C) p,r ; (D) q,s; (E) - t
1. Calculate (i) [H+] and (ii) [PO43–] in a 0.15 M solution of phosphoric acid, H 3PO4. Given that for H3PO4 :
Ka1 = 7.5 × 10–3, Ka2 = 6.2 × 10–8, Ka3 = 3.6 × 10–13.
(A) [H+] = 0.03 M (B) [PO43–] = 7.44 × 10–19 M (C*) Both (A) and (B) (D) None of these
0.15 M QkWLQksfjd vEy (H3PO4) ds foy;u esa (i) [H+] rFkk (ii) [PO43–] dh x.kuk dhft;sA H3PO4 ds fy,
K1 = 7.5 × 10–3, K2 = 6.2 × 10–8, K3 = 3.6 × 10–13.
(A) [H+] = 0.03 M (B) [PO43–] = 7.44 × 10–19 M (C*) (A) o (B) nksuksa (D) buesa ls dksbZ ugha
2. Find the concentration of H+, HCO3 & CO32 in a solution, which is 0.01 M wrt H2CO3 and may
contain some other non-reactive solute also. pH of this solution is 2.74.
Given : Ka(H2CO3) = 4  10 –7 ; Ka (HCO3) = 4.8  10 –11 .
,d foy;u tks H2CO3 ds lkis{k 0.01 M gS rFkk dksbZ vU; vfØ; foys; Hkh j[k ldrk gS] esa H+ , HCO3 rFkk
CO32 dh lkUnzrk,¡ Kkr dhft,A bl foy;u dh pH 2.74 gSA
fn;k x;k gS : Ka(H2CO3) = 4  10 –7 ; Ka (HCO3) = 4.8  10 –11 .
(A) [H+] = 1.8 × 10–3 M (B) [HCO3–] = 2.22 × 10–6 M
(C) [CO32–] = 6 × 10–14 M (D*) All of these mijksDr lHkh
[HPO2–
4 ]
3. The pH of blood is 7.4. What is the ratio of in the blood ? Given : Ka1, Ka2 and Ka3 for H3PO4
[H2PO4– ]
are
10–3, 8 × 10–8 and 10–12 respectively.
[HPO2–4 ]
jDr dh pH 7.4 gSA jDr esa dk vuqikr D;k gS \ fn;k gS : H3PO4 ds fy;s Ka1, Ka2 o Ka3Øe'k%
[H2PO4– ]
10–3, 8 × 10–8 o 10–12 gSaA
(A*) 2 : 1 (B) 1 : 2 (C) 3 : 1 (D) 1 : 3
PAGE NO.-58
Sol. H2PO4– HPO42– + H+ .
 HPO4 
2–  HPO2–  2
8 × 10–8 =  –
× 4 × 10–8.  
4
–
=
 H2PO 4   H2PO 4  1
4.* Two gas samples are separated by a conducting frictionless piston as shown in the figure :
If the piston is in equilibrium in the position shown. Then which of the following statement is/are correct :
gas A gas B
(A*) TA = TB
(B*) PA = PB
(C*) nB = 3nA
(D) Total Translational K.E. of Gas A = 3 × Total Translational K.E. of gas B
fp=k esa n'kkZ;s vuqlkj nks xSl uewuksa dks pkyd ?k"kZ.kjfgr fiLVu (conducting frictionless piston) }kjk i`Fkd
djrs gSA ;fn n'kkZ;h xbZ fLFkfr es fiLVu lkE;koLFkk esa gSaA rc fuEu esa ls dkSulk dFku xyr gS %&
(A*) TA = TB (B*) PA = PB
(C*) nB = 3nA (D) xSl A dh dqy xfrt ÅtkZ = 3× xSl B dh dqy xfrt ÅtkZ
Sol. Since system is conducting frictionless
Hence TA = TB and PA = PB
Since volume is different hence nB = 3nA.
Sol. pawfd fudk; pkyd rFkk ?k"kZ.kjfgr gSA
vr% TA = TB o PA = PB
pwafd vk;ru fHkUu gS vr% nB = 3nA
5.* When 0.1 mole arsenic acid (H3AsO4) is dissolved in a 1L buffer solution of pH = 8. Which of the
following options is/are correct ? For arsenic acid : Ka1 = 2.5 × 104, Ka2 = 5 × 108, Ka3 = 2 × 1013. [‘<<’
sign denotes that the high concentration is at least more than 100 times the lower one]
tc pH = 8 okys ,d cQj foy;u ds 1 L esa 0.1 eksy vklsZfud vEy (H3AsO4) ?kksyk tkrk gS] rks fuEu esa ls
dkSulk¼ls½ fodYi lgh gS¼gSa½ \ vklsZfud vEy ds fy, Ka1 = 2.5 × 104, Ka2 = 5 × 108, Ka3 = 2 × 1013 [‘<<’
fpUg crkrk gS fd mPp lkUnzrk] fuEu lkUnzrk ls de ls de 100 xquk vf/kd gS]
(A*) [H3AsO4] << [H2AsO4] (B) [H2AsO4] << [HAsO42]
2 
(C) [HAsO4 ] << [H2AsO4 ] (D*) [AsO43] << [HAsO42]
 8
[H3 AsO 4 ] [H ] 10 1
Sol. (A) = = =  [H3AsO4] << [H3AsO4–].
[H2 AsO 4  ] K1 2.5  10 4 25000
[H2 AsO4  ] [H ] 10 8 1
(B) 2
= = 8
=
[HAsO4 ] K2 5  10 5
[AsO43  ] K3 2  10 13 1
(C) = = =  [AsO43–] << [HAsO42–].
[HAsO42 ] [H ] 10 8
50000
6.* Hydrazine, N2H4, can interact with water in two stages.
N2H4(aq) + H2O(l) N2H5+ (aq) + OH–(aq) Kb1 = 8.1 × 10–7
+
N2H5 (aq) + H2O (l) 2+
N2H6 (aq) + OH (aq) – Kb2 = 9 × 10–16
What are the concentrations of OH–, N2H5+ & N2H62+ and also pH value in a 0.01 M aqueous solution of
hydrazine?
gkbMªsthu N2H4, ty ds lkFk nks inkssa esa fØ;k djrk gSA
N2H4(aq) + H2O(l) N2H5+ (aq) + OH–(aq) Kb1 = 8.1 × 10–7
+
N2H5 (aq) + H2O (l) 2+
N2H6 (aq) + OH (aq) – Kb2 = 9 × 10–16
gkbMªsthu ds 0.01 M tyh; foy;u esa OH , N2H5 o N2H6 dh lkUnzrk,¡ rFkk lkFk gh pH dk eku D;k gS \
– + 2+
(A*) [OH–] = 9 × 10–5 M (B*) [N2H5+] = 9 × 10–5 M (C*) [N2H62+] = 9 × 10–16 M (D) pH = 4.04
Sol. [OH–] = C1Kb1
PAGE NO.-59
[N2H5+] = C1Kb1 .
[N2H6+] = Kb2 .
Comprehension
50 mL, 0.1 M HCl solution is titrated against 0.1 M NaOH solution. Titration curve is as follows :
The suitable indicator for this titration can be selected on the following basis :
The steep section of the titration curve at the equivalence point must encompass an internal of pH
values at least as large as the pH transition range of an indicator. The pH transition range of the
indicator should most concide with the steep portion of the titration curve.
Details of some indicators are given below :
Indicator Colour change pH transition range
in acid form in basic form
Phenolphthalein Colourless Pink 8.3 to 10
Bromomethyl blue Orange Blue 6.0 to 8.0
Methyl orange Red Yellow 3.1 to 4.5

