DPP 10 Jee Advanced Revision DPP B

TARGET : JEE (ADVANCED) 2016
Course : VIJETA & VIJAY (ADP & ADR) Date : 08-05-2016
DATE : 11.05.2016 PART TEST (PT)-5

Syllabus : Kinetic theory of gasses, Heat and thermodynamics


3. DPP Syllabus : KTG and thermodynamics + Miscellaneous

Total Total Marks : 137 Max. Time: 114½ min.
Single choice Objective (–1 negative marking) Q.1 to 12 (3 marks 2½ min.) [36, 30]
Multiple choice objective (–1 negative marking) Q. 13 to 17 (4 marks, 3 min.) [20, 15]
Single Digit Subjective Questions (–1 negative marking) Q.18 to Q.23 (3 marks 2½ min.) [18, 15]
Double Digits Subjective Questions (–1 negative marking) Q.24 to Q.26 (3 marks 2½ min.) [09, 7½]
Comprehension (–1 negative marking) Q.27 to 40 (3 marks 2½ min.) [42, 35]
Match Listing (–1 negative marking) Q.41 to Q.44 (3 marks, 3 min.) [12, 12]

ANSWER KEY OF DPP NO. # 10


1. (C) 2. (D) 3. (C) 4. (D) 5. (A) 6. (B) 7. (C)
8. (D) 9. (D) 10. (C) 11. (B) 12. (B) 13. (B)(C)
14. (A) (C)(D) 15. (B) (C) (D) 16. (A)(B)(C) 17. (A) (B) 18. 5
19. 5 20. 3 21. 7 22. 4 23. 2 24. 11 25. 14
26. 10 27. (A) 28. (C) 29. (A) 30. (C) 31. (A) 32. (C)
33. (D) 34. (B) 35. (B) 36. (A) 37. (D) 38. (C) 39. (A)
40. (C) 41. (B) 42. (C) 43. (D) 44. (B)
1. The ratio of translational and rotational kinetic energies at 100 K temperature is 3 : 2. Then the internal
energy of one mole of an ideal gas at that temperature is[R = 8.3 J/mol-K]
100 K     3 : 2      1  
 [R = 8.3 J/mol-K]
(A) 1175J (B) 1037.5 J (C*) 2075 J (D) 4150J
Sol. According to law of equipartition of energy, energies equally distributed among its degree of freedom,
Let translational and rotational degree of freedom be f1 and f2.
KT 3
and KT + KR = U
KR 2
Hence the ratio of translational to rotational degrees of freedom is 3:2. Since translational degrees of
freedom is 3, the rotational degrees of freedom must be 2.
1
Internal energy (U) = 1 × (f1 + f2) × RT
2
1 5 8.3 100
U= = U = 2075 J
2
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PAGE NO.-1
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    
 f1  f2  
KT 3
 KT + KR = U
KR 2
3 : 2 3 
2 
1
 (U) = .(f1 + f2) × RT
2
1 5 8.3 100
U= =U = 2075 J
2
2. P-T curve for a cyclic process is as shown`

  P–T 
P-V graph for this process will be :  P–V 
(A) (B) (C) (D*)
Sol.
PV = nRT
P 1
T V
1
Slope of line joining origin to that point
V
as the slope of line OE is greater than the slope of line OC, So, volume at 'E' is less than that at 'C'.
So, ans.is (D).
     1
V
OE OC  'E' 'C'  
 (D) 
PAGE NO.-2
3. A rod of length is sliding such that one of its ends is always in contact with a vertical wall and its other end
is always in contact with horizontal surface. Just after the rod is released from rest, the magnitude of
acceleration of end points of the rod is a and b respectively. The angular acceleration of rod at this instant
will be
    
            
 a  b 
a b | a2 b2 | a2 b2
(A) (B) (C*) (D) None of these  
Sol.
At the initial moment, angular velocity of rod is zero.

Acceleration of end B of rod with respect to end A is shown in figure.
Centripetal acceleration of point B with respect to A is zero ( 2
= 0)
So at the initial moment , acceleration of end B with respect
to end A is perpendicular to the rod which is equal to a2 b2
a rel =
a2 b2
where is angular acceleration
 
  B A 
 A  B  ( 2
= 0)
 B A  a2 b2 

a rel =
a2 b2
 
PAGE NO.-3
4. One mole of an ideal gas is kept enclosed under a light piston (area=10 –2 m 2) connected by a compressed
spring (spring constant 100 N/m). The volume of gas is 0.83 m 3 and its temperature is 100K. The gas is
heated slowly so that it compresses the spring further by 0.1 m. The work done by the gas in the process
is: (Take R = 8.3 J/K-mole and suppose there is no atmosphere). 
  100 N/m  =10–2 m 2 
0.83 m 3 100K 
0.1 m. : (R = 8.3 J/K-mole 
 )
(A) 3 J (B) 6J (C) 9J (D*) 1.5 J

Sol. Before heating let the pressure of gas be P1 from the equilibrium piston, 
   P1 - 
PA = kx1
PA nRT A 1 8.3 100 10 2
x1 = = =
K V K 0.83 100
= 10 = 0.1 m
–1
Since during heating process, ,

