3:

04) :
HCOOH + CH 3COOH :

HCOO + CH 3COOH

n
n

HCOO

n1

5 mmol

n 2 = C V2

CH 3COOH

Qr i

C V1

CH3COOH

HCOO

CH 3COO

HCOOH

10 mmol

CH 3COOH
CH 3COO
CH 3COOH

CH 3COO

3
C r2O

.3

HCOO

HCOOH

2
7

+ 8H

2
7

2 C r 3+ + 7 H 2O

2 C O 2 + 2H + + 2 )

( H 2C 2O 4
+ 3 H 2C 2O 4

2 Cr

Cr2O + 8 H3O +3 H2C2O4

3+

.1

+ 7 H 2O + 6 C O 2

2 Cr + 15 H2O + 6 CO2
.2

H 3O

H 3O

2
7

.4
t = 0
-

Q ri

H C O O H + C H 3C O O H

3+

Cr2O + 8 H3O +3 H2C2O4

Ka 2
= 0,1
Ka 1

- II

n1 = Cv
=2mmol
n1 - x

"

n1
xmax

"

2 Cr + 15 H2O + 6 CO2

n2 =CV
= 8mmol

n2 3x

2x

n2 3xmax

2xmax

0
"

HCOO

+ C H 3C O O H

n2 = 10

n1 - x

n2 - x

8 - 3 xmax = 0

n1 xf

n2 - xf

xf

xf

2 - xmax 0

CH3COOH
CH 3COO

q
q

HCOO
HCOOH

(n1

x V
x f )(n 2
V2

xf )

x
:
(n1 x f )(n1 x f )

v =
3-

Cr 3

(1 )

xf

m mol

xmax = 2 m mol
( .3
= 40 s

= 0175 m mol / L.s

= 20 mmol/L :

(
.

1,67

xf
= 0,33
x max

xf
1,67
=
= 11,1 mmol/L
V
0,15
n -x
3,33
HCOO = 1 f =
= 22,2 mmol/L
V
0,15
n - xf
8,33
=
= 55,5 mmol/L
CH 3COOH = 2
V
0,15

10 mmol/L
2

HCOOH =

2 . 10
0,2

7
40

8
3

5 mmol

xmax

: t = 40 s

2
f

x f = - 1,33 x f = 1,67 :

x max

6xmax

.1

t
2

6x

"

n1 = 5

2
f

3+

HCOOH

HCOO

04 ) :

C r2O 72 + 14 H + + 6

.2

=0 :
q

.1

t 1 = 12 s :
2

.4

F + P + R
R

ND

+ f = m a

- m g co s (

) = m a

HCOOH / HCOO

:
V D2
= 164 N
r

= m

PH = 3,8 + log

04 ):

AAH

PH

22,2
= 4,1
11,1

04 ):
:

m = 4 m( He ) + 2m(e)

( .2
dq
d uc
i =
=C
dt
dt

u c = u 0 cos(

LC

t+

22,5 = 2,25 T0 :

.5

T02

.6

= 0,11 H : L
4 2 .C
2
q
E = E c E L = 12
+ 12 L i 2 : LC
C
d E
q
d q
d i
=
+ L i
d t
C
d t
d t
d q
d 2q
q
( L
+
)
d t 2
d t
C
:
d q
d 2u c
( L
+
u
)
c
d t 2
d t
d q
( 0 ) = 0
d t
L =

1,26 .10

34

1,66054 . 10-27 . 4 . 1,007

m(H)

.3

m (H ) = 10 % :

9,34 )

= 9 ,3 4 . 1 0
(

.4
9

1 an
m (H )
m '(H ) = 0 ,1 m
sol

ans

04 ) :
: AB

.7

E =

2
0

C u = 1,1 m J

:a
(

.1 - 1
( S )

F + P + RN + f = m a :

F - f = m ax

ax =

F - f
= 9 0 m /s 2 : AX
m

P + RN = m ay = 0
a x = 9 0 m /s

R N = mg

: AY

v x = 90 t + v 0 x = 9 0 t

x
1
2

.2

E'

m (H ) = 2,13 . 10 19 Kg

d 2u c
=0 :
dt 2

u c = u 0 cos(
LC = 10 m s

3,96 . 10-12

.3
uc

34

E ' = 4 . 10 . 365 . 24 . 3600 = 1,26 . 10 j :

uC (t )

uc + uL = 0 :

- 4 m(H) = 0,02650 u

26

) :

t+

.1

m . C2 = 3,96 . 10-12 J

E =

q = c uc

T0 = 2

.1

uC (t )
C

PH = PK a + log

1,2 m = 45 t 2

x
VB

1
2

.2

ax t2 + v0 xt + x0 = 45 t2
tA B

0,16 s

90 t A B = 14,7 m/s

:B D

E (B )

.3
:

w (F ) + w (f) = E (D )

V D = 12,3 m/s
:

:B

: VD

(1

: RN

(2