Now answer the following questions :]
vuqPNsn %
0.1 M HCl foy;u ds 50 mL dk vuqekiu 0.1 M NaOH foy;u ds lkFk fd;k tkrk gSA fuEu vuqekiu oØ izkIr
gksrk gS %
fuEu vk/kkj ij vuqekiu ds fy, mi;qDr lwpd dk p;u fd;k tkrk gS %
vuqekiu oØ esa] rqY;kad fcUnq ij vuqekiu oØ dk yEc Hkkx ] lwpd ds vf/kd ls vfèkd pH laØe.k ijkl dks
n'kkZrk gSA
lwpd dk pH laØ.ke ijkl] vuqekiu oØ ds yEc Hkkx ls vf/kdre lqesfyr gksuk pkfg,A
PAGE NO.-60
dqN lwpdksa dh tkudkfj;k¡ uhps nh xbZ gSa %

lwpd jax ifjorZu pH ¼ifjorZu½ laØe.k ijkl
vEy :Ik esa {kkj :Ik esa
fQuks¶Fksyhu jaxghu xqykch 8.3 to 10
czkseksesfFky CY;w ukjaxh uhyk 6.0 to 8.0
esfFky vkWjsUt yky ihyk 3.1 to 4.5
vc fuEu iz'uksa ds mÙkj nhft, %
7. Which of the following indicator can be used for this titration ?
(A) Phenophthalein (B) Bromomethyl blue (C) Methyl orange (D*) All of these
bl vuqekiu esa fdl lwpd dks ç;qDr fd;k tk ldrk gS \
(A) fQukW¶FkSyhu (B) czkseksesfFky CY;w (C) esfFky vkWjsUt (D*) mijksDr lHkh
8. At pH = 3, volume of NaOH solution used is (approximately) :
(A*) 49 mL (B) 50 mL (C) 45 mL (D) 41 mL
pH = 3 ij NaOH foy;u dk ç;qDr fd;k x;k vk;ru (yxHkx) fuEu gS %
(A*) 49 mL (B) 50 mL (C) 45 mL (D) 41 mL
9. 100 mL of 0.1 M NaOH solution is titrated with 100 mL of 0.05 M H2SO4 solution. The pH of the
resulting solution is : (For H2SO4, Ka1 = , Ka2 = 10–2 )
(A) 7 (B*) 7.2 (C) 7.4 (D) 6.8
0.1 M NaOH foy;u ds 100 mL dks 0.05 M H2SO4 foy;u ds 100 mL ds lkFk vuqekfir fd;k tkrk gSA
ifj.kkeh foy;u dh pH fuEu gS % (H2SO4 ds fy, Ka1 = , Ka2 = 10–2 )
(A) 7 (B*) 7.2 (C) 7.4 (D) 6.8Z
Sol. NaOH + H2SO4  NaHSO4 + H2O
initial m mole 10 5 0
izkjEHk esa m eksy
reaction 5 0 5
vfHkfØ;k NaOH + NaHSO4   Na2SO4 + H2O
5 5 0
0 0 5
1  5  1 1
pH = 7 + 2  log
2  
200 
=7+
2
 2  log5  log200 = 7 +
2
[2 + 0.7 – 0.3 – 2] = 7.2
PAGE NO.-61
10. 0.1 M solution of a weak acid HA is titrated against 0.05 N NaOH solution. Calculate pH at 1/4th and
3/4th neutralization of acid.Given that the pH of 0.1 M HA solution is 3.
pH1  pH2
Report your answer as .
2
,d nqcZy vEy HA ds 0.1 M foy;u dks 0.05 N NaOH foy;u ds fo:) vuqekfir fd;k tkrk gSA vEy ds 1/4th
rFkk 3/4th Lrj ij mnklhuhdj.k ds fy, pH dh x.kuk dhft,A fn;k gS fd 0.1 M HA foy;u dh pH 3 gSA
pH  pH2
viuk mÙkj 1 ds :i esa nsaA
2
Ans. 5
11. A solution of weak acid HA was titrated with NaOH solution. The end point is obtained by the addition of
36 mLof 0.1 N NaOH solution. Now 9 mL of 0.2 N HCl solution was added to titrated solution. The final
pH was found to be 4.5. Calculate Ka for the acid HA.
Report your answer after multiplying it by 105 and rounding it off to nearest whole number.
nqcZy vEy HA ds ,d foy;u dks NaOH ds lkFk vuqekfir djrs gSaA 0.1 N NaOH foy;u ds 36 mL dks feykus