The spring is compressed further by 0.1 m   0.1 m 
x2 = 0.2 m
1 1
work done by gas  = .100(0.22 – 0.12) = .100.(0.1) (0.3)
2 2
= 1.50 = 1.5 J
5. For a given thermodynamic cyclic process, P – V indicator diagram is shown in the figure. Process AB, BC
& CA are isobaric, adiabatic & isothermal respectively. Then which of the following curve represent correct
V – T indicator diagram for the process ABCA?
     P – V     AB, BC  CA 
 ABCA V – T  ?
A B
P
C
V
C
C
V V
B B
(A*) (B)
A
A
T T
C C
V V
B B
(C) (D)
A A
T T
PAGE NO.-4
6. The radii of a spherical capacitor are equal to a and b (b > a). The space between them is filled with a
dielectric of dielectric constant K and resistivity . At t = 0, the inner electrode is given a charge q0. Choose
the incorrect options :
t
K 0
(A) Charge q on the inner electrode as a function of time is given by q q0 e
(B*) In a short time, the charge on the inner electrode will become zero
(C) After a long time, the charge on the outer sphere will become q0
1 1 q02
(D) The total amount of heat generated during the spreading of charge will be given by H
a b 8 0K
 a b (b > a)   K  
t = 0,   q0  
t
(A)  q  q q0 e K 0


(B*) 
(C)  q 0 
1 1 q02
(D)   H 
a b 8 0K
4 abK
0
Sol. C=
b a
b
dr (b a)
R= 2
=
a
4 r 4 ab
= RC = K 0
q = q0e–t/
t
q = q0e K 0
t= , q=0
Amount of heat generated 
1 1 q02
H
a b 8 0K
7. A fixed container is fitted with a piston which is attached to a spring of spring constant k. The other end of
the spring is attached to a rigid wall. Initially the spring is in its natural length and the length of container
between the piston and its side wall is L.Now an ideal diatomic gas is slowly filled in the container so that
the piston moves quasistatically. It pushed the piston by x so that the spring now is compressed by x. The
total rotational kinetic energy of the gas molecules in terms of the displacement x of the piston is (there is
vacuum outside the container)
    k  (spring)  
  
     L                
(quasistatically)  x   x   (compression)
     x     

L
K
2kx 2
(A) k x L (B) 4k x L (C*) kx(x+L) (D)
L
PAGE NO.-5
1
Sol. Rotational K.E. = Rotational degree of freedom x nRT
2
1
=2x nRT = nRT = PV
2
V
= PA . = force on piston (L + x) = kx (L + x)
A
1
. = x nRT
2
1
=2x nRT = nRT = PV
2
V
= PA . =  (L + x) = kx (L + x)
A
8. Some of the thermodynamic parameters are state variables while some are process variables. Some
grouping of the parameters are given. Choose the correct one.
        
 
(A) State variables : Temperature, No. of moles
Process variables : Internal energy, work done by the gas.
 
 
(B) State variables : Volume, Temperature
Process variables : Internal energy, work done by the gas.

 
(C) State variables : work done by the gas, heat rejected by the gas
Process variables : Temperature, volume.

 
(D*) State variables : Internal energy, volume
Process variables : Work done by the gas, heat absorbed by the gas.

 
Sol. Internal energy and volume depend upon states.
 

9. The state of an ideal gas is changed through an isothermal process at temperature T 0 as shown in figure.
The work done by gas in going from state B to C is double the work done by gas in going from state A to B.
P
If the pressure in the state B is 0 then the pressure of the gas in state C is :
2
T0 B C 
P0
 A B  B   
2
C :
P0 P0 P0 P0
(A) (B) (C) (D*)
2 4 6 8
PAGE NO.-6
Sol. Work done by gas in going isothermally from state A to B is
P
W AB = nRT n A = nRT n2 ................(1)
PB
Work done by gas in going isothermally from state B to C is
P P
W BC = nRT n B = nRT n 0 ................(2)
PC 2PC
It is given that W BC = 2 WAB
P P0
n 0 = n(2)2 Pc =
2PC 8
Sol. A  B  
PA
W AB = nRT n = nRT n2 ................(1)
PB
B C  
PB P
W BC = nRT n = nRT n 0 ................(2)
PC 2PC
  WBC = 2 W AB
P0
n = n(2)2
2PC
P0
Pc =
8
10. As shown in the figure a variable force F is applied on conducting wire of length such that its velocity
remains constant. There is no resistance in any branch in the circuit. There is uniform magnetic field B in
the region directed into the plane of paper. Consider the motion of wire from t = 0 initially there is no current
in inductor. Now when wire has covered a distance x (from initial position) then at that time energy of
inductor will be: (Neglect gravity) 
F,  
    B t = 0  
  x  () 
  ( )
(A) independent of x (B) directly proportional to x

(C*) directly proportional to x2 (D) directly proportional to x1/2
(A) x  (B) x 
(C*) x2  (D) x1/2 
PAGE NO.-7
B v B v
Sol. Current in circuit at any time t is, I = t  t  I = t
L L
2 2
1 B v 1 B v
So, energy of inductor at time t = L t ,  t  = L t
2 L 2 L
x
t=
v
So,  E x2
11. Two large non conducting plates having surface charge densities + and – respectively, are fixed d
distance apart. A small test charge q of mass m is attached to two non conducting springs each of spring
constant k as shown in the figure. The sum of lengths of both springs in undeformed state is d. The charge
q is released from rest with both the springs nondeformed. Then charge q will (neglect gravity)
+  –   d  m  q 
k  
 d  q  q–
()
+ –
+ –
+ q –
–
+ –
+ m –
+ –
–
+ –
d
2k q
(A) performs SHM with angular frequency and amplitude .
m k 0
2k q
   
m k 0
2k q
(B*) performs SHM with angular frequency and amplitude .
m 2 k 0
2k q
  
m 2 k 0
(C) not perform SHM, but will execute periodic motion.

