PHY./INORG.

CHEMISTRY

TARGET : JEE(MAIN)
 


E E ST INFORM ATIO
DPP
DAILY PRACTICE PROBLEMS

Class - XII NO. 3

Hints & Solutions

1. A  B + C
rate constant = 0.001 Ms–1
[A]0 = 1 M
From unit of rate constant, we can conclude that rate is of zero order.
Decrease in concentration of A in 10 min = 0.001 × 10 × 60 = 0.6 M
At t = 10 min, [A]t = 1 – 0.6 = 0.4 M
t = 10 min, [B]t = 0.6 M.
Sol. A  B + C
nj fu;rkad = 0.001 Ms–1
[A]0 = 1 M
nj fu;rkad dh bdkbZ ls ;g izekf.kr gksrk gS fd vfHkfØ;k 'kwU; dksfV dh gSA
10 feuV esa A dh lkUnzrk esa deh = 0.001 × 10 × 60 = 0.6 M
t = 10 min, [A]t = 1 – 0.6 = 0.4 M
t = 10 min, [B]t = 0.6 M.

24. Only for this reaction E0 will come out to be positive, calculate using relation
G° = G10 + G20 and G0 = – nFE°cell
Sol. dsoy bl vfHkfØ;k ds fy, E0 /kukRed vkrk gS fuEu laca/k dk mi;ksx djds x.kuk djrs gSaA
G° = G10 + G20 ,oa G0 = – nFE°cell

25. pH = 14, pH + pOH = 14, 14 + pOH = 14, pOH = 0, [OH–] = 1 M

Ksp 1033
[AI3+] = – 3
= = 10–33
[OH ] 1
Al3+ + 3e–  Al
0.0591 1
Ecell = EºAI3 / Al – log .
3 [AI3  ]

26.  eq {Ba(OH)2} =  eq (Ba2+)+  eq , OH–

 eq (BaCI2) =  eq (Ba2+) +  eq (CI–)
 eq (NH4CI) =  eq (NH+4) +  eq (CI–)
 eq (NH4OH) =  eq (NH4+) +  eq (OH)
 eq (NH4OH) =  eq (NH4CI) +  eq {Ba(OH)2} –  eq (BaCI2) = (228.8 + 129.8) – 120.3 = 238.33 cm2eq–1
4.766  10 –14  1000
 ceq (NH4OH) = = 2.383
0.2
ceq (NH4OH)
= = 10–2
eq (NH4OH)

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 NH4OH NH4+ + OH–
c(1–) c c
[OH–] = 0.2 × 10–12 = 2 × 10–3
pOH = 3– log2  pH = 14 –(3–log2) = 11.3

27.  = 3.2 × 10–5 –1.cm–1

  103
=
C
3.2  10 2
 = = 16 × 10–2
0.2
  16  10 2
 =   = = =8
  0.02

29. 4Zn = 10HNO3(dil ruq)  4Zn(NO3)2 + 5H2O + N2O

30. (1) 2O3– + 5H2SO3  2 + 5SO42– + OH+ + H2O; 2O3– + 5H2S + 2H+  2 + 5S + 6H2O
14001500ºC
(2) 2Ca3 (PO4)2 + 6SiO2 + 10C   6CaSiO3 + 10CO + P4.
(3) 2HS– + 4HSO3–  3S2O32– + 3H2O
20ºC
(4) NO + NO2   N2O3

31. 4HNO3 + P4O10 

250K
 4HPO3 + N2O5 (anhydride of HNO3)
Sol. 4HNO3 + P4O10  4HPO3 + N2O5 (HNO3 dk ,ugkbMªkbM)
250K

36. (1) Neutralisation reaction

(2) Addition reaction
(3) SO2 reduces Fe3+ to Fe2+ and itself oxidised to SO42–.
(4) SO2 acts as oxidising agent.

37. As water has H-bonding due to the presence of highly electronegative oxygen but H 2S does not
(electronegativity of sulphur is low).
Sol. mPp fo|qr_.kh vkWDlhtu dh mifLFkfr ds dkj.k ty esa gkbMªkstu ca/k ik;s tkrs gS] ysfdu H2S esa H-ca/k ugha gksrs
gSaA ¼lYQj dh fo|qr _.krk de gSA½

38. H2S  (CH3COO)2 Pb  PbS  2CH3COOH

black
PbS + 4H2O2  PbSO4  4H2O
white

Sol. H2S  (CH3COO)2 Pb  PbS  2CH3COOH

dkyk
PbS + 4H2O2  PbSO4  4H2O
'osr

40. Factual question.

rF;kRed iz'u

41. 3X2 + 8NH3  N2 + 6NH4X

(X : F, Cl, Br)
–
42. NO3 gives NO2 with conc. H2SO4 which on passing through water form colourless HNO 3() and
HNO2().
–
Br + MnO2 on heating with conc. H2SO4 gives Br2 gas which on passing through water imparts it a
reddish brown colour.