ds i'pkr~ vfUre fcUnq izkIr gksrk gSA vc 0.2 N HCl foy;u ds 9 mL dks vuqekfir foy;u esa feyk;k tkrk gSA
rc vafre pH 4.5 izkIr gksrh gSA vEy HA ds fy, Ka dh x.kuk dhft,A
viuk mÙkj 105 ls xq.kk djds fudVre iw.kk±d ds :i esa nhft,A
Ans. 3
12. 25 mL of 0.1 M aqueous pyridine (K b = 1.6  109) solution is titrated with 0.1 M hydrochloric acid.
Calculate pH at equivalence point and after 35 cm3 hydrochloric acid solution has been added.
Report your answer as the sum of two pH values, rounding it off to the nearest whole number.
0.1 M tyh; fijhMhu ( Kb = 1.6  10 9) foy;u ds 25 mL dks 0.1 M gkbMªksDyksfjd vEy ds lkFk vuqekfir djrs
gaSA rqY;kad fcUnq rFkk 35 cm3 gkbMªksDyksfjd vEy dks feykus ds ckn Øe'k% pH dh x.kuk dhft,A
viuk mÙkj] nksukas pH ekuksa ds ;ksx ds :i esa fudVre iw.kk±d ds :i esa nhft,A
Ans. 5
13. The equivalence point in a titration of 40 mL of a solution of a weak monoprotic acid occurs when 32
mL of a 0.1 M NaOH solution has been added. The pH of the solution is 5.74 after addition of 20 mL of
above NaOH solution. What is Ka of the acid ?
Report your answer after multiplying it by 106.
,d nqcZy ,dyizksfVd vEy ds foy;u ds 40 mL ds vuqekiu esa] 0.1 M NaOH foy;u ds 32 mL dks feykus ij
rqY;kad fcUnq izkIr gksrk gSA NaOH foy;u ds 20 mL dks feykus ds i'pkr~ foy;u dk pH 5.74 gSA vEy dk Ka
D;k gS \
viuk mRrj 106 ls xq.kk djds nhft,A
Ans. 3
14. Calculate the volume (in mL) of 0.1 M Na2SO4 solution, which must be added to 10 mL of HCl solution
(pH = 1), so that pH of the resulting solution becomes 2. (Given : Ka2 for H2SO4 = 10–2 and Ka1 = )
0.1 M Na2SO4 dk og vk;ru (mLesa) ifjdfyr dhft,] ftls fd HCl (pH = 1) ds 10 mL esa feyk;s tkus ij
izkIr ifj.kkeh foy;u dh pH 2 gks tk;sA (fn;k x;k gS : [H2SO4 ds fy, Ka2 = 10–2 rFkk Ka1 = ]
Ans. 15
15. What is the [Cd2+] in mol/L in 1 L of solution prepared by dissolving 0.001 mole Cd(NO 3)2 & 2 mole
NH3?
Equilibrium constant Kd for the dissociation of Cd(NH3)42+ into Cd2+ & 4 NH3 is 2 x 107. Neglect any
other compound formation by Cd2+ ions.
Report your answer after multiplying by 4 × 1011.
0.001 eksy Cd(NO3)2 rFkk 2 eksy NH3 dks ?kksydj cuk;s x;s 1 yhVj foy;u esa [Cd2+], mol/L esa D;k gS \
Cd(NH3)42+ ds Cd2+ rFkk 4 NH3 esa fo;kstu ds fy, lkE; fLFkjkad Kd 2 x 107 gSA Cd2+ vk;u }kjk fdlh vU;
;kSfxd dks curk gqvk u ekusaA
viuk mÙkj 4 × 1011 ls xq.kk djds nhft,A
Ans. 5
PAGE NO.-62
16. Match the following :
Column I Column II
(A) NaHCO3 (aq.) (p) Significant cationic hydrolysis
(B) CH3COONH4 (aq.) (q) Significant anionic hydrolysis
(C) K2SO4. Al2(SO4)3.24H2O (aq.) (r) Acidic (pH < 7)
(D) NaCN (aq) (s) Basic (pH > 7)
(E) NaCl (aq.) (t) pH is independent of concentration
Given : Ka1 = 5 × 10–7, Ka2 = 5 × 10–11 for H2CO3