(D) remain stationary. 
Sol. The electrostatic force on charge is constant, hence it does not affect the time period of spring + particle
system
2k
=
m
Initially the charge is at rest, i.e., at extreme position.
The equilibrium position, shall be at a distance A towards right, where A (by definition) is amplitude of
vibration.
q
2kA = q or A=
0 2k 0
PAGE NO.-8
Sol. 
2k
=
m
 
A A 
q
 2kA = q or A=
0 2k 0
12. Suppose the earth was covered by an ocean of uniform depth h. (h<<R). Let be density of ocean and
be mean density of earth. Let g be the approximate difference of value of net acceleration due to gravity
between the bottom of the ocean and top. ( g = gtop – gbottom). Choose the correct option :
  h,(h<<R)        
  g      . ( g = gtop – gbottom). 
 
4 4
(A) g = Gh [2 – 3 ] (B*) g = G h[3 – 2 ]
3 3
4 4
(C) g = G h[2 – 3 ] (D) g = G h[3 – 3 ]
3 3
Sol.
4
gA = G R
3
4 4 4
G R3 (R h)3 R3
3 3 3
gB =
(R h)2
4 2h 4 2h
= G R 1 G (R h) 1 R
3 R 3 R
4
g = gB – gA = Gh [3 – 2 ].
3
13. One mole of an ideal monoatomic gas undergoes a cyclic process ‘abca’ shown in figure. If U denotes the
internal energy and W the work done by the gas. Then choose the incorrect alternative (s)
 ‘abca’  U 
W  
(A) Uc Ua 10.5RT0 (B*) Ub Ua 4RT0

(C*) Wc a 3P0 V0 (D) Uc Ub Ua
PAGE NO.-9
Sol. (a) Uc – U a = nC vdT
3R 21
= (1) (8T0 – T 0) = RT0
2 2
P
c(8T 0)
2P 0
(T0)
P0
a b(4T 0)
V0 4V 0 V
(b) Ub – U a = nC vdT
3R
= (1) (4T0 – T0) = 4.5RT0 (wrong )
2
(c) W c a cannot be determined, but 
|W c a| > |W a b|
|W c | > 3P0V0, Hence (C) is wrong  (C) 
a
14. AB is a light rigid rod, which is rotating about a vertical axis passing through A. A spring of force constant K
and natural length is attached at A and its other end is attached to a small bead of mass m. The bead can
slide without friction on the rod. At the initial moment the bead is at rest (w.r.t. the rod) and the spring is
unstrecthed. Select correct options :
AB   A  K 
 A m  
 () 
  
    
m 4 2
(A*) The maximum velocity attained by the bead w.r.t the rod is given by Vmax 2
K m
4
m K 2 2
(B) The maximum velocity attained by the bead w.r.t the rod is given by Vmax 2
m K
2
2m
(C*) The maximum extension in the spring is given by Vmax
K m 2
(D*) The maximum value of contact force between the bead and the rod is greater than mg
m 4 2
(A*)  Vmax 2

K m
4
m K 2 2
(B)    Vmax 2

m K
2m 2
(C*)  Vmax 2

K m
(D*) mg 
PAGE NO.-10
Sol. Velocity will be maximum at equilibrium position

vmax
l x
2
m ( x ) Kx
m 2
x 2
K m
1 x 1 2
2 2
mVmax m ( x) dx kx
2 0 2
2
2 2m x m 2 x 2 kx 2
Vmax
m
2 2
2 (m m ( x ) kx )x
Vmax
m
4 4
2 2 m
Vmax 2
m K
4 2
m
Vmax 2
K m
For maximum extension  
x
2 1 2 2m 2
m ( x )dx kx max = 0 x max 2
0 2 K m
15. Three projectiles are thrown all with same speed u but at different angles of projection ( 1
> 2
> ) all
3
taken from horizontal. Maximum height attained by projectile (3) is H. Range of (1) & (3) is same & that of
(2) is maximum for the given speed. At height H, speeds are v1 , v2 & v3 as shown. Total time of flights are
T 1, T2 & T 3. Choose the correct statement(s).
   u   ( 1 > 2 > 3) 

 (3)  H  (1)  (3)   
 (2) H   v1 , v2  v3 T 1, T2
 T 3 
(A) v1 > v2 > v3 (B*) v1 = v2 = v3
(C*) T12 , T22 & T32 are in AP (D*) 1 , 2 & 3 are in AP

(A) v1 > v2 > v3 (B*) v1 = v2 = v3
(C*) T12 , T22  T 32 ,  (AP)  (D*) 1
, 2
 3
, AP  
PAGE NO.-11
Sol. from work energy theorem 
v1 = v2 = v3
1
+ 3 = 90° & 2 = 45°
1 3
2 ,
1 2
& 3
are in AP AP 
2
2usin 1 2usin 45 2ucos 1
T1 = T2 = T3 =
g g g
2 2
T1 T3
= T 22 T 12 , T22 & T 32 are in AP AP 
2
16. The figure shows the velocity as a function of the time for an object with mass 10 kg being pushed along a
frictionless horizontal surface by external horizontal force. At t = 3 s, the force stops pushing and the object
moves freely. It then collides head on and sticks to another object of mass 25 kg.
        10 kg  
t = 3 s 
 25 kg 
(A*) External force acting on the block of mass 10 kg is 50 N from t = 0 to t = 3 sec.