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 –
Sol. NO3 lkUnz H2SO4 ds lkFk NO2 nsrk gS ftls ty esa izokfgr djus ij jaxghu HNO3() rFkk HNO2() cukrk gSA
–
Br + MnO2 dks lkUnz H2SO4 ds lkFk xeZ djus ij Br2 xSl nsrk gS ftls ty esa izokfgr djus ij ;g yky&Hkwjk
jax gks tkrk gSA

47. 6 XeF4  12H2O  4 Xe  2XeO3  24HF  3O2

XeF6  3H2O  XeO3  6HF
Hence, (1) is correct
blfy,] (1) lgh gSA

48. (I) They do not form compounds readily as they are chemically inert on account of stable electron
configuration.
(II), (III) & (IV) are correct statement.
Sol. (I) ukscy xSlsa 'kh?kzrk ls ;kSfxd ugha cukrh gSa D;ksafd buesa LFkk;h bysDVªkWfud foU;kl gksus ds dkj.k ;s jklk;fud
:i ls fuf"Ø; gksrh gSA
(II), (III) rFkk (IV) lgh dFku gSAa

º –0.0591 [H ]2
61. Ecell = Ecell log 2 
2 [N ][H2 ]
–0.0591
 º
Ecell – Ecell log [H+] = 0.0591 × pH  pH = 1
1
H2  2H+ + 2e–
Ni2+ + 2e–  Ni(s)
H2 + Ni2+  2H+ + Ni(s).

2H SO  H S O  2H  2e 

63. (A) Anode  2 4 2 2 8

2H2O  O2  4H  4e 
Cathode {2H2O  H2 + 2OH – 2e } × 3.
– –

Net : 2H2SO4 + 8H2O  H2S2O8 + O2 + 3H2 + 6H+ + 6OH–

Hence ratio of nO2 and nH2 is 1 : 3.
2H SO  H S O  2H  2e 
Sol. (A) ,uksM  2 4 2 2 8

2H2O  O2  4H  4e 
dSFkksM {2H2O  H2 + 2OH– – 2e–} × 3.

ifj.kkeh : 2H2SO4 + 8H2O  H2S2O8 + O2 + 3H2 + 6H+ + 6OH–

bl izdkj nO2 rFkk nH2 dk vuqikr 1 : 3 gSA

1  t1/ 2 1 A 
2
64. t1/ 2  =  2 .
(a0 )n 1  t1/ 2 2  A1 

66. 4A(g)   B(g) + 2C(g)

t=0 800 – –
t = 8 minutes, 800 – 4p p 2p
800 – p = 650  p = 150 Pressure of A = 200, so
 2 x t1/2 = 8 minutes t1/2 = 4 minutes
Sol. 4A(g)   B(g) + 2C(g)
t=0 800 – –
t = 8 feuV, 800 – 4p p 2p
800 – p = 650  p = 150 A dk nkc = 200, blfy,
 2 x t1/2 = 8 feuV t1/2 = 4 feuV

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67. A C
Kf 0.3 1 [C]
 = = KC = =
Kb 0.6 2 [A]
2C 2A
1
KC' = 2 = 4.
K

69. PbO2 + 2HNO3  Pb(NO3)2 +1/2 O2 + H2O

2MnO2 + 2H2SO4  2MnSO4 + H2O + O2
2 KMNO4 + 16HCl  2KCl + 2MnCl2 + 8H2O + 5Cl2

70. Cl2O7 + H2O  2HClO4; Cl2O3 + H2O  2HClO2; 2NO2 + H2O  HNO2 + HNO3
2ClO2 + H2O  HClO2 + HClO3
Cl2O5 + 2H2O  2HClO3

71. 5 (Cd2+(aq), Ni2+(aq), Zn2+(aq), Cu2+(aq), Ag+(aq))

5 (Cd2+(tyh;), Ni2+(tyh;), Zn2+(tyh;), Cu2+(tyh;), Ag+(tyh;))

72. 4 ((NH4)3PO4.12MoO3)

73. H2C2O4, Cu, Ag, FeSO4, S8, Na2S2O3 will oxidized & reduce conc. HNO3 to NO2, Fe will be passivated.
gy H2C2O4, Cu, Ag, FeSO4, S8, Na2S2O3 vkWDlhÑr gksaxs rFkk HNO3 dk NO2 esa vipf;r djsaxs] Fe fuf"Ø; jgsxkA

74. H3PO4, Ca(H2PO4)2, CaHPO4, HF, CaSO4 can be obtained, not others.
H3PO4, Ca(H2PO4)2, CaHPO4, HF, CaSO4 izkIr gks ldrs gS] vU; ughaA

75. H2SO4, H2SO3, H3PO3, H4P2O5 are diprotic. HCl, HNO3, H3PO2, H3BO3 are monoprotic.
Sol. H2SO4, H2SO3, H3PO3, H4P2O5 f}{kkjh; gSaA HCl, HNO3, H3PO2, H3BO3 ,d {kkjh; gSA

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