Ka(CH3COOH) = 1.8 × 10–5 ; Kb(NH4OH) = 1.8 × 10–5
fuEu dks lqesfyr dhft, %
dkWye-I dkWye-II
(A) NaHCO3 (aq.) (p) lkFkZd /kuk;fud ty-vi?kVu
(B) CH3COONH4 (aq.) (q) lkFkZd _.kk;fud ty-vi?kVu
(C) K2SO4. Al2(SO4)3.24H2O (aq.) (r) vEyh; (pH < 7)
(D) NaCN (aq) (s) {kkjh; (pH > 7)
(E) NaCl (aq.) (t) pH dk eku lkUnzrk ls Lora=k gSA
fn;k x;k gS : K1 = 5 × 10–7, K2 = 5 × 10–11 for H2CO3
K (CH3 COOH) = 1.8 × 10–5 , K (NH4OH) = 1.8 × 10–5
Ans. (A) q,s,t ; (B) p,q,t ; (C) p,r ; (D) q,s; (E) - t
P / I-CHEMISTRY


EST INFORM AT IO
DPP

ANSWER KEY
1. (B) 2. (C) 3. (A) 4. (A) 5.* (ABCD)
6.* (ABC) 7.* (CD) 8. 9 9. 0 10. 5
11. 38 12. 30 13. 50 14. 50
15. (A – s); (B – p, q); (C – q, s) ; (D – q, r)
1. 3 moles of ammonia are heated in presence of 1 mole of neon gas. At equilibrium the mole fraction of
hydrogen is found to be 0.5. The value of 'KC.V' (V – Volume of container) for the given reaction is :
1 3
NH3(g) N2(g) + H2(g)
2 2
3 eksy veksfu;k dks 1 eksy fuvkWu xSl dh mifLFkfr esa xeZ djrs gSaA lkE; ij gkbMªkstu dk eksy izHkkt 0.5 gSA nh
xbZ vfHkfØ;k ds fy, 'KC.V' dk eku Kkr djsa % (V – ik=k dk vk;ru)
1 3
NH3(g) N2(g) + H2(g)
2 2
PAGE NO.-63
(A) 27 3 (B*) 3 3 (C) 27 (D) 3 /8
1 3
Sol. NH3(g) N2(g) + H2(g) and 1 mole Ne
2 2
3
3x / 2 1
3-x x/2 3x/2 
4x 2
1 1 3 x=2
(3 / V)3 / 2 (1/ V)1/ 2
KC =   KC.V = 3 3 .
1/ V
2. A solution is saturated with respect to SrCO3 & SrF2. The [CO32] was found to be 1.2 x 103 M. The
concentration of F in the solution would be: Ksp (SrCO3) = 10–9, Ksp(SrF2) = 3 × 10–11.
,d foy;u SrCO3 rFkk SrF2 ds lkis{k larÌr gSA [CO32] 1.2 x 103 M ik;h x;hA foy;u esa F dh lkUnzrk D;k
gksxh% Ksp (SrCO3) = 10–9, Ksp(SrF2) = 3 × 10–11
(A) 3 x 103 M (B) 3.6 x 105 M (C*) 6 x 103 M (D) 6 x 102 M
3. Ksp of AgCl is 1.96 × 10–10. 100 mL of saturated AgCl solution is titrated with 1 × 10 –5 M NH4 SCN
solution. Minimum volume of NH4 SCN solution required to precipitate all Ag+ from saturated AgCl
solution as AgSCN is:
(A*) 140 mL (B) 14 mL (C) 1.4 L (D) None of these
AgCl dk Ksp 1.96 × 10 gSA larÌr AgCl foy;u ds 100 mL dks, 1 × 10–5 M NH4 SCN foy;u ds lkFk
–10
vuqekfir fd;k tkrk gSaA larÌr AgCl foy;u ls iw.kZ :i ls Ag+ dks AgSCN ds :i esa vD{ksfir djus ds fy,
NH4 SCN foy;u dk vko';d U;wure vk;ru fuEu gksxk %
(A*) 140 mL (B) 14 mL (C) 1.4 L (D) buesa ls dksbZ ugha
Sol. m.moles of Ag+ in 100 ml of saturated solution of AgCl = K sp × 100 = 1.4 × 10–3
Now Ag+ + SCN–  AgSCN (s)

–
m.moles of SCN = m.moles of Ag+
1 × 10–5 × V = 1.4 × 10–3    volume = 140 mL.
Sol. 100 ml AgCl ds larÌr foy;u esa Ag ds feyh eksy = K sp × 100 = 1.4 × 10–3
+
vc Ag+ + SCN–  AgSCN (s)