(B*) Speed of the 2nd particle just before the collision is 1 m/s.
(C*) before collision both bodies are moving in the same direction.
(D) before collision, bodies are moving in opposite direction.
(A*) 10 kg  t = 0  t =3 sec 50 N 
(B*) 1 m/s 
(C*)  
(D)  
Sol. From graph in time from t = 0 to t = 3 sec.
acceleration of object of mass m 1 = 10 kg is
15 0
a= = 5 m/s2
3
Force on object of mass m 1 from t = 0 to t = 3 sec. (i)
= 10 × 5 = 50 N
Before and after collision at t = 4 sec, the velocities of blocks are as shown.
Before collision
after collision
initial momentum of system
= m 1u 1 + m 2u2 = 150 + 25 u2
final momentum of system
= (m 1 + m 2) v = 35 × 5 = 175
From conservationof momentum
150 + 25 u 2 = 175
or u 2 = + 1 m/s
speed of second particle just before collision is 1 m/s and before collision both blocks move in same
direction.
PAGE NO.-12
  t = 0  t = 3 sec 
 m 1 = 10 kg 
15 0
a= = 5 m/s2
3
t = 0 t = 3 sec m1 
= 10 × 5 = 50 N
t = 4 sec  


 
= m 1u 1 + m 2u2 = 150 + 25 u2

= (m 1 + m 2) v = 35 × 5 = 175

150 + 25 u 2 = 175
or u 2 = + 1 m/s
1 m/s  
17. In an isobaric process ( is adiabatic exponent of the gas)

( )
(A*) The heat given to gas is times the work done by gas.
1
(B*) The work done by gas is ( – 1) time the change in internal energy.
(C) The temperature of gas is increased.
(D) The temperature of gas is decreased.
(A*)   , 
1
(B*)  ( – 1)  
(C) 
(D) 
Sol. At constant pressure. 
If volume increases, temperature also increases  
volume decreases, temperature decreases. 
In Isobaric process. 
Q= U
Q= U+ W
W = U – U = ( – 1) U
W = ( – 1) U
Q= . W
( 1)
PAGE NO.-13
18. Solid uniform conducting sphere of mass ‘m’ and charge Q, rotates about its axis of symmetry with
constant angular velocity ‘ ’ then the ratio of magnetic moment to the moment of inertia of the sphere
xQ.
is then x is : ( Neglect induced charges due to centrifugal force)
6m
‘m’ Q  ‘ ’
      xQ.  x : (  
6m
) 
Ans. 5
Q 2
Sol. M= mR2 .
2m 3
2mR2
I
5
M 5Q.
I 6m
19. A stationary observer receives a sound from a source of frequency 2000 Hz moving with constant velocity.
The apparent frequency varies with time as shown in the figure.
 2000 Hz         

The value of fm is (2300 – 10x)Hz. Find the value of x. (Take speed of sound = 300 m/s and neglect the
time taken by sound to reach the stationary observer).
fm (2300 – 10x) Hz  x = 300 m/s 
)
Ans. 5
v
Sol. fm = f
(v v s cos )min
v
1800 = f
(v v s cos )max
On solving, 
fm = 2250 Hz
= 2300 – 50
PAGE NO.-14
20. In a moving coil galvanometer, a coil of area cm2 and 10 windings is used. Magnetic field strength applied
on the coil is 1 tesla and torsional stiffness of the torsional spring is 6 × 10 –5 N.m/rad. A needle is welded
with the coil. Due to limited space, the coil (or needle) can rotate only by 90º, For marking, the 90º space is
equally divided into 10 parts as shown. Find the least count of this galvanometer in mA.
 cm2  10  
 1  6 × 10–5 N.m/rad     () 
  ()  90º    90º   10 
mA
Ans. 3
Sol. (NBA)i = c
C (6 10 5 )
i= = 4
sss
NBA 10 1 10 2
i = 30 mA
30
So current corresponding 1 part = = 3 mA.
10
30
1  = = 3 mA
10
21. A gas consisting of rigid di–atomic molecules (degree of freedom = 5) at pressure P0 = 105 N/m 2 and
1
temperature 273 K was compressed adiabatically to of its initial volume. The mean kinetic energy of
5
rotation of molecules in final state is n × 10–21 J (approx). Find value of ‘n’. (K = 1.38 × 10–23 J/K,
(5)2/5 = 1.90).
 (= 5)   P0 = 105 N/m 2 273 K 
1
                  
5
n × 10–21 J ()  ‘n’ (K = 1.38 × 10 –23 J/K, (5)2/5 = 1.90).
Ans. 7
Sol. In an adiabatic expansion, 
TV = constant 
–1
1
V 2
T 0V –1 = T =1+
5 5
T = (273). (5)2/5
< (KE)rotational > = kT
< (KE) > = kT
= 1.38 × 10 –23 × 273 × (5)2/5
= 7 × 10–21 J (approx).
22. The degree of freedom per molecule for a gas is 6. At constant pressure work done by gas is 25 J. The
heat supplied to the gas for this purpose is 25x Joule then x is :
  6  25 J 
 25x   x 
Ans. 4
PAGE NO.-15
2 1
Sol. =1+ =1+
f 3
4
=
3
As we know  W= Q– U
W Q U C
= =1– v
Q Q Cp
W 1 1
=1– =
Q 4
Q = 4. W
Q = 100 J.
23. 5 moles of Nitrogen gas are enclosed in an adiabatic cylindrical vessel. The piston itself is a rigid light
cylindrical container containing 3 moles of Helium gas. There is a heater which gives out a power 100
cal/second to the nitrogen gas . A power of 30 cal /sec is transferred to Helium through the bottom surface
of the piston. The rate of increment of temperature of the nitrogen gas is (assuming that the piston moves
slowly) :
  5   
       100   
    30      
() :
He
N2
Ans. 2
Sol. Net power given to N2 gas = 100 – 30 = 70 cal/s
The nitrogen gas expands isobarically.
dq dT 7 dT
= n Cp or 70 = 5 x R
dt dt 2 dt
dT
= 2k/sec
dt
. N 2 = 100 – 30 = 70  /

dq dT 7 dT
= n Cp  70 = 5 x R
dt dt 2 dt
dT
= 2K/sec.
dt
PAGE NO.-16
24. At the middle of the mercury barometer tube there is a little column of air with the length 0 and there is
vacuum at the top as shown. Under the normal atmospheric pressure and the temperature of 300 kelvin,
0 = 10 cm. What will be the length (in cm) of the air column if the temperature rises to 330 kelvin ?
(Neglect expansion of the tube)
  0  
300  0 = 10 cm  (cm ) 
330 
Ans. 11
Sol. Pressure in the air inside the column of mercury is equal to the weight of mercury over the air divided by
the internal cross sectional area of the tube. When the temperature increases, the weight of the upper part
of the mercury column does not change. That is why the pressure in the air is also constant. For the
isobaric process, the change in volume is proportional to the change in temperature. The same is true for
the lengths of the air column.
    

 
T 0T
= 11
0 T0 T0
25. One mole of an ideal gas ( = 1.4) at 500 K, is filled in an adiabatic cylinder. The piston is free to move
against atmospheric pressure. A non–conducting fan is inserted into the gas space and rotated vigorously,
so that the gas expands slowly, till its volume is doubled. Find work done by the fan in kJ.
(Take R = 8 J/mole.K, neglect heat capacity of the cylinder, piston and the fan).
    ( = 1.4)  500 K  
      
kJ 
(R = 8 J/mole.K, ,  )
Ans. 14
PAGE NO.-17
Sol. Using 1st law of TD 
Q=W+U
f
0 = ( Wfan ) P v n R T
2
f
Wfan = n R T + n R T
2
Wfan = n C p T
f
Wfan = (1) R R (500 k) (as the gas is expending slowly so p = constant, so T v)
2
(p =   T v)
Wfan = 14 kJ
26. The current density J inside a long, solid, cylindrical wire of radius a = 12 mm is in the direction of the
Jr
central axis, and its magnitude varies linearly with radial distance r from the axis according to J = 0 ,
a
105 a
where J 0 = A/m 2. Find the magnitude of the magnetic field at r = in µT.
4 2
 a = 12 mm,    J  
J0r 105
 r  J = , J 0 = A/m 2 
a 4
a
r =  µT  
2
Ans. 10
dr
Sol. r
Current in the element = J(2 r . dr)

Current enclosed by Amperian loop of radius
a/2 3
J0r 2 J0 a J0 a 2
I= . 2 r . dr = =
a 3a 2 12
0
Applying Ampere's law
a J0a 2 0J0a
B.2 . = µ0 . B=
2 12 12
On putting values
B = 10 µT
PAGE NO.-18
dr
 = J(2 r . dr)


a/2 3
J0r 2 J0 a J0 a 2
I= . 2 r . dr = =
a 3a 2 12
0

a J0a 2 0J0a
B.2 . = µ0 . B=
2 12 12

B = 10 µT
COMPREHENSION-1
The basic idea of Quantum Mechanics is that motion in any system is quantized. The system obeys
Classical Mechanics except that not every motion is allowed, only those motions which obey the Bohr -
Sommerfeld Quantization,
  
    

P.dr nh, n N
where P is the momentum, r is the position vector and the integral is carried over a closed path.
Assuming this is applicable to a particle of mass m moving with a constant speed in a box of length L
having elastic collisions with the walls of the box, Answer the following questions. (h = 6.6 × 10–34 J–sec,L
= 3.3 Å, m = 10 –30 kg)
 P  r    L  
m 
 (h = 6.6 × 10–34 J–sec,L = 3.3 Å, m = 10–30 kg)
27. The allowed momenta are given by : (allowed)

nh nh nh nh
(A*) (B) (C) (D)
2L L 2 L 4L
Sol. From the condition given in the paragraph, 
P 2L nh , where 
P is the momentum, P 
nh
P=
2L
PAGE NO.-19
28. The allowed kinetic energy of the particle is :  
2 2 2 2
nh nh n2h2 n2h2
(A) (B) (C*) (D)
8 2 mL2 2mL2 8mL2 32mL2
P2
Sol.. Kinetic energy  E
2m
n2h2
E=
8mL2
st nd
29. The difference between and energy levels is :
Ist  IInd 
(A*) 1.5 × 10–18 J (B) 3 × 10–18 J (C) 6 × 10–18 J (D) 12 × 10 –18 J
COMPREHENSION-2
The fixed non-conducting cylinder shown in figure has a nonconducting heavy piston of mass M that can
slide without friction. The area of piston is S and the cylinder is filled with an ideal gas ( = 1.5), with an
initial volume V and an initial pressure P. Assume that the outside pressure on the piston is zero (vacuum).
(Neglect acceleration due to gravity).
  M  
 S    ( = 1.5)    V 
P  () ()
L
30. The initial acceleration of piston is :

PS PS PS PS
(A) (B) (C*) (D)
M M M 1
Sol. The initial force on the piston is PS
 PS 
PS
a=
M
31. After the piston has moved by distance L, its velocity is :
L   
1/ 2 1/ 2
1/ 2
4PV V 4PV V
(A*) 1 (B) 1
M V LS M V LS
1/ 2
1/ 2
4PV V LS
(C) 1 (D) None of these   
M V
Sol. Workdone by gas in the adiabatic process ( )

1/ 2
V 1
= 2PV 1 Mv2 = W
V LS 2
1/ 2
1/ 2
4PV V
v= 1
M V LS
PAGE NO.-20
32. For the temperature of the gas to drop to one half of its original value, the piston will have to move by a
distance :
 