SCN– ds feyh eksy = Ag+ ds feyh eksy
1 × 10–5 × V = 1.4 × 10–3    vk;ru = 140 mL.
4. 0.2 millimoles of Zn2+ ion is mixed with (NH4)2 S solution of molarity 0.02 M. The amount of Zn2+ that
remains unprecipitated in 20 mL of this solution would be : (Given : KSP ZnS = 4 × 10–24)
Zn2+ vk;u ds 0.2 feyheksy dks 0.02 M eksyjrk ds (NH4)2 S foy;u ds lkFk fefJr fd;k x;k gSA bl foy;u ds
20 mL esa vu~vo{ksfir jgus okys Zn2+ dh ek=kk fuEu gksxh % (fn;k x;k gS : KSP ZnS = 4 × 10–24)
(A*) 5.2 × 10–22 g (B) 2.6 × 10–22 g (C) 1.04 × 10–21 g (D) 5.2 × 10–23 g
Sol. S 2– + Zn  ZnS (s)
2+
m.moles 0.4 0.2
0.2 –
so in solution,
0.2
[S2–] = = 0.01 M
20
K sp 4  10 24
 [Zn2+] = 2  = = 4 × 10–22 M
[S ] 0.01
4  10 24
 mass of Zn2+ remain unprecipitated in 20 ml of solution = × 20 × 65 = 5.2 × 10–22 gm.
1000
gy. S2– + Zn2+  ZnS (s)
feyh eksy 0.4 0.2
PAGE NO.-64
0.2 –
vr% foy;u esa]
0.2
[S2–] = = 0.01 M
20
K sp 4  10 24
 [Zn2+] = 2  = = 4 × 10–22 M
[S ] 0.01
4  10 24
 20 ml foy;u esa Zn2+ dk nzO;eku tks vo{ksfir ugha gksrk gS = × 20 × 65 = 5.2 × 10–22 gm.
1000
5.* If the amount given below is added in pure water, will all of the salt dissolve before equilibrium can be
established, or will some salt remain undissolved ?
(a) 4.96 mg of MgF2 in 125 mL of pure water, Ksp of MgF2 = 3.2 x 10–8
(b) 3.9 mg of CaF2 in 100 mL of pure water, Ksp of CaF2 = 4 x 10–12
Also find the percentage saturation in each case. Assume no hydrolysis of cation or anion.
(A*) MgF2 will completely dissolve (B*) MgF2 solution will have 32% saturation
(C*) CaF2 will not completely dissolve (D*) CaF2 solution will have 100% saturation
;fn uhps nh x;h ek=kk dks 'kq) ty esa feyk;k tkrk gS] rks D;k lkE;koLFkk vkus ls igys lkjk yo.k foys; gksxk ;k
dqN yo.k vfoys; jgsxk ?
(a) 125 mL 'kq) ty esa MgF2 ds 4.96 mg, MgF2 dk Ksp = 3.2 x 10–8
(b) 100 mL 'kq} ty esa CaF2 ds 3.9 mg, CaF2 dk Ksp = 4 x 10–12
izR;sd ifjfLFkfr esa larÌrrk dh izfr'kr Kkr dhft,A /kuk;u o _.kk;u dk ty vi?kVu u ekusaA
(A*) MgF2 iw.kZr% foys; gksxk (B*) MgF2 foy;u 32% larÌr gksxk
(C*) CaF2 iw.kZr% foys; ugha gksxk (D*) CaF2 foy;u 100% larÌr gksxk
6.* The solubility product for silver iodate AgIO3 is 1 x 108. If 0.1 g of solid AgIO3 is added to
100 mL of 0.02 M KIO3 solution, what are the concentrations of K+, IO3 & Ag+ at equilibrium?
flYoj vk;ksMsV AgIO3 ds fy, foys;rk xq.kuQy 1 x 108 gSA ;fn 0.1 g Bksl AgIO3 dks 0.02 M KIO3 ds 100
mL esa feyk;k tkrk gS] rks lkE;koLFkk ij K+, IO3 rFkk Ag+ dh lkUnzrk,¡ D;k gSa \
(A*) [Ag+] = 5 × 10–7 M (B*) [IO3–] = 2 × 10–2 M (C*) [K+] = 2 × 10–2 M (D) [IO3–] = 0.023 M
7.* When 0.01 mole HCl is added in 1 L of 0.01 M CH3COOH (Ka = 2 × 10–5) solution, then which statement
is wrong?
(A) Degree of dissociation of CH3COOH approaches zero.
(B) Change in pH by adding HCl would be 1.35.
(C*) On addition of HCl, Ka of CH3COOH decreases.