V 2V 3V 5V
(A) (B) (C*) (D)
S S S S
1
Tf V V 1
Sol. =
T Vf V LS 2
3V
L=
S
COMPREHENSION–3
In the following passage we will study how the problems of collision can be solved with the help of simple
geometrical construction.
Let us consider a case of elastic collision in which second mass is at rest before collision.
For collision process we can write two equations, one for momentum conservation & other for energy
conservation ;
P P1 P2 ............(1)
P2 P12 P22
............(2)
2m1 2m1 2m2
where, P = Initial momentum of particle 1,
P1 = Final momentum of particle 1,
P2 = momentum of second particle after collision.
Let ‘ ’ be the angle between P &P2 .
Then, P1 P P2
P12 = P2 + P22 – 2PP2cos ..........(3)
From equation (2) & (3) we get ;
2m2
P2 P cos ..............(4)
m1 m2
Now we can proceed for a geometrical construction :
Step 1 : Draw vector P from a certain point ‘O’ to represent the momentum of the incident particle.
2m2
Step 2 : Draw P1 a circle of diameter P with its centre lying on straight line coinciding with P in
m1 m2
such a way that circle passes through point ‘O’.
Step 3 : Draw vector P2 from point ‘O’ at an angle ‘ ’ with its head touching the circumference of the circle.
Step 4 : Draw P1 so as to satisfy the equation P P1 P2 .
PAGE NO.-21
Here the angle between the momentum of the first and the second particle after collision is denoted by ,
while is the angle by which the incident particle deflects from initial direction after the collision.
Since, the angle inscribed by a diameter on the circumference is a right angle therefore all vectors drawn
from point ‘O’ to the circumference of the circle will satisfy the equation :
2m2
P2 = P cos
m1 m2
Here ‘ ’ represents the angle made by the line of impact with the initial line of motion of first particle. By
changing ‘ ’ we can draw all possible cases of the collision.
2m2
All above diagrams are for the case when : 1, which implies that the mass of incident particle is
m1 m2
larger than the mass at rest. i.e. m 1 > m 2.
2m2
But when the case changes to 1 m2 > m1 ;
m1 m2
our diagram will be become ;
Where ; = angle of divergence between the particles,

= angle of deviation or deflection of the incident particle,
& = angle of incidence.
Similarly for m1 = m2 our diagram will be :
Now answer the following questions taking ‘m 2’ to be initially at rest :
PAGE NO.-22
     # 1
                                  
                         
                        

P P1 P2 ............(1)
2 2
P2 P1 P2
............(2)
2m1 2m1 2m2
  , P =  1        

P1 =  1     
P2 =           
  ‘ ’, P  P2       
  , P1 P P2
P12 = P2 + P22 – 2PP2cos ..........(3)
 (2)  (3)   ;
2m2
P2 P cos ..............(4)
m1 m2
       
 1 :   O    P                
2m2
 2 :  P                   P  
m1 m2
         ‘O’         
 3 :   O           P2                 
 4 : P1            P P1 P2     
                           

              
                           ‘O’        
             
2m2
P2 = P cos
m1 m2
  ‘ ’              ‘ ’   
          
PAGE NO.-23
2m2
               1               
m1 m2
             m1 > m 2 
2m2
    1        m2 > m 1 ;      
m1 m2
  ; =         

=       
=   
     m1 = m2       
m2             
33. In which of the following cases the incident particle can not change its direction of motion by all possible
angles from 0 to ?
  0                             
 ?
(A) m 1 > m2 (B) m 2 > m1 (C) m1 = m 2 (D*) m 1 m2
PAGE NO.-24
Sol.
P P1 P2
and P2 is a chord of the circle and from diagram (A) it is clear that P1 cannot reverse its direction as it can
do in diagram "B".
In case of m1 = m 2
It can be judged by chaning ' ' that P1 cannot change its direction from 0 to .
34. Consider the case when m1 = m2 & m2 is initially at rest and elastic collision takes place. When = 30°, the
angle of deflection of the incident particle from initial direction of motion will be :
 m1 = m 2    m2                   = 30°    
          
(A) 300 (B*) 600 (C) 120 0 (D) 150 0
Sol.
From figure = – /2 – 30 0 = 60 0.
35. The two colliding particles will diverge at an angle greater than 900 for the case :
             900          :
(A) m 1 > m2 (B*) m 2 > m 1 (C) m1 = m 2 (D) m1 m2
Ans. Clearly from the passage :
> 900 for m 2 > m 1 (here angle of divergence is ' ')

Hence (B).
PAGE NO.-25
COMPREHENSION-4
One mole of an ideal gas is contained in a perfectly Insulating cylinder. Initially adiabatic piston of unit area
and unit mass is in equilibrium. Now a block of same mass is kept gently on piston as shown in figure.
(Take = 1.5, g = 10 m/s2 and neglect friction and assume change in temperature in whole gas is
simultaneous)
  
    ( = 1.5,g =10 m/s2
)

/////////////////////////////////
1m
36. Depth upto which (piston + block) will move before coming to rest again is :
(+ )  
5 1 5 1 5 1
(A*) m (B) m (C) m (D) None of these   
2 3 4
37. Maximum pressure of gas during its motion : 

20 2 20 2 20 5 20 2
(A) 3/ 2
N/m 2 (B) 1/ 2
N/m 2 (C) 3/ 2
N/m 2 (D*) N/m 2
(5 3) (3 5) (3 5) (3 5 )3 / 2
Sol. By energy conservation,   
4
2mgh = R T
2
10h
T= ..............(i)
R
mg
Initially,  (A. ) = RT1 ..............(ii)
A
and finally, Pmax A( – h) = RT2 ..............(iii)
, Pmax A( – h) = RT2 ..............(iii)
(iii) – (ii)
Pmax.(1 – h) – 10 = 10 h ..............(iv)
By equation of adiabatic process PV = constant
PV = 
mg
(A ) = Pmax {A( – h)}
A
10 = Pmax.(1 – h)
Put this Pmax. in equation (iv) (iv) Pm 
10(1 – h)1– – 10 = 10h
(1 – h)1– – 1 = h
(1 – h)1– = (h + 1)
PAGE NO.-26
1 1
= (1 + h) = (1 + h)2
1 h (1 h)
h(h 2 + h – 1) = 0
5 1
h= m
2
10 20 2
and  Pmax. = 3/2
= N/m 2.
5 1 (3 5 )3 / 2
1
2
COMPREHENSION
One mole of a diatomic gas is heated under a "Kibolinsky Process" in which gas pressure is temperature
4
controlled according to law P = CT3/2. Where C is Kibolinsky constant. In this process, gas is heated by
5
300 K temperature. Answer the following questions.
  (Kibolinsky Process) 
P = 4 CT3/2  C 
5
300 K 
38. The amount of workdone by gas under above heating is :

 
(A) 600 R (B) 750 R (C*) – 150 R (D) None of these   
39. The amount of heat supplied to the gas under above heating is :

(A*) 600 R (B) – 750 R (C) – 150 R (D) None of these   
40. Under above process the molar specific heat of gas is :


R
(A) (B) R (C*) 2 R (D) None of these   
2
4
Sol. For P = CT 3/2
5
We have PV3 = Constant
Thus molar specific heat of gas is
R R 5R
C = CV + = CV – = 2 R [as CV = ]
1 3 2 2
Heat supplied to gas in temperature increment by T = 300 K in this process is
Q = nC T = n (2R) (300) = 600 R
Charge in internal energy of gas in this process is
5R
U = nCV T = × 300 = 750 R.
2
Thus work done by the gas is W = Q – U = – 150 R.
PAGE NO.-27
4
 P= CT3/2 
5
 PV3 = 

R R 5R
C = CV + = CV – = 2 R [CV = ]
1 3 2 2
 T = 300 K   
Q = nC T = n (2R) (300) = 600 R

5R
U = nCV T = × 300 = 750 R.
2
 W = Q – U = – 150 R.
41. In column–II, some situations are given, and in column–I, their results are given. Match the proper entries
from column-2 to column-1 using the codes given below the columns.
Column–I      Column–II
(P) 0ºC ice kept at atmospheric pressure, melts (1) Net work is done by the system
and converts into 0ºC water ( ice = 0.9 water).
For the ice water system during this process.
(Q) A gas is undergoing a cyclic process. Density (2) Net work is done on the system
( ) v/s internal energy (U) graph is as shown.
Here process B–C is an adiabatic process.
Consider the gas as the system, for the complete
cyclic process :
(R) In a closed, non–conducting room, a fan is (3) Internal energy of the system
turned on. Consider the air in the room as a increases
system. During this process.
(S) Gas is filled in a conducting container of negligible (4) Internal energy of the system
heat capacity. The container is kept in ice–water decreases
mixture for a long time. Now the piston is slowly
brought down, till the gas is very much compressed.
Now the cylinder is coated with an insulating material
and now the piston is released. When the piston is
allowed to reach the initial position slowly then in whole
process (Assume the gas in the container to be the system).
P Q R S
(A) 3 1 4 2
(B*) 2 1 3 4
(C) 3 2 1 4
(D) 2 4 3 1
Ans. (P) – 2,3 ; (Q) – 1 ; (R) – 2,3 ; (S) – 2,4
PAGE NO.-28
Sol. (A) When 0ºC ice converts into 0ºC water volume decreases slightly, so W system = –ve. To melt the ice, some
heat has to be given (Q = mLf) which is almost equal to increase in internal energy.
(B)
Since, P–v cycle is clockwise, so W net = +ve

and ( u)cycle = 0
(C) By the fan, some work is done on the room air. Due to this, temperature of the gas increases slightly,
so internal energy will increase slightly. Mathematically,
Q=W+ u
Q = –ve + u u = +ve.
(D) P–V diagram for the process is
From the diagram

W A B C = –ve
(PV)C < (PV)A T C < TA
So, internal energy decrease.
–II,  –I,   -

1  -2  
 –I     –II
(P) 0ºC   (1)   
 0ºC 
(  = 0.9 ) 
 
(Q)   (2)  
( ) v/s  (U)    
 B–C   
 
(R)  (3)  

 
(S)  (4)  

   

   
 
  
  
PAGE NO.-29
P Q R S
(A) 3 1 4 2
(B*) 2 1 3 4
(C) 3 2 1 4
(D) 2 4 3 1
Ans. (P) – 2,3 ; (Q) – 1 ; (R) – 2,3 ; (S) – 1,4
Sol. (A)  0ºC  0ºC    W  = –ve    
(Q = mLf)  
(B)
 , P–V W net = +ve

 ( u)cycle = 0
(C)        
 