(D*) On addition of HCl, Ka of CH3COOH increases.
tc 0.01 eksy HCl dks 0.01 M tyh; CH3COOH (Ka = 2 × 10–5) ds 1 yhVj esa feyk;k tkrk gS] rc dkSulk
dFku xyr gS\
(A) CH3COOH ds fo;kstu dh ek=kk yxHkx 'kwU; gks tkrh gSA
(B) HCl feykus ij pH esa ifjorZu 1.35 gksxkA
(C*) HCl dks feykus ls CH3COOH ds Ka dk eku ?kV tkrk gSA
(D*) HCl dks feykus ls CH3COOH ds Ka dk eku c<+ tkrk gSA
1 1
Sol. Initial pH = (pKa – log C) = (5 – log 2 – log 0.01) = 3.35
2 2
After adding HCl, pH of solution = 2
Change in pH = 1.35
1 1
gy. izkjfEHkd pH = (pKa – log C) = (5 – log 2 – log 0.01) = 3.35
2 2
HCl feykus ds ckn, pH dk foy;u = 2
pH esa ifjorZu = 1.35
8. The number of completely filled orbitals in 29Cu which have atleast two nodes is/are :
29Cu esa de ls de nks uksM j[kus okys iw.kZiwfjr d{kdksa dh la[;k gS@gSa %
PAGE NO.-65
Ans. 9
Sol. 29Cu  1s2 2s2 2p6 3s2 3p6 3d10 4s1
Nodes 0 1 1 2 2 2 3 (but incompletely filled)
uksM ¼ysfdu viw.kZ Hkjk gksrk gSA½
Orbitals (d{kd) 1 3 5
So (vr%) 9.
9. (i) What pH of solution will reduce [S2–] ion to 4 × 10–18 M in a saturated (0.1 M) solution of H2S ?
(ii) What concentration of H 3O+ ions will reduce [HS–] ion to 2 × 10–6 M in a saturated (0.1 M) solution of
H2S?
Given : Ka1(H2S) = 1 × 10–7 , Ka2(H2S) = 10–14.
Report your answer as (pH + log [H3O+]).
(i) larÌr (0.1 M) H2S foy;u esa H3O+ vk;u dh fdl lkUnzrk ij] [S2–] vk;u dh lkUnzrk 4 × 10–18 M rd de
dh tk ldrh gS \
(ii) larÌr (0.1 M) H2S foy;u esa [H3O+] vk;u dh fdl lkUnzrk ij] [HS–] vk;u dh lkUnzrk 2 × 10–6 M rd de
dh tk ldrh gS \
K1(H2S) = 1 × 10–7 , K2(H2S) = 10–14.
viuk mÙkj (pH + log [H3O+]) ds :i esa nhft;sA
Ans. 0
10. Assume that 1.184 g of solid Ca(OH)2 are placed in 1 litre of pure water at 25ºC. The pH of the solution
is found to be 12. Estimate the Ksp for Ca(OH)2. Report your answer after multiplying by 107.
,slk ekusa fd 25ºC ij 'kq) ty ds 1 yhVj esa Bksl Ca(OH)2 ds 1.184 xzke j[ks tkrs gSaA foy;u dh pH 12 izkIr
gksrh gSA Ca(OH)2 ds fy, Ksp dh x.kuk dhft,A viuk mÙkj 107 ls xq.kk djds nhft,A
Ans. 5
11. If the solubility product of silver oxalate is 5 × 10–10, what will be the weight of salt (in gram) in 0.25 m 3
of a saturated solution ?
;fn flYoj vkWDlsysV dk foys;rk xq.kuQy 5 × 10–10 gS] rks ,d larÌr foy;u ds 0.25 m3 esa yo.k dk nzO;eku
¼xzke esa½ D;k gksxk \
Ans. 38
12. Calculate [F–] in a solution saturated with respect of both MgF 2 and SrF2. Assume no hydrolysis of
cation or anion.
Ksp(MgF2) = 9.5 x 10–9, Ksp(SrF2) = 4 x 10–9.
Report your answer after multiplying by 104.
MgF2 rFkk SrF2 nksukas ds lkis{k larÌr foy;u esa [F–] dh x.kuk dhft,A /kuk;u o _.kk;u dk ty vi?kVu u
ekusaA
Ksp(MgF2) = 9.5 x 10–9, Ksp(SrF2) = 4 x 10–9
viuk mÙkj 104 ls xq.kk djds nhft,A
Ans. 30
13. Determine the number of moles of AgI which may be dissolved in 1 L of 1 M CN solution. Ksp for AgI
and Kf for [Ag (CN)2] are 4 × 1017 M2 & 6.25 × 1017 respectively .
Report your answer after multiplying by 11.
1 M CN foy;u ds 1 L esa ?kksys tk ldus okys AgI ds eksykas dh la[;k Kkr dhft,A AgI ds fy, Ksp 4 × 1017
M2 rFkk [Ag (CN)2] ds fy, Kf 6.25 × 1017 gSA
viuk mÙkj 11 ls xq.kk djds nhft,A
Sol. 5
14. What is the maximum concentration (in M) of equimolar solutions of ferrous sulphate and sodium
sulphide so that when mixed in equal volumes, there is no precipitation of ferrous sulphide ? (For
ferroussulphide, Ksp = 6.25 × 10–18). Report your answer after multiplying it by 1010.
PAGE NO.-66
Qsjl lYQsV rFkk lksfM;e lYQkbM ds leeksyj foy;uksa dh lkUnzrk (M esa) vf/kdre D;k gks] fd bUgsa leku
vk;ru esa fefJr djus ij Qsjl lYQkbM dk vo{ksi izkIr ugha gksrk gks \ (Qsjl lYQkbM ds fy, Ksp = 6.25 ×
10–18) viuk mÙkj 1010 ls xq.kk djds nhft,A
Ans. 50
Sol. FeSO4 + Na2S  FeS + Na2SO4
a a
a a
KSP =     = 6.25 × 10–18
2 2
a = 4 × 6.25 × 10–18 = 4 × 625 × 10–20
2
a = 2 × 25 × 10–10 = 5 × 10–9 M
15. Match the following column :
Column I Column II
(A) AgBr (p) Solubility in water is more than expectation.
(B) AgCN (q) Solubility in acidic solution is more than that in pure water.
(C) Fe(OH)3 (r) Solubility in strongly basic solution is more than that in pure water.
(D) Zn(OH)2 (s) Solubility decreases in presence of common anion.
LrEHk I LrEHk II
(A) AgBr (p) ty esa vuqekfur ls vf/kd foys;rk gSA
(B) AgCN (q) vEyh; foy;u esa 'kq) ty dh rqyuk esa vf/kd foys;rk gSA
(C) Fe(OH)3 (r) izcy {kkjh; foy;u esa 'kq) ty dh rqyuk esa vfèkd foys;rk gSA
(D) Zn(OH)2 (s) le_.kk;u dh mifLFkfr esa foys;rk ?kVrh gSA
Ans. (A – s); (B – p, q); (C – q, s) ; (D – q, r)
Sol. (A) For AgBr, Ksp = [Ag+] [Br–]
so on increase in [Br–], solubility of AgBr decreases.
(B) For AgCN, Ksp = [Ag+] [CN–]
–
CN undergoes hydrolysis so solubility in water is more than expectation.
In acidic solution, CN– gets protonated so solubility of AgCN increases.
AgCN forms complex Ag(CN)2– with excess of CN–.
(C) For Fe(OH)3, Ksp = [Fe3+] [OH–]3.
In acidic solution OH– decreases so solubility increases.
Solubility decreases in presence of OH–.
(D) For Zn(OH)2, Ksp = [Zn2+] [OH–]2
Zn(OH)2 is amphoteric in nature so its solubility increases in both acidic as will as strongly basic
solution.
gy- (A) AgBr ds fy,, Ksp = [Ag+] [Br–]
vr% [Br–] dks c<+kus ij, AgBr dh foys;rk ?kVrh gSA
(B) AgCN ds fy,, Ksp = [Ag+] [CN–]
CN– dk tyvi?kVu gksrk gS blfy, ty esa bldh foys;rk vuqekfur foys;rk ls vf/kd gksrh gSA
vEyh; foy;u esa] CN– dk izksVksuhdj.k gksrk gS vr% AgCN dh foys;rk c<+rh gSA
AgCN, CN– ds vkf/kD; esa Ag(CN)2– dk ladqy cukrk gSA
(C) Fe(OH)3 ds fy,, Ksp = [Fe3+] [OH–]3.
vEyh; foy;u esa] OH– ?kVrs gS vr% foys;rk c<+rh gSA
OH– dh mifLFkfr esa foys;rk ?kVrh gSA
(D) Zn(OH)2 ds fy,, Ksp = [Zn2+] [OH–]2
Zn(OH)2 mHk;/kehZ gS blfy, bldh foys;rk vEyh; rFkk {kkjh; ek/;e esa c<+rh gSA
PAGE NO.-67

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DPPs BOOKLET-3 VIKAAS (JA) | CHEMISTRY

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C1

6. Statement-1 : T, P & V are state functions.

7. Which of the following is an intensive property ?

8. Thermodynamic equilibrium involves

10.* Which of the following is/are extensive properties ?

11.* Which of the following is/are thermodynamic function ?

12. Categorise the following into state and path functions :

13. Categorise these properties into extensive and intensive property :

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C2

15. tc ,d ra=k ¼fudk;½] fp=kkuqlkj] iFk 'acb' ds vuqlkj voLFkk&'a' ls voLFkk&'b' rd ys

or Qbda = – 60 – 30 = – 90 J Ans.

(A) A (p) Temperature is increasing

(C) (r) Volume is constant

(D) A (s) Pressure is increasing

fuEu dks lqesfyr dhft,&

(A) A (p) rkieku esa o`f) gksrh gSA

(C) (r) vk;ru fu;r g

(D) A (s) nkc esa o`f) gksrh gSA

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C3

9. In the balanced chemical reaction, O3– + a– + bH+ CH2O + d2

(A) Magnitude = 4L atm; work is done by the system.

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C4

(A) (B) (C) (D)

2. If a chemical reaction is non-spontaneous at high temperatures and spontaneous at low temperatures,

vuqPNsn # (13 to 15)

13. What is the value of H for the overall cyclic process :

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C5

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C6

(C) Li(aq )  Na(aq )  K (aq ) (D*) Both (A) & (B)

(C) Li(aq )  Na(aq )  K (aq ) (D*) (A) o (B) nksuksa

S2 : Ca2+ + Na2CO3  CaCO3 + 2Na+

(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2

(D) 2CsO2 + 2H2O  2Cs+ + 2OH– + H2O2 + O2

ChemINFO s-BLOCK ELEMENT

Reactions Charts (Quick Revision) :

+ Slaking with NaOH + Ca(OH)2

ChemINFO s-BLOCK ELEMENT

vfHkfØ;k pkVZ ¼'kh?kz iquZjkoyksdu½ :

NaOH foy;u NaOH + Ca(OH)2

18. Which hydrocarbon obtained by the hydrolysis of calcium carbide?

20. Which product will obtain when CaC2 react with N2 ?

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C7

1. BC3 is more stable than TC3 because :

4. From B2H6, all the following can be prepared except :

7.* Which of the following are correct

TARGET : JEE (Main + Advanced) 2022

Course : VIKAAS(JA) NO. C8

2. Select the correct statements

3. Moderate electrical conductivity is shown by :

6. The straight chain polymer is formed by :

9. Which of the following anions is present in the chain structure of silicates ?

10. Glass reacts with HF to produce

11. The oxide which is not a reducing agent is :

12.* Which of the following oxides are acidic :

TARGET : JEE (Main + Advanced) 2022