Q=W+ u
Q = –ve + u u = +ve.
(D)  P–V 

WA B C
= –ve
(PV)C < (PV)A T C < TA
 
42. An ideal gas consists of a large number of identical molecules. Absolute temperature of the gas is T(in
kelvin), molecular weight of gas is M and R is gas constant. Match the proper entries from column-2 to
column-1 using the codes given below the columns.
      T (),  M   R
 -1  -2  
Column-I Column-II
RT
(P) Root mean square speed of molecules is greater than (1)
M
RT
(Q) Most probable speed of molecues is smaller than (2) 1.5
M
RT
(R) Average velocity of a molecule is smaller than (3) 2
M
RT
(S) Speed of a molecule may be greater than (4) 2.5
M
P Q R S
(A) 2 1 3 4
(B) 3 1 4 2
(C*) 1 3 2 4
(D) 4 2 3 1
PAGE NO.-30
 -I  -II
RT
(P)  (1)
M

RT
(Q) (most probable speed) (2) 1.5
M

RT
(R)  (3) 2
M
RT
(S)   (4) 2 .5
M

  P Q R S
(A) 2 1 3 4
(B) 3 1 4 2
(C*) 1 3 2 4
(D) 4 2 3 1
Ans. (P) 1,2 (Q) 2,3,4 (R) 1,2,3,4 (S) 1,2,3,4
3 RT RT
Sol. Root mean square speed of molecules = = 1.732
M M
2 RT RT
Most probable speed of molecues = = 1.44
M M
Average velocity of a molecule is zero
Speed of any individual molecule may be anything.
3 RT RT
  = = 1.732
M M
2 RT RT
 = = 1.44
M M

 

43. In a hydrogen atom, a0 = 0.529 Å, E1 = –13.6 eV. Some modified situations are given compare the energy
of levels and radius of allowed orbits.
 , a0 = 0.529 Å, E1 = –13.6 eV     

Column–I Column–II
E
(P) An atom consists of positive charge 2e and (1) 1 or 2E1
2
mass m and an electron of mass m revolving around
the centre of mass of the system
a0
(Q) An atom consists of positron and an electron (2) 2a0 or
2
revolving around the centre of mass of system
2 9
(R) An atom consists of a particle of mass double that (3) E1 or E1
9 2
of electron and charge same as that of electron revolving
around a heavy nucleus of charge 4e
(S) An atom consists of a nucleus of infinite mass and an (4) a0 or 8a0
electron revolving around the nucleus of charge 2e (5) 4E1
PAGE NO.-31
–I –II
E1
(P) m 2e  (1)  2E1
2
m   
 
a0
(Q)   (2) 2a0 
2

2 9
(R)  2m   (3) E  E1
9 1 2
 4e  
 
(S) 2e   (4) a0  8a0  
 
(5) 4E1
P Q R S
(A) 1 3 4 5
(B) 2 2 5 4
(C) 3 1 2 1
(D*) 4 2 1 5
Ans. (P) – 1,3,4 ; (Q) – 1,2,4 ; (R) – 1,2,4 ; (S) – 2,4,5
z2 mM
Sol. E n = E1 2 ( = )
n m m M
n2 m
r n = a0 
z
44. An ide al gas u nde rgoes a cyclic p rocess a s sho wn in P -V graph. Match each process given
in co lumn-I with the corresponding results give n in c olumn II.
 P-V  -I   II 
 
P(N/ m2)
J
30
20 M
10 L
K
10 20 V(m3)
Column-I Column-II
(P) Process J – K (1) W > 0
(Q) Process K – L (2) W < 0
(R) Process L – M (3) Q> 0
(S) Process M – J (4) Q< 0
PAGE NO.-32
 -I  -II
(P) J – K  (1) W > 0
(Q) K – L  (2) W < 0
(R) L – M  (3) Q> 0
(S) M – J  (4) Q< 0
P Q R S
(A) 1 2 3 4
(B*) 4 3 3 2
(C) 4 1 3 3
(D) 1 3 2 4
Ans. (P) 4 (Q) 1,3 (R) 3 (S) 2,4
Sol. For process ( )
J K : W = 0 and  U < 0
K L : W > 0 and  U > 0
L M : W = 0 and  U > 0
M J : W < 0 and  U < 0
PAGE NO.-33

DPP 10 Jee Advanced Revision DPP B

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TARGET : JEE (ADVANCED) 2016

Course : VIJETA & VIJAY (ADP & ADR) Date : 08-05-2016

DATE : 11.05.2016 PART TEST (PT)-5

ANSWER KEY OF DPP NO. # 10

2. P-T curve for a cyclic process is as shown`

P-V graph for this process will be :  P–V 

(A) (B) (C) (D*)

At the initial moment, angular velocity of rod is zero.

 B A  a2 b2 

(A) 3 J (B) 6J (C) 9J (D*) 1.5 J

Since during heating process, ,

(A)  q  q q0 e K 0

(A) independent of x (B) directly proportional to x

(A) Uc Ua 10.5RT0 (B*) Ub Ua 4RT0

(A) v1 > v2 > v3 (B*) v1 = v2 = v3

(C*) T12 , T22 & T32 are in AP (D*) 1 , 2 & 3 are in AP

(A*) External force acting on the block of mass 10 kg is 50 N from t = 0 to t = 3 sec.

17. In an isobaric process ( is adiabatic exponent of the gas)

Current in the element = J(2 r . dr)

 = J(2 r . dr)

27. The allowed momenta are given by : (allowed)

Sol. Workdone by gas in the adiabatic process ( )

Where ; = angle of divergence between the particles,

  , P =  1        

  ; =         

m2             

> 900 for m 2 > m 1 (here angle of divergence is ' ')

37. Maximum pressure of gas during its motion : 

38. The amount of workdone by gas under above heating is :

40. Under above process the molar specific heat of gas is :

Since, P–v cycle is clockwise, so W net = +ve

From the diagram

(R)  (3)  

(S)  (4)  

 , P–V W net = +ve

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(C) T12 , T22 & T32 are in AP (D) 1 , 2 & 3 are